JP4830323B2 - Method for producing dye-sensitized solar cell module - Google Patents

Description

The present invention relates to a method of manufacturing a dye-sensitized solar cell module having a plurality of cells.

  Dye-sensitized solar cells that can realize low cost, light weight, and colorful are attracting attention all over the world and are actively studied.

  Dye-sensitized solar cells have been around for more than 10 years since they were announced by Prof. Gretcher in Switzerland in 1991, but they are not yet commercialized despite their high performance. Together, it is envisaged that there are various technical difficulties compared to other solar cells.

  By the way, not only a dye-sensitized solar cell but a solar cell has a small electromotive force per cell, and a plurality of cells are connected in series to obtain a necessary voltage. When a plurality of cells are connected in series, a certain number of cells are often integrated from the viewpoints of downsizing and improving reliability.

  Dye-sensitized solar cells generally have a liquid electrolyte in the cell, so when multiple cells are arranged side by side in a dense state and electrically connected in series, the sealing property between adjacent cells Need to be high.

Conventional sealing techniques include (1) means for sealing with a so-called laminate film (aluminum foil is laminated with PET as the first layer and ionomer as the second layer, respectively), and (2) water. Means for sealing with glass are mentioned.
J. of Photochemistry and Photobiology, 164 (2004) p209-219 Nikkei Electronics, 2003. 9.15, P67-74 Solar Energy Materials and Solar Cells 44 (1996) p99-117

  However, in the means of (1), since the laminated films are adhered by being held between rolls, when applied to a dye-sensitized solar cell having a plurality of cells closely arranged in parallel, The adhesion of the laminate film was not sufficient. In addition, with the means (2), it is difficult to improve the dimensional accuracy of the adhesion, and water and sodium, which are components contained in the water glass, may elute into the electrolyte and deteriorate the battery performance. It was.

  The present invention has been made in view of the above circumstances, and provides a method for producing a dye-sensitized solar cell with improved sealing performance between cells when a plurality of cells are provided in a dense state. It should be a challenge.

(1) A method for producing a dye-sensitized solar cell of the present invention that solves the above problems includes a light-transmitting substrate provided on the light-receiving surface side of the module,
On the opposite side with respect to the light receiving surface side of the translucent substrate, and composed light pole of a transparent conductive film and the light-receiving electrode, facing at a predetermined distance on the opposite side of the light receiving surface of the light pole a counter electrode to the electrolyte filling between the optical electrode and the counter electrode, and a power generating unit cells are arranged in parallel are connected in series several electrical double comprising,
A moisture barrier member overturned be a surface opposite to moisture the power generation unit to the light-receiving surface side of the power generating unit,
Between prior Symbol plurality of cells to a method of manufacturing a solar cell module sensitized with an intermediate sealing portion rib-like partitioning between the cells,
The intermediate seal portion includes a spacer that regulates a distance between the translucent substrate and the moisture-proof member,
A plurality of said cells after placed on the translucent substrate, the fluid-like or is at a site before Symbol intermediate seal portion is provided comprising the steps of placing a solid adhesive material,
After the step of placing the adhesive material, the step of overlapping the moisture-proof member,
And a step of heating the portion where the intermediate seal portion is disposed to form the intermediate seal portion after the step of stacking the moisture-proof members .

  That is, by adopting a rib-shaped member as an intermediate seal portion that partitions a plurality of cells, it is possible to ensure the sealing property between the cells without adversely affecting the cells.

  Here, after the plurality of cells are placed on the translucent substrate, the intermediate seal portion is formed in a fluid state or a solid state between the plurality of cells, thereby improving the sealing property between the cells. can do. Here, the intermediate seal portion also functions to partition the cells and prevent the electrolyte from moving when the electrolyte is injected. For example, when the intermediate seal portion is integrated with the moisture-proof member, the effect of preventing the movement of the electrolytic solution during injection of the electrolytic solution cannot be expected so much, and a large residual stress may occur due to heat fusion.

  And as a material of an intermediate seal part, it can be comprised from the heat-adhesive material which has resin as a main component, such as polyolefin-type material which introduce | transduced the adhesive functional group. By introducing the adhesive functional group, it is possible to firmly bond, and the high barrier property of the polyolefin-based material can be sufficiently exhibited. By introducing a thermosetting functional group as an adhesive functional group, workability when sealing between cells at the intermediate seal portion can be improved. Also, by improving the affinity between the intermediate seal part and the part in contact with the intermediate seal part (for example, using the same kind of material), the bonding between the two can be completed with a simple operation Thus, a dye-sensitized solar cell that has high sealing performance between cells and can maintain high performance can be manufactured.

