JP5046703B2 - Polyimide film and method for producing the same - Google Patents

Description

  The present invention relates to a polyimide film and a method for producing the same, and in particular, is used as a support for an electric wiring board on which a metal foil or a metal thin film represented by copper foil is laminated, or a cover for protecting a flexible printed circuit The present invention relates to a polyimide film having a precise surface suitable for use as a lay film and a production method capable of producing such a polyimide film.

  Polyimide films are used in a wide range of industrial fields as electrical insulating materials that require heat resistance because they have high heat resistance and high electrical insulation. Particularly in recent years, in applications as a support for electrical wiring boards laminated with a copper layer, the use of polyimide film allows the use of solder to connect electrical components such as IC and copper foil, Smaller and lighter can be achieved. For this reason, the use range of a flexible printed circuit board has expanded, and the demand of a polyimide film is also increasing in connection with it.

  As the demand for polyimide films expands, the demands on the characteristics of polyimide films are becoming more severe. For example, the circuit pitch of IC drivers around liquid crystal displays that have been used in the past is becoming narrower year by year, and the two-layer type in which a copper layer is directly provided on a polyimide film by sputtering, vapor deposition, plating, etc. without using an adhesive is increasing. However, there are cases where defects in appearance occur due to the presence of foreign matter such as scratches on the surface of the polyimide film used as the base material and low molecular weight substances (hereinafter referred to as oligomers).

  As a general method for producing a polyimide film, first, an aromatic diamine and an aromatic tetracarboxylic acid are reacted in a polar solvent, and in the case of chemical ring closure, a polyamic acid solution further added with an imidization catalyst and a dehydrating agent is used. A so-called gel film is prepared by casting the polyamic acid solution on a support such as a metal surface to form a film. Thereafter, the polyamic acid in the gel film is changed to polyimide by the action of heat or a chemical ring-closing agent, and the polyimide film is produced by removing the solvent in the drying step.

  In such a polyimide film manufacturing method, various rolls are used to support or stretch the gel film in the process from the film forming process to the drying process. Impurities such as unreacted polymers and low polymers derived from polyamic acid or polyimide and modified products thereof are discharged. Therefore, there is a problem that the surface of the roll in the polyimide film manufacturing process is contaminated with the above impurities, so the roll is regularly cleaned to prevent the dirt from adhering to or transferring to the film. However, the work is complicated, and it is not always possible to completely prevent the adhesion of dirt, which causes defects on the film surface.

  As a roll used in the manufacturing process of such a polyimide film, a roll excellent in chemical resistance such as a metal roll or a roll having a fluororesin layer on the surface has been used conventionally. In general, although metal rolls have high hardness and are not easily damaged, there has been a problem that unreacted polymerization products and low polymerization products that cause dirt are likely to adhere. On the other hand, it is known to use a roll having a surface coated with a Teflon film (trade name) as a roll having a fluororesin layer on the surface, which is difficult to adhere dirt (for example, see Patent Document 1). This roll having a fluororesin layer on the surface is difficult to adhere to dirt such as unreacted polymers and low polymers, but the surface smoothness is poor and the friction coefficient is relatively large. There has been a problem that solids generated by polymerization unreacted substances and low polymer substances that have been generated and grown in the film process accumulate on the scratched part, which is transferred and deteriorates the quality of the polyimide film. In addition, the defect which arises by transferring such a stain | pollution | contamination is usually a crater-like spot, and when a surface is inspected by incandescent lamp or polarized light on a film, it is recognized as a white defect.

On the other hand, a metal roll having an amorphous chrome plating on the surface has been proposed as an improved metal roll that is difficult to get surface contamination (see, for example, Patent Document 2). The polyimide film manufactured using this improved metal roll has few white defects caused by unreacted polymers and low polymers. However, even such an improved metal roll cannot completely prevent adhesion of unreacted polymers or low polymers, and when the roll is used as a transport roll, Since the film is slippery on the surface, when the film slides on the roll, it is not taken into consideration to prevent scratches caused by dirt slightly adhered to the roll surface.
Japanese Patent Laid-Open No. 6-104317 (Claims) Agent letter JP 2004-223787 A (Claims)

  From the above situation, it has not been known that conventional polyimide films are long and free of defects and scratches. Then, this invention makes it a subject to provide the polyimide film excellent in the surface quality without a fault and a flaw on the surface over a long length.

