JP4806844B2 - Rotation prevention device for marine organisms - Google Patents

Rotation prevention device for marine organisms Download PDF

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Publication number
JP4806844B2
JP4806844B2 JP2000371715A JP2000371715A JP4806844B2 JP 4806844 B2 JP4806844 B2 JP 4806844B2 JP 2000371715 A JP2000371715 A JP 2000371715A JP 2000371715 A JP2000371715 A JP 2000371715A JP 4806844 B2 JP4806844 B2 JP 4806844B2
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Japan
Prior art keywords
marine organisms
jellyfish
storage tank
odor
conveyor
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Expired - Fee Related
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JP2000371715A
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Japanese (ja)
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JP2002172381A (en
Inventor
恒夫 川崎
詔雄 川島
武男 浜田
孝文 村上
保一 生島
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Kansai Electric Power Co Inc
Kurita Water Industries Ltd
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Kansai Electric Power Co Inc
Kurita Water Industries Ltd
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Description

【0001】
【発明の属する技術分野】
本発明は海棲生物の腐敗臭発生防止装置に係り、特に、火力発電所や原子力発電所等の冷却水取水口のスクリーンから採取されるクラゲ等の海棲生物の腐敗臭を効率良く防止する装置に関するものである。
【0002】
【従来の技術及び先行技術】
発電所、化学コンビナート、製鉄所等のプラントでは、海水が工業用冷却水として大量に使用されているが、この海水の採水のための海水水路に押し寄せたクラゲ等の海棲生物を放置すると、配管閉塞、海水採水量の低下、冷却効率の低下、ひいては装置故障、発電装置等の装置稼動効率の低下等の様々な障害を引き起こすため、取水路入り口にスクリーンを設け、押し寄せたクラゲ等をかき揚げて採取している。採取したクラゲ等は、水切りコンベアーで移送し、一旦クラゲ貯留槽(一次貯留槽)に溜め、この貯留槽が一杯になるとポンプで別の二次貯留槽に移して処分するが、この貯留中にクラゲ等の海棲生物の腐敗が始まり、悪臭が発生するために、作業環境の悪化や周辺住民からの苦情等の問題が生じていた。
【0003】
このような海棲生物の腐敗臭は、主に、海棲生物の腐敗で発生した硫化水素(HS)、メチルメルカプタン(MM)、アンモニア(NH)等に起因するものである。
【0004】
従来、この海棲生物の腐敗臭を防止するために、マスキング剤や、金属塩、塩素系酸化剤、硝酸塩(特開平10−330206号公報)が使用されている。
【0005】
また、特願平11−298570号には、硫酸アルミニウム又はその塩、例えばカリウムミョウバン等を含む腐敗臭防止剤が提案されている。
【0006】
特に、カリウムミョウバンや硝酸塩であれば良好な腐敗臭防止効果が得られる。
【0007】
【発明が解決しようとする課題】
