JP5104888B2 - PET bottle sterilization method and apparatus - Google Patents

Description

  The present invention relates to a method and apparatus for sterilizing PET bottles.

  As a method of sterilizing a PET bottle to be applied to an aseptic filling machine, for example, a method of sterilizing by spraying an aqueous solution of peracetic acid or hydrogen peroxide onto a PET bottle as disclosed in Japanese Patent No. 2851373 is known. ing. JP-A-3-224469 discloses that hydrogen peroxide sprayed in a chamber is heated and vaporized, and then hydrogen peroxide is condensed in air to form a hydrogen peroxide mist. A method of sterilization by contacting with a PET bottle is disclosed.

Japanese Patent No. 2851373 JP-A-3-224469

  As an aseptic filling system for PET bottles, there is an in-line type system that consistently performs from bottle molding to filling of contents on the same line. In this system, a processing capacity of about 500 to 1000 bottles per minute is desired, and in order to achieve this, reduction of the time required for bottle sterilization is a problem.

  An object of this invention is to provide the sterilization method which can sterilize a PET bottle at high speed and reliably, and an apparatus suitable for it.

  The present invention will be described below. In order to facilitate understanding of the present invention, reference numerals in the accompanying drawings are appended in parentheses, but the present invention is not limited to the illustrated embodiment.

  In the sterilization method of the present invention, a step of introducing hydrogen peroxide mist into the PET bottle (1) and discharging the mist from the PET bottle while heating the PET bottle into which the mist has been introduced. A process.

  Since the hydrogen peroxide mist is generated by once vaporizing hydrogen peroxide droplets and condensing, it has a high concentration and can be sterilized efficiently. After the mist is introduced, the sterilizing effect is improved by heating the PET bottle, and at the same time, the permeation of hydrogen peroxide into the PET bottle is suppressed, and the sterilizing component easily floats on the surface of the PET bottle. In addition, by discharging the mist drifting in the interior space of the PET bottle, excess hydrogen peroxide is prevented from adhering to the inner surface of the PET bottle from the viewpoint of the sterilization effect, and the hydrogen peroxide to the PET bottle is Can be more effectively suppressed.

  The sterilization method of the present invention includes a step of preheating the PET bottle prior to the introduction of the mist. By performing preheating, a high sterilization effect can be exhibited from the beginning of the mist introduction, and sterilization can be performed efficiently in a short time. The penetration of hydrogen peroxide into the PET bottle can be more effectively suppressed.

  In the preliminary heating step, in addition to heating the entire PET bottle, the mouth portion (1a) of the PET bottle is separately heated. Alternatively, in the preliminary heating step, hot air may be sent into the PET bottle to heat the entire PET bottle, and the mouth (1a) of the PET bottle may be separately heated. Since the mouth is less likely to rise in temperature compared to other parts, the effect of the preheating can be more effectively brought out by heating this part separately. The supply of hot air into the PET bottle is preferably performed from a nozzle inserted in the PET bottle. The mouth can be heated by, for example, a method of blowing hot air from the outside of the mouth.

  In the sterilization method of the present invention, a predetermined holding time may be provided after the introduction of the mist and before the discharge of the mist is started. By providing the holding time, the mist can be brought into uniform contact with the inner surface of the PET bottle and can be sterilized reliably. The holding time can also be used as the transportation time of the PET bottle from the step of introducing mist to the step of discharging mist.

  In the sterilization method of the present invention, hot air is sent to the PET bottle into which the mist has been introduced to heat the PET bottle and discharge the mist. In this way, it is possible to efficiently discharge the mist and heat the PET bottle.

  The sterilizing apparatus of the present invention comprises a means (16) for introducing hydrogen peroxide mist into a PET bottle (1), a means (17) for heating the PET bottle into which the mist has been introduced, and the PET product. Means (17) for discharging the mist from the bottle.

