JP4859973B2 - Method for producing foam cleaning agent and cleaning method - Google Patents

Description

The present invention relates to a method for producing a foam detergent and a washing method.

  Conventionally, solid detergents, liquid detergents, and the like are known as detergents for washing hair, skin and the like, but foam detergents are used because bubbles can be easily generated.

  Patent Document 1 discloses a foam cleaning composition comprising an anionic surfactant, a fatty acid alkylolamide, and a polyalkylene terephthalate. Moreover, the foam cleaning agent which filled the composition for foam cleaning agents in non-aerosol type foam discharge containers, such as a pump former and a squeeze foamer, is disclosed.

  However, since there is much content of surfactant in the composition for foam cleaning agents, there exists a problem that the discharge amount of surfactant by washing | cleaning increases. On the other hand, when the content of the surfactant in the foam cleaning composition is decreased, there is a problem that the cleaning property and the feeling in use are lowered.

JP 2007-161906 A

In view of the problems of the above-described conventional technology, the present invention provides a method for producing a foam cleaning agent capable of producing a foam cleaning agent having excellent detergency and use feeling even when the surfactant content is small. And it aims at providing the washing | cleaning method using the manufacturing method of this foamy washing | cleaning agent.

The invention according to claim 1 is a method for producing a foam cleaning agent by using a foam generating device having a screw rotated by a motor to generate foam by mixing the composition for foam cleaning agent and air. The foam viscosity at 30 ° C. of the foam cleaning agent 10 seconds after the generation of the bubbles and the average foam diameter of the foam cleaning agent after 30 seconds are 40 mPa · second to 100 mPa · second and 10 μm or more, respectively. The foam viscosity at 30 ° C. of the foam cleaning agent after 40 seconds after generating the foam and the average foam diameter of the foam cleaning agent after 60 seconds are 35 mPa · second or more and 150 μm or less, respectively. The foam detergent composition comprises water, a surfactant and a cationic polymer, and the content of the surfactant is 0.4% by mass or more and 12% by mass or less. the cationic po And the content of mer 1 mass% or more 0.1% by weight, viscosity of the 1500 mPa · sec or less than 5 mPa · sec at 30 ° C., the surfactant, amphoteric surfactant and anionic surfactant It is characterized by including.

The invention according to claim 2 is the method for producing a foam detergent according to claim 1 , wherein the cationic polymer is cationized cellulose and propyltrimonium chloride acrylamide / dimethylacrylamide copolymer. .

The invention described in 請 Motomeko 3 is a method of manufacturing a foam cleaning agent according to claim 1 or 2, wherein the foam detergent composition, characterized in that it further comprises an anionic polymer.

The invention according to claim 4 is the method for producing a foam detergent according to claim 3 , wherein the anionic polymer is xanthan gum.

Invention of Claim 5 is a manufacturing method of the foam cleaning agent of Claim 3 or 4 , In the composition for foam cleaning agent, content of the anionic polymer is 0.01 mass% or more It is 0.5 mass% or less.
The invention according to claim 6, in the manufacturing method of the foam cleaning agent according to any one of claims 1 to 5, wherein the amphoteric surfactant is cocamidopropyl betaine and 2-alkyl -N -Carboxymethyl-N-hydroxyethylimidazolinium betaine.
The invention according to claim 7 is the method for producing a foam cleaning agent according to any one of claims 1 to 6 , wherein the anionic surfactant is N-acyl-methyl taurine sodium and polyoxyethylene. It is characterized by being sodium lauryl ether sulfate.
Invention of Claim 8 is a manufacturing method of the foam cleaning agent as described in any one of Claims 1 thru | or 7 , The said surfactant further contains a cationic surfactant, It is characterized by the above-mentioned. .
The invention according to claim 9 is the method for producing a foam detergent according to claim 8 , wherein the cationic surfactant is dicocoylethylhydroxyethylmonium methosulfate.

