JP4972078B2 - Acid oil-in-water emulsified food and method for producing the same - Google Patents

Acid oil-in-water emulsified food and method for producing the same Download PDF

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JP4972078B2
JP4972078B2 JP2008335627A JP2008335627A JP4972078B2 JP 4972078 B2 JP4972078 B2 JP 4972078B2 JP 2008335627 A JP2008335627 A JP 2008335627A JP 2008335627 A JP2008335627 A JP 2008335627A JP 4972078 B2 JP4972078 B2 JP 4972078B2
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聡 寺岡
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本発明は、食品に塗布し焼成した後の食品からの剥れと保存時の油分離を抑えた酸性水中油型乳化食品およびその製造方法に関する。 TECHNICAL FIELD The present invention relates to an acidic oil-in-water emulsified food that suppresses peeling from food after being applied to food and baked and oil separation during storage, and a method for producing the same.

酸性水中油型乳化食品とは、pHを4.6以下にすることで常温流通を可能にした乳化食品であり、代表的なものとして、マヨネーズ様食品などの半固体状ドレッシング、乳化液状ドレッシングなどが挙げられる。 Acidic oil-in-water emulsified foods are emulsified foods that can be distributed at room temperature by adjusting the pH to 4.6 or lower. Typical examples include semi-solid dressings such as mayonnaise-like foods, and emulsified liquid dressings. Is mentioned.

マヨネーズなどの酸性水中油型乳化食品は、サラダにかける、または野菜と和えるなどの用途が一般的であるが、近年その用途が拡大している。特に、パンとの相性は良く、ソーセージやコーンと一緒にマヨネーズをのせて焼成したパン、マヨネーズと野菜を挟んだサンドイッチなど、パンのメニュー拡充のためには欠かせない調味料となっている。 Acidic oil-in-water emulsified foods such as mayonnaise are commonly used in salads or with vegetables, but in recent years their use has expanded. In particular, it has good compatibility with bread and is a seasoning essential for expanding bread menus, such as bread baked with mayonnaise with sausage and corn, and sandwiches with mayonnaise and vegetables.

しかしながら、従来のマヨネーズは、パンなどの食品に塗布し焼成した際、マヨネーズが分離し、マヨネーズの存在感が薄れるという問題があった。これらの問題を解決するため、少なくとも乳清蛋白質と卵白とを含む乳化剤を使用し、それぞれの配合量を特定範囲に規定した、耐熱性を有した水中油型乳化食品の製造方法が知られている(特許文献1)しかしながら、これらの水中油型乳化食品は、パンに塗布し焼成した際、分離はしないものの、水中油型乳化食品がパンから剥れやすいとの問題があった。 However, the conventional mayonnaise has a problem that when it is applied to a food such as bread and baked, the mayonnaise is separated and the presence of the mayonnaise is reduced. In order to solve these problems, there is known a method for producing a heat-resistant oil-in-water-type emulsified food that uses at least an emulsifier containing whey protein and egg white, and defines the respective blending amounts within a specific range. However, although these oil-in-water emulsified foods are not separated when applied to bread and baked, the oil-in-water emulsified foods have a problem that they are easily peeled off from the bread.

また、パン等と共に焼成する酸性水中油型乳化食品として、食用油脂、卵黄、卵白、醸造酢、調味料等を主材とするマヨネーズ原料に、α化されていない小麦粉を添加し、攪拌して均一に混合したパン等と共に焼成するトッピング材が知られている(特許文献2)。しかしながら、これらのトッピング材は、パンに塗布し焼成した際、保存により油分離を起こしやすいとの問題があった。 In addition, as an acidic oil-in-water emulsified food that is baked with bread, etc., add non-alphanated flour to the mayonnaise raw material mainly composed of edible oil and fat, egg yolk, egg white, brewed vinegar, seasoning, etc., and stir A topping material that is baked with a uniformly mixed bread or the like is known (Patent Document 2). However, these topping materials have a problem that when they are applied to bread and baked, oil separation tends to occur due to storage.

特開平11−318354号公報Japanese Patent Laid-Open No. 11-318354 特開2001−204375号公報JP 2001-204375 A

そこで、本発明の目的は、酸性水中油型乳化食品において、食品に塗布し焼成した後の食品からの剥れと保存時の油分離を抑えた酸性水中油型乳化食品およびその製造方法を提供するものである。 Accordingly, an object of the present invention is to provide an acidic oil-in-water emulsified food in which the oil-in-water emulsified food is applied to the food and baked after being baked, and the oil separation during storage is suppressed. To do.

