JP4791407B2 - Sauce composition - Google Patents

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JP4791407B2
JP4791407B2 JP2007120171A JP2007120171A JP4791407B2 JP 4791407 B2 JP4791407 B2 JP 4791407B2 JP 2007120171 A JP2007120171 A JP 2007120171A JP 2007120171 A JP2007120171 A JP 2007120171A JP 4791407 B2 JP4791407 B2 JP 4791407B2
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crystalline cellulose
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昭宏 坂元
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Asahi Kasei Chemicals Corp
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本発明は、特に濃厚なソース類において、麺類や惣菜等の食材への付着性を格段に高め且つ流動性を改善したソース組成物に関する。具体的には、結晶セルロースを主剤とし強い剪断力を有する設備を用いることなく容易に再分散する易分散安定剤を含有し、製造工程中に、高圧ホモジナイザーや、高速攪拌機など高剪断力を有する装置を使うことなく、プロペラ攪拌やパドル攪拌程度の弱い剪断力の攪拌装置を用いて製造した濃厚なソース類に関する。   The present invention relates to a sauce composition that significantly increases the adhesion to foods such as noodles and sugar beet and improves the fluidity, particularly in dense sauces. Specifically, it contains an easy-dispersion stabilizer that is easily redispersed without using equipment with strong shearing force, mainly composed of crystalline cellulose, and has a high shearing force such as a high-pressure homogenizer or high-speed stirrer during the manufacturing process. The present invention relates to thick sauces produced by using a stirrer having a weak shearing force such as propeller stirring or paddle stirring without using an apparatus.

近年、デパート、スーパーマーケットやコンビニの惣菜売り場にはテイクアウト用の惣菜や弁当のおかず等に、病院や学校等の給食用に、また外食産業等で調理済み食品が多く使用されている。これらの調理済み食品の惣菜には、食材を更においしくするために、トマトソースやデミグラスソースなど食材にあった濃厚なソース類をかけるケースが多い。その場合に用いるソース類は、一部はその場で調理されるものもあるが、大半はソース製造業者の工場で連続的に生産された容器詰ソースが一般的である。   In recent years, prepared foods for department stores, supermarkets, and convenience stores are often used for side dishes for take-out and side dishes for lunch, hospitals, schools, etc., and the food service industry. In order to make the ingredients more delicious, these prepared foods are often applied with rich sauces such as tomato sauce and demiglace sauce. Some of the sauces used in that case are cooked on the spot, but most of the sauces are generally packaged sauces produced continuously at the source manufacturer's factory.

連続的に生産されるこれら濃厚なソース類は、専用の充填装置を用いて容器に充填されるが、容器詰めソース類の生産性に悪影響を与えないために、濃厚なソースが充填装置からスムースに流動することがきわめて重要となっている。
また、濃厚なソースは、充填装置のノズルからスムースに流動して容器に充填できることが求められるとともに、ソース本来の目的である食材の味向上のために、ソースが食材から容易にたれ落ちないような付着性も要求されている。
These thick sauces produced continuously are filled into the container using a dedicated filling device, but the thick sauce is smoothly removed from the filling device so as not to adversely affect the productivity of the container-filled sauces. It is extremely important to flow into
In addition, it is required that the thick sauce flows smoothly from the nozzle of the filling device and can be filled into the container, and in order to improve the taste of the food, which is the original purpose of the sauce, the sauce does not easily fall off from the food. Adhesion is also required.

ところが、充填装置で充填されるソースの流動性は、ソースの粘度によって大きく左右されることが分かっており、汎用の充填装置(例えば、10DT-H型、(株)ナオミ製)を用いる場合、流動性を優先してソース配合を決めるとソース粘度を低く設計する必要があり、連続生産に合ったソースは得られるが、食材への付着性が小さいソースとなってしまう。一方、食材への付着性を優先してソース配合を決めると、これまで高い粘度のソースとするのが一般的な手段であり、高い粘度のソースの場合は汎用の充填装置からスムースに流動しないために、高粘度用充填装置が新たに必要となるうえに、高粘度であるため容器への充填速度が小さくなってしまい、生産性に少なからず悪影響を及ぼしてしまうことになる。このため、濃厚なソース類において、付着性が良く且つ汎用の充填装置を用いて充填できる流動性の良いものが望まれていた。   However, it is known that the fluidity of the sauce filled in the filling device is greatly influenced by the viscosity of the sauce, and when using a general-purpose filling device (for example, 10DT-H type, manufactured by Naomi Co., Ltd.) If the sauce composition is determined with priority on fluidity, it is necessary to design the sauce viscosity low, and a sauce suitable for continuous production can be obtained, but it becomes a sauce with low adhesion to foods. On the other hand, when deciding on the source composition with priority given to adhesion to foods, it has been common practice to use a high-viscosity sauce so far. For this reason, a high-viscosity filling device is newly required, and since the viscosity is high, the filling speed into the container is reduced, which adversely affects productivity. For this reason, in dense sauces, a material having good adhesion and good fluidity that can be filled using a general-purpose filling device has been desired.