The invention according to claim 10 is a method for producing a foam cleaning agent using the method for producing a foam cleaning agent according to any one of claims 1 to 9 , and the foam cleaning. It has the process of wash | cleaning using an agent.

According to the present invention, even with a small amount of surfactant, manufacturing preparation and該泡shaped detergent cleaning properties and used excellent feeling foam cleaning agent capable of generating a foam detergent A cleaning method using the method can be provided.

It is sectional drawing which shows an example of the foam generator which has a screw. It is a figure which shows the viscosity of the foaming detergent 10 to 40 seconds after generating foam. It is a figure which shows the average bubble diameter of the foam cleaning agent after generating a bubble 30 seconds and after 60 seconds.

  Next, the form for implementing this invention is demonstrated with drawing.

  The composition for foam cleaning agent of the present invention generates bubbles by mixing air, and the foam viscosity at 30 ° C. of the foam cleaning agent after 10 seconds and the average bubble diameter of the foam cleaning agent after 30 seconds. And 40 to 100 mPa · s and 10 to 100 μm, respectively, preferably 50 to 70 mPa · s and 10 to 80 μm, and used to generate bubbles and contain water and a surfactant. At this time, content of surfactant in the composition for foaming detergents is 0.4-12 mass%, and 5-10 mass% is preferable. Moreover, the viscosity at 30 ° C. of the foam cleaning composition is 5 to 1500 mPa · sec, preferably 300 mPa · sec or less.

  When the foam viscosity at 30 ° C. after 10 seconds after generating bubbles exceeds 100 mPa · second, or when the average bubble diameter after 30 seconds after generating bubbles is less than 10 μm, it becomes a kneaded or liquid form, respectively. The foamy form cannot be maintained. For this reason, a fine and creamy foamy detergent cannot be obtained, and the cleanability and the feeling of use are lowered. On the other hand, when the foam viscosity at 30 ° C. of the foam cleaning agent after 10 seconds after generating the foam is less than 40 mPa · second, or when the average foam diameter of the foam cleaning agent after 30 seconds after generating the foam is 100 μm When it exceeds, it becomes fine and it becomes difficult to maintain a creamy state.

  When the content of the surfactant in the foam detergent composition is less than 0.4% by mass, a fine and creamy foam detergent cannot be obtained, and the detergency and feel of use are reduced. If it exceeds 12% by mass, the amount of surfactant discharged by washing increases.

  When the viscosity at 30 ° C. of the foam detergent composition is less than 5 mPa · sec or more than 1500 mPa · sec, a fine and creamy foam detergent cannot be obtained, and the detergency and feel of use are excellent. descend.

  The composition for a foam cleaning agent of the present invention generates bubbles by mixing air, and the foam viscosity at 30 ° C. of the foam cleaning agent after 40 seconds and the average bubble diameter of the foam cleaning agent after 60 seconds are as follows: Are preferably not less than 35 mPa · s and not more than 150 μm, more preferably not less than 40 Pa · s and not more than 130 μm.

  When the foam viscosity at 30 ° C. of the foam cleaning agent after 40 seconds after generating foam is less than 35 mPa · s or when the average foam diameter of the foam cleaning agent after 60 seconds after generating foam exceeds 150 μm May be fine and difficult to maintain a creamy state.

  The viscosity of the foam detergent composition and the foam viscosity of the foam detergent can be measured using a B-type viscometer and a tuning-fork vibration viscometer SV-10 (manufactured by A & D), respectively. .

  The average bubble diameter of the foam detergent is calculated from the obtained image using a digital microscope VHX-200 (manufactured by Keyence Corporation) after the foam detergent is placed on a slide glass and sandwiched between cover glasses. can do.

  The surfactant is not particularly limited, but is a cationic surfactant such as stearyltrimethylammonium chloride, behenyltrimerylammonium chloride, dicocoylethylhydroxyethylmonium methosulfate; AMT taurine sodium, palm oil fatty acid methyl taurine sodium, poly Anionic surfactants such as sodium oxyethylene lauryl ether sulfate; amphoteric surfactants such as coconut oil fatty acid amidopropyl betaine and 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine You may use together. Among these, from the viewpoint of detergency, it is preferable to use an anionic surfactant and an amphoteric surfactant in combination.