本発明者等は、上記目的を達成すべく酸性水中油型乳化食品に使用されている様々な配合原料、及び製造工程について鋭意研究を重ねた。その結果、澱粉、およびゼラチンを配合し、当該澱粉が非糊化状態で分散されてなる酸性水中油型乳化食品は、意外にも食品に塗布し焼成した後の食品からの剥れと保存時の油分離が抑えられることを見出し本発明を完成するに至った。 In order to achieve the above object, the present inventors have conducted extensive research on various blended raw materials used in acidic oil-in-water emulsified foods and production processes. As a result, acidic oil-in-water emulsified foods that contain starch and gelatin and in which the starch is dispersed in a non-gelatinized state are unexpectedly applied to foods and baked after being baked and stored. As a result, the present invention was completed.

すなわち、本発明は、
(1)澱粉0.3〜2%、および加熱溶解性を有するゼラチン0.3〜3%を含有する酸性水中油型乳化食品であって、前記澱粉が非糊化状態で分散されてなり、前記ゼラチンが非溶解状態で分散されてなる酸性水中油型乳化食品、
(2)澱粉0.3〜2%、および加熱溶解性を有するゼラチン0.3〜3%を含有する酸性水中油型乳化食品の製造方法であって、製造工程において前記澱粉およびゼラチンを60℃以上の温度で加熱することなく製造し、前記澱粉が非糊化状態で分散されてなり、前記ゼラチンが非溶解状態で分散されてなる酸性水中油型乳化食品の製造方法、
である。
That is, the present invention
(1) starch 0.3 to 2%, and an acidic oil-in-water emulsified food containing 0.3 to 3% gelatin with a heating solubility, wherein the starch is dispersed in a non-gelatinized state, Acidic oil-in-water emulsified food in which the gelatin is dispersed in a non-dissolved state ,
(2) starch 0.3 to 2%, and a process for the preparation of acidic oil-in-water emulsified food containing 0.3 to 3% gelatin with a heating solubility, 60 ° C. the starch and gelatin in the manufacturing process A method for producing an acidic oil-in-water emulsified food produced by heating without heating at the above temperature, wherein the starch is dispersed in a non-gelatinized state, and the gelatin is dispersed in a non-dissolved state ,
It is.

本発明によれば、酸性水中油型乳化食品において、食品に塗布し焼成した後の食品からの剥れと保存時の油分離を抑えた酸性水中油型乳化食品およびその製造方法を提供することが出来る。したがって、酸性水中油型乳化食品を焼成して使用するパンなどの食品において、酸性水中油型乳化食品の剥れによる商品価値の低下を防ぐことができ、酸性水中油型乳化食品の更なる需要拡大が期待できる。 According to the present invention, in an acidic oil-in-water emulsified food, an acidic oil-in-water emulsified food that suppresses peeling from the food after application and baking to the food and oil separation during storage and a method for producing the same are provided. I can do it. Therefore, in foods such as breads that are used by baking acid oil-in-water emulsified foods, it is possible to prevent reduction in commercial value due to peeling of acid oil-in-water emulsified foods, and further demand for acid oil-in-water emulsified foods Expansion can be expected.

以下本発明を詳細に説明する。なお、本発明において「%」は「質量%」を意味する。 The present invention will be described in detail below. In the present invention, “%” means “mass%”.

本発明において酸性水中油型乳化食品とは、食用油脂が油滴として水相中に略均一に分散して水中油型の乳化状態が維持され、pHを4.6以下に調整した酸性乳化食品である。例えば、マヨネーズ様食品、酸性乳化液状ドレッシング、具材入り酸性乳化液状食品などが挙げられる。 In the present invention, the acidic oil-in-water emulsified food is an acid emulsified food in which edible fats and oils are dispersed substantially uniformly in the water phase as oil droplets to maintain an oil-in-water emulsified state and the pH is adjusted to 4.6 or less. It is. Examples include mayonnaise-like foods, acidic emulsified liquid dressings, and acidic emulsified liquid foods with ingredients.

本発明の酸性水中油型乳化食品は、澱粉を含有し、当該澱粉が非糊化状態で分散されてなることを特徴とし、これにより酸性水中油型乳化食品は、食品に塗布し焼成した後の食品からの剥れが抑えられたものとなる。一方、あらかじめ糊化した澱粉を用いた酸性水中油型乳化食品、または、非糊化状態の澱粉を用いた場合であっても、加熱により澱粉が糊化した状態で分散されてなる酸性水中油型乳化食品は、食品に塗布し焼成した際、食品から剥れやすいものとなるためである。 The acidic oil-in-water emulsified food of the present invention contains starch, and the starch is dispersed in a non-gelatinized state, whereby the acidic oil-in-water emulsified food is applied to the food and baked. Peeling from food is suppressed. On the other hand, acidic oil-in-water emulsified foods using starch that has been gelatinized in advance, or acidic oil-in-water, in which starch is gelatinized by heating even when non-gelatinized starch is used This is because the mold-emulsified food is easily peeled off from the food when applied to the food and baked.

