JP5147186B2 - Water-liquid type cement crystal formation accelerator and its construction method - Google Patents
Water-liquid type cement crystal formation accelerator and its construction method Download PDFInfo
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- JP5147186B2 JP5147186B2 JP2006041503A JP2006041503A JP5147186B2 JP 5147186 B2 JP5147186 B2 JP 5147186B2 JP 2006041503 A JP2006041503 A JP 2006041503A JP 2006041503 A JP2006041503 A JP 2006041503A JP 5147186 B2 JP5147186 B2 JP 5147186B2
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- 239000004568 cement Substances 0.000 title claims description 34
- 239000013078 crystal Substances 0.000 title claims description 33
- 230000015572 biosynthetic process Effects 0.000 title claims description 26
- 238000010276 construction Methods 0.000 title claims description 15
- 239000007788 liquid Substances 0.000 title claims description 15
- 239000000463 material Substances 0.000 claims description 26
- 230000001737 promoting effect Effects 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 230000003197 catalytic effect Effects 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 7
- 230000035515 penetration Effects 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000001747 exhibiting effect Effects 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 230000000644 propagated effect Effects 0.000 claims 1
- 238000009751 slip forming Methods 0.000 claims 1
- 238000004458 analytical method Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- RYDFXSRVZBYYJV-TYYBGVCCSA-N (e)-but-2-enedioic acid;sodium Chemical compound [Na].OC(=O)\C=C\C(O)=O RYDFXSRVZBYYJV-TYYBGVCCSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 238000011041 water permeability test Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/04—Carboxylic acids; Salts, anhydrides or esters thereof
- C04B24/06—Carboxylic acids; Salts, anhydrides or esters thereof containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00293—Materials impermeable to liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
Description
本発明は、コンクリート構造物の恒久的防止水化、即ち不透水化と劣化抑止を図り、これをもって高耐久化を可能にするための触媒性化合物を含有する水液型セメント結晶形成促進材と、これを用いる方法に関する。 The present invention relates to a water-liquid type cement crystal formation promoting material containing a catalytic compound for achieving permanent prevention watering of concrete structures, that is, impermeability and deterring deterioration, and enabling high durability with this. , And a method of using the same.
従来のこの種の結晶形成促進材（以下、単に促進材と言う）にあっては、触媒性化合物あるいはそれに類する化合物、薬剤を配したものであっても、それらのコンクリートへの浸透拡散性と拡散後の躯体深部の必要濃度確保に充分対応できる材料は、本願発明者の知るところでは未だ皆無に等しい。公知のこれら促進材が含有する各種化合物、薬剤等のコンクリートへの浸透性は、施工対象とするコンクリート自体のひびわれ等の存在や、これらに類似する空隙の存在等、組織の粗密状態だけに依存せざるを得ないのが実態であり、躯体深部への浸透、拡散は極めて困難で、促進材とはいいつつも、コンクリート躯体深部へ深くは浸透しにくく、その表層に止まってしまわざるを得ないのが現状である。 In this type of conventional crystal formation promoter (hereinafter simply referred to as a promoter), even if a catalytic compound, a compound similar to it, or a chemical is disposed, the diffusibility of these into concrete A material that can sufficiently cope with securing the necessary concentration in the deep part of the housing after diffusion is still not known to the inventors of the present application. The penetration of various compounds and chemicals contained in these known accelerators into concrete depends only on the density of the structure, such as the presence of cracks in the concrete subject to construction and the presence of similar voids. In reality, it is unavoidable that penetration and diffusion into the deep part of the frame are extremely difficult. There is no current situation.
さらに従来の促進材にあっては、施工上の問題として、粉体材料では水あるいは液材等との配合、混練に加えて、対象コンクリートの与湿、湿潤化を含めた事前処理から、事後養生に至までの煩雑な管理が求められる。液状である従来の促進材の代表的材料である水ガラス系材料においても、塗布あるいは散布の事前処理に加え、施工後の散水、養生等の反復等、多くの作業工程とそれらの管理が必要とされ、これらが工費低減化の壁となり、幅広い適用に至らない要因の一つとなっている。
本発明は前述した従来技術における問題点を解決するためになしたものであり、あらゆるコンクリート構造物における漏水変状及び各種の劣化、変状に対してコンクリート表層から深部に至るまでの恒久的で確実性のある防止水性、即ち不透水化効果と各種の劣化防止、即ち高耐久化効果を奏することが可能な新規な材料とその施工法と提供することを目的とする。 The present invention has been made to solve the above-described problems in the prior art, and is a permanent leak from the concrete surface layer to the deep part with respect to water leakage deformation and various deteriorations and deformations in all concrete structures. It is an object of the present invention to provide a novel material capable of exhibiting a certain water-proofing property, that is, an impermeability effect, and various deterioration preventions, that is, a high durability effect, and a construction method thereof.