  The sterilizing apparatus of the present invention comprises means (16) for introducing hydrogen peroxide mist into the PET bottle (1), means (17) for sending hot air into the PET bottle into which the mist has been introduced, and Is provided.

  According to these apparatuses, the mist of hydrogen peroxide can be introduced into the PET bottle, and the mist can be discharged from the PET bottle while heating the PET bottle into which the mist has been introduced. The sterilization method can be realized.

  The sterilization apparatus of the present invention includes means for preheating the PET bottle prior to the introduction of the mist. As the preheating means, there are provided means for sending hot air into the PET bottle to heat the whole PET bottle and means for heating the mouth of the PET bottle from the outside. The supply of hot air into the PET bottle is preferably performed from a nozzle inserted in the PET bottle.

  Furthermore, in the method for heating a container according to the present invention, hot air is sent from the nozzle (2) inserted into the container (1) to heat the entire container, and the mouth (1a) of the container is separately heated. It is characterized by that.

  According to this heating method, hot air can be reliably introduced into the container from the nozzle inserted into the container. In addition, by separately heating the mouth portion that is difficult to rise in temperature, the entire container can be reliably and quickly heated to a desired temperature. Therefore, if this heating method is applied in the preheating step in the sterilization method of the present invention, it can contribute to speeding up the sterilization treatment. In addition, the heating method of the container of this invention can be utilized not only for the preheating in the sterilization process of a container but for every case where the heating of a container is required.

  As described above, according to the sterilization method and apparatus of the present invention, the PET bottle introduced with the hydrogen peroxide mist is heated to enhance the sterilization effect by the mist, while the hydrogen peroxide component is added to the PET bottle. In addition to suppressing permeation, the hydrogen peroxide mist drifting in the PET bottle is forcibly discharged to further effectively prevent the hydrogen peroxide component from penetrating into the PET bottle. The inner surface of the PET bottle can be reliably sterilized in a short time while minimizing the residual concentration of hydrogen peroxide.

The figure which shows the outline | summary of the disinfection procedure of the PET bottles for drinks concerning one Embodiment of this invention. The figure which shows the state which inserted the nozzle in the bottle. The figure which shows the apparatus for producing | generating the mist of hydrogen peroxide. The top view of the aseptic filling system which concerns on one Embodiment of this invention.

  FIG. 1: has shown the outline | summary of the disinfection procedure of the bottle made from PET for drinks concerning one Embodiment of this invention. In this sterilization method, first, as shown in FIG. 1A, the nozzle 2 is inserted into the inside of the bottle 1 from the mouth 1a, and hot air is sent from the nozzle 2 to preheat the bottle 1. At the same time, nozzles 3 and 3 are installed on the outer periphery of the mouth portion 1a of the bottle 1, and hot air is blown from the nozzles 3 to the mouth portion 1a to further heat the mouth portion 1a. This is because the mouth 1a may not be sufficiently heated by only the hot air from the nozzle 2. The reason why the nozzle 2 is inserted into the bottle 1 is to reliably send hot air into the bottle 1. The insertion amount of the nozzle 2 may be appropriately changed according to the flow rate of hot air, the diameter of the mouth portion 1a, etc., but as shown in FIG. 2, the bottle provided between the mouth portion 1a and the body portion 1c of the bottle 1 The tip of the nozzle 2 may be positioned in the diameter transition region 1b. The transition region 1b can be defined as a range in which the bottle diameter expands to, for example, 70% of the maximum diameter from the lower end of the mouth 1a. The preheating is desirably performed so that the inner surface of the bottle 1 is 40 ° C. or higher.

The preheated bottle 1 is conveyed to a mist supply process. In the mist supply step, hydrogen peroxide mist is supplied from the nozzle 4 into the bottle 1. The hydrogen peroxide mist is generated, for example, by a mist generator 33 shown in FIG. The generator 33 includes a hydrogen peroxide supply unit 35 that supplies an aqueous solution of hydrogen peroxide (H ₂ O ₂ ) in drops, and an aqueous solution of hydrogen peroxide supplied from the hydrogen peroxide supply unit 35. And a vaporization section 36 that is heated to a boiling point or higher and vaporizes. The hydrogen peroxide supply unit 35 is provided with a spray 35a. The spray 35a is provided with a hydrogen peroxide supply port 35b and a compressed air supply port 35c, and these supply ports 35b and 35c are connected to a hydrogen peroxide supply source or a compressed compressed air supply source (not shown).