本発明で用いる澱粉としては、食用として供されるものであれば特に限定するものではないが、例えば、市販の馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、小麦澱粉、米澱粉、これらの澱粉を架橋などの処理を施した加工澱粉、澱粉分解物などが挙げられ、本発明ではこれらの1種または2種以上を用いるとよい。 The starch used in the present invention is not particularly limited as long as it is provided for edible use. For example, commercially available potato starch, corn starch, tapioca starch, wheat starch, rice starch, cross-linking these starches, etc. The processed starch, the starch decomposition product, etc. which performed the process are mentioned, In this invention, it is good to use these 1 type (s) or 2 or more types.

また、本発明において非糊化状態とは、澱粉の一部または全部が糊化していない状態のことをいい、この状態の澱粉が略均一に分散していることをいう。このように澱粉を非糊化状態で略均一に分散させるためには、酸性水中油型乳化食品の製造工程において、澱粉を60℃以上の温度で加熱することなく製造することが必要となる。 In the present invention, the non-gelatinized state means a state in which part or all of the starch is not gelatinized, and the starch in this state is dispersed substantially uniformly. Thus, in order to disperse starch substantially uniformly in a non-gelatinized state, it is necessary to produce starch without heating it at a temperature of 60 ° C. or higher in the production process of an acidic oil-in-water emulsified food.

本発明の酸性水中油型乳化食品は、前述した澱粉に加え、ゼラチンを使用することを特徴とする。これにより酸性水中油型乳化食品は、食品に塗布し焼成した後の食品からの剥れと保存時の油分離が抑えられたものとなる。 The acidic oil-in-water emulsified food of the present invention is characterized by using gelatin in addition to the above-mentioned starch. As a result, the acidic oil-in-water emulsified food is one in which peeling from the food after application and baking on the food and oil separation during storage are suppressed.

ゼラチンは、動物の皮膚や骨などの結合組織の主成分であるコラーゲンを加熱し、抽出したものであり、蛋白質を主成分とする混合物ある。本発明で用いるゼラチンとしては、食用として供されるものであれば特に限定するものではないが、例えば、市販のブタゼラチン、ウシゼラチン、または魚ゼラチンなどが挙げられ、本発明ではこれらの1種または2種以上を用いるとよい。 Gelatin is a mixture obtained by heating and extracting collagen, which is the main component of connective tissue such as animal skin and bone, and is a mixture containing protein as the main component. The gelatin used in the present invention is not particularly limited as long as it is provided for edible use, and examples thereof include commercially available porcine gelatin, bovine gelatin, fish gelatin and the like. Or it is good to use 2 or more types.

また、本発明の酸性水中油型乳化食品に配合されるゼラチンは加熱溶解性を有するものであることが好ましい。常温溶解性のゼラチンを用いた酸性水中油型乳化食品に比べ、焼成時の剥れ防止効果と保存時の油分離抑制効果が得られ易いためである。本発明において加熱溶解性のゼラチンとは、常温(15〜25℃)で水と混同攪拌しても、その一部または全部が溶解しない性質を有するゼラチンのことをいい、当該性質を有するものであれば特に限定するものではない。具体的には、溶解温度が40℃以下に規定されている常温溶解性のゼラチン以外のゼラチンを用いればよい。 Moreover, it is preferable that the gelatin mix | blended with the acidic oil-in-water type emulsion foodstuff of this invention has a heat solubility. This is because, compared to acidic oil-in-water emulsified foods using gelatin that is soluble at room temperature, it is easy to obtain a peeling prevention effect during baking and an oil separation inhibiting effect during storage. In the present invention, heat-soluble gelatin refers to gelatin having a property that even if mixed with water at room temperature (15 to 25 ° C.) and stirred, it does not dissolve in part or all. If there is no particular limitation. Specifically, gelatin other than normal temperature soluble gelatin having a melting temperature of 40 ° C. or lower may be used.

さらに、本発明の酸性水中油型乳化食品に配合されるゼラチンは非溶解状態で分散されてなることが好ましい。加熱溶解性のゼラチンを加熱により溶解して用いた酸性水中油型乳化食品は、焼成時の剥れ防止効果と保存時の油分離抑制効果が得難い傾向となるためである。本発明において非溶解状態とは、ゼラチンの一部または全部が水に溶解せず、この状態のゼラチンが酸性水中油型乳化食品中に略均一に分散していることをいう。このように加熱溶解性を有するゼラチンを非溶解状態で略均一に分散させるためには、酸性水中油型乳化食品の製造工程において、ゼラチンを60℃以上の温度で加熱することなく製造することが必要となる。 Furthermore, the gelatin blended in the acidic oil-in-water emulsified food of the present invention is preferably dispersed in an undissolved state. This is because acidic oil-in-water emulsified foods obtained by dissolving heat-soluble gelatin by heating tend to have difficulty in obtaining an effect of preventing peeling during baking and an effect of suppressing oil separation during storage. In the present invention, the non-dissolved state means that part or all of gelatin is not dissolved in water, and gelatin in this state is dispersed substantially uniformly in the acidic oil-in-water emulsion food. Thus, in order to disperse gelatin having heat solubility substantially uniformly in an undissolved state, it is possible to produce gelatin without heating at a temperature of 60 ° C. or higher in the production process of acidic oil-in-water emulsion foods. Necessary.