しかしながら、従来においては、一次貯留槽や二次貯留槽へのこれらの腐敗臭防止剤の投与は、ひしゃくやバケツで振り撒くか、或いはポンプにより注入することによって行っているため、クラゲ等の海棲生物量に対して適正量を投与することが困難であり、薬剤の過不足が生じていた。また、人手を要するため作業も繁雑であった。特に、クラゲが大量に揚がるときには、続々と投入されるクラゲの量を計量することが難しく、多くの場合、薬剤の注入量が不足することで腐敗臭を防止し得なかった。
【0008】
本発明は、上記従来の問題点を解決し、クラゲ等の海棲生物の引き揚げ量に応じて腐敗臭防止剤の適正量を自動的に薬注することができ、これにより薬注作業を軽減すると共に薬剤の過不足を防止して海棲生物の腐敗臭を確実に防止することができる海棲生物の腐敗臭発生防止装置を提供することを目的とする。
【0009】
【課題を解決するための手段】
本発明の海棲生物の腐敗臭発生防止装置は、海棲生物を貯留する貯留槽と、海棲生物を海水から分離して該貯留槽に移送する移送手段と、該移送手段の稼動装置と連動して該貯留槽に移送された海棲生物に腐敗臭防止剤として硫酸アルミニウムカリウムAlK(SO 又は硫酸アルミニウムナトリウムAlNa(SO を添加する薬注装置とを備えてなることを特徴とする。
【0010】
本発明の海棲生物の腐敗臭発生防止装置により、海棲生物の移送手段と連動させて腐敗臭防止剤の薬注を行うことで、引き上げられたクラゲ等の海棲生物の量の変動に対応した適正な薬注を行うことができ、人手を要することなく、簡便かつ確実に腐敗臭を防止することができる。
【0011】
即ち、一般にクラゲ等の海棲生物はスクリーンによって揚げられ脇に設けられた側溝に入り、水流で水切りコンベアーまで送られる。そして、水切りコンベアーで水が分離されつつ移送され、クラゲ等の海棲生物が貯留槽に投入される。
【0012】
従って、この水切りコンベアーと連動させて腐敗臭防止剤の注入ポンプを運転することにより、自動薬注が可能となる。特に、水切りコンベアーはクラゲ等の海棲生物の引き揚げ量に応じて回転数を変えることができるので、この回転数に比例させて薬注ポンプを制御して腐敗臭防止剤の注入量を調整すれば、クラゲ等の海棲生物量に応じた適正量の薬注が可能となる。
【0013】
【発明の実施の形態】
以下に図面を参照して本発明の実施の形態を詳細に説明する。
【0014】
図1は本発明の海棲生物の腐敗臭発生防止装置の実施の形態を示す模式図である。
【0015】
取水口のスクリーンから揚げられたクラゲは側溝1に入り、側溝1から水に押し流されて水切りコンベアー2に送られる。水切りコンベアー2では、水はコンベアーの網2Aを通過し下方に流れ落ちる。即ち、水切りコンベアー2は無限軌道状の網2Aがモーターで上下方向に移動しながら回転するものであり、さらに、網2Aの面と直角に網2Aの幅方向に押し上げ用の板2Bが取り付けてあり、網2Aで水を切りながら板2Bでクラゲをかき揚げる構造になっている。水切りコンベアー2で押し上げられたクラゲは、シュート3を経てクラゲ貯留槽4に落下し、更に移送ポンプ5で二次貯留槽(図示せず)に送られる。
【0016】
この実施の形態では、水切りコンベアー2からクラゲが落下する位置に薬注ポンプ6で腐敗臭防止剤を注入するが、この薬注ポンプ6は、水切りコンベアー2の稼動装置に連動し、好ましくはコンベアー2の回転数に基づいて回転数が多いときには薬注量を多く、回転数が少ないときには薬注量を少なくするように、薬注制御するように設定されている。
【0017】
前述の如く、水切りコンベアー2は、クラゲの量に応じて回転数を変えることができ、クラゲの量が多ければ高速回転(高速走行)で運転され、逆にクラゲの量が少なければ低速回転(低速走行)で運転されるため、この水切りコンベアー2の回転数に応じて、例えばこの回転数に比例して薬注ポンプ6の作動を制御することにより、クラゲの量に応じた適正量の腐敗臭防止剤を自動的に薬注することができる。
【0018】
なお、薬注装置としての薬注ポンプ6と連動させるコンベアーの稼動装置の具体例としては上述したコンベアーのベルト(網2A)の他、コンベアーを走行または停止させる運転スイッチや網2Aを走行させる回転体7、あるいは回転体7を駆動させるモータ(図示せず)などが挙げられる。
【0019】
そして、網2Aの走行速度、回転数、回転体7の回転数、回転体を駆動させるモータの回転数等と連動させて薬注ポンプ6の開閉を調整するようにすることで、クラゲの量に応じて薬注量を増減させることができる。
【0020】
本発明において、腐敗臭防止剤としては腐敗臭防止効果に優れることから硫酸アルミニウム塩を用いる。
【0021】
酸アルミニウム塩としては、硫酸アルミニウムカリウムAlK(SO(カリウムミョウバン)、硫酸アルミニウムナトリウムAlNa(SO(ナトリウムミョウバン)、好ましくはカリウムミョウバンが挙げられる。
【0022】
