JP5137637B2 - Agricultural sterilization filter - Google Patents

Agricultural sterilization filter Download PDF

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JP5137637B2
JP5137637B2 JP2008067066A JP2008067066A JP5137637B2 JP 5137637 B2 JP5137637 B2 JP 5137637B2 JP 2008067066 A JP2008067066 A JP 2008067066A JP 2008067066 A JP2008067066 A JP 2008067066A JP 5137637 B2 JP5137637 B2 JP 5137637B2
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filter
agricultural
synthetic fiber
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antibacterial agent
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JP2009221145A (en
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哲 亀嶋
智彦 丹羽
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Akechi Ceramics Co Ltd
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Description

本発明は農業用水中に存在する病原菌を捕捉し、その後も病原菌の繁殖を抑制する農業用除菌フィルターに関する。   The present invention relates to an agricultural sanitizing filter that captures pathogenic bacteria present in agricultural water and suppresses the propagation of pathogenic bacteria thereafter.

農業用水、特に養液栽培に使用する水は、栽培状況を左右する非常に重要な要因である。この水において、水道水を利用している場合は病原菌の混入は比較的少ない。しかしながら、用水や地下水を利用している場合は、その原水に病原菌が含まれる可能性が多い。その病原菌は水を介して繁殖し、栽培物に付着することで発病し、栽培物へ大きな悪影響を及ぼす。例えば、循環する養液を介して根腐れ病が繁殖して、栽培物の根に感染してほとんどの栽培物を枯らしてしまう被害も出ている。この悪影響を最小限に留めるフィルタリング方式として、フィルターから銀などの除菌成分を養液中へ溶出させて除菌する方法や精密濾過膜で菌を捕捉する方法などがある。この銀などの除菌成分を養液中へ溶出させて除菌する方法は、養液中に溶出した銀イオンが病原菌の生殖機能を阻害し、病原菌を死滅させる方法である。また、精密濾過膜による菌の捕捉方法は、そこを通過する養液中の菌を濾過膜で高精度に取り除く方法である。 Agricultural water, especially water used for hydroponics, is a very important factor that affects the cultivation situation. In this water, when tap water is used, contamination with pathogenic bacteria is relatively small. However, when irrigation water or groundwater is used, pathogenic bacteria are likely to be contained in the raw water. The pathogen propagates through water and becomes ill when it adheres to the cultivated product, which has a serious adverse effect on the cultivated product. For example, root rot propagates through the circulating nutrient solution, infecting the roots of the cultivated product, and causing damage to most cultivated products. As a filtering method for minimizing this adverse effect, there are a method of sterilization by eluting a sterilizing component such as silver from a filter into a nutrient solution, and a method of capturing bacteria with a microfiltration membrane. The method of eradicating bacteria by eluting the sterilizing component such as silver is a method in which the silver ions eluted in the nutrient solution inhibit the reproductive function of the pathogenic bacteria and kill the pathogenic bacteria. Moreover, the microbe-capturing method using a microfiltration membrane is a method for removing microbes in a nutrient solution passing therethrough with a microfiltration membrane with high accuracy.

しかしながら、銀などの除菌成分を養液中へ溶出させる除菌方法は、銀の溶出量の制御が難しく効果にばらつきがある。更に多量の銀イオンが養液中に溶出した場合は根に薬害を及ぼし、栽培物の成長を阻害すると同時に効果寿命も短くなる可能性がある。 However, the sterilization method for eluting sterilizing components such as silver into the nutrient solution is difficult to control the elution amount of silver and varies in effectiveness. In addition, when a large amount of silver ions are eluted in the nutrient solution, it may cause phytotoxicity to the roots and inhibit the growth of the cultivated product, and at the same time may shorten the effective life.

