JP5119583B2 - Oil-containing pet food - Google Patents

Description

  TECHNICAL FIELD The present invention relates to an oil-containing pet food pet food, and more particularly, to an oil-containing pet food having high storage stability.

  The number of pets is increasing due to the pet boom, and accordingly, adult illnesses in humans such as pet obesity, diabetes and liver diseases are increasing due to aging of pets, lack of exercise, overnutrition and the like. In addition, dogs and cats who become obese due to hormonal imbalance after contraceptive surgery are increasing. For this reason, the raw materials used in the past have begun to change.

  For example, regarding fats and oils, only animal fats and oils have been used in the past, but vegetable fats and oils that are considered to be healthier have come to be used. Furthermore, in addition to processed fats and oils that have been further enhanced in vegetable oils and fats, highly functional oils and fats collected from nature have been used. By the way, as described above, vegetable oils and high-functional oils and fats are used, and at the same time, deterioration of the oils and fats is a problem. In this connection, the amount of ethoxyquin that has been used in chicken oil and fish oil, which are easily deteriorated oils and fats, is being regulated from the viewpoint of animal protection around the world.

  In addition, minerals have not been well controlled in the past, and only natural minerals have been used in large quantities, but due to the human health food boom, many nutritional ingredients have been used in pet food. It was. Although each nutritional component is a physiologically important component of an animal, there is a problem that the stability of the product is lowered due to its sensitizing action. Here, the sensitizing action means that minerals and nutrients work in the direction of promoting oxidation in combination with the effects of oil and fat inside the product, external heat, and light.

  Recently, many pet foods that are good for animal health have been developed. For example, extracts of laurel leaves that are amylase inhibitors (Patent Document 1), lipase inhibitors such as hesperidin (Patent Document 2), Maiko powder and / or Maiko extract (Patent Document 3), containing unsaturated fatty acids A pet food containing a high amount of fats and oils (Patent Document 4) is known.

  However, when fats and nutrients with a high unsaturated fatty acid content are blended in pet food, the fats and oils are denatured during long-term storage, resulting in problems of odor generation and a decrease in palatability. Furthermore, it is known that when fats and oils with high unsaturated fatty acid content are blended with minerals such as copper, iron, manganese and cobalt as nutrients, the oxidation reaction of the fats and oils is promoted and the long-term storage stability is further reduced. It has been.

  On the other hand, changes in quality in the process of material degradation and reactions between related material components are very diverse, and many of them occur simultaneously or in a chain. Recent research clearly shows that most degradation processes involve oxidation and photodegradation. Oxidation and photodegradation are also known to occur in air, water, air / water interface, water / oil interface, and air / oil interface. Further, enzymes, metals, sensitizers, and the like are known as enhancement factors for oxidative degradation, and oxidative degradation occurs in these combinations. On the other hand, photodegradation occurs when a substance absorbs ultraviolet light, visible light, or near infrared light.

JP 05-192092 A JP 09-187230 A Japanese Patent Laid-Open No. 08-38069 Japanese Patent Laid-Open No. 06-217710

  This invention is made | formed in view of the said situation, The objective is to provide the fat-containing pet food with favorable long-term storage stability in spite of having high content of an unsaturated fatty acid and a mineral.

  The present inventor has studied the stability by blending various ingredients into a pet food system using a combination of fats and minerals with a high unsaturated fatty acid content, and by blending a predetermined amount of carnosol and carnosic acid, The present inventors have found that the long-term storage stability of oil-containing pet food is remarkably improved, and the present invention has been completed.

That is, the gist of the present invention resides in an oil-containing pet food characterized by satisfying the following requirements (A) to (D) .

(A) The content of fats and oils in which the content of unsaturated fatty acids having two or more double bonds in the fatty acid constituent fatty acids is 20% by mass or more is 5 to 50% by mass.

(B) The total content of zinc and calcium as the mineral is 0.002 to 1% by mass.

(C) The total content of carnosol and carnosic acid is 7 ppm or more with respect to fats and oils in which the content of unsaturated fatty acids having two or more double bonds in the fatty acid-constituting fatty acid is 20% by mass or more.
(D) The emulsifier is contained in an amount of 0.05 to 50 times the total content of carnosol and carnosic acid, and the emulsifier has 6 to 24 carbon atoms in the constituent fatty acid and 3 to 15 HLB. Some are polyglycerol fatty acid esters or sucrose fatty acid esters.

