JP4899006B2 - Manufacturing method of high quality white scallops - Google Patents

Manufacturing method of high quality white scallops Download PDF

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JP4899006B2
JP4899006B2 JP2008162531A JP2008162531A JP4899006B2 JP 4899006 B2 JP4899006 B2 JP 4899006B2 JP 2008162531 A JP2008162531 A JP 2008162531A JP 2008162531 A JP2008162531 A JP 2008162531A JP 4899006 B2 JP4899006 B2 JP 4899006B2
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雅夫 山崎
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本発明は高品質ホタテ白干しの製造方法に関するものである。さらに詳しくは、製造中の褐変が少なく適度のアメ色を有し、かつ呈味成分を豊富に含む高品質ホタテ白干しの製造方法に関するものである。  The present invention relates to a method for producing high-quality scallop white dried. More specifically, the present invention relates to a method for producing a high-quality scallop white dried product that has little browning during production, has an appropriate candy color, and contains abundant taste components.

ホタテガイの貝柱を乾燥させた干し貝柱(「白干し」と称される)は、我が国において数少ない輸出水産加工品の一つである。このため、主要産地となっている北海道・青森地域の漁業ならびに水産加工業において重要な加工品となっている。この白干しは、水で戻して調味食材として使われているものの、その品質は製造中の褐変によって生じる外観の色と身割れの状況で評価されている。  Dried scallops (called “white dried”), which are dried scallop shells, are one of the few processed fishery products in Japan. For this reason, it is an important processed product in the fishery and fishery processing industries in Hokkaido and Aomori, which are the main production areas. Although this white dried product is reconstituted with water and used as a seasoning ingredient, its quality is evaluated based on the appearance color and cracking caused by browning during production.

従来のホタテ白干しの製造方法は、天日乾燥などの工程や製造期間が約40日を要すなど、改良の余地が多い。また、原料貝が生鮮貝に限定されているため、製造が漁期に限定され半年間と短期で、周年稼働がなされていない。昨今頻発する貝毒による不測の原料規制への対策は無い。これらの課題解決として、衛生的な短期間の製造方法の確立と冷凍原料の利用が必要であると考え、本発明者らは、食品分野では新しい加工技術である過熱水蒸気(SHS)による焙乾を適用し、白干しの高品質化を図り、製造期間の短縮と冷凍原料を使った製造を実現し、成果を得ている(下記特許文献1及び非特許文献1及び2参照)。  The conventional method for producing scallop dried white has much room for improvement, such as a process such as sun drying and a production period of about 40 days. In addition, since raw shellfish are limited to fresh shellfish, production is limited to the fishing season, and there are no half-year and short-term operations. There is no countermeasure against unexpected raw material regulations due to shellfish poisons that are frequently occurring recently. In order to solve these problems, it is necessary to establish a hygienic short-term production method and use frozen raw materials, and the present inventors have performed a drying process using superheated steam (SHS), which is a new processing technique in the food field. Is applied to improve the quality of dried white, achieve a shortened manufacturing period and manufacture using frozen raw materials (see Patent Document 1 and Non-Patent Documents 1 and 2 below).

従来の製造方法では、冷凍貝柱原料の場合、褐変が過度に進むため原料として不適当と言われていたが、上記の過熱水蒸気を用いる方法ではかえって製品の白色度が高くなりすぎ、適度なアメ色を出す工夫が課題となっている。  In the conventional manufacturing method, in the case of frozen scallop raw material, it was said that it was inappropriate as a raw material because browning progressed excessively, but the method using the above-mentioned superheated steam was rather high in whiteness of the product, and moderate candy Ingenuity to produce colors is an issue.

ホタテ白干しの褐変の機序は、アミノカルボニル反応であるといわれているが、詳細は明らかではないものの、熟練者の永年の経験と勘によって製品の色調が調整されてきた。ところが、最近は適切な経験と勘を具備する熟練者の高齢化と後継となる人材の不足が、技術の伝承という観点と高品質製品の継続的製造において問題となっている。このため、熟練者の永年の経験と勘に頼ることなく、過度の褐変がなくかつ適度のアメ色を有し呈味成分の含有率の高い白干し製品の製造技術が期待されている。  The mechanism of browning of scallops is said to be the aminocarbonyl reaction, but although the details are not clear, the color tone of the product has been adjusted by the experience and intuition of many years of experience. However, in recent years, the aging of skilled workers who have appropriate experience and intuition and the shortage of successors have become problems in terms of technology transfer and continuous production of high-quality products. For this reason, without relying on the experience and intuition of many years of skill, the manufacturing technology of the white dried product which is not excessive browning and has a moderate candy color and a high content rate of a taste component is anticipated.

