JP4868622B2 - Tissue paper and tissue paper manufacturing method - Google Patents

Description

  The present invention relates to tissue paper and a method for manufacturing tissue paper.

The tissue paper in the domestic market is broadly divided into non-moisturizing tissue and moisturizing tissue. Here, the moisturizing tissue is a tissue produced by applying a moisturizing agent such as glycerin to a tissue base paper that has been made, and the non-humidifying tissue is a general tissue that does not apply a moisturizing agent to the tissue base paper.
The use of tissue paper is mainly for personal use, mainly for facial use, and the moisturizing tissue is considered to be a product specification specialized for use in the nose.
Traditionally, tissue paper has been used for facial applications, mainly for nasal clasps, and so many attempts have been made in the past to improve the touch and quality improvements have been repeated. For example, various softeners are added to the raw materials to improve the flexibility of the product. Many supple fibers with low fiber roughness are used. Fine creping by sticking when wet paper dryer is dried and adjusting per doctor. The softness and smoothness of the paper is achieved by technologies such as forming the surface, improving the surface properties by a calender, and adjusting the raw material beating rate to a low level while maintaining the lateral strength by adjusting the ratio of the web speed. Improvements have been made.

However, in order to further improve quality, non-moisturizing tissue has technical limitations and an increase in the number of people suffering from hay fever and allergic rhinitis has led to the development of moisturizing tissue that is now part of the tissue market. Accounted for.
Heavy users, such as allergic rhinitis and hay fever, bite their nose more than tens of times a day, and the nose and its surroundings are rubbed against tissue, causing mild inflammation and redness. Therefore, for such a user, a material having a small friction on the tissue surface, that is, a material having smoothness is preferably used. The moisturizing tissue applies an aqueous lotion solution containing a hygroscopic moisturizing agent such as glycerin to the base paper of the sanitary thin paper. Glycerin is less irritating to the skin as used in cosmetics, absorbs moisture and moistens and softens the tissue, forms a thin film on the surface of the tissue, and is clearly softer than ordinary non-applied tissue It is recognized as a differentiated product with a smooth touch. For example, a technique for externally applying an oily substance and a humectant has been introduced (Patent Document 1).

In this way, moisturizing tissue is recognized and consumption is increasing, but some moisturizing tissue heavy users leave moisturizers on their skin after biting their nose and feel sticky, and some dislike this Exists. Regarding this sticky feeling, a method for improving the sticky feeling by changing the chemical composition such as blending organic and inorganic powders as in Patent Document 2 is also known.
However, the conventional moisturizing tissue has the moist feeling, softness and smoothness that are its original characteristics, and because of its hygroscopicity, its paper strength is not strong compared to its thickness, so it strongly There was a problem that it was easily broken when it was bitten or when a sticky runny nose attached to the skin was wiped off. In addition, conventional moisturizing tissue reduces the above-mentioned stickiness that occurs as a price for its moist feeling, softness and smoothness, and there are no products that fully solve this fragility. It was.

Japanese Patent Laid-Open No. 4-9121 JP 2007-143664 A

  An object of the present invention is to provide a tissue paper that has a softness, smoothness, and moist feeling equal to or higher than those of conventional moisturizing tissue paper, and has reduced stickiness and tearability during use. .

The present invention that has solved the above problems is as follows.
<Invention of Claim 1>
A two-ply tissue paper with a chemical applied on its surface,
The chemical solution is applied only to one side of the two plies, the drug content is 2.0 to 5.5 g / m ^{2 on} both sides,
The basis weight per layer of the sheet constituting 2 plies is 10 to 25 g / m ² ,
2-ply paper thickness is 100-140 μm,
A tissue paper having a static friction coefficient of 0.50 to 0.65 measured by the following procedures (A) to (D) .
(A) The tissue paper is peeled off in one ply and attached to the acrylic plate so that the surface that was on the outer surface of the tissue paper at the time of two plies becomes the outside.
(B) A tissue paper different from the tissue paper is wound around a 100 g weight with 2 plies and placed on the tissue paper on the acrylic plate.
(C) Tilt the acrylic plate and measure the angle at which the weight slides down.
(D) The angle is measured in the MD direction of the tissue paper and in the CD direction of the tissue paper. The average angle is calculated by measuring a total of 8 times, 4 times each, and the tangent value is static friction. It is a coefficient.

<Invention of Claim 2>
The tissue paper of Claim 1 whose water content of the said chemical | medical solution is 1 to 15 weight%.

<Invention of Claim 3>
The tissue paper of Claim 1 whose moisture content is 10.0-13.0%.

<Invention of Claim 4>
The tissue paper of Claim 1 whose basic weight per layer of the sheet | seat which comprises 2 plies is 10-16 g / m < ² >.

<Invention of Claim 5>
The tissue paper according to claim 1, wherein the dry tensile strength in the CD direction of the two plies is 80 to 120 cN / 25 mm, and the wet tensile strength in the CD direction of the two plies is 33 to 60 cN / 25 mm.

<Invention of Claim 6>
The tissue paper of Claim 1 whose softness is 1.1-1.7 cN / 100mm.

