JP5041480B2 - MnZn ferrite - Google Patents

Description

  The present invention relates to a MnZn ferrite suitable as a ferrite core for a line filter.

  In recent years, development of plasma televisions and the like has become active, and noise countermeasures associated therewith have become important. In particular, noise countermeasures in the vicinity of 150 kHz are important, and a material having a high initial permeability up to a frequency band of about 500 kHz is required.

In MnZn ferrite has been used in anti-noise component than conventional, the permeability is increased by Kusuru small magnetocrystalline anisotropy. Further, the magnetic permeability is increased by increasing the average crystal grain size.
In order to reduce the magnetocrystalline anisotropy, it is generally known that the ZnO content of the main component composition of MnZn ferrite is the Rich composition. Specifically _52.0mol% ~52.5mol% Fe ₂ O 3 is, 24.0~28.0mol% MnO, the composition in the vicinity of the balance ZnO are produced as high-permeability material. In order to increase the crystal grain size, a technique of adding an appropriate amount of various grain growth additives for the purpose of promoting grain growth is used. In addition, a technique for promoting grain growth by increasing the sintering holding temperature is also used. Patent Document 1 proposes that Bi ₂ O ₃ is added to increase the crystal grain size.

  However, the grain growth additive is also an abnormal grain growth promoting factor, and abnormal grains are easily generated. Abnormal grains increase eddy current loss and lead to a decrease in specific resistance. As a result, the initial permeability in the high frequency region is lowered. In order to increase the crystal grain size, the sintering temperature is increased. However, if the sintering temperature is increased too much, ZnO volatilizes from the surface of the sintered body, resulting in distortion due to the resulting composition gradient. This leads to a decrease in magnetic permeability. In order to show high permeability over a wide band from low frequency to high frequency, it is necessary to increase the specific resistance of the material. Additives that precipitate at the grain boundaries are added to increase the specific resistance of the grain boundaries. Methods are also being considered. As described above, it is extremely difficult to obtain a high magnetic permeability and a high magnetic permeability over a wide frequency band.

JP-A-47-8176

Ferrite sintered bodies have a larger magnetic permeability than metal green compacts, and are therefore often used for transformers and inductors on power supply circuits. In particular, Mn Zn ferrite has a larger magnetic permeability than NiZn ferrite, and is therefore used as a transformer or a line filter in a low frequency range. Accordingly, the development of Mn Zn ferrite materials has been mainly focused on increasing the magnetic permeability and loss in transformer applications and increasing the magnetic permeability mainly in line filter applications.

  However, with the recent spread of thin televisions and plasma televisions, broadband noise attenuation characteristics are also required for line filter applications. For this reason, a material having high permeability in a wide frequency band is required, but generally, a material having high permeability at a low frequency has a problem that it is difficult to maintain high permeability up to a high frequency. there were. Therefore, an object of the present invention is to provide a MnZn ferrite exhibiting high magnetic permeability in a wide frequency band.

The present invention has been made in order to solve the above-described problems. As main components, Fe ₂ O ₃ is 52.0 mol% or more and 53.0 mol% or less, ZnO is 19.0 mol% or more and 23.5 mol% or less, MnO the 23.5Mol% or more 29.0Mol% or less, 0.005 wt% SiO ₂ as subcomponent less, 0.05 wt% or more 0.2 wt% or less CaO, the MoO ₃ 0.1 wt% or more 0.5 wt% Hereinafter, Bi ₂ O ₃ is 0.005 wt% or more and 0.1 wt% or less, B ₂ O ₃ is 0.005 wt% or more and 0.1 wt% or less, and P ₂ O ₅ is 0.005 wt% or more and 0.1 wt% or less. containing to Ri Na, average crystal grain size 30μm or more of the sintered body, 100 [mu] m or less, the specific resistance is more than 20 .OMEGA.cm, a MnZn ferrite which is characterized in der Rukoto below 100 .OMEGA.cm.

Further, the present invention is pre-Symbol sintered body having a specific resistance not less than 20 .OMEGA.cm, a MnZn ferrite which is characterized in that not more than 100 .OMEGA.cm.

According to the present invention, since the amount of CaO added to MnZn ferrite is 0.05 wt% or more and 0.2 wt% or less, a high resistivity grain boundary layer can be formed without hindering crystal grain growth. Eddy current loss can be reduced. Further, by setting the amount of MoO ₃ added to MnZn ferrite to 0.05 wt% or more and 0.5 wt% or less, the crystal grain size can be increased at a sintering temperature at which ZnO does not volatilize from the surface of the sintered body. By doing so, a high permeability ferrite can be obtained.

The SiO ₂ amount added to the MnZn ferrite is 0.005 wt% or less. If the SiO ₂ content exceeds 0.005 wt%, the crystal grain growth is inhibited and the magnetic permeability is remarkably lowered. Because.