特開2005−137340号公報  JP 2005-137340 A 西岡不二男・浅岡大介・山▲崎▼雅夫「過熱水蒸気を用いたホタテ白干し製品の高品質化」日本食品科学工学会誌 51.3 pp.167−171(2004)  Fujio Nishioka, Daisuke Asaoka, Yamasaki Masao “Improvement of quality of dried scallops using superheated steam” Journal of Japanese Society of Food Science and Technology 51.3 pp. 167-171 (2004) 山▲崎▼雅夫・西岡不二男「ホタテガイ白干し中のATP関連物質含量に及ぼす製造工程の冷凍・解凍処理の影響」日本食品科学工学会誌、52、10 pp.435−440(2005)  Yamazaki Sasaki Masao and Nishioka Fujio “Effects of Freezing and Thawing Processes on ATP-Related Substance Content in Scallop White Dried”, Journal of Japanese Society of Food Science and Technology, 52, 10 pp. 435-440 (2005)

したがって、本発明の目的は、熟練者の永年の経験と勘に頼ることなく、過度の褐変がなくかつ適度のアメ色を有し呈味成分(旨味成分ともいう)の含有率の高い白干し製品を短時間で製造する方法を提供することにある。さらに具体的には、ホタテ貝柱を過熱水蒸気(SHS)により焙乾した後、あん蒸をして白干しを製造するに当り、適度のアメ色を有し、呈味成分の含有率の高い高品質の白干し製品を短時間で製造する方法を提供することにある。  Therefore, the object of the present invention is to dry white with a high content of taste ingredients (also referred to as umami ingredients) without excessive browning and moderate candy color without relying on the experience and intuition of many years of experience. The object is to provide a method for producing a product in a short time. More specifically, after producing scallops with superheated steam (SHS) and then fumigating them to produce white dried, they have a moderate candy color and a high content of taste ingredients. It is to provide a method for producing a quality white dried product in a short time.

本発明者は上述の目的を達成すべく鋭意研究の結果、白干しに呈味成分を付与する方策として、呈味成分が付与された貝柱は、白干し製造において過度の褐変を引き起こす可能性があるが、過熱水蒸気(SHS)による焙乾と特定温湿度にコントロールされた条件下でのあん蒸を組み合わせることで、製造期間を7日間と従来の35日〜40日間より1/6〜1/5に短縮するとともに、好ましい色調と呈味をもつ製品を製造できることを見出し、本発明を完成した。さらに、焙乾に先立って二番煮を行う場合は、その温度を低くし処理時間を長くすると良いことを見出した。  As a result of diligent research to achieve the above-mentioned object, the present inventor has a possibility of causing excessive browning in white-dried production, as a measure for imparting a taste component to white-dried white shell. However, by combining roasting with superheated steam (SHS) and fumigation under conditions controlled to a specific temperature and humidity, the production period is 7 days, which is 1/6 to 1/1 than the conventional 35 to 40 days. The present invention was completed by finding that a product having a preferable color tone and taste can be produced while shortening to 5. Furthermore, when performing the second cooking prior to the drying, it was found that the temperature should be lowered and the treatment time should be lengthened.

かくして、本発明によれば、以下のような方法によって、上記目的が達成される。
(1)ホタテ貝柱を、焙乾工程を実施した後、あん蒸工程を実施することによって白干しを製造するに当り、上記焙乾工程を110〜250℃の過熱水蒸気により行うこと、及び、上記あん蒸工程を、少なくとも該工程の途中から温湿度条件が管理された雰囲気中で行うこと、を特徴とする高品質ホタテ白干しの製造方法。
(2)上記あん蒸工程において、処理雰囲気を、当初から10〜50℃でかつ20〜80%RHに調整することを特徴とする上記(1)に記載の高品質ホタテ白干しの製造方法。
(3)上記あん蒸工程において、当初は室温であん蒸を行い、開始から2〜7日後に、雰囲気を40〜70℃で20〜80%RHに調整することを特徴とする上記(1)又は(2)に記載の高品質ホタテ白干しの製造方法。
(4)ホタテ貝柱を焙乾工程に供する前に、40〜100℃で二番煮を行うことを特徴とする上記(1)〜(3)のいずれかに記載の高品質ホタテ白干しの製造方法。
(5)上記二番煮工程をNaCl濃度4〜15重量%、温度40〜95℃の塩水中で5〜120分間行うことを特徴とする上記(4)に記載の高品質ホタテ白干しの製造方法。
Thus, according to the present invention, the above object is achieved by the following method.
(1) When the white scallop is produced by carrying out the anomaly process after the roasting process is performed on the scallops, the roasting process is performed with superheated steam at 110 to 250 ° C., and A method for producing a high-quality scallop white-dried, characterized in that the fumigation step is performed in an atmosphere in which temperature and humidity conditions are controlled at least partway through the step.
(2) The method for producing high-quality scallop white dried as described in (1) above, wherein the treatment atmosphere is adjusted to 10 to 50 ° C. and 20 to 80% RH from the beginning in the fumigation step.
(3) In the above-mentioned fumigation step, fumigation is initially performed at room temperature, and after 2 to 7 days from the start, the atmosphere is adjusted to 20 to 80% RH at 40 to 70 ° C. (1) Or the manufacturing method of the high quality scallop white-drying as described in (2).
(4) The high-quality scallop white dried product according to any one of the above (1) to (3), wherein the scallops are second-boiled at 40 to 100 ° C. before being subjected to the roasting process. Method.
(5) The high-quality scallop white dried product according to the above (4), wherein the second cooking step is performed in a salt water having a NaCl concentration of 4 to 15% by weight and a temperature of 40 to 95 ° C. for 5 to 120 minutes. Method.