すなわち本発明の請求項１に係る水液型セメント結晶形成促進材は、セメント結晶構成要素材料である水ガラスを含まず、コンクリートへの高い浸透拡散性を持ち且つコンクリート躯体内にセメント結晶を形成、促進することを反復継続し、コンクリート躯体全体の恒久的不透水化、高耐久を示現可能な触媒性化合物を含有する水液型セメント結晶形成促進材であって、前記触媒性化合物は、フマール酸のナトリウム塩であり、該触媒性化合物を前記コンクリート躯体内に浸透拡散させ、セメント結晶形成促進反応を反復、継続させることにより、経時的に前記コンクリート躯体の組織の空孔、空隙内にセメント結晶を形成し、増殖させることを継続し、対象コンクリートを恒久的に緻密組織化することを特徴とする。
That according to Claim 1 of the present invention the water-part cement crystal formation promoting material does not contain water glass is cement crystalline component material, the cement crystals and concrete skeleton body has a high penetration diffusion of the concrete It is a water-liquid type cement crystal formation promoter containing a catalytic compound capable of repeatedly forming and promoting, and making permanent impermeability of the entire concrete frame and exhibiting high durability, wherein the catalytic compound is : It is a sodium salt of fumaric acid , and the catalytic compound is infiltrated and diffused into the concrete body, and the cement crystal formation promoting reaction is repeated and continued, so that the pores and voids in the structure of the concrete body over time It is characterized by continuing to form and grow cement crystals and to make the target concrete densely permanently.
また本発明の請求項２に係る水液型セメント結晶形成促進材の施工方法は、請求項１の水液型セメント結晶形成促進材を施工する方法であって、前記水液型セメント結晶形成促進材を、前記コンクリート躯体の表面に散布、噴霧または塗布することにより前記コンクリート躯体内へ浸透拡散させることを特徴とする。
The construction method of water liquid cement crystal formation promoting material according to claim 2 of the present invention is a method of applying a water solution cement crystal formation promoting material of claim 1, wherein the aqueous solution-type cement crystals formed The promoting material is diffused, sprayed, or applied to the surface of the concrete body to diffuse into the concrete body.
そして請求項３に係るものは、請求項２の水液型セメント結晶形成促進材の施工方法において、乾燥状態のコンクリート躯体への施工においても、該コンクリート躯体に対する与湿作業を行わずに前記コンクリート躯体表面に前記セメント結晶形成促進材を散布、噴霧または塗布することを特徴とする。
And those according to claim 3, in the construction method of water liquid cement crystal formation promoting material of claim 2, also in the construction of the concrete skeleton of dry, the concrete without Azukashime work on the concrete skeleton The cement crystal formation promoting material is sprayed, sprayed or applied on the surface of the casing .
すなわち本発明の促進材は、従来のセメント結晶生成、増殖系とされる材料に比べ、含有する触媒性化合物に、コンクリートへの優れた浸透拡散性、すなわち迅速な浸透拡散性とそれに相応する高濃度の浸透量の確保に卓越した特性も併せ持つものを配していること、及び、その高浸透拡散性触媒性化合物を含有する本発明の促進材が水液型であるため、対象とするコンクリート面に散布、噴霧あるいは塗布、これらの組み合わせによる施工のみという極めて単純、簡便な工法をもって、確実かつ恒久的な施工効果をコンクリート躯体へ付与することができるようにするものである。 In other words, the accelerator of the present invention is superior to conventional cement crystal formation and propagation materials in that it contains excellent catalytic diffusivity in concrete, that is, rapid osmotic diffusivity and correspondingly high permeation diffusivity. Because it has a property that has excellent characteristics for securing the amount of permeation of the concentration, and because the promoter of the present invention containing the highly permeable and diffusible catalytic compound is a water-liquid type, the target concrete With a very simple and simple construction method that involves only application by spraying, spraying or coating on the surface, a reliable and permanent construction effect can be imparted to the concrete frame.
