JP5019265B2 - Skin mounting sheet - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a sheet to be attached to the skin, providing good attaching feeling and attaching stability on the skin, and capable of efficiently enhancing benefit and effect. <P>SOLUTION: The sheet to be attached on the skin is a wet sheet obtained by impregnating a laminate sheet comprising a hydrophilic fiber layer and an ultrafine fiber layer with 100-1,500 pts.mass medical fluid or cosmetics based on 100 pts.mass laminate sheet. The modulus strength at 10% elongation at least in one direction of the wet sheet is within the range of 0.1-4.0 N/25 mm, and the elastic recovery from 30% elongation in the same direction is within the range of 30-100%. <P>COPYRIGHT: (C)2010,JPO&amp;INPIT

Description

  The present invention relates to a skin mounting sheet, and more particularly to a skin mounting sheet that can be used for, for example, a beauty sheet, a skin pack sheet, a face mask, a bandage, a poultice material, a plaster material, and the like.

  Conventionally, many fibers such as cellulosic fibers have been known as hydrophilic fibers. And since they are hydrophilic, they have been used in absorbent articles, cleaning articles, cosmetic sheets and the like. Especially in applications that are used in contact with human skin, touch and fit are important performance requirements, but cellulose-based non-woven fabrics that have been used in the past are somewhat rough and soft. Lack of feeling and fit.

  As an example of a sheet to be attached to the skin, an ultrafine fiber layer obtained by dividing a split type composite fiber substantially made of a non-elastomer is integrated into a hydrophilic fiber layer by hydroentanglement, and the ultrafine fiber layer is integrated with the skin. There has been proposed a face mask that has less irritation to the skin and improved wearability to the skin (for example, see Patent Document 1).

International Publication No. 2006/016601 Pamphlet

  An object of the present invention is to provide a skin-mounting sheet that is a skin-mounting sheet and that has a good feeling on the skin and good mounting stability. Furthermore, it aims at providing the sheet | seat for skin mounting which can raise efficiently the effect and effect which are brought to skin by the chemical | medical solution and cosmetics which are the liquid components impregnated in the sheet | seat.

  As a result of intensive studies to solve the above problems, the present inventors have obtained a sheet containing a hydrophilic fiber layer and an ultrafine fiber layer and containing a chemical solution or a cosmetic, with a specific modulus strength and a specific elongation. It has been found that a device having a recovery rate can solve the above problems, and has completed the present invention.

The present invention has the following configuration.
(1) A wet sheet in which a laminated sheet including a hydrophilic fiber layer and an ultrafine fiber layer is impregnated with 100 to 1500 parts by mass of a chemical solution or cosmetic with respect to 100 parts by mass of the laminated sheet, the wet sheet 10% elongation modulus strength in at least one direction is in the range of 0.1 to 4.0 N / 25 mm, and the elongation recovery rate at 30% elongation in the same direction is in the range of 30 to 100%. , Skin mounting sheet.
(2) The skin attachment according to (1), wherein the ultrafine fiber layer includes at least one kind of elastomer fiber selected from styrene-based elastomer fiber, olefin-based elastomer fiber, ester-based elastomer fiber, and urethane-based elastomer fiber. Sheet.
(3) The skin mounting sheet according to (1), wherein the ultrafine fiber layer includes at least two types of elastomer fibers selected from styrene elastomer fibers, olefin elastomer fibers, and urethane elastomer fibers.

The skin mounting sheet of the present invention provides an excellent mounting feeling and mounting stability on the skin.
Moreover, according to the structure of the sheet | seat for skin mounting | wearing of this invention, a hydrophilic fiber layer and an ultra-fine fiber layer are laminated | stacked sheet | seats, such as delamination resistance, etc. by being partially thermocompression bonded and integrated, for example Thus, the strength required for the skin can be sufficiently secured, and in particular, it is possible to exhibit excellent stretchability as a skin mounting sheet in which the laminated sheet is impregnated with a chemical solution or a cosmetic. Further, it is possible to efficiently enhance the effects and effects that the liquid component brings to the object such as the skin.
The skin mounting sheet of the present invention can be suitably used as, for example, a beauty sheet, a skin pack sheet, a face mask, a bandage, a poultice material, a plaster material, and the like.

Hereinafter, the present invention will be described in detail according to embodiments of the invention.
The skin mounting sheet of the present invention is a laminated sheet including a hydrophilic fiber layer and an ultrafine fiber layer.
As the hydrophilic fiber layer used in the present invention, a hydrophilic short fiber layer or a hydrophilic long fiber layer having extensibility in at least one direction is preferably used. The fiber layer that is preferably used includes a card web in which short fibers are arranged in one direction, an air-lay web or wet papermaking web in which short fibers are randomly accumulated, and needle punches or spunlaces of these fibers. Nonwoven fabrics obtained by three-dimensional entanglement by (water flow entanglement) or the like can be mentioned. A wet papermaking web or a spunlace nonwoven fabric is preferable from the viewpoint of the mounting feeling and mounting stability of the skin mounting sheet. In particular, the spunlace nonwoven fabric obtained by performing hydroentanglement treatment on a card web in which short fibers are arranged in one direction and three-dimensionally interlacing the fibers is particularly laminated with an ultrafine fiber layer containing elastomer fibers. Stretch suitable for the skin mounting sheet obtained by impregnating chemicals and cosmetics, ensuring excellent mounting feeling and mounting stability on the skin.

Although the length of the fiber which comprises a hydrophilic short fiber layer is not specifically limited, It is preferable that it is 2-100 mm. As a fiber constituting the hydrophilic short fiber layer, a specific technique for preparing the fiber layer, for example, a short length usually used depending on the embodiment of the card web, air lay web, wet papermaking web, etc. Fiber can be used.
In the present invention, when the hydrophilic fiber layer is composed of long fibers or continuous fibers, the degree of freedom of individual fibers is likely to be hindered due to mutual interference or entanglement between the fibers, and in the integrated ultrafine fiber layer In particular, when elastomer fibers are included, it may be difficult to exhibit extensibility that can follow the stretchability. When the hydrophilic fiber layer is composed of short fibers, interference between the fibers is reduced and the degree of freedom of each fiber is likely to increase. As a result, it becomes easy for the hydrophilic fiber layer to exhibit followability (extensibility) to the extent that the stretchability of the ultrafine fiber layer can be sufficiently reflected in the laminated sheet.

