JP4801599B2 - Manufacturing method of anticorrosion water pipe - Google Patents
Manufacturing method of anticorrosion water pipe Download PDFInfo
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- JP4801599B2 JP4801599B2 JP2007012377A JP2007012377A JP4801599B2 JP 4801599 B2 JP4801599 B2 JP 4801599B2 JP 2007012377 A JP2007012377 A JP 2007012377A JP 2007012377 A JP2007012377 A JP 2007012377A JP 4801599 B2 JP4801599 B2 JP 4801599B2
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Description
この発明は、防食塗装水道管の製造方法、特に、水質に悪影響を及ぼさず、厚塗り塗装が可能であることから高い防食性能を長期間に亘って維持することができると共に耐衝撃性に優れ、しかも、内外面同時塗装が可能であり、さらに、塗装後、急冷することによって、直ちに使用可能な状態になる防食塗装水道管の製造方法に関するものである。 This invention is a method for producing a corrosion-resistant water pipe, and in particular, it can maintain a high anti-corrosion performance over a long period of time and has excellent impact resistance because it does not adversely affect water quality and can be thickly coated. In addition, the present invention relates to a method for producing a corrosion-proof coated water pipe that can be painted simultaneously on the inner and outer surfaces, and is immediately ready for use by rapid cooling after painting .
従来、水道用あるいは下水道用等に使用されている塗装金属製管において、内面塗装は、2液の液状エポキシ樹脂塗料あるいはエポキシ樹脂粉体塗料等が使用され、外面塗装は、一般的に、液状の合成樹脂塗料が使用されている。 Conventionally, in coated metal pipes used for water supply or sewerage, two-part liquid epoxy resin paint or epoxy resin powder paint is used for inner surface coating, and outer surface coating is generally liquid. Synthetic resin paints are used.
特許文献1(特開2003−11253号公報)には、エポキシ樹脂の成分を特定したエポキシ樹脂粉体塗料を塗装した金属管が開示されている。 Patent Document 1 (Japanese Patent Laid-Open No. 2003-11253) discloses a metal tube coated with an epoxy resin powder coating material in which an epoxy resin component is specified.
内面塗装にエポキシ樹脂粉体塗料を使用する場合、エポキシ樹脂粉体塗料には、溶剤が含有されておらず、予熱した金属製管に塗装することから、乾燥に時間がかからず、しかも、水質に悪影響を及ぼす懸念はない。従って、エポキシ樹脂粉体塗料は、内面塗装に適している。 When using epoxy resin powder paint for inner surface coating, the epoxy resin powder paint does not contain solvent and is applied to preheated metal tubes, so it takes less time to dry, There is no concern of adversely affecting water quality. Therefore, the epoxy resin powder coating is suitable for inner surface coating.
しかしながら、上記のように内面に2液の液状エポキシ樹脂塗料が使用されている場合、一般に液状エポキシ樹脂塗料には、溶剤が含有されているので、厚塗りすると乾燥に時間がかかり、また、水質に悪影響を及ぼす懸念がある。 However, when a two-part liquid epoxy resin paint is used on the inner surface as described above, the liquid epoxy resin paint generally contains a solvent. There are concerns about adversely affecting
これに対して、エポキシ樹脂粉体塗料の場合には、上述したように、溶剤が含有されておらず、予熱した金属製管に塗装することから、乾燥に時間がかからず、しかも、水質に悪影響を及ぼす懸念はないことから、内面塗装に適しているが、これを外面に適用する場合は、塗膜が硬く、耐衝撃性が低いことから不向きである。 In contrast, in the case of an epoxy resin powder coating, as described above, it does not contain a solvent, and since it is applied to a preheated metal tube, it does not take time to dry, and the water quality This is suitable for inner surface coating because there is no concern that it will adversely affect the surface, but when this is applied to the outer surface, it is unsuitable because the coating film is hard and impact resistance is low.
一方、外面については、一般的に使用されている液状の合成樹脂塗料は、厚塗りが困難で、また、乾燥に時間がかかり、防食性も低く、腐食性の土壌に埋設された場合、短期間に、金属製管が腐食し、短期間にその寿命を終えるケースがある。 On the other hand, generally used liquid synthetic resin paints are difficult to coat thickly, take time to dry, have low anticorrosion properties, and are embedded in corrosive soil for a short period of time. In some cases, metal pipes corrode and finish their life in a short time.
また、従来は、管の内外面を同一の塗料による同時塗装は不可能であり、一般的に内面塗装後に外面塗装を行っているのが現状である。 Conventionally, the inner and outer surfaces of the pipe cannot be simultaneously coated with the same paint, and the outer surface is generally coated after the inner surface is coated.