  The present inventors diligently studied about a roll for conveying a gel film used in the production process of a polyimide resin, developed a specific roll having a fluororesin layer on the surface, and used this roll to develop a polyimide film. As a result of manufacturing, it was found that the above problems could be solved at once, and the present invention was completed.

That is, the present invention
[1] A flaw having a roughness of 0.1 μm or more and an area of 0.2 mm ² or more present on the film surface and having 30 or less defects per 1000 m ² , a roughness of 0.1 μm or more and a width of 1 μm or more Polyimide film whose number is 1 or less per 100 m ² ,
[2] A laminate formed by laminating the polyimide film according to [1] and a metal layer,
[3] In a method for producing a polyimide film by stretching a gel film containing polyamic acid using a transport roll and then heat-treating the gel film, the transport film has a roll surface made of a fluororesin layer, and the surface Using a roll having a center line average roughness of 0.03 to 0.55 μm, a maximum roughness of 4.0 μm or less, and a water contact angle of 80 degrees or more, and [4 The production of the polyimide film as described in [3] above, wherein the fluororesin layer comprises a tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer (PFA) or a tetrafluoroethylene / hexafluoropropylene copolymer (FEP). Regarding the method.

  The polyimide film of the present invention is a polyimide film having a good surface quality with few defects such as crater-like spots on a wide range of film surfaces, and extremely small fine scratches, so various applications that require precision For example, it can be suitably applied to applications such as a cover lay film for protecting a flexible printed circuit, a wire or cable insulating film, and an adhesive tape coated with a film surface adhesive.

  Moreover, the laminated body formed by laminating the polyimide of the present invention and the metal layer is an excellent laminated body derived from the excellent characteristics of the polyimide film of the present invention, such as an electric wiring board support (TAB). It can apply suitably for the use of.

  Further, in the production method of the present invention, by using the roll unique to the present invention, there is little contamination of the roll due to unreacted polymerization products and low polymerization products, and the surface hardness of the roll is high during use. Since the trouble which a crack generate | occur | produces on a roll surface can be prevented, the polyimide film with a favorable surface quality can be manufactured continuously.

The polyimide film of the present invention is characterized by very few surface scratches. Specifically, the number of scratches having a roughness of 0.1 mm or more and a width of 1 μm or more per 1000 m ^{2 of} film area is 1 or less, and preferably 0. More specifically, the number of scratches having a roughness of 0.1 mm or more and a width of 1 μm or more per 1000 m ^{2 of} film area is preferably 1 or less, and particularly preferably 0.

  Considering the number of the above scratches in terms of the length of a general film produced industrially, the number of scratches having a roughness of 0.1 mm or more and a width of 1 μm or more is 1 or less over a film length of 50 m, Further, it is preferably 0, more preferably 1 or less, and even more preferably 0 over a film length of 500 m.

Further, in the polyimide film of the present invention, there are few surface defects other than scratches, and specifically, defects of roughness 0.1 mm or more and area 0.2 mm ² or more per 1000 m ^{2 of} film area ( Hereinafter, the number of “defects” may be distinguished from the above-mentioned scratches is 30 or less, preferably 25 or less, and more preferably 20 or less. Considering the number of defects in terms of the length of a general film produced industrially, it is preferably 30 or less, more preferably 25 or less over a film length of 500 m, and 20 or less. It is particularly preferred.

The number of the scratches and the number of defects are specified as follows.
(Number of scratches)
Light is applied to the film surface with a fluorescent lamp, and the film surface is visually observed while the film is running to detect a scratch. The detected scratch is rough (height) with a three-dimensional microscope with a magnification of 100 times. ), The width is measured, and the number of scratches having a roughness of 0.1 μm or more and a width of 1 μm or more is determined.

