JP4976268B2 - Cobweb removal composition - Google Patents
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- JP4976268B2 JP4976268B2 JP2007321797A JP2007321797A JP4976268B2 JP 4976268 B2 JP4976268 B2 JP 4976268B2 JP 2007321797 A JP2007321797 A JP 2007321797A JP 2007321797 A JP2007321797 A JP 2007321797A JP 4976268 B2 JP4976268 B2 JP 4976268B2
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- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 241000221931 Hypomyces rosellus Species 0.000 title claims abstract description 41
- 239000000126 substance Substances 0.000 claims abstract description 22
- 239000007921 spray Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- 241000239290 Araneae Species 0.000 claims description 23
- 239000004094 surface-active agent Substances 0.000 claims description 9
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical group Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 7
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 238000005507 spraying Methods 0.000 abstract description 5
- 238000004804 winding Methods 0.000 abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- -1 specifically Chemical compound 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 229910052754 neon Inorganic materials 0.000 description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000195940 Bryophyta Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 235000011929 mousse Nutrition 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 108010004032 Bromelains Proteins 0.000 description 1
- 108090000604 Hydrolases Proteins 0.000 description 1
- 102000004157 Hydrolases Human genes 0.000 description 1
- 108090000526 Papain Proteins 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920001872 Spider silk Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000019835 bromelain Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Abstract
Description
本発明は、家屋やその玄関、窓枠、軒下、壁面、門灯、店舗や工場の出入口、屋外外灯、自動販売機、商業施設のネオン、樹木の間などに張られたクモの巣を溶解して取り除く、クモの巣除去用組成物、該組成物を含有するスプレー剤、及び該組成物を用いたクモの巣除去方法に関する。 The present invention dissolves and removes spider webs stretched between houses and their entrances, window frames, eaves, walls, gate lamps, store and factory doorways, outdoor lights, vending machines, neon lights of commercial facilities, and trees. The present invention relates to a composition for removing a cobweb, a spray containing the composition, and a method for removing a cobweb using the composition.
クモの巣を除去する方法としては、クモの巣を物理的に除去する方法が知られている（特許文献１参照）。また、化学的な除去方法としては、殺虫剤でクモを駆除してクモの巣の再発を防止する方法が知られている（特許文献２参照）。
従来の物理的なクモの巣の除去方法では、クモの巣を巻き取り集めて捨てるというわずらわしい作業が伴う。また、化学的な除去方法は、殺虫剤でクモ自体を駆除するものであり、直接クモの巣に作用するものではないため、張られたクモの巣が除去されるものではない。 The conventional method for removing the cobweb involves the troublesome work of winding up the cobweb and discarding it. In addition, the chemical removal method is to remove the spider itself with an insecticide and does not directly act on the web, so that the stretched web is not removed.
従って、本発明の課題は、クモの巣を巻き取り集めて捨てるというわずらわしい作業を伴うことなく、噴霧などするだけでクモの巣を除去することができるクモの巣除去用組成物、該組成物を含有するスプレー剤、及び該組成物を用いたクモの巣除去方法を提供することにある。 Accordingly, an object of the present invention is to provide a composition for removing a cobweb that can remove the cobweb only by spraying, without the troublesome work of winding up the web and discarding it, a spray containing the composition, And providing a spider web removing method using the composition.
本発明者は、アルカリ性物質をクモの巣に接触させることで、クモの巣自体を溶解させて除去できることを見出し本発明に到った。 The inventor has found that the cobweb itself can be dissolved and removed by bringing an alkaline substance into contact with the cobweb, and the present invention has been reached.
本発明は、
〔１〕 アルカリ性物質を含有してなる、クモの巣除去用組成物、
〔２〕 前記〔１〕記載の組成物を含んでなる、クモの巣除去用スプレー剤、並びに
〔３〕 前記〔１〕記載の組成物を用いてクモの巣を除去する、クモの巣除去方法
に関する。
The present invention
[1] A cobweb removing composition comprising an alkaline substance,
[2] A cobweb removing spray comprising the composition of [1], and [3] a cobweb removing method of removing the cobweb using the composition of [1].
本発明は、クモの巣を巻き取り集めて捨てるというわずらわしい作業を伴うことなく、噴霧などするだけでクモの巣を溶解して除去することができるという優れた効果を奏する。 INDUSTRIAL APPLICABILITY The present invention has an excellent effect that the cobweb can be dissolved and removed only by spraying without the troublesome work of winding up the web and discarding it.