The fibers that make up the hydrophilic fiber layer include cellulose fibers such as cotton and hemp, semi-synthetic fibers obtained using wool, silk, rayon, cupra, pulp, cellulose, etc., and synthetic fibers subjected to hydrophilic treatment. These may be used, and two or more of these may be used. From the viewpoint of hydrophilicity, cotton, rayon, cupra and pulp are preferred. In the hydrophilic fiber layer, these hydrophilic fibers are contained in a range of 30% or more on a mass basis in order to maintain a sufficient amount of chemicals or cosmetics or to ensure an appropriate penetration rate thereof. It is preferable. The hydrophilic fiber layer contains, in particular, cotton, rayon, cupra, pulp, or a mixture of two or more of these in a range of 30% or more based on the mass of the hydrophilic fiber layer. Is preferred.
For the purpose of increasing the retention ability and penetration rate of the chemical solution or cosmetic to the laminated sheet, it is preferable that the hydrophilic fiber layer is composed of only these hydrophilic fibers, particularly these hydrophilic short fibers. For the purpose of efficiently adjusting the retention ability of the chemical solution or cosmetic in the laminated sheet and the penetration rate into the laminated sheet as appropriate, the hydrophilic fiber is added to the hydrophilic fiber layer in a range not exceeding 70% based on its mass. Other fibers may be mixed. Examples of the fibers to be mixed include water-repellent synthetic fibers such as fibers obtained using polyester, polyolefin, polyamide, or composite fibers obtained by combining two or more of these. .

  The cross-sectional shape of the fiber contained in the hydrophilic fiber layer is not particularly limited, and examples thereof include a round cross section, a flat cross section, an atypical cross section, and a hollow cross section. When the cross-sectional shape of the fiber contained in the hydrophilic fiber layer is a round cross section, the fiber diameter is preferably in the range of 15 μm to 50 μm.

The basis weight of the hydrophilic fiber layer is preferably 5 to 95 g / m ² from the viewpoint of the strength of the skin mounting sheet, the amount of liquid component impregnation (retention amount), and the stretchability during liquid component impregnation, More preferred is a range of 10 to 70 g / m ² . The thickness of the hydrophilic fiber layer is preferably 20% or more on the basis of the thickness of the laminated sheet before impregnating the chemical solution or cosmetic, and the laminated sheet has a sufficient amount of liquid impregnation and sufficient liquid impregnation. In order to ensure stretchability, it is more preferably 30 to 95%.
Further, the elongation in the dry state of the hydrophilic fiber layer is preferably 20 to 250%, and more preferably in the range of 20 to 200%, in order to ensure suitable stretchability of the skin mounting sheet. is there.

As the ultrafine fiber layer in the skin mounting sheet of the present invention, one having elasticity in at least one direction is preferable. By adopting woven fabric or knitted fabric in this fiber layer and devising the weaving or knitting method, it is possible to develop stretchability.
The ultrafine fiber layer used in the present invention preferably contains elastomer fibers. In particular, an elastomer fiber having a fiber diameter of 15 μm or less is preferable, and an elastomer long fiber having a fiber diameter of 10 μm or less is more preferable. When the fiber diameter of the elastomer long fiber is 10 μm or less, the skin mounting sheet including the ultrafine fiber layer becomes more flexible, and the feeling of mounting on the skin or the like is further improved.

The elastomer fiber is preferably at least one elastomer fiber selected from styrene-based elastomer fibers, olefin-based elastomer fibers, ester-based elastomer fibers, and urethane-based elastomer fibers. In particular, it was selected from styrene-based elastomer fibers, olefin-based elastomer fibers, and urethane-based elastomer fibers in terms of the mounting comfort associated with the flexibility and stretchability of the skin-mounting sheet and the stretchability. Preferably at least two types of elastomer fibers.
As a mixture of two or more kinds of elastomer fibers, for example, a mixture of 1 to 99% by mass of styrene elastomer fiber and 99 to 1% by mass of olefin elastomer fiber, 1 to 99% by mass of urethane elastomer fiber and And a mixture with 99 to 1% by mass of an olefin-based elastomer fiber. Depending on the type and amount ratio of these elastomer fibers to be mixed, the feeling of wearing accompanying the flexibility and stretchability of the skin wearing sheet and the wearing stability accompanying the stretchability are adjusted to a desired range at a relatively high level. It becomes possible to do.

  In particular, as the fibers constituting the ultrafine fiber layer, by selecting styrene-based elastomer long fibers and olefin-based elastomer long fibers having a fiber diameter of 15 μm or less, preferably 10 μm or less, and mixing them, It is possible to adjust and control the wearing stability accompanying the flexibility and stretchability of the skin wearing sheet and the wearing stability accompanying the stretchability at a high level. Preferably, a styrene elastomer long fiber and an olefin elastomer long fiber are uniformly and randomly mixed. More specifically, an ultrafine fiber layer in which the mixing ratio is appropriately set as desired in the range of 30 to 70% by mass of the styrene elastomer long fiber and in the range of 70 to 30% by mass of the olefin elastomer long fiber is used. Accordingly, it is possible to adjust and control the wearing stability accompanying the flexibility and stretchability of the skin wearing sheet and the wearing stability accompanying the stretchability at a higher level.

The skin mounting sheet of the present invention exhibits superior performance in terms of flexibility, particularly stretching performance, as compared with the conventional sheet. From such performance, it is suitably used for applications such as a face mask that is impregnated with chemicals and cosmetics and is attached to the skin. The part of the skin on which the face mask or the like is attached is moistened or moistened with a chemical solution or cosmetic. As a result, the skin surface becomes more sensitive and delicate.
Styrenic elastomer fibers are generally excellent in flexibility, but because they are slightly sticky, depending on the liquid component to be impregnated and the part of the skin to be worn, if you feel that the adhesion to the skin is too strong There is. In addition, since the styrene elastomer fiber is sufficiently high in stretchability, it causes a feeling of slipping due to the skin being pulled by following the shrinkage of the sheet after being attached to the skin, and the amount of liquid to be impregnated and the skin to be attached Depending on the part, it may be difficult to obtain a comfortable wearing feeling. By mixing olefinic elastomer fiber therewith at a specific ratio within the above range, it is possible to give a gentle and extremely comfortable wearing feeling to the wearing site of sensitive and delicate skin.

  In the ultrafine fiber used in the present invention, a stabilizer, a flame retardant, an antibacterial agent, a coloring agent, a lubricant, a light-proofing agent, a hydrophilic agent, an antistatic agent, a charging agent and the like are added within a range not impeding the effects of the present invention. May be.