酸性水中油型乳化食品に対する澱粉の含有量は、製品に対し0.1〜3%が好ましく、0.3〜3%がより好ましい。澱粉の含有量が、前記値より少ないと、たとえゼラチンを併用したとしても、酸性水中油型乳化食品の焼成後の剥れ防止効果が得難い傾向となり好ましくない。また、澱粉の含有量が前記値より多くても、含有量に応じた効果が期待し難く経済的でない。 The starch content in the acidic oil-in-water emulsified food is preferably 0.1 to 3%, more preferably 0.3 to 3%, based on the product. If the starch content is less than the above value, even if gelatin is used in combination, the effect of preventing peeling after baking of the acidic oil-in-water emulsified food tends to be difficult to obtain. Moreover, even if the content of starch is larger than the above value, it is difficult to expect an effect according to the content, which is not economical.

酸性水中油型乳化食品に対するゼラチンの含有量は、製品に対し0.1〜3%が好ましく、0.3〜3%がより好ましい。ゼラチンの含有量が、前記値より少ないと、たとえ前述した澱粉を併用したとしても、酸性水中油型乳化食品の焼成後の剥れ防止効果、および保存時の油分離抑制効果が得難い傾向となり好ましくない。また、ゼラチンの含有量が前記値より多くても、含有量に応じた効果が期待し難く経済的でない。 The content of gelatin in the acidic oil-in-water emulsified food is preferably 0.1 to 3%, more preferably 0.3 to 3%, based on the product. If the gelatin content is less than the above value, even if the above-mentioned starch is used in combination, it tends to be difficult to obtain a peeling prevention effect after baking of an acidic oil-in-water emulsified food and an oil separation suppressing effect during storage. Absent. Moreover, even if the content of gelatin is larger than the above value, it is difficult to expect an effect according to the content, which is not economical.

本発明の酸性水中油型乳化食品の粘度は、本発明の焼成後の剥れ防止効果、および保存時の油分離抑制効果を奏し易いものとするため、品温5℃のときの測定値で、50〜500Pa・sが好ましく、100〜400Pa・sがより好ましい。なお、粘度は、BH形粘度計を用いローター:No.6、回転数:2rpmの条件で測定し、2回転後の示度により算出した値である。 The viscosity of the acidic oil-in-water emulsified food of the present invention is a measured value at a product temperature of 5 ° C. in order to facilitate the effect of preventing peeling after baking of the present invention and the effect of suppressing oil separation during storage. 50 to 500 Pa · s is preferable, and 100 to 400 Pa · s is more preferable. The viscosity was measured using a BH viscometer using a rotor No. 6. Rotational speed: Measured under the condition of 2 rpm, a value calculated from the reading after 2 revolutions.

本発明の酸性水中油型乳化食品は、上述の澱粉、ゼラチンを配合する他に、本発明の効果を損なわない範囲で酸性水中油型乳化食品に通常用いられている各種原料を適宜選択し含有させることができる。例えば、菜種油、コーン油、綿実油、サフラワー油、オリーブ油、紅花油、大豆油、パーム油、魚油、卵黄油などの動植物油及びこれらの精製油、並びにMCT(中鎖脂肪酸トリグリセリド)、ジグリセリドなどのように化学的あるいは酵素的処理を施して得られる油脂などの食用油脂、キサンタンガム、タマリンドシードガム、ローカストビーンガム、ジェランガム、グアーガム、アラビアガム、サイリュームシードガムなどのガム質、デキストリン、デキストリンアルコール、オリゴ糖、オリゴ糖アルコールなどの糖類、食酢、クエン酸、乳酸、レモン果汁などの酸味材、グルタミン酸ナトリウム、食塩、砂糖などの各種調味料、卵黄、全卵、液卵白、レシチン、リゾレシチン、ラクトアルブミン、カゼインナトリウム、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、オクテニルコハク酸化澱粉などの乳化材、アスコルビン酸又はその塩、ビタミンEなどの酸化防止剤、各種エキス、からし粉、胡椒などの香辛料、各種蛋白質やこれらの分解物、ダイス状のゆで卵、きゅうりのピクルス、タマネギ、パセリなどのみじん切りにした野菜などが挙げられる。 The acidic oil-in-water emulsified food of the present invention contains, in addition to the above-mentioned starch and gelatin, appropriately selected from various raw materials usually used in acidic oil-in-water emulsified foods as long as the effects of the present invention are not impaired. Can be made. For example, rapeseed oil, corn oil, cottonseed oil, safflower oil, olive oil, safflower oil, soybean oil, palm oil, fish oil, egg yolk oil and other animal and vegetable oils and refined oils thereof, and MCT (medium chain fatty acid triglyceride), diglyceride, etc. Edible fats and oils such as fats and oils obtained by chemical or enzymatic treatment, xanthan gum, tamarind seed gum, locust bean gum, gellan gum, guar gum, gum arabic, silium seed gum, gum quality, dextrin, dextrin alcohol, oligo Saccharides such as sugar, oligosaccharide alcohol, sour materials such as vinegar, citric acid, lactic acid, lemon juice, various seasonings such as sodium glutamate, salt, sugar, egg yolk, whole egg, liquid egg white, lecithin, lysolecithin, lactalbumin, Casein sodium, glycerin fat Emulsifiers such as esters, polyglycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, octenyl succinated starch, antioxidants such as ascorbic acid or salts thereof, various extracts, spices such as mustard powder, pepper, Various proteins and their degradation products, diced boiled eggs, pickled cucumbers, onions, parsley and other chopped vegetables.