一方、精密濾過膜による菌の捕捉方法は、病原菌を捕捉する性能は非常に高いが、単位面積あたりの通過流量が少ないため多くの水を流すことができない。また、膜自体に除菌性能が無いため捕捉した病原菌はそこで繁殖し、病巣になる可能性もある。更には、フィルターが高精度であるため、養液中に含まれる養分をも除去(捕捉)してしまう場合がある等の問題点がある。
On the other hand, although the microbe-capturing method using a microfiltration membrane has a very high ability to capture pathogenic bacteria, it cannot flow a large amount of water because the flow rate per unit area is small. In addition, since the membrane itself has no sterilizing performance, the captured pathogenic bacteria may propagate there and become a lesion. Furthermore, since the filter has high accuracy, there is a problem that nutrients contained in the nutrient solution may be removed (captured).
Nothing

本発明は、上記問題点を解決するために化学パルプを主体とするフィルターに無機銀系抗菌剤を付着させることで、養液中の病原菌の捕捉、病原菌の繁殖抑制を瞬時に行うことができる点に着目したもので、稲、花き、果物、等の作物栽培中に発生する立ち枯れ病、根腐れ病、等の原因となる病原菌に対し除菌効果のある農業用除菌フィルターを提供することを目的とするものである。 In order to solve the above problems, the present invention can instantly capture pathogenic bacteria in a nutrient solution and suppress the propagation of pathogenic bacteria by attaching an inorganic silver antibacterial agent to a filter mainly composed of chemical pulp. Providing an agricultural sanitizing filter that is effective in sanitizing pathogens that cause blight, root rot, etc. that occur during cultivation of crops such as rice, flowers, fruits, etc. It is intended.

上記目的を達成するための請求項1に記載の農業用除菌フィルターは、化学パルプと、熱溶融型合成繊維と、無機銀系抗菌剤からなり、該無機系抗菌剤が前記熱溶融型合成繊維の表面に均一に付着していることを特徴とする。   The agricultural sterilization filter according to claim 1 for achieving the above object comprises a chemical pulp, a hot-melt synthetic fiber, and an inorganic silver antibacterial agent, and the inorganic antibacterial agent is the hot-melt synthetic filter. It is characterized by being uniformly attached to the surface of the fiber.

請求項2に記載の農業用除菌フィルターは、請求項1に記載の構成において、前記化学パルプの含有量が40〜80wt%、前記熱溶融型合成繊維の含有量が20〜60wt%であることを特徴とする。   The agricultural sanitization filter according to claim 2 is the composition according to claim 1, wherein the chemical pulp content is 40 to 80 wt%, and the hot-melt synthetic fiber content is 20 to 60 wt%. It is characterized by that.

また、請求項3に記載の農業用除菌フィルターは、請求項1又は請求項2に記載の構成において、絶対濾過精度が10μm以下であることを特徴とする。   Moreover, the agricultural sanitization filter according to claim 3 is characterized in that, in the configuration according to claim 1 or 2, the absolute filtration accuracy is 10 μm or less.

請求項1に記載の農業用除菌フィルターによれば、化学パルプと熱溶融型合成繊維と無機銀系抗菌剤とからなるもので、無機系抗菌剤が熱溶融型合成繊維の表面に均一に付着している。このため、水圧により化学パルプが横方向に広がってフィルター目が小さくなり、熱溶融型合成繊維で効率よく病原菌を捕捉できる。捕捉された病原菌は、表面に均一に付着している無機系抗菌剤によって繁殖を抑制される。さらに、無機系抗菌剤は抗菌成分の溶出が無いため、長期にわたってその効果が持続する。 According to the agricultural sterilization filter of claim 1, consisting of chemical pulp, hot melt synthetic fiber and inorganic silver antibacterial agent, the inorganic antibacterial agent is uniformly on the surface of the hot melt synthetic fiber It is attached. For this reason, the chemical pulp spreads in the lateral direction due to the water pressure, the filter mesh becomes smaller, and pathogenic bacteria can be efficiently captured by the hot-melt synthetic fiber. Propagation of the captured pathogen is suppressed by an inorganic antibacterial agent uniformly attached to the surface. Furthermore, since the inorganic antibacterial agent has no elution of antibacterial components, its effect lasts for a long time.