  When the amphoteric surfactant is used as the surfactant, the foam cleaning composition of the present invention preferably further contains a cationic polymer or an anionic polymer.

  Although it does not specifically limit as a cationic polymer, A cationized cellulose, a cationized locust bean gum, a cationized starch, a propyltrimonium chloride acrylamide / dimethyl acrylamide copolymer etc. are mentioned, You may use together 2 or more types. Among them, cationized cellulose and / or propyltrimonium chloride acrylamide / dimethylacrylamide copolymer are preferable because of the excellent feeling of use of the foam detergent.

  The content of the cationic polymer in the foam detergent composition is usually 0.1 to 1% by mass, preferably 0.3 to 0.5% by mass. When the content of the cationic polymer is less than 0.1% by mass, the feeling of use of the foamy detergent may be lowered, and when it exceeds 1% by mass, the hair may be hardened by washing.

  Although it does not specifically limit as an anionic polymer, A carrageenan, a xanthan gum, etc. are mentioned, You may use 2 or more types together. Among these, xanthan gum is preferable because the use feeling of the foamy detergent is excellent.

  The content of the anionic polymer in the foam detergent composition is usually 0.01 to 0.5% by mass, preferably 0.05 to 0.1% by mass. When the content of the anionic polymer is less than 0.01% by mass, the feeling of use of the foamy detergent may be lowered, and when it exceeds 0.5% by mass, the hair may be hardened by washing.

  The foam cleaning composition of the present invention may further contain a moisturizing agent, a fragrance, a preservative, a pH stabilizer, a hair repair component, and the like.

  The foam cleaning agent can be used for cleaning hair, skin, and the like, and can be used, for example, as a shampoo, body shampoo, facial cleanser, and the like. Above all, it is effective when used as a shampoo.

  As a method for generating foam by mixing air into the foam cleaning composition, the foam viscosity at 30 ° C. of the foam cleaning agent after 10 seconds after generating the foam and the foam cleaning agent after 30 seconds Although it will not specifically limit if a bubble can be generated so that an average bubble diameter may be 40-100 mPa and 10-100 micrometers, respectively, It is preferable to use the foam generator which has a screw.

  FIG. 1 shows an example of a foam generating device having a screw. In the foam generating device 1, the hand insertion portion 3 is formed on the front side of the main body portion 2. Moreover, the operation part 4 is provided in the upper part of the main-body part 2, and if the user of the foam generation apparatus 1 operates the operation part 4, as will be described later, the foam cleaning agent A ′ is discharged from the discharge port 16. Discharged. Further, a lid 6 is provided on the top plate of the main body 2, and the lid 6 is opened when the foam cleaning composition A is loaded into the stock solution tank 5 in the main body 2. .

  Inside the foam generating device 1, a tank 5, a motor 7, a foam generating chamber 8, a screw 9 and an opening / closing valve 10 are provided.

  The operation unit 4 is provided with two shafts 12 and 17. The shaft 12 constitutes a part of an on-off valve 10 described later, and is attached to the main body 2 so as to be movable in the vertical direction (Z1-Z2 direction).

  The tank 5 is filled with the foam cleaning composition A. When the amount of the foam cleaning composition A in the tank 5 decreases, the lid 6 provided on the main body 2 is opened and the tank 5 is filled with the foam cleaning composition A. . Thus, the foam generator 1 can replenish the foam cleaning composition A.

  The motor 7 is configured to be driven and stopped by the ON / OFF operation of the switch 15. The switch 15 is connected to a shaft 17 disposed in the operation unit 4 and performs an ON / OFF operation by a pressing operation (operation in the Z1 direction) of the operation unit 4.