ソース類において、低粘度で且つ付着性を改善する方法として、乳化剤、増粘安定剤及び結晶セルロースを添加し、高剪断力で攪拌して作る方法がある(例えば特許文献1参照)。
従来、食品中に結晶セルロース複合体を用いる場合、結晶セルロース複合体の懸濁安定化効果、乳化安定性改善効果や流動性改善効果などの結晶セルロースの特徴を発現させるために、結晶セルロース製剤を食品等に配合する前または配合した後に、結晶セルロース粒子が水中で平均粒径20μm以下に分散するような、強い剪断力で磨砕できる高圧ホモジナイザーや高速攪拌機等の特殊な設備を用いて、結晶セルロースの再分散処理が行われるのが通常であった(例えば、特許文献2、特許文献3参照)。
しかしながら、工業的に製造されるソース類の製造工程には、高剪断力を有する製造設備はなく蒸煮工程や混合工程等でパドル攪拌装置など緩やかな回転で攪拌混合する程度の設備が一般的である。
As a method for improving the adhesiveness of the sauces, there is a method of adding an emulsifier, a thickening stabilizer and crystalline cellulose and stirring them with a high shearing force (see, for example, Patent Document 1).
Conventionally, when a crystalline cellulose composite is used in food, a crystalline cellulose preparation is used in order to develop the characteristics of crystalline cellulose such as the suspension stabilizing effect, the emulsion stability improving effect and the fluidity improving effect of the crystalline cellulose composite. Before or after blending into foods, etc., using special equipment such as a high-pressure homogenizer or high-speed stirrer that can be ground with a strong shearing force so that the crystalline cellulose particles are dispersed in water with an average particle size of 20 μm or less. Usually, redispersion treatment of cellulose is performed (see, for example, Patent Document 2 and Patent Document 3).
However, in the manufacturing process of sauces manufactured industrially, there is no manufacturing equipment with high shearing force, and there is a general facility that stirs and mixes with gentle rotation such as a paddle stirrer in a steaming process or mixing process. is there.

特開2000−210047号公報Japanese Patent Laid-Open No. 2000-210047 特開平10−56960号公報Japanese Patent Laid-Open No. 10-56960 特開平6−335348号公報JP-A-6-335348

本発明は、パドル攪拌のような比較的軽い攪拌操作で作る濃厚なソース類において、食材への付着性が高く且つ良好な流動性を有するソース類を提供することを課題とする。   An object of the present invention is to provide sauces having high fluidity and high adhesion to foods in dense sauces made by a relatively light stirring operation such as paddle stirring.

本発明者は、前記問題点を解決すべく鋭意研究した結果、ソース類に易分散安定剤を含有することで、製造工程中に高剪断力を有する製造設備がなくても、パドル攪拌装置など緩やかな回転で攪拌混合する程度で汎用の充填装置からの流動性が良好で且つ食材への付着性が改善することを見出して本発明を完成した。
すなわち、本発明は以下に記載する通りの易分散安定剤を含有するソース組成物である。
(1)易分散安定剤を0.05重量%以上20重量%以下の割合で含有し、高ずり速度が14.0/秒時の粘度が3.6〜4.3Pa・s含有することを特徴とするソース組成物。
(2)降伏値が31.8から46.3Paである上記(1)記載のソース組成物。
As a result of earnest research to solve the above problems, the present inventor has included an easy-dispersion stabilizer in the sauces, so that even if there is no production facility having a high shear force during the production process, a paddle stirring device, etc. The present invention was completed by finding that the fluidity from a general-purpose filling device was good and the adhesion to food was improved by stirring and mixing at a gentle rotation.
That is, the present invention is a source composition containing an easy dispersion stabilizer as described below.
(1) It contains an easy-dispersion stabilizer in a proportion of 0.05% by weight or more and 20% by weight or less, and a viscosity at a high shear rate of 14.0 / second is 3.6 to 4.3 Pa · s. Source composition characterized.
(2) The source composition according to the above (1) , wherein the yield value is 31.8 to 46.3 Pa .