  The aqueous solution of hydrogen peroxide and compressed air supplied from the supply ports 35b and 35c are mixed inside the two-fluid spray 35a, so that the vaporizer 36 is connected to the spray 35a and the nozzle 35d connected via the extension pipe 35e. An aqueous solution of hydrogen peroxide is sprayed into the vaporizing tube 37. The vaporizing pipe 37 is, for example, an outer cylinder 37a made of asbestos ribbon, an inner cylinder 37b made of a sanitary pipe forming the inner wall of the vaporizing pipe 37, and a heater as heating means provided between the outer cylinder 37a and the inner cylinder 37b. 37c. The nozzle 4 described above is connected to the discharge port 37 d at the lower end of the vaporizing tube 37.

  Drop-like hydrogen peroxide supplied to the inside of the vaporizing tube 37 is vaporized by the heat of the heater 37c. The vaporized hydrogen peroxide is liquefied again by the temperature drop until it is led to the vicinity of the bottle 1 through the nozzle 4. As a result, hydrogen peroxide mist finer than the hydrogen peroxide droplets generated by the two-fluid spray 35a is generated. By introducing the mist hydrogen peroxide into the inside of the bottle 1, the inner surface of the bottle 1 comes into contact with the hydrogen peroxide and is sterilized. It should be noted that the amount of hydrogen peroxide mist attached to one bottle having a capacity of 500 ml is preferably in the range of 5 μl to 100 μl in terms of a 35 wt% hydrogen peroxide solution. That is, the amount of mist is set so that hydrogen peroxide equivalent to when hydrogen peroxide solution containing 35% by weight of hydrogen peroxide is supplied into the bottle in the range of 5 μl to 100 μl adheres to the bottle 1. Is preferred. The blowing time of mist is preferably in the range of 0.1 second to 1 second with respect to one bottle. The concentration of hydrogen peroxide contained in the generated mist is preferably 35% by weight or more.

  After supplying the mist, the bottle 1 is conveyed to the hot air supply process. During conveyance, the bottle 1 is held for a predetermined time with hydrogen peroxide mist introduced therein. In the hot air supply process, the nozzle 5 is inserted into the bottle 1, and hot air is sent from the nozzle 5. The bottle 1 is heated from the inner surface by hot air, and the sterilizing effect by the hydrogen peroxide mist is enhanced, and the permeation of hydrogen peroxide into the bottle 1 is suppressed, so that the hydrogen peroxide easily floats on the inner surface of the bottle 1. Further, mist drifting inside the bottle 1 is discharged out of the bottle 1 by hot air. At this point, since the sterilization has already been sufficiently performed by the hydrogen peroxide mist adhering to the inner surface of the bottle 1, even if the mist drifting in the inner space of the bottle 1 is discharged, the sterilization effect is not impaired, but rather an excess. By discharging the mist at an early stage, there is an advantage that excessive permeation of hydrogen peroxide into the inner surface of the bottle 1 can be suppressed and cleaning in the subsequent process can be completed in a short time.

  The holding time after the introduction of the hydrogen peroxide mist until the start of the blowing of hot air is preferably in the range of 1.0 to 10 seconds. The hot air may be blown in a range in which all of the mist drifting inside the bottle 1 can be discharged, and about 1 second is sufficient for the time. When the temperature of the hot air is equal to or higher than the heat resistance temperature (for example, 60 ° C.) of the bottle 1, if the hot air blowing time is too long, the bottle 1 may be heated beyond the heat resistance temperature and may be deformed. It is desirable to insert the nozzle 5 up to the bottle diameter transition region 1b as in the preheating step.