本発明のクモの巣除去用組成物は、アルカリ性物質を含有する組成物であって、該アルカリ性物質としては、次亜塩素酸塩及び水酸化物塩が好ましく、具体的には、ナトリウム、カリウム等のアルカリ金属等の次亜塩素酸塩、水酸化物塩等が挙げられる。これらの中では、経済性、入手のしやすさ、及び取り扱いの容易さの観点から、次亜塩素酸ナトリウム及び水酸化ナトリウムが好ましく、反応性の観点から次亜塩素酸ナトリウムがより好ましい。 The composition for removing a spider web of the present invention is a composition containing an alkaline substance, and the alkaline substance is preferably a hypochlorite or a hydroxide salt, specifically, sodium, potassium, etc. Examples include hypochlorites such as alkali metals and hydroxide salts. Among these, sodium hypochlorite and sodium hydroxide are preferable from the viewpoint of economy, availability, and handling, and sodium hypochlorite is more preferable from the viewpoint of reactivity.
本発明のクモの巣除去用組成物は、アルカリ性物質が溶解したアルカリ性水溶液であることが好ましい。 The cobweb removing composition of the present invention is preferably an alkaline aqueous solution in which an alkaline substance is dissolved.
アルカリ性物質の含有量は、クモの巣除去用組成物中、0.2〜15.0重量％が好ましく、2.0〜10.0重量％がより好ましい。 The content of the alkaline substance is preferably 0.2 to 15.0% by weight, more preferably 2.0 to 10.0% by weight, in the cobweb removing composition.
アルカリ性物質が次亜塩素酸塩である場合、クモの巣の溶解性の観点から、アルカリ性溶液の有効塩素濃度は、0.1〜5.0重量％が好ましく、1.0〜5.0重量％がより好ましい。 When the alkaline substance is hypochlorite, the effective chlorine concentration of the alkaline solution is preferably 0.1 to 5.0% by weight and more preferably 1.0 to 5.0% by weight from the viewpoint of the solubility of the spider web.
本発明のクモの巣除去用組成物は、クモの巣への付着性及び反応性の観点から、さらに界面活性剤を含有することが好ましい。界面活性剤としては、ポリオキシエチレンアルキルエーテル硫酸ナトリウム等の陰イオン界面活性剤、アルキルジメチルアミンオキシド、アルキルジメチルアミノ酢酸ベタイン等の両性界面活性剤、ポリオキシエチレンアルキルエーテル等の非イオン界面活性剤、陽イオン界面活性剤等が挙げられる。界面活性剤は、クモの糸の撥水性を低下させ、アルカリ性物質の付着性を向上させる成分であれば特に限定されないが、アルキルアミンオキシド等の起泡性に優れた界面活性剤は、クモの糸に対する付着性が高いばかりでなく、噴霧粒子の空中への飛散抑制、人体への付着低減等の効果もあり、好ましい。 The cobweb removing composition of the present invention preferably further contains a surfactant from the viewpoint of adhesion to the web and reactivity. Surfactants include anionic surfactants such as polyoxyethylene alkyl ether sodium sulfate, amphoteric surfactants such as alkyldimethylamine oxide and alkyldimethylaminoacetic acid betaine, and nonionic surfactants such as polyoxyethylene alkyl ether. And cationic surfactants. The surfactant is not particularly limited as long as it is a component that lowers the water repellency of the spider silk and improves the adhesion of the alkaline substance. However, surfactants having excellent foaming properties such as alkylamine oxide are not limited. Not only has high adhesiveness to yarn, but also has effects such as suppression of scattering of spray particles into the air and reduction of adhesion to the human body, which is preferable.
界面活性剤の含有量は、クモの巣除去用組成物中、1〜10重量％が好ましい。ただし、かかる濃度はあくまでも使用時の濃度であり、これらの組成物を濃縮品として流通させ、使用者が必要に応じて希釈して使用する場合においてはこの濃度の限りではない。 The content of the surfactant is preferably 1 to 10% by weight in the spider web removing composition. However, such a concentration is a concentration at the time of use, and is not limited to this concentration when these compositions are distributed as a concentrated product and diluted by the user as necessary.
本発明のクモ巣除去用組成物は、品質保持の観点から、発明の効果を損なわない程度にpH安定剤を含んでもよい。 The cobweb removing composition of the present invention may contain a pH stabilizer to the extent that the effects of the invention are not impaired from the viewpoint of maintaining quality.