本発明の易分散安定剤を含有するソース組成物は、製造工程中に高剪断力を有する製造設備がなくても、パドル攪拌装置など緩やかな回転で攪拌混合する程度で、汎用の充填装置からの流動性が良好で且つ食材への付着性を改善するという効果を奏する。
また、本発明の濃厚なソース組成物は、ソース表面が乾きにくいと言う特長があり、従来ソース表面の乾き防止に用いている水あめ、糖類や糖アルコールが有する甘味や粘度の増大といった問題点も解消することができる。
The source composition containing the easy-dispersion stabilizer of the present invention can be mixed from a general-purpose filling device to the extent that it is stirred and mixed with gentle rotation, such as a paddle stirring device, even without a manufacturing facility having a high shear force during the manufacturing process. Has the effect of improving the adhesion to foods.
In addition, the rich sauce composition of the present invention has the feature that the source surface is difficult to dry, and there are also problems such as the increase in sweetness and viscosity of sugar candy and sugars and sugar alcohols conventionally used to prevent the source surface from drying. Can be resolved.

以下、本発明の内容を詳細に説明する。
易分散安定剤とは、結晶セルロースに対し特定の割合の水溶性ガム及び糖類を混合し、これを水に溶解分散してから、水中下で強い剪断力をかけて磨砕したのち乾燥することで得られるものであり、水に分散溶解した場合に、手攪拌のごとき剪断力の弱い攪拌条件下でも容易に水に分散して、結晶セルロースの平均粒径が20μm以下となるものである。
Hereinafter, the contents of the present invention will be described in detail.
Easily dispersible stabilizer is a mixture of water-soluble gum and saccharide in a specific ratio with respect to crystalline cellulose, dissolved and dispersed in water, then ground under strong shearing force in water and then dried. When it is dispersed and dissolved in water, it is easily dispersed in water even under stirring conditions with weak shearing force such as hand stirring, and the average particle size of crystalline cellulose is 20 μm or less.

易分散安定剤に用いる結晶セルロースは、木材パルプなど天然セルロースを加水分解して得られる結晶セルロースであり、結晶性部分が10重量%を超える(結晶化度が10%を超える)ものを言う。なお、結晶性部分とは、X線回折においてバックグラウンドを生じる非晶性部分に対して、ブラッグ反射のピークを生じる部分をいう。このような結晶セルロースを用いることにより、易分散安定剤を食品等に配合した場合に、懸濁安定性や乳化安定性等の特性が発揮できるようになる。好ましくは結晶化度は30%以上であり、より好ましくは50%以上である。   The crystalline cellulose used for the easy dispersion stabilizer is a crystalline cellulose obtained by hydrolyzing natural cellulose such as wood pulp, and refers to a crystalline part exceeding 10% by weight (crystallinity exceeding 10%). In addition, a crystalline part means the part which produces the peak of Bragg reflection with respect to the amorphous part which produces a background in X-ray diffraction. By using such crystalline cellulose, characteristics such as suspension stability and emulsification stability can be exhibited when an easy-dispersion stabilizer is added to foods and the like. Preferably the crystallinity is 30% or more, more preferably 50% or more.

また、再分散の際に水に容易に分散できるようにするためには、結晶セルロースとして加水分解されたままのスラリー状で未乾燥のものか、または加水分解後に磨砕されたままのスラリー状で未乾燥のものを用いる。未乾燥でウェットな状態のものを用いるのは、乾燥状態をいったん経ることにより生じるセルロース粒子間の強固な水素結合の発生を避けて、再分散の際の易分散性を確保するためである。   Also, in order to be able to easily disperse in water during redispersion, it is a slurry that has been hydrolyzed as crystalline cellulose and is undried, or a slurry that has been ground after hydrolysis. Use an undried product. The reason for using an undried and wet state is to avoid the generation of strong hydrogen bonds between cellulose particles that occur once through the dry state and to ensure easy dispersibility during redispersion.

