JP4897553B2 - Nanofiber manufacturing apparatus and nanofiber manufacturing method - Google Patents

Description

  The present invention relates to an apparatus and a method for producing a nanofiber made of a polymer material.

  An electrospinning (charge-induced spinning) method is known as a method for producing a filamentous material (hereinafter referred to as “nanofiber”) made of a polymer material and having a submicron-scale diameter.

  This electrospinning method is a method in which a polymer solution in which a polymer substance is dispersed in a solvent is ejected (outflowed) from a needle-like nozzle to which a high voltage is applied to a collector (collecting electrode) toward the collector. This is a method for obtaining a nanofiber. More specifically, the charged polymer solution is injected into the space by setting the injection nozzle to a high voltage, and the charge density of the polymer solution flying in the space increases as the solvent evaporates. A phenomenon (electrostatic explosion) in which the polymer solution is explosively stretched linearly occurs when the repulsive Coulomb force generated in the polymer solution exceeds the surface tension of the polymer solution. This electrostatic explosion occurs one after another in the space, so that nanofibers made of a polymer having a submicron diameter are manufactured.

  In addition, by depositing nanofibers manufactured by the above-mentioned method on a substrate, a three-dimensional thin film having a three-dimensional network can be obtained, and by forming a thicker film, a high thickness having a submicron network can be obtained. A porous web (nonwoven fabric) can be produced.

  The web produced by employing the electrospinning method as described above is highly porous composed of nano-order pores and has a large surface area as a whole, so that it is a filter, battery separator, or fuel cell polymer electrolyte membrane. It is expected to obtain a high effect when applied to electrodes and electrodes.

Conventionally, as a method for producing a large amount of nanofibers to produce a practical web made of nanofibers, an apparatus for producing a web by arranging a plurality of nozzles in parallel and depositing a large amount of nanofibers has been proposed. (For example, refer to Patent Document 1).
JP 2002-201559 A

Conventionally, the following knowledge has been obtained through experiments and research.
That is, in order to improve the uniformity of the deposition direction of nanofibers deposited on the collector and the spatial uniformity of the deposition amount, a nozzle for injecting a polymer solution and a collector for collecting the manufactured nanofibers It is desirable to make the distance of as short as possible. In addition, the higher the voltage between the nozzle and the collector, the greater the number of occurrences of not only the primary explosion but also the high-order electrostatic explosion after the secondary explosion, and the diameter of the nanofiber to be manufactured becomes finer. become.

  On the other hand, as the distance between the nozzle and the collector is increased, the amount of evaporation of the solvent is increased, and the number of high-order electrostatic explosions is increased. Moreover, the abnormal discharge which generate | occur | produces between a nozzle and a collector can be suppressed, so that the voltage between a nozzle and a collector is low, and the distance between a nozzle and a collector is lengthened.

  When manufacturing a nonwoven fabric with nanofibers, the distance between the nozzle and the collector and the voltage are determined as a compromise in view of the above conflicting viewpoints. In particular, the conditions are determined so that the abnormal discharge does not occur as much as possible. This is remarkable when a flammable solvent is used, and the distance between the nozzle and the collector is increased, the voltage is lowered, and the ignition based on abnormal discharge is suppressed. As a result, it is difficult to ensure good uniformity in the deposition direction of nanofibers and spatial uniformity in deposition amount.

  The present invention has been made in view of the above problems, and in producing a nonwoven fabric composed of nanofibers, when the distance between the injection means including the nozzle and the collecting electrode including the collector is relatively long, or between the nozzle and the collector It is an object of the present invention to provide a nonwoven fabric manufacturing apparatus that can ensure uniformity in the deposition direction of nanofibers and spatial uniformity in the deposition amount even when the voltage between them is relatively low.

  In order to achieve the above object, a nanofiber manufacturing apparatus according to the present invention includes an injection means having injection holes for injecting a raw material liquid for producing nanofibers, and a collection for collecting nanofibers generated from the injection holes. A nanofiber manufacturing apparatus comprising: an electrode; and a first power source that applies a first voltage between the ejection unit and the collection electrode, the auxiliary electrode being separate from the ejection unit, and the auxiliary electrode And a second power source for applying a second voltage between the collector electrode and the collector electrode.

  Accordingly, a second voltage different from the first voltage applied between the ejection unit and the collecting electrode can be provided, and the behavior of the manufactured nanofiber (for example, the flight direction) can be changed to the second voltage. It is possible to easily control using the voltage. As a result, it is possible to easily ensure the uniformity of the deposition direction of the nanofibers and the spatial uniformity of the deposition amount.