  The rotation shaft of the motor 7 protrudes into the bubble generation chamber 8. The rotation shaft of the motor 7 passes through the wall portion of the bubble generation chamber 8 and protrudes into the bubble generation chamber 8. The penetration portion is sealed and has a liquid-tight configuration. Further, a screw 9 is disposed at a portion of the rotating shaft of the motor 7 protruding into the bubble generating chamber 8. For this reason, the screw 9 is rotated by the motor 7.

  The bubble generation chamber 8 communicates with the tank 5, and an open / close valve 10 is provided at the communication portion 18 between the tank 5 and the bubble generation chamber 8. The valve body 13 of the opening / closing valve 10 is configured to be able to open / close the communication portion 18 between the tank 5 and the bubble generation chamber 8. When the valve element 13 is opened, the foam cleaning composition A flows into the foam generation chamber 8 from the tank 5. Moreover, when the valve body 13 is closed, the inflow of the foam cleaning composition A from the tank 5 into the foam generation chamber 8 is stopped.

  The valve body 13 is disposed at the lower end portion of the shaft 12. A coil spring 11 is disposed on the shaft 12, and the coil spring 11 always urges the shaft 12 in a direction (Z2 direction) in which the valve body 13 closes the communication portion 18.

  Furthermore, a suction port 14 is provided at the upper part of the end of the bubble generation chamber 8 in the X2 direction. When the screw 9 rotates, air flows into the bubble generation chamber 8 from the air suction port 14.

  When the operation unit 4 is pressed in the foam generating device 1, the switch 15 is turned on via the shaft 17 and the motor 7 is activated. Further, when the motor 7 is activated, the screw 9 starts to rotate in the bubble generation chamber 8.

  Further, when the operation unit 4 is pressed, the shaft 12 moves in the Z1 direction against the spring force of the coil spring 11, and the valve body 13 is opened. As a result, the foam cleaning composition A in the tank 5 flows into the foam generation chamber 8 via the communication portion 18.

  The screw 9 generates foam in the foam cleaning composition A by mixing and stirring the foam cleaning composition A that has flowed into the foam generation chamber 8 and sends it out in the X1 direction. At the end of the bubble generating chamber 8 in the X1 direction, a discharge port 16 that opens into the manual insertion portion 3 is formed, and the foam cleaning agent A ′ is discharged from the discharge port 16.

  On the other hand, when the user releases the pressing operation of the operation unit 4, the shaft 12 moves in the Z <b> 2 direction by the elastic restoring force of the coil spring 11, and the communication unit 18 is closed by the valve body 13. Thereby, the inflow of the foam cleaning composition A from the tank 5 to the foam generation chamber 8 is stopped. As the shaft 12 moves in the Z2 direction, the operation unit 4 also moves in the Z2 direction, and the shaft 17 also moves in the Z2 direction. Thereby, the switch 15 is turned off and the motor 7 is stopped. Further, by stopping the switch 15, the rotation of the screw 9 is also stopped, and the discharge of the foamy cleaning agent A ′ is also stopped.

  A method for washing hair, skin and the like using the foamy detergent A ′ is not particularly limited, and a method for washing hair, skin and the like using a known detergent can be used. As the foam cleaning agent A ′ used for washing hair, skin and the like, the foam cleaning agent A ′ immediately after generating bubbles by mixing air is preferable in consideration of cleanability and feel of use. However, it is not particularly limited as long as it is fine and creamy foam detergent A ′. For example, it is possible to use the foam cleaning agent A ′ after 30 seconds after mixing air to generate bubbles.

[Example 1]
Coconut oil fatty acid amidopropyl betaine solution 3.6% by mass
2-alkyl-N-carboxymethyl-N-
Hydroxyethylimidazolinium betaine 3.6% by mass
AMT taurine sodium 2.5% by mass
Sodium polyoxyethylene lauryl ether sulfate 0.6% by mass
Cationized cellulose 0.3% by mass
Propyltrimonium chloride acrylamide / dimethylacrylamide copolymer 0.5% by mass
Xanthan gum 0.05% by mass
Dicocoylethylhydroxyethylmonium methosulfate 0.3% by mass
Sorbit liquid 3.0% by mass
Sodium benzoate 0.3% by mass
Aqueous citric acid aqueous solution Appropriate amount Purified water Residue The above components were mixed by a conventional method to prepare a foam cleaning composition A. The viscosity of the foam cleaning composition A was measured at 30 ° C. using a B-type viscometer and found to be 45 mPa · s.