本発明の方法は、上述のとおり、過熱水蒸気による焙乾工程と、少なくとも該工程の途中から温湿度条件が管理された雰囲気中で行うあん蒸工程とを組み合わせることを最大の特徴としているので、二番煮工程は必ずしも必須ではないが、ホタテ貝柱に、二番煮工程−焙乾工程−あん蒸工程を順次実施することによって白干しを製造する場合には、
a)二番煮工程を40〜95℃で行うこと、
b)焙乾工程を110〜250℃の過熱水蒸気により行うこと、及び、
c)あん蒸工程を、少なくとも該工程の途中から温湿度条件が管理された雰囲気中で行うこと、
が高品質ホタテ白干しを製造する上で好ましい。
この場合、二番煮工程は、NaCl濃度4〜15重量%、温度50〜90℃の塩水中で10〜30分間行うことが特に好ましい。また、あん蒸工程において、処理雰囲気を、当初から10〜50℃でかつ20〜80%RHに調整するか、又は、当初は室温であん蒸を行い、開始から2〜7日後に、雰囲気を40〜70℃で20〜80%RHに調整することが好適である。
The method of the present invention, as described above, is characterized by combining the roasting process with superheated steam and the fumigation process performed in an atmosphere where temperature and humidity conditions are controlled at least from the middle of the process. The second boiled step is not necessarily essential, but when producing white dried scallops by sequentially performing the second boiled step-roasting step-an fumigation step,
a) performing the second cooking step at 40-95 ° C;
b) performing the drying step with superheated steam at 110-250 ° C; and
c) performing the fumigation step in an atmosphere where temperature and humidity conditions are controlled at least from the middle of the step;
Is preferred for producing high quality white scallops.
In this case, the second cooking step is particularly preferably performed for 10 to 30 minutes in salt water having a NaCl concentration of 4 to 15% by weight and a temperature of 50 to 90 ° C. Also, in the annealing process, the treatment atmosphere is adjusted to 10-50 ° C. and 20-80% RH from the beginning, or initially at room temperature, the atmosphere is changed to 2-7 days after the start. It is preferable to adjust to 20 to 80% RH at 40 to 70 ° C.

従来の製造工程では、内在酵素の失活や貝柱の脱水に配慮し、一番煮、二番煮の両工程で充分加熱することが推奨されている。このため、焙乾による加熱時の貝柱水分は80%前後と低く、褐変を進行させる可能性が高い。乾燥という観点からの効率を考慮すると理にかなった方法ではあるが、本発明者の研究によって明らかとなった品質を左右する色調と水分活性との関係との観点から見ると、上記の従来法は高品質白干しの製造方法として適切であるとは言い難い。
これに対し、本発明では、従来の方法とは反対に、活貝より分離後速やかに冷凍される冷凍貝柱を原料としても、従来法より短期間で良好な色調の製品を製造することができる。しかも、製品の白干し中にはホタテ独自の呈味成分が多く残っており、調味成分としての効果も大きい。すなわち、調味効果も大きく、調味成分の付与効果も大きい。
In the conventional production process, it is recommended to heat sufficiently in both the first and second steps in consideration of inactivation of endogenous enzymes and dehydration of scallops. For this reason, the scallop moisture at the time of the heating by roasting is as low as about 80%, and the possibility that browning will advance is high. Although it is a reasonable method considering the efficiency from the viewpoint of drying, the above-mentioned conventional method is seen from the viewpoint of the relationship between the color tone that influences the quality and the water activity that are clarified by the study of the present inventors. Is not suitable as a method for producing high-quality white dried fish.
On the other hand, in the present invention, in contrast to the conventional method, a product of good color tone can be produced in a shorter period of time than the conventional method, even if the raw material is a frozen scallop frozen immediately after being separated from the live shellfish. . Moreover, many scallop-specific tasting ingredients remain in the white dried product, and the effect as a seasoning ingredient is great. That is, the seasoning effect is large and the seasoning component imparting effect is also large.