  The auxiliary electrode is preferably disposed between the ejection unit and the collecting electrode.

  With such an arrangement, the electric field (lines of electric force) can be easily controlled, and the deposition position of nanofibers considered to fly along the lines of electric force can be easily controlled.

  Further, it is desirable that the auxiliary electrode is disposed outside a range where the collecting electrode is desired from the ejection unit.

  This makes it possible to avoid the presence of the auxiliary electrode from becoming an obstacle to ensuring uniformity of the deposition direction of the nanofibers and spatial uniformity of the deposition amount.

  In addition, it is desirable that the voltage applied to the auxiliary electrode can be controlled independently of the ejection unit and the collecting electrode.

  Thereby, not only the spatial arrangement of the auxiliary electrodes but also the electric field (lines of electric force) can be controlled by the voltage, and the flight of the nanofiber can be controlled more flexibly.

  Further, the collecting electrode is disposed on the injection hole side of the collecting electrode and includes a deposition means for holding the manufactured nanofibers in a deposited state, and a moving means for moving the deposition means in a predetermined direction. It is preferable that they are arranged in front of and behind the injection means with respect to the moving direction of the deposition means.

  Thereby, even when manufacturing a long nonwoven fabric, the uniformity of the deposition direction of nanofibers and the spatial uniformity of the deposition amount can be ensured.

  The auxiliary electrode may have a plate shape, and may be disposed on the side opposite to the collecting electrode with respect to the ejection unit.

  Thereby, since the nanofiber which flies away from the collection electrode can be reflected and the flight direction can be changed to the collection electrode, the deposition efficiency of the nanofiber can be improved. In particular, it is effective when using a type of injection means for injecting the raw material liquid by centrifugal force.

  In order to achieve the above object, the nanofiber manufacturing method according to the present invention includes a first electric field between an injection means for injecting a raw material liquid for nanofiber manufacturing and a collecting electrode for collecting the manufactured nanofibers. In the nanofiber manufacturing method including a first electric field generating step for generating a gas and an injection step for injecting the raw material liquid into the electric field, a first electric field is generated between the auxiliary electrode separate from the collection electrode and the collection electrode. And a second electric field generating step for generating a second electric field.

  The effect by this is the same as the above.

  According to the present invention, even when the distance between the ejecting means and the collecting electrode is relatively long, or when the voltage between the nozzle and the collector is relatively low, the uniformity of the nanofiber deposition direction and the spatial amount of the deposition amount can be reduced. Uniformity can be ensured and a homogeneous nonwoven fabric can be produced.

  Next, an embodiment of a nonwoven fabric manufacturing apparatus including the nanofiber manufacturing apparatus according to the present invention will be described.

FIG. 1 is a perspective view schematically showing a non-woven fabric manufacturing apparatus according to the present invention.
As shown in the figure, the nonwoven fabric manufacturing apparatus 100 includes a jetting unit 110, a collecting electrode 120, an auxiliary electrode 180, and a sheet 160 as a depositing unit. In addition, since the raw material liquid to be injected and the nanofiber being manufactured cannot be clearly distinguished, the reference numeral 200 is assigned to each, and the manufactured nonwoven fabric is assigned 210.

  The injection means 110 is an apparatus having an injection hole for injecting (flowing out) a raw material liquid for producing nanofibers, and is connected to a power source 150a as a first power source and maintained at a predetermined potential. ing. A pipe 111 connected to a tank (not shown) for storing the raw material liquid is connected to the injection means 110 so that the raw material liquid is supplied at a predetermined pressure.

  The collection electrode 120 is connected to a power source 150b as a first power source so that a predetermined voltage is applied to the ejection unit 110, and is a device for collecting the manufactured nanofibers.

  The power source 150a and the power source 150b are both for generating a voltage between the ejection unit 110 and the collecting electrode 120, and may be a single power source.

  The sheet 160 is a member on which the nanofibers 200 manufactured in the space are to be deposited, and is a thin and flexible long sheet made of a material that can be easily separated from the deposited nanofibers 200. . The sheet 160 is supplied in a state of being wound in a roll shape, and slowly moves in the direction of the arrow in the drawing by the moving means 170 through the portion where the nanofibers 200 are deposited. And it rolls around with the nonwoven fabric 210 manufactured on the sheet | seat 160 again in roll shape.