本発明の酸性水中油型乳化食品の製造方法は、製造工程において澱粉、またはゼラチンを60℃以上の温度で加熱することなく、好ましくは50℃以上の温度で加熱することなく製造することを特徴とする。製造工程のいずれかの段階で澱粉、またはゼラチンが前記値よりも高い温度で加熱されると、澱粉が糊化状態に、またゼラチンが溶解状態になりやすくなるなり、酸性水中油型乳化食品の焼成後の剥れ防止効果、および保存時の油分離抑制効果が得難いためである。 The method for producing an acidic oil-in-water emulsified food according to the present invention is characterized in that starch or gelatin is not heated at a temperature of 60 ° C. or higher, preferably without heating at a temperature of 50 ° C. or higher in the manufacturing process. And When starch or gelatin is heated at a temperature higher than the above value at any stage of the production process, starch becomes gelatinized and gelatin is easily dissolved. This is because it is difficult to obtain an effect of preventing peeling after firing and an effect of suppressing oil separation during storage.

また、本発明の酸性水中油型乳化食品の製造方法は、上述の澱粉、およびゼラチンを配合し、製造工程において澱粉、またはゼラチンを60℃以上の温度で加熱することなく製造すること以外は、酸性水中油型乳化食品の常法に則り製造すればよく、例えば、上述の澱粉、及びゼラチンを含む水相原料を均一に混合し、ミキサー等で攪拌させながら、油相原料を注加して粗乳化し、次にコロイドミル、高圧ホモゲナイザーなどで仕上げ乳化をした後、ボトル容器やガラス容器などに充填密封する方法などにより製造すればよい。 Moreover, the method for producing an acidic oil-in-water emulsified food according to the present invention includes the above-described starch and gelatin, and in the production process, except that the starch or gelatin is produced without heating at a temperature of 60 ° C. or higher. What is necessary is just to manufacture according to the conventional method of acidic oil-in-water type emulsified food, for example, add the above-mentioned starch and the water phase raw material containing gelatin, and add the oil phase raw material while stirring with a mixer or the like. After rough emulsification and then final emulsification with a colloid mill, a high-pressure homogenizer, etc., it may be manufactured by a method of filling and sealing in a bottle container or a glass container.

以下、本発明の酸性水中油型乳化食品について、実施例、比較例、及び試験例に基づき具体的に説明する。なお、本発明は、これらに限定するものではない。 Hereinafter, the acidic oil-in-water emulsified food of the present invention will be specifically described based on Examples, Comparative Examples, and Test Examples. The present invention is not limited to these.

[実施例1]
<マヨネーズ様食品の製造方法>
下記に示す配合割合でマヨネーズ様食品を製した。つまり、食酢、生卵黄、食塩、澱粉、ゼラチン(加熱溶解性)、グルタミン酸ソーダ、清水をミキサーに入れ、攪拌混合し、水相部を調製した。次いで、水相部を攪拌しながら植物油を徐々に添加して粗乳化し、更に高速で攪拌して仕上げ乳化を施した。次に、得られた乳化物を容量300gの三層のラミネート容器に充填することにより本発明品のマヨネーズ様食品を製した。なお、得られたマヨネーズ様食品は、製品に対し澱粉を1%、ゼラチンを1%含有するものであり、澱粉が非糊化状態で分散されているものである。また、得られたマヨネーズ様食品の粘度は140Pa・sであった。
[Example 1]
<Production method of mayonnaise-like food>
A mayonnaise-like food was produced at the following blending ratio. That is, vinegar, raw egg yolk, salt, starch, gelatin (heat solubility), sodium glutamate, and fresh water were placed in a mixer and mixed with stirring to prepare an aqueous phase. Subsequently, vegetable oil was gradually added while stirring the aqueous phase and coarsely emulsified, and further stirred at a high speed for final emulsification. Next, the obtained emulsion was filled in a three-layer laminate container having a capacity of 300 g to produce a mayonnaise-like food of the present invention. The obtained mayonnaise-like food contains 1% starch and 1% gelatin in the product, and the starch is dispersed in a non-gelatinized state. Moreover, the viscosity of the obtained mayonnaise-like food was 140 Pa · s.