  The reason why the amount of CaO added to MnZn ferrite is 0.05 wt% or more and 0.2 wt% or less is that if it is less than 0.05 wt, the grain boundary layer is not sufficiently formed, so that the specific resistance becomes low, and the vortex This is because a high magnetic permeability cannot be obtained over a wide frequency band due to an increase in current loss, and when it exceeds 0.2 wt%, excessive CaO inhibits crystal grain growth and a sufficient magnetic permeability cannot be obtained.

Also, less 0.5 wt% or more 0.05 wt% of MoO ₃ amount to be added to MnZn ferrite, the Bi ₂ O ₃ amount was not less than 0.005 wt% 0.1 wt% or less MoO ₃ added to MnZn ferrite If it is less than 0.05 wt% and Bi ₂ O ₃ is less than 0.005 wt%, the crystal growth is insufficient and the magnetic permeability is lowered, MoO ₃ exceeds 0.5 wt%, and Bi ₂ O ₃ is 0.00. This is because, if it exceeds 1 wt%, the excessive addition causes abnormal grain growth and a high magnetic permeability cannot be obtained over a wide frequency band.

The amount of B ₂ O ₃ added to MnZn ferrite is 0.005 wt% or more and 0.1 wt% or less, and P ₂ O ₅ is 0.005 wt% or more and 0.1 wt% or less because B ₂ O ₃ is 0 If it is less than 0.005 wt% and P ₂ O ₅ is less than 0.005 wt%, the crystal grain size of the sintered body is insufficient and the magnetic permeability is low, and B ₂ O ₃ is 0.1 wt%. This is because, if P ₂ O ₅ exceeds 0.1 wt%, the excessive addition causes abnormal grain growth and a high magnetic permeability cannot be obtained over a wide frequency band.

Further, the average crystal grain size of the sintered body in high permeability MnZn ferrite obtained was 30 mu m or more, had a 100μm or less, sufficient for the average crystal grain size of a small grain size is less than 30μm This is because the magnetic permeability cannot be obtained. When the thickness exceeds 100 μm, the grain boundary phase is not sufficiently formed, so that the specific resistance is lowered, and the increase in eddy current loss makes it impossible to obtain a high magnetic permeability over a wide frequency band. .

  The specific resistance is set to 20 Ωcm or more and 100 Ωcm or less because if the specific resistance is less than 20 Ωcm, a high initial permeability cannot be obtained over a wide frequency band due to an increase in eddy current loss. This is because if it exceeds, the crystal grain size is small, and sufficient magnetic permeability cannot be obtained.

According to the present invention, Fe ₂ O ₃ , ZnO, and MnO are the main components, and as additives, SiO ₂ is 0 to 0.005 wt%, CaO is 0.05 wt% to 0.2 wt%, and MoO ₃ is 0.05 wt%. % ~0.5wt%, Bi ₂ O ₃ is _{0.005wt% ~0.1wt%, B 2 O} 3 is 0.005~0.1wt%, P ₂ O ₅ is 0.005wt% ~0.1wt% In the MnZn ferrite containing, the sintered body surface of the obtained sintered body has a precipitated phase containing MoO ₃ and CaO, the average crystal grain size is 30 μm or more and 100 μm or less, and the sintered body specific resistance is 20 Ωcm or more. MnZn ferrite having a high magnetic permeability in a wide frequency band of 100 Ωcm or less, having a permeability of 12000 or more at 1 kHz and a permeability of 12,500 or more at 150 kHz is obtained.

Furthermore, according to the present invention, by setting CaO to 0.05 wt% to 0.2 wt%, a high resistance grain boundary layer can be formed without hindering crystal grain growth, thereby reducing eddy current loss. I can plan. Also, MoO ₃ is 0.05 wt% to 0.5 wt%, Bi ₂ O ₃ is 0.005 wt% to 0.1 wt%, B ₂ O ₃ is 0.005 wt% to 0.1 wt%, and P ₂ O ₅ is added. By setting the content to 0.005 wt% to 0.1 wt%, the crystal grain size can be increased at a sintering temperature at which ZnO does not volatilize from the surface of the sintered body, and as a result, a high permeability ferrite is obtained. .

  Hereinafter, specific examples will be given to describe embodiments of the present invention.

  In the production of MnZn ferrite, the main components and additives are weighed in advance so as to have a predetermined ratio, and these are mixed for 2 hours using an attritor to obtain a mixed powder. And pre-baked at a predetermined temperature for 2 hours. The pre-baking temperature is appropriately selected within the temperature range of 850 to 950 ° C. depending on the composition range. The pre-fired powder is pulverized with an attritor or a ball mill, and then a MnZn ferrite sintered body is obtained through a normal ferrite production process including granulation, molding with a spray dryer, and further sintering.