(Number of defects)
An incandescent lamp or polarized light is applied to the film surface, and the film surface is visually observed while the film is running to detect white defects, and the detected defects are measured with a three-dimensional microscope with a magnification of 100 times. ), Measuring the dimensions, and determining the number of defects having a roughness of 0.1 μm or more and an area of 0.2 mm ² or more.

  The polyimide film of the present invention can be obtained by forming a film using a solution obtained by dissolving polyamic acid in an organic solvent and imidizing the polyamic acid. Here, the polyamic acid in the solution may be partially imidized. The solution may contain a small amount of an inorganic compound, and as a result, the polyimide film of the present invention may contain a small amount of an inorganic compound.

  The thickness of the polyimide film of the present invention is not particularly limited.

  The polyamic acid which is a polyimide precursor in the present invention is preferably composed of an aromatic tetracarboxylic acid and an aromatic diamine and composed of a repeating unit represented by the following formula [I].

（上記式［Ｉ］において、Ｒ１は、少なくとも１個の芳香族環を有する４価の有機基で、その炭素数が２５以下であるものを表わし、Ｒ２は、少なくとも１個の芳香族環を有する２価の有機基で、その炭素数が２５以下であるものを表わし、Ｒ１に結合する２つのカルボキシル基のそれぞれは、Ｒ１における芳香族環のアミド基が結合する炭素原子と相隣接する炭素原子に結合しており、アミノ基は、Ｒ２における芳香族環の炭素原子と結合しているものとする。）

(In the above formula [I], R1 represents a tetravalent organic group having at least one aromatic ring, the carbon number of which is 25 or less, and R2 represents at least one aromatic ring. A divalent organic group having 25 or less carbon atoms, each of the two carboxyl groups bonded to R1 is adjacent to the carbon atom to which the amide group of the aromatic ring in R1 is bonded. It is bonded to an atom, and the amino group is bonded to the carbon atom of the aromatic ring in R2.)

  Specific examples of the aromatic tetracarboxylic acids include pyromellitic acid, 3,3 ′, 4,4′-biphenyltetracarboxylic acid, 2,3 ′, 3,4′-biphenyltetracarboxylic acid, 3,3 ', 4,4'-benzophenonetetracarboxylic acid, 2,3,6,7-naphthalenetetracarboxylic acid, 2,2-bis (3,4-dicarboxyphenyl) propane, pyridine-2,3,5,6 -Aromatic tetracarboxylic acids derived from tetracarboxylic acids or acid anhydrides, or ester compounds or halides of the acids.

  Specific examples of the aromatic diamines include paraphenylene diamine, metaphenylene diamine, benzidine, paraxylylene diamine, 4,4′-diaminodiniphenyl ether, 3,4′-diaminodiphenyl ether, 4,4′- Diaminodiphenylmethane, 4,4′-diaminodiphenylsulfone, 3,3′-dimethyl-4,4′-diaminodiphenylmethane, 1,5-diaminonaphthalene, 3,3′-dimethoxybenzidine, 1,4-bis (3-methyl -5-aminophenyl) benzene and derivatives thereof.

  As a combination of an aromatic tetracarboxylic acid component and an aromatic diamine component particularly suitable for the polyimide in the present invention, pyromellitic dianhydride, 4,4′-diaminodiphenyl ether, and 3,3 ′, 4,4′-biphenyl are used. Examples thereof include a combination of tetracarboxylic dianhydride and 4,4′-diaminodiphenyl ether, and copolymerization of these and / or paraphenylenediamine is preferred.

  The intrinsic viscosity (measured in sulfuric acid at 25 ° C.) of the polyimide constituting the polyimide film of the present invention is preferably in the range of 0.2 to 3.0, and in the range of 0.8 to 2.0. Is more preferable.

  In the polyimide film of the present invention, different polymers may be blended for the purpose of increasing the strength as long as the object of the present invention is not impaired. In addition, organic additives such as antioxidants, heat stabilizers, ultraviolet absorbers, light-shielding agents, and antistatic agents may be added to the extent that they are usually added. Moreover, 0.05-5 weight% of inorganic particles may be added in order to impart the slipperiness of the film.

