JP5157841B2 - Exhaust gas treatment method and treatment system for cement firing equipment - Google Patents

Description

  The present invention relates to an exhaust gas treatment method and treatment system for a cement firing facility using a chlorine bypass that suppresses an increase in the chlorine concentration in the system of the cement firing facility.

  In recent years, in order to solve the problem of waste disposal, various types of waste have been used as part of cement raw materials or part of heating fuel in cement kilns. However, in particular, when waste such as synthetic resin is introduced into the cement kiln as part of the fuel, a volatile chlorine component is generated during combustion. Such a chlorine component is accompanied by the exhaust gas discharged from the cement kiln and is sent to the upstream preheater. However, if the ambient temperature becomes lower than the melting point as it is transferred to the upper stage of the preheater, it is condensed. Then, it adheres to the cement raw material, is sent again into the cement kiln, and evaporates again as the ambient temperature rises.

  As described above, the chlorine component taken into the system of the cement firing facility is repeatedly circulated and evaporated in the cement kiln and the preheater, and the chlorine component generated from the newly input waste is added thereto. As a result, the concentration of the preheater is increased due to coaching, which hinders stable operation and adversely affects the quality of the manufactured cement clinker.

  In order to solve the above problems, for example, in Patent Document 1 below, a process of extracting a part of the kiln exhaust gas from the kiln, a process of cooling the extracted exhaust gas below the melting point of the chlorine compound, and the exhaust gas A kiln exhaust gas treatment method comprising a process of separating dust inside into coarse powder and fine powder, and a process of returning the separated coarse powder to the kiln and sending the fine powder downstream of the classifier. The ratio of the extraction amount of the kiln exhaust gas is more than 0% and not more than 5%, the separation particle size in the classifier is 5 μm to 7 μm, and the amount of fine powder delivered is 0.1% of the kiln production amount A kiln exhaust gas treatment method using chlorine bypass, characterized by the following, has been proposed.

According to the kiln exhaust gas treatment method having the above configuration, the exhaust gas containing fine dust having a high chlorine content separated in the classifier is sent to a dust collector, and the fine dust having a high chlorine concentration is collected and discharged out of the system. As a result, the rotary kiln can be operated stably, chlorine can be removed effectively with minimal heat loss, and the amount of extracted gas can be reduced, resulting in a smaller processing facility and lower space and equipment costs. It is said that the effect that the stable operation of the kiln can be secured economically is obtained.
Japanese Patent No. 3318714

  However, in the above conventional kiln exhaust gas treatment method, the particle size of the fine dust recovered by the dust collector is set to a very fine particle size range of 5 μm to 7 μm or less, so that it is widely used as a classifier. There is a problem in that the installation cost increases because it is not possible to use a thing, and it is necessary to install a high-performance one and to require fine control during operation.

  In addition, as a result of collecting fine fine dust, the chlorine concentration in the collected fine dust becomes extremely high. For this reason, if the chlorine concentration of the fine dust exceeds 20%, the handleability of the recovered fine dust is greatly reduced due to the deliquescence of the chlorine compound adsorbed on the fine dust, There is also a problem that accidents such as hopper clogging and chute clogging are likely to occur due to fine powder dust adhering to the inner peripheral walls of the transfer pipe, hopper, etc. (coaching). As a result, there are problems that it is difficult to perform a stable operation and the maintenance cost increases.

Furthermore, when the organic waste sludge such as sewage sludge is introduced into the kiln bottom part of the cement kiln or the calcining furnace as the waste, the chlorine is contained in the exhaust gas as shown in the following formula. Metal chloride (KCl, NaCl) reacts with water contained in the organic sludge and CO ₂ and SO ₂ in the exhaust gas to form sulfate and carbonate, and hydrogen chloride (HCl) is generated.

2KCl + SO ₂ + (1/2) H ₂ O → K ₂ SO ₄ + 2HCl
2KCl + CO ₂ + H ₂ O → K ₂ CO ₃ + 2HCl
And even if hydrogen chloride taken in in exhaust gas in this way is cooled to near normal temperature, most of it exists as vapor.

  For this reason, depending on the conventional kiln exhaust gas treatment method, although the chlorine content entrained as a metal oxide can be collected, the hydrogen chloride cannot be collected. As a result, the chlorine in the chlorine bypass can be collected. There has been a problem that the amount of bypass (the amount of chlorine removed per unit bleed gas amount) is reduced. In addition, since hydrogen chloride (HCl) remains in the exhaust gas, it cannot be discharged into the atmosphere as it is, and there are also problems such as corrosion of the apparatus due to the generation of acid dew point.

Further, in general, in the above cement manufacturing facility, the amount of dust contained in the extracted gas varies greatly depending on the operating state of the cement kiln, the state of adhesion of the coating, or the change in the rotational speed of the cement kiln.
For this reason, the amount of dust recovered in the chlorine bypass also changes greatly, and as a result, the quality of the recovered dust also fluctuates. There was a risk of adverse effects.

  The present invention has been made in view of such circumstances, and can improve the handleability of the recovered fine powder dust, thereby realizing a maintenance-free stable operation and incinerating organic sludge. An object of the present invention is to provide an exhaust gas treatment method and treatment system for a cement firing facility that can smoothly remove hydrogen chloride generated due to the above.