<マヨネーズ様食品の配合割合>
(油相)
植物油 40%
(水相)
食酢(酸度10%) 10%
生卵黄 10%
食塩 3%
澱粉 1%
ゼラチン(加熱溶解性) 1%
グルタミン酸ソーダ 0.3%
清水 残余
―――――――――――――――――――――――
合計 100%
<Mixed ratio of mayonnaise-like food>
(Oil phase)
40% vegetable oil
(Water phase)
Vinegar (acidity 10%) 10%
10% raw egg yolk
3% salt
1% starch
Gelatin (heat solubility) 1%
Sodium glutamate 0.3%
Shimizu Residue ―――――――――――――――――――――――
Total 100%

得られたマヨネーズ様食品を食パンに塗布し、オーブンで焼成(200℃、10分間)したところ、焼成後のマヨネーズ様食品はパンから剥れにくいものであった。また、得られたマヨネーズ様食品を冷蔵(5℃)で3ヶ月保存し、保存後のマヨネーズ様食品を目視で観察したところ、油分離は確認されなかった。 When the obtained mayonnaise-like food was applied to bread and baked in an oven (200 ° C., 10 minutes), the mayonnaise-like food after baking was hardly peeled from the bread. Moreover, when the obtained mayonnaise-like food was stored in a refrigerator (5 ° C.) for 3 months and the mayonnaise-like food after storage was visually observed, no oil separation was confirmed.

[比較例1]
実施例1のマヨネーズ様食品の調製において、配合原料の澱粉を糊化澱粉に置き換えた以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は210Pa・sであった。
[Comparative Example 1]
In the preparation of the mayonnaise-like food of Example 1, a mayonnaise-like food was produced in the same manner as in Example 1 except that the starch of the blending raw material was replaced with gelatinized starch. The obtained mayonnaise-like food had a viscosity of 210 Pa · s.

得られたマヨネーズ様食品を実施例1と同様の方法で焼成したところ、マヨネーズ様食品はパンから剥れやすかった。 When the obtained mayonnaise-like food was baked in the same manner as in Example 1, the mayonnaise-like food was easily peeled from the bread.

[比較例2]
実施例1のマヨネーズ様食品の調製において、澱粉と清水を混合し、60℃まで加熱することで、澱粉を十分に糊化させた後、他の水相原料を混合した以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は240Pa・sであった。
[Comparative Example 2]
In the preparation of the mayonnaise-like food of Example 1, starch and fresh water were mixed and heated to 60 ° C. to sufficiently gelatinize the starch, and then mixed with other aqueous phase ingredients as in Example 1. A mayonnaise-like food was produced in the same manner. The obtained mayonnaise-like food had a viscosity of 240 Pa · s.

得られたマヨネーズ様食品を実施例1と同様の方法で焼成したところ、マヨネーズ様食品はパンから剥れやすかった。 When the obtained mayonnaise-like food was baked in the same manner as in Example 1, the mayonnaise-like food was easily peeled from the bread.

[実施例2]
実施例1のマヨネーズ様食品の調製において、配合原料のゼラチン(加熱溶解性)をゼラチン(常温溶解性)に置き換えた以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は190Pa・sであった。
[Example 2]
In the preparation of the mayonnaise-like food of Example 1, a mayonnaise-like food was produced in the same manner as in Example 1 except that gelatin (heating solubility) as a raw material was replaced with gelatin (room temperature solubility). The obtained mayonnaise-like food had a viscosity of 190 Pa · s.

[実施例3]
実施例1のマヨネーズ様食品の調製において、調製した水相部を45℃まで加熱した後、水相部を攪拌しながら植物油を徐々に添加して粗乳化した以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は160Pa・sであった。
[Example 3]
In the preparation of the mayonnaise-like food of Example 1, the prepared aqueous phase part was heated to 45 ° C., and then the vegetable oil was gradually added while stirring the aqueous phase part, followed by rough emulsification. And made mayonnaise-like food. The obtained mayonnaise-like food had a viscosity of 160 Pa · s.

[実施例4]
実施例1のマヨネーズ様食品の調製において、調製した水相部を55℃まで加熱した後、水相部を攪拌しながら植物油を徐々に添加して粗乳化した以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は190Pa・sであった。
[Example 4]
In the preparation of mayonnaise-like food of Example 1, the prepared aqueous phase part was heated to 55 ° C, and then the vegetable oil was gradually added while stirring the aqueous phase part, followed by rough emulsification. And made mayonnaise-like food. The obtained mayonnaise-like food had a viscosity of 190 Pa · s.