In particular, a modified polyolefin material having an adhesive functional group is preferred as the polyolefin material. Among these, modified polyethylene materials, modified polyisobutylene materials, modified ionomer materials, and modified polypropylene materials are desirable. Modified polyethylene material, (1) double bond iodine ions I contained no electrolyte ^- no reaction occurs between, (2) the bonding strength is high, it is possible by thermal fusion bonding or the (3) cold Other (4) Since the intermediate seal part can be made transparent, the translucency can be maintained, and the power generation output can be improved by guiding light to the photoelectrode by scattering light, etc. ) Since it is easy to dye, it is possible to make the intermediate seal part the same color as the cell, and there is an advantage that a solar cell in which the seam of the cell becomes seamless can be obtained.

  The modified polyisobutylene-based material has the advantages (1), (2), (4) and (5) described above. The modified ionomer material has the advantage of (6) excellent impact strength in addition to the advantages (1), (2), (3), (4) and (5) described above. The modified polypropylene material has the advantage of (7) excellent weather resistance and light resistance in addition to the advantages of (1) and (5).

  Moreover, it is desirable to employ a functional group containing a carboxy group or a salt thereof as the adhesive functional group. The “adhesive functional group” means a functional group that reacts with a material constituting a counterpart material (for example, transparent conductive film, translucent substrate, counter electrode, etc.) to form a strong bond, and other adhesive properties. A strong bonding can be realized by causing a crosslinking reaction or the like to proceed with the functional group and solidifying the intermediate seal portion itself.

  Here, as a method of bonding and forming the intermediate seal portion made of the heat-adhesive material, heating is performed through the light-transmitting substrate and / or the moisture-proof member after the step of placing the moisture-proof member. It can be performed by a step of forming the intermediate seal portion by pressurizing a portion where the intermediate seal portion is disposed by a mold. Sealing can be performed more reliably while reducing the influence on other parts by pressurizing the intermediate seal portion. In particular, by performing pressurization by pressurizing only a portion other than the cell, such as an intermediate seal portion, high sealing performance can be realized while preventing adverse effects on the cell. Here, a roll press can be adopted instead of the mold.

  Then, instead of heating the heat-adhesive material with a heated mold, the transparent conductive film or the heat-adhesive material contains an absorbent that absorbs light of a specific wavelength, and then irradiates a laser with a specific wavelength. A step of heating the thermally adhesive material.

  Moreover, a photocurable material (resin) can be adopted as the adhesive material. As a result, the influence of the heat on the cell can be reduced.

  In order to further improve the moisture resistance, it is desirable that the moisture-proof member includes a moisture-proof layer formed from a metal or an inorganic oxide. For example, a so-called laminate film in which a metal foil or the like is sandwiched between resin thin films. Here, it is desirable that the material of the portion in contact with the intermediate seal portion is a material having affinity (adhesiveness) for the intermediate seal portion. For example, it is desirable to employ the same modified polyolefin material as described above, for example, the same material as the intermediate seal portion.

Further, the intermediate seal portion that have a restriction to absence pacers the distance between the translucent substrate and the moisture barrier member. The interposed spacer can receive a pressure applied between the light-transmitting substrate and the moisture-proof member, and can effectively prevent a strong force from being applied to the cell.

  Here, it is desirable that an adhesive material layer is provided on the side of the moisture-proof member facing the cell. The adhesive material layer has affinity with the adhesive material forming the intermediate seal portion, and can adhere firmly, thereby preventing the liquid from flowing between adjacent cells. For example, the adhesive material layer may be formed of the same material as the intermediate seal portion.

  The manufacturing method of the dye-sensitized solar cell of this invention can make the sealing performance between these cells high, when a some cell is integrated. Therefore, design performance can be exhibited over a long period.

  A dye-sensitized solar cell to which the method for manufacturing a dye-sensitized solar cell of the present invention is applied has a configuration in which a plurality of cells are electrically connected in series and arranged in parallel. A plurality of cells are densely arranged on one side of the conductive substrate. Between the plurality of cells, there is a rib-shaped intermediate seal portion that partitions the cells. The intermediate seal portion is a member that prevents movement of an electrolyte solution between adjacent cells.