  The moving means 170 is a device capable of feeding the sheet 160 in one direction while maintaining a predetermined tension, and moves the sheet 160 by rotating a roller shown in the drawing by driving a motor (not shown) or the like. Is.

  The auxiliary electrode 180 is an electrode to which a voltage that is the same as that of the ejection unit 110 or closer to the ejection unit 110 than the collecting electrode 120 is applied by a power source 150c as a second power source, and is separated from the ejection unit 110. The attachment position can be arbitrarily set.

  The ejection unit 110, the auxiliary electrode 180, and the collection electrode 120 have various modes, and there are various combinations of these modes. In FIG. 1, the ejecting means 110, the auxiliary electrode 180, and the collecting electrode 120 are symbolically indicated by alternate long and short dash lines, and specific embodiments thereof will be specifically described in the embodiments described later.

  The power source 150c generates a second voltage between the auxiliary electrode 180 and the collecting electrode 120, and it is preferable that the voltage can be adjusted independently of the power sources 150a and 150b.

(Embodiment 1)
FIG. 2 is a diagram illustrating a specific example of the ejection unit, the auxiliary electrode, and the collection electrode.

  Although the drawing shows the relationship between the ejecting means 110, the auxiliary electrode 180, and the collecting electrode 120, the ejecting means 110 and the auxiliary electrode 180 are shown larger, but the diameter of the collecting electrode 120 is actually several meters. In contrast, the diameters of the tips of the nozzle 113 and the auxiliary electrode 180 are about several millimeters.

  The collecting electrode 120 shown in the figure has a cylindrical shape and can rotate with the movement of the sheet 160 or in synchronization. The collecting electrode 120 has a rounded chamfer at the cylindrical edge portion so that the diameter gradually decreases toward the end surface of the collecting electrode 120.

  In this way, by making the peripheral edge of the collecting electrode 120 desired from the ejecting means 110 a curved surface that moves away from the ejecting means 110, the disturbance of the electric field due to the edge of the collecting electrode 120 is suppressed, and the deposition state of the nanofiber 200 is improved. It can be.

  The injection means 110 includes a plurality of nozzles 113 each having an injection hole (not shown) for injecting the raw material liquid at the tip. The nozzles 113 are arranged at equal intervals in a direction perpendicular to the moving direction of the sheet 160 (X direction in the figure, width direction of the sheet 160). The nozzle 113 is arranged on a diagonal line with respect to the Y direction. Therefore, the adjacent nozzles 113 are in a state of being displaced in the Y direction. Further, the nozzle 113 is arranged in a radial direction around the rotation axis so that the raw material liquid 200 can be sprayed toward the rotation axis of the collecting electrode 120. The nozzle 113 at the extreme end in the X direction and the nozzle 113 at the other extreme end (nozzles 113 at both ends in the width direction of the sheet 160) are set so that the distance in the X direction is narrower than the width of the sheet 160. Also, it is tilted toward the center of curvature of the curved surface portion.

  By disposing the nozzle 113 as described above, the distance between the nozzles 113 can be increased while maintaining the collection electrode 120 and the nozzle 113 at a predetermined distance, and the nano-particles manufactured from the adjacent nozzles 113 can be made. The deposition positions of the fibers 200 on the sheet 160 can be arbitrarily overlapped.

  Therefore, the disturbance of the electric lines of force caused by the nozzles 113 affecting each other is suppressed, the positional deviation of the deposited amount of the nanofibers 200 in the width direction of the sheet 160 is prevented, and the thickness in the width direction of the sheet 160 is prevented. It is possible to produce a uniform nonwoven fabric.

  The auxiliary electrode 180 has a thin cylindrical shape, and the lower end has a conical shape. On the other hand, a voltage applying lead 181 is attached to the upper base end, and the same voltage is applied to all the auxiliary electrodes by the power source 150c. Note that the tip of the auxiliary electrode 180 may have a curved surface such as a spherical shape, and other shapes can be arbitrarily selected.

  A plurality of auxiliary electrodes 180 are arranged so as to intersect the moving direction of the sheet 160 and to be parallel to the surface of the sheet 160 to constitute an auxiliary electrode row. Further, the auxiliary electrode row is parallel to the row of nozzles 113. In addition, the nozzles 113 are arranged before and after the sheet 160 in the moving direction. The auxiliary electrode row is disposed on the opposite side of the collecting electrode 120 with respect to the sheet 160 and between the ejection unit 110 and the sheet 160. The auxiliary electrodes arranged before and after the ejection unit 110 are inclined along the moving direction of the sheet 160 so that the tips approach each other.