The ultrafine fiber layer in the skin mounting sheet of the present invention may contain fibers other than “elastomer long fibers having a fiber diameter of 15 μm or less”. In order to obtain a comfortable wearing feeling associated with flexibility, stretchability, and wearing stability associated with stretchability as a skin wearing sheet, elastomer long fibers having a fiber diameter of 15 μm or less are based on the mass of the ultrafine fiber layer. , Preferably in a range of 50% or more, more preferably 70% or more. In order to obtain a skin mounting sheet having a high feeling of mounting and mounting stability, it is particularly preferable that the ultrafine fiber layer is composed of only such elastomer long fibers.
Examples of fibers other than “long elastomer fibers having a fiber diameter of 15 μm or less” include elastomer fibers having a fiber diameter of more than 15 μm and 50 μm or less, and non-elastomeric fibers such as polyester, polyolefin, and polyamide. Using non-elastomeric fibers with a fiber diameter of 1 to 15 μm in a ratio of 1 to 50% by mass to “elastomer long fibers with a fiber diameter of 15 μm or less” means mixing different types of elastomer fibers at a specific ratio as described above. Although not as delicate as the case, it is effective in appropriately and efficiently adjusting the feeling of wearing and the wearing stability associated with the flexibility and stretchability of the obtained skin wearing sheet. Examples of the non-elastomeric fiber having a fiber diameter of 1 to 15 μm used in combination include polyester terephthalate, polypropylene, polyethylene, nylon 6, nylon 66, and the like.
Under the condition that the hydrophilicity of the ultrafine fiber layer is not higher than the hydrophilicity of the hydrophilic fiber layer, it is not excluded that at least a part of the fibers constituting the ultrafine fiber layer is a hydrophilic fiber. As hydrophilic fibers that can be used, cellulose fibers such as cotton and hemp, semi-synthetic fibers obtained using wool, silk, rayon, cupra, cellulose, etc., and synthetic fibers were subjected to a hydrophilic treatment. The thing etc. can be illustrated.

The “elastomer long fiber having a fiber diameter of 15 μm or less” preferably contained in the ultrafine fiber layer is not limited in its production method as long as the fiber diameter is 15 μm or less. More specifically, since the stretchability of the elastomer long fiber itself is not uniformly biased in one direction and is uniformly contributed / reflected in the laminated sheet obtained by integrating it, the elastomer long fiber is an ultrafine fiber layer. Among them, it is preferable to accumulate at random. In a fiber layer in which elastomer long fibers are arranged in one direction, the stretchability of the fiber itself is reflected without delay in the same direction as the length direction of the fiber, but in the direction perpendicular to this, the fiber itself The stretchability of is difficult to contribute.
The elastomer long fibers are preferably long fibers produced by the melt blow method, and the ultrafine fiber layer contains elastomer long fibers having a fiber diameter of 15 μm or less produced by the melt blow method and randomly accumulated. preferable. Compared to the general manufacturing method in which a surfactant is attached to the fiber surface in order to prevent problems due to the charging of the fiber that occurs in the manufacturing process of the fiber layer, the melt-blowing method has a surface-active agent adhesion because of its manufacturing method. Do not need. For this reason, by employing the melt blow method, it becomes possible to efficiently produce water-repellent fibers that are suitably used for the ultrafine fiber layer.

The mixing method of “elastomer long fibers having a fiber diameter of 15 μm or less” used for the ultrafine fiber layer and “other fibers” which may be mixed with this is not particularly limited. Each may be manufactured individually and then mixed. Alternatively, it is preferable to employ a so-called fiber mixing nozzle in which spinning holes for discharging different kinds of fibers are alternately arranged in one nozzle, and simultaneously spinning these different kinds of fibers by a melt blow method. According to this method, it is possible to obtain an ultrafine fiber layer in which different kinds of fibers are collected extremely uniformly and randomly.
When the ultrafine fiber layer contains 0 to 10% by mass of non-elastomeric long fiber and 100 to 90% by mass of elastomer long fiber, the elastomer long fiber is composed of only elastomer long fiber, and the elastomer long fiber is composed of two or more types of elastomers. When it is a mixed fiber of long fibers, and particularly when it is a mixed fiber of 30 to 70% by mass of styrene elastomeric long fibers and 70 to 30% by mass of olefinic elastomeric long fibers, two or more of them are used. These fibers are preferably spun by the melt blow method using the above-mentioned fiber mixing nozzle.
In particular, when a high level of delicateness is required, such as an extremely comfortable wearing feeling associated with a high degree of flexibility and stretchability, and an excellent wearing stability feeling associated with an extremely suitable stretchability, It is necessary that two or more kinds of elastomer long fibers are uniformly collected and mixed uniformly in the ultrafine fiber layer.

  The mixing nozzle is not limited to the structure as long as different fibers can be spun at the same time and they can be collected uniformly and randomly. As the fiber mixing nozzle, for example, nozzles in which spinning holes from which different kinds of resins flow out are alternately arranged in a single row or nozzles arranged in a staggered manner can be suitably used. As another aspect, a device in which a plurality of nozzles each having only a spinning hole through which one resin flows is arranged in the moving direction of the stacking conveyor is used to spin different resins from each nozzle. Further, a method of mixing fibers by entanglement treatment of the obtained web laminate with a needle punch or the like can also be exemplified. From the viewpoint that no post-treatment is involved, the former nozzle in which the spinning holes from which different kinds of resins flow out are alternately arranged in a line in one nozzle is preferably used.

The basis weight of the ultrafine fiber layer is preferably 5 to 100 g / m ² in that the elongation recovery rate of the skin mounting sheet is excellent. More preferred is a range of 10 to 70 g / m ² . The thickness of the ultrafine fiber layer is preferably 80% or less, and preferably 5 to 70%, based on the thickness of the laminated sheet before impregnating with the chemical solution or cosmetic. It is preferable in that the wearing feeling can be secured.

Generally, the hydrophilic fiber used for the hydrophilic fiber layer itself has water absorption. For this reason, when trying to impregnate a non-woven sheet consisting only of hydrophilic fibers with a chemical solution or cosmetic, the fiber itself absorbs such a liquid, so that the amount of the chemical solution that greatly exceeds the amount actually replenished to the skin or Cosmetics must be filled in the sheet beforehand. For this reason, the utilization efficiency of the chemical | medical solution or cosmetics to be used was bad, and it was a wasteful thing in cost.
On the other hand, the skin mounting sheet of the present invention is a laminated sheet having a delamination resistance and the like, since the hydrophilic fiber layer and the ultrafine fiber layer are integrated by partial thermocompression bonding, as will be described later. It is possible to sufficiently ensure the required strength. For this reason, it is generally possible to reduce the thickness according to the strength required for the product. As a result, the absolute amount absorbed by the hydrophilic fiber itself in the chemical solution or cosmetic filled in the laminated sheet can be reduced, and the effective amount can be efficiently replenished to the skin or the like.