なお、色調の調整を念頭においた製造では、焙乾後に比較的高水分含量であることがポイントになると思われる。この場合、菌の繁殖のリスクが高まるが、表面殺菌法としても有用性が知られているSHSが有効であり、これとUV照射を組み合わせたあん蒸法が高品質白干しの製造法として好適である。  It should be noted that in manufacturing with color tone adjustment in mind, a relatively high water content after roasting seems to be a point. In this case, the risk of bacterial growth increases, but SHS, which is known to be useful as a surface sterilization method, is effective, and the fumigation method in combination with UV irradiation is suitable as a method for producing high-quality white dried food. It is.

本発明で使用するホタテ貝柱は、新鮮な原貝を一番煮あるいは水蒸気処理などにより開殻し、原貝から摘出したナマの貝柱だけでなく、冷凍した貝柱(玉冷)も同様に使用することができる。すなわち、活貝より分離後速やかに冷凍された冷凍貝柱を解凍したものは、製造工程中で褐変が生じやすいため、従来は白干しの原料として適さないとされてきたが、本発明ではこのような貝柱も使用可能であり、これが本発明方法の利点の1つとなっている。  The scallops used in the present invention are not only raw shells extracted from raw shellfish, but also frozen scallops (ball-cooled) as well. be able to. That is, thawing frozen frozen scallops that have been frozen immediately after separation from live shellfish has been considered unsuitable as a raw material for white drying since it is prone to browning during the manufacturing process. Can be used, which is one of the advantages of the method of the present invention.

この貝柱には、次に、NaCl濃度が5〜10重量%程度の塩水中で煮る二番煮が施されることが多い。この二番煮の工程(塩水煮工程)の目的は、味付けの他に褐変原因物質を溶出させ、貝柱中の褐変原因物質の含量を低減化させることにある。通常100℃程度で行われている二番煮工程を、本発明では、より低い温度で時間を掛けて実施するのがよく、二番煮の温度を、通常より低い40〜95℃(特に50〜90℃)とし、20〜40分間行うのが好適である。繰り返し使われて呈味成分が濃厚となった二番煮液(濃厚二番煮液)を使って、このような低温加熱の二番煮を実施すれば、貝柱への呈味成分の移行がなされ従来法では得られない好ましい風味や味のよい製品の製造が可能となる。ただし、場合によっては、この二番煮工程を省略することも可能である。
なお、二番煮を行う場合は、二番煮液としてNaClの他に、呈味成分を含んだ液を用いると、旨味の増した白干しを得ることができる。特に、後述の焙乾工程で生じるドリップにはアミノ酸、糖などの呈味成分を含むので、このドリップを再利用して二番煮液に添加したり、あるいは、後述の濃厚二番煮液を二番煮に使用すると、旨味の増した白干しが得られる。
Secondly, the scallops are often second-boiled in salt water having a NaCl concentration of about 5 to 10% by weight. The purpose of this second cooking process (salt water cooking process) is to elute the browning causative substance in addition to seasoning, and to reduce the content of the browning causative substance in the scallop. In the present invention, the second boiled step usually performed at about 100 ° C. is preferably carried out at a lower temperature over time, and the second boiled temperature is 40 to 95 ° C. (especially 50 to 50 ° C.). ˜90 ° C.), and preferably 20 to 40 minutes. Using the second boiled liquid (concentrated second boiled liquid) that has been used repeatedly to thicken the taste component, if the second boil of such low temperature heating is carried out, the transfer of the taste component to the scallop will be This makes it possible to produce a product with a favorable flavor and taste that cannot be obtained by conventional methods. However, in some cases, this second cooking step can be omitted.
In addition, when performing second boiled, if the liquid containing a taste component other than NaCl is used as the second boiled liquid, white dried with increased umami can be obtained. In particular, since the drip produced in the roasting process described below contains taste ingredients such as amino acids and sugar, this drip can be reused and added to the second boiled liquid, or the thick second boiled liquid described later can be added. When used in Niban-ni, white dried with increased umami is obtained.