硫酸アルミニウム塩の添加量は、海棲生物の腐敗状況や用いる硫酸アルミニウム塩の種類等に応じて、腐敗臭が十分に防止される量となるように適宜決定されるが、一般的には、カリウムミョウバン(AlK(SO・12HO)等の硫酸アルミニウムの複合塩を用いる場合、水切りコンベアーから投入される海棲生物に対して50〜10000mg/L、特に500〜5000mg/L程度の濃度となるように添加するのが好ましい。硫酸アルミニウム塩は、取り扱い性、海棲生物との接触効率等の面から5〜30重量%、例えば10重量%程度の水溶液として用いるのが好ましい。
【0023】
なお、これらの腐敗臭防止剤の水溶液は、海水や工業用水、水道水等に腐敗臭防止剤を溶解させて調製するのが好ましい。
【0024】
図1では、腐敗臭防止剤をクラゲ貯留槽4のクラゲが落下する位置に投入しているが、腐敗臭防止剤はクラゲ貯留槽4のどの部分に投入しても良く、また、クラゲ貯留槽4を攪拌して均一化を図ることも有効である。
【0025】
【実施例】
以下に実施例を挙げて本発明をより具体的に説明する。
【0026】
実施例1
図1に示す実規模の水切りコンベアーとクラゲ貯留槽を使って以下の試験を実施した。
【0027】
先ず、クラゲ貯留槽に貯留されたクラゲを無薬注の状態で10日間放置してクラゲ貯留槽におけるクラゲの腐敗状況を硫化水素(HS)ガス濃度を測定して求めた。この結果を図2に示した。
【0028】
この結果、クラゲは直ちに腐敗が始まり、数日後にはHS濃度が3000〜4000ppmに達することを確認した。
【0029】
次に、水切りコンベアーと連動して薬注ポンプを作動させ、カリウムミョウバン水溶液を注入する方式で試験を行った。試験開始から8日間はクラゲの移送と薬注を行い、その後クラゲの移送、薬注とも停止した。この結果を図3に示した。
【0030】
図2において、Run−1は薬注ポンプを水切りコンベアーの運転スイッチと連動して作動した時の結果であり、Run−2は水切りコンベアーの回転数、具体的には網の回転数に合わせて薬注量も増減させたときの結果である。薬注の位置は水切りコンベアーからクラゲが落下する所である。これらの結果、カリウムミョウバンを注入することによりHSの発生を大幅に抑制できることを確認した。
【0031】
ただし、Run−1の場合、HS濃度に変動が認められる。これはクラゲの量に見合った量の薬注が必ずしも十分にできていない場合があることを示すものである。
【0032】
一方、Run−2におけるHS濃度は常時低いレベルで安定している。これはクラゲの増減に追従して薬注ができていることを示しているものである。なお、Run−2は、水切りコンベアーによって採取されるクラゲ量に対してカリウムミョウバンの12水塩として3000〜4000mg/Lになるように、水切りコンベアーの回転速度に対する10重量%カリウムミョウバン水溶液の薬注量を次のようにして注入したものである。
水切りコンベアーの網の回転数 薬注量
0.5〜2rpm 8〜35L/分
2〜3.5rpm 35〜70L/分
3.5〜5rpm 70〜150L/分
【0033】
この結果から、クラゲの水切りコンベアーと連動して腐敗臭防止剤の薬注ポンプを作動させる自動薬注システムが、クラゲの腐敗臭防止に有効であることが確認された。
【0034】
【発明の効果】
以上詳述した通り、本発明の海棲生物の腐敗臭発生防止装置によれば、繁雑な薬剤注入作業は不要となり、腐敗臭防止剤の適正量を自動的に薬注することにより、薬注量の過不足を防止して海棲生物の腐敗臭を確実に防止することができる。
【図面の簡単な説明】
【図1】 本発明の海棲生物の腐敗臭発生防止装置の実施の形態を示す模式図である。
【図2】 実施例1における無薬注時のHS濃度の経日変化を示すグラフである。
【図3】 実施例1における薬注時のHS濃度の経日変化を示すグラフである。
【符号の説明】
1 側溝
2 水切りコンベアー
3 シュート
4 クラゲ貯留槽
5 移送ポンプ
6 薬注ポンプ
7 回転体
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a device for preventing the occurrence of rot odor of marine organisms, and in particular, efficiently prevents the odor of marine organisms such as jellyfish collected from the screen of a cooling water intake of a thermal power plant or nuclear power plant. It relates to the device.