  Moreover, the polyimide film of the present invention may be subjected to adhesive treatment such as plasma treatment, corona discharge treatment, and annealing treatment, and low heat recovery treatment as desired.

  As described above, the polyimide film of the present invention has excellent surface characteristics, and as a single film, is coated with various uses, for example, a coverlay film for protecting a flexible printed circuit, a wire or cable insulating film, and a film surface adhesive. It can be suitably used for applications such as tape.

  Moreover, the polyimide film of this invention can be used for various uses as a laminated body with metal layers, such as metal foil and a metal thin film, by a well-known method. A laminate formed by laminating with such a metal layer can be suitably used for applications such as a support (TAB) of an electrical wiring board.

  Next, the manufacturing method of this invention which can manufacture the above-mentioned polyimide film of this invention is demonstrated.

  The production method of the present invention is a method for producing a polyimide film by subjecting a gel film comprising polyamic acid to stretching using a transport roll and then heat-treating, and the production method is roughly classified into (1) polyamic acid. The process includes three steps: forming a solution to obtain a gel film, (2) stretching the gel film, and (3) heat-treating. Hereinafter, each step will be described in order.

(1) Step of forming a polyamic acid solution to obtain a gel film The polyamic acid solution used in this step is not particularly limited, and a solution obtained by dissolving polyamic acid in an appropriate organic solvent is used. be able to. Specific examples of the organic solvent include organic polar amide solvents such as N, N-dimethylformamide, N, N-dimethylacetamide and N-methyl-2-pyrrolidone. These organic solvents may be used alone or in combination of two kinds. These are used in combination, but may be used in combination with non-solvents such as benzene, toluene and xylene.

  The polyamic acid solution used in the present invention preferably contains a solid content of 5 to 40% by mass, more preferably 10 to 30% by mass. Moreover, as a viscosity of a polyamic acid solution, it is preferable that the viscosity (temperature 20 degreeC) measured with the Brookfield viscometer is 10-2000 Pa.s from the point that the stable liquid feeding is possible, 100-1000 Pa -It is more preferable that it is s.

  When imidization is performed by the chemical ring closure method, a ring closure catalyst and a dehydrating agent may be added to the polyamic acid, and a gelation retarder such as acetylacetone may be used in combination as desired. Specific examples of the ring-closing catalyst include aliphatic tertiary amines such as trimethylamine and triethylamine, and heterocyclic tertiary amines such as isoquinoline, pyridine, and betapicoline, which are selected from heterocyclic tertiary amines. It is preferred to use at least one amine. The content of the ring-closing catalyst with respect to the polyamic acid is preferably in the range where the content (mol) of the ring-closing catalyst / the content (mol) of the polyamic acid is 0.5 to 8. Specific examples of the dehydrating agent include aliphatic carboxylic acid anhydrides such as acetic anhydride, propionic anhydride and butyric anhydride, and aromatic carboxylic acid anhydrides such as benzoic anhydride. Or benzoic anhydride is preferable. The content of the dehydrating agent relative to the polyamic acid is preferably in the range where the content of dehydrating agent (mol) / polyamic acid content (mol) is 0.1-4.

  A preferable method for obtaining the polyamic acid solution includes, for example, a method in which the above-described aromatic tetracarboxylic acid and aromatic diamine are polymerized in an appropriate organic solvent according to a conventional method. The polymerization reaction is continuously carried out in a temperature range of 0 to 80 ° C. for 10 minutes to 30 hours with stirring and / or mixing in an organic solvent. The polymerization reaction can be divided or the temperature can be increased or decreased as necessary. It does not matter if you let them.

  In the above polymerization reaction, the aromatic tetracarboxylic acids and the aromatic diamines are preferably polymerized at a ratio in which the respective substance amounts (number of moles) are approximately equal, but one of them is preferable with respect to the other. May be larger than the other within the range of 10 mol%, more preferably within 5 mol%.

  Although there is no restriction | limiting in particular in the addition order of aromatic tetracarboxylic acid and aromatic diamine in a polymerization reaction, It is preferable to add aromatic tetracarboxylic acid in the solution of aromatic diamine.