次の焙乾工程では、貝柱を110〜250℃、好ましくは110〜180℃、さらに好ましくは120〜160℃、の過熱水蒸気(SHS)で、1〜6分間加熱する。過熱水蒸気処理の具体的条件については本発明者らが先に提案した特開2005−137340号に記載の条件を採用することができる。
なお、白干しの用途によっては、焙乾工程へ供給する貝柱を予め複数の小片に分割(切り分け)しておき、小片にした状態で焙乾を行ってもよい。この場合は、分割しない場合に比べて乾燥効率が高まるので、焙乾工程での加熱時間を短縮することができる。
In the next drying step, the scallop is heated with superheated steam (SHS) at 110 to 250 ° C, preferably 110 to 180 ° C, more preferably 120 to 160 ° C for 1 to 6 minutes. Regarding specific conditions for the superheated steam treatment, the conditions described in Japanese Patent Application Laid-Open No. 2005-137340 previously proposed by the present inventors can be employed.
Depending on the application of white drying, the scallop to be supplied to the roasting step may be divided (cut) into a plurality of small pieces in advance, and roasted in a state of being made into small pieces. In this case, since the drying efficiency is increased as compared with the case where it is not divided, the heating time in the roasting step can be shortened.

焙乾した貝柱のあん蒸工程では、これまで天日・通風乾燥が主として行われているが、本発明方法では、槽内の温湿度をコントロールできる恒温恒湿機や恒温恒湿室を使用した温湿度調整あん蒸を行う。あん蒸における温湿度調整を行うことで製品の白干しの色調を調整することは従来知られていないが、後述する実施例に示すように、この工程で意図的に雰囲気の温湿度調整をすることにより非常に高く評価されるアメ色(a値2.0付近)の製品が得られる。In the fumigation process of the dried scallops, the sun and ventilation have been mainly used so far, but in the method of the present invention, a constant temperature and humidity chamber or a constant temperature and humidity chamber capable of controlling the temperature and humidity in the tank was used. Perform temperature and humidity adjustment. Although it has not been known in the past to adjust the color tone of the white dried product by adjusting the temperature and humidity in the fumigation, the temperature and humidity of the atmosphere are intentionally adjusted in this step as shown in the examples described later. As a result, a product of candy color (a * value around 2.0) which is highly evaluated is obtained.

具体的には、次のいずれかの方法が採用される。
1)当初から温度10〜50℃、相対湿度20〜80%RHに調整した雰囲気中で実施する。
2)当初は室温で行い、開始から2〜7日後に、雰囲気を温度40〜70℃、相対湿度20〜80%RHに調製して実施する。
Specifically, one of the following methods is adopted.
1) Carry out in an atmosphere adjusted to a temperature of 10 to 50 ° C. and a relative humidity of 20 to 80% RH from the beginning.
2) Initially performed at room temperature, and after 2 to 7 days from the start, the atmosphere is adjusted to a temperature of 40 to 70 ° C. and a relative humidity of 20 to 80% RH.

上記のあん蒸工程により貝柱の水分率が16(重量)%以下になっている場合は、それを製品とするが、水分が多い場合は、あん蒸に引き続き、水分率が16(重量)%以下に低下するまで再度の焙乾とあん蒸を繰り返す。  If the moisture content of scallops is 16% (by weight) or less due to the above-mentioned fumigation process, the product is used as a product, but if the moisture content is high, the moisture content is 16% (by weight) following fumigation. Repeat roasting and fumigation until it drops below.

本発明方法では、焙乾工程を終えた貝柱をあん蒸工程に供給するにあたり、貝柱を複数の小片に分割し、分割した状態の貝柱に上記のあん蒸を施してもよい。小片に分割された貝柱は、あん蒸処理の効率が高いので、処理に要する時間を短縮することができる。  In the method of the present invention, when supplying the scallops after the drying process to the fumigation step, the scallops may be divided into a plurality of small pieces, and the above-described fumigation may be performed on the divided scallops. Since the scallop divided into small pieces has high efficiency of the fumigation treatment, the time required for the treatment can be shortened.