The obtained MnZn ferrite sintered body has a precipitated phase containing MoO ₃ and CaO on the surface of the sintered body, the average crystal grain size is 30 μm or more and 100 μm or less, and the sintered body specific resistance is 20 Ωcm or more and 100 Ωcm or less. Yes, it has high permeability in a wide frequency band where the permeability at 1 kHz is 12000 or more and the permeability at 150 kHz is 12,500 or more.

The main component is 52.5 mol% Fe ₂ O ₃ , 22.5 mol% ZnO and the balance MnO, and the additive is added to the main component 100 as SiO ₂ , CaO, MoO ₃ , Bi ₂ O ₃ , P ₂ O _5. Each powder raw material was weighed at various ratios shown in Table 1 for B ₂ O ₃ , and these powders were mixed for 2 hours using an attritor. Next, it was granulated with a spray dryer and pre-baked in the air at 850 ° C. for 2 hours. The obtained pre-baked powder was pulverized with an attritor. After pulverization, polyvinyl alcohol as a binder is added and granulated with a spray dryer to form a toroidal core having an outer diameter of 25 mm, an inner diameter of 15 mm, and a height of 12 mm. The molded body is then placed in a firing furnace at 1320 ° C. It sintered and obtained the MnZn ferrite sintered compact sample of this invention. Magnetic characteristics were measured by applying a 10-turn winding to the sample. The specific resistance was measured by applying a Ga-In paste on the upper and lower surfaces of the sample. The results are shown in Table 1 and FIG.

Further, as comparative products, the main component is 52.5 mol% Fe ₂ O ₃ , 22.5 mol% ZnO and the balance MnO, and the additive SiO ₂ , CaO, MoO ₃ , Bi ₂ O _{3 with} respect to the main component 100. It was prepared in _{P 2 O 5, B 2 O} 3 the same procedure as inventions the MnZn ferrite added with added amounts shown in Table 1. Magnetic permeability measurement, specific resistance measurement and average crystal grain size measurement were also performed in the same manner as the invention. In Table 1, those with an addition amount within the range of the present invention were regarded as inventions, and those outside the range were regarded as comparative products.

Further, as conventional products, the main components are 52.5 mol% Fe ₂ O ₃ , 22.5 mol% ZnO, and the remaining MnO, and the addition amounts of SiO ₂ and CaO shown in Table 1 with respect to the main components 100 are as shown in Table 1. The added MnZn ferrite was produced in the same procedure as the product of the invention. Magnetic permeability measurement, specific resistance measurement and average crystal grain size measurement were also performed in the same manner as the invention.

  Table 1 shows the average crystal grain size, specific resistance, magnetic permeability μ at 1 kHz, and magnetic permeability μ at 100 kHz for the inventive products (1 to 21), comparative products (1 to 11) and conventional products. Samples of all inventive products (Inventive products 1 to 21) have an average crystal grain size of 30 μm or more and 100 μm or less, a sintered body specific resistance of 20 Ωcm or more and 100 Ωcm or less, and a magnetic permeability at 1 kHz of 12000 or more and 150 kHz. It can be seen that the magnetic permeability is 12,500 or more.

  FIG. 1 shows the frequency characteristics of the initial permeability of Invention 6 and the conventional product. The inventive product is useful as a material for noise countermeasure parts for line filters because it has a higher magnetic permeability than the conventional product in the entire frequency range in which the measurement was performed and a high initial permeability over a wide band.

The graph which shows the frequency characteristic of the magnetic permeability ((micro | micron | mu) ': real part complex magnetic permeability, (micro | micron | mu): imaginary part complex magnetic permeability) of the invention product 6 and a conventional product.

Claims (2)

_Fe 2 _{O 3} the 52.0Mol% or more 53.0Mol% or less as a main component, ZnO and 19.0 mol% or more 23.5Mol% or less, less 29.0Mol% or more 23.5Mol% of MnO, SiO ₂ as subcomponent Is 0.005 wt% or less, CaO is 0.05 wt% or more and 0.2 wt% or less, MoO ₃ is 0.1 wt% or more and 0.5 wt% or less, and Bi ₂ O ₃ is 0.005 wt% or more and 0.1 wt% or less. , _B 2 _{O 3} and 0.005 wt% or more 0.1 wt% or _less, P 2 _{O 5} Ri greens contain more than 0.005 wt% 0.1 wt% or less, the average crystal grain size of the sintered body is more than 30μm , MnZn ferrite, characterized in der Rukoto below 100 [mu] m. Before SL sintered body having a specific resistance not less than 20 .OMEGA.cm, MnZn ferrite according to claim 1, characterized in that not more than 100 .OMEGA.cm.

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