  3 is a cross-sectional view showing a state cut along line AA in FIG. In addition, the sheet | seat 160 is not described in the figure. Further, hatching attached to the collecting electrode 120 and the nozzle 113 is omitted.

  As shown in the figure, the auxiliary electrode 180 is disposed outside the region where the collecting electrode 120 is desired from the tip of the nozzle 113 (hatched portion in the figure). In addition, the tip of the auxiliary electrode 180 is disposed closer to the collection electrode 120 than the half of the closest distance from the nozzle 113 to the collection electrode 120.

  By arranging in this way, the electric force lines from the auxiliary electrode 180 are added to the portion where the electrical relationship between the nozzle 113 and the collecting electrode 120 is thin, that is, the portion where the electric force lines are sparse. The line becomes dense. Therefore, the nanofibers 200 manufactured due to the sparse electric field lines are not deposited on the collection electrode 120 by utilizing the property of the nanofibers 200 that tend to gather the electric field lines in dense portions. It is possible to prevent the nanofiber 200 from being scattered in the air and to increase the integration efficiency of the nanofiber 200 above the collection electrode 120.

(Embodiment 2)
FIG. 4 is a diagram showing another embodiment of the ejecting means, the auxiliary electrode, and the collecting electrode.

  The figure shows the ejection means 110 larger to show the relationship between the ejection means 110, the auxiliary electrode 180, and the collection electrode 120, but the collection electrode 120 is actually several meters in size. On the other hand, the diameter of the rotary cylinder 114 is several centimeters to several tens of centimeters.

  The collecting electrode 120 shown in the figure has a flat plate shape, and has a shape with a smooth curved surface such that the peripheral edge moves away from the injection hole 112 over the entire circumference of the flat plate.

  The collecting electrode 120 is fixedly arranged with respect to the nonwoven fabric manufacturing apparatus 100 and is in a rubbing state with the moving sheet 160.

  With such a collecting electrode 120, it is not necessary to rotate the collecting electrode 120. Therefore, the potential of the collecting electrode 120 can be easily stabilized, and the size can be easily reduced.

  The injection means 110 includes a cylindrical rotary cylinder in which a large number of nozzles 113 having a large number of injection holes 112 are provided on the peripheral wall.

Here, the ejection unit 110 according to the present embodiment will be described in detail.
FIG. 5A is a perspective view of the ejecting means, and FIG. 5B is a cross-sectional view.

  As shown in the figure, the injection means 110 is a device that injects (flows out) the raw material liquid by centrifugal force, and includes a rotary cylinder 114, a tank 115 that stores the raw material liquid 200, a tank 115, and a rotary cylinder 114. A pipe 111 to be connected, a shaft 301 serving as a rotating shaft that also serves as the pipe 111, a rotating body support 312, a bearing 310, gears 307 and 308, and a rotating means 306 are provided.

  The rotary cylinder 114 is rotatably supported with respect to the rotating body support 312 via a shaft 311 and a bearing 310. Further, it is maintained at a predetermined potential by the power source 150 via the brush 315. The rotary cylinder 114 is connected to a rotating means 306 attached to the rotating body support 312 via gears 307 and 308 and is rotated by a driving force applied from the rotating means 306.

  Further, a pipe for distributing the raw material liquid 200 is connected to one of the shafts 301, and the raw material liquid 200 supplied from the tank 115 is pumped by the pump 117, and passes through a hole drilled in the peripheral wall of the shaft 301. The raw material liquid 200 is supplied inside 114. Thus, the raw material liquid 200 is evenly supplied in the axial direction by injecting the raw material liquid 200 in an equal amount by supplying the raw material liquid to the rotary cylinder 114 through the hole provided in the peripheral wall of the shaft 301. Be able to.

  If the above injection means 110 is employ | adopted, a comparatively large amount of nanofiber 200 can be manufactured at once, and it will become possible to manufacture the nonwoven fabric 210 efficiently.

  In addition, a reflection plate 140 as an auxiliary electrode 180 is provided on the opposite side of the rotary cylinder 114 from the collection electrode 120.