Moreover, the efficiency of the chemical | medical solution and cosmetics to be used can also be aimed at by mixing fibers other than a hydrophilic fiber in the range which does not exceed 70 mass% in a hydrophilic fiber layer. On the other hand, although the ultrafine fiber layer is laminated, there is a tendency that the amount of the chemical solution or cosmetics to be held on the skin mounting sheet itself and the permeation rate tend to decrease, but these are the hydrophilic properties of the ultrafine fiber layer. It can also be adjusted by mixing the hydrophilic fibers in the ultrafine fiber layer within a range not exceeding 50 mass% under the condition that the property is lower than the hydrophilicity of the hydrophilic fiber layer. As this hydrophilic fiber, those exemplified above can be used.
According to these methods, it is possible to reduce the total amount of hydrophilic fibers contained in the skin mounting sheet while maintaining the retention amount and penetration rate of the chemical solution or cosmetic in a desired range. And can contribute to effective use of cosmetics and cost reduction.

As a means for laminating the hydrophilic fiber layer and the ultrafine fiber layer, in addition to a method using a heating roll, a heating oven method, a needle punch method, a spunlace method (hydroentanglement method), a method using ultrasonic waves, a method using an adhesive, etc. Can be illustrated.
In the skin mounting sheet of the present invention, it is particularly preferable to employ a partial thermocompression bonding method. The partial thermocompression bonding can be suitably performed using a heating roll whose roll surface is engraved in a concavo-convex shape (hereinafter sometimes referred to as a “heating embossing roll”). In the production of the skin mounting sheet of the present invention, when performing partial thermocompression bonding using an embossing roll, the heated embossing roll is bonded to the surface on the hydrophilic fiber layer side exposed on one surface of the laminated sheet. Preferably it is done. At this time, the surface of the other side of the laminated sheet, that is, the surface on the side of the ultrafine fiber layer exposed on the other side of the laminated sheet is a roll having a surface that is engraved in a smooth or uneven shape that may be heated. It is done in contact with. It is preferable that the surface of the hydrophilic fiber layer exposed on one surface of the laminated sheet of the present invention is formed with a discontinuous and regular uneven shape due to this partial thermocompression bonding. On the other hand, the surface of the ultrafine fiber layer exposed on the other surface of the laminated sheet preferably forms a smooth surface due to contact with a smooth roll or the like.

On the surface of the hydrophilic fiber layer exposed on one side of the laminated sheet and / or the surface of the ultrafine fiber layer exposed on the other side, discontinuous and regular formed due to this partial thermocompression bonding The concave / convex shape is preferably 3 to 40% of the area of the concave portion occupying the surface of each fiber layer (hereinafter sometimes referred to as “crimping area”) in terms of interlayer strength and texture at the time of lamination. The range of 5 to 30% is preferable.
Moreover, the depth of the recessed part in the lamination sheet surface is 0.1-1 mm in the point of the interlayer intensity | strength at the time of lamination | stacking, and a texture, The area of each recessed part is 0.15-15mm < ² >, The distance between recessed parts is 0.5- 20 mm is preferred.

In the sheet thickness direction of the portion where the concave portion exists, at least some of the fibers are thermally bonded. When the ultrafine fiber layer contains an elastomer fiber, the elastomer fiber is bonded to the fiber constituting the hydrophilic fiber layer by the softening, whereby the hydrophilic fiber layer and the ultrafine fiber layer are integrated. The pressure and temperature at the time of partial thermocompression bonding can be appropriately selected under the condition that the hydrophilic fiber layer and the ultrafine fiber layer are integrated by at least some of the fibers being softened. The range of 5 to 100 kg / cm ² and the temperature at the time of thermocompression bonding are preferably in the range of 50 to 150 ° C., and the above bonding mode is formed between the ultrafine fiber layer and the hydrophilic fiber layer to obtain interlayer strength. There is no particular limitation as long as it is within the range.

As described above, in the present invention, the hydrophilic fiber layer is preferably a short fiber layer because it can follow the stretchability of the ultrafine fiber layer.
The laminated sheet constituting the skin-worn sheet of the present invention is particularly excellent in stretching in the direction in which the hydrophilic short fiber layer has extensibility, particularly in the wet state compared to the dry state. It has the feature that it can express sex. This feature is presumed to be due to the fact that interference and entanglement due to hydrophilic short fibers or between hydrophilic short fibers are alleviated by wetting. On the other hand, as the interference and entanglement between the hydrophilic short fibers is alleviated, the strength of the hydrophilic short fiber layer itself is weakened, and the fiber layer may be easily broken.

  In order to maintain a good balance between the followability of the hydrophilic fiber layer to the stretchability of the ultrafine fiber layer and the strength of the hydrophilic fiber layer, in the present invention, as an integration method between both layers, “partial thermocompression bonding” It is preferable to adopt the “method”. According to the partial thermocompression bonding method, in the “thermocompression bonding part”, the fibers are firmly bonded by thermal softening of the fibers, and therefore, the peel resistance between the ultrafine fiber layer and the hydrophilic fiber layer is enhanced. On the other hand, by adopting this partial thermocompression bonding method, in the “non-thermocompression bonding part” formed together with the “thermocompression bonding part”, individual fibers exist without being restricted to each other. The stretchability of the resulting laminated sheet is imparted by the elongation of the fibers. The stretchability of the ultrafine fiber layer, the followability by the stretchability of the hydrophilic fiber layer integrated therewith, and the excellent stretchability of the resulting laminated sheet are due to the “thermocompression bonding part”. This is ensured by the enhanced peel resistance between the two layers. That is, if the integration of both layers is weak, the hydrophilic fiber layer easily peels off before sufficiently following the stretchability of the ultrafine fiber layer. The reason why the laminated sheet of the present invention can exhibit excellent stretchability, particularly when wet, is that the restriction of interference and entanglement between hydrophilic fibers existing in the “non-thermocompression bonding part” is further relaxed. This is considered to be because the followability of the hydrophilic fiber layer to the stretchability of the ultrafine fiber layer is further increased.

The elastomeric long fibers in the ultrafine fiber layer are softened by thermocompression bonding and joined to the constituent fibers of the hydrophilic fiber layer, which contributes to the integration of both layers. The adhesive strength inherently possessed by the elastomer long fiber itself increases the bonding strength with the fibers constituting the hydrophilic fiber layer, thereby further enhancing the peel resistance between the two layers.
By integration through such strong bonding, it is possible to provide a laminated sheet that is not easily broken even when highly expanded and contracted. Thus, in the present invention, it is preferable that at least the hydrophilic fiber layer is composed of short fibers, the ultrafine fiber layer includes elastomer fibers, and the two layers are integrated by partial thermocompression bonding. .