なお、色調の調整を念頭に置いた製造では、最初の焙乾後に比較的高水分含量であることがポイントになると思われる。この場合、菌繁殖のリスクが高まるが、表面殺菌法としても有用性が知られているSHSが有効であり、特にこれとUV(紫外線)照射を組み合わせたあん蒸法が高品質白干しの製造法として好適である。  In production with color tone adjustment in mind, it seems that the point is that the water content is relatively high after the initial roasting. In this case, the risk of bacterial growth increases, but SHS, which is known to be useful as a surface sterilization method, is effective, and in particular, the fumigation method that combines this with UV (ultraviolet) irradiation produces high-quality white dried food. It is suitable as a method.

[実施例1]
北海道常呂漁業協同組合冷凍工場より購入した冷凍貝柱(Sサイズ玉冷)を用い、上記冷凍貝柱(玉冷)の吸水を避けるため包装のまま流水下で水に浸した後、自然解凍した貝柱を用いた。
15個の解凍貝柱について2Lの7%NaCl溶液にて70℃30分間加熱し、二番煮を行った。二番煮液として褐変要因となる、Glu(グルコース)やG6P(グルコース6リン酸)を0.4mMになるよう調整した液を使用した場合についても検討した。
[Example 1]
Using frozen scallops (S size ball cooling) purchased from the Hokkaido Tokoro Fisheries Cooperative Frozen Factory, soaking the frozen scallops in natural water after immersing them in running water without wrapping them in order to avoid water absorption of the frozen scallops (ball cooling) Using.
The 15 thawed scallops were heated in 2 L of a 7% NaCl solution at 70 ° C. for 30 minutes, and then boiled. The case of using a solution prepared by adjusting Glu (glucose) or G6P (glucose 6-phosphate), which is a browning factor, to 0.4 mM as the second boiled solution was also examined.

二番煮後に焙乾を行った。焙乾では清本鐵工社製小型過熱水蒸気装置(K・SO−0935S)を用いて貝柱を150℃の過熱水蒸気で、4分間加熱した。焙乾は1日1回とし、製品の水分活性が0.65以下になるまで行った。乾燥の進行に従い加熱時間は1回当り1分30秒まで適宜短縮した。水分活性測定はRotronic社製測定装置(Hygro Palm)を用いた。試料貝柱の15個のうち10個を適宜用いて測定した。  It was roasted after the second boil. In the drying, the scallop was heated with superheated steam at 150 ° C. for 4 minutes using a small superheated steam device (K · SO-0935S) manufactured by Kiyomoto Seiko Co., Ltd. The roasting was performed once a day until the water activity of the product was 0.65 or less. The heating time was appropriately shortened to 1 minute 30 seconds per time as the drying progressed. The water activity was measured using a measuring device (Hygro Palm) manufactured by Rotronic. Measurement was performed using 10 of 15 sample shell pillars as appropriate.

なお、焙乾直前の所定試料5個についてコニカミノルタ製色彩色差計(CR−400)により、表面のL値を測定し、L値を明るさ(明度)、a値を褐変度として評価した。なお、北海道水産試験場によると一等品の条件としてa値4.5以下、L値40以上が目安となっている。In addition, the L * a * b * value of the surface was measured with a Konica Minolta color difference meter (CR-400) for five predetermined samples immediately before roasting, and the L * value was brightness (brightness) and a * value. Was evaluated as the degree of browning. According to the Hokkaido Fisheries Experiment Station, the a * value is 4.5 or less and the L * value is 40 or more as a standard condition.

続いて、焙乾後の貝柱をあん蒸を実施するに当り、あん蒸方法として、
イ)干物ネットに貝柱を置いて室温(15〜20℃、RH約30%)で放置する方法、及び、ロ)所定の温湿度に設定した東京理化製恒温恒湿機(KCL−2000A)を用い、温湿度コントロール下で貝柱をあん蒸する方法、により行った。
上記の焙乾−あん蒸をセットとして、貝柱水分が16%になるまで、繰り返し行った。なお、繰り返す場合、あん蒸は、その後に続く焙乾の直前まで実施した。
Subsequently, in carrying out the steaming of the dried scallops,
B) A method of placing scallops on a dried net and leaving them at room temperature (15-20 ° C, RH approx. 30%), and b) a constant temperature and humidity machine (KCL-2000A) made by Tokyo Rika set to a predetermined temperature and humidity. The method of fumigating scallops under temperature and humidity control was used.
The above-described roasting-aneration was repeated until the scallop moisture was 16%. In addition, in the case of repetition, the fumigation was carried out until immediately after the subsequent roasting.

