JP4843375B2 - Switchgear - Google Patents

Description

The present invention is a so-called environmentally friendly switchgear that does not use SF6 gas such as an air-insulated switchgear including a vacuum valve, a high-pressure gas-insulated switchgear enclosing dry air, nitrogen and carbon dioxide, and a solid-insulated switchgear ( Green switchgear: environmentally-friendly switchgear).

  Conventionally, there are air-insulated switchgear (air-insulated switchgear), high-pressure gas-insulated switchgear, and solid-insulated switchgear as switchgear.

  The air-insulated switchgear has a problem that the entire switchgear becomes large in order to prevent insulation deterioration due to the installation environment and secure a sufficient insulation distance, and in order to remove dust etc., the main circuit part Need to be cleaned regularly.

The high-pressure gas-insulated switchgear is made compact by enclosing an insulating gas such as dry air, nitrogen, carbon dioxide, or SF6 gas in an airtight container. Of these, SF6 gas is expensive, and not only does it require a great deal of time and skill to produce an airtight container that encloses SF6 gas, but SF6 gas is extremely excellent in insulation performance,
Considering global warming, it is not preferable.

In this way, SF6 gas has been developed in consideration of the environment by developing a new switchgear that uses the aforementioned vacuum insulation, high-pressure gas insulation methods such as dry air, nitrogen, carbon dioxide, etc., and the aforementioned solid insulation using epoxy casting resin (See Patent Document 1).
JP2003-333715A

 With the trend toward environmentally friendly SF6 gas reduction, there is a tendency to use petrochemical materials such as epoxy resins and unsaturated polyester resins for reducing switchgear and designing reliability.

 Thermosetting resins such as epoxy resins have excellent durability performance, so their performance remains unchanged even after enduring use for many years, and they are important as materials that support social infrastructure, but at the stage of disposal Reuse and disassembly are difficult, and the idea of the disposal method itself becomes a social issue.

  In addition, the current social trend calls for a new function that breaks away from the society that has depended on oil, especially in terms of cooperation with the global environment, and does not rely on oil as much as possible. The same applies to an insulating structure material as a solid insulator that at least insulates the power application section.

  Therefore, an object of the present invention is to provide a switch gear in which environmental load factors, which are the fate of a resin material that requires durability, are reduced.

In order to achieve the above object, the invention corresponding to claim 1 does not use SF6 gas such as air insulated switchgear, high pressure gas insulated switchgear in which dry air, nitrogen and carbon dioxide are sealed , and solid insulated switchgear. In a switchgear in which at least the power application unit is insulated by a solid insulator,
The switchgear is characterized in that at least one of a wood material and a wood material extract is introduced into the solid insulator.

According to the invention corresponding to claim 1, wood material to the solid insulator, by introducing at least one of the wooden material extract reduced the environmental impact factors is fate of resin material required durability Switch gear can be obtained.

In order to achieve the above object, the invention corresponding to claims 2 to 8 is as follows. That is, invention corresponding to claim 2, wherein the wooden material is lignocellulosic, hemicellulosic, or xylo-saccharides its hydrolyzate product, crystalline cellulose or cello-saccharides its hydrolyzate products, Ru der either lignin 請 The switchgear according to claim 1.

According to the invention corresponding to claim 2, the wood material constituting the insulator is any one of lignocellulose, hemicellulose or xylooligosaccharides that are hydrolyzed products thereof, crystalline cellulose or cellooligosaccharides that are hydrolyzed products thereof, and lignin . By using it, the above-mentioned purpose can be achieved.

According to a third aspect of the present invention, a wooden material and an organic material are introduced into the solid insulator, and the organic material is at least one of an epoxy resin, an unsaturated polyester resin, a melamine resin, and a phenol resin. and thermosetting resins consisting of a switchgear according to engineering plastics, 請 Motomeko 1 Ru heat resistance of the thermoplastic resin der consisting of at least one or more modified polyethylene polycarbonate belong.

According to the invention corresponding to claim 3, a thermosetting resin or polycarbonate comprising at least one of an epoxy resin, an unsaturated polyester resin, a melamine resin, and a phenol resin belongs to the organic material constituting the insulator together with the wooden material. By using a high heat-resistant thermoplastic resin consisting of at least one of engineering plastics and modified polyethylene , without changing the insulation's heat resistance and mechanical properties, and changing the method of making the insulation such as molding and casting The above-mentioned purpose can be achieved.

According to a fourth aspect of the present invention, a wooden material, an organic material, and an inorganic material are introduced into the solid insulator, and the inorganic material includes glass fiber, hydrated alumina, crystalline silica, fused silica, carbonic acid. a switchgear according to 請 Motomeko 1 consisting of at least one calcium.

