JP4976129B2 - ポリオレフィン用チーグラー・ナッタ触媒 - Google Patents

ポリオレフィン用チーグラー・ナッタ触媒 Download PDF

Info

Publication number
JP4976129B2
JP4976129B2 JP2006526927A JP2006526927A JP4976129B2 JP 4976129 B2 JP4976129 B2 JP 4976129B2 JP 2006526927 A JP2006526927 A JP 2006526927A JP 2006526927 A JP2006526927 A JP 2006526927A JP 4976129 B2 JP4976129 B2 JP 4976129B2
Authority
JP
Japan
Prior art keywords
catalyst
reaction product
titanium
carbon atoms
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2006526927A
Other languages
English (en)
Japanese (ja)
Other versions
JP2007505970A (ja
Inventor
ノーペル，デイビツド・ダブリユー
コフイ，テイム・ジエイ
エンリケズ，ヘンリー
グレイ，ステイーブン
ビジニ，カヨ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/667,578 external-priority patent/US6930071B2/en
Priority claimed from US10/667,546 external-priority patent/US6864207B2/en
Priority claimed from US10/685,643 external-priority patent/US20050085601A1/en
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of JP2007505970A publication Critical patent/JP2007505970A/ja
Application granted granted Critical
Publication of JP4976129B2 publication Critical patent/JP4976129B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/32—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2006526927A 2003-09-22 2004-09-07 ポリオレフィン用チーグラー・ナッタ触媒 Expired - Fee Related JP4976129B2 (ja)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US10/667,546 2003-09-22
US10/667,578 US6930071B2 (en) 1997-01-28 2003-09-22 Ziegler-natta catalyst for polyolefins
US10/667,546 US6864207B2 (en) 1997-01-28 2003-09-22 Ziegler-Natta catalyst for polyolefins
US10/667,578 2003-09-22
US10/685,643 2003-10-15
US10/685,643 US20050085601A1 (en) 2003-10-15 2003-10-15 Process for forming Ziegler-Natta catalyst for use in polyolefin production
PCT/US2004/029019 WO2005032714A1 (en) 2003-09-22 2004-09-07 Ziegler-natta catalyst for polyolefins

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2011091094A Division JP2011157561A (ja) 2003-09-22 2011-04-15 ポリオレフィン用チーグラー・ナッタ触媒

Publications (2)

Publication Number Publication Date
JP2007505970A JP2007505970A (ja) 2007-03-15
JP4976129B2 true JP4976129B2 (ja) 2012-07-18

Family

ID=34426928

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006526927A Expired - Fee Related JP4976129B2 (ja) 2003-09-22 2004-09-07 ポリオレフィン用チーグラー・ナッタ触媒

Country Status (8)

Country Link
EP (1) EP1673166A4 (de)
JP (1) JP4976129B2 (de)
KR (1) KR20060126929A (de)
BR (1) BRPI0414649A (de)
CA (1) CA2536804A1 (de)
MX (1) MXPA06003170A (de)
TW (1) TW200528190A (de)
WO (1) WO2005032714A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1860126A1 (de) * 2006-05-26 2007-11-28 INEOS Manufacturing Belgium NV Polyolefinpulver
EP2032612A1 (de) * 2006-06-23 2009-03-11 Basell Poliolefine Italia S.r.l. Katalysatorvorläufer auf magnesiumchloroalkolat-basis
US7473664B2 (en) * 2006-06-23 2009-01-06 Fina Technology, Inc. Formation of Ziegler-Natta catalyst
US20080051535A1 (en) * 2006-08-23 2008-02-28 Fina Technology, Inc. Promoter system for polymerization processes and polymers formed therefrom
US8063159B2 (en) * 2007-07-16 2011-11-22 Fina Technology, Inc Process for controlling morphology of Ziegler-Natta catalysts
US7655590B2 (en) * 2007-12-20 2010-02-02 Fina Technology, Inc. Ziegler-Natta catalyst for particle size control
US7786237B2 (en) * 2008-02-01 2010-08-31 Fina Technology, Inc. Polyethylene materials prepared using mixed ziegler-natta catalysts systems
US8003741B2 (en) * 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
US10351640B2 (en) * 2010-04-22 2019-07-16 Fina Technology, Inc. Formation of Ziegler-Natta catalyst using non-blended components
US9650448B2 (en) * 2014-06-13 2017-05-16 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
EP3074464B1 (de) 2014-07-10 2017-04-19 Total Research & Technology Feluy Verfahren zur herstellung einer hochdichten polyethylenzusammensetzung mit hoher spannungsrissbeständigkeit aus post-consumer-kunststoff und aus einer solchen zusammensetzung hergestellte gegenstände