  Foam was generated in the foam cleaning composition A using a laser mate (Okuno Denki Sangyo Co., Ltd.) having the same configuration as the foam generating apparatus having the screw of FIG. 1 to generate foam cleaning agent A ′.

  FIG. 2 shows the measurement results of the foam viscosity of the foam detergent A ′ after 10, 20, 30, and 40 seconds after generating the foam. The foam viscosity of the foam detergent A ′ is an average value measured seven times at 30 ° C. using a tuning fork type vibration viscometer SV-10 (manufactured by A & D).

  FIG. 3 shows the average bubble diameter of the foam cleaning agent A ′ after 30 seconds and 60 seconds after generating bubbles. The average bubble diameter of the foam cleaning agent A ′ is obtained using a digital microscope VHX-200 (manufactured by Keyence Corporation) after the foam cleaning agent A ′ is placed on a slide glass and sandwiched between cover glasses. Calculated from the measured images.

  Next, when the hair was washed using the foam cleaning agent A ′ immediately after the generation of foam, the fine and creamy state was maintained, and the cleanability and feel of use of the foam cleaning agent A ′ were improved. I found it excellent.

  From the above, foam detergent A ′ having a foam viscosity after 10 seconds and an average foam diameter after 30 seconds of 40 to 100 mPa · second and 10 to 100 μm, respectively, is generated from the surfactant. It can be seen that even if the content is small, it is excellent in cleanability and use feeling.

[Comparative Example 1]
In the same manner as in Example 1 except that a commercially available pump former container (manufactured by Yoshino Kogyo Co., Ltd.) of a type in which a two-mesh is adopted is used instead of the laser mate (manufactured by Okuno Electric Industrial Co., Ltd.) Foam was generated in the cleaning composition A, and the foam viscosity of the foam cleaning agent A ′ after 10, 20, 30, and 40 seconds was measured.

  FIG. 2 shows the measurement results of the foam viscosity of the foam detergent A ′ after 10, 20, 30, and 40 seconds after generating the foam.

  FIG. 3 shows the average bubble diameter of the foam cleaning agent A ′ after 30 seconds and 60 seconds after generating bubbles.

  Next, when the hair was washed using the foam cleaning agent A ′ immediately after the generation of the foam, the foam was easy to disappear, the texture was fine and the creamy state was not maintained, and the foam cleaning agent A ′. It was found that the cleanability and feel of use of this product were low.

[Comparative Example 2]
A foam was generated in the foam cleaning composition A in the same manner as in Example 1 except that the wash wash face washing set EH2611P (manufactured by Panasonic) was used instead of the laser mate (manufactured by Okuno Electric Industrial Co., Ltd.). The foam viscosity of the foam cleaning agent A ′ after 10, 20, 30 and 40 seconds was measured.

  FIG. 2 shows the measurement results of the foam viscosity of the foam detergent A ′ after 10, 20, 30, and 40 seconds after generating the foam.

  FIG. 3 shows the average bubble diameter of the foam cleaning agent A ′ after 30 seconds and 60 seconds after generating bubbles.

  Next, when the hair was washed using the foam cleaning agent A ′ immediately after the generation of the foam, the foam was easy to disappear, the texture was fine and the creamy state was not maintained, and the foam cleaning agent A ′. It was found that the cleanability and feel of use of this product were low.

