JP5101207B2 - Method for producing polymer resin molded body with controlled distribution of magnetic particles in polymer resin, and apparatus for producing the same - Google Patents

Description

The present invention relates to a method for manufacturing a polymer resin molded body in which the distribution state of magnetic particles in a polymer resin is controlled , and a manufacturing apparatus therefor.

Currently, in the polymer material field, functional materials are being actively developed using composite technology and nanotechnology.
One of them is a functionally gradient material having different functions in one material by tilting the blending components.
Regarding the gradient orientation of different resin components, various polymerization methods using compatible / phase-separable polymers (the following non-patent document 1) and production methods applying photopolymerization reactions (the following non-patent document 2) have been reported. ing.
I. Hopkins and M.M. Myatt, “Macromolecules”, 35, 5153 (2002) Hideyuki Nakanishi, “Measurement of IPN Inclined Structure Created by Photoreaction”, Polymer Papers, Vol. 62, no. 10, pp. 519-522 (Oct, 2005)

As described above, regarding the tilted orientation of different resin components, polymerization methods using various compatible / phase-separable polymers and production methods using photopolymerization reactions have been reported. There are no reports of the tilt alignment method in various compounding agents.
In view of the above situation, the present invention provides a method for producing a polymer resin molded body in which the distribution state of magnetic particles in a polymer resin capable of performing tilted orientation in the magnetic particles in the polymer resin is controlled, and the production thereof. An object is to provide an apparatus.

In order to achieve the above object, the present invention provides
[1] In the method for producing a polymer molded resin distribution is controlled in the magnetic particles in the polymer resin, mixed with magnetic particles in a polymer resin, changing the distribution of the magnetic field by the superconducting coil field , said magnetic particles are applied to the mixed polymer resin, it said have rows concentration gradient orientation of the magnetic particles, characterized in that to obtain a long life of polymeric resin molding.

[2] In the method for producing a polymer resin molded article in which the distribution state of magnetic particles in the polymer resin described in [1] is controlled, the magnetic field generated by the superconducting coil is changed.
[3] In the method for producing a polymer resin molded article in which the distribution state of the magnetic particles in the polymer resin described in [1] is controlled , to the polymer resin in which the magnetic particles of the magnetic field by the superconducting coil are mixed. The application time is controlled.

[4] In a polymer resin molding manufacturing apparatus in which the distribution state of magnetic particles in a polymer resin is controlled, a superconducting coil that generates a magnetic field and magnetic particles disposed in the magnetic field of the superconducting coil are mixed. wherein the polymer resin, and a device for varying the distribution of the magnetic field applied to the polymer resin, it has rows concentration gradient orientation of the magnetic particles, to obtain a long life of polymeric resin molded article And

[5] The apparatus for producing a polymer resin molded body in which the distribution state of the magnetic particles in the polymer resin described in [4] is controlled , wherein the apparatus for changing the distribution of the magnetic field applied to the polymer resin is Kenzan. A polymer resin in which the magnetic particles are mixed is disposed on the sword-like magnetic body.
[6] The apparatus for producing a polymer resin molded body in which the distribution state of the magnetic particles in the polymer resin according to [4] is controlled , wherein the apparatus for changing the distribution of the magnetic field applied to the polymer resin is a disk And a polymer resin in which the magnetic particles are mixed is disposed on the disk-shaped magnetic body.

According to the present invention, the concentration gradient of the distribution state of the magnetic particles in the polymer resin can be controlled in accordance with the change in the shape of the magnetic material disposed in the magnetic field.
Further, the concentration gradient orientation of the magnetic particles can be performed by controlling the application time of the magnetic field applied to the polymer resin mixed with the magnetic particles.
For example, it is possible to extend the life of the polymer resin molded body by intensive blending of magnetic particles as a deterioration preventing agent in the polymer resin.

The method of manufacturing a polymeric molded resin distribution state of the magnetic particles is controlled in the polymer resin of the present invention, by mixing magnetic particles in a polymeric resin, changing the distribution of the magnetic field by the superconducting coil field , said magnetic particles are applied to the mixed polymer resin, it has rows concentration gradient orientation of the magnetic particles, to obtain a long life of polymeric resin molding.

Hereinafter, embodiments of the present invention will be described in detail.
In the present invention, magnetic particles (Sr ferrite powder) having an average particle diameter of 1 μm are mixed with polyester resin used in FRP for the purpose of causing the magnetic particles in the polymer resin to be inclined by an external magnetic field. The orientation state of the magnetic particles was observed when the resin was cured in a magnetic field generated using a coil or the like.

FIG. 1 is a photograph showing a state in which magnetic particles having an average particle diameter of 1 μm are mixed and cured in a polyester resin in a magnetic field of only a superconducting coil showing a comparative example of the present invention.
In this photograph, a sample 2 in which magnetic particles are mixed with a polyester resin as a polymer resin is set above the superconducting coil 1.
Thus, when magnetic particles having an average particle size of 1 μm were mixed and hardened in a polyester resin in a magnetic field using only a superconducting coil, almost no tilted orientation of the magnetic particles was observed.