また、結晶セルロースとして一旦乾燥されたものをあえて用いる場合には、結晶セルロースが加水分解後に未乾燥のスラリー状態で、後述の水溶性ガム又は水溶性ガム及び糖類の比較的少量をあらかじめ混合し、しかるのちに乾燥して得られる結晶セルロース複合体を用いればよい。このような結晶セルロース複合体を用いることが可能なのは、後述の水溶性ガムを混合したり、後述の糖類等を比較的少量混合したりしてから乾燥することで、結晶セルロースの乾燥に伴う水素結合の発生が妨害されるからである。なお、結晶セルロース複合体を用いる場合に、結晶セルロース複合体の各成分の質量比は、後述の易分散安定剤とする場合の質量比の範囲内であってもよいし、また、外れていても良いが、好ましくは結晶セルロース:水溶性ガム及び糖類=50:50〜95:5(ただし、合計で100)の範囲である。   In addition, when using what was once dried as crystalline cellulose, in a slurry state that is not dried after the crystalline cellulose is hydrolyzed, a relatively small amount of water-soluble gum or water-soluble gum and saccharide described later are mixed in advance, Thereafter, a crystalline cellulose composite obtained by drying may be used. It is possible to use such a crystalline cellulose composite by mixing the water-soluble gum described later or mixing a relatively small amount of a sugar described below and then drying, so that the hydrogen associated with the drying of the crystalline cellulose. This is because the occurrence of coupling is hindered. In addition, when using a crystalline cellulose composite, the mass ratio of each component of the crystalline cellulose composite may be within the range of the mass ratio in the case of using an easy-dispersion stabilizer described later, or may be deviated. However, it is preferably in the range of crystalline cellulose: water-soluble gum and sugar = 50: 50 to 95: 5 (however, 100 in total).

用いることができる結晶セルロース複合体としては、例えば、旭化成ケミカルズ社製の商品名セオラス(登録商標)のRC−591が挙げられる。また、少量のデキストリンをあらかじめ含有したものとしては、旭化成ケミカルズ社製の商品名セオラス(登録商標)のRC−N81、RC−N30等が挙げられる。いずれもデキストリンの含有量は結晶セルロース複合体100重量部に対して90重量部以下である。   As a crystalline cellulose composite that can be used, for example, RC-591 under the trade name Theolas (registered trademark) manufactured by Asahi Kasei Chemicals Corporation may be mentioned. Examples of those containing a small amount of dextrin in advance include RC-N81 and RC-N30 of the trade name Theolas (registered trademark) manufactured by Asahi Kasei Chemicals Corporation. In any case, the dextrin content is 90 parts by weight or less with respect to 100 parts by weight of the crystalline cellulose composite.

易分散安定剤に用いる水溶性ガムは、天然に産するか、あるいは発酵法等により得られる水膨潤性または水溶性で増粘性を有するものであれば良く特に限定されない。水溶性ガムを用いることにより、易分散安定剤における結晶セルロースの比率の低下を補償して、懸濁安定性や乳化安定性を高く維持できる。   The water-soluble gum used for the easy-dispersion stabilizer is not particularly limited as long as it is naturally produced or is water-swellable or water-soluble and has a thickening property obtained by a fermentation method or the like. By using the water-soluble gum, it is possible to compensate for a decrease in the ratio of crystalline cellulose in the easy-dispersion stabilizer and to maintain high suspension stability and emulsion stability.

水溶性ガムとしては、結晶セルロースと水中における相溶性がよい多糖類が好ましく、例えば、グアーガム、キサンタンガム、ローカストビーンガム、タマリンド種子ガム、タラガントガム、ガッテーガム、寒天、アルギン酸およびその塩、カラギナン、カラヤガム、アラビアガム、ジェランガム、ペクチン、マルメロ等が例示される。
水溶性ガムの配合量は、結晶セルロース100重量部に対して0.1重量部〜20重量部とするのが好ましい。この範囲で懸濁安定性や乳化安定性の向上が明確になり、一方で粘度の上昇が適切な範囲に留まる。より好ましくは0.5重量部〜15重量部である。さらに好ましくは1重量部〜10重量部である。
As the water-soluble gum, polysaccharides having good compatibility with crystalline cellulose and water are preferable. Examples include gum, gellan gum, pectin, quince and the like.
The blending amount of the water-soluble gum is preferably 0.1 to 20 parts by weight with respect to 100 parts by weight of crystalline cellulose. In this range, the suspension stability and the emulsion stability are clearly improved, while the increase in viscosity remains within an appropriate range. More preferably, it is 0.5 to 15 parts by weight. More preferably, it is 1 to 10 parts by weight.