従って、この発明の目的は、水質に悪影響を及ぼさず、厚塗り塗装が可能であることから高い防食性能を長期間に亘って維持することができると共に耐衝撃性に優れ、しかも、内外面同時塗装が可能であり、さらに、塗装後、急冷することによって直ちに使用することができる防食塗装水道管の製造方法を提供することにある。 Accordingly, the object of the present invention is that it can be applied with a thick coating without adversely affecting the water quality, so that high anticorrosion performance can be maintained over a long period of time, and it has excellent impact resistance, and at the same time the inner and outer surfaces are simultaneously coated. It is another object of the present invention to provide a method for producing a corrosion-proof coated water pipe that can be painted and that can be used immediately by being rapidly cooled after painting .
そこで、本願発明者は、上記目的を達成すべく、鋭意研究を重ねた。この結果、以下のような知見を得た。 Therefore, the inventor of the present application has made extensive studies in order to achieve the above object. As a result, the following findings were obtained.
熱可塑性飽和ポリエステル樹脂粉体塗料は、溶剤を含有せず、しかも、環境ホルモン等の有害な物質も含まないことから、水質に悪影響を及ぼすことはない。また、熱可塑性飽和ポリエステル樹脂粉体塗料によれば、管内外面の同時塗装が可能であり、さらに、塗装後、急冷すれば、直ちに使用可能な状態となる。 Since the thermoplastic saturated polyester resin powder coating does not contain a solvent and does not contain harmful substances such as environmental hormones, it does not adversely affect water quality. Moreover, according to the thermoplastic saturated polyester resin powder coating, the inner and outer surfaces of the pipe can be coated at the same time. Furthermore, if the coating is rapidly cooled after coating, it can be used immediately.
この発明は、上記知見に基づきなされたものであって、下記を特徴とするものである。 The present invention has been made on the basis of the above findings, and is characterized by the following.
請求項1記載の発明は、金属製管に表面仕上処理を施し、次いで、表面仕上処理を施した前記金属製管の外面に、亜鉛または亜鉛−アルミニウムを溶射し、次いで、前記金属製管を280℃から300℃の範囲内の温度に予熱し、次いで、予熱した前記金属製管の内外面に、粒度が40メッシュ、融点が230℃から240℃の範囲内、密度が1.28から1.30の範囲内の熱可塑性飽和ポリエステル樹脂粉体を膜厚が0.3mmから1.0mmの範囲内となるように内外面同時に塗装し、そして、前記金属製管を100℃/分から200℃/分の範囲内の冷却速度で冷却し、かくして、前記金属製管の内外面に熱可塑性飽和ポリエステル樹脂からなる塗膜を形成することに特徴を有するものである。 According to the first aspect of the present invention, a metal pipe is subjected to a surface finishing treatment, and then, zinc or zinc-aluminum is thermally sprayed on an outer surface of the metal pipe subjected to the surface finishing treatment, and then the metal pipe is Preheated to a temperature in the range of 280 ° C. to 300 ° C., and then on the inner and outer surfaces of the preheated metal tube, the particle size is 40 mesh, the melting point is in the range of 230 ° C. to 240 ° C., and the density is 1.28 to 1 The thermoplastic saturated polyester resin powder in the range of .30 is coated at the same time on the inner and outer surfaces so that the film thickness is in the range of 0.3 mm to 1.0 mm, and the metal tube is coated at 100 ° C./min to 200 ° C. It is characterized by cooling at a cooling rate in the range of / min. And thus forming a coating film made of a thermoplastic saturated polyester resin on the inner and outer surfaces of the metal pipe .
この発明によれば、水質に悪影響を及ぼさず、厚塗り塗装が可能であることから高い防食性能を長期間に亘って維持することができると共に耐衝撃性に優れ、しかも、内外面同時塗装が可能であり、さらに、塗装後、急冷することによって直ちに使用することができる。 According to the present invention, it is possible to maintain a high anti-corrosion performance for a long period of time without affecting the water quality and enabling a thick coating, and it is excellent in impact resistance. In addition, it can be used immediately after coating by rapid cooling.
次に、この発明の方法により製造した防食塗装水道管の一実施態様を説明する。 Next, one embodiment of the anticorrosion paint water pipe manufactured by the method of the present invention will be described.
この発明の方法により製造した防食塗装水道管は、鋳鉄管または鉄管等の金属製管の内外面に、熱可塑性飽和ポリエステル樹脂粉体からなる膜厚0.3mmから1.0mmの範囲内の塗膜が形成されたものからなっている。 The anticorrosion-coated water pipe manufactured by the method of the present invention is applied to the inner and outer surfaces of a metal pipe such as a cast iron pipe or an iron pipe within a thickness range of 0.3 mm to 1.0 mm made of thermoplastic saturated polyester resin powder. It consists of a film formed.