[比較例3]
実施例1のマヨネーズ様食品の調製において、調製した水相部を60℃まで加熱した後、水相部を攪拌しながら植物油を徐々に添加して粗乳化した以外は実施例1と同様の方法でマヨネーズ様食品を製した。得られたマヨネーズ様食品の粘度は220Pa・sであった。
[Comparative Example 3]
In the preparation of mayonnaise-like food of Example 1, the prepared aqueous phase part was heated to 60 ° C., and then the vegetable oil was gradually added while stirring the aqueous phase part, followed by rough emulsification. And made mayonnaise-like food. The obtained mayonnaise-like food had a viscosity of 220 Pa · s.

[試験例1]
酸性水中油型乳化食品に用いるゼラチンの種類、及び酸性水中油型乳化食品の製造工程における加熱処理の有無、および加熱温度による、酸性水中油型乳化食品の焼成後の剥れやすさ、および保存時の油分離への影響を調べた。具体的には、実施例1乃至4、および比較例3で得られたマヨネーズ様食品を実施例1と同様の方法で焼成し、焼成後のマヨネーズ様食品の剥れやすさを下記の評価基準で評価した。また、得られたマヨネーズ様食品を15℃で3週間保存し、目視で観察することで、保存時のマヨネーズ様食品の油分離を下記の評価基準で評価した。なお、本発明において、15℃で1週間の保存は、冷蔵(5℃)で1ヶ月間の保存に相当する。
[Test Example 1]
The kind of gelatin used for acidic oil-in-water emulsion foods, the presence or absence of heat treatment in the production process of acidic oil-in-water emulsion foods, and the ease of peeling after baking of acidic oil-in-water emulsion foods depending on the heating temperature, and storage The influence of oil on oil separation was investigated. Specifically, the mayonnaise-like food obtained in Examples 1 to 4 and Comparative Example 3 was baked in the same manner as in Example 1, and the ease of peeling of the mayonnaise-like food after baking was evaluated according to the following evaluation criteria. It was evaluated with. Moreover, the obtained mayonnaise-like food was preserve | saved at 15 degreeC for 3 weeks, and the oil separation of the mayonnaise-like food at the time of preservation | save was evaluated by the following evaluation criteria by observing visually. In the present invention, storage for 1 week at 15 ° C. corresponds to storage for 1 month at refrigeration (5 ° C.).

「焼成後のマヨネーズ様食品の剥れやすさ」の評価
ランク:基準
○:マヨネーズ様食品がパンから剥れにくい。
△:マヨネーズ様食品がややパンから剥れやすいが問題のない程度である。
×:マヨネーズ様食品がパンから剥れやすい。
Evaluation rank of “Ease of peeling of mayonnaise-like food after baking”: Standard ○: Mayonnaise-like food is difficult to peel from bread.
Δ: The mayonnaise-like food is slightly peelable from the bread, but there is no problem.
X: Mayonnaise-like food is easy to peel off from bread.

「保存時のマヨネーズ様食品の油分離」の評価
ランク:基準
○:マヨネーズ様食品が油分離していない。
△:マヨネーズ様食品がやや油分離しているが問題のない程度である。
×:マヨネーズ様食品が油分離している。
Evaluation rank of “oil separation of mayonnaise-like food during storage”: Standard ○: Mayonnaise-like food is not oil-separated.
Δ: Mayonnaise-like food is slightly separated from oil, but there is no problem.
X: The mayonnaise-like food is oil-separated.

表1より、ゼラチン(加熱溶解性)に代えて、ゼラチン(常温溶解性)を用いたマヨネーズ様食品(実施例2)、およびマヨネーズ様食品の製造工程においてゼラチン(加熱溶解性)に55℃の加熱がされたマヨネーズ様食品(実施例4)は、焼成後のマヨネーズ様食品がやや剥れやすく、また、保存によって、やや油分離していた。また、ゼラチン(加熱溶解性)に60℃の加熱がされたマヨネーズ様食品(比較例3)は焼成後のマヨネーズ食品が剥れやすく、また、保存によって、油分離していた。このことにより、製造工程においてゼラチンを60℃以上の温度で加熱することなく製造された酸性水中油型乳化食品は、焼成後の剥れ防止効果、および保存時の油分離抑制効果に優れていることが理解される。また、加熱溶解性ゼラチンを用い、ゼラチンが非溶解状態で分散されてなる酸性水中油型乳化食品は、焼成後の剥れ防止効果、および保存時の油分離抑制効果により優れていることが理解される。 From Table 1, in place of gelatin (heat solubility), mayonnaise-like food (Example 2) using gelatin (room temperature solubility), and gelatin (heat solubility) in the production process of mayonnaise-like food was 55 ° C. In the heated mayonnaise-like food (Example 4), the mayonnaise-like food after baking was slightly peeled off, and the oil was slightly separated by storage. In addition, the mayonnaise-like food (Comparative Example 3) heated to 60 ° C. in gelatin (heat solubility) was easily peeled off after baking, and the oil was separated by storage. Thus, the acidic oil-in-water emulsified food produced without heating gelatin at a temperature of 60 ° C. or higher in the production process is excellent in the effect of preventing peeling after baking and the effect of suppressing oil separation during storage. It is understood. In addition, it is understood that acidic oil-in-water emulsified foods using gelatin that is heat-dissolved and dispersed in a non-dissolved state are superior in preventing peeling after baking and suppressing oil separation during storage. Is done.