Interference and entanglement between short fibers is reduced by wetting in laminated sheets that are integrated by simply three-dimensional entanglement of fibers by the spunlace method (hydroentanglement method) or needle punch method The phenomenon presumed to be likely appears also at the three-dimensional confounding point. As a result of loosening of the entanglement between the fibers at the entanglement point that supports this integration, such an integration method generally provides sufficient followability of the hydrophilic fiber layer to the stretchability of the ultrafine fiber layer. Before being formed, delamination tends to occur.
In addition, when integration is performed using the spunlace method (hydroentanglement method) or the needle punch method, the high-pressure water or needle used penetrates or passes through the laminate, so that the fibers are pushed around the fiber. Are generally rearranged, and generally, the air permeability of the laminated body after the integration becomes higher than that before the integration as the distance between fibers in the penetration or passage portion increases.

On the other hand, when the integration is performed by the partial thermocompression bonding method, the fibers are bonded to each other by the softening of the fibers, that is, the gap between the fibers is blocked. In comparison, the air permeability of the laminated body after integration is lowered.
The skin mounting sheet of the present invention is preferably integrated by a partial thermocompression bonding method. As a result of the integration by this method, the air permeability is effectively reduced. As a result, when worn on the skin, a high masking effect and a wrapping effect are achieved, and the impregnated chemical solution and cosmetics bring the skin. It is possible to increase the efficacy and effect efficiently. Air permeability of the laminated sheet of the present invention is preferably from 10~100cm ³ / cm ² · sec, and even more preferably 20~80cm ³ / cm ² · sec. In addition, when the air permeability satisfies such a range, the transpiration of the liquid component impregnated in the skin mounting sheet is reduced and drying is suppressed. Sustainability can also be improved.

In the present invention, when the surface of the hydrophilic fiber layer exposed on one surface of the skin mounting sheet has a concavo-convex shape, the sheet surface can be reduced in stickiness, and the sheets are overlapped with each other. It will be excellent in releasability.
Further, it is preferable that the surface of the ultrafine fiber layer exposed on the other surface of the skin mounting sheet has a smooth shape because it is excellent in a feeling of mounting on the skin and adhesion.

The skin mounting sheet of the present invention is impregnated with 100 to 1500 parts by mass of a chemical or cosmetic with respect to 100 parts by mass of the laminated sheet. The elongation recovery rate at 30% elongation in at least one direction of the skin mounting sheet of the present invention is 30 to 100%. Most preferably, it is 50 to 100%.
The skin-mounting sheet of the present invention can exhibit significantly superior elongation and elasticity as compared to a laminated sheet before impregnating with a chemical solution or cosmetic. Thus, before impregnating chemicals and cosmetics, the property that excellent elongation and expansion / contraction performance do not appear is the resistance to deformation against unexpected stress applied in the manufacturing process before the process of impregnating the liquid component. Industrially, it has an excellent effect in that it is excellent in. More specifically, the shape of the obtained sheet may be lost in the process of die cutting or shearing the laminated sheet to an appropriate shape and size, particularly for the purpose of wearing each part of the body or face. Therefore, the desired shape is easily reproduced on the product.

  In the production of the skin mounting sheet of the present invention, as a means for impregnating the laminated sheet with a liquid chemical or cosmetic, which is a liquid component, a method of immersing in a chemical or cosmetic, a nip roller after being immersed in the chemical or cosmetic Etc., a method of adhering by contact with a touch roll to which a chemical solution or cosmetic is adhered, a method of attaching a chemical solution or cosmetic by transfer using a gravure roller, etc., a chemical solution or makeup using a spray or the like The method of adhering a material by spraying is mentioned. When impregnating by immersion, it is appropriate to immerse for at least 10 minutes.

The chemical | medical solution and cosmetics which the sheet | seat for skin mounting | wearing of this invention can impregnate are not specifically limited. Examples of chemicals include refreshing agents, deodorants, antibacterial agents, keratin softeners, sebum discharge inhibitors, keratolytic agents, bactericides, analgesics, anti-inflammatory agents, disinfectants, pest repellents, brighteners, and light removers , Healing agents, protein removers and the like. Further, as cosmetics, for example, liquid cosmetics such as skin lotion, milky lotion, and beauty liquid containing moisturizing ingredients, cleansing ingredients, antiperspirant ingredients, scent ingredients, whitening ingredients, blood circulation promoting ingredients, UV protection ingredients, slimming ingredients, etc. Can be illustrated.
Examples of the chemical solution or cosmetic component impregnated in the skin mounting sheet of the present invention include polypeptides such as collagen-like polypeptides. Examples of the polypeptide include those disclosed in JP2003-321500A and JP2005-60314A. As another specific example of the polypeptide, the formula: R1- (X-Hyp-Gly) n-R2 or the formula: R1 (Pro-Y-Gly) n-R2 (wherein X and Y are amino acid residues) , R1 is H or other functional group, R2 is OR3 or other functional group, R3 is H or a monovalent metal, and n is an integer. .
The elongation of the sheet for skin attachment of the present invention is 1 in the direction perpendicular to the direction in which the laminated hydrophilic fiber layer has extensibility with respect to the elongation of the laminated sheet before impregnating the chemical solution or cosmetic. It is preferably in the range of 1 to 2.0 times, and more preferably in the range of 1.2 to 2.0 times.

Because of its excellent stretchability, the skin mounting sheet of the present invention stretches somewhat when worn on the skin, and fits the skin moderately with the force of shrinking after wearing. The feeling of tightening caused by the skin being pulled appropriately by the force to be shrunk brings about a comfortable wearing feeling and wearing stability.
In the present invention, it is preferable that the laminated sheet before impregnating with the chemical solution or the cosmetic has a 10% elongation modulus strength in at least one direction within a range of 0.2 to 5.0 N / 25 mm. In particular, the length of the fibers arranged in a direction perpendicular to the direction in which the integrated hydrophilic fiber layer is extensible, preferably in one direction constituting the spunlace nonwoven fabric included in the integrated hydrophilic fiber layer. The 10% elongation modulus strength in the longitudinal direction is preferably in the range of 0.2 to 5.0 N / 25 mm. Further, the 10% elongation modulus strength is preferably in the range of 0.5 to 3.0 N / 25 mm.
On the other hand, the skin mounting sheet of the present invention has a 10% elongation modulus strength in a range of 0.1 to 4.0 N / 25 mm in at least one direction. The skin-mounting sheet of the present invention comprises a spunlace nonwoven fabric that is included in a direction perpendicular to the direction in which the integrated hydrophilic fiber layer has extensibility, preferably in the integrated hydrophilic fiber layer. The 10% elongation modulus strength in the length direction of the fibers arranged in the direction is preferably in the range of 0.1 to 4.0 N / 25 mm. The 10% elongation modulus strength is more preferably in the range of 0.2 to 2.5 N / 25 mm. Moreover, it is preferable that the ratio of the 10% elongation modulus strength of the skin mounting sheet to the 10% elongation modulus strength of the laminated sheet before impregnation with the chemical solution or cosmetic is in the range of 0.1 to 0.9 times. The range of 0.2 to 0.8 times is more preferable.