  The intermediate seal part has the same thickness as the cell or thicker than the cell (for example, the thickness before processing is preferably thicker than the cell, more preferably twice or more, especially three times or more). The electrodes are not crushed or the space filled with the electrolyte is lost and the electrodes are short-circuited. Moreover, even if the thickness of the intermediate seal portion is lower than the thickness of the cell (for example, about 1/2), by adopting a flexible member (a member on a film, such as a laminate film) as a moisture-proof member, The moisture-proof member can be deformed and bonded to the intermediate seal portion. That is, the “rib shape” as the shape of the intermediate seal portion is a shape that connects between the light-transmitting substrate that holds the cell and the moisture-proof member. In particular, the intermediate seal portion desirably has a shape (thickness, width, etc.) that allows the light-transmitting substrate and the moisture-proof member to be bonded so as not to adversely affect the cell.

  The intermediate seal portion is formed of a material that is chemically stable to the electrolytic solution and does not elute harmful substances into the electrolytic solution. Examples thereof include polyolefin materials such as polyisobutylene, polypropylene, and polyethylene that are excellent in chemical stability, copolymers thereof, and silicone polymers. In particular, modified polyolefin materials (modified polyethylene materials, modified polyisobutylene materials, modified ionomer materials, modified polypropylene materials) in which adhesive functional groups are introduced into these polyolefin materials are preferable. In addition, the material of the portion that contacts the intermediate seal part with a moisture-proof member is not particularly limited, but the adhesiveness is improved by selecting a material having high affinity such as the same material as the intermediate seal part, and the sealing property between cells. Can be improved.

Furthermore, a filler such as glass fiber can be introduced as necessary. As the filler, a spacer having a particle shape or the like that regulates the distance between the translucent substrate and the moisture-proof member can be contained. By adopting a size of the spacer that is about the same as or slightly larger than the thickness of the cell, it is possible to prevent unwanted unnecessary pressure from being applied to the cell.
By regulating the distance between the translucent substrate and the moisture-proof member, it is possible to prevent a short circuit between the transparent conductive film formed on the translucent substrate and the counter electrode in close contact with the moisture-proof member, and to inject an electrolyte Space can be secured. Here, since the use of a spherical shape as the shape of the spacer is preferable from the viewpoint of workability, it is preferable to use a material mixed with the spacer in advance when forming the intermediate seal portion. This is so as not to disturb the sex.

  Here, when a polyolefin-based material is employed for the intermediate seal portion, it is desirable to employ a material into which an adhesive functional group has been introduced for the purpose of improving adhesiveness. A carboxy group can be illustrated as an adhesive functional group. By introducing a carboxy group, the polarity is increased and the adhesion is improved. Further, by introducing a photocurable functional group or a thermosetting functional group that undergoes crosslinking by irradiation with light such as ultraviolet rays or heating, the intermediate seal portion can be formed more easily.

  An electrolyte can be used as the electrolyte. An electrolytic solution in which an electrolyte substance is dissolved in a solvent can be employed. As a solvent for the electrolytic solution, a nitrile compound such as acetonitrile, methoxyacetonitrile, propylonitrile, a solvent such as ethylene carbonate, propylene carbonate, butylene carbonate, γ-butyrolactone, or a mixed solvent thereof can be employed. . The electrolyte may be a solid electrolyte. Examples of the solid electrolyte include gels of the above electrolytic solutions, polymer electrolytes having iodine ion conductivity, inorganic electrolytes having iodine ion conductivity, and the like. The moisture-proof member has a purpose of preventing leakage of an electrolyte such as an electrolytic solution inside the dye-sensitized solar cell and a purpose of preventing oxygen, water vapor, and the like from being mixed from the outside.

(Constitution)
In the dye-sensitized solar cell module of this example, as shown in FIGS. 1 and 2, six elongated rectangular cells C are formed on a glass transparent substrate 1 (thickness 1.1 mm × 100 mm × 100 mm). It has two side-by-side structures. The cells have a strip shape having a width w and a thickness t, and are formed at a pitch of 12 mm on the translucent substrate 1 except for 5 mm at both ends. These cells C are electrically connected in series. The upper part of the cell C in FIG. 1 is covered with a laminate film (7, 8, 9, 8) as a moisture-proof member. The laminate film is laminated from the cell C side in the order of a film 7 as an adhesive material layer made of modified low density polyethylene, a film 8 made of PET, a thin film 9 made of aluminum, and a film 8 made of PET. The film 7 is in direct contact with the intermediate seal portion 6, and the adhesiveness is improved by adopting the same material as the intermediate seal portion 6 (Here, the film 7 and the intermediate seal portion 6 are made of different materials. Needless to say, the film 7 and the intermediate seal portion 6 are preferably formed of a material having high affinity (hereinafter the same).