易分散安定剤には、比較的大量の糖類を配合する。糖類を配合することで、再分散性が良好となる一方で、結晶セルロースによる懸濁安定性や乳化安定性の効果も発現可能となる。ここで比較的大量とは、結晶セルロースと水溶性ガムとの合計1重量部に対して、1重量部を超え30重量部以下の割合をいう。糖類が1重量部を超えると、易分散安定剤を用いた場合の再分散性が良好となり、食品などに配合した場合に懸濁安定性や乳化安定性が発現できるようになる。30重量部以下の割合であれば、再分散性が良好となり、結晶セルロースに求められる機能が十分発現するし、また、食品等に易分散安定剤を含有せしめた際に、食品の味や口当たりに影響しにくい。好ましくは2重量部以上20重量部以下の割合であり、より好ましくは3重量部以上10重量部以下の割合である。
配合できる糖類としては、水溶性の糖類であればよく、単糖類、オリゴ糖、デキストリンなどが例示できる。糖類のうちでは、甘み、生産性などの観点からデキストリンが好ましく、より好ましくはDE(澱粉の糖化度)5〜40のデキストリンである。
A relatively large amount of saccharide is added to the easy dispersion stabilizer. By blending saccharides, the redispersibility is improved, while the effects of suspension stability and emulsion stability due to crystalline cellulose can be expressed. Here, a relatively large amount means a ratio of more than 1 part by weight and 30 parts by weight or less with respect to 1 part by weight of the total of crystalline cellulose and water-soluble gum. If the saccharide exceeds 1 part by weight, the redispersibility when using an easy-dispersion stabilizer is improved, and suspension stability and emulsification stability can be expressed when blended in foods. If the proportion is 30 parts by weight or less, the redispersibility will be good, and the functions required of crystalline cellulose will be fully expressed, and when an easy-dispersing stabilizer is added to the food, etc., the taste and mouthfeel of the food It is hard to affect. The ratio is preferably 2 parts by weight or more and 20 parts by weight or less, more preferably 3 parts by weight or more and 10 parts by weight or less.
The saccharides that can be blended may be water-soluble saccharides, and examples include monosaccharides, oligosaccharides, and dextrins. Among the saccharides, dextrin is preferable from the viewpoint of sweetness, productivity, and the like, more preferably dextrin having DE (degree of saccharification of starch) of 5 to 40.

易分散安定剤は、このように結晶セルロースと水溶性ガムの合計に対して比較的大量の糖類を配合することを要する。これにより結晶セルロースの再分散性が良好になる理由は定かではないが、後述の製造方法における磨砕後の乾燥処理において、比較的大量の糖類が結晶セルロースをいわば包み込む状態となり、結晶セルロースどうしがお互いに分離されることで、結晶セルロース間の水素結合が生じにくくなって角質化しにくくなるのではないかと推測している。   Thus, the easy-dispersion stabilizer needs to mix a relatively large amount of saccharides with respect to the total of crystalline cellulose and water-soluble gum. The reason why the redispersibility of the crystalline cellulose is improved by this is not certain, but in the drying process after grinding in the production method described later, a relatively large amount of saccharide wraps up the crystalline cellulose, so that the crystalline celluloses are It is speculated that by separating them from each other, hydrogen bonds between the crystalline celluloses are less likely to occur and the keratinization is less likely to occur.