The skin mounting sheet of the present invention can be used with the ultrafine fiber layer side in contact with the skin. In this case, the hydrophilic fiber layer has a function of holding a chemical solution and cosmetics, and the ultrafine fiber layer has a function of oozing it into the skin by a necessary amount. It is also possible to adjust the amount of exudation and the rate of exudation at this time, such as reducing the thickness of the ultrafine fiber layer, mixing an appropriate amount of hydrophilic fibers into the ultrafine fiber layer, By adding a hydrophilic agent and applying a hydrophilic treatment to the constituent resin, it is possible to increase the amount of bleeding and increase the speed of bleeding.
In the present invention, in addition to the ultrafine fiber layer being composed of thin fibers, the flexibility brought about by including particularly elastic elastomer fibers can contribute to a comfortable wearing feeling. In addition, an appropriate grip effect due to the adhesiveness of the elastomer fibers can further improve the fit, tightening, and mounting stability. In addition to the fact that the ultrafine fiber layer is composed of relatively thin fibers with fine fibers, the surface of the fiber layer in contact with the skin and the like is smooth, so that the adhesion to the skin and the like is increased, and the masking effect and A wrap effect is produced, and the effects of the chemicals and cosmetics can be improved.

  On the other hand, when a large amount of chemical liquid or cosmetic is impregnated, the excessively exuded chemical liquid or cosmetic forms a film between the smooth ultrafine fiber layer surface and the surface of the object such as the skin, and the skin surface. As a result of causing a phenomenon that the skin mounting sheet becomes slippery, the fit may be impaired. In such a case, the hydrophilic fiber layer side can be used in contact with the skin. The hydrophilic fiber layer itself absorbs and retains chemicals and cosmetics, so it has the ability to replenish chemicals and cosmetics to the skin, and the fiber layer surface has an uneven shape. In the case where it is formed, the slipperiness with the skin or the like is thereby improved, and a fit can be ensured.

  Moreover, even when the viscosity of the chemical solution or cosmetic to be impregnated is relatively high, it may be advantageous to use the hydrophilic fiber layer side so as to contact the skin. Such chemical solutions and cosmetics are unlikely to penetrate into the ultrafine fiber layer. Therefore, if the ultrafine fiber layer side is used so as to be in contact with the skin, the chemical solution and cosmetics may not spread sufficiently to the skin. On the other hand, if the hydrophilic fiber layer side is used so as to come into contact with the skin, the effect of fitting the skin mounting sheet to the skin moderately occurs due to the viscosity of the high-viscosity chemicals and the cosmetic itself, and the one side of the ultrafine fiber layer Since these high-viscosity chemicals and cosmetics do not penetrate, the stickiness caused by them does not occur and the handling property is improved.

The thickness of the skin mounting sheet of the present invention is not particularly limited. However, the thickness of the laminated sheet when a load of 2 kg / cm ² (0.196 MPa) is applied is 0 from the viewpoint of impregnation and permeability of chemicals and cosmetics. It is preferable to be in the range of 2 to 0.7 mm. It can be appropriately selected depending on the flexibility required for the skin mounting sheet, the amount and viscosity of the drug solution or cosmetic, the site to be mounted, and the like.

The skin mounting sheet of the present invention is impregnated with 100 to 1500 parts by mass of a chemical or cosmetic with respect to 100 parts by mass of the laminated sheet.
The skin mounting sheet of the present invention is suitable for mounting on all parts of the human body, the entire face, nose, eyes, mouth, neck, arms, hands, fingers, waist, abdomen, thighs, calves, knees, ankles, etc. Specifically, it can be suitably used for beauty sheets, skin pack sheets, face masks, adhesive plasters, poultice base fabrics, plaster base fabrics, and the like.

Hereinafter, the content of the present invention will be described with reference to examples, but the present invention is not limited thereto.
The definitions and measuring methods of various physical properties examined for the stretchable laminated sheets produced in each Example and Comparative Example are described below.
In the following description, “MD” means a direction that coincides with the length direction of fibers arranged in one direction constituting the spunlace nonwoven fabric of the hydrophilic fiber layer used, and “CD "Means the direction perpendicular to it.
(1) Average fiber diameter Using a scanning electron microscope (SEM), an enlarged photograph of the nonwoven fabric surface was taken, the diameter of 100 fibers was measured, and the arithmetic average value was taken as the average fiber diameter.
(2) Pressure bonding area ratio Using a scanning electron microscope (SEM), an enlarged photograph of the surface of the nonwoven fabric was taken, and the ratio of the pressure bonding points to the area per unit pressure bonding point pitch was defined as the pressure bonding area ratio.
Crimping area ratio (%) = (crimping point area occupying unit pitch / unit pitch area) × 100

(3) Elongation recovery rate Measured according to JIS L1096 “General Textile Test Method”. From a sheet, a test piece having a width of 25 mm and a length of 200 mm was measured. The length direction of the test piece was perpendicular to the length direction in which the fibers constituting the spunlace nonwoven fabric of the hydrophilic fiber layer were arranged in one direction (CD (Direction) and cut to match.
Place this test piece and a moisturizing lotion (product name: Moistage Essence Lotion, Kracie Home Products) in an amount sufficient to immerse the test piece in a polyethylene bag and leave it for 10 minutes. By holding the both sides with the hand three times and taking out, the skin was impregnated with lotion so that the test piece was at least twice its own weight. This test piece was fixed using a tensile tester Autograph AG-G (trade name, manufactured by Shimadzu Corporation) with the gap between the chucks set to 100 mm. After extending to 30 mm at a pulling speed of 300 mm / min, it was returned at the same speed, and the load applied to the test piece was set to zero. Immediately after that, it was stretched again to 30% at the same speed, and the stretched length when the load started again was defined as Lmm. The elongation recovery rate was determined according to the following formula.
Elongation recovery rate at 30% elongation (%) = {(30 ^{* 1} -L) / 30 ^{* 1} } x 100
* 1: Length of the test piece extended (mm)