  Vacuum degassing during the polymerization reaction is an effective method for obtaining a good quality polyamic acid solution. Moreover, you may perform polymerization by adding a small amount of terminal blockers to aromatic diamines before a polymerization reaction.

  The polyamic acid solution is prepared as described above, and this is formed into a gel film. However, the film forming method is not particularly limited, and a known film forming method may be employed. . Moreover, you may form into a multilayer form if desired.

  As a preferable film forming method, there is a method in which a polyamic acid solution is continuously extruded or applied in a film form on a rotating or traveling support and then peeled off from the support. A metal rotating drum or endless belt is preferably used as the support, and its temperature can be controlled by a liquid or gaseous heat medium and / or by radiant heat from an electric heater or the like.

  In the above preferred film forming method, when the polyamic acid solution does not contain the above-mentioned ring-closing catalyst and dehydrating agent, the polyamic acid solution is cast on a support from a base with a slit, for example, and is heated and dried on the support. Thus, the gel film can be peeled from the support after the gel film has self-supporting property.

  On the other hand, when the polyamic acid solution contains the above ring-closing catalyst and a dehydrating agent, the polyamic acid solution is cast on a support from a base with a slit, for example, and imidation by chemical ring closure is partially performed on the support. It is preferable to peel the gel film from the support after the gel film has self-supporting property by proceeding. This method is advantageous in that a gel film having a self-supporting property can be obtained in a short time although it requires equipment for containing a ring-closing catalyst and a dehydrating agent in the polyamic acid solution, and is particularly preferably employed in the present invention. . In this method, the gel film is preferably heated to 30 to 200 ° C., preferably 40 to 150 ° C. by receiving heat from the support and / or receiving heat from a heat source such as hot air or an electric heater, and further undergoes a ring-closing reaction. By drying the volatile components such as the organic solvent, it becomes self-supporting and is peeled off from the support.

  In order to perform chemical ring closure, a method in which an organic solvent solution of polyamic acid is cast on a support and then contacted with a ring closure catalyst and a dehydrating agent can be employed. From the viewpoint of uniformity, a method of previously containing a ring-closing catalyst and a dehydrating agent in the polyamic acid solution is preferable.

  The polyamic acid solution may contain a ring-closing catalyst and a dehydrating agent by adding the ring-closing catalyst and the dehydrating agent to the polyamic acid solution and mixing with a rotary mixer, or while feeding the polyamic acid solution to a static mixer. A method of injecting a ring-closing catalyst and a dehydrating agent just before the static mixer can be mentioned. At this time, the viscosity of a polyamic acid solution containing a ring-closing catalyst and a dehydrating agent (hereinafter sometimes abbreviated as “mixed solution”) is 10 to 1000 Pa · S (measured at 20 ° C. using a Brookfield viscometer). It is preferable to adjust the solid content concentration so that. Further, in the mixed solution, if the viscosity of the polyamic acid is significantly increased due to a thermal ring-closing reaction, it may not be ejected from the die, so it is kept at a low temperature (for example, −20 ° C. to + 5 ° C.) until just before film formation. It is preferable to keep it.

(2) Step of stretching gel film In this step, the gel film obtained by the step (1) is stretched using a transport roll. In that case, the running speed of the gel film is regulated by the roll. However, it is preferable to extend in the running direction. As temperature at the time of extending | stretching, 140 degrees C or less is preferable. Moreover, as a draw ratio, 1.05-1.9 times are preferable, 1.1-1.6 times are more preferable, 1.1-1.5 times are especially preferable.

  What is important in the production method of the present invention is to use a roll described below as a transport roll used in this step.

  The conveyance roll used for this invention is a roll which has the roll surface which consists of a fluororesin layer. The center line average roughness of the roll surface made of this fluororesin layer is in the range of 0.03 to 0.55 μm, preferably 0.05 to 0.50 μm. When the center line average roughness exceeds 0.55 μm, the unreacted polymer or low polymer that oozes out from the inside of the gel film is likely to adhere, and the roll surface becomes dirty. It adversely affects the surface properties of the polyimide film. On the other hand, if the center line average roughness is less than 0.03 μm, the film becomes slippery on the roll surface at the time of stretching, which causes a scratch on the polyimide film surface.