請求項2に記載の農業用除菌フィルターは、請求項1に記載の構成において、化学パルプの含有量が40〜80wt%で、熱溶融型合成繊維の含有量が20〜60wt%であるので、抗菌剤を捕捉する役目の化学パルプが比較的多く存在するため、病原菌の捕捉効率を上昇させる。また熱溶融型繊維は表面に均一に付着した無機銀系抗菌剤の効果で病原菌の繁殖を抑制すると同時に、水の流れをスムーズにするため大きな圧力損失を受けずに多くの水を通すことができる。 The agricultural sanitizing filter according to claim 2 has the chemical pulp content of 40 to 80 wt% and the hot-melt synthetic fiber content of 20 to 60 wt% in the configuration according to claim 1. Since there are relatively many chemical pulps that capture antibacterial agents, the trapping efficiency of pathogenic bacteria is increased. In addition, the heat-melt fiber suppresses the propagation of pathogenic bacteria due to the effect of the inorganic silver antibacterial agent evenly adhered to the surface, and at the same time allows a large amount of water to pass through without causing a large pressure loss to smooth the flow of water. it can.

この場合、化学パルプの含有量が40wt%未満であると除菌率が低下し、80wt%を超えると瞬間流量が減少する。また、熱溶融型合成繊維の含有量が20wt%未満であるとフィルターの強度が減少して水圧で変形する可能性があり、60wt%を超えると菌の捕捉効率が減少する。   In this case, if the chemical pulp content is less than 40 wt%, the sterilization rate decreases, and if it exceeds 80 wt%, the instantaneous flow rate decreases. In addition, if the content of the hot-melt synthetic fiber is less than 20 wt%, the strength of the filter may be reduced and the pressure may be deformed by water pressure, and if it exceeds 60 wt%, the bacteria capture efficiency is reduced.

請求項3に記載された農業用除菌フィルターによれば、請求項2に記載の構成において、絶対濾過過精度が10μm以下であるので、10μm以上の病原菌等を化学パルプ及び熱溶融型合成繊維で確実に捕捉することができる。 According to the agricultural sterilization filter described in claim 3, in the configuration according to claim 2, since the absolute filtration over-accuracy is 10 μm or less, pathogenic bacteria of 10 μm or more can be treated with chemical pulp and hot-melt synthetic fiber. Can be reliably captured.

(実施例)
非溶出性の無機銀系抗菌剤3wt%、化学パルプが67wt%、熱溶融型合成繊維30wt%の配合で3%のスラリーを作製し、吸引機を該スラリー中に作用させて、内径42mm、肉厚12mm、長さ250mm、絶対濾過精度が10μmの農業用除菌フィルターを得た。ここで非溶出性の無機銀系抗菌剤とは、溶出量が0.05ppb以下であるものをいう。また、化学パルプとは、木材から取り出した繊維から硫酸などの薬品や熱を使ってリグニンを溶かし出し、繊維だけを取り出したものである。
(Example)
A non-eluting inorganic silver-based antibacterial agent 3 wt%, chemical pulp 67 wt%, hot melt synthetic fiber 30 wt% of 3% slurry was prepared, a suction machine was allowed to act on the slurry, inner diameter 42 mm, An agricultural sterilization filter having a wall thickness of 12 mm, a length of 250 mm, and an absolute filtration accuracy of 10 μm was obtained. Here, the non-eluting inorganic silver-based antibacterial agent means one having an elution amount of 0.05 ppb or less. The chemical pulp is a fiber obtained by dissolving lignin from a fiber taken out of wood using chemicals such as sulfuric acid or heat and taking out only the fiber.

(比較例1)
非溶出性の無機銀系抗菌剤3wt%、化学パルプが97wt%、熱溶融型合成繊維0wt%の配合であること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 1)
An agricultural sterilization filter similar to the example was obtained except that the composition was 3 wt% non-eluting inorganic silver antibacterial agent, 97 wt% chemical pulp, and 0 wt% hot melt synthetic fiber.