(4) Breaking strength and elongation of the laminated sheet (dried state before impregnating with chemicals and cosmetics)
Measured according to JIS L1906 “General long fiber nonwoven fabric test method”. A test piece having a width of 25 mm and a length of 200 mm was prepared. The test piece is cut from the sheet so that the length direction of the test piece coincides with the length direction (MD direction) in which the fibers constituting the spunlace nonwoven fabric of the hydrophilic fiber layer are arranged in one direction. Two types of test pieces were prepared, and the test piece was prepared by cutting the length direction of the test piece so as to coincide with the direction perpendicular to the MD direction (CD direction). Using a tensile tester Autograph AG-G (trade name, manufactured by Shimadzu Corporation), the distance between chucks was set to 100 mm, and the test piece was fixed. The maximum strength and the maximum elongation until the material was stretched at a tensile speed of 300 mm / min and ruptured were defined as the rupture strength and rupture elongation, respectively. The strength at 10% elongation was defined as 10% elongation modulus strength.
(5) Breaking strength and elongation of the sheet for skin mounting (wet state after impregnation with chemicals and cosmetics)
Measured according to JIS L1906 “General long fiber nonwoven fabric test method”. A test piece having a width of 25 mm and a length of 200 mm was cut from the sheet so that the length direction thereof coincided with the MD direction and the CD direction in accordance with the procedure (4). Two types of test pieces were prepared. Place this test piece and a moisturizing lotion (product name: Moistage Essence Lotion, Kracie Home Products) in an amount sufficient to immerse the test piece in a polyethylene bag and leave it for 10 minutes. By holding the both sides with the hand three times and taking out, the skin was impregnated with lotion so that the test piece was at least twice its own weight. This test piece was fixed using a tensile tester Autograph AG-G (trade name, manufactured by Shimadzu Corporation) with the gap between the chucks set to 100 mm. The maximum strength and the maximum elongation until the material was stretched at a tensile speed of 300 mm / min and ruptured were defined as the rupture strength and rupture elongation, respectively. The strength at 10% elongation was defined as 10% elongation modulus strength.

(6) Weight per unit area Measured according to JIS L1906 “General long fiber nonwoven fabric test method”. After cutting out test pieces having a size of 20 cm × 20 cm from arbitrary five locations of the nonwoven fabric, the weight of each test piece was measured with an electronic balance, and the average value was converted to a mass per 1 m ² to obtain a basis weight.
(7) Thickness of laminated sheet, thickness ratio of each constituent layer (%)
Measured according to JIS L1906 “General long fiber nonwoven fabric test method”.
(i) The thickness L1 (mm) of the laminated sheet or the dried skin mounting sheet is measured.
(ii) The hydrophilic fiber layer and the ultrafine fiber layer are peeled off, and the thickness L2 (mm) of the ultrafine fiber layer is measured.
(iii) The thickness L3 (mm) of the hydrophilic fiber layer is calculated by the following formula.
L3 (mm) = L1-L2
(iv) The thickness ratio R1 of the ultrafine fiber layer based on the laminated sheet and the thickness ratio R2 of the hydrophilic fiber layer are calculated by the following formulas.
R1 (%) = L2 / L1 × 100
R2 (%) = L3 / L1 × 100

(8) Mounting stability The laminated sheet is cut into a face mask, and the cut sheet and a moisturizing lotion (product name: Moistage Essence Lotion, manufactured by Kracie Home Products) in which the sheet is sufficiently immersed are made of polyethylene. Put it in a bag, leave it for 10 minutes, hold the both sides of the test piece with your hand three times through the bag and take it out, so that the test piece is impregnated with lotion so that it is at least twice its own weight. Created a mask. Separately, in the same manner, instead of the above moisturizing lotion, a sheet cut into the same face mask mold is impregnated with moisturizing emulsion (trade name: Moistage Essence Milk, Kracie Home Products), Created a face mask. These two types of face masks are put on the face for 10 minutes by the panelist, and the results of the two types are combined to give adhesion, dryness, and feeling of skin tightening. It was evaluated in three stages.
○: Good Δ: Slightly inferior ×: Inferior (9) Air permeability The laminated sheet or the dried sheet for skin mounting was measured in accordance with the fragile form method of JIS L1906 “General Long Fiber Nonwoven Fabric Test Method”. A test piece of 200 mm × 200 mm was collected and measured using a breathability tester (manufactured by Toyo Seiki).

The abbreviations and contents in the following table of the raw material resins used in the present invention are as follows.
A: Styrene-ethylenebutylene-styrene block copolymer, Kraton MD6705NS ((trade name), manufactured by Kraton Polymer)
B: Propylene / ethylene copolymer, VM2125 ((trade name), manufactured by ExxonMobil)
C: Thermoplastic polyurethane, Pandex T-1180 ((trade name), manufactured by DIC-Bayer)
D: Polypropylene Mitsui Polypro S119 ((trade name), made by Prime Polymer)

[Example 1]
A meltblown nonwoven fabric using A as a raw material resin was used for the ultrafine fiber layer. As meltblown equipment, equipped with screw (30mm diameter), extruder with heating element and gear pump, spinneret (hole diameter 0.3mm, number of holes 501 holes, effective width 500mm), compressed air generator, air heater, polyester net A device comprising a collecting conveyor and a winder was used. A is charged into the extruder, heated and melted at 230 ° C. by a heating element, discharged from the spinneret at a spinning speed of 0.45 g / min per single hole, and the discharged fiber was heated to 400 ° C. and 98 kPa (gauge pressure) The melt-blown nonwoven fabric in which fibers are randomly collected was obtained by spraying onto a polyester net collection conveyor running at a running speed of 22 m / min. The collection conveyor was installed at a distance of 25 cm from the spinneret. The blown air was removed with a suction device provided on the back side of the collection conveyor.

In the process of producing the melt blown nonwoven fabric of the above method, the hydrophilic fiber layer is a rayon having a fiber length of 51 mm, a pulp having a fiber length of 7 mm, and the fibers are arranged in one direction and have a stretchability in that direction. A spunlace nonwoven fabric composed of / m ² rayon / pulp / rayon (laminated fiber layer having a weight ratio of 25/50/25) was inserted, and a 20 g / m ² meltblown nonwoven fabric was laminated thereon. Furthermore, with this non-woven fabric laminate, the engraving roll is in contact with the spunlace nonwoven fabric at a temperature of 80 ° C. and a pressure of 20 N / cm using a point bond processing machine having an engraving roll engraved with an uneven pattern on the surface and a smooth roll. Laminated sheet with partial thermocompression bonding, with a recess area ratio of 25%, an area of each recess of 0.46 mm ² , a depth of 0.55 mm, a distance between the recesses of 1.36 mm in length and 2.72 mm in width Got. The thickness of the laminated sheet was 0.465 mm, and the ultrafine fiber layer accounted for 25% and the hydrophilic fiber layer accounted for 75% on the basis of the thickness. Table 1 shows the physical properties and the like of this laminated sheet.