<Invention of Claim 7>
A method for producing a two-ply tissue paper having a chemical applied to the surface,
The chemical solution is applied to only one side of two plies so that the drug content is 2.0 to 5.5 g / m ^{2 on} both sides,
The basis weight per layer of the sheet constituting the two plies of the tissue paper is 10 to 25 g / m ² ,
2-ply paper thickness is 100-140 μm,
A method for producing tissue paper, characterized in that the static friction coefficient measured by the following procedures (A) to (D) is 0.50 to 0.65 .
(A) The tissue paper is peeled off in one ply and attached to the acrylic plate so that the surface that was on the outer surface of the tissue paper at the time of two plies becomes the outside.
(B) A tissue paper different from the tissue paper is wound around a 100 g weight with 2 plies and placed on the tissue paper on the acrylic plate.
(C) Tilt the acrylic plate and measure the angle at which the weight slides down.
(D) The angle is measured in the MD direction of the tissue paper and in the CD direction of the tissue paper. The average angle is calculated by measuring a total of 8 times, 4 times each, and the tangent value is static friction. It is a coefficient.

By applying and infiltrating a chemical solution containing a predetermined amount of moisture into the sheet constituting the two-ply tissue paper, the crepe structure of the sheet is extended, and the tissue paper having a smooth surface is formed. Further, since the paper thickness is reduced and the fiber density is increased due to the elongation, the strength between fibers is increased, and a tissue paper having a high tensile strength in the CD direction, particularly a high wet tensile strength can be obtained. Whereas conventional moisturizing tissue applies a lotion solution to a thick base paper to create a film on the surface of the tissue to give the user smoothness, the present invention suppresses the thickness and the amount of solution applied, and provides a crepe structure. The surface is made smooth by stretching, thereby providing a smoothness higher than that of a conventional moisturizing tissue. In other words, the sticky feeling is reduced as a minimum amount of the lotion solution film on the tissue surface to make it feel smooth. Therefore, the drug content in the dry state is lower than that of conventional lotion type tissue paper, and it contains a sufficient amount of drug to exert its effect even though it does not easily cause stickiness when used. Therefore, it has enough moist and moisturizing properties. Furthermore, since the paper thickness is thin, it has a soft feeling in use as compared with the drug content.
As described above, the present invention provides a tissue paper that has a soft and smooth texture equal to or higher than that of a conventional moisturizing tissue, is less sticky than the conventional moisturizing tissue, and has a high tensile strength in the CD direction. It is.

It is a figure which shows the apparatus outline | summary of the ply process of the tissue paper of 1st Embodiment which concerns on this invention. It is the schematic which shows an example of a multi stand type inter folder, and has shown the state seen from the front. It is the schematic which shows an example of a multi stand type inter folder, and has shown the state seen from the side. It is the schematic which shows an example of a multi stand type inter folder, and has shown the state seen from the front. It is a longitudinal cross-sectional view of the folded tissue paper. It is a principal part expansion perspective view of the site | part regarding a folding plate. It is a principal part expansion perspective view which shows how to fold a secondary continuous sheet (tissue paper). It is a principal part expansion perspective view which shows how to fold a secondary continuous sheet (tissue paper). It is a principal part expansion perspective view which shows how to fold a secondary continuous sheet (tissue paper). It is a figure which shows a mode that the (a) tissue paper bundle | flux of 1st Embodiment is accommodated in the storage box. (B) It is a partially broken figure which shows a mode that the tissue paper accommodated in the storage box is taken out. It is a figure which shows the measuring method of the MMD value of tissue paper. It is a figure which shows the apparatus outline | summary of the ply process of the tissue paper of 2nd Embodiment which concerns on this invention. It is the schematic which shows an example of the chemical | medical solution application | coating process of an off machine. It is the schematic which shows an example of a rotary type | system | group interfolder. It is a figure which shows a mode that the (a) tissue paper bundle | flux of 2nd Embodiment is accommodated in the storage box. (B) It is a partially broken figure which shows a mode that the tissue paper accommodated in the storage box is taken out.

Hereinafter, embodiments of the present invention will be described in detail. The “drug content” in the present invention indicates the content of the drug component in a dry state (absolutely dry) contained in the unit area of tissue paper in the standard state of JIS P 8111. The content of components other than water in the chemical solution is shown.
[Example of structure]
The base paper of the tissue paper according to the present invention has a ply structure in which two thin papers (hereinafter also referred to as sheets) are laminated.

[Thin paper]
On the other hand, as the raw pulp of the thin paper (sheet) constituting the tissue paper according to the present invention, for example, mechanical pulp such as ground wood pulp (GP), pressure-rise ground wood pulp (PGW), thermomechanical pulp (TMP), etc. : Semi-chemical pulp (CP), softwood high yield unbleached kraft pulp (HNKP), softwood bleached kraft pulp (NBKP), hardwood unbleached kraft pulp (HNKP), hardwood unbleached kraft pulp (LUKP), hardwood bleached kraft pulp ( Chemical pulp such as LBKP): Waste paper pulp such as deinked pulp (DIP) and waste pulp (WP). The raw material pulp can be used by selecting one kind or two or more kinds. Preferably, a chemical pulp containing no filler or foreign matter is preferred. Further, the raw material pulp may contain woody materials such as straw pulp, bamboo pulp, kenaf pulp, and herbs.

  In particular, the raw material pulp is preferably a blend of NBKP and LBKP. Waste paper pulp may be blended as appropriate, but in terms of texture and the like, it is preferably composed only of NBKP and LBKP. In this case, the blending ratio is NBKP: LBKP = 20: 80 to 80:20. In particular, NBKP: LBKP = 30: 70 to 60:40 is desirable.