In order to solve the above problems, the present inventors have examined the influence of the chlorine concentration and the particle size of fine dust on the handling properties.
First, although the average particle | grains of cement raw material powder are distributed from the maximum 200 micrometers to the minimum several micrometers, it is about 20 micrometers-about 30 micrometers. Therefore, when the classification particle size of the dust from the extraction gas is set to 10 μm or less, most of the dust finally collected from the extraction gas becomes chlorine particles, and extremely fine cement raw material powder is mixed in this. Conceivable.

  Therefore, when the classified particle size is 10 μm or less, in addition to the rapid increase in chlorine concentration, the collected fine dust becomes cotton-like, resulting in extremely deteriorated handling properties and clarification of chlorine components. As a result, it has been found that coaching that causes blockage and clogging of equipment is likely to occur. It has also been found that if the chlorine concentration in the fine powder dust is suppressed to 20% or less, adhesion of fine powder dust and clogging due to coating can be prevented in the conveyance process.

  Next, the extraction gas from the cement kiln is cooled to below the melting point of the chlorine compound, the dust having a particle size of about 25 μm or more is separated from the extraction gas by a cyclone type classifier, and then the fine dust having a particle size of about 25 μm or less by a bag filter. When collecting the cement raw material positively in the extraction gas, the dust concentration in the extraction gas was changed, and the influence on the chlorine concentration of the fine dust was observed. As shown, it was confirmed that the chlorine concentration decreased as the dust concentration increased.

  Further, if the cement raw material is positively dispersed in the exhaust gas from the extracted cement kiln, the dust concentration in the extraction gas increases and the temperature of the exhaust gas decreases. Then, it was found that this relationship is generally proportional as shown in FIG.

  Therefore, from FIG. 2 and FIG. 3, as shown in FIG. 4, the dust concentration in the extracted gas is adjusted by adjusting the temperature of the extracted gas by dispersing the cement raw material, and finally collected fine dust It came to the knowledge that the chlorine concentration of can be easily controlled. And it became clear by the said confirmation test that in order to make the said chlorine concentration into 20% or less which does not affect the handling property mentioned above, the temperature of extraction gas should just be made into 1150 degreeC or less.

  Further, when separating the coarse dust from the extracted gas by the cyclone classifier, if the classification particle size is reduced, the particle size of the fine dust is reduced, so that the chlorine concentration in the fine dust is also increased. However, when the classification particle size is set to 10 μm or less as described above, most of the dust finally collected from the extraction gas becomes chlorine particles, and the chlorine concentration rapidly increases thereby. More preferably, if the adjustment is made within a range of 12 μm or more, the chlorine concentration can be suppressed to 20% or less as long as the temperature of the extraction gas is set to 1150 ° C. or less.

Furthermore, according to the study by the present inventors, as described above, when a larger amount of cement raw material is dispersed in the extracted gas than in the past in order to improve the handling property of the recovered fine dust, Since the cement raw material at the bottom of the preheater or the kiln bottom of the cement kiln contains a large amount of highly active CaO after calcination, hydrogen chloride gas (HCl) in the extraction gas reacts with the CaO to cause CaCl It was found that ₂ was produced and could be effectively recovered by dust trapping means such as a bag filter.

  That is, as shown in FIG. 5, the amount of dust collected by the dust collecting means when the sewage sludge is introduced as organic sludge at 50 kg (50 kg / t-cli) per ton of clinker and incinerated (unit bleed air volume) The amount of the chlorine bypass was measured while changing the amount of dust collected per unit. As a result, when the amount of collected dust is increased, that is, when the amount of cement raw material dispersed is increased to increase the dust concentration in the extraction gas, the amount of chlorine bypass increases as shown by the dotted arrow in the figure, and the above-mentioned chloride It was found that the recovery effect of hydrogen gas was manifested.

By setting the recovered dust amount to 50 g / m ³ N or more, the chlorine bypass amount reaches approximately 8 g-Cl ⁻ / m ³ N, and even if the recovered dust amount is further increased, the chlorine bypass amount is large. It was also found that there was no change.
Therefore, it was found that by setting the recovered dust amount in the range of 50 to 150 g / m ³ N, it is possible to effectively recover hydrogen chloride gas contained in the exhaust gas without recovering excessive dust.

By the way, when the recovered dust amount is set in the range of 50 to 150 g / m ³ N, as shown in FIG. 6, the classification particle size in the cyclone classifier (solid-gas separation means) is adjusted in the range of 15 to 30 μm. This confirmed that the recovered dust amount could be maintained in the range of 50 to 150 g / m ³ N. However, the amount of dust in the extracted gas may increase due to fluctuations in the operation state of the cement kiln, the adhesion state of the coaching, and the like.

  In such a case, the extracted gas on the downstream side of the cyclone classifier (solid-gas separation means) has a low dust concentration as a result of the removal of coarse dust, so that the extracted gas is extracted again from the exhaust gas. Therefore, it has also been found that it is possible to cope with this by reducing the dust concentration of the extracted gas extracted from the exhaust gas.