(比較例2)
非溶出性の無機銀系抗菌剤3wt%、化学パルプが0wt%、熱溶融型合成繊維97wt%の配合であること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 2)
An agricultural sterilization filter similar to the example was obtained except that the composition was composed of 3 wt% non-eluting inorganic antibacterial agent, 0 wt% chemical pulp, and 97 wt% hot-melt synthetic fiber.

(比較例3)
非溶出性の無機銀系抗菌剤0wt%、化学パルプが70wt%、熱溶融型合成繊維30wt%の配合であること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 3)
An agricultural sterilization filter similar to the example was obtained except that the composition was non-eluting inorganic silver antibacterial agent 0 wt%, chemical pulp 70 wt%, and hot-melt synthetic fiber 30 wt%.

(比較例4)
非溶出性の無機銀系抗菌剤3wt%、パルプが85wt%、熱溶融型合成繊維15wt%の配合であること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 4)
An agricultural sterilization filter similar to the example was obtained except that the composition was 3% by weight of non-eluting inorganic silver antibacterial agent, 85% by weight of pulp and 15% by weight of hot-melt synthetic fiber.

(比較例5)
非溶出性の無機銀系抗菌剤3wt%、パルプが30wt%、熱溶融型合成繊維67wt%の配合であること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 5)
A sanitary filter for agriculture similar to the example was obtained except that the composition was 3 wt% of non-eluting inorganic silver antibacterial agent, 30 wt% of pulp and 67 wt% of hot-melt synthetic fiber.

(比較例6)
絶対濾過精度が20μmであること以外は、実施例と同様の農業用除菌フィルターを得た。
(Comparative Example 6)
Except that the absolute filtration accuracy was 20 μm, an agricultural sterilization filter similar to the example was obtained.

上記実施例及び比較例1〜6によって得られた各農業用除菌フィルターFを、図1及び図2に示すように除菌装置1のフィルターハウジング2内に設置し、それぞれ流速50L/minで根腐れ病(Pythium helicoides)菌液(1.0×103 cfu/ml)を通過させた時の瞬間流量、トータル流量(フィルター寿命流量)、圧力損失、菌液通過後の減菌率及びフィルター表面の菌数を確認した。その結果を表1に示す。 Each agricultural sterilization filter F obtained by the above Examples and Comparative Examples 1 to 6 is installed in the filter housing 2 of the sterilization apparatus 1 as shown in FIG. 1 and FIG. root rot (Pythium helicoides) instantaneous flow rate when passed through bacteria solution (1.0 × 10 3 cfu / ml ), total flow rate (filter life flow rate), pressure drop, the sterilization rate and the filter surface after the bacterial liquid passing The number of bacteria was confirmed. The results are shown in Table 1.

Figure 0005137637
Figure 0005137637

上記表1の比較例2及び比較例5に示されるように、化学パルプの含有量が40wt%未満であると除菌率が約20%も低下し、比較例1及び比較例4に示されるように80wt%を超えると・瞬間流量が減少するだけでなく、フィルター表面の菌数が増大する。また、比較例1及び比較例4に示されるように熱溶融型合成繊維の含有量が20wt%未満であると、フィルターの変形により圧力損失が上昇するだけでなく、抗菌剤の付着量が減少するためにフィルター表面の菌数が増加し、比較例2及び比較例5に示されるように60wt%を超えると、菌の捕捉効率が低下するため、通過後の除菌率が低下する。比較例6に示されるように、絶対濾過精度が20μmであると菌の捕捉効率が低下するため、通過後の除菌率が低下する。 As shown in Comparative Example 2 and Comparative Example 5 in Table 1 above, when the chemical pulp content is less than 40 wt%, the sterilization rate decreases by about 20%, which is shown in Comparative Example 1 and Comparative Example 4. Thus, when it exceeds 80 wt%, not only the instantaneous flow rate decreases but also the number of bacteria on the filter surface increases. Further, as shown in Comparative Example 1 and Comparative Example 4, when the content of the hot-melt synthetic fiber is less than 20 wt%, not only the pressure loss increases due to the deformation of the filter but also the amount of the antimicrobial agent attached decreases. Therefore, when the number of bacteria on the filter surface increases and exceeds 60 wt% as shown in Comparative Example 2 and Comparative Example 5, the bacteria capture efficiency decreases, and thus the sterilization rate after passage decreases. As shown in Comparative Example 6, when the absolute filtration accuracy is 20 μm, the bacteria capture efficiency is lowered, so that the sterilization rate after passage is lowered.