  The reflector 140 is connected to the power source 150 c and is applied with the same voltage as the ejection unit 110 or a voltage closer to the ejection unit 110 than the collecting electrode 120. Moreover, it is a separate body from the injection means 110, and the relative positional relationship with the injection means 110 can be arbitrarily changed. The reflector 140 pushes and collects the raw material liquid 200 that is radially ejected by the rotation of the rotary cylinder 114 or the raw material liquid 200 that is not ejected toward the collecting electrode 120 among the manufactured nanofibers 200 by voltage. It is a metal or alloy plate-like body facing the electrode 120.

FIG. 6 is a cross-sectional view showing the relationship between the rotary cylinder and the reflecting plate.
As shown in the figure, the reflector 140 has a shape in which two parabolas overlap each other, is provided as a separate body so as to surround the rotary cylinder 114, and is separate from the power source 150 a that applies a voltage to the rotary cylinder 114. A voltage having the same polarity as that of the rotary cylinder 114 is applied by the power source 150c.

  As described above, the raw material liquid 200 ejected by the centrifugal force from the rotary cylinder 114 or the manufactured nanofiber 200 reflects the raw material liquid 200 or the like to move away from the collecting electrode 120 to the reflecting plate 140 or the reflecting plate. It is pushed out by the electric field formed by 140 and the collecting electrode 120. Therefore, the reflector 140 can direct almost all the nanofibers 200 in the direction opposite to the position of the reflector 140, that is, in the direction of the collecting electrode 120.

  As described above, the nanofibers 200 can be deposited on the sheet 160 in a large amount and evenly, and the non-woven fabric 210 uniform in the width direction of the sheet 160 can be manufactured with high efficiency.

(Embodiment 3)
FIG. 7 is a diagram showing another embodiment of the ejecting means, the auxiliary electrode, the reflecting plate, and the collecting electrode.

  Although the drawing shows the ejection unit 110 in a larger scale in order to show the relationship among the ejection unit 110, the auxiliary electrode 180, the reflector 140, and the collection electrode 120, the diameter of the collection electrode 120 is actually several. The diameter of the vertical cylinder 116 is several centimeters while it is a meter. In the present embodiment, the auxiliary electrode 180 and the reflecting plate 140 are described with different names in order to clearly distinguish them, but the reflecting plate 140 is one of the auxiliary electrodes 180.

  The collecting electrode 120 shown in the figure is a part of a spherical surface, and is arranged in a fixed manner with respect to the nonwoven fabric manufacturing apparatus 100. Therefore, the moving sheet 160 is in a rubbing state.

  With such a collecting electrode 120, it is not necessary to rotate the collecting electrode 120. Therefore, the potential of the collecting electrode 120 can be easily stabilized, and the size can be easily reduced.

  The injection means 110 includes a cylindrical vertical cylinder 116 in which a number of nozzles 113 including a large number of injection holes 112 are provided on the peripheral wall. In the vertical cylinder 116, the raw material liquid 200 is jetted substantially parallel to the sheet 160 from the nozzle by centrifugal force.

  The reflector 140 is a donut-shaped plate-like electrode disposed on the opposite side of the collecting electrode 120 with respect to the vertical cylinder 116. A voltage is applied to the reflector 140 by the power source 150d so as to have the same polarity as the vertical cylinder 116, and the voltage is controlled independently of the vertical cylinder 116, the collecting electrode 120, and the auxiliary electrode 180. Further, the reflecting plate 140 is maintained in a fixed state without rotating together with the vertical cylinder 116.

  The auxiliary electrode 180 is arranged on the circumference in the vicinity of the collecting electrode 120. The tip of the auxiliary electrode 180 is pointed, and the tip of the auxiliary electrode 180 is tilted in a direction approaching each other. A voltage is applied to the auxiliary electrode 180 by a power source 150 c, and the voltage is controlled independently of the vertical cylinder 116, the collection electrode 120, and the reflection plate 140.

  With the above configuration, the spatial positional relationship among the vertical cylinder 116, the reflector 140, the auxiliary electrode 180, and the collection electrode 120 is equivalent on the XY plane, and uneven distribution of electric lines of force can be easily avoided. Therefore, the raw material liquid 200 sprayed substantially horizontally from the nozzles is evenly fly toward the collecting electrode 120, ensuring the spatial uniformity of the deposited state of the nanofibers 200 on the sheet 160, and the uniform nonwoven fabric 210. Can be manufactured.

  The shape of the collecting electrode 120 is not limited to the above, and may be the collecting electrode 120 having an arbitrary curved surface such as an elliptical sphere. The collecting electrode 120 may be a flat surface.