The present invention has been made on the basis of such knowledge. The invention according to claim 1 is a method in which a cement raw material is fired in a cement kiln and organic sludge is introduced into a kiln bottom portion or a calciner of the cement kiln. In a cement manufacturing facility to be incinerated, a part of exhaust gas containing dust discharged from the cement kiln and sent to a preheater for preheating the cement raw material is provided at the lowermost part of the preheater or the kiln bottom of the cement kiln. The extracted gas is extracted as an extracted gas, and after the extracted gas is cooled below the melting point of the chlorine compound, the dust having a predetermined particle size or more is separated from the extracted gas by a solid-gas separation means, and the cement raw material is fired. And returning from the extracted gas containing fine dust having the predetermined particle size or less by the dust capturing means. An exhaust gas treatment method for a cement firing facility for removing chlorine compounds contained in the extraction gas by collecting and removing powder dust, wherein the exhaust gas at the bottom of the preheater or the kiln bottom of the cement kiln In addition, by dispersing the cement raw material and adjusting the amount of dispersion, the temperature of the extraction gas is maintained in the range of 950 ° C. to 1150 ° C., and the predetermined particle size in the solid-gas separation means is 15 μm to 30 μm. The amount of the fine dust recovered in the dust trapping means is adjusted to 50 to 150 g / m ³ by adjusting the pressure within the range and circulatingly supplying the extraction gas extracted from the downstream side of the solid-gas separation means to the probe. While holding in the range of N, the chlorine concentration of the collected fine dust is held in the range of 5 to 20%. It is intended.

Here, as the cement raw material to be dispersed in order to adjust the temperature of the extraction gas, that is, the dust concentration in the extraction gas, the cement charged mainly into the kiln bottom through the raw material chute from the lowermost stage of the preheater. It is preferable to use raw materials.
In addition to the dispersion of the cement raw material in the exhaust gas, in order to adjust the temperature of the kiln bottom, that is, the temperature of the extraction gas, a lower temperature cement raw material extracted from the pre-heater auxiliary, A cement raw material (so-called raw material) before being conveyed to the preheater, which is a cement raw material after various raw materials are mixed and dried to form a cement raw material, may be introduced into the kiln bottom.

Next, the invention according to claim 2 is provided in a cement manufacturing facility in which a transfer pipe for introducing and incinerating organic sludge is connected to a kiln bottom portion of a cement kiln for calcining cement raw material or a calcining furnace. A cement for removing a chlorine compound contained in the extracted gas by extracting a part of exhaust gas containing dust discharged from the cement kiln and sent to a preheater for preheating the cement raw material as an extracted gas An exhaust gas treatment system for a firing facility, wherein a probe for extracting the extraction gas is provided at a lowermost part of the preheater or a kiln bottom of the cement kiln, and the extraction gas is disposed along an extraction duct connected to the probe. Cooler below the melting point of the chlorine compound, and the dust having a predetermined particle size or more is separated from the extracted gas exhausted from the cooler. Solid gas separation means, dust trapping means for collecting and removing fine dust particles of the predetermined particle size or less accompanying the extracted gas from which the dust particles of a predetermined particle size or more have been separated in the solid gas separation device, and the dust trapping device A dust amount detecting means for measuring the amount of the fine dust recovered from, an induction fan provided downstream of the dust capturing means for sucking the extracted gas, and one end portion downstream of the solid-liquid separating means The dust concentration control is connected to the bleed duct, and the other end is connected to the probe and an air supply fan is interposed to circulate a part of the bleed gas flowing through the bleed duct to the probe. Means is provided at the bottom of the preheater or inside the kiln bottom of the cement kiln and in the vicinity of the connection portion of the extraction duct, Dispersing means for dispersing the material is provided, driving means for adjusting the amount of the cement raw material to be dispersed by the dispersing means, temperature detecting means for detecting the temperature of the extracted gas, and detected by the temperature detecting means A first control device that controls the driving means based on temperature to maintain the temperature of the extracted gas in a range of 950 ° C. to 1150 ° C., and the amount of fine dust detected by the dust amount detecting means is 50 The predetermined particle size in the solid-gas separation means is in the range of 15 μm to 30 μm so that the chlorine concentration of the collected fine dust is in the range of 5 to 20% while being held in the range of −150 g / m ³ N. A part of the extracted gas extracted from the downstream side of the solid gas separation means by driving the air supply fan of the dust concentration control means and controlling the drive. By comprising a circularly supplying the second control device to the serial probe is characterized in.

The invention according to claim 3 is the invention according to claim 2, wherein the solid-gas separation means is a cyclone type classifier, and the flow rate of the extraction gas is adjusted to the inlet side of the cyclone type classifier. An apparatus is provided, and the dust capturing means is a bag filter, and a chlorine concentration detection device for the fine dust recovered from the bag filter is provided, and the second control device is provided for the chlorine concentration detection means. Based on the detection signal and the detected amount of the dust amount detecting means, the amount of the fine dust recovered in the dust capturing means is in the range of 50 to 150 g / m ³ N, and the chlorine of the recovered fine dust By controlling the amount of suction of the extraction gas by the induction fan and / or the flow adjustment device of the extraction gas so that the concentration is in the range of 5 to 20%. The predetermined particle size is adjusted within a range of 15 μm to 30 μm, and a part of the extracted gas extracted from the downstream side of the solid gas separation unit by drivingly controlling the air supply fan of the dust concentration control unit is supplied to the probe. It is characterized by circulating supply.