  After the supply of hot air, the bottle 1 is conveyed to the cleaning process. During conveyance, the bottle 1 is held in a heated state for a predetermined time. And the bottle 1 is reversed up and down at the end of conveyance. In the cleaning process, the nozzle 6 is inserted into the bottle 1 and aseptic water heated from the nozzle 6 is fed as a cleaning liquid. Thereby, the hydrogen peroxide adhering to the inner surface of the bottle 1 is washed away. It is desirable to insert the nozzle 6 to a position overlapping the transition region 1b inside the bottle 1 as in the preheating process and the hot air supply process.

  The standby time until the start of the supply of sterile water after the supply of hot air is stopped is preferably in the range of 0.1 to 10 seconds. Aseptic water is preferably heated to improve washing efficiency. The temperature of the cleaning liquid is preferably in the range of 40 ° C to 80 ° C. Since the permeation of hydrogen peroxide into the bottle 1 is suppressed in the hot air supply step described above, cleaning with sterile water can be completed in a short time. For example, a 500 ml bottle can be completed in about 3 seconds.

  FIG. 4 shows an example of an aseptic filling system using the sterilization method described above. The aseptic filling system has an aseptic chamber 10. Prior to filling the bottle 1 with the beverage, the inside of the sterile chamber 10 is subjected to a predetermined sterilization treatment. Thereafter, aseptic air filtered by a filter is constantly supplied into the chamber 10, and the inside of the chamber 10 is maintained at a positive pressure (a state higher than the atmospheric pressure).

  The aseptic chamber 10 is provided with an inlet 11 and an outlet 12 for the bottle 1. A bottle molded by a bottle molding machine (not shown) is transported along the transport line 13, taken into the chamber 10 from the introduction port 11, and further supplied to the outer surface sterilizer 15 via the turntable 14. The outer surface sterilizer 15 sterilizes the outer surface of the bottle 1 by bringing a mist of hydrogen peroxide (hydrogen peroxide) into contact with the outer surface of the bottle 1 conveyed by the turntable 15a. A preheating zone 15b is provided in a part of the turning path of the turntable 15a. In the zone 15b, the nozzle 2 of FIG. 1A is inserted into the bottle 1, and hot air is sent into the bottle 1 while the nozzle 2 moves in synchronization with the bottle 1 to preheat the bottle 1. . If necessary, the zone 15b is also provided with a nozzle 3 for heating the mouth 1a.

  The bottle 1 whose outer surface is sterilized by the outer surface sterilizer 15 is then transferred to the turntable 16 a of the inner surface sterilizer 16. A holding zone 16b is provided in a part of the turning path of the turntable 16a, and the bottle 1 is held for a predetermined time by passing through the zone 16b. The bottle 1 that has passed through the holding zone 16b is guided to the internal sterilization zone 16c. A nozzle 4 (see FIG. 1B) for supplying hydrogen peroxide mist is provided in the internal sterilization zone 16c, and hydrogen peroxide mist is supplied from the nozzle 4 to the inside of the bottle 1. The bottle 1 that has passed through the internal sterilization zone 16 c is transferred to the turntable 17 a of the hot air supply machine 17.

  A holding zone 17b and a hot air blowing zone 17c are provided on the turning path of the turntable 17a. By passing through the holding zone 17b, the bottle 1 is held for a predetermined time while hydrogen peroxide mist is blown into the bottle 1. In the hot air blowing zone 17 c, the nozzle 5 of FIG. 1C is inserted into the bottle 1, and the hot air is sent into the bottle 1 while the nozzle 5 moves in synchronization with the bottle 1 to heat the bottle 1. The hydrogen peroxide mist inside is discharged.