  The maximum roughness of the roll surface is 4.0 μm or less. When the maximum roughness exceeds 4.0 μm, the roll surface is easily damaged.

  The centerline average roughness and maximum roughness of the roll surface described above are values measured based on JIS B-0601.

  The water contact angle on the roll surface is 80 degrees or more. When the water contact angle is 80 degrees or more, there is little soiling of the roll due to the above-mentioned unreacted polymerization products and low polymerization products, and as a result, the surface characteristics of the manufactured polyimide film are excellent. The water contact angle is measured by dropping 20 ° C. pure water with a dropper at 15 points on the roll surface, and an average value of 15 points is adopted.

  In realizing the roll surface as described above, the fluororesin constituting the fluororesin layer may be tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer (PFA) or tetrafluoroethylene / hexafluoropropylene copolymer (FEP). ) Is preferably employed. Since these preferable fluororesins are excellent in hardness among fluororesins, a smooth roll surface can be obtained by polishing, and a surface that is not easily damaged when used can be obtained.

  Moreover, as thickness of the fluororesin layer in the roll surface, it is preferable that it is 0.01 mm or more, and 0.1-10 mm is more preferable. If the thickness of the fluororesin layer is less than 0.01 mm, the durability tends to be insufficient, such as being easily torn and the effect of preventing the adhesion of dirt from being easily reduced. On the other hand, if the thickness is too large, the processing accuracy of the roll surface tends to decrease.

  The roll having the roll surface described above can be obtained, for example, by coating the surface of a roll made of metal, rubber or the like with a fluororesin and polishing the surface of the fluororesin layer so as to have a desired surface. A method of performing such polishing is not particularly limited, and examples thereof include a method of polishing using sandpaper or a wrapping film having a count of # 2000 or more. Of course, it is preferable that no scratches or pinholes are generated on the polished surface.

  In addition, in the manufacturing method of this invention, it has the roll surface which consists of a fluororesin layer, the centerline average roughness of this surface is 0.03-0.55 micrometer, the maximum roughness is 4.0 micrometer or less, and a water contact angle is It is also preferable to use the roll which is 80 degree | times or more as various rolls for supporting a gel film in the middle from not only a conveyance roll but a film forming process to a drying process.

(3) Step of heat treatment In this step, the gel film stretched in the step (2) is subjected to heat treatment. The purpose of this heat treatment is to dry, i.e. volatilize the organic solvent, and imidize the polyamide in the gel film. Therefore, the heat treatment conditions may be appropriately selected within the range in which the object is achieved. Below, although the preferable method of performing this process is demonstrated, it is not limited to this.

  The stretched gel film is introduced into the tenter device before or simultaneously with the heat treatment, and the tenter clip is held at both ends in the width direction and stretched in the width direction while running with the tenter clip. It is preferable.

  Next, the gel film is dried in the drying zone, but before being heated by hot air or the like in the drying zone, a nozzle that can exhaust the leaked air and the heated air is installed, and after the film is dried in the drying zone Means for preventing mixing of air containing solvent and leaked air is also preferably performed. The hot air temperature in the drying zone is preferably in the range of 200 to 300 ° C. Moreover, you may use not only a hot air but radiation heating.

  It is preferable that the film dried in the drying zone is further heat-treated with hot air, an infrared heater or the like for 15 seconds to 10 minutes. Next, it is more preferable to perform heat treatment with hot air and / or an electric heater at a temperature of 250 to 500 ° C. for 15 seconds to 20 minutes. In this case, since the planarity is lost when the film is heated rapidly, it is preferable to select a heating method as appropriate.

  The polyimide film obtained by the heat treatment as described above is cooled and wound on the winding core. And the wound-up polyimide film is slit as needed, and is provided for various uses.

EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, it cannot be overemphasized that this invention is not limited to a following example.
The roll surface characteristics and film surface characteristics described in the examples are both measured by the methods described above. Among them, the water contact angle was measured using Kyowa Interface Chemical Co., Ltd. fully automatic contact angle meter CA-150 type.