本発明のクモの巣除去用組成物は、さらに、消臭剤、殺虫剤、忌避剤、除菌剤、洗浄剤、香料、光触媒、撥水剤、皮膜形成剤等の添加剤を含んでもよい。 The cobweb removing composition of the present invention may further contain additives such as deodorants, insecticides, repellents, disinfectants, cleaning agents, fragrances, photocatalysts, water repellents, and film forming agents.
また、本発明のクモの巣除去用組成物は、スプレー剤、ムース剤等として用いることができる。これらは、トリガータイプ及びポンプタイプのいずれであってもよく、収容容器も大型の蓄圧式散布器、噴霧器等、小型の噴霧器等、特に限定されない。 Moreover, the composition for removing a spider web of the present invention can be used as a spray agent, a mousse agent or the like. These may be either a trigger type or a pump type, and the container is not particularly limited, such as a large pressure accumulation type sprayer, a sprayer, or a small sprayer.
本発明の組成物は、より短時間に広範囲の処理が可能である観点からは、スプレー剤が好ましく、取り扱いの容易なハンドスプレーの形態で用いることがより好ましい。また、クモの巣への付着性を向上させて飛沫を防止することにより安全性を高めることができる観点からは、ムース剤が好ましい。 The composition of the present invention is preferably a spray from the viewpoint that a wide range of treatment can be performed in a shorter time, and more preferably used in the form of a hand spray that is easy to handle. In addition, a mousse agent is preferable from the viewpoint of improving safety by improving adhesion to the web and preventing splashes.
さらに本発明は、本発明のクモの巣除去用組成物を用いてクモの巣を除去する、クモの巣除去方法に関する。 Furthermore, the present invention relates to a spider web removing method for removing a spider web using the spider web removing composition of the present invention.
クモの巣の除去方法としては、本発明の組成物を家屋やその玄関、窓枠、軒下、壁面、門灯、店舗や工場の出入口、屋外外灯、自動販売機、商業施設のネオン、樹木の間などに張られたクモの巣に直接噴霧する方法等が挙げられる。 As a method for removing the cobweb, the composition of the present invention is applied to a house, its entrance, window frame, eaves, wall surface, gate lamp, store / factory doorway, outdoor lamp, vending machine, neon of commercial facilities, between trees, etc. For example, a method of spraying directly on a stretched spider web.
次に、本発明を実施例に基づいてさらに詳細に説明するが、本発明は、かかる実施例のみに限定されるものではない。 Next, the present invention will be described in more detail based on examples. However, the present invention is not limited to such examples.
実施例１〜６
有効塩素濃度が、表１に示す濃度となるように、アルカリ性物質として次亜塩素酸ナトリウムを水に溶解させ、クモの巣除去用組成物を調製した。
Examples 1-6
A cobweb removing composition was prepared by dissolving sodium hypochlorite in water as an alkaline substance so that the effective chlorine concentration would be the concentration shown in Table 1.
実施例７〜９
さらに界面活性剤を添加した以外は、実施例３と同様にして、クモの巣除去用組成物を調製した。界面活性剤として、実施例７ではラウリルジメチルアミンオキシド（両性界面活性剤：アンヒトール20Ｎ、花王(株)製）を、実施例８ではポリオキシエチレンラウリルエーテル（非イオン界面活性剤：エマルゲン106、花王(株)製）を、実施例９ではポリオキシエチレンラウリルエーテル硫酸ナトリウム（陰イオン性界面活性剤：エマール327、花王(株)製）を、それぞれ2.0重量％となるように添加した。
Examples 7-9
Further, a cobweb removing composition was prepared in the same manner as in Example 3 except that a surfactant was added. As the surfactant, lauryl dimethylamine oxide (amphoteric surfactant: Amphital 20N, manufactured by Kao Corporation) was used in Example 7, and polyoxyethylene lauryl ether (nonionic surfactant: Emulgen 106, Kao) was used in Example 8. In Example 9, sodium polyoxyethylene lauryl ether sulfate (anionic surfactant: EMAL 327, manufactured by Kao Corporation) was added at 2.0% by weight.
実施例１０
アルカリ性物質として、水酸化ナトリウムを用いて、水酸化ナトリウム10重量％水溶液を調製し、クモの巣除去用組成物とした。
Example 10
Using sodium hydroxide as an alkaline substance, a 10% by weight aqueous solution of sodium hydroxide was prepared as a cobweb removing composition.