  FIG. 2 shows the magnetic field generated by the superconducting coil according to the first embodiment of the present invention, in which magnetic particles are mixed with polyester resin as a polymer resin in order to further focus local magnetic flux lines and change magnetic field distribution. It is a photograph which shows the state which arrange | positions and hardens the magnetic body 3 of a sword mountain shape directly under the sample 4. FIG. Here, in the sword mountain-like magnetic body 3, 17 × 17 iron needles having a diameter of 1.6 mm and a length of 25 mm were arranged at intervals of 4 mm.

FIG. 3 shows a second embodiment of the present invention in which a disk-shaped magnetic body 5 is further arranged in a magnetic field generated by a superconducting coil, and a polyester resin as a polymer resin is magnetically disposed immediately above the disk-shaped magnetic body 5. It is a photograph which shows the state which set and hardened the sample 6 which mixed particle | grains. Here, the disk-shaped magnetic body 5 was fixed by sandwiching an iron disk having a thickness of 1 mm between aluminum plates.
When the magnetic flux density of the superconducting coil was set to 0.1 T to 1.5 T (Tesla), localization due to orientation increased as the magnetic flux density increased. In addition, when the diameter of the disk-shaped magnetic material was increased to expand the focusing range of the magnetic flux density, the range of orientation expanded, but the localization decreased. Therefore, it has been found that the localization of magnetic particles can be adjusted by the magnetic flux density and magnetic field distribution.

Hereinafter, the situation of the polymer resin when cured in each installation situation when the sample is installed on the superconducting coil as described above will be shown.
FIG. 4 is a photograph showing the case where the sample according to the present invention was cured [0T (Tesla)] without applying a magnetic field. The magnetic particles were dispersed and the orientation of the magnetic particles was not obtained.
FIG. 5 is a photograph showing the case where the sample according to the present invention was cured by applying a magnetic field [0.1 T (Tesla)] of only the superconducting coil, and almost no orientation of the magnetic particles was obtained.

  Therefore, in order to change the magnetic field distribution (including focusing of local magnetic flux lines), the sample was arranged as shown in FIG. Here, when the magnetic flux density of the superconducting coil was set to 1.0 T (Tesla), as shown in FIG. 6, the gradient orientation of the magnetic particles concentrated in the portion directly above the sword-like magnetic material was observed. . Further, when the magnetic flux density of the superconducting coil was 0.3 T (Tesla), the orientation of the magnetic particles as shown in FIG. 7 was observed.

Similarly, when the sample is arranged as shown in FIG. 3, if the magnetic flux density is 1.0 T (Tesla) on a disk having a diameter of 14 mm, the gradient orientation of the magnetic particles densely arranged on the disk is as shown in FIG. It was seen. Further, when the diameter φ of the disk was 100 mm and the magnetic flux density was 1.0 T (Tesla), the orientation of magnetic particles as shown in FIG. 9 was observed.
Further, a polymer resin molded body in which magnetic particles produced by changing the arrangement time of the sample in the magnetic field are mixed will be described.

  FIG. 10 is a photograph of a polymer resin molded body in which magnetic particles are mixed when a magnetic field is applied to the sample shown in FIG. 2 until curing is complete, and FIG. 11 is a magnetic field applied to the sample shown in FIG. 2 for 5 minutes from the start of curing. 3 is a photograph of a polymer resin molded body in which magnetic particles are mixed. FIG. 12 is an electron micrograph of the polymer resin mixed with the magnetic particles shown in FIG. 11. The left side of FIG. 12 is the bottom side of the sample, and the white portion corresponds to the magnetic particles. FIG. 13 is a diagram showing the distribution state of magnetic particles divided by the height of the polymer resin mixed with the magnetic particles shown in FIG. 12, where the horizontal axis is the height (mm) from the bottom of the sample, and the vertical axis is white. The area ratio (%) of dots is shown. This is calculated by image processing.

As shown in FIG. 10, it was observed that the magnetic particles in the resin completely cured in the magnetic field were aggregated and oriented in a needle shape, but when released from the magnetic field during the curing of the sample, It was found that the magnetic particles were oriented in the form of needles without agglomeration, and the magnetic field state during curing of the sample affected the distribution of the magnetic particles in the polymer resin.
In FIG. 11, a concentration gradient was observed in the distribution state of the magnetic particles in the height direction from the bottom surface.

  In addition, this invention is not limited to the said Example, Based on the meaning of this invention, a various deformation | transformation is possible and these are not excluded from the scope of the present invention.

The method for producing a polymer resin body in which the inclination tendency of magnetic particles in the polymer resin of the present invention is controlled can be used for producing a polymer resin molded body having a long lifetime.