(二番煮における成分浸透)
二番煮工程は、一般にNaCl濃度7%程度の塩水により100℃15分前後で実施され、この過程で貝柱の水分減少と塩味が付与され、グリコーゲンなどが溶出し、結果として貝柱の褐変を抑制すると言われている。従って、この工程では貝柱が本来持つ呈味成分が除去されることになる。白干し(干し貝柱)は、調味材料として用いられることも多いから、呈味成分を保持した製造方法は重要である。そこで、塩水の代わりに既に二番煮に繰り返し使われ、貝柱成分が溶出した濃厚二番煮液を用いて、二番煮液成分が貝柱へ浸透するかを検討した。この結果、図1に示す通り、加熱時間が長いほど、また処理温度が低いほど、呈味成分が貝柱に浸透することがわかった。
(Ingredient penetration in Niban-ni)
The second boiled process is generally carried out with salt water with a NaCl concentration of about 7% at around 100 ° C for 15 minutes. During this process, water loss and saltiness of the scallop are added, and glycogen and the like are eluted, resulting in suppression of browning of the scallop. It is said that. Therefore, in this process, the taste component inherent to the scallop is removed. Since white dried (dried scallop) is often used as a seasoning material, a production method that retains a taste component is important. Therefore, instead of salt water, we used a thick second boiled liquid that had already been used repeatedly for second boiled and eluted the scallop component, and examined whether the second boiled liquid component penetrated into the scallop. As a result, as shown in FIG. 1, it was found that as the heating time was longer and the processing temperature was lower, the taste component penetrated into the scallop.

(あん蒸条件と色調調節)
褐変のモデル実験として褐変が見られたGlu(グルコース)、G6P(グルコース6リン酸)の各溶液を加えた塩水を二番煮液として用い、低温長時間(70℃、30分)の二番煮を実施し、白干し製造を行った。温湿度調整(50℃、60%RH)あん蒸を当初から実施すると、図に示すように、6日間で所定の水分率(16%以下)となり、製造中の白干しの褐変に過度な上昇が見られ、特にGlu処理が高い値を示した。
しかしながら、モデル実験で褐変が見られたG6Pは、コントロールである塩水による二番煮処理と色調に差はなく、白干しの褐変に影響しなかった。貝柱成分の褐変時にG6P含量に変化が見られることから、その褐変への関与が推察されているが、実際に白干し製造時にG6P添加しても色調への影響があまり見られなかったことは興味深い結果と言える。
(Fumigation conditions and color adjustment)
As a model experiment for browning, the salt solution containing each solution of Glu (glucose) and G6P (glucose 6-phosphate) in which browning was observed was used as the second boiled solution, and the second one at low temperature and long time (70 ° C, 30 minutes) Boiled and white dried. Temperature / humidity adjustment (50 ° C, 60% RH) When fumigated from the beginning, as shown in the figure, the moisture content reaches a predetermined level (less than 16%) in 6 days, which is excessively increased in browning of white air during production. In particular, Glu treatment showed a high value.
However, G6P, in which browning was observed in the model experiment, had no difference in color tone from the second boiled treatment with salt water, which was a control, and did not affect the browning of dried white. The change in G6P content during the browning of the scallop component is presumed to be involved in the browning, but even when G6P was actually added during white drying, the effect on the color tone was not seen so much. This is an interesting result.

あん蒸を室温で実施後、温湿度調整(50℃、60%RH)あん蒸を途中から実施すると、あん蒸温度の上昇と共に、褐変は進行したがGlu処理とコントロールとで差は無く、それぞれ7日間で一等級製品の色調であるa値2前後で製品となった。すなわち、この方法は、Glu処理などの褐変し易い状況であっても過度な褐変は生じないあん蒸方法であることがわかった。
水分活性と褐変との関係を図3に示した。製造の進行と共に製品水分活性は低下し褐変は上昇する傾向にあり、特に水分活性0.8付近で大きく褐変値が上昇した。
After carrying out the annealing at room temperature and adjusting the temperature and humidity (50 ° C, 60% RH), the browning progressed with an increase in the anemone temperature, but there was no difference between the Glu treatment and the control. In 7 days, it became a product with a * value of around 2 which is the color tone of the first grade product. That is, it was found that this method is an fumigation method in which excessive browning does not occur even in a situation where browning easily occurs such as Glu treatment.
The relationship between water activity and browning is shown in FIG. As the production progressed, the water activity of the product decreased and the browning tended to increase, and the browning value increased largely around the water activity of 0.8.