  The sheet obtained by impregnating the obtained laminated sheet with a chemical or a cosmetic (skin mounting sheet) had particularly excellent elongation and elasticity. Further, when the obtained skin mounting sheet was used as a cosmetic face mask, the mounting stability on the face was good regardless of whether the hydrophilic fiber layer or the ultrafine fiber layer was on the skin side.

[Example 2]
A meltblown nonwoven fabric using A and B as raw resin was used for the ultrafine fiber layer. Two extruders having screws (30 mm diameter), heating elements and gear pumps as meltblown devices, spinnerets for blending fibers (hole diameters of 0.3 mm, spinning holes for discharging fibers of different components) alternately for each row A device comprising a lined spinning hole, a hole number of 501 holes, an effective width of 500 mm), a compressed air generator, an air heater, a collection conveyor equipped with a polyester net, and a winder was used. A and B are charged separately into each extruder, heated and melted at 230 ° C. by a heating element, and a gear pump is set so that the A / B ratio (weight%) is 50/50, and spinning is performed. Both A and B per single hole are discharged from the base at a spinning speed of 0.45 g / min, and the discharged fiber is running at a running speed of 22 m / min with 98 kPa (gauge pressure) compressed air heated to 400 ° C. A melt blown nonwoven fabric in which fibers made of A and fibers made of B were uniformly and randomly accumulated was obtained by spraying onto a collection conveyor of a polyester net. The collection conveyor was installed at a distance of 25 cm from the spinneret. The blown air was removed with a suction device provided on the back side of the collection conveyor.

Example 1 except that the spunlace nonwoven fabric used in Example 1 was inserted as a hydrophilic fiber layer in the process of producing the melt blown nonwoven fabric of the above method, and a 20 g / m ² melt blown nonwoven fabric was laminated thereon. In accordance with the above, a laminated sheet was obtained. The obtained laminated sheet has a concave area ratio of 25%, an area of each concave part of 0.46 mm, a depth of 0.55 mm, a distance between the concave parts of 1.36 mm in length and 2.72 mm in width. The thickness was 0.484 mm, and on the basis of the thickness, the ultrafine fiber layer accounted for 26% and the hydrophilic fiber layer accounted for 74%. Table 1 shows the physical properties and the like of this laminated sheet.
The sheet obtained by impregnating the obtained laminated sheet with a chemical or a cosmetic (skin mounting sheet) had particularly excellent elongation and elasticity. Further, when the obtained skin mounting sheet was used as a cosmetic face mask, the mounting stability on the face was good regardless of whether the hydrophilic fiber layer or the ultrafine fiber layer was on the skin side.

[Example 3]
A laminated sheet was obtained in accordance with Example 2 except that a melt blown nonwoven fabric using B and C as raw material resins was used for the ultrafine fiber layer. The obtained laminated sheet has a concave area ratio of 25%, an area of each concave part of 0.46 mm, a depth of 0.55 mm, a distance between the concave parts of 1.36 mm in length and 2.72 mm in width. The thickness was 0.411 mm, and the ultrafine fiber layer accounted for 30% and the hydrophilic fiber layer accounted for 70% on the basis of the thickness. Table 1 shows the physical properties and the like of this laminated sheet. The sheet obtained by impregnating the obtained laminated sheet with a chemical or a cosmetic (skin mounting sheet) had particularly excellent elongation and elasticity. Further, when the obtained skin mounting sheet was used as a cosmetic face mask, the mounting stability on the face was good regardless of whether the hydrophilic fiber layer or the ultrafine fiber layer was on the skin side.

[Comparative Example 1]
Only the spunlace nonwoven fabric used as the hydrophilic fiber layer in Example 1 was used as a single layer. The results are shown in Table 2. This was inferior in stretchability when wet. When the obtained laminated sheet was used as a cosmetic face mask, the non-woven fabric was not stretchable, so the mounting stability was poor.

[Comparative Example 2]
A laminated sheet was obtained in accordance with Example 1 except that a melt blown nonwoven fabric using D as a raw material resin was used for the ultrafine fiber layer. The results are shown in Table 2. This was inferior in elongation and stretchability when wet. When the obtained laminated sheet was used as a face mask for cosmetics, the mounting stability was inferior because the nonwoven fabric was not stretchable.

[Comparative Example 3]
A laminated sheet using a spunlace nonwoven fabric used as a hydrophilic fiber layer in Example 1 was obtained by using polyethylene / polyester terephthalate-based split fibers (trade name: Sepa, manufactured by Daiwabo Polytech Co., Ltd.) for the ultrafine fiber layer. The results are shown in Table 2. This was inferior in elongation and stretchability when wet. When the obtained laminated sheet was used as a face mask for cosmetics, the wearing stability was poor because the nonwoven fabric was not stretchable.

^*1: 肌：親水・・・肌側を親水性繊維層とした。
肌：極細・・・肌側を極細繊維層とした。

^{* 1} : Skin: Hydrophilic ... The skin side is a hydrophilic fiber layer.
Skin: Extra fine ... The ultrafine fiber layer was used on the skin side.

^*1: 肌：親水・・・肌側を親水性繊維層とした。
肌：極細・・・肌側を極細繊維層とした。

^{* 1} : Skin: Hydrophilic ... The skin side is a hydrophilic fiber layer.
Skin: Extra fine ... The ultrafine fiber layer was used on the skin side.

  The skin mounting sheet of the present invention has an elongation recovery rate that occurs when it is impregnated with a liquid, so that every part of the human body, the entire face, nose, eyes, mouth, neck, arms, hands, fingers, waist, abdomen, thighs, Suitable for wearing on calves, knees, ankles, etc., specifically, it can be suitably used for beauty sheets, skin pack sheets, face masks, bandages, poultices, plaster materials, etc. It is not limited.

Claims (3)

A laminated sheet comprising a hydrophilic fiber layer stretchable microfiber layer, 100 to 1500 parts by weight of the drug solution or cosmetics with respect laminated sheet 100 parts by mass a wet sheet made of impregnated, hydrophilic fibers The layer and the ultrafine fiber layer are laminated by a partial thermocompression bonding method, and the 10% elongation modulus strength in at least one direction of the wet sheet is in the range of 0.1 to 4.0 N / 25 mm, and 30% in the same direction. A skin mounting sheet, wherein an elongation recovery rate when stretched is in a range of 30 to 100%.   The sheet | seat for skin mounting | wearing of Claim 1 in which an ultra-fine fiber layer contains the at least 1 sort (s) of elastomer fiber chosen from the styrene-type elastomer fiber, the olefin-type elastomer fiber, the ester-type elastomer fiber, and the urethane-type elastomer fiber.   The skin mounting sheet according to claim 1, wherein the ultrafine fiber layer includes at least two types of elastomer fibers selected from styrene-based elastomer fibers, olefin-based elastomer fibers, and urethane-based elastomer fibers.