  On the other hand, in papermaking raw materials, other fiber raw materials include polyethylene terephthalate, polybutylene terephthalate, and polyester fibers such as copolymers thereof, polyolefin fibers such as polyethylene, polypropylene, and polystyrene, acrylics such as polyacrylonitrile and modacrylic. Fiber, polyamide fiber such as nylon 6, nylon 66, nylon 12, etc., synthetic fiber such as polyvinyl alcohol fiber, polyvinylidene chloride fiber, polyvinyl chloride fiber, urethane fiber, semi-synthetic fiber such as triacetate fiber, diacetate fiber, screw Include regenerated cellulose fiber such as coarse rayon, copper ammonia rayon, polynosic rayon, lyocell, and chemical fiber such as regenerated fiber spun from solution of collagen, alginic acid, chitin, etc. It is possible. The polymer constituting the chemical fiber may be in the form of a homopolymer, a modified polymer, a blend, a copolymer or the like.

  Raw materials such as pulp fibers are used as a base paper through, for example, a known papermaking process, specifically, a wire part, a press part, a dryer part, a size press, a calendar part, and the like. In this papermaking, for example, a dry paper strength enhancer, a wet paper strength enhancer, a softener, a release agent, a coating agent, a viscosity agent (knurl), a pH adjuster such as caustic soda, an antifoaming agent, a dye, etc. Chemicals can be added.

[US tsubo]
The rice paper weight per sheet of the tissue paper according to the present invention is preferably 10 to 25 g / m ² , more preferably 11 to 16 g / m ² . If the rice tsubo is less than 10 g / m ² , it is preferable from the viewpoint of improving softness, but it is difficult to ensure adequate strength that can withstand use. On the other hand, when the rice tsubo exceeds 25 g / m ² , the entire paper becomes hard, and a feeling of stickiness is generated, resulting in poor touch. In addition, the US tsubo is based on the US tsubo measurement method of JIS P 8124 (1998).

[Crepe rate]
The crepe rate of the primary raw sheet constituting the tissue paper of the present invention is 10 to 30%, more preferably 13 to 20%. Here, the crepe rate is expressed by the following equation.
Crepe rate: {(peripheral speed of the dryer during papermaking)-(peripheral speed of the reel)} / (peripheral speed of the dryer during papermaking) × 100.

[Medical solution]
Tissue paper of the present invention, the drug combined duplex 2.0~5.5g / m ^2, more preferably 3.0~5.0g / m ² containing. If the drug content is less than 2.0 g / m ² , the effect of the drug is not exhibited, and if it exceeds 5.5 g / m ² , the tissue paper has a sticky feeling and the wet paper strength is reduced.

  About the chemical | medical solution to apply | coat, a viscosity shall be 1-700 mPa * s at 40 degreeC from a viewpoint of performing high-speed processing. More preferably, it is 50 to 400 mPa · s. If it is less than 1 mPa · s, the chemical solution is likely to scatter on rolls such as anilox roll, printing plate roll, and gravure roll, and conversely if it is greater than 700 mPa · s, it is difficult to control the amount of application to each roll or continuous sheet. Ingredients include 70-90% polyol, 1-15% moisture, and 0.01-22% functional chemicals. The water content of the chemical solution to be applied was determined by the Karl Fischer method.

  Polyols include polyhydric alcohols such as glycerin, diglycerin, propylene glycol, 1,3-butylene glycol, polyethylene glycol, and derivatives thereof, and sugars such as sorbitol, glucose, xylitol, maltose, maltitol, mannitol, and trehalose.

  Functional agents include softeners, surfactants, inorganic and organic fine particle powders, oily components, and the like. Softeners and surfactants have the effect of imparting flexibility to the tissue and smoothing the surface, and anionic surfactants, cationic surfactants and zwitterionic surfactants are applied. Inorganic and organic fine particle powders have a smooth surface. The oil component has a function of improving lubricity, and higher alcohols such as liquid paraffin, cetanol, stearyl alcohol, and oleyl alcohol can be used.

  In addition, as a functional agent, one of a hydrophilic polymer gelling agent, collagen, hydrolyzed collagen, hydrolyzed keratin, hydrolyzed silk, hyaluronic acid or a salt thereof, ceramide, etc. A moisturizing agent such as any combination can be added.

  Deodorants such as flavors, emollients such as various natural extracts, vitamins, emulsifiers that stabilize compounding ingredients, antifoaming agents, antifungal agents, organic acids, etc. An agent can be appropriately blended. Furthermore, you may contain the antioxidant of vitamin C and vitamin E.

Of the above components, it is preferable to use a polyhydric alcohol such as glycerin or propylene glycol as a main component in order to stabilize the viscosity and coating amount of the chemical solution.
The temperature at the time of chemical solution application is preferably 30 ° C to 60 ° C, preferably 35 ° C to 55 ° C.

[Amount of application]
The coating amount was calculated from the difference between each sheet basis weight when the chemical solution after ply was not applied during operation and each sheet basis weight immediately after the corresponding application.
(Coating amount g / m ²⁾ = (basis weight g / m ² immediately after coating) - (the basis weight g / m ² in the case of not applying)
The coating amount of both surface layers or the total coating amount of both surfaces is the total coating amount per unit area of the plyed tissue paper sheet, and the coating amount of each sheet is added.