  The cell C is composed of a transparent conductive film 2 (thickness 500 nm), a light receiving electrode 3 (thickness 10 μm), a separator 4 (thickness 5 μm), and a counter electrode 5 (thickness 30 μm), which are laminated on the light-transmitting substrate 1 in this order. Yes. The cell C is filled with a fluid electrolyte. The electrolytic solution is obtained by dissolving an electrolyte in an organic solvent. As the electrolyte, iodine which is a halogen is adopted. Iodine exists as an ion. The electrolytic solution is impregnated from the opposite side with respect to the photoelectrode of the counter electrode 2.

  The transparent conductive film 2 extends to the right in FIG. 1 beyond the boundary of the cell C, and is connected to the counter electrode 5 of the cell C adjacent on the right side. The counter electrode 5 is formed up to the transparent conductive film 2 side through the left end of the cell C, and is connected to the transparent conductive film 2 extending from the cell C adjacent to the left side.

The transparent conductive film 2 and the light receiving electrode 3 together function as a photoelectrode. The transparent conductive film 2 is formed of an SnO ₂ film doped with F or Sb or an ITO film. The light-receiving electrode 3 is formed by supporting a photosensitizing dye (having an electron-emitting property by light irradiation) on a porous N-type semiconductor (anatase-type titanium oxide).

  The separator 4 is disposed between the light receiving electrode 3 and the counter electrode 5 and is made of a rutile titanium oxide porous body.

  The counter electrode 5 faces the light receiving electrode 3 at a predetermined interval. The counter electrode 5 is formed from carbon fine particles. The counter electrode 5 can be formed of carbon or metal having high corrosion resistance with respect to iodine and conductivity. For example, titanium, tantalum, niobium, tungsten, platinum, or the like can be used.

  The cell C is partitioned by a rib-shaped intermediate seal portion 6. The intermediate seal portion 6 is formed between the cells C, and connects the transparent conductive film 2 extending from the cell C on the left side of the intermediate seal portion 6 and the moisture-proof member. The intermediate seal portion 6 is made of modified low-density polyethylene and has excellent adhesion to the film 7 of the laminate film. The intermediate seal portion 6 is made of silica and includes 10% by mass of a spherical spacer having a diameter (50 μm) slightly larger than the thickness t of the cell C. Suppressing deformation.

  An outer peripheral seal 61 is provided around the six cells C. The outer peripheral seal portion 61 is made of the same material as the intermediate seal portion 6. A carboxy group is introduced as an adhesive functional group in the modified low density polyethylene constituting the intermediate seal portion 6, the outer peripheral seal portion 61 and the film 7.

(Production method)
As shown in FIG. 3, after forming the transparent conductive film 2 on the translucent substrate 1 (FIG. 3A), unnecessary portions between the cells C are removed by scribing (FIG. 3 ( b)). The scribing of the transparent conductive film 2 can be performed with a YAG laser, a CO ₂ laser, or the like when a glass substrate is employed as the translucent substrate 1, or with a pin or the like when a resin substrate is employed.

  After forming the transparent conductive film 2, the light receiving electrode 3, the separator 4 and the counter electrode 5 are sequentially formed by printing by screen printing. That is, after printing by screen printing at a predetermined position, a drying process was performed in the order of the light receiving electrode 3, the separator 4 and the counter electrode 5.

  Here, the light receiving electrode 3 uses anatase-type titanium oxide fine particles having an average particle diameter of 20 nm, the separator 4 uses rutile-type titanium oxide fine particles having an average particle diameter of 280 nm, and the counter electrode 5 uses carbon fine particles. The light receiving electrode 3 had a thickness of 10 μm, the separator 4 had a thickness of 5 μm, and the counter electrode 5 had a thickness of 30 μm. .

  Thereafter, a photosensitizing dye dissolved in an acetonitrile / t-butanol mixed solution was soaked into the light receiving electrode 3 and adsorbed thereon. Thereafter, an intermediate seal portion 6 was formed (FIG. 3C). Then, an electrolytic solution was impregnated from the back side of the counter electrode 5.