以上の結果、本発明品によれば化学パルプが効率よく病原菌をトラップし、熱溶融型合成繊維の表面に付着した非溶出性の無機銀系抗菌剤が病原菌の繁殖を抑制するため、1回通過後での除菌率が非常に高くフィルター自体も病巣になりにくい。 As a result, according to the product of the present invention, the chemical pulp efficiently traps pathogenic bacteria, and the non-eluting inorganic silver-based antibacterial agent attached to the surface of the hot-melt synthetic fiber suppresses the propagation of pathogenic bacteria. The sterilization rate after passing is very high, and the filter itself is less likely to become a lesion.

除菌装置を例示したブロック図である。It is the block diagram which illustrated the disinfection apparatus. 農業用除菌フィルターの使用状況を示した説明図である。It is explanatory drawing which showed the use condition of the disinfection filter for agriculture.

符号の説明Explanation of symbols

F 農業用除菌フィルター
1 除菌装置
2 フィルターハウジング
F Agricultural disinfection filter 1 Disinfection device 2 Filter housing

Claims (3)

化学パルプと、熱溶融型合成繊維と、無機銀系抗菌剤からなり、該無機系抗菌剤が前記熱溶融型合成繊維の表面に均一に付着していることを特徴とする農業用除菌フィルター。   Agricultural sterilization filter comprising chemical pulp, hot melt synthetic fiber, and inorganic silver antibacterial agent, wherein the inorganic antibacterial agent is uniformly attached to the surface of the hot melt synthetic fiber . 前記化学パルプの含有量が40〜80wt%、前記熱溶融型合成繊維の含有量が20〜60wt%であることを特徴とする請求項1に記載の農業用除菌フィルター。   2. The agricultural sterilization filter according to claim 1, wherein a content of the chemical pulp is 40 to 80 wt% and a content of the hot-melt synthetic fiber is 20 to 60 wt%. 絶対濾過精度が10μm以下であることを特徴とする請求項1又は請求項2に記載の農業用除菌フィルター。   3. The agricultural sterilization filter according to claim 1, wherein absolute filtration accuracy is 10 μm or less.
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JP3777387B2 (en) * 1996-09-13 2006-05-24 日本特殊陶業株式会社 Antibacterial fiber, antibacterial fabric, antibacterial filter material, and production method thereof
US6811771B1 (en) * 1999-04-27 2004-11-02 Ebara Corporation Bactericidal organic polymeric material
JP2003040713A (en) * 2001-07-26 2003-02-13 Tadashi Inoue Inorganic antibacterial agent and product containing the same
JP2003080266A (en) * 2001-09-17 2003-03-18 Akechi Ceramics Co Ltd Antimicrobial treatment method for aqueous solution
JP4075606B2 (en) * 2002-12-20 2008-04-16 明智セラミックス株式会社 Antibacterial rock wool medium for hydroponics
JP3734803B2 (en) * 2003-03-27 2006-01-11 明智セラミックス株式会社 Liquid processing equipment
JP2005245282A (en) * 2004-03-03 2005-09-15 Akechi Ceramics Co Ltd Method for producing antibacterial rock wool medium
JP2006320282A (en) * 2005-05-20 2006-11-30 Tokushima Ken Culture solution circulation feeder, sterilization device for culture solution circulation supply and culture solution circulation supply method
JP2008168170A (en) * 2007-01-09 2008-07-24 Akechi Ceramics Co Ltd Method for removing bacteria in aqueous solution
JP2009082899A (en) * 2007-09-28 2009-04-23 Kanai Juyo Kogyo Co Ltd Filter element

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