[0002]
[Prior art and prior art]
In plants such as power plants, chemical complexes, and steelworks, seawater is used in large quantities as industrial cooling water, but if jellyfish and other marine organisms rushed to the seawater channel for seawater sampling are left unattended In order to cause various obstacles such as piping blockage, reduction in seawater sampling volume, cooling efficiency, equipment failure, equipment operation efficiency such as power generation equipment, etc. Kakiage is collected. The collected jellyfish, etc. are transported by a draining conveyor, temporarily stored in a jellyfish storage tank (primary storage tank), and when this storage tank is full, it is transferred to another secondary storage tank by a pump and disposed. Corruption of marine organisms such as jellyfish began, and a foul odor was generated, which caused problems such as deterioration of the working environment and complaints from the surrounding residents.
[0003]
Such a rotting odor of marine organisms is mainly caused by hydrogen sulfide (H 2 S), methyl mercaptan (MM), ammonia (NH 3 ), etc. generated by the rotting of marine organisms.
[0004]
Conventionally, masking agents, metal salts, chlorinated oxidants, and nitrates (Japanese Patent Laid-Open No. 10-330206) are used to prevent the rot odor of marine organisms.
[0005]
Japanese Patent Application No. 11-298570 proposes a rotting odor inhibitor containing aluminum sulfate or a salt thereof, such as potassium alum.
[0006]
In particular, potassium alum or nitrate can provide a good antiseptic odor effect.
[0007]
[Problems to be solved by the invention]
Conventionally, however, these anti-corrosion odors are administered to the primary storage tank and the secondary storage tank by sprinkling with a ladle, a bucket, or by injecting with a pump. It was difficult to administer an appropriate amount with respect to the amount of organisms, resulting in excessive or insufficient drugs. Also, the work is complicated because it requires manpower. In particular, when a large amount of jellyfish is fried, it is difficult to measure the amount of jellyfish that is continuously added, and in many cases, the odor of spoilage cannot be prevented due to a shortage of the amount of medicine injected.
[0008]
The present invention solves the above-mentioned conventional problems, and can automatically inject an appropriate amount of anti-septic odor according to the amount of marine organisms such as jellyfish, which reduces the amount of chemical injection work. In addition, an object of the present invention is to provide a device for preventing the occurrence of rot odor of marine organisms, which can prevent the odor of rot of marine organisms reliably by preventing excess and deficiency of drugs.
[0009]
[Means for Solving the Problems]
The apparatus for preventing the occurrence of rot odor of marine organisms of the present invention includes a storage tank for storing marine organisms, a transfer means for separating marine organisms from seawater and transferring them to the storage tank, an operating device for the transfer means, It is provided with a chemical injection device for adding aluminum potassium sulfate AlK (SO 4 ) 2 or sodium aluminum sulfate AlNa (SO 4 ) 2 as an anti- corrosion agent to the marine organisms that are transferred to the storage tank in conjunction. It is characterized by.
[0010]
With the apparatus for preventing the generation of rot odor of marine organisms of the present invention, the amount of marine organisms such as jellyfish pulled up can be changed by injecting a rot odor inhibitor in conjunction with the means for transferring marine organisms. Corresponding appropriate chemical injection can be performed, and the rot odor can be prevented easily and reliably without requiring manual labor.
[0011]
That is, in general, marine organisms such as jellyfish are fried by a screen, enter a side groove provided on the side, and are sent to a draining conveyor by a water flow. Then, water is transferred while being separated by a draining conveyor, and marine organisms such as jellyfish are introduced into the storage tank.
[0012]
Therefore, automatic chemical injection can be performed by operating the injection pump of the antiseptic odor in conjunction with the draining conveyor. In particular, since the draining conveyor can change the number of rotations according to the amount of jellyfish and other marine organisms withdrawn, the injection rate of the rot odor inhibitor can be adjusted by controlling the chemical injection pump in proportion to the number of rotations. For example, an appropriate amount of medicine can be injected according to the amount of marine organisms such as jellyfish.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
[0014]
FIG. 1 is a schematic view showing an embodiment of a marine organism rotting odor generation preventing apparatus according to the present invention.