易分散安定剤には、上記の3成分の他に、易分散安定剤の効果を損なわない範囲で他の成分を混合しても良い。他の成分としては、例えば、デンプン類、油脂類、蛋白質類、ペプチド、アミノ酸、界面活性剤、保存料、日持向上剤、pH調整剤、食塩、各種リン酸塩等の塩類、乳化剤、酸味料、甘味料、香料、色素、消泡剤、発泡剤、抗菌剤、崩壊剤などの成分が適宜配合されていても良い。   In addition to the above three components, other components may be mixed with the easy dispersion stabilizer as long as the effect of the easy dispersion stabilizer is not impaired. Examples of other components include starches, fats and oils, proteins, peptides, amino acids, surfactants, preservatives, shelf life improvers, pH adjusters, salt, various phosphate salts, emulsifiers, acidity Ingredients such as additives, sweeteners, fragrances, pigments, antifoaming agents, foaming agents, antibacterial agents, and disintegrating agents may be appropriately blended.

次に、上記の各成分を用いた易分散安定剤の製造方法について説明する。まず、上記の結晶セルロースと水溶性ガムと糖類とを水に分散溶解する。その際の結晶セルロースと水溶性ガムと糖類とその他の成分とを合わせた濃度は、1重量%以上70重量%以下となるように、水を含めたそれぞれの量を調整するのが好ましい。この範囲で水分散液の取り扱い性が良好で生産性が高く、後の乾燥エネルギー負荷も許容できる範囲に留まる。より好ましくは3重量%以上65重量%以下、最も好ましくは5重量%以上60重量%以下である。   Next, the manufacturing method of the easy dispersion stabilizer using each said component is demonstrated. First, the above crystalline cellulose, water-soluble gum and saccharide are dispersed and dissolved in water. In this case, it is preferable to adjust the respective amounts including water so that the combined concentration of crystalline cellulose, water-soluble gum, saccharide and other components is 1% by weight or more and 70% by weight or less. Within this range, the handleability of the aqueous dispersion is good, the productivity is high, and the subsequent drying energy load remains in an acceptable range. More preferably, they are 3 weight% or more and 65 weight% or less, Most preferably, they are 5 weight% or more and 60 weight% or less.

次いで、高圧ホモジナイザーを用いてこの水分散液を磨砕する。高圧ホモジナイザーとは、原料(液体または液体と固体)を加圧して、間隙(スリット)を通り抜ける際の剪断力を利用して粉砕・分散・乳化を行う装置であり、例えば、商品名:ナノマイザー(ナノマイザー社製)、商品名:マイクロフルイダイザー(マイクロフルイディクス社製)、商品名:アリート(ニロソアビ社製)、商品名:APVホモジナイザー(APV社製)等の装置が例示される。   The aqueous dispersion is then ground using a high pressure homogenizer. A high-pressure homogenizer is a device that pressurizes raw materials (liquid or liquid and solid) and pulverizes, disperses, and emulsifies using shearing force when passing through gaps (slits). For example, trade name: Nanomizer ( Examples include devices such as Nanomizer Co., Ltd., trade name: Microfluidizer (Microfluidics Co., Ltd.), trade name: Alite (Nirososovi Co., Ltd.), and trade name: APV homogenizer (manufactured by APV).

高圧ホモジナイザーの運転は、運転圧力が4MPa以上150MPa以下の範囲で行う。4MPa以上とすることにより磨砕が十分になされ、懸濁安定性や乳化安定性の改善が見られる。150MPaを超える圧力で運転することもできるが、対応する装置が高価となりコストがかかる割には、懸濁安定性や乳化安定性の向上が頭打ちとなる。好ましくは8MPa以上100MPa以下であり、より好ましくは10MPa以上80MPa以下である。   The operation of the high-pressure homogenizer is performed in an operating pressure range of 4 MPa to 150 MPa. By setting the pressure to 4 MPa or more, the grinding is sufficiently performed, and the suspension stability and the emulsion stability are improved. Although it is possible to operate at a pressure exceeding 150 MPa, the improvement in suspension stability and emulsification stability has reached its peak, although the corresponding apparatus is expensive and expensive. Preferably they are 8 MPa or more and 100 MPa or less, More preferably, they are 10 MPa or more and 80 MPa or less.