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4914069A (en) * 1987-05-04 1990-04-03 Shell Oil Company Preparation of olefin polymerization catalyst component
JP2598287B2 (ja) * 1988-01-20 1997-04-09 東邦チタニウム株式会社 オレフイン類重合用固体触媒成分及び触媒
GB8820357D0 (en) * 1988-08-26 1988-09-28 Shell Int Research Solid alkene polymerization catalyst components & process for their preparation
JPH0565311A (ja) * 1991-09-05 1993-03-19 Toho Titanium Co Ltd オレフイン類重合用触媒
US5817591A (en) * 1995-06-07 1998-10-06 Fina Technology, Inc. Polyolefin catalyst from metal alkoxides or dialkyls, production and use
US6486274B1 (en) * 1997-01-28 2002-11-26 Fina Technology, Inc. Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith
US6930071B2 (en) * 1997-01-28 2005-08-16 Fina Technology, Inc. Ziegler-natta catalyst for polyolefins
US6174971B1 (en) * 1997-01-28 2001-01-16 Fina Technology, Inc. Ziegler-natta catalysts for olefin polymerization
EP1308465A1 (de) * 2001-11-06 2003-05-07 Fina Technology, Inc. Ziegler-Natta Katalysator mit verbesserter Wasserstoffempfindlichkeit zur Einschränkung der MWD eines Polyolefins, Verfahren zur seiner Herstellung, Olefinpolymerisationsverfahren unter Verwendung desselben und daraus hergestellte Polyolefine
JP2003155305A (ja) * 2001-11-21 2003-05-27 Fina Technol Inc ポリオレフィンのｍｗｄを狭くするための改善された水素応答チーグラー−ナッタ触媒、その製造方法、使用方法、及びそれを用いて製造されたポリオレフィン
US20050085601A1 (en) * 2003-10-15 2005-04-21 Kayo Vizzini Process for forming Ziegler-Natta catalyst for use in polyolefin production

Also Published As

Publication number Publication date
EP1673166A1 (de) 2006-06-28
TW200528190A (en) 2005-09-01
CA2536804A1 (en) 2005-04-14
KR20060126929A (ko) 2006-12-11
WO2005032714A1 (en) 2005-04-14
MXPA06003170A (es) 2006-06-05
BRPI0414649A (pt) 2006-11-14
JP2007505970A (ja) 2007-03-15
EP1673166A4 (de) 2009-06-17

Similar Documents

Publication Publication Date Title
US6930071B2 (en) Ziegler-natta catalyst for polyolefins
US6864207B2 (en) Ziegler-Natta catalyst for polyolefins
JP2011157561A (ja) ポリオレフィン用チーグラー・ナッタ触媒
US6486274B1 (en) Hydrogen response Ziegler-Natta catalyst for narrowing MWD of polyolefin, method of making, method of using, and polyolefins made therewith
US6734134B1 (en) Ziegler-natta catalyst for tuning MWD of polyolefin, method of making, method of using, and polyolefins made therewith
US6693058B1 (en) Ziegler-natta catalyst for narrow to broad MWD of polyoefins, method of making, method of using, and polyolefins made therewith
JP4976129B2 (ja) ポリオレフィン用チーグラー・ナッタ触媒
CN109843945B (zh) 用于烯烃聚合的主催化剂
US20090143549A1 (en) Catalyst Components for the Polymerization of Olefins
US20120064268A1 (en) Process for Controlling Morphology of Ziegler-Natta Catalysts
US20070004876A1 (en) Cocatalysts for olefin polymerizations
JP4001477B2 (ja) ポリオレフィンのｍｗｄを調整するチーグラー・ナッタ触媒、製造方法、使用方法そしてそれを用いて製造したポリオレフィン
RU2356911C1 (ru) Способ получения полиэтилена и сополимеров этилена с альфа-олефинами с широким молекулярно-массовым распределением
US7468339B2 (en) Diketonate complex-derived catalysts useful for preparing polyolefins
JP2003155305A (ja) ポリオレフィンのｍｗｄを狭くするための改善された水素応答チーグラー−ナッタ触媒、その製造方法、使用方法、及びそれを用いて製造されたポリオレフィン
KR100851032B1 (ko) 폴리올레핀의 분자량 분포를 좁히기 위한 향상된 수소반응지글러-나타 촉매, 이것의 제조방법, 사용방법 및이것으로 제조된 폴리올레핀
EP1306394B1 (de) Ziegler-Natta-Katalysator für Polyolefine mit engen bis breiten Molekulargewichtsverteilung, Herstellungsverfahren, Verwendungsverfahren; und damit hergestellte Polyolefine
JP2003147012A (ja) 狭いｍｗｄから広いｍｗｄのポリオレフィンを製造するためのチーグラー・ナッタ触媒、製造方法、使用方法そしてそれを用いて製造したポリオレフィン
CA2485168A1 (en) Mixed catalyst compositions for the production of polyolefins
EA040081B1 (ru) Способ получения прокатализатора для полимеризации олефинов
CN1418894A (zh) 聚烯烃催化剂、其制造方法、使用方法、及由其制得的聚合物
EP1308465A1 (de) Ziegler-Natta Katalysator mit verbesserter Wasserstoffempfindlichkeit zur Einschränkung der MWD eines Polyolefins, Verfahren zur seiner Herstellung, Olefinpolymerisationsverfahren unter Verwendung desselben und daraus hergestellte Polyolefine
CN1418893A (zh) 聚烯烃催化剂、其制造方法、使用方法和由该催化剂制得的聚合物

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070903

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20071009

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20071012

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100218

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110118

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110415

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110517

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110810

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110818

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110914

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110922

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111017

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20111115

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111116

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120110

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120111

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120410

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120412

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150420

Year of fee payment: 3

LAPS Cancellation because of no payment of annual fees