  The intermediate seal portion 6 was formed of a modified low density polyethylene using a quantitative application device such as a dispenser. The quantitative coating apparatus applied the modified low density polyethylene heated to 180 ° C. between the cells C and around the cells C. In addition, the intermediate seal portion 6 can be provided by heating-type screen printing (Example 1-2) or previously formed into the shape of the intermediate seal portion 6 (Example 1-3).

  Then, it covered with a moisture-proof member. The intermediate seal part 6 completes adhesion by heating to a melting temperature via a moisture-proof member. Since this modified low density polyethylene has a carboxy group as an adhesive functional group, it is excellent in adhesiveness.

  In addition, when it has a thermosetting adhesive functional group, it thermosets by heating to the predetermined temperature which thermosetting develops. When it has a photocurable adhesive functional group, it is cured by irradiation with light.

  As a method for heating the intermediate seal portion 6, a heating mold 92 can be employed as shown in FIG. 4. First, after the process has proceeded until just before all components are arranged and bonded on the translucent substrate 1, the components are placed on the surface plate 91, and then heated and bonded by the heating mold 92 from above. . The heating die 92 is provided with a protrusion formed in accordance with the shape of the intermediate seal portion 6 so that no pressure is applied to portions other than the intermediate seal portion 6. The pressurizing condition was 60 kg for several seconds.

  Furthermore, it can replace with the method of performing pressurization using the surface plate 91 and the heating metal mold | die 92, and can pressurize by pinching in order by one set of heated rolls (Example 1-4). The pressurizing conditions with the roller were a linear pressure of 500 kg, a roller surface temperature of 180 ° C., and a speed of 50 mm / min.

  In the dye-sensitized solar cell module of this example, the material constituting the intermediate seal portion 6 is thermosetting polyisobutylene, has a low molecular weight and is fluid at room temperature, and further, a film as an adhesive material layer 7 has the same configuration as that of Example 1 except that it is made of a thermosetting polyisobutylene material having high affinity for the thermosetting polyisobutylene.

  When the intermediate seal portion 6 is disposed between the cells C, it is in a fluid state. Therefore, in manufacturing the solar cell module of this embodiment, the work is simplified and the adhesion can be improved. Furthermore, since the temperature at which thermosetting proceeds can be lowered, the risk of adverse effects due to heat on other elements constituting the cell C is reduced.

  In the dye-sensitized solar cell module of the present embodiment, the material constituting the intermediate seal portion 6 is ultraviolet curable polyisobutylene, has a low molecular weight and is fluid at room temperature, and is a film as an adhesive material layer 7 has the same configuration as that of Example 1 except that it is made of an ultraviolet curable polyisobutylene material having a high affinity for the ultraviolet curable polyisobutylene.

  The ultraviolet ray irradiation is performed from the translucent substrate 1 side, and is shielded so that the ultraviolet ray is not irradiated except for the intermediate seal portion 6 and the outer peripheral seal portion 61.

  When the intermediate seal portion 6 is disposed between the cells C, it is in a fluid state. Therefore, in manufacturing the solar cell module of this embodiment, the work is simplified and the adhesion can be improved. Furthermore, since UV curing generally proceeds rapidly, workability is improved.

  The dye-sensitized solar cell module of this example was replaced with an aluminum vapor deposition film (Example 4-1) or a silica vapor deposition film (Example 4-2) in place of the aluminum thin film 9 in the moisture-proof member. It has the same configuration as that of the first embodiment and is manufactured by the same manufacturing method as that of the first embodiment.

  The dye-sensitized solar cell module of this example has the same configuration as that of Example 1, and is manufactured by the same method except that the mechanism for heating the intermediate seal portion 6 and the outer peripheral seal portion 61 is different. That is, the transparent conductive film 2 is heated by irradiating the portion having the intermediate seal portion 6 and the outer peripheral seal portion 61 with a YAG laser having a wavelength that can be absorbed by the transparent conductive film 2, and the intermediate seal portion 6 is heated by the heat. And the outer periphery seal | sticker part 61 is also heated, it fuse | melts and thermal bonding is completed. The same manufacturing is possible by adopting a material that can absorb the wavelength of the corresponding laser after adopting a heat-sealing material or a thermosetting (thermo-crosslinking) material as the material constituting the intermediate seal portion 6 and the outer peripheral seal portion 61. The method becomes applicable.