異なる温湿度調整あん蒸とその実施タイミングとを変えて製造した白干し製品の色調を図4に示した。この結果、あん蒸温度が40℃程度であれば、温湿度調整あん蒸を焙乾後の当初より実施していても、a値が2前後の好ましい製品色調となることがわかった。一方、50℃のあん蒸温度では、好ましい製品の色調とするには、室温あん蒸を2、3日実施した後、温湿度調整あん蒸を導入しなければならず、上述の図3の結果と併せて考えると、貝柱の水分活性が0.8前後でのあん蒸温度が高いと褐変を進行させる可能性が示された。なお、40℃80%RHの温湿度調整あん蒸を実施した試験区の全ての白干しは、実際の加工現場で一等級の評価を得た。FIG. 4 shows the color tone of the white dried product manufactured by changing the temperature and humidity control fumigation and the execution timing thereof. As a result, it has been found that when the temperature of the mist is about 40 ° C., even if the temperature / humidity-controlled mist is carried out from the beginning after roasting, the a * value is a preferable product color tone of around 2. On the other hand, at a temperature of 50 ° C., in order to obtain a preferable product color tone, room temperature aeration must be carried out for a few days, and then temperature and humidity adjustment aeration must be introduced. When combined with the above, it was shown that browning may be promoted when the water activity of the scallops is high at a fumigation temperature of around 0.8. In addition, all the white drying of the test section which implemented the temperature / humidity adjustment | tempering fumigation of 40 degreeC80% RH obtained the first grade evaluation in the actual processing field.

濃厚二番煮液の二番煮処理による呈味成分(糖)の貝柱中心部への浸透を示すグラフ  Graph showing the penetration of the taste component (sugar) into the center of the scallop by the second boiled treatment of the thick second boiled liquid 二番煮液添加物と温湿度調整あん蒸の開始時期が白干し色調に及ぼす影響を示すグラフ  Graph showing the effect of the second boiled liquid additive and temperature / humidity-controlled fumigation on the color of dried white 処理試料における製造期間中の褐変と水分活性値との関係を示すグラフ  Graph showing the relationship between browning and water activity during the production period for treated samples 温湿度調整あん蒸の開始時期が白干し色調に及ぼす影響を示すグラフ  Graph showing the effect of temperature / humidity control fumigation on the color of dried white

Claims (4)

ホタテ貝柱を、焙乾工程を実施した後、あん蒸工程を実施する高品質ホタテ白干し製造方法であって、
焙乾工程を110〜250℃の過熱水蒸気により行
あん蒸工程を、あん蒸開始当初から処理雰囲気を40℃以上50℃未満でかつ20〜80%RHに調整された雰囲気中で行う
とを特徴とする高品質ホタテ白干しの製造方法。
The scallops, after performing the Abuinui step, a high-quality Scallop white Dried manufacturing method of carrying out the bean evaporation step,
There line by superheated steam 110 to 250 ° C. The Abuinui step,
The sauce evaporation step, dried quality scallop white and wherein the <br/> this carried out in an atmosphere which is adjusted to Ann evaporation starting RH and 20-80% in less than 50 ° C. 40 ° C. or more treatment atmosphere from the beginning Manufacturing method.
ホタテ貝柱を、焙乾工程を実施した後、あん蒸工程を実施する高品質ホタテ白干しの製造方法であって、
該焙乾工程を110〜250℃の過熱水蒸気により行い、
あん蒸工程あん蒸開始当初は室温であん蒸を行い、あん蒸開始から2〜7日後に、処理雰囲気を40〜70℃で20〜80%RHに調整された雰囲気中で行う
ことを特徴とする高品質ホタテ白干しの製造方法。
A method for producing high-quality scallop white-dried scallops, in which a roasting process is performed after a roasting process,
Performing the drying step with superheated steam at 110 to 250 ° C .;
The sauce evaporation step, performed Ann vapor beginning at room temperature with sauce steam, in 2-7 days after the sauce steam starts, carried out in a treatment atmosphere is adjusted to RH 20 to 80% at 40 to 70 ° C. ambient < br /> method for producing a dried high-quality scallop white you wherein a.
ホタテ貝柱を焙乾工程に供する前に、40〜100℃で二番煮を行う
ことを特徴とする請求項1又は2に記載の高品質ホタテ白干しの製造方法。
The method for producing high-quality white scallops according to claim 1 or 2 , wherein the scallops are second-boiled at 40 to 100 ° C before being subjected to a roasting process.
記二番煮工程をNaCl濃度4〜15重量%、温度40〜95℃の塩水中で5〜120分間行うことを特徴とする請求項に記載の高品質ホタテ白干しの製造方法。


Before SL double-dip boiled step a NaCl concentration of 4-15% by weight, method of manufacturing the dry quality scallop white according to claim 3, characterized in that brine at a temperature of 40 to 95 ° C. 5 to 120 minutes.


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