[0015]
The jellyfish fried from the screen of the water intake enters the side groove 1, is pushed into the water from the side groove 1, and is sent to the draining conveyor 2. In the draining conveyor 2, the water flows down through the conveyor net 2A. That is, the draining conveyor 2 is such that an endless track-like net 2A is rotated while being moved in the vertical direction by a motor, and a push-up plate 2B is attached in the width direction of the net 2A perpendicular to the surface of the net 2A. There is a structure in which jellyfish is scooped up with a plate 2B while draining water with a net 2A. The jellyfish pushed up by the draining conveyor 2 falls to the jellyfish storage tank 4 through the chute 3 and further sent to the secondary storage tank (not shown) by the transfer pump 5.
[0016]
In this embodiment, the antiseptic odor is injected by the chemical injection pump 6 to the position where the jellyfish falls from the draining conveyor 2, and this chemical injection pump 6 is linked to the operation device of the draining conveyor 2, and preferably the conveyor. Based on the rotational speed of 2, the chemical injection control is set so that the chemical injection amount is increased when the rotational speed is large and the chemical injection amount is decreased when the rotational speed is small.
[0017]
As described above, the draining conveyor 2 can change the number of rotations according to the amount of jellyfish. If the amount of jellyfish is large, the conveyor 2 is operated at high speed (high speed running). Therefore, by controlling the operation of the medicine pump 6 in proportion to the rotational speed of the draining conveyor 2, an appropriate amount of spoilage corresponding to the amount of jellyfish It can automatically dispense odor control agents.
[0018]
In addition, as a specific example of the conveyor operating device interlocked with the chemical injection pump 6 as the chemical injection device, in addition to the above-described conveyor belt (net 2A), an operation switch for running or stopping the conveyor and a rotation for running the net 2A are used. Examples thereof include a body 7 or a motor (not shown) that drives the rotating body 7.
[0019]
The amount of jellyfish is adjusted by adjusting the opening and closing of the medicinal pump 6 in conjunction with the traveling speed of the mesh 2A, the number of revolutions, the number of revolutions of the rotating body 7, the number of revolutions of the motor that drives the rotating body, and the like. The dosage can be increased or decreased depending on
[0020]
In the present invention, Ru using the or al sulfate aluminum salt which is excellent in corruption odor prevention effect as rancidity inhibitor.
[0021]
The sulfuric acid aluminum salt, sulfate aluminum potassium AlK (SO 4) 2 (potassium alum), aluminum sulfate Sodium AlNa (SO 4) 2 (sodium alum), with preference given to potassium alum.
[0022]
The addition amount of sulfuric acid aluminum salt, according to the type of corruption situation and using sulfuric aluminum salt sea棲生product be appropriately determined such that the amount of rancidity can be sufficiently prevented, generally When using a composite salt of aluminum sulfate such as potassium alum (AlK (SO 4 ) 2 · 12H 2 O), 50 to 10000 mg / L, particularly 500 to 5000 mg / L with respect to marine organisms introduced from a draining conveyor. It is preferable to add so that the concentration is about L. Sulfate aluminum salts, handling property, 5 to 30 wt% from the viewpoint of such contact efficiency between the sea棲生thereof, for example, is preferably used as an aqueous solution of about 10 wt%.
[0023]
In addition, it is preferable to prepare the aqueous solution of these decay odor inhibitors by dissolving the decay odor inhibitor in seawater, industrial water, tap water or the like.
[0024]
In FIG. 1, the rot odor preventing agent is put into the jellyfish storage tank 4 at the position where the jellyfish falls, but the rot odor preventing agent may be put into any part of the jellyfish storage tank 4, and the jellyfish storage tank. It is also effective to stir 4 to make it uniform.
[0025]
【Example】
Hereinafter, the present invention will be described more specifically with reference to examples.
[0026]
Example 1
The following tests were carried out using the full scale draining conveyor and jellyfish storage tank shown in FIG.
[0027]
First, the jellyfish stored in the jellyfish storage tank were allowed to stand for 10 days in a non-chemically poured state, and the jellyfish decay status in the jellyfish storage tank was determined by measuring the hydrogen sulfide (H 2 S) gas concentration. The results are shown in FIG.
[0028]
As a result, it was confirmed that the jellyfish began to rot immediately, and the H 2 S concentration reached 3000 to 4000 ppm after a few days.