[Comparative example]
The solar cell module of this comparative example was manufactured by the same configuration and manufacturing method as Example 1-4 except that the intermediate seal portion 6 was not provided and the temperature of the roll was 180 ° C.

[test]
About the manufactured solar cell module of each Example and Comparative Example, the open circuit voltage Voc was measured by irradiating light with an irradiation intensity of 100 mW / cm ² with a xenon lamp at a module temperature of 25 ° C. As a result, all the solar cell modules of the respective examples exhibited an open circuit voltage of 4.5V. This value indicates that there was no electrolyte bridge between the cells C because the open voltage of the single cell having the same configuration was 0.75V. This value did not change even after being left outdoors for 3 months, indicating high stability.

  On the other hand, in the solar cell module of the comparative example, variation occurred between the open circuit voltage of 0 and 2.3V. It can be inferred that this is because the sealing property between the adjacent cells C is not sufficient, and a micro short circuit occurs.

  As described above, it was found that by providing the intermediate seal portion, it is possible to provide a solar cell module that can exhibit high sealing performance and can maintain high performance. This advantage is presumed to be derived from the fact that the adhesion was improved by the adhesive functional group.

It is the cross-sectional schematic of the solar cell module manufactured in the Example. It is a top view of the solar cell module manufactured in the Example. It is the figure which showed one process of manufacturing the solar cell module of an Example. It is the figure which showed one process of manufacturing the solar cell module of an Example.

Explanation of symbols

    DESCRIPTION OF SYMBOLS 1 ... Translucent board | substrate 2 ... Transparent electrically conductive film 3 ... Light receiving electrode 4 ... Separator 5 ... Counter electrode 6 ... Intermediate seal part 61 ... Outer periphery seal part 7, 8, 9 ... Laminate film 91 ... Surface plate 92 ... Heating die

Claims (8)

A translucent substrate provided on the light-receiving surface side of the module;
On the opposite side with respect to the light receiving surface side of the translucent substrate, and composed light pole of a transparent conductive film and the light-receiving electrode, facing at a predetermined distance on the opposite side of the light receiving surface of the light pole a counter electrode to the electrolyte filling between the optical electrode and the counter electrode, and a power generating unit cells are arranged in parallel are connected in series several electrical double comprising,
A moisture barrier member overturned be a surface opposite to moisture the power generation unit to the light-receiving surface side of the power generating unit,
Between prior Symbol plurality of cells to a method of manufacturing a solar cell module sensitized with an intermediate sealing portion rib-like partitioning between the cells,
The intermediate seal portion includes a spacer that regulates a distance between the translucent substrate and the moisture-proof member,
A plurality of said cells after placed on the translucent substrate, the fluid-like or is at a site before Symbol intermediate seal portion is provided comprising the steps of placing a solid adhesive material,
After the step of placing the adhesive material, the step of overlapping the moisture-proof member,
And a step of heating the portion where the intermediate seal portion is disposed to form the intermediate seal portion after the step of stacking the moisture-proof members .   The method for manufacturing a solar cell module according to claim 1, wherein the intermediate seal portion is made of a heat-adhesive material whose main component is a polyolefin-based material into which an adhesive functional group is introduced. The method for manufacturing a solar cell module according to claim 2, wherein the adhesive functional group includes a carboxy group or a salt thereof. Wherein after the step of placing the moisture barrier member, through said light transmitting substrate and / or the moisture barrier member, heated mold or roll pressing by the pressurizing a portion the intermediate seal portion is disposed intermediate The manufacturing method of the solar cell module of Claim 2 or 3 which has the process of forming a seal | sticker part. The adhesive material contains an absorbent that absorbs light of a specific wavelength,
The manufacturing method of the solar cell module of Claim 4 which has the process of irradiating the laser of a specific wavelength and heating and adhere | attaching the said intermediate seal part instead of the process of pressurizing with the said heated metal mold | die. The moisture barrier member includes a moisture barrier is formed from a metal or an inorganic oxide, and method for manufacturing a solar cell module according to any of the film-like Der Ru claim 1-5. The manufacturing method of the solar cell module in any one of Claims 1-6 with which the adhesive material layer is provided in the side which faces the said cell of the said moisture-proof member. The said adhesive material layer is a manufacturing method of the solar cell module of Claim 7 currently formed with the same kind of material as the said intermediate seal part.

Images