[試験例2]
澱粉、およびゼラチンの含有量の違いによる、酸性水中油型乳化食品の焼成後の剥れやすさ、および保存時の油分離への影響を調べた。具体的には、実施例1において、澱粉、及びゼラチンの含有量を表3に示す割合に変更した以外は、実施例1と同様の方法でマヨネーズ様食品を製した。次いで、得られたマヨネーズ様食品を実施例1と同様の方法で焼成し、焼成後のマヨネーズ様食品の剥れやすさを評価した。また、得られたマヨネーズ様食品を15℃で3週間保存し、目視で観察することで、保存時のマヨネーズ様食品の油分離を評価した。なお、焼成後のマヨネーズ様食品の剥れやすさ、および保存時のマヨネーズ様食品の油分離の評価基準は試験例1と同様とする。
[Test Example 2]
The effects of starch and gelatin content on the ease of peeling after baking of acidic oil-in-water emulsified foods and the oil separation during storage were investigated. Specifically, a mayonnaise-like food was produced in the same manner as in Example 1 except that the contents of starch and gelatin were changed to the ratios shown in Table 3 in Example 1. Next, the obtained mayonnaise-like food was baked in the same manner as in Example 1, and the ease of peeling of the mayonnaise-like food after baking was evaluated. The obtained mayonnaise-like food was stored at 15 ° C. for 3 weeks and visually observed to evaluate oil separation of the mayonnaise-like food during storage. The ease of peeling of the mayonnaise-like food after baking and the evaluation criteria for oil separation of the mayonnaise-like food during storage are the same as in Test Example 1.

表2より、澱粉の含有量が、製品に対し0.1〜3%であり、かつゼラチンの含有量が、製品に対し0.1〜3%である酸性水中油型乳化食品(No.2〜4、No.7〜9)は、焼成後の剥れ防止効果、および保存時の油分離抑制効果において優れていることが理解され、特に、澱粉の含有量が、製品に対し0.3〜3%であり、かつゼラチンの含有量が、製品に対し0.3〜3%である酸性水中油型乳化食品(No.3、4、8、9)は、焼成後の剥れ防止効果、および保存時の油分離抑制効果において、より優れていることが理解される。 From Table 2, acidic oil-in-water emulsified food (No. 2) in which the starch content is 0.1 to 3% of the product and the gelatin content is 0.1 to 3% of the product. -4 and No. 7-9) are understood to be excellent in the effect of preventing peeling after firing and the effect of suppressing oil separation during storage, and in particular, the starch content is 0.3% of the product. The acidic oil-in-water emulsified food (No. 3, 4, 8, 9) having a gelatin content of 0.3 to 3% based on the product is effective in preventing peeling after baking. It is understood that the oil separation suppressing effect during storage is superior.

Claims (2)

澱粉0.3〜2%、および加熱溶解性を有するゼラチン0.3〜3%を含有する酸性水中油型乳化食品であって、前記澱粉が非糊化状態で分散されてなり、前記ゼラチンが非溶解状態で分散されてなることを特徴とする酸性水中油型乳化食品。 Starch 0.3 to 2%, and an acidic oil-in-water emulsified food containing 0.3 to 3% gelatin with a heating solubility, wherein the starch is dispersed in a non-gelatinized state, the gelatin An acidic oil-in-water emulsified food, characterized by being dispersed in a non-dissolved state . 澱粉0.3〜2%、および加熱溶解性を有するゼラチン0.3〜3%を含有する酸性水中油型乳化食品の製造方法であって、製造工程において前記澱粉およびゼラチンを60℃以上の温度で加熱することなく製造し、前記澱粉が非糊化状態で分散されてなり、前記ゼラチンが非溶解状態で分散されてなることを特徴とする酸性水中油型乳化食品の製造方法。 Starch 0.3 to 2%, and heating a process for the preparation of an acidic oil-in-water emulsified food containing 0.3 to 3% gelatin with solubility, the starch and temperatures above 60 ° C. Gelatin in the manufacturing process A method for producing an acidic oil-in-water emulsified food, wherein the starch is dispersed in a non-gelatinized state and the gelatin is dispersed in a non-dissolved state .
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