  ADVANTAGE OF THE INVENTION According to this invention, although the content of an unsaturated fatty acid and a mineral is high, fats and oils containing pet food with favorable long-term storage stability is provided.

  Hereinafter, the present invention will be described in detail. However, the description of the constituent elements described below is a representative example of embodiments of the present invention, and the present invention is not limited to these contents.

  The oil-containing pet food of the present invention contains specific fats and oils, minerals, carnosol and carnosic acid as essential components.

<Oil and fat>
In the present invention, fats and oils that have two or more double bonds in the fat-and-fatty fatty acids and an unsaturated fatty acid content of 20% by mass or more are used. Here, examples of the unsaturated fatty acid having two or more double bonds include unsaturated fatty acids having 18 to 24 carbon atoms such as linoleic acid, linolenic acid, EPA, DHA, and arachidonic acid. Other fatty acids are unsaturated fatty acids and saturated fatty acids having one double bond. Examples of unsaturated fatty acids having one double bond include unsaturated fatty acids having 16 to 24 carbon atoms such as oleic acid and palmitooleic acid, and saturated fatty acids include fatty acids having 10 to 24 carbon atoms.

  The unsaturated fatty acid content in the oil and fat is preferably 20 to 90% by mass, more preferably 23 to 80% by mass, and particularly preferably 25 to 70% by mass from the viewpoint of anti-obesity effect and skin and hair health. It is. Moreover, the total saturated fatty acid content in said fats and oils is 0-60 mass% normally, Preferably it is 2-40 mass%, More preferably, it is 2-20 mass%.

  The fats and oils that contain two or more double bonds in the fatty acid component fatty acid and the content of unsaturated fatty acid is 20% by mass or more include both animal fats and vegetable fats, such as safflower oil, olive oil, and cottonseed oil. Corn oil, rapeseed oil, soybean oil, palm oil, sunflower oil, linseed oil, sesame oil, lard, beef tallow, fish oil, milk fat, fractionated oils thereof, randomized oil, hardened oil, transesterified oil and the like.

  In the oil / fat-containing pet food of the present invention, the content of the oil / fat is 5 to 50% by mass, preferably 5 to 45% by mass, and more preferably 10 to 45% by mass, as a ratio to the total components. .

<Mineral>
In the present invention, physiologically useful zinc and calcium are used as minerals. By the way, in general, heavy metals such as zinc act as a catalyst and promote the oxidation of fats and oils. In addition, calcium forms a complex with protein and acts as an antioxidant or as an accelerator, making it difficult to control oxidation. However, in the oil-and-fat-containing pet food of the present invention, the above problems are solved at once by blending a predetermined amount of carnosol and carnosic acid.

  In the oil-and-fat-containing pet food of the present invention, the total content of zinc and calcium is 0.002 to 1% by mass, preferably 0.001 to 0.5% by mass, and more preferably, as a ratio to all components. It is 0.005-0.1 mass%.

  In addition, the oil-and-fat containing pet food of this invention may contain copper, iron, manganese, cobalt, phosphorus, sodium, potassium, etc. other than said mineral.

<Carnosol and carnosic acid>
Unlike other antioxidants, carnosol and carnosic acid have an isoprene skeleton apietan structure. Antioxidants such as fats and oils are much stronger than other antioxidants. In addition, it has a conjugated double bond in the structure, and further has a tautomeric structure even under the influence of radicals generated by light. high.

  Carnosol and carnosic acid are abundant in herbaceous plants such as perilla, sage, oregano, rosemary, and Lamiaceae. In general, carnosol and carnosic acid can be extracted by drying leaves and stems and using hexane, ethyl acetate, ethanol, ether, alkaline water, neutral water, acidic water, or a mixture thereof. . It can also be extracted using supercritical carbon dioxide. Preferably, extraction is performed using hexane, hexane / ethanol, ethanol, ethanol / water. Usually, 10 kg of the above solvent is used to stir and extract at 5 to 60 ° C. with respect to 1 kg of plant, followed by filtration to obtain a filtrate. Further, the residue is repeated several times with the same solvent to obtain a filtrate. These filtrates are combined and concentrated under reduced pressure to obtain a plant extract. As a raw material plant, sage, oregano and rosemary are preferable, and rosemary is particularly preferable.