[0029]
Next, a test was performed by operating a chemical injection pump in conjunction with a draining conveyor and injecting an aqueous potassium alum solution. Jellyfish transfer and drug injection were conducted for 8 days from the start of the test, and then both jellyfish transfer and drug injection were stopped. The results are shown in FIG.
[0030]
In FIG. 2, Run-1 is the result when the chemical injection pump is operated in conjunction with the operation switch of the draining conveyor, and Run-2 is in accordance with the rotational speed of the draining conveyor, specifically the rotational speed of the net. It is a result when the amount of chemical injection is also increased or decreased. The medicinal position is where the jellyfish fall from the draining conveyor. As a result, it was confirmed that the generation of H 2 S can be significantly suppressed by injecting potassium alum.
[0031]
However, in the case of Run-1, a change is observed in the H 2 S concentration. This indicates that there may be cases where the amount of drug injection commensurate with the amount of jellyfish is not always sufficient.
[0032]
On the other hand, the H 2 S concentration in Run-2 is always stable at a low level. This indicates that the medicine is being delivered following the increase and decrease of jellyfish. In addition, Run-2 is a chemical injection of 10% by weight potassium alum aqueous solution with respect to the rotation speed of the draining conveyor so that the amount of jellyfish collected by the draining conveyor is 3000 to 4000 mg / L as 12 salt of potassium alum. The amount was injected as follows.
Number of rotations of draining conveyor net Chemical dosage 0.5-2 rpm 8-35 L / min 2-3.5 rpm 35-70 L / min 3.5-5 rpm 70-150 L / min
From this result, it was confirmed that the automatic chemical injection system that operates the chemical injection pump of the rot odor prevention agent in conjunction with the drainage conveyor of jellyfish is effective in preventing the rot odor of jellyfish.
[0034]
【The invention's effect】
As described in detail above, according to the apparatus for preventing the occurrence of rot odor of marine organisms of the present invention, complicated drug injection work is not required, and the appropriate amount of the rot odor preventive agent is automatically dispensed. The amount of excess and deficiency can be prevented and the rot odor of marine organisms can be surely prevented.
[Brief description of the drawings]
FIG. 1 is a schematic diagram showing an embodiment of a marine organism rotting odor generation preventing apparatus according to the present invention.
2 is a graph showing daily changes in H 2 S concentration during no drug injection in Example 1. FIG.
3 is a graph showing daily changes in H 2 S concentration at the time of drug injection in Example 1. FIG.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Side groove 2 Draining conveyor 3 Chute 4 Jellyfish storage tank 5 Transfer pump 6 Chemical injection pump 7 Rotating body

Claims (2)

海棲生物を貯留する貯留槽と、海棲生物を海水から分離して該貯留槽に移送する移送手段と、
該移送手段の稼動装置と連動して該貯留槽に移送された海棲生物に腐敗臭防止剤として硫酸アルミニウムカリウムAlK(SO 又は硫酸アルミニウムナトリウムAlNa(SO を添加する薬注装置とを備えてなる海棲生物の腐敗臭発生防止装置。
A storage tank for storing marine organisms, a transfer means for separating marine organisms from seawater and transferring them to the storage tank;
A chemical injection in which potassium aluminum sulfate AlK (SO 4 ) 2 or sodium aluminum sulfate AlNa (SO 4 ) 2 is added as an anti- corrosion agent to marine organisms transferred to the storage tank in conjunction with the operating device of the transfer means. An apparatus for preventing the generation of rot odors of marine organisms.
該移送手段がコンベアーであり、
該薬注装置は該コンベアーの回転数に基づいて腐敗臭防止剤を薬注制御することを特徴とする請求項1に記載の海棲生物の腐敗臭発生防止装置。
The transfer means is a conveyor;
2. The apparatus for preventing the occurrence of rot odor of marine organisms according to claim 1, wherein the chemical injection device performs chemical injection control of the rot odor inhibitor based on the number of rotations of the conveyor.
JP2000371715A 2000-12-06 2000-12-06 Rotation prevention device for marine organisms Expired - Fee Related JP4806844B2 (en)

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JP5247208B2 (en) * 2008-03-31 2013-07-24 中国電力株式会社 Jellyfish processing system and method for controlling jellyfish processing system
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