  The bottle 1 that has passed through the hot air blowing zone 17 c is transferred to the turntable 19 a of the washing machine 19 through the turntable 18. A holding reversal zone 18a is provided between the hot air blowing zone 17c and the delivery point of the bottle 1 from the turntable 18 to the washing machine 19. As the bottle 1 passes through the holding reversal zone 18a, a predetermined waiting time is ensured between the blowing of hot air and the start of cleaning. Further, the bottle 1 is inverted up and down while passing through the holding inversion zone 18a.

  The nozzle 1 shown in FIG. 1D is inserted into the bottle 1 transferred to the turntable 19 a of the washing machine 19, and the aseptic water heated inside the bottle 1 while moving in synchronization with the bottle 1. Is sent to clean the inside of the bottle 1.

  The bottle 1 washed by the washing machine 19 is subsequently transferred to the turntable 21a of the filling machine 21 via the transfer turntable group 20. While the bottle 1 is conveyed along the turntable 21a, the bottle 1 is filled with a beverage. The bottle 1 filled with the beverage is guided to the lid closing machine 22. The capping machine 22 seals the bottle 1 by screwing a cap (not shown) into the mouth 1 a of the bottle 1. The cap tightener 22 is supplied with a sterilized cap through a cap sterilizer 24 from a cap feeder 23 installed outside the aseptic chamber 10. The bottle 1 sealed by the lid fastening machine 22 is carried out from the discharge port 12 to the outside of the aseptic chamber 10 by the transport line 25.

  In addition, this invention is not limited to the above embodiment, It can implement with a various form. The discharging of the mist from the bottle 1 and the heating of the bottle 1 may be performed by different means. For example, air may be sucked from the inside of the bottle 1 to discharge mist, and the bottle 1 may be heated by radiant heat from a heat source installed outside thereof. A hot air jet outlet may be provided at a position facing the inner surface of the mouth of the nozzle 2 so that the mouth 1a can be heated separately from the body 1c and the like. The present invention is not limited to beverage bottles 1 and can be used to sterilize various PET bottles. The hot air supply may be started immediately after the supply of hydrogen peroxide mist is stopped. After removing mist by supplying hot air, cleaning may be started immediately.

  The sterilization treatment was carried out on the PET bottle (polyethylene terephthalate bottle) having a capacity of 500 ml while changing the detailed conditions according to the following procedure.

1. The bottle was preheated by supplying hot air of 0.1 m ^{3 /} min from a nozzle with an inner diameter of 10 mm to the inside of the bottle. The temperature of the hot air was set to 105 ° C. to 125 ° C. in the vicinity of the tip of the nozzle, and the insertion amount of the nozzle into the bottle was set to 30 mm. At the same time, hot air at 85 ° C. was blown from the nozzle with an inner diameter of 50 mm toward the mouth of the bottle at a flow rate of 0.1 m ³ per minute. Note that the number of nozzles for heating the mouth was two for one bottle. The hot air blowing time from each nozzle was set to 3 seconds. The temperature in the bottle after completion of the hot air blowing reached 50 ° C.

  2. After stopping the hot air blowing, the bottle was left for 1 second, and then hydrogen peroxide mist was blown into the bottle for 0.6 seconds. The amount of hydrogen peroxide attached to the inner surface of the bottle was 15 to 40 μl in terms of a 35 wt% hydrogen peroxide solution.

  3. After completion of the mist blowing, the bottle was left for 0.5 to 3.5 seconds. Thereafter, a nozzle was inserted into the bottle and hot air was blown in for 1 second. The inner diameter of the nozzle, the amount of insertion, the temperature and flow rate of hot air are the same as in preheating.

  4). After blowing hot air, the bottle was left for 1 to 3.5 seconds. Thereafter, the bottle was inverted, a nozzle with an inner diameter of 6 mm was inserted into the bottle, and aseptic water heated to 70 ° C. was sent in for 3 seconds to wash the inside of the bottle. The flow rate of sterile water was 8.5 liters per minute.

  Moreover, some processes were abbreviate | omitted and sterilized.