  According to the invention of any one of claims 1 to 3, by collecting and removing fine dust dust having a high chlorine concentration contained in the extraction gas by the dust trapping means, the chlorine concentration in the system can be reduced. The rise can be prevented. In addition, by dispersing the cement raw material in the exhaust gas at the bottom of the preheater where the extraction gas is extracted or the kiln bottom of the cement kiln, the temperature of the extraction gas is easily maintained in the range of 950 ° C to 1150 ° C. The chlorine concentration of the fine dust finally collected can be reduced to 20% or less.

  For this reason, while being excellent in the handling property of the said fine powder dust, the chlorine component contained in the said fine powder dust during conveyance does not have a possibility that problems, such as obstruction | occlusion and clogging, may arise, and can operate stably.

Moreover, since the amount of the fine dust recovered in the dust capturing means is set in the range of 50 to 150 g / m ³ N, hydrogen chloride gas resulting from incineration of organic sludge contained in the exhaust gas Also, it can be effectively recovered by the dust trapping means as CaCl ₂ by reacting with CaO having a high activity in the cement raw material after calcination.

Further, in this type of conventional cement manufacturing facility, when a bag filter is used as a dust trapping means, the SO ₂ gas contained in the extraction gas is downstream of the bag filter in which the atmosphere is below its dew point temperature. In order to cause corrosion in the exhaust gas duct etc. on the side, there is a problem that a lot of work such as maintenance is required.

In this respect, in the present invention, since a cement raw material containing more CaO than that in the past is entrained in the extraction gas, a CaO layer is formed on the surface of the filter cloth of the bag filter, and in this CaO layer, and sO ₂ in the extracted gas, to sO ₃ caused by the oxidation is fixed as CaSO ₃ and CaSO ₄ are chemically absorbed, due to sO ₂ and sO ₃ contained in the extracted gas as described above An additional effect that sulfuric acid corrosion can also be reduced is obtained.

  In addition, since the classification particle size in the solid-gas separation means may be adjusted within the range of 15 μm to 30 μm, a general-purpose cyclone classifier or the like can be used as the solid-gas separation means, which may increase the equipment cost. Nor.

  Here, the temperature of the extraction gas is set to 950 ° C. or more, and as a result, the chlorine concentration in the fine dust is set to 5% or more. When the cement raw material is dispersed in the exhaust gas so that the temperature of the extraction gas becomes 950 ° C. or less, This is because the heat loss becomes large and the economy is inferior, and the dust gas dust concentration becomes excessively high. As a result, the volume of fine dust that is finally collected and removed becomes large, which is inconvenient.

In addition, the classification particle size in the solid-gas separation means is set to 15 μm to 30 μm, as described above, if the classification particle size is less than 15 μm, the ratio of chlorine particles in the fine dust rapidly increases, and as a result, the chlorine in the fine dust This is because it becomes difficult to keep the concentration to 20% or less and to keep the amount of fine dust in the range of 50 to 150 g / m ³ N. On the other hand, when the classified particle size exceeds 30 μm, the amount of fine dust However, the amount of fine dust to be finally disposed exceeds 150 g / m ³ N, whereas the tendency to increase the amount of chlorine bypass is not observed, which is uneconomical.

  Further, as described above, as the cement raw material that is dispersed in the exhaust gas and increases the dust concentration in the extraction gas, the cement raw material that is introduced into the kiln bottom through the raw material chute from the lowest stage of the preheater is used. For example, it is not necessary to significantly change existing facilities, and since the temperature of the cement raw material is high, it is preferable because it contains a large amount of activated CaO. In addition, it is necessary to disperse a relatively large amount in order to adjust the temperature. Therefore, the dust concentration in the extraction gas can be increased, and the chlorine concentration of the fine dust can be easily reduced to 20% or less. is there.

  Further, in parallel with the dispersion of the cement raw material charged from the raw material chute to the kiln bottom, the cement raw material at 600 ° C. to 700 ° C. in the preheater and the temperature before being conveyed to the preheater are 50 ° C. to 100 ° C. When raw materials of cement as low as ℃ are supplied for temperature adjustment in the kiln bottom, these cement materials are much lower in temperature than the cement material from the material chute. By dispersing in a small amount, the temperature of the extraction gas can be efficiently reduced.

  In addition to this, in the present invention, the dust concentration in the extraction gas is increased as compared to the conventional case, whereas the extraction gas having a low dust concentration extracted from the downstream side of the solid-gas separation means is used as described above. Since the dust concentration of the extracted gas extracted from the exhaust gas can be reduced by circulating supply to the probe, the operating state of the cement kiln and the adhesion state of the coaching fluctuate, and the amount of dust in the extracted gas becomes excessive. Even when the height is increased, it is possible to prevent draft inhibition occurring in the extraction duct.

FIG. 1 shows an embodiment of an exhaust gas treatment system for cement burning equipment according to the present invention.
First, the cement manufacturing facility provided with the exhaust gas treatment system will be described. Reference numeral 1 in the figure denotes a cement kiln for firing cement raw materials. This cement kiln 1 is a rotary kiln provided so as to be rotatable around an axis, and a kiln butt portion 2 comprising a kiln butt housing 2a for supporting the rotary portion and its rising portion 2b at the left end in the figure. Is provided.