According to the invention corresponding to claim 4, insulation is achieved by using an inorganic material comprising at least one of glass fiber, hydrated alumina, crystalline silica, fused silica, and calcium carbonate as a material constituting an insulator together with an organic material. The aforementioned object can be achieved without deteriorating thermomechanical properties such as linear expansion coefficient and elastic modulus of the object.

According to a fifth aspect of the present invention, a wood material and an organic material are introduced into the solid insulator, and the organic material is a natural cellulose fiber composed of at least one of hemp, cotton, and kenaf. a switch gear as set forth in 請 Motomeko 1 that.

According to the invention corresponding to claim 5, achieved organic material constituting the insulator with wood material, hemp, cotton, and more to the use of natural cellulose fibers comprising at least one or more kenaf, the purpose of the above it can.

The invention corresponding to claim 6 is characterized in that the wooden material is lignocellulose, hemicellulose or a hydrolyzed product thereof, xylooligosaccharide, crystalline cellulose or hydrolyzed product thereof, which is obtained by allowing a strong acid to act on a wood resource. the product is a cello-saccharide, a switchgear according to lignin der Ru請 Motomeko 1.

According to the invention corresponding to claim 6, a xylooligosaccharide which is a lignocellulose, hemicellulose, or a hydrolyzed product thereof produced by neutralizing and purifying a wood material constituting an insulator by applying a strong acid to a wood resource. By using crystalline cellulose or cellooligosaccharides and lignin which are hydrolyzed products thereof, chemical plant processes such as pulp industry can be used as they are, and the above-mentioned object can be achieved.

The invention corresponding to claim 7 is characterized in that the wood material is lignocellulose, hemicellulose or a hydrolyzed product xylooligosaccharide, crystalline cellulose or a hydrolyzed product thereof produced by causing a hydrothermal reaction to act on a wood resource. The switchgear according to claim 1, wherein the switchgear is a cellooligosaccharide or lignin.

According to the invention corresponding to claim 7, lignocellulose, hemicellulose or xylooligosaccharides or crystals thereof, which are produced by causing a high-pressure hydrothermal reaction to act on woody resources, on the woody material constituting the insulator. By using cellulose or cellooligosaccharide and lignin which are hydrolyzed products thereof, the above-mentioned object can be achieved.

The invention corresponding to claim 8 is that the wood material is lignocellulose, hemicellulose or xylooligosaccharides that are hydrolyzed products thereof, crystalline cellulose or hydrolyzed products thereof, which are produced by allowing enzyme cellulase to act on wood resources. cello sugars, a switchgear according to lignin der Ru請 Motomeko 1.

According to the invention corresponding to claim 8, lignocellulose, hemicellulose or xylooligosaccharides that are hydrolyzed products thereof, crystalline cellulose or crystalline cellulose produced by allowing enzyme cellulase to act on woody materials on the woody material constituting the insulator By using the cellooligosaccharide, lignin, which is the hydrolyzed product, the aforementioned object can be achieved.

  ADVANTAGE OF THE INVENTION According to this invention, the switch gear which reduced the environmental load factor which is the fate of the resin material by which durability is calculated | required can be provided.

(Configuration of the embodiment)
Embodiments of the present invention will be described below with reference to the drawings.

 The present invention introduces at least one of a wood material or a wood material extract, a wood material and an organic material, a wood material, an organic material and an inorganic material into a solid insulator used for a switchgear described later. These specific materials will be described next.

 FIG. 1 is a structural formula 1 of cellulose showing an example of a wooden material. This cellulose is a cellulose obtained by using a strong acid hydrolysis method, a high pressure hydrothermal reaction method, and an enzymatic method as a starting material. The cellulose is obtained by combining (1 → 4) -β-glucoside bond 2 with glucose as a unit.

 There are many hydroxyl groups derived from the glucose skeleton in the cellulose straight chain, and there are many cases where hydrogen bonds are generated between adjacent cellulose chains and exist in a crystalline state. FIG. 2 shows the structure of the cellulose crystal 3. Since the residual hydroxyl group in the cellulose crystal reacts with the thermosetting matrix 4, as an embodiment using this property, the reactive organic filler is used in an amount of 5 to 200 weights with respect to the resin component of the insulating structural material constituting the switchgear. % Configuration is adopted.