比較例１及び２
酸性物質として、比較例１では硫酸を、比較例２では塩酸を用い、それぞれの10重量％水溶液を調製して、クモの巣除去用組成物とした。
Comparative Examples 1 and 2
As acidic substances, sulfuric acid was used in Comparative Example 1 and hydrochloric acid was used in Comparative Example 2, and 10% by weight aqueous solutions of each were prepared to obtain a spider web removing composition.
比較例３及び４
アルカリ性物質の代わりに市販のタンパク質加水分解酵素として、比較例３ではパパイン（和光純薬工業社製）、比較例４ではブロメライン（和光純薬工業社製）を用い、それぞれの1重量％水溶液を調製して、クモの巣除去用組成物とした。
Comparative Examples 3 and 4
As a commercially available protein hydrolase in place of the alkaline substance, papain (manufactured by Wako Pure Chemical Industries, Ltd.) is used in Comparative Example 3, and bromelain (manufactured by Wako Pure Chemical Industries, Ltd.) is used in Comparative Example 4, and each 1% by weight aqueous solution is used. A spider web removing composition was prepared.
試験例
実施例１〜１０及び比較例１〜４のクモの巣除去用組成物をスプレーボトルに移し、噴霧量約1.5ｇ/回、かつ噴霧粒子径範囲50〜150μｍ（実施例７においては泡状）のスプレートリガーを用いクモの巣の糸全体がまんべんなく濡れる程度に10回程度噴霧してクモの巣の溶解度を観察し、クモの巣が完全に崩落するまでに要した時間を測定した。結果を表１及び２に示す。
Test Example The composition for removing cobwebs of Examples 1 to 10 and Comparative Examples 1 to 4 was transferred to a spray bottle, the spray amount was about 1.5 g / time, and the spray particle size range was 50 to 150 μm (in the form of foam in Example 7). A spray trigger was used to spray the spider web about 10 times so that the entire spider web was evenly wet. The solubility of the spider web was observed, and the time required for the spider web to completely collapse was measured. The results are shown in Tables 1 and 2.
以上の結果より、アルカリ性物質を含有する実施例１〜１０のクモの巣除去用組成物は、噴霧するだけでクモの巣を容易に溶解除去し得ることが分かる。さらに、実施例３と実施例７〜９との比較により、アルカリ性物質の他に界面活性剤を添加することでクモの巣への付着性及び反応性が上昇し、クモの巣の溶解性が向上することが分かる。これに対し、酸性物質を含有する比較例１、２やタンパク質分解酵素を含有する比較例３、４の組成物では、クモの巣を溶解することはできないことが分かる。 From the above results, it can be seen that the cobweb removing compositions of Examples 1 to 10 containing an alkaline substance can easily dissolve and remove the cobweb by spraying. Furthermore, by comparing Example 3 with Examples 7 to 9, the addition of a surfactant in addition to the alkaline substance increases adhesion and reactivity to the web and improves the solubility of the web. I understand. In contrast, the compositions of Comparative Examples 1 and 2 containing an acidic substance and Comparative Examples 3 and 4 containing a proteolytic enzyme show that the web cannot be dissolved.
本発明のクモの巣除去用組成物、該組成物を含有するスプレー剤、及び該組成物を用いたクモの巣除去方法は、家屋やその玄関、窓枠、軒下、壁面、門灯、店舗や工場の出入口、屋外外灯、自動販売機、商業施設のネオン、樹木の間などに張られたクモの巣の除去に好適に使用することができる。 The composition for removing a spider web of the present invention, a spray containing the composition, and a spider web removing method using the composition include a house and its entrance, a window frame, an eaves, a wall surface, a gate lamp, an entrance of a store or factory, It can be suitably used for the removal of cobwebs stretched between outdoor outdoor lights, vending machines, neon lights in commercial facilities, and between trees.
Claims (5)
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| JP2007321797A JP4976268B2 (en) | 2007-12-13 | 2007-12-13 | Cobweb removal composition |
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|---|---|---|---|
| JP2007321797A JP4976268B2 (en) | 2007-12-13 | 2007-12-13 | Cobweb removal composition |
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| JP4976268B2 true JP4976268B2 (en) | 2012-07-18 |
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| JP4741780B2 (en) * | 2001-08-31 | 2011-08-10 | ライオン株式会社 | Resin foam aerosol for capturing insects, and method for capturing and killing insects using the resin foam aerosol |
| JP4754472B2 (en) * | 2006-12-28 | 2011-08-24 | アース製薬株式会社 | Spider nesting prevention aerosol agent and spider nesting prevention method |
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