  A preheater 3 for preheating the cement raw material is provided on the upstream side of the kiln bottom 2, and a main burner for heating the inside is provided in front of the right kiln (not shown) in the drawing. Is provided.

  Here, the pre-heater 3 is composed of a plurality of (for example, four) cyclones arranged in series in the vertical direction, and the lowermost (fourth) cyclone 3a is sequentially moved downward from the upper cyclone. The sent cement raw material is supplied, and a raw material chute 4 for connecting the internal cement raw material to the kiln bottom 2 of the cement kiln 1 is connected to the bottom of the cyclone 3a.

  On the other hand, an exhaust pipe 5 for supplying the combustion exhaust gas discharged from the cement kiln 1 to the lowermost cyclone is connected to the rising part 2b of the kiln bottom part 2, and is discharged from the upper part of the uppermost cyclone. Exhaust exhaust gas is exhausted through an exhaust line by an exhaust fan.

  Furthermore, in this cement manufacturing facility, a transfer pipe 25 is connected to the kiln bottom part 2 of the cement kiln 1 for introducing and incinerating sewage sludge (organic sludge) directly into the interior while containing water.

And the exhaust gas treatment system called a chlorine bypass is attached to the cement manufacturing equipment which consists of the said structure.
This processing system is for extracting a part of exhaust gas containing dust discharged from the cement kiln 1 and sent to the preheater 3 as extraction gas, and removing chlorine compounds contained in the extraction gas. In the figure, reference numeral 26 is a cylindrical probe connected to the rising portion 2b of the kiln bottom 2 of the cement kiln 1 for extracting the extracted gas, and reference numeral 10 is connected to an end of the probe 26 to extract the extracted gas. It is a bleed duct that sends gas.

  In this processing system, along the extraction duct 10, a cooler 11 that cools the extraction gas extracted from the extraction duct 10, and dust of a predetermined particle size or more from the extraction gas exhausted from the cooler 11. A cyclone type classifier (solid gas separating means) 12 to be separated, and a bag filter (dust collecting means) for collecting and removing fine dust accompanying the extracted gas from which dust of a predetermined particle size or more has been separated in the cyclone type classifier 12 ) 13, an induction fan 14 provided on the downstream side of the bag filter 13 for sucking the extraction gas, and one end connected to the extraction duct 10 on the exhaust side (downstream side) of the cyclone classifier 12, and the other end A return line 27 having a portion connected to the probe 26 is provided, and in this return line 27, the air supply fan 2 that returns the extracted gas to the probe 26. There has been interposed.

  The return line 27 and the air supply fan 28 constitute dust concentration control means for circulating and supplying a part of the extracted gas from which coarse dust is separated in the cyclone classifier 12 to the probe 26.

  Here, the cooler 11 performs heat exchange with the extraction gas using, for example, the cooling air from the cooling fan or the cooling water from the cooling pump as a refrigerant, so that the temperature of the extraction gas is reduced to the melting point (600 to 700 ° C.) or less of the chlorine compound. It is to be cooled.

  In addition, a flow rate adjusting valve 15 whose opening degree can be adjusted by a motor 15a is interposed at the inlet of the extraction gas in the cyclone classifier 12. On the other hand, a return pipe 16 is connected to the bottom of the cyclone classifier 12 to return the separated dust having a predetermined particle size or more to the kiln bottom 2 again.

Further, on the suction side of the attracting fan 14, a flow rate adjusting valve 17 whose opening degree is adjustable by a motor 17a is interposed.
A dispersion plate (dispersing means) 18 for dispersing the cement raw material in the exhaust gas is provided in the kiln bottom 2.

  The dispersion plate 18 is a plate-like member formed in a shape such as a square, an ellipse, or a polygon. The plate surface is horizontal and directly below the drop 4 a of the raw material chute 4. It is provided so that it can be moved in and out. This dispersion plate 18 is for dispersing the cement raw material falling from the drop opening 4a in the exhaust gas in the kiln bottom 2, and at the base end portion, the dispersion plate 18 is made to appear and drop to form the drop opening 4a. A drive motor (driving means) 19 is provided for adjusting the amount of cement raw material to be dispersed by changing the area located immediately below.

  Furthermore, in this exhaust gas treatment system, a temperature detector (temperature detection means) 20 for detecting the temperature of the extraction gas is provided in the vicinity of the connection portion of the extraction duct 10 at the rising portion 2b of the kiln bottom 2. Is provided. And based on the detection signal from this temperature detector 20, the drive motor 19 is operated and the dispersion | distribution plate 18 is made to appear and retracts, The 1st control which maintains the temperature of extraction gas in the range of 950 degreeC-1150 degreeC. A device 21a is provided.

  Further, a dust amount detecting means 22 for detecting the amount of collected fine dust and a chlorine concentration detecting means 23 for detecting the chlorine concentration in the fine dust are installed at the bottom of the bag filter 13.