For each sterilization condition, sterilize 5 bottles with 10 ³ , 10 ⁴ , or 10 ⁵ Bacillus subtilis spores, and aseptically dispense tryptic soy bouillon medium into the bottles, and culture and sterilize The presence or absence of sex was evaluated. From the test results under each sterilization condition, the number of surviving bacteria is calculated stochastically by the most probable number (MPN), and the logarithmic value of the number of adherent bacteria and the number of surviving bacteria is obtained by the following formula to sterilize The effect was evaluated.
Bactericidal effect = log (number of adherent bacteria / number of surviving bacteria)

  The list of test results is shown in the following table.

なお、残留判定、殺菌判定及び総合判定はそれぞれ４段階に分けて評価し、最も良好なものから順に◎、○、△、×で示している。

The residue determination, sterilization determination, and comprehensive determination are each evaluated in four stages, and are indicated by ◎, ○, Δ, and X in order from the best.

  The following points can be confirmed from the above table.

  Condition 3 and condition 7 differ in the amount of hydrogen peroxide mist adhered and the presence or absence of preheating. In conditions 2 and 6, the residual concentration of hydrogen peroxide is the same, and the presence or absence of preheating is different. From these results, it can be seen that the sterilization effect is higher when hydrogen peroxide mist is supplied after preheating. However, if the holding time after mist spraying is lengthened, the bactericidal effect is improved to a practically sufficient level.

  Next, when the conditions 2 and 8 or the conditions 3 and 9 are compared, even if the residual amount of hydrogen peroxide or the amount of hydrogen peroxide mist adhered is the same, after introducing the hydrogen peroxide mist into the bottle, It can be seen that the bactericidal effect is impaired when the holding time until the start of feeding is short.

  Conditions 10 and 11 omit the blowing of hot air after the introduction of mist. Comparing condition 3 and condition 10, it can be seen that the residual concentration of hydrogen peroxide increases if hot air blowing is omitted even if the amount of hydrogen peroxide mist adhered is the same. Comparing condition 2 and condition 11, it can be seen that when the residual concentration of hydrogen peroxide mist is the same, the bactericidal effect is insufficient if hot air blowing is omitted.

  In order to see the effect of heating the bottle mouth part in the preheating step, the mouth part was not heated from the outside in Condition 3, and the mouth part of the bottle was heated from the outside in Condition 5. As is clear from these comparisons, the bactericidal effect increases if the mouth is heated separately.

DESCRIPTION OF SYMBOLS 1 PET bottle 1a Mouth part 2 Preheating nozzle 3 Mouth heating nozzle 4 Mist supply nozzle 5 Mist discharge nozzle 6 Cleaning liquid supply nozzle 10 Aseptic chamber 15 External sterilizer 15b Preheating zone 16 Internal sterilizer 16c Internal sterilization zone 17 Hot air supply machine 19 Washing machine 21 Filling machine 22 Capping machine 23 Cap feeder 24 Cap sterilizer 35 Hydrogen peroxide supply part 35a Two-fluid spray

Claims (11)