 In this embodiment, corn cob used for enokitake cultivation is selected as the starting material wood material, hydrothermally treated at 180 ° C. and 1.48 MPa, and separated into lignocellulose and hemicellulose containing xylooligosaccharides, and basidiomycetes on the lignocellulose component Crystalline cellulose containing cellooligosaccharide treated with Kyowa Hakko's enzyme preparation doriserase derived from the fungus Irpex lacteus was used as a woody material (cellulose derivative). Lignocellulose is a plant cell wall-derived material in which lignin and cellulose are combined, and hemicellulose is a woody material (hemicellulose derivative) in which the glucose unit of cellulose structural formula 1 is D-xylose.

 On the other hand, there is a thermosetting matrix shown in FIG. 3 as an example of the organic material. As the structural formula, bisphenol A type epoxy resin and methyltetrahydrophthalic anhydride shown in FIG. 4 are used. The epoxy resin has an epoxy group 5 at the end of the structure. When heated in the presence of an appropriate catalyst such as an amine, ring-opening polymerization is initiated with methyltetrahydrophthalic anhydride. The hydroxyl group (—OH) present in the bisphenol A type epoxy resin affects the crosslinked structure of the resin. Similarly, the hydroxyl group (—OH) in the sugar skeleton of the cellulose derivative can also mediate in the resin curing reaction.

 In this embodiment, 50 parts by weight of lignocellulose, cellulose derivative and hemicellulose derivative are each 1 micron or less with respect to 100 parts by weight of bisphenol A type epoxy resin and 80 parts by weight of methyltetrahydrophthalic anhydride. The metal conductor is added in a vacuum similar to the method of preparing a switchgear insulator, usually by adding silica powder to a content of 70% by weight and adjusting the liquid casting material. The material was vacuum-cast into a mold in which was placed, and the insulating material released after heat curing at 100 ° C. for 3 hours was completely cured at 130 ° C. for 15 hours.

Here, a solid insulation switchgear, which is an example of an object to which the present invention is applied, will be described with reference to FIG. In this configuration, the bus connection conductor 10 and the cable 11 are electrically connected in series, and a disconnecting part 12 made of a vacuum valve, a blocking part 13 made of a vacuum valve,
The main circuit connection conductor 19 that electrically connects the breaker 13 and the cable 11, the current transformer 14 that detects the current flowing through the cable 11, and the operation rods 17 and 18 for opening and closing the disconnection part 12 and the breaker 13, respectively. Are provided with operation mechanisms 15 and 16 connected to each other, and these power-applying units, that is, the main circuit units are insulated and coated with the above-described solid insulator, specifically, the valve mold unit VM and the valve movable unit. A side mold part VMM, a bus connection mold part BM, and a main circuit connection mold part CM are provided.

 The operation mechanisms 15 and 16 described above are housed in the operation mechanism box 47, and the valve movable side mold portion VMM of the switch gear body described above is placed and fixed on the upper surface of the operation mechanism box 47. A control box 46 that houses a control circuit (not shown) for controlling the operation mechanisms 15 and 16, the disconnecting part 12, and the blocking part 13 is connected to the back side of the operation mechanism box 47.

 The valve mold part VM is obtained by covering the disconnection part 12 and the blocking part 13 with the solid insulating part 31, respectively, and provided with concave joints 32a and 32a on the upper part of the disconnection part 12 and the blocking part 13, respectively. 12 and the lower part of the blocking part 13 are respectively provided with convex joint parts 32b and 32b.

 The valve movable side mold part VMM is provided with a cylindrical solid insulating part 33 formed so as to surround the movable side conductors 20 and 21 of the disconnection part 12 and the blocking part 13. Recessed joint portions 34a and 34a that are respectively fitted to the convex joint portions 32b and 32b of the mold portion VM are provided.

 The bus bar connection mold part BM includes a solid insulating part 35 formed so as to surround the bus bar connection conductor 10, and a concave joint part 32a on the disconnection part 12 side of the valve mold part VM when the assembly is completed at the lower part thereof. A convex joint 36a to be joined is provided.

 The main circuit connection mold part CM is joined to the main circuit external lead-in cable joint 48 at the tip of the cable 11 and the end of the main circuit connection conductor 19, and the main circuit connection conductor 19 around the joint 48 is excluded. Is provided with a solid insulating portion 37 formed substantially in an L shape, and a convex portion to be joined to the concave joint portion 32a on the side of the shut-off portion 13 of the valve mold portion VM at the end of assembly at one end thereof. A joint portion 38a is provided.

 The outer peripheral surface of the solid insulating portion 31 of the valve mold portion VM and the outer peripheral surface excluding the joint portions 32a and 32b, and the outer peripheral surface of the solid insulating portion 33 of the valve movable side mold portion VMM and the operation rods 17 and 18 are disposed. The outer peripheral surface excluding the inner peripheral surface of the space and the joint 34a, the outer peripheral surface excluding the joint 36a of the outer peripheral surface of the solid insulating part 35 of the busbar connection mold part BM, and the solid insulating part 37 of the main circuit connecting mold part CM. Ground layers 39, 40, 41, and 42 are formed on the outer peripheral surface, excluding the joint portion 38a and the joint portion 48, respectively.