[Drug content]
The drug content refers to the content of the drug component in a dry state (absolutely dry) contained in the unit area of tissue paper in the standard state of JIS P 8111 (1998). Specifically, in the applied chemical solution The content of components other than moisture shall be indicated. The unit area of the tissue paper is an area of the plyed sheet viewed from a viewpoint perpendicular to the plane, and does not mean the total area of each plyed sheet and its front and back surfaces.

[Drug content]
The chemical application rate is the tissue paper product with a predetermined mass adjusted under the conditions of JIS P 8111 (1998) as the denominator (A) (g), and the water content in the chemical solution contained in the tissue paper product with the predetermined mass. The ratio of (B) divided by (A) is expressed as (%), with the removed mass (B) (g) as a molecule.
(Drug content%) = (B) ÷ (A) × 100 (%)

[Drug density]
The chemical solution density is the drug content per volume of two-ply tissue paper in the standard state of JIS P 8111 (1998).

[Paper thickness]
The paper thickness of the tissue paper according to the present invention is 100 to 140 μm, more preferably 120 to 140 μm in a 2-ply state. If the paper thickness is less than 100 μm, it is preferable from the viewpoint of improving the softness, but it is difficult to ensure adequate strength as tissue paper. On the other hand, when the thickness exceeds 140 μm, the texture of the tissue paper is deteriorated and a feeling of tingling is generated during use.

  As a method for measuring the paper thickness, the specimen is fully conditioned under the conditions of JIS P 8111 (1998), and then the dial thickness gauge (thickness measuring instrument) “PEACOCK G type” (manufactured by Ozaki Seisakusho) under the same conditions. It shall be measured in the state of 2 plies using. Specifically, confirm that there is no dust, dust, etc. between the plunger and the measuring table, lower the plunger on the measuring table, move the memory of the dial thickness gauge to adjust the zero point, and then Raise the plunger, place the sample on the test bench, slowly lower the plunger and read the gauge at that time. At this time, only the plunger is placed. The terminal of the plunger is made of metal so that a circular plane having a diameter of 10 mm is perpendicular to the plane of the paper, and the load at the time of measuring the paper thickness is about 70 gf. The paper thickness is an average value obtained by performing measurement 10 times.

[Tensile strength]
The tensile strength of the tissue paper according to the present invention is measured in a two-ply state.
The dry tensile strength is measured according to the tensile test method of JIS P 8113 (1998). Among them, it is cut into a width of 25 mm in the vertical direction and the horizontal direction under the standard conditions defined in JIS P 8111 (1998).

  The dry tensile strength of the tissue paper according to the present invention is 180 to 350 cN / 25 mm in the MD direction, more preferably 160 to 300 cN / 25 mm, 80 to 120 cN / 25 mm in the CD direction, and more preferably 80 to 110 cN / 25 mm. The ratio of the direction / CD direction is preferably 1.5 to 3.0.

  The wet tensile strength is determined according to JIS P 8135 (1998). The wet tensile strength of the tissue paper is 70 to 160 cN / 25 mm in the MD direction, more preferably 80 to 130 cN / 25 mm, and 33 to 50 cN / 25 mm, more preferably 35 to 45 cN / 25 mm in the CD direction.

[Softness]
The softness value of the tissue paper of the present invention is 0.9 to 1.5 cN / 100 mm. The softness here is measured based on the handle ohm method according to the JIS L1096 E method.
However, the test piece was 100 mm × 100 mm in size, and the clearance was 5 mm. The measurement was performed 5 times each in the longitudinal direction and the lateral direction with 1 ply, and the average value of all 10 times was represented by 2 digits of decimal point and expressed in units of cN / 100 mm.

〔Moisture percentage〕
The moisture content of the product is desirably 10.0 to 13.0%. The moisture content is determined based on JIS P 8127.
Moisture content (%) = {(weight of paper before drying) − (weight of paper after drying)} / (weight of paper before drying) × 100

〔Growth rate〕
The elongation in the MD direction of the product is desirably 11.0 to 15.0%. The elongation rate here is measured using “Universal Tensile Compression Tester TG-200N” manufactured by Minebea Co., Ltd. The elongation is the “stretch at break” described in “3. Definition e) of JIS P 8113.

[Static friction coefficient]
On the other hand, the tissue paper of the present invention desirably has a static friction coefficient of 0.50 to 0.65, more preferably 0.55 to 0.60. The static friction coefficient here is measured by the following method according to JIS P 8147 (1998).
The tissue paper peeled off in one ply is attached to the acrylic plate so that the outer surface of the tissue paper is on the outside. Wrap tissue paper around a 100 g weight with 2 plies and place it on the tissue on the acrylic plate. Tilt the acrylic plate and measure the angle at which the weight slides down. The angle is measured four times in the MD direction and four times in the CD direction for a total of eight times, the average angle is calculated, and the tangent value is taken as the coefficient of static friction.