When the detection signal from the chlorine concentration detection means 23 is less than 5%, and when the detection signal is more than 20%, and the fine dust amount detected by the dust amount detection means 22 is 50 g. / m ³ when it becomes a value less than N, and when a value of greater than 150 g / m ³ N, while maintaining the amount of the fine powder dust in the range of 50 to 150 g / m ³ N, collecting A second control device 21b is provided for controlling the chlorine concentration of the fine powder dust to be in the range of 5 to 20%.

The second control device 21b first operates the motor 15a and / or the motor 17a to open and close the flow rate adjusting valve 15 and / or the valve 17 to change the flow rate of the extracted gas, thereby changing the cyclone type classifier. 12 is adjusted within a range of 15 μm to 30 μm to keep the amount of fine dust in a range of 50 to 150 g / m ³ N, and the chlorine concentration of the collected fine dust is 5 to 20 Control to be in the range of%.

Further, only by adjusting the classification particle size in the cyclone type classifier 12, particularly when the fine dust amount detected by the dust amount detection means 22 becomes a value exceeding 150 g / m ³ N, the air supply fan 28 is adjusted. A part of the extraction gas having a low dust concentration extracted from the extraction duct 10 on the downstream side of the cyclone classifier 12 by operating is supplied to the probe 26 from the return line 27.

  The second control device 21b performs inverter control of the suction amount by the induction fan 14 together with or in place of the control of the valves 15 and 17, thereby controlling the extraction gas in the cyclone type classifier 12. It can also be configured to adjust the flow rate. The entire control device 21 is configured by the first and second control devices 21a and 21b.

  In addition, the rising portion 2b includes a cement raw material of 600 ° C. to 700 ° C. from the third-stage cyclone and a raw material of cement as low as 50 ° C. to 100 ° C. before being transferred to the preheater 3. An introduction pipe (not shown) for introduction for temperature adjustment in the kiln bottom 2 is connected.

Next, an embodiment of the exhaust gas treatment method according to the present invention using the exhaust gas treatment system having the above configuration will be described.
First, in this cement baking equipment, the cement raw material supplied to the first-stage cyclone of the preheater 3 from a supply pipe (not shown) from the cement kiln 1 that rises from below as it sequentially falls to the lower cyclone. It is preheated by the high-temperature exhaust gas and is finally introduced into the kiln bottom 2 of the cement kiln 1 through the raw material chute 4 from the lowermost cyclone 3a.

  And in this cement kiln 1, it is heated to about 1450 ° C. by the combustion exhaust gas from the main burner in the process of being gradually sent to the right side in the figure from the kiln bottom 2 side to the kiln front side. Become. Next, the clinker that has reached before the kiln is dropped into the clinker cooler and sent. At this time, it is cooled to a predetermined temperature by the air supplied into the clinker cooler and finally taken out from the clinker cooler.

In parallel with this, sewage sludge (organic sludge) is introduced into the cement kiln 1 from the kiln bottom 2 side through the transfer pipe 25 and incinerated in a high-temperature atmosphere. Used as part of raw materials.
In the above-described cement clinker manufacturing process, 1% or more of the amount of exhaust gas discharged from the cement kiln 1 by the induction fan 14 continuously or intermittently is extracted from the kiln bottom 2 of the cement kiln 1 to the extraction duct 10. It bleeds as bleed gas through.

  At this time, the dispersion plate 18 is positioned below the outlet 4a of the raw material chute 4 to disperse the cement raw material falling from the raw material chute 4 in the exhaust gas, and at the same time, the first controller 21a controls the temperature detector 20. By operating the drive motor 19 so that the temperature of the bleed gas detected by the above is maintained in the range of 950 ° C. to 1150 ° C., the dispersion plate 18 is advanced and retracted below the outlet 4a of the raw material chute 4 and exhaust gas is discharged. Adjust the amount of cement raw material dispersed in.

  In parallel with the dispersion of the cement material by the dispersion plate 18, the material is conveyed from the introduction pipe connected to the rising portion 2 b to the cement material at 600 ° C. to 700 ° C. from the third-stage cyclone or to the preheater 3. The temperature of the kiln bottom part 2 can also be adjusted by introducing into the kiln bottom part 2 a cement raw material having a low temperature of 50 ° C. to 100 ° C. before being processed.

  Next, the extracted gas is cooled to a temperature below the melting point (600 ° C. to 700 ° C.) of the chlorine compound in the cooler 11 and then sent to the cyclone type classifier 12 to separate coarse dust with a classification particle size in the range of 15 μm to 30 μm. Then, the coarse dust is returned from the return pipe 16 to the kiln bottom 2 again.

  On the other hand, the extracted gas that is finer than the classified particle size and thus contains fine dust with a high chlorine concentration is removed from the extracted gas by collecting the collected fine dust that is sent to the bag filter 13 and collecting it. Thereby, the raise of the chlorine concentration in the system of the cement kiln 1 and the preheater 3 is prevented. Then, the extracted gas from which the fine dust has been removed is sent from the exhaust side of the induction fan 14 to the exhaust gas line and exhausted.

  Further, regarding the fine dust collected by the bag filter 13, the amount is detected by the dust amount detection means 22, and the chlorine concentration is detected by the chlorine concentration detection means 23.