[Example 1]
In a polymerization apparatus equipped with a stirrer, 1900.6 kg of dried N, N-dimethylacetamide was added, and further 200.024 kg (1 kmol) of 4,4′-diaminodiphenyl ether was added and dissolved by stirring. Next, a total of 218.12 kg (1 kmol) of pyromellitic dianhydride was added little by little. After completion of the addition, stirring was continued for 1 hour to obtain a transparent polyamic acid solution. This solution had a viscosity of 350 Pa · S at 20 ° C.
To this polyamic acid solution, 2.5 mol of acetic anhydride and 2.0 mol of pyridine with respect to the polyamic acid unit were added to and mixed with the polyamic acid solution. The gel film was extruded from a 1800 mm T-die and cast on a metal endless belt at 90 ° C. to obtain a self-supporting gel film.

The gel film was peeled off from the metal endless bell, and stretched in the running direction with two pairs of rolls having a fluororesin layer on the surface at a temperature of 65 ° C.
Subsequently, the gel film was dried at a temperature of 260 ° C. for 40 seconds, further heat-treated at 430 ° C. for 1 minute, cooled for 30 seconds while relaxing in the cooling zone, the film was edge-cut, and the surface of the film was commercially available By cleaning with a cleaner, 500 m of a polyimide film having a width of 2000 mm and a thickness of 25 μm was obtained.

  The roll having a fluororesin layer on the surface used in this example is obtained by coating a metal roll surface made of SUS304 with a PFA layer having a thickness of 0.5 mm. Ra) was 0.51 μm, the maximum roughness (Rmax) was 3.40 μm, and the water contact angle was 109 degrees.

[Comparative Example 1]
When the gel film was stretched in the running direction, the same operation as in Example 1 was used except that instead of the roll having the fluororesin layer on the surface, a metal roll made of SUS304 having a surface plated with chrome was used. As a result, a polyimide film having a width of 2000 mm and a thickness of 25 μm was obtained with a length of 500 m.

[Comparative Example 2]
The same operation as in Example 1 except that the roll surface characteristics of the roll having a fluororesin layer on the surface used when stretching the gel film in the running direction were Ra = 0.02 μm and Rmax = 2.0 μm. As a result, a polyimide film having a width of 2000 mm and a thickness of 25 μm was obtained with a length of 500 m.

[Comparative Example 3]
The same operation as in Example 1 except that the roll surface characteristics of the roll having a fluororesin layer on the surface used when the gel film was stretched in the running direction were Ra = 0.6 μm and Rmax = 6.0 μm. As a result, a polyimide film having a width of 2000 mm and a thickness of 25 μm was obtained with a length of 500 m.

Table 1 below shows the results of evaluating the surface characteristics of the polyimide films obtained in the above Examples and Comparative Examples. The number of defects in the table is the total number of defects having a roughness of 0.1 μm or more and an area of 0.2 mm ² or more over the entire 500 m long film, and the number of scratches is obtained. Furthermore, the total number of scratches having a roughness of 0.1 μm or more and a width of 1 μm or more over the entire 500 m long film.

Claims (2)

A gel film comprising polyamic acid is stretched using a transport roll and then heat treated , and the transport roll is made of tetrafluoroethylene / perfluoroalkyl vinyl ether copolymer (PFA) or tetrafluoroethylene / hexa It has a roll surface composed of a fluororesin layer containing a fluoropropylene copolymer (FEP), the center line average roughness of the surface is 0.03 to 0.55 μm , and the maximum roughness is 4.0 μm or less. , and the water contact angle Ri der than 80 degrees, the resulting film is present on the film surface, or roughness 0.1μm and the number of area 0.2 mm ² or more drawbacks 1000 m ² per 30 or less The number of scratches having a roughness of 0.1 μm or more and a width of 1 μm or more is 1 or less per 100 m ^2. Manufacturing method. The method for producing a polyimide film according to claim 1 , wherein the thickness of the fluororesin layer is 0.01 mm or more and 10 mm or less .