[MMD]
MMD is an average deviation (unit: dimensionless) of the friction coefficient μ. MMD is one of the indices of smoothness. The smaller the numerical value, the smoother, and the larger the numerical value, the less smooth.
As a method for measuring the MMD value, as shown in FIG. 11A, a tension of 20 g / cm is applied to the contact surface of the friction element 112 in a predetermined direction (downward and rightward in FIG. 11A). While being brought into contact with the surface of the tissue paper 111, which is the measurement sample, at a contact pressure of 25 g, it is moved 2 cm at a speed of 0.1 cm / s in the same direction as the direction in which the tension is applied. At this time, the friction coefficient was measured using a friction tester KES-SE (manufactured by Kato Tech Co., Ltd.), and the average deviation of the friction coefficient μ at a friction distance of 2 cm (moving distance was 3 cm and excluding 5 mm before and after each). Was defined as the MMD value.
The friction element 112 has 20 piano wires P with a diameter of 0.5 mm adjacent to each other, and has a contact surface formed so that the length and width are both 10 mm. The contact surface is formed with a unit bulging portion whose tip is formed of 20 piano wires P (curvature radius 0.25 mm).
FIG. 11A schematically shows the friction element 112, and FIG. 11B shows an enlarged view of a portion surrounded by an alternate long and short dash line in FIG. 11A.

[Product density]
The tissue paper according to the present invention is folded by an interfolder or the like, and is cut into a product size at any stage before or after the folding process. For example, 180 sets are packed into a product. The paper density after 180 sets of folding is preferably 0.15 to 0.25 g / cm ³ , more preferably 0.17 to 0.23 g / m ³ . If it is lower than 0.15 g / cm ³ , moist feeling and smoothness cannot be obtained, and if it is higher than 0.25 g / cm ³ , the thickness of the tissue paper is impaired and a sticky feeling is produced, and the water absorption is deteriorated. End up.
The product density is the paper thickness (D) of tissue paper (2 ply) according to “PEACOCK G type”, which is a double value (C) of the tissue paper product tsubo conditioned under JIS P 8111 conditions. The unit is expressed in g / cm ³ and 3 decimal places.
((Density (g / cm ³ )) = (C (g / m ² )) × 2 ÷ (D (μm))

[First embodiment: Example of manufacturing method by on-machine coating]
The tissue paper of the present invention described above can be manufactured as follows. In FIG. 1, the outline | summary of the apparatus of the ply process of the tissue paper which concerns on this invention was shown. In addition, it is preferable to implement the process which concerns on FIG. 1 with the ply machine which is an apparatus integrated with the coating device (on-machine coating).

  The base paper produced by the paper machine is creped as a continuous sheet, calendered, and wound up to form primary rolls 11 and 12 (generally also called jumbo rolls). The

  The continuous sheets 31 and 32 are laminated by the laminating roller 13 to form two plies, and if necessary, calendered by the ply machine calendar 14 and sent to the chemical solution coating process. Any known coating method such as dipping, spray coating, flexo coating, and gravure coating can be used as the chemical coating method, but printing such as gravure coating and flexo coating that performs uniform chemical coating on the entire coated surface is possible. Use of the method, particularly the use of a flexo coater equipped with a doctor chamber 15, is more preferable because the chemical solution can be supplied in a stable coating amount.

  In the ply process of FIG. 1, two flexo coaters 16 and 17 are provided, and a chemical solution is applied to each surface of a two-ply continuous sheet.

When the flexographic printing method is used as the chemical solution applying means, the processing speed is 100 to 1100 m / min, preferably 350 to 1050 m / min, particularly preferably 450 to 1000 m / min. If it is less than 100 m / min, the productivity is low, and if it is more than 1100 m / min, uneven coating occurs and the chemical solution is likely to scatter. The number of lines of the flexographic printing plate roll is 10 to 60 lines, preferably 15 to 40 lines, and particularly preferably 20 to 35 lines. If the number of lines is less than 10, many coating irregularities occur. On the other hand, if the number of lines exceeds 60 lines, the paper dust tends to clog. The number of lines of anilox roll is 10 to 300 lines, preferably 25 to 200 lines, particularly preferably 50 to 100 lines. If the number of lines is less than 10, many coating irregularities occur. On the other hand, if the number of lines exceeds 300 lines, the paper dust tends to be clogged. The anilox roll has a cell capacity of 10 to 100 cc, preferably 15 to 70 cc, particularly preferably 30 to 60 cc. If the cell capacity is less than 10 cc, a desired coating amount cannot be obtained. On the other hand, if the cell capacity is more than 100 cc, the amount of chemical solution scattered increases.
The flexographic printing method can stabilize the coating amount even when the processing speed is high, and can stably apply a wide range of chemical viscosity with a single roll.

  When the gravure printing method is used as the chemical solution applying means, the processing speed is 100 to 1000 m / min, preferably 350 to 950 m / min, particularly preferably 450 to 950 m / min. When it is less than 100 m / min, productivity is low, and when it is more than 1000 m / min, coating unevenness occurs and the chemical solution is likely to be scattered. The number of gravure rolls is 40 to 160 lines, preferably 60 to 140 lines, particularly preferably 80 to 120 lines. If the number of lines is less than 40 lines, the amount of chemical solution scattered increases, whereas if the number of lines exceeds 160 lines, paper dust tends to be clogged.

  The sheet after application of the chemical solution is supplied to a contact embossing roller 18 and a roller roll 19 and fixed by subjecting a two-ply continuous sheet to a contact embossing (knurling) process. At this time, the continuous sheet 32 with a small amount of chemical solution applied is disposed so as to contact the contact embossing roller 18. The contact embossing is preferably applied uniformly in the vertical direction with a width of 1 to 10 mm at positions of 1/10 to 1/20 with respect to the paper width from both sides. Any of the known methods such as fixing the ply with an adhesive may be used. However, when using an adhesive, there is a problem that the touch tends to become hard, and it is easy to peel off when applying a chemical solution. It can be said that the use of embossing is more preferable.