このような本発明の水液型セメント結晶形成促進材に配合する触媒性化合物としては、コンクリート内でセメント結晶成促進性に優れていることと共にコンクリート内への高い浸透拡散性、即ち迅速な浸透拡散と、それに伴う高い浸透量の確保に優れた特性を持つ材料が好ましい。そのような材料としては、既述のように、多価カルボン酸のナトリウム塩か、それと同等あるいは近似の特性を有する酸のナトリウム塩がある。 As a catalytic compound to be blended in the water-liquid type cement crystal formation promoting material of the present invention, it has excellent cement crystal formation promoting property in concrete and has high penetration diffusibility into concrete, that is, rapid penetration. A material having excellent characteristics in diffusion and securing a high permeation amount associated therewith is preferable. As described above, as described above, there is a sodium salt of a polyvalent carboxylic acid or an acid sodium salt having the same or similar characteristics.
具体的には、コンクリート内に浸透拡散した触媒性化合物の多価カルボン酸のナトリウム塩等は後述する基本的なセメント結晶形成促進反応を反復、継続することにより、経時的にコンクリート組織の空孔、空隙内にセメント結晶を形成し、増殖させることを継続し、対象コンクリートを恒久的に緻密組織化する。
Specifically, a polyvalent sodium salts of carboxylic acids of permeate and diffuse catalyst compounds in the concrete or the like is repeated a basic cement crystal formation promoting reaction described below, by continuing, empty over time to the concrete structure Cement crystals are formed in the pores and voids and continued to grow, and the target concrete is permanently finely textured.
基本的セメント結晶形成促進反応メカニズムを下式に示す。
本発明は、含有する触媒性化合物に、コンクリートへの優れた浸透拡散性とそれに相応する高濃度の浸透量の確保に卓越した特性も併せ持つものを配した促進材を水液型としたため、対象コンクリート面に散布、分霧あるいは塗布、これらの組み合わせによって施工するだけの極単純、簡便な工法でもって、確実かつ恒久的な施工効果をコンクリート躯体へ付与することができる。 Since the present invention uses a water-liquid type accelerator as a catalyst compound containing a compound having excellent osmotic diffusibility to concrete and excellent properties for securing a high amount of permeation corresponding thereto, A reliable and permanent construction effect can be imparted to the concrete frame with an extremely simple and simple method of construction that is simply applied by spreading, fogging or coating on the concrete surface.
以下、本発明を実施するための最良の形態について、図面を参照して詳細に説明する。なお、各図中、同一又は相当する部分には同一の符号を付しており、重複する説明は適宜に簡略化ないし省略する。 Hereinafter, the best mode for carrying out the present invention will be described in detail with reference to the drawings. In addition, in each figure, the same code | symbol is attached | subjected to the part which is the same or it corresponds, and the overlapping description is simplified or abbreviate | omitted suitably.
標準的な配合コンクリート（設計基準強度２４N／ｍｍ２）で円柱供試体（直径１０ｃｍ、高さ１５ｃｍ）を４体を作成し、材齢２週経過時点において、
（ａ）２体の上端面に、本発明の水液型セメント結晶形成促進材（フマール酸ナトリウム７％配合）を１体当り１．６ｍｌ散布した後、２週間放置し、
(ｂ）他の２体は無処理のままとし、
（ａ）、(ｂ）の両供試体共に材齢４週で、次のような３種の試験を行った。
Standard formulations concrete (design criteria strength of 24N / mm 2) cylindrical specimens with (diameter 10 cm, height 15cm) to create a four-body, in an age of 2 weeks elapsed time,
(A) the upper end face of the two bodies, after the water-part cement crystal formation promoting material of the present invention (fumaric acid Sodium 7% formulation) was 1 body blow 1.6 m l spraying, allowed to stand for 2 weeks,
(b) Leave the other two untreated,
Both specimens (a) and (b) were subjected to the following three types of tests at the age of 4 weeks.
［１］前記ａ、ｂの円柱供試体各２体に割裂法により、ひび割れ（幅0.1ないし0.15ｍｍ程度）を生じさせ、止水性試験装置にセットした。供試体のセットにあたっては、各供試体の加圧面周縁及び側面からの漏水を防止するため、エポキシ系シール材で防水処理を施した。 [1] Cracks (width of about 0.1 to 0.15 mm) were generated in each of the two cylindrical specimens a and b by the splitting method and set in a water-stopping test apparatus. In setting the specimen, waterproofing treatment was performed with an epoxy-based sealing material in order to prevent water leakage from the peripheral edge and side face of each specimen.