膜厚が0.3mm未満であると、ピンホール等の塗膜欠陥が生じやすく、所望の防食効果が得られない。一方、膜厚が1.0mmを超えると、塗料垂れが生じて外観が悪くなる。また、塗膜の耐衝撃性が低下する。さらに、管外径が大きくなって継手よる管接合に影響を及ぼす。従って、この発明では、熱可塑性飽和ポリエステル樹脂粉体の膜厚を0.3mmから1.0mmの範囲内とした。好ましくは、0.5mmから0.8mmの範囲内が良い。 If the film thickness is less than 0.3 mm, coating film defects such as pinholes are likely to occur, and the desired anticorrosive effect cannot be obtained. On the other hand, if the film thickness exceeds 1.0 mm, paint dripping occurs and the appearance deteriorates. In addition, the impact resistance of the coating film decreases. In addition, the outer diameter of the pipe is increased, affecting the pipe joining by the joint. Therefore, in this invention, the film thickness of the thermoplastic saturated polyester resin powder is set in the range of 0.3 mm to 1.0 mm. Preferably, it is in the range of 0.5 mm to 0.8 mm.
一般の合成樹脂塗料は、固形分(塗膜となる成分)が30%から50%と低いので、厚く塗ると塗料垂れ等の不都合が発生するので、厚塗りが困難であるが、熱可塑性飽和ポリエステル樹脂粉体の場合には、固形分がほぼ100%であり、一般の合成樹脂塗料に比べ、10倍以上の厚塗りが可能である。 General synthetic resin paints have a solid content (component that becomes a coating film) as low as 30% to 50%. If thickly applied, inconveniences such as paint sag occur, so thick coating is difficult. In the case of a polyester resin powder, the solid content is almost 100%, and it can be applied ten times or more thicker than a general synthetic resin paint.
次に、この発明の防食塗装水道管の製造方法について説明する。 Next, the manufacturing method of the anticorrosion coating water pipe of this invention is demonstrated.
この発明の方法により製造された防食塗装水道管は、鋳鉄管または鉄管等の金属製管に表面仕上処理を施し、次いで、表面仕上処理を施した金属製管を予熱し、次いで、予熱した金属製管の内外面に熱可塑性飽和ポリエステル樹脂粉体を同時に塗装し、そして、金属製管を冷却し、かくして、金属製管の内外面に熱可塑性飽和ポリエステル樹脂からなる塗膜を形成することによって製造される。 The anticorrosion coated water pipe manufactured by the method of the present invention is obtained by subjecting a metal pipe such as a cast iron pipe or an iron pipe to a surface finish treatment, preheating the metal pipe subjected to the surface finish treatment, and then preheating the metal pipe. By simultaneously coating thermoplastic saturated polyester resin powder on the inner and outer surfaces of the pipe making and cooling the metal pipe, thus forming a coating film made of thermoplastic saturated polyester resin on the inner and outer faces of the metal pipe Manufactured.
金属製管の予熱温度は、270℃から320℃の範囲内とする。予熱温度が270℃未満であると、粉体が完全に溶融しないので、本来の塗膜の効果が得られない。しかも、耐衝撃性が低下する。一方、320℃を超えると、塗料の樹脂が熱劣化して、本来の塗膜の効果が得られない。また、変色して、外観が悪くなる。従って、この発明では、金属製管の予熱温度を270℃から320℃の範囲内とした。好ましくは、280℃から300℃の範囲内が良い。 The preheating temperature of the metal pipe is in the range of 270 ° C to 320 ° C. When the preheating temperature is less than 270 ° C., the powder does not completely melt, so that the original effect of the coating film cannot be obtained. Moreover, the impact resistance is reduced. On the other hand, if it exceeds 320 ° C., the resin of the paint is thermally deteriorated and the original effect of the coating film cannot be obtained. Moreover, it discolors and an external appearance worsens. Therefore, in the present invention, the preheating temperature of the metal pipe is set in the range of 270 ° C. to 320 ° C. Preferably, the temperature is in the range of 280 ° C to 300 ° C.
熱可塑性飽和ポリエステル樹脂粉体の膜厚は、上述した通りである。 The film thickness of the thermoplastic saturated polyester resin powder is as described above.
金属製管の冷却速度は、40℃/分から200℃/分の範囲内とする。塗膜の効果は、急冷による熱可塑性飽和ポリエステル樹脂の結晶化によってもたらされるが、冷却速度が40℃/分未満であると、樹脂が結晶化しにくいので、所望の効果が得られない。一方、200℃/分を超えても樹脂の結晶化の効果は変わらず、冷却設備が大型化する分、無駄となる。従って、この発明では、金属製管の冷却速度を40℃/分から200℃/分の範囲内とした。好ましくは、100℃/分から200℃/分の範囲内が良い。 The cooling rate of the metal pipe is in the range of 40 ° C./min to 200 ° C./min. The effect of the coating film is brought about by crystallization of the thermoplastic saturated polyester resin by rapid cooling. However, if the cooling rate is less than 40 ° C./min, the resin is difficult to crystallize, so that a desired effect cannot be obtained. On the other hand, even if it exceeds 200 ° C./min, the effect of crystallization of the resin does not change, and the cooling equipment is increased in size and is wasted. Therefore, in the present invention, the cooling rate of the metal pipe is set within the range of 40 ° C./min to 200 ° C./min. Preferably, it is in the range of 100 ° C./min to 200 ° C./min.