 In addition to this, the main circuit connecting conductor 19 that electrically connects one end of the cable 11 and the fixed side of the blocking portion 13, and the connection that connects the other end of the main circuit connecting conductor 19 and the fixed side of the blocking portion 13. The connection part 23 which connects the fixed part of the disconnection part 12, and the edge part of the bus-bar connection conductor 10 is provided. The movable side conductor 24 of the disconnecting portion 12 and the movable side conductor 25 of the blocking portion 13 are electrically connected, and the conductors 44 are provided that join the joining portions 34a and 34a and include the sliding current-carrying portions 43a and 43b. Yes.

 The busbar connection conductor 10 includes a rod-shaped conductor 10a and an L-shaped conductor 10b whose one end is connected to substantially the center of the rod-shaped conductor 10a.

 The bottom surface of the insulating portion 33 is a concave surface in which a hole (opening) 45 is formed. The ground layer 40 is applied to the surface of the insulating portion 33, but is not applied to the inner surface of the hole 45 and the joint portion 32b. The hole 45 of the valve movable side mold part 2 is sealed. A gas insulating medium such as air is sealed in the sealed hole 45.

(Operation of the embodiment)
The prepared liquid casting material showed a slight increase in viscosity due to the introduction of the wood material. However, casting in vacuum was possible without impairing workability, and the cured material composition shown in FIG. 5 was obtained. The glass transition temperature of the material after curing was 108 ° C., which was the same as before the introduction of the wood material, and the mechanical strength of 80 MPa was obtained. Further, the dielectric breakdown characteristics due to the flat plate and the sphere gap were 20 kV / mm, which was the same as that of the conventional material. Since this material characteristic was obtained, an insulation barrier and cast parts were manufactured and used for the solid insulation of the solid insulation switchgear shown in FIG.

(Effect of embodiment)
In general, cellulose and its derivatives have a glass transition temperature exceeding 200 ° C. and a glass transition point of the switchgear insulator greatly exceeding 90 to 150 ° C., so that the heat resistance is not impaired. In addition, the ideal tensile strength of cellulose is 160 MPa, and the strength of the highest liquid casting resin exceeds 100 MPa. Therefore, it is possible to suppress a decrease in strength caused by the introduction of natural materials.

The idea of carbon neutral is the idea of using the CO ₂ (carbon dioxide) circulation of plants on the earth as products, and by using carbon materials converted from biomass resources that are not fossil materials for many years, they are naturally decomposed naturally. Even if carbon that is converted into carbon dioxide is fixed and subjected to combustion disposal, it becomes difficult to participate in global warming. In switchgear, which constitutes the power distribution equipment necessary for social energy supply, material performance plays a major role in the social infrastructure, and it has been difficult to use carbon neutral materials such as polylactic acid from the viewpoint of quality performance. However, in this embodiment, the use of lignocellulose, a cellulose derivative, and a hemicellulose derivative makes it possible to introduce a carbon neutral material into the switchgear.

In the case of this embodiment, about 30% of the thermosetting resin component has been converted to a carbon neutral material. For the use of 100 kg of resin, 30 kg is a carbon neutral material, and the structure of the material (C6H12O5) n is 72 / 13.5 kg of 158 × 100 = 45% is the amount of carbon derived from natural materials. When this is converted into a CO ₂ fixed amount, about 50 kg of carbon is fixed. The combination with the thermosetting resin has high durability, and enables carbon fixation over a long period of time which does not easily decompose naturally.

  In addition, when cellulose is used at a temperature exceeding 250 ° C., if the property of being easily pyrolyzed than thermosetting resin is used, the heat is applied to the insulating material for switchgear of this embodiment. Separation of metal conductors in insulators, which would be difficult without using sufficient energy, is facilitated, and recycling application development becomes possible.

  The solid insulator made of the above-mentioned liquid casting material can satisfy all of the required heat resistance, dielectric breakdown strength, and mechanical strength in the bending and uneven shape unique to switchgear. Can be recycled by easy separation of the conductor and the solid insulator and carbon fixation. These are suitable for the disconnection part 12 and the interruption | blocking part 13 which consist of a vacuum valve which embeds a complicated shape and a different material.