2 ply continuous sheet with contact embossing is cut directly into product size after being subjected to folding processing by being directly applied to a rotary interfolder or the like, or after being cut into product width by slitter 20, The winding roll 21 makes a take-up secondary raw roll 22 which is folded and stored in a paper box.
In this embodiment, the chemical solution is applied before the contact embossing. However, the chemical solution may be applied after the contact embossing.

  The secondary raw roll described above is subjected to a folding process particularly in tissue paper products. As the folding process, a known method such as a rotary interfolder or a multi-stand interfolder can be used, but it is more preferable to use a multi-stand interfolder with high productivity.

[Multi-stand type inter folder]
A large number of secondary web rolls 22 are set in a multi-stand type interfolder, and a tissue paper bundle is manufactured by drawing out a secondary continuous sheet from the set secondary web roll 22 and folding and stacking them. Hereinafter, an example of the multi-stand type interfolder will be described.

  2 and 3 show an example of a multi-stand type interfolder. Reference numeral 2 in the drawing denotes secondary raw rolls 22, 22... Set on secondary raw roll support portions (not shown) of the multi-stand type interfolder 1. These secondary raw rolls 22, 22... Are set side by side in the direction (the horizontal direction in FIG. 2, the front-to-back direction in FIG. 3) in which the required number is orthogonal to the illustrated plane. Each secondary raw roll R has slits in the width of tissue paper product in the above-described manufacturing equipment and manufacturing method of the secondary raw roll for tissue paper products. It is wound and set in double width.

  The continuous belt-like secondary continuous sheets 63A and 63B unwound from the secondary raw roll 22 are guided by guide means such as guide rollers G1 and G1 and fed into the folding mechanism section 60. Moreover, the folding mechanism part 60 is provided with the folding plate group 64 in which the required number of folding plates P, P ... are arranged in parallel as shown in FIG. For each folded plate P, guide rollers G2, G2 and guide round bar members G3, G3 for guiding a pair of continuous secondary continuous sheets 63A or 63B are respectively provided at appropriate positions. Further, below the folded plates P, P..., A conveyor 65 is provided that receives and conveys the laminated band 67 that is stacked while being folded.

  A folding mechanism using this type of folded plates P, P... Is a known mechanism, for example, from US Pat. As shown in FIG. 5, this type of folding mechanism folds each continuous secondary continuous sheet 63A, 63B... In the Z-shape and is adjacent to the adjacent secondary continuous sheets 63A, 63B. Stack the ends together.

  FIGS. 6 to 9 show in detail the portions of the folding mechanism 60 that are particularly related to the folded plate P. FIG. In the folding mechanism 60, a pair of continuous secondary continuous sheets 63A and 63B are guided for each folded plate P. At this time, the continuous secondary continuous sheets 63A and 63B are guided by the guide round bar members G3 and G3 while being shifted in position so that the side end portions do not overlap each other.

  The continuous secondary continuous sheet that overlaps the lower side when guided by the folded plate P is the first continuous secondary continuous sheet 63A, and the continuous secondary continuous sheet that overlaps the upper side is the second continuous sheet. As shown in FIGS. 5 and 7, these continuous secondary sheets 63A and 63B are second continuous secondary continuous sheets of the first continuous secondary continuous sheet 63A. The side end e1 that does not overlap the sheet 63B is folded back to the upper side of the second continuous secondary continuous sheet 63B by the side plate P1 of the folded plate P, and as shown in FIG. 5 and FIG. The side end portion e2 of the continuous secondary continuous sheet 63B that does not overlap the first continuous secondary continuous sheet 63A is folded downward so as to be drawn under the folded plate P from the slit P2 of the folded plate P. . At this time, as shown in FIGS. 5 and 9, the side end e3 (e1) of the continuous secondary continuous sheet 63A stacked while being folded in the upstream folded plate P is second from the slit P2 of the folded plate P. Are guided between the folded portions of the secondary continuous sheet 63B. In this way, each continuous secondary continuous sheet 63A, 63B... Is folded in a Z shape and the side ends of adjacent continuous secondary continuous sheets 63A and 63B are crossed together, so that the product is used. In some cases, when the top tissue paper is pulled out, the side edge of the next tissue paper is pulled out.

  As shown in FIG. 2, the laminated band 70 obtained in the multi-stand type interfolder 6 as described above is cut (cut) at a predetermined interval in the flow direction FL by the cutting means 66 at the subsequent stage, and the tissue is cut. This tissue paper bundle 30a is further stored in the storage box B in the subsequent equipment as shown in FIG. 10 (a). In the multi-stand type interfolder 1 as described above, the paper direction of the laminated band 70 is the vertical direction (MD direction) along the flow direction FL, and the horizontal direction along the direction orthogonal to the flow direction. Direction (CD direction). For this reason, the direction of the paper of the tissue paper constituting the tissue paper bundle 67a obtained by cutting the laminated band 70 into a predetermined length is along the folding direction of the tissue paper as shown in FIG. The horizontal direction (CD direction) and the vertical direction (MD direction) along the direction orthogonal to the folding direction of the tissue paper.

  FIG. 10B shows an example of a product in which the tissue paper bundle 67a is stored in the storage box B. A perforation M is provided on the upper surface of the storage box B, and a part of the upper surface of the storage box B is broken by the perforation M so that the upper surface of the storage box B is opened. The opening is covered with a film F having a slit at the center, and the tissue paper T can be taken out through the slit provided in the film F.