上述のように、熱可塑性飽和ポリエステル樹脂は、急冷することによって結晶化して、本来の性能が発揮されるために急冷は、必須である。 As described above, the thermoplastic saturated polyester resin is crystallized by rapid cooling, and thus the rapid cooling is essential because the original performance is exhibited.
塗料の粒度は、本来の性能を得るために、40メッシュ、融点は、230℃から240℃、密度は、1.28から1.30の範囲内が良い。 The particle size of the paint is preferably 40 mesh, the melting point is 230 ° C. to 240 ° C., and the density is 1.28 to 1.30 in order to obtain the original performance.
なお、外面防食性能を更に向上させるために、プライマーとして、亜鉛あるいは亜鉛−アルミの溶射を行った後、その上に熱可塑性飽和ポリエステル樹脂粉体塗装を行うと良い。これによって、たとえ、塗膜に傷がついても亜鉛あるいは亜鉛−アルミの犠牲陽極反応にて管体の腐食の進行を防ぐことができる。 In order to further improve the outer surface anticorrosion performance, after spraying zinc or zinc-aluminum as a primer, thermoplastic saturated polyester resin powder coating is preferably performed thereon. Thereby, even if the coating film is damaged, it is possible to prevent the progress of corrosion of the pipe body by the sacrificial anode reaction of zinc or zinc-aluminum.
次に、この発明を実施例により、さらに説明する。 Next, the present invention will be further described with reference to examples.
口径φ75mm、肉厚7.5mm、長さ4000mmのダクタイル鋳鉄管を加熱炉で300℃に予熱し、内外面自動粉体塗装装置を使用して、膜厚が0.5mmになるように熱可塑性飽和ポリエステル粉体塗料を管内外面に同時塗装した。なお、この熱可塑性飽和ポリエステル粉体塗料は、イソフタル酸成分8〜20モル%、固有粘度0.7〜1.0の熱可塑性ポリエチレンテレフタレート共重合体より成るポリエステル系重合体からなり、粒度は、40メッシュ、融点は、230℃、密度は、1.28であった。このようにして、管内外面に粉体塗料を同時塗装した後、直ちに、管を冷却速度100℃/分で水冷して、内外面熱可塑性飽和ポリエステル粉体塗装管を製造した。 A ductile cast iron pipe with a diameter of 75mm, a wall thickness of 7.5mm, and a length of 4000mm is preheated to 300 ° C in a heating furnace. A saturated polyester powder coating was simultaneously applied to the inside and outside of the tube. The thermoplastic saturated polyester powder coating is composed of a polyester polymer composed of a thermoplastic polyethylene terephthalate copolymer having an isophthalic acid component of 8 to 20 mol% and an intrinsic viscosity of 0.7 to 1.0. 40 mesh, melting | fusing point was 230 degreeC, and the density was 1.28. In this way, after the powder coating was simultaneously applied to the inner and outer surfaces of the tube, the tube was immediately cooled with water at a cooling rate of 100 ° C./min to produce an inner and outer surface thermoplastic saturated polyester powder coated tube.
図1に、この発明の防食塗装水道管の製造方法の工程図を示す。 In FIG. 1, the process drawing of the manufacturing method of the anticorrosion coating water pipe of this invention is shown.
以上のように、この発明の方法により製造した防食塗装水道管によれば、熱可塑性飽和ポリエステル粉体塗料を使用することによって、水質に悪影響を及ぼさず、厚塗り塗装が可能であることから高い防食性能を長期間に亘って維持することができた。また、耐衝撃性に優れ、しかも、管内外面に同じ塗料を使用できるので、内外面同時塗装が可能となり、管の塗装時間が大幅に短縮された。さらに、塗装後、急冷することによって、直ちに使用可能な状態になるので、管製造後の保管、出荷等に便利であった。 As described above, according to the anticorrosion-coated water pipe manufactured by the method of the present invention, the use of the thermoplastic saturated polyester powder coating does not adversely affect the water quality and can be thickly coated. The anticorrosion performance could be maintained for a long time. In addition, it has excellent impact resistance, and because the same paint can be used on the inner and outer surfaces of the pipe, the inner and outer surfaces can be painted simultaneously, and the pipe coating time has been greatly reduced. Furthermore, since it is ready for use immediately after being painted, it is convenient for storage and shipment after pipe production.
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