  In the oil / fat-containing pet food of the present invention, the total content of carnosol and carnosic acid is a ratio (mass ratio) with respect to the oil / fat whose content of unsaturated fatty acid having two or more double bonds in the oil / fat fatty acid is 20% by mass or more However, it is preferably at least 10 ppm, more preferably at least 15 ppm.

<Tocopherol>
In a preferred embodiment of the invention, tocopherol is used. In nature, α, β, γ, and δ tocopherols exist, but tocopherols that have a high antioxidant effect and are hardly affected by heat and that contain a large amount of γ or δ are preferred. In the present invention, tocotrienol can also be used.

  In the oil-containing pet food of the present invention, the content of tocopherol is 0.5 to 200 times as a ratio (mass ratio) to the total content of carnosol and carnosic acid, preferably 1 to 100 times, More preferably, the amount is 10 to 100 times. The amount of tocotrienol used is the same as that of tocopherol.

<Emulsifier>
In a preferred embodiment of the invention, an emulsifier is used. Since the degradation reaction takes place at the interface, it is recommended to arrange a component that prevents degradation at the interface and to prevent the degradation factor from being arranged at the interface. From such a viewpoint, an emulsifier is used. Examples of the emulsifier include polyglycerin fatty acid esters such as polyglyceryl laurate, polyglyceryl myristate, polyglyceryl palmitate, polyglyceryl stearate, polyglycerin oleate, sucrose laurate, and sucrose. Examples thereof include sucrose fatty acid esters such as myristic acid ester, sucrose palmitic acid ester, sucrose stearic acid ester, and sucrose oleic acid ester. These constituent fatty acids have 6 to 24 carbon atoms and HLB is 3 to 15. Moreover, sorbitan ester, polyoxyethylene ether, etc. can also be used.

  In the oil-and-fat-containing pet food of the present invention, the content of the emulsifier is 0.05 to 50 times, preferably 0.5 to 10 times as a ratio (mass ratio) to the total content of carnosol and carnosic acid. The amount is more preferably 1 to 10 times.

<Other additives>
In the present invention, as other additive components, saccharides, sugar alcohols, vegetable oils and fats, catechins (including catechins-containing natural extracts) and the like can be used. Examples of the saccharide include glucose, sucrose, and oligosaccharide. Examples of the sugar alcohol include oligotoose, trehalose, xylitol, and erythritol. In addition, a gelling agent, a shape-retaining agent, a pH adjuster, a seasoning, a preservative, and a nutrition reinforcing agent that are generally used in pet foods can also be contained.

<Basic ingredients>
The oil-and-fat-containing pet food of the present invention contains various components as basic components, as in the conventional pet food. Examples of such components include animal meat, plant sterols, plant proteins, grains, bran, potatoes, sugars, vegetables, and vitamins as proteins.

  Examples of plant proteins include soy protein; grains include wheat, barley, rye, milo, corn and the like; rice bran, bran and the like; bran includes soybean meal and the like. Examples of animal protein include beef, chicken, pork and fish. These contents are usually 0.2 to 60% by mass, preferably 1 to 30% by mass. The total amount of plant protein, cereals, bran and potatoes is preferably 5 to 95% by mass as a proportion of all components. Examples of the vegetables include vegetable extracts and the like, and the content thereof is preferably 1 to 30% by mass as a ratio in all components. Examples of vitamins include A, B1, B2, D, E, niacin, pantothenic acid, carotene and the like, and the content thereof is preferably 0.05 to 10% by mass as a ratio in all components.

  In general, pet food is classified into wet type, soft dry type, semi-moist type, and dry type according to the amount of water, and classified into comprehensive nutritional food, snacks, and other target foods depending on the application. The kind, use, shape, etc. of the oil-containing pet food of the invention are not limited at all.

  EXAMPLES Hereinafter, although an Example demonstrates this invention still in detail, this invention is not limited to a following example, unless the summary is exceeded. In the following, “%” means mass%.