  By the way, as described above, the direction of the paper of the tissue paper constituting the tissue paper bundle 67a is the horizontal direction (CD direction) along the folding direction of the tissue paper, as shown in FIG. When the tissue paper T is pulled out from the storage box B, the pulling direction is along the horizontal direction (CD direction) of the tissue paper T.

[Second Embodiment: Example of Manufacturing Method by Off-Machine Application]
The chemical-coated tissue paper according to the present invention can also be manufactured using an off-machine chemical-coated device. When performing off-machine chemical application, the ply process is performed using a ply machine as shown in FIG. The continuous sheets 31 and 32 from the primary raw rolls 11 and 12 are laminated by the laminating roller 13 to form two plies, and then supplied to the contact embossing roller 18 and the roller roll 19 without going through the chemical solution coating process.

  The two-ply continuous sheet provided with contact embossing is taken up by a winding roll 221 to form a secondary raw roll (not applied with a chemical) 222. The secondary raw roll is supplied to an off-machine chemical coating apparatus.

  The ply machine can be operated at 100 to 1100 m / min. However, when a rotary interfolder described later is used for folding, the current speed is to operate at 80 to 100 m / min because the operation speed of the interfolder is rate limiting.

[Off-machine chemical application device]
FIG. 13 shows a chemical liquid coating apparatus according to the second embodiment. In the illustrated example, the secondary raw sheet fed from the secondary original roll 222 is coated with a chemical solution by a flexo coater 216 provided with a doctor chamber 215. In the illustrated example, the chemical solution is applied only to one side of the two-ply secondary raw sheet, but may be applied to both sides. The sheet after applying the chemical solution is wound up by a winding drum 224 to form a tertiary raw roll 223. The tertiary material roll is supplied to a rotary interfolder and subjected to folding. In addition, after cutting a sheet | seat after chemical | medical solution application | coating to a product width through a slitter, you may wind up and make it into a tertiary original fabric roll, and you may fold by a multi-stand type inter folder.

[Rotary interfolder]
FIG. 14 shows an example of a rotary interfolder. In the rotary interfolder 300, the two tertiary raw sheets 301A and 301B after applying the chemical solution are successively fed to the folding rolls 303A and 303B via the feed rolls 302A and 302B, respectively. Cutter blades 304A and 304B are fixed above the folding roll, and the original fabric sheet is cut at the position of the cutting die 305 on the folding roll. Vacuum holes V are arranged on both sides of the top of the cutting die 305 so that the cut sheet is not detached from the roll, and the sheet is fixed on the roll by the action of the vacuum. The folding roll also has a folding mold 306, and the cutting mold 305 and the folding mold 306 are alternately arranged at equal intervals. The length on the roll circumference between the two cutting dies 305 is the same as the length in the MD direction of the tissue product, and the length on the roll circumference of the folding die 306 adjacent to the cutting 305 is half of that. The folding mold 306 also has a vacuum hole.

  The cutting and folding molds of the two folding rolls 303A and 303B, or the folding mold and the cutting mold are fitted by rotation. In the illustrated example, the sheet 301A and the sheet 301B are overlapped at the fitting position, and a crease is formed at a position where the sheet 301B overlaps the cutting line of the sheet 301A. The overlaid and creased sheets 301A and 301B are peeled off from the folding roll 303B by the vertical movement of the folding bar 307B. At the next mating position, the sheet 301A is creased and peeled off from the folding roll 303A by the folding bar 307A.

  As described above, by cutting and folding the sheets 301A and 301B alternately, the cut sheets 301A and 301B are folded so as to engage with each other. The folded sheet is cut in the product width (CD direction) and boxed (FIG. 15). In the tissue paper manufactured in the present embodiment, the pulling direction during use is the MD direction.

In order to confirm the effect of the present invention, Table 1 shows the results of evaluating the paper quality of the products of Examples and Comparative Examples according to the present invention.
An example is tissue paper manufactured using the manufacturing process shown in the second embodiment, in which chemical solution application is performed on one side and folding is performed using a rotary interfolder.

Comparative Examples 1 and 4 to 7 are commercially available products, Comparative Example 1 is a non-moisturizing general purpose tissue paper, Comparative Examples 4 and 5 are moisturizing lotion type tissue papers, and Comparative Examples 6 and 7 are non-humidifying systems. It is a high-quality tissue paper with a large thickness. Comparative Example 2 is a tissue paper manufactured by using the manufacturing process shown in the first embodiment of the present invention and reducing the amount of chemical solution applied. Further, Comparative Example 3 was manufactured by applying a chemical solution by double-sided coating by a gravure printing method in the manufacturing process shown in the second embodiment of the present invention, and applying a large amount of the chemical solution compared to the Example. Tissue paper.
The composition of the chemical solution applied to Examples and Comparative Examples 2 and 3 was adjusted as shown in Table 1.

  The measuring methods of rice tsubo, paper thickness, tensile strength, elongation rate, softness, static friction coefficient, and moisture content are as described in the section of the embodiment for carrying out the invention. The drug content indicates the ratio of the dry weight of the drug to the tissue paper basis weight.