試験法は、水圧０．１ｋｇｆ／ｃｍ２（０．００９１８Ｍｐａ／ｍｍ２）を加え、各供試体の漏水量の経時変化を計測した。４体の供試体の漏水状態の経時変化を図１の水量グラフに示す。前記ａ、ｂの円柱供試体各２体、計４体とも試験開始時は６ないし７ｇ／ｈ程度と同じレベルであったが、４時間経過頃から明らかな差を示すようになり、前記ｂの無処理体は、２０時間以降横ばい状態であるのに対し、前記ａの処理体は２２０ないし２３０時間経過時点で漏水が認められなくなった。 Test method, water pressure 0.1 kgf / cm 2 to (0.00918Mpa / mm 2) was added, was measured the time course of leakage of the specimen. The change over time in the leakage state of the four specimens is shown in the water amount graph of FIG. In each of the two specimens a and b, a total of four cylindrical specimens were at the same level as about 6 to 7 g / h at the start of the test. The untreated body of No. 2 remained flat after 20 hours, whereas the treated body of No. a showed no water leakage after 220 to 230 hours.
［２］前記透水試験後、各供試体を前述のひび割れ部で分割し、分割面の中央部で軸方向（高さ方向）における頂端部、中央部（７ないし８ｃｍ程度）、下端部の３箇所において分析用試料を採取し、各部位における触媒性化合物の残留量分析を行った。 [2] After the water permeability test, each specimen is divided at the above-mentioned cracked part, and the top part, the central part (about 7 to 8 cm) in the axial direction (height direction), the bottom part 3 at the central part of the dividing surface. Samples for analysis were collected at the locations, and the residual amount of the catalytic compound at each location was analyzed.
触媒性化合物の残留濃度の分析結果を下記表１に示す。なお分析方法には、UV検出器によるイオンクロマトグラフィーの定量分析法を用いた。
［３］さらに、前記透水試験後の分割供試体のうち、前記ａの処理体の一体と、前記ｂの無処理体の一体の分析用試料を採取した残りの分割体において、それぞれの分割面中央部（７ないし８ｃｍ）から走査型電子顕微鏡（SEM）用試料を採取し、両方の供試体の組織構造、特に空孔内の状態を１０００倍の倍率で撮影し、観察した。前記ａの処理体のSEM写真を図２（Ａ）に、前記ｂの無処理体のSEM写真を図２（Ｂ）に示す。処理体の組織空孔内には、形成されたセメント結晶の群生が明確に認められる。 [3] Further, among the divided specimens after the water permeation test, in the remaining divided bodies obtained by collecting samples for analysis of the treated body of a and the untreated body of b, the respective divided surfaces A sample for a scanning electron microscope (SEM) was taken from the center (7 to 8 cm), and the structure of both specimens, particularly the state in the vacancies, was photographed and observed at a magnification of 1000 times. An SEM photograph of the treated body a is shown in FIG. 2A, and an SEM photograph of the untreated body b is shown in FIG. A cluster of formed cement crystals is clearly observed in the tissue vacancies of the treated body.
Claims (3)
前記触媒性化合物は、フマール酸のナトリウム塩であり、該触媒性化合物を前記コンクリート躯体内に浸透拡散させ、セメント結晶形成促進反応を反復、継続させることにより、経時的に前記コンクリート躯体の組織の空孔、空隙内にセメント結晶を形成し、増殖させることを継続し、対象コンクリートを恒久的に緻密組織化することを特徴とする水液型セメント結晶形成促進材。
Free of water glass is cement crystalline component material, forming the cement crystals and concrete skeleton body has a high penetration diffusivity of the concrete, and repeatedly and continuously to promote permanent impermeable of the entire concrete skeleton A water-liquid type cement crystal formation promoter containing a catalytic compound capable of exhibiting high durability,
The catalytic compound is a sodium salt of fumaric acid. The catalytic compound is infiltrated and diffused into the concrete body, and the cement crystal formation promoting reaction is repeated and continued. A water-liquid type cement crystal formation promoting material characterized in that cement crystals are continuously formed and propagated in pores and voids, and the target concrete is permanently densely structured.
A method for applying a water-part cement crystal formation promoting material of claim 1, said aqueous liquid-type cement crystal formation promoting material, sprayed on the surface of the concrete skeleton, the concrete skeleton body by spraying or coating A construction method of a water-liquid type cement crystal formation promoting material characterized in that it is permeated into and diffused into the water.
A construction method according to claim 2 of the water-liquid cement crystal formation promoting material, even in the construction of the concrete skeleton of dry, the cement crystals on the surface of the concrete skeleton without Azukashime work on the concrete skeleton A method for constructing a water-liquid type cement crystal formation promoting material, characterized in that the formation promoting material is sprayed, sprayed or applied.
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