(Other embodiments)
An unsaturated polyester resin was used as a thermosetting resin, and lignocellulose, a cellulose derivative, and a hemicellulose derivative were added in fine powders of 1 micron or less, and a molding material was prepared using glass fibers as a filling material. This can also be molded without deterioration of moldability and thermomechanical characteristics, and can be applied to an insulation barrier of an air-insulated switchgear. Moreover, if hemp and kenaf fiber are introduced into the filling material, the content of the wood material can be further increased.

According to the embodiment described above, the following operational effects can be obtained. That is, it can withstand long-term use without impairing thermal, mechanical, and electrical performance, and fixing CO ₂ during the use period of the product contributes to the reduction of CO _{2 as} a result. After use, carbon can be fixed and hardened even if it is buried underground, and has a function of utilizing microorganisms in a very long span. Also, even if the insulator is burnt and discarded after use, unlike the conventional switchgear, the emission of CO ₂ derived from fossil materials that significantly burdens the environment is greatly reduced due to the nature of the carbon neutral material. In this way, it is possible to supply a switchgear having a new function that reduces the environmental load factor that is the fate of the thermosetting resin material and reduces the dependence on petroleum, especially in terms of cooperation with the global environment.

(Modification)
In the above-described embodiment, the solid insulation switchgear is taken as an example of the subject of the present invention. However, the present invention is not limited to this. In the above-described embodiment, a wood material, a wood material extract, an organic material, and an inorganic material similar to those described above are introduced into a solid insulator disposed at least around the vacuum valve. The same effect can be obtained.

The figure which shows the structural formula of the cellulose derivative of the solid insulator of this invention. The figure showing the material structure of the solid insulator of this invention. The figure which shows the structural formula of the thermosetting resin epoxy which shows embodiment of this invention. The figure which shows the structural formula of the thermosetting resin modified acid anhydride which shows embodiment of this invention. The figure showing the insulating-material structure which shows embodiment of this invention. Sectional drawing of the solid insulation switchgear which shows embodiment of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 ... Cellulose structural formula, 2 ... (beta) glucoside bond, 3 ... Cellulose crystal, 4 ... Thermosetting resin matrix, 5 ... Epoxy group, 6 ... Silica, 7 ... Wood material, 8 ... Casting part insulator.
VM ... Valve mold part, VMM ... Valve movable side mold part, BM ... Busbar connection mold part, CM ... Main circuit connection mold part, 31, 33, 35, 37 ... Solid insulation part.

Claims (8)

It does not use SF6 gas, such as air insulation switchgear, high pressure gas insulation switchgear sealed with dry air, nitrogen and carbon dioxide , and solid insulation switchgear, so that at least the voltage applying part is insulated by a solid insulator. In the switchgear
A switchgear, wherein at least one of a wood material and a wood material extract is introduced into the solid insulator.   2. The switchgear according to claim 1, wherein the wood material is any one of lignocellulose, hemicellulose or xylooligosaccharides which are hydrolyzed products thereof, crystalline cellulose or cellooligosaccharides which are hydrolyzed products thereof, and lignin. .   A wooden material and an organic material are introduced into the solid insulator, and the organic material is a thermosetting resin or polycarbonate made of at least one of an epoxy resin, an unsaturated polyester resin, a melamine resin, and a phenol resin. 2. The switchgear according to claim 1, wherein the switchgear is a heat-resistant thermoplastic resin made of at least one of engineering plastics and modified polyethylene.   A wooden material, an organic material, and an inorganic material are introduced into the solid insulator, and the inorganic material is made of at least one of glass fiber, hydrated alumina, crystalline silica, fused silica, and calcium carbonate. The switchgear according to claim 1.   The wood material and the organic material are introduced into the solid insulator, and the organic material is natural cellulose fiber composed of at least one of hemp, cotton, and kenaf. The switchgear described.   The wood material is lignocellulose, hemicellulose or xylooligosaccharide that is a hydrolyzed product thereof produced by neutralizing and purifying a woody resource with a strong acid, cellooligosaccharide or lignin that is a crystalline cellulose or hydrolyzed product thereof. The switchgear according to claim 1, wherein the switchgear is provided.   The wood material is lignocellulose, hemicellulose or xylooligosaccharides that are hydrolyzed products thereof, crystalline cellulose or cellooligosaccharides that are hydrolyzed products, or lignin, which is produced by causing a hydrothermal reaction to act on wood resources. The switchgear according to claim 1, wherein   The wood material is lignocellulose, hemicellulose or xylooligosaccharides that are hydrolyzed products thereof, crystalline cellulose or cellooligosaccharides that are hydrolyzed products thereof, or lignin produced by allowing enzyme cellulase to act on wood resources. The switchgear according to claim 1.

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