Along with the evaluation of paper quality, sensory evaluation based on the following criteria was performed for the softness, smoothness, thickness, and moistness of 30 people in Examples and Comparative Examples 1-7. The sensory evaluation was performed based on the following criteria, with all results of Comparative Example 1 being a non-humidifying tissue paper set to 3.
5: Very good 4: Excellent 3: Equivalent to the standard 2: Inferior 1: Notably inferior Furthermore, regarding the chemical-coated tissue paper, the presence or absence of a sticky feeling was also evaluated.
○: Little sticky feeling ×: Clearly sticky feeling

The tissue paper according to the present invention showed high values of the dry tensile strength and the wet tensile strength in the CD direction as compared with a commercially available moisturizing tissue. The wet tensile strength in the CD direction was higher than that of conventional general-purpose tissue paper. It was also shown that the softness and static friction coefficient were lower than those of commercial products, and the paper was smooth and soft.
In sensory evaluation, the tissue paper according to the present invention is not excellent in thickness, but has a softness, smoothness, moist feeling equal to or higher than that of a moisturizing tissue, and a sticky feeling seen in a moisturizing tissue. I found out that it was alleviated.

  In particular, the following factors can be considered as factors that have good slipperiness for the tissue paper according to the present invention. Although it depends on the permeability of the chemical applied to tissue paper, when a chemical containing both hydrophilic and lipophilic components is applied, the hydrophilic components are absorbed into the pulp and the lipophilic components tend to remain on the paper surface. It is considered that surface friction is reduced. However, increasing the amount of chemical solution applied as in conventional moisturizing tissue, the hydrophilic component is not sufficiently absorbed into the pulp and remains on the surface, reducing the friction-reducing effect of the lipophilic component and hydrophilic components (such as glycerin). It is presumed that the slipperiness decreases due to the viscosity of.

  In Comparative Example 2 manufactured by reducing the amount of the chemical solution applied to the tissue paper according to the present invention, the tissue paper according to the present invention is more functional, although there is an advantage that it has excellent smoothness and no stickiness. In the evaluation, good results were obtained in softness and moist feeling.

  As described above, the tissue paper according to the present invention has a sticky feeling seen in conventional moisturizing tissue and has a softness, smoothness, and moist feeling equivalent to or higher than that of the moisturizing tissue. It turned out to be.

  The tissue paper of the present invention can be used for tissue paper that is used for wiping, particularly for wiping the body, and for facial use.

DESCRIPTION OF SYMBOLS 1 Multi stand type interfolder 11 Primary raw roll 12 Primary raw roll 15 Doctor chamber 16 Flexo coater 17 Flexo coater 20 Slitter 21 Winding drum 22 Original roll 60 Folding mechanism part 63 Secondary continuous sheet 65 Conveyor 67 Laminated belt 112 Friction element 215 Doctor chamber 216 Flexo coater 222 Secondary material roll 223 Tertiary material roll 300 Rotary interfolder

Claims (7)

A two-ply tissue paper with a chemical applied on its surface,
The chemical solution is applied only to one side of the two plies, the drug content is 2.0 to 5.5 g / m ^{2 on} both sides,
The basis weight per layer of the sheet constituting 2 plies is 10 to 25 g / m ² ,
2-ply paper thickness is 100-140 μm,
A tissue paper having a static friction coefficient of 0.50 to 0.65 measured by the following procedures (A) to (D) .
(A) The tissue paper is peeled off in one ply and attached to the acrylic plate so that the surface that was on the outer surface of the tissue paper at the time of two plies becomes the outside.
(B) A tissue paper different from the tissue paper is wound around a 100 g weight with 2 plies and placed on the tissue paper on the acrylic plate.
(C) Tilt the acrylic plate and measure the angle at which the weight slides down.
(D) The angle is measured in the MD direction of the tissue paper and in the CD direction of the tissue paper. The average angle is calculated by measuring a total of 8 times, 4 times each, and the tangent value is static friction. It is a coefficient.   The tissue paper of Claim 1 whose water content of the said chemical | medical solution is 1 to 15 weight%.   The tissue paper of Claim 1 whose moisture content is 10.0-13.0%. The tissue paper of Claim 1 whose basic weight per layer of the sheet | seat which comprises 2 plies is 10-16 g / m < ² >.   The tissue paper according to claim 1, wherein the dry tensile strength in the CD direction of the two plies is 80 to 120 cN / 25 mm, and the wet tensile strength in the CD direction of the two plies is 33 to 60 cN / 25 mm.   The tissue paper of Claim 1 whose softness is 1.1-1.7 cN / 100mm. A method for producing a two-ply tissue paper having a chemical applied to the surface,
The chemical solution is applied to only one side of two plies so that the drug content is 2.0 to 5.5 g / m ^{2 on} both sides,
The basis weight per layer of the sheet constituting the two plies of the tissue paper is 10 to 25 g / m ² ,
2-ply paper thickness is 100-140 μm,
A method for producing tissue paper, characterized in that the static friction coefficient measured by the following procedures (A) to (D) is 0.50 to 0.65 .
(A) The tissue paper is peeled off in one ply and attached to the acrylic plate so that the surface that was on the outer surface of the tissue paper at the time of two plies becomes the outside.
(B) A tissue paper different from the tissue paper is wound around a 100 g weight with 2 plies and placed on the tissue paper on the acrylic plate.
(C) Tilt the acrylic plate and measure the angle at which the weight slides down.
(D) The angle is measured in the MD direction of the tissue paper and in the CD direction of the tissue paper. The average angle is calculated by measuring a total of 8 times, 4 times each, and the tangent value is static friction. It is a coefficient.

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