A nozzle that moves in synchronization with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and hot air is blown into the PET bottle from the tip of the nozzle. A preheating step of heating the entire PET bottle to a desired temperature by blowing hot air from the outside to the mouth of the PET bottle that is difficult to increase in temperature, while heating the entire bottle;
A sterilization step of introducing hydrogen peroxide mist into the preheated PET bottle and sterilizing the inner surface of the PET bottle;
A nozzle that moves in synchronism with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and then the inside of the PET bottle is sterilized from the tip of the nozzle. Hot air is sent to the bottle and the PET bottle is heated with the hot air to enhance the sterilization effect of the hydrogen peroxide mist, and the penetration of hydrogen peroxide into the PET bottle is suppressed, and the mist drifting in the PET bottle is made of PET. A method for sterilizing a PET bottle, characterized by comprising a step of discharging to the outside of the bottle. A nozzle that moves in synchronization with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and hot air is blown into the PET bottle from the tip of the nozzle. A preheating step of heating the entire PET bottle to a desired temperature by blowing hot air from the outside to the mouth of the PET bottle that is difficult to increase in temperature, while heating the entire bottle;
Introducing a hydrogen peroxide mist into the preheated PET bottle and sterilizing the PET bottle inner surface;
After the mist is introduced and a predetermined holding time is set, a nozzle that moves in synchronization with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle. The hot air is sent into the PET bottle from the tip of the nozzle, and the PET bottle is heated with the hot air to enhance the sterilization effect by the hydrogen peroxide mist, thereby suppressing the penetration of hydrogen peroxide into the PET bottle. A method for sterilizing a PET bottle, comprising the step of discharging mist drifting in the bottle to the outside of the PET bottle. A nozzle that moves in synchronization with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and hot air is blown into the PET bottle from the tip of the nozzle. A preheating step of heating the entire PET bottle to a desired temperature by blowing hot air from the outside to the mouth of the PET bottle that is difficult to increase in temperature, while heating the entire bottle;
A sterilization step of introducing hydrogen peroxide mist into the preheated PET bottle and sterilizing the inner surface of the PET bottle;
A nozzle that moves in synchronism with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and then the inside of the PET bottle is sterilized from the tip of the nozzle. Hot air is sent to the bottle and the PET bottle is heated with the hot air to enhance the sterilization effect of the hydrogen peroxide mist, and the penetration of hydrogen peroxide into the PET bottle is suppressed, and the mist floating in the PET bottle is made of PET. A method for sterilizing a PET bottle, characterized by comprising a step of discharging to the outside of the bottle.   The method for sterilizing a PET bottle according to any one of claims 1 to 3, wherein the temperature in the PET bottle is set to 40 ° C to 50 ° C in the preliminary heating step.   The PET bottle sterilization method according to claim 2, wherein the predetermined holding time is 1.0 to 10 seconds.   4. The PET product according to claim 1, wherein an amount of the mist attached to a 500 ml PET bottle is 5 μl to 100 μl in terms of a 35 wt% hydrogen peroxide solution. How to sterilize bottles.   The method for sterilizing a PET bottle according to any one of claims 1 to 3, wherein the mist is blown into the PET bottle from a nozzle in a range of 0.1 second to 1 second. A nozzle that moves in synchronization with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and hot air is blown into the PET bottle from the tip of the nozzle. Preheating means for heating the entire PET bottle and heating the entire PET bottle to a desired temperature by blowing hot air from the outside to the mouth of the PET bottle which is difficult to rise in temperature,
Means for introducing hydrogen peroxide mist into the preheated PET bottle and sterilizing the inner surface of the PET bottle;
A nozzle that moves in synchronism with the PET bottle is inserted into the PET bottle so that its tip is located in the transition region of the diameter of the PET bottle, and then the inside of the PET bottle is sterilized from the tip of the nozzle. Hot air is sent to the bottle and the PET bottle is heated with the hot air to enhance the sterilization effect of the hydrogen peroxide mist, and the penetration of hydrogen peroxide into the PET bottle is suppressed, and the mist drifting in the PET bottle is made of PET. A PET bottle sterilization apparatus comprising: means for discharging outside the bottle.   9. The PET bottle sterilization apparatus according to claim 8, wherein the preheating means sets the temperature in the PET bottle to 40 ° C. to 50 ° C.   The preliminary heating means, the sterilizing means, and the discharge means are arranged in order along a continuous swirling path formed by a plurality of turntables, and a preliminary is obtained by blowing hot air into the bottle moving on the swirling path. 9. The PET bottle sterilization apparatus according to claim 8, wherein heating, sterilization with hydrogen peroxide mist, and discharge of hydrogen peroxide mist by blowing hot air are sequentially performed. The PET bottle sterilization apparatus according to claim 10 , wherein a holding zone for holding a state in which hydrogen peroxide mist is blown into the bottle for a predetermined time is provided in the turning path.

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