When the chlorine concentration of the fine dust deviates from the range of 5 to 20%, or when the fine dust amount deviates from the range of 50 to 150 g / m ³ N, the second controller 21b first The amount of extraction gas drawn by the induction fan 14 and / or the opening degree of the valves 15 and 17 are adjusted by operating the motors 15a and 17a. Thereby, by adjusting the classification particle size in the cyclone type classifier 12 by increasing / decreasing the flow rate of the extraction gas flowing through the extraction duct 10, the recovered fine dust amount is kept in the range of 50 to 150 g / m ³ N. However, the chlorine concentration is controlled again within the range of 5 to 20%.

When the fine particle dust amount detected by the dust amount detection means 22 becomes a value exceeding 150 g / m ³ N only by adjusting the classification particle size in the cyclone classifier 12, the second control device 21b is used. Operates the air supply fan 28 and supplies a part of the extraction gas having a low dust concentration extracted from the extraction duct 10 on the downstream side of the cyclone classifier 12 to the probe 26 from the return line 27, thereby fine powder. The dust amount is kept in the range of 50 to 150 g / m ³ N.

Therefore, the fine dust which is stably recovered by the classification particle size in the cyclone type classifier 12 set in advance by maintaining the extraction temperature in the above-described range of 950 ° C. to 1150 ° C. by the first control device 21a. When the amount is in the range of 50 to 150 g / m ³ N and the chlorine concentration in the fine dust can be maintained in the range of 5 to 20%, the second control device 21b does not operate.

  As described above, according to the exhaust gas treatment method having the above-described configuration, by collecting and removing fine dust dust having a high chlorine concentration contained in the extracted gas extracted from the kiln bottom 2 by the bag filter 13, It is possible to prevent the chlorine concentration in the system including the cement kiln 1 and the preheater 3 from increasing.

  Moreover, the first control device moves the dispersion plate 18 based on the temperature of the extracted gas, adjusts the amount of cement raw material dispersed in the exhaust gas of the kiln bottom 2 where the extracted gas is extracted, and adjusts the temperature of the extracted gas. Is maintained in the range of 950 ° C. to 1150 ° C., the chlorine concentration of the fine dust that has been finally collected can be easily reduced to 20% or less.

  For this reason, while being excellent in the handling property of the said fine dust collected in the bag filter 13, there is no possibility that the chlorine component contained in the said fine dust during conveyance may cause troubles, such as obstruction | occlusion and clogging, and stable. Operations can be performed.

In addition, since the amount of fine dust collected in the bag filter 13 is set in the range of 50 to 150 g / m ³ N, hydrogen chloride gas resulting from incineration of organic sludge contained in the exhaust gas Also, it can be effectively recovered by the dust trapping means as CaCl ₂ by reacting with CaO having a high activity in the cement raw material after calcination.

Furthermore, since the cement gas containing more CaO than before is accompanied in the extraction gas, a CaO layer is formed on the surface of the filter cloth of the bag filter 13, and the CaO layer contains the extraction gas in the extraction gas. Since SO ₂ and SO ₃ generated by oxidation thereof are chemically absorbed and fixed as CaSO ₃ and CaSO ₄ , sulfuric acid corrosion caused by SO ₂ and SO ₃ contained in the extraction gas described above is also reduced. Can be made.

  Moreover, since it is only necessary to adjust the classification particle size of the coarse dust returned from the bleed gas to the kiln bottom part 2 within the range of 15 μm to 30 μm, a general-purpose cyclone classifier or the like can be used, which may increase the equipment cost. Nor.

In addition, in the said embodiment, although the probe 26 was provided in the kiln bottom part 2 of the cement kiln 1 and it demonstrated only about the case where exhaust gas was extracted from the said location, it is not limited to this, In preheater 3 A similar probe may be provided in the exhaust gas pipe 5 to extract air.
In addition to the cyclone classifier 12 and the bag filter 13 described above, various types of solid-gas separation means and dust trapping means can be used.

Further, as a driving means for the dispersion plate 18 and the valves 15 and 17, a driving source such as a hydraulic or pneumatic cylinder can be used in addition to the driving motor 19 and the motors 15a and 17a.
Further, without using the second control device 21b described above, based on the detection value obtained by the chlorine concentration detection means 23, the valves 15 and 17 are manually opened and closed, or the extraction gas by the induction fan 14 is manually operated. The suction amount may be switched.

It is a schematic block diagram which shows one Embodiment of the waste gas processing system of the cement baking equipment which concerns on this invention. It is a graph which shows the relationship between the dust concentration in the extraction gas in a cement baking equipment, and the chlorine concentration in the collected fine dust. It is a graph which shows the relationship between the temperature of the extraction gas in a cement baking equipment, and the dust density | concentration in extraction gas. It is a graph which shows the relationship between the temperature of the extraction gas obtained from the graph shown in FIG. 2 and FIG. 3, and the chlorine concentration in the collected fine dust. It is a graph which shows the relationship between the collection | recovery dust amount in a dust capture | acquisition means, and a chlorine bypass amount in a chlorine bypass. It is a graph which shows the relationship between the separation particle size in the solid-gas separation means in chlorine bypass, and the amount of collection | recovery dusts in a dust capture means.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Cement kiln 2 Kiln bottom part 3 Preheater 3a Bottom cyclone 4 Raw material chute 4a Drop port 10 Extraction duct 11 Cooler 12 Cyclone classifier (solid-gas separation means)
13 Bag filter (Dust capture means)
14 Induction fan 16 Return pipe 18 Dispersion plate (dispersion means)
19 Drive motor (drive means)
20 Temperature detector (temperature detection means)
21a 1st control device 21b 2nd control device 22 Dust amount detection means 25 Transfer pipe 25 of hydrous sludge (organic sludge)
26 Probe 27 Return line 28 Air supply fan