  From the above, since the foam cleaning composition A has a low surfactant content, a pump former container (manufactured by Yoshino Kogyo Co., Ltd.) and an Awash Wash Face Wash Set EH2611P (manufactured by Panasonic) are used. It can be seen that even when foam is generated in the foam cleaning composition A, the foam cleaning agent A ′ having a low cleaning property and a feeling of use is generated. On the other hand, in the foam cleaning composition A, the foam viscosity of the foam cleaning agent A ′ after 10 seconds and the average bubble diameter of the foam cleaning agent A ′ after 30 seconds are generated. It can be seen that when foams are generated so as to be 40 to 100 mPa · sec and 10 to 100 μm, respectively, a foamy cleaning agent A ′ having excellent detergency and use feeling can be obtained.

  Another example of the foam cleaning composition A is shown below.

[Composition for foam detergent (hair shampoo)]
As a surfactant, 4.0% by mass of lauryldimethylaminoacetic acid betaine and 0.2% by mass of stearyltrimethylammonium chloride, propylene glycol, cationized cellulose, xanthan gum, sodium benzoate, citric acid, phenoxyethanol, dye, fragrance, purification Water is mixed by a conventional method to prepare a foam detergent (hair shampoo) composition so that the viscosity at 30 ° C. is 5 to 1500 Pa · sec.

[Composition for foam detergent (hair shampoo)]
As a surfactant, 0.5% by mass of sodium polyoxyethylene lauryl ether sulfate, 0.5% by mass of sodium coconut oil fatty acid methyl taurine and 8.0% by mass of coconut oil fatty acid amidopropyl betaine solution, cationized guar gum, stearoxy Hydroxypropylamine, sorbit liquid, L-arginine, hydroxyethylurea, colorant, fragrance, and purified water are mixed by a conventional method to prepare a composition for a foam detergent (hair shampoo).

[Composition for foam detergent (hair shampoo)]
Polyoxyethylene sulfosuccinate disodium disodium 6.0% by mass, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 2.0% by mass and coconut oil fatty acid amidopropyl betaine solution as surfactants 1.0% by mass, polydimethylmethylenepiperidinium chloride, glycerin, cationized locust bean gum, alkyltrimethylammonium chloride, colorant, fragrance, and purified water are mixed in a conventional manner for foam detergent (hair shampoo) A composition is prepared.

[Composition for foam detergent (hair shampoo)]
As a surfactant, sodium taurine laurate 2.0% by mass, sodium polyoxyethylene lauryl ether sulfate 3.0% by mass, lauryl dimethylaminoacetic acid betaine 1.0% by mass and coconut oil fatty acid amidopropyl betaine solution 2.0 Mass%, propyltrimonium chloride acrylamide / dimethylacrylamide copolymer (purified water mixture), sorbite liquid, succinic acid, camellia oil, colorant, fragrance, purified water are mixed in a conventional manner for foamy detergent (hair shampoo) A composition is prepared.

[Composition for foam detergent (body shampoo)]
As surfactant, 6.0% by mass of triethanolamine laurate and 2.0% by mass of betaine lauryldimethylaminoacetate, glycerin, dipropylene glycol, camomila extract, trisodium edetate, preservative, colorant, fragrance, purification Water is mixed by a conventional method to prepare a composition for a foam detergent (body shampoo).

[Composition for Foam Cleaner (Face Cleansing Foam)]
As surfactant, stearic acid 0.05 mass%, lauric acid 2.0 mass%, myristic acid 3.0 mass%, potassium hydroxide 1.8 mass%, coconut oil fatty acid diethanolamide 0.3 mass% and Coconut oil fatty acid amidopropyl betaine solution 2.0% by mass, glycerin, polyethylene glycol 1500, sorbit solution, melissa extract, edetate trisodium, fragrance, purified water are mixed in a conventional manner for foaming detergent (facial cleansing foam) A composition is prepared.

[Composition for Foam Cleaner (Face Cleansing Foam)]
As a surfactant, N-methyltaurine sodium 2.0% by mass and lauryldimethylaminoacetic acid betaine 1.0% by mass, glycerin, dipropylene glycol, 1,3-butylene glycol, polyethylene glycol 1500, sorbit solution, laurin Acid, myristic acid, Izayoi rose extract, dipotassium glycyrrhizinate, trisodium edetate, fragrance, and purified water are mixed by a conventional method to prepare a composition for foaming detergent (face washing foam).