  Further, as shown in FIG. 8, the ejection unit 110 may adopt a shape in which nozzles are arranged in a staggered pattern (or a matrix pattern).

  In each of the embodiments, a voltage is applied to the ejection unit 110 and a voltage having a polarity opposite to that applied to the nozzle is applied to the collecting electrode 120. However, the present invention is not limited to this. In order to charge the raw material liquid injected from the nozzle, a voltage difference is generated between the injection means 110 and the collecting electrode, and the raw material liquid injected from the nozzle injection hole of the injection means 110 is It only has to be charged. For example, even when the injection hole of the injection unit 110 is grounded and a voltage is applied to the collection electrode, nanofibers are generated, and each embodiment can be applied.

  Also, with regard to the auxiliary electrode 180, in each embodiment, an example in which a voltage is applied to the auxiliary electrode 180 has been described. However, the present invention is not limited to this, and a voltage difference is generated between the auxiliary electrode and the collecting electrode. The collection of the charged nanofibers generated by the explosion of the raw material liquid injected from the injection holes to the collection electrode may be accelerated. For example, when the injection hole of the injection unit 110 is grounded and a voltage is applied to the collection electrode, and the auxiliary electrode is grounded, the voltage between the auxiliary electrode and the collection electrode is Differences can occur and electric field lines can be generated between them, facilitating the collection electrodes to collect nanofibers with the generated charge.

  INDUSTRIAL APPLICABILITY The present invention can be used for a nonwoven fabric manufacturing apparatus that can be applied to a filter using microporosity or a catalyst support using a wide surface area.

It is a perspective view showing roughly the nonwoven fabric manufacturing device concerning the present invention. It is a figure which shows the specific example of an injection means, an auxiliary electrode, and a collection electrode. It is sectional drawing which shows the state cut | disconnected by the AA line in FIG. It is a figure which shows other embodiment of an injection means, an auxiliary electrode, and a collection electrode. (A) is a perspective view of an injection means, (b) is sectional drawing. It is sectional drawing which shows the relationship between a rotary cylinder and a reflecting plate. It is a figure which shows other embodiment of an injection means, an auxiliary electrode, a reflecting plate, and a collection electrode. It is a perspective view which shows another injection means.

Explanation of symbols

DESCRIPTION OF SYMBOLS 100 Nonwoven fabric manufacturing apparatus 110 Injection means 111 Pipe 112 Injection hole 113 Nozzle 114 Rotary cylinder 115 Tank 116 Vertical cylinder 117 Pump 120 Collection electrode 140 Reflector 150 Power supply 150a Power supply 150b Power supply 150c Power supply 150d Power supply 160 Sheet 170 Moving means 180 Auxiliary electrode 200 Nanofiber 200 Raw material liquid 210 Non-woven fabric 301 Shaft 306 Rotating means 307 Gear 310 Bearing 311 Shaft 312 Rotating body support 315 Brush

Claims (4)

An injection means having an injection hole for injecting a raw material liquid for producing nanofibers, a collection electrode for collecting nanofibers generated by injection from the injection hole, and a first between the injection means and the collection electrode A nanofiber manufacturing apparatus comprising a first power supply for applying a voltage,
A reflector that is separate from the ejection means, and is disposed on the opposite side of the collection electrode with respect to the ejection means ;
An auxiliary electrode disposed between the ejection means and the collecting electrode;
A power source for applying a voltage between the auxiliary electrode and the reflector and the collecting electrode;
The injection means includes a cylinder having a tube axis arranged along an axis extending from the injection means in the direction of the collecting electrode and having a plurality of injection holes in a peripheral wall, and the raw material liquid is supplied by centrifugal force by rotating the cylinder. nano-fiber manufacturing apparatus that be injected. 2. The nanofiber manufacturing apparatus according to claim 1, wherein the distance between the tip of the auxiliary electrode and the collection electrode is half or less of the distance between the ejection unit and the collection electrode. The nanofiber manufacturing apparatus according to claim 1, wherein the auxiliary electrode is capable of controlling a voltage applied independently of the ejection unit and the collection electrode. further,
A deposition means disposed on the injection hole side of the collecting electrode and holding the manufactured nanofibers in a deposited state;
Moving means for moving the deposition means in a predetermined direction,
The nanofiber manufacturing apparatus according to claim 1, wherein the auxiliary electrode is disposed in front of and behind the ejecting unit with respect to a moving direction of the deposition unit.

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