<Production Method of Rosemary Extract (RM1)>
10 kg of 50% aqueous ethanol was added to 1 kg of rosemary, heated under reflux for 3 hours, and filtered while warm to obtain a filtrate. An operation of treating and extracting the residue with 6 L of 50% aqueous ethanol in the same manner was further repeated twice to obtain a filtrate. When these filtrates were combined and 5 L of water was added, a precipitate was deposited. To this filtrate, 100 g of activated carbon was added, stirred for 1 hour, allowed to stand overnight in a cool place, and then filtered to obtain a mixture of precipitate and activated carbon. 4 L of ethanol was added to this mixture, and the mixture was heated to reflux for 3 hours and filtered while warm to obtain a filtrate. The operation of extracting and treating the residue with 2.4 L of ethanol in the same manner was further repeated twice to obtain a filtrate. These filtrates were combined, concentrated under reduced pressure, and ethanol was distilled off to obtain a powdered carnosol and carnosic acid-containing rosemary extract (RM1).

<Production Method of Rosemary Extract (RM2)>
10 kg of hexane was added to 1 kg of rosemary and stirred for 3 hours, followed by filtration to obtain a filtrate. An operation of treating and extracting the residue in the same manner with 6 L of hexane was further repeated twice to obtain a filtrate. These filtrates were combined, 100 g of activated carbon was added, stirred for 1 hour, allowed to stand overnight in a cool place, and then filtered to obtain carnosol and carnosic acid-containing rosemary extract (RM2).

<Preparation of Formulation 1>
Formulation 1 was prepared by stirring 20 g of RM2 and 10 g of polyglycerin ester (“O50D” manufactured by Mitsubishi Chemical Foods Co., Ltd.) at 70 ° C. in 70 g of rapeseed oil for 1 hour.

<Preparation of formulation 2>
Formulation 2 was prepared by stirring 20 g of RM1 and 10 g of polyglycerin ester (“O50D” manufactured by Mitsubishi Chemical Foods Co., Ltd.) under conditions of 50 ° C. with 70 g of rapeseed oil for 1 hour.

<Preparation of Formulation 3>
Formulation 3 was prepared by stirring 10 g of RM1 and 30 g of tocopherol (manufactured by Sigma) and 5 g of polyglycerin ester (“O50D” manufactured by Mitsubishi Chemical Foods) in 55 g of rapeseed oil for 1 hour at 50 ° C. .

Comparative Examples 1-4 and Examples 1 and 2:
<Preparation of pet food>
Corn 35%, chicken bone meat powder 30%, wheat flour 10%, soybean 15%, vitamins and minerals (vitamins A, B, D, E, K; 4.5%, calcium carbonate, calcium phosphate, zinc carbonate 0.5 %) And 5% beef tallow were further added with an antioxidant (concentration: ppm) as shown in Table 1 to prepare a pet food. The obtained pet food was extracted with ether, silylated, and analyzed by GC-MS, whereby the fat content and unsaturated fatty acid content of the pet food were measured. As a result, the fat content of the pet food was 26.15% and the unsaturated fatty acid content was 48.5%.

<Pet food deterioration prevention function test>
10 g of the above pet food was put into a sample tube, air was blown in, and the sample tube was kept at 110 ° C. In general, as an oxidative deterioration phenomenon, a certain volatile component appears with time after the start, and thereafter, the volatile component rapidly increases with time due to oxidative deterioration. Therefore, this volatile component was trapped in water, the change in conductivity of the trapped water was traced every hour, and the time when the volatile component increased rapidly (oxidation induction time) was evaluated as a deterioration preventing function. The results are shown in Table 1.

Claims (2)

An oil-containing pet food characterized by satisfying the following requirements (A) to (D) .
(A) The content of fats and oils in which the number of double bonds in the fatty acid constituent fatty acid is 2 or more and the unsaturated fatty acid content having 18 to 24 carbon atoms is 20% by mass or more is 5 to 50% by mass.
(B) The total content of zinc and calcium as the mineral is 0.002 to 1% by mass.
(C) The total content of carnosol and carnosic acid is 7 ppm or more with respect to fats and oils in which the content of unsaturated fatty acids having two or more double bonds in the fatty acid-constituting fatty acid is 20% by mass or more.
(D) The emulsifier is contained in an amount of 0.05 to 50 times the total content of carnosol and carnosic acid, and the emulsifier has 6 to 24 carbon atoms in the constituent fatty acid and 3 to 15 HLB. Some are polyglycerol fatty acid esters or sucrose fatty acid esters.   The fat-containing pet food according to claim 1, wherein tocopherol is contained in an amount of 0.5 to 200 times the total content of carnosol and carnosic acid.