Claims (3)

To a preheater that preheats the cement raw material discharged from the cement kiln in a cement manufacturing facility that burns cement raw material in the cement kiln and introduces organic sludge into the kiln bottom of the cement kiln or calcining furnace. After extracting a part of the exhaust gas containing dust to be sent as extraction gas from the probe provided at the bottom of the preheater or the kiln bottom of the cement kiln, and cooling the extraction gas below the melting point of the chlorine compound The dust having a predetermined particle size or more is separated from the extracted gas by the solid gas separation means and returned to the firing step of the cement raw material, and the fine dust from the extracted gas containing the fine dust having the predetermined particle size or less by the dust capturing means. Chlorination compound contained in the extracted gas by collecting and removing Is the exhaust gas processing method of the cement burning facility to eliminate,
Maintaining the temperature of the extraction gas in the range of 950 ° C. to 1150 ° C. by dispersing the cement raw material and adjusting the dispersion amount in the exhaust gas at the bottom of the preheater or the kiln bottom of the cement kiln, In addition, the predetermined particle size in the solid-gas separation unit is adjusted within a range of 15 μm to 30 μm, and the extraction gas extracted from the downstream side of the solid-gas separation unit is circulated and supplied to the probe, thereby capturing the dust. Cement characterized by maintaining the chlorine concentration of the collected fine dust in the range of 5 to 20% while maintaining the amount of fine dust recovered in the means in the range of 50 to 150 g / m ³ N. Exhaust gas treatment method for firing equipment. The cement raw material that is discharged from the cement kiln and installed in a cement manufacturing facility in which a transfer pipe for introducing and incinerating organic sludge is installed in the kiln bottom part or calcining furnace of the cement kiln that fires the cement raw material. An exhaust gas treatment system for a cement firing facility for extracting a part of exhaust gas containing dust sent to a preheater for preheating as extraction gas and removing chlorine compounds contained in the extraction gas,
A probe for extracting the extracted gas is provided at the lowermost part of the preheater or the kiln bottom of the cement kiln, and cooling is performed to cool the extracted gas below the melting point of the chlorine compound along an extraction duct connected to the probe. A solid-gas separation means for separating the dust of a predetermined particle size or more from the extraction gas exhausted from the cooler, and the extraction gas accompanied by the dust of a predetermined particle size or more separated in the solid-gas separation means Dust capturing means for collecting and removing the fine dust of the predetermined particle size or less, dust amount detecting means for measuring the amount of the fine dust collected from the dust capturing means, and provided downstream of the dust capturing means. And an attracting fan for sucking the bleed gas and one end connected to the bleed duct on the downstream side of the solid-liquid separation means and the other end connected to the probe. And a dust concentration control means for circulating a part of the extraction gas flowing through the extraction duct to the probe by interposing an air supply fan, and provided at the bottom of the preheater or the cement kiln. Dispersion means for dispersing the cement raw material in the exhaust gas is provided inside the kiln bottom and in the vicinity of the connection portion of the extraction duct,
A driving means for adjusting the amount of the cement raw material to be dispersed by the dispersing means; a temperature detecting means for detecting the temperature of the extracted gas; and the driving means is controlled based on the temperature detected by the temperature detecting means. A first control device for maintaining the temperature of the extraction gas in a range of 950 ° C to 1150 ° C;
The amount of the fine dust detected by the dust amount detecting means is maintained in the range of 50 to 150 g / m ³ N, and the chlorine concentration of the collected fine dust is in the range of 5 to 20%. The extracted gas extracted from the downstream side of the solid gas separation means by adjusting the predetermined particle size in the solid gas separation means within a range of 15 μm to 30 μm and drivingly controlling the air supply fan of the dust concentration control means. And a second control device that circulates and supplies a part of the exhaust gas to the probe. The solid-gas separation means is a cyclone type classifier, the extraction gas flow rate adjusting device is provided on the inlet side of the cyclone type classifier, and the dust trapping means is a bag filter. A device for detecting the chlorine concentration of the collected fine dust is provided, and the second control device is configured so that the dust trapping means is based on the detection signal of the chlorine concentration detecting means and the detection amount of the dust amount detecting means. The extraction gas by the induction fan so that the amount of the fine dust to be recovered is in the range of 50 to 150 g / m ³ N and the chlorine concentration of the recovered fine dust is in the range of 5 to 20%. The predetermined particle size is adjusted within the range of 15 μm to 30 μm by controlling the suction amount and / or the flow rate adjusting device for the extracted gas, and 3. The cement according to claim 2, wherein a part of the extraction gas extracted from the downstream side of the solid gas separation means is circulated and supplied to the probe by drivingly controlling the air supply fan of the dust concentration control means. Exhaust gas treatment system for firing equipment.

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