It is a photograph which shows the state which mixes and hardens the magnetic particle with an average particle diameter of 1 micrometer in polyester resin in the magnetic field only of the superconducting coil which shows the comparative example of this invention. In the first embodiment of the present invention, immediately below a sample in which magnetic particles are mixed with polyester resin as a polymer resin in order to cause the magnetic field generated by the superconducting coil to further focus local magnetic flux lines and change the magnetic field distribution. It is a photograph which shows the state which arrange | positions and hardens a sword mountain-like magnetic body. A sample in which a disk-shaped magnetic body is further arranged in a magnetic field generated by a superconducting coil according to the second embodiment of the present invention, and magnetic particles are mixed with a polyester resin as a polymer resin immediately above the disk-shaped magnetic body. It is a photograph which shows the state which installs and hardens. It is a photograph which shows the case where a sample is hardened to [0T (Tesla)] without applying a magnetic field to the sample according to the present invention. It is a photograph which shows the case where the magnetic field [0.1T (tesla)] only of a superconducting coil is added to the sample which concerns on this invention, and a sample is hardened. It is a photograph which shows the case where the sample is hardened by adding the magnetic field [1.0T (Tesla)] of only a superconducting coil to the sample on the sword mountain-shaped magnetic body which concerns on this invention. It is a photograph which shows the case where the sample is hardened by applying the magnetic field [0.3T (Tesla)] of only the superconducting coil to the sample on the sword mountain-shaped magnetic body according to the present invention. It is a photograph which shows the case where the sample is hardened by adding the magnetic field [1.0T (Tesla)] of only a superconducting coil to the sample on the disk-shaped magnetic body with a diameter of 14 mm according to the present invention. It is a photograph which shows the case where the sample is hardened by adding the magnetic field [1.0T (Tesla)] of only a superconducting coil to the sample on the disk-shaped magnetic body with a diameter of 100 mm according to the present invention. It is a photograph which shows the case where a magnetic field is applied to the sample concerning this invention until completion of hardening. It is a photograph which shows the case where a magnetic field is applied to the sample concerning this invention for 5 minutes from the start of hardening. It is an electron micrograph of the polymer resin mixed with the magnetic particles shown in FIG. It is a figure which shows the distribution state of the magnetic particle divided according to the height of the polymer resin which mixed the magnetic particle shown in FIG.

DESCRIPTION OF SYMBOLS 1 Superconducting coil 2, 4, 6 Sample in which magnetic particles are mixed with polyester resin as polymer resin 3 Kenyama-shaped magnetic material 5 Disc-shaped magnetic material

Claims (6)

(A) mixing magnetic particles in a polymer resin;
(B) a magnetic field with varying distribution of the magnetic field by the superconducting coil, is applied to the polymeric resin in which the magnetic particles are mixed, the have a row density gradient orientation of the magnetic particles, long life polymeric resin molding A method for producing a polymer resin molded article in which the distribution state of magnetic particles in the polymer resin is controlled. The method for producing a polymer resin molded body in which the distribution state of magnetic particles in the polymer resin according to claim 1 is controlled, wherein a magnetic field generated by the superconducting coil is changed. A method for producing a polymer resin molded article in which a distribution state is controlled. 2. The method for producing a polymer resin molded body in which the distribution state of magnetic particles in the polymer resin is controlled according to claim 1, wherein the application time of the magnetic field by the superconducting coil to the polymer resin mixed with the magnetic particles is set. A method for producing a polymer resin molded article in which the distribution state of magnetic particles in the polymer resin is controlled. (A) a superconducting coil that generates a magnetic field;
(B) a polymer resin mixed with magnetic particles arranged in the magnetic field of the superconducting coil;
(C) a device for changing the distribution of the magnetic field applied to the polymer resin,
; (D) have a row density gradient orientation of the magnetic particles, long life was the polymer resin moldings distribution is controlled in the magnetic particles in a polymer resin, characterized in that to obtain a polymer resin shaped body Manufacturing equipment. 5. The apparatus for producing a polymer resin molded body in which the distribution state of magnetic particles in the polymer resin is controlled according to claim 4, wherein the apparatus for changing the distribution of the magnetic field applied to the polymer resin is a sword-like magnetic body. , and the the該剣mountains shaped polymer molded resin distribution is controlled in the magnetic particles in the polymer resin, wherein the magnetic particles on the magnetic material mixed polymer resin is placed Manufacturing equipment. 5. The apparatus for producing a polymer resin molded body in which the distribution state of magnetic particles in the polymer resin is controlled according to claim 4, wherein the apparatus for changing the distribution of the magnetic field applied to the polymer resin is a disk-shaped magnetic body. , and the of the disc-shaped polymer molded resin distribution is controlled in the magnetic particles in the polymer resin, wherein the magnetic particles on the magnetic material mixed polymer resin is placed Manufacturing equipment.