[Composition for foam detergent (hand soap)]
As a surfactant, lauric acid 3.0 mass%, myristic acid 1.0 mass%, triethanolamine 2.5 mass%, polyoxyethylene sulfosuccinate disodium lauryl 1.0 mass%, coconut oil fatty acid diethanolamide 0.5% by mass and coconut oil fatty acid amidopropyl betaine solution 2.0% by mass, propylene glycol, sodium chloride, edetate trisodium, fragrance, purified water are mixed in a conventional manner for foam detergent (hand soap) A composition is prepared.

[Composition for foam detergent (hand soap)]
As a surfactant, sodium tetradecene sulfonate solution 6.0% by mass, propylene glycol, polyoxyethylene lauryl ether, malic acid, eucalyptus oil, sodium benzoate, benzalkonium chloride solution, trisodium edetate, purified water Are mixed by a conventional method to prepare a composition for a foam detergent (hand soap).

DESCRIPTION OF SYMBOLS 1 Foam generator 2 Main body part 3 Manual insertion part 4 Operation part 5 Tank 6 Lid body 7 Motor 8 Foam generation chamber 9 Screw 10 Open / close valve 11 Coil spring 12 Shaft 13 Valve body 14 Suction port 15 Switch 16 Discharge port A Foam washing Composition A 'foam cleaning agent

Claims (10)

Using a foam generator having a screw rotated by a motor, a foam detergent is produced by mixing foam composition and air to generate foam,
The foam viscosity at 30 ° C. of the foam detergent 10 seconds after generating the foam and the average foam diameter of the foam detergent 30 seconds after are 40 mPa · second to 100 mPa · second and 10 μm to 100 μm, respectively. In addition, the foam viscosity at 30 ° C. of the foam cleaning agent after 40 seconds after generating the bubbles and the average foam diameter of the foam cleaning agent after 60 seconds are 35 mPa · second or more and 150 μm or less, respectively. Generate bubbles,
The foam detergent composition contains water, a surfactant and a cationic polymer, wherein the surfactant content is 0.4 mass% or more and 12 mass% or less, and the cationic polymer content. Is 0.1 mass% or more and 1 mass% or less, and the viscosity at 30 ° C. is 5 mPa · second or more and 1500 mPa · second or less,
The said surfactant contains an amphoteric surfactant and an anionic surfactant, The manufacturing method of the foam cleaning agent characterized by the above-mentioned.   The method for producing a foam detergent according to claim 1, wherein the cationic polymer is cationized cellulose and propyltrimonium chloride acrylamide / dimethylacrylamide copolymer. The method for producing a foam cleaning agent according to claim 1 or 2 , wherein the composition for foam cleaning agent further contains an anionic polymer. The said anionic polymer is a xanthan gum, The manufacturing method of the foaming detergent of Claim 3 characterized by the above-mentioned. The foamy detergent compositions, foam cleaning agent according to claim 3 or 4 content of the anionic polymer is characterized in that 0.5 wt% or less than 0.01 wt% Production method. 6. The amphoteric surfactant is coconut oil fatty acid amidopropyl betaine and 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, according to any one of claims 1 to 5. Method for producing a foam detergent. The method for producing a foamy detergent according to any one of claims 1 to 6 , wherein the anionic surfactant is sodium N-acyl-methyltaurine and sodium polyoxyethylene lauryl ether sulfate. . The method for producing a foam cleaning agent according to any one of claims 1 to 7 , wherein the surfactant further comprises a cationic surfactant. The method for producing a foamy detergent according to claim 8 , wherein the cationic surfactant is dicocoylethylhydroxyethylmonium methosulfate. A step of producing a foam cleaning agent using the method of producing a foam cleaning agent according to any one of claims 1 to 9 ,
A cleaning method comprising a step of cleaning using the foam cleaning agent.

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