この高圧ホモジナイザー処理により、結晶セルロースの平均粒径を20μm以下とすることができる。なお、高圧ホモジナイザーのパス回数は1回で良いが、複数回パスさせても良い。また、高圧ホモジナイザー工程の前または後の工程に、高速攪拌機などの高い剪断力のかかる別の装置による処理工程を付け加えても良い。
各成分の水への分散と高圧ホモジナイザー処理とは、上記のように、全部の成分を混合して一括して行っても良いが、成分ごとに水に分散し、成分ごとに高圧ホモジナイザーによる磨砕処理を行い、しかるのち全部の成分を高圧ホモジナイザーや高速攪拌機または各種のミルを用いて均一に混合するようにしてもよい。
By this high-pressure homogenizer treatment, the average particle size of the crystalline cellulose can be reduced to 20 μm or less. Note that the number of passes of the high-pressure homogenizer may be one, but a plurality of passes may be used. Moreover, you may add the process process by another apparatus which requires high shearing force, such as a high-speed stirrer, to the process before or after a high pressure homogenizer process.
The dispersion of each component in water and the high-pressure homogenizer treatment may be performed by mixing all the components as described above, but each component is dispersed in water, and each component is polished by a high-pressure homogenizer. A crushing treatment is performed, and then all components may be mixed uniformly using a high-pressure homogenizer, a high-speed stirrer, or various mills.

このようにして得られた組成物を最後に乾燥する。これにより各成分を複合化する。複合化により、理由は不明であるが複合化された粉末を水に再投入した際に、水への分散特性が飛躍的に向上する。乾燥方法としては、噴霧乾燥法など食品工業で用いられる一般的な乾燥方法であれば良く、具体的な例として噴霧乾燥法、凍結乾燥法、ドラム乾燥法等が挙げられる。また、乾燥条件もそれぞれの乾燥方法に適した条件を適宜選択すればよい。こうして得られた乾燥物は、必要に応じて粉砕処理や分級処理を行うことができ、目的とする易分散安定剤が得られる。用いることができる易分散安定剤としては、例えば、旭化成ケミカルズ(株)製の商品名セオラス(登録商標)のDX−1が挙げられる。   The composition thus obtained is finally dried. Thereby, each component is compounded. Although the reason is unknown due to the compounding, when the compounded powder is reintroduced into water, the dispersion characteristics in water are greatly improved. The drying method may be any general drying method used in the food industry such as spray drying, and specific examples include spray drying, freeze drying, drum drying and the like. Moreover, what is necessary is just to select suitably the drying conditions suitable for each drying method. The dried product thus obtained can be subjected to a pulverization treatment or a classification treatment as required, and the intended easy dispersion stabilizer can be obtained. As an easily dispersible stabilizer which can be used, DX-1 of the brand name Theolas (trademark) by Asahi Kasei Chemicals Co., Ltd. is mentioned, for example.

なお、易分散安定剤を再分散した場合の結晶セルロースの平均粒径は、レーザー回折散乱式粒度分布測定装置(商品名:LA910、堀場製作所社製)を用い、得られた積算体積50%の粒径を平均粒径として求めることができる。なお、この測定に適する易分散安定剤の分散液は、プロペラ攪拌機を用いて、水道水(25℃)495gを400rpmで攪拌しながら易分散安定剤5gを投入し、さらに10分間攪拌して得ることができる。   In addition, the average particle diameter of the crystalline cellulose in the case of redispersing the easy-dispersion stabilizer is obtained by using a laser diffraction scattering type particle size distribution measuring device (trade name: LA910, manufactured by HORIBA, Ltd.) with an obtained integrated volume of 50%. The particle size can be determined as the average particle size. A dispersion of an easy dispersion stabilizer suitable for this measurement is obtained by adding 5 g of easy dispersion stabilizer while stirring 495 g of tap water (25 ° C.) at 400 rpm using a propeller stirrer, and further stirring for 10 minutes. be able to.

本発明の濃厚なソース類中における易分散安定剤の含有量は、0.05重量%以上20重量%以下である。易分散安定剤の含有量が0.05重量%を下回ると、高い付着性や流動性改善効果が小さい。20重量%を超えると、ソース粘度が大きくなり、汎用の充填装置を用いて充填できなくなる場合がある。好ましくは0.2重量%以上15重量%以下の割合であり、より好ましくは1重量部以上10重量部以下の割合である。   The content of the easy dispersion stabilizer in the concentrated sauces of the present invention is 0.05% by weight or more and 20% by weight or less. When the content of the easy dispersion stabilizer is less than 0.05% by weight, the effect of improving high adhesion and fluidity is small. If it exceeds 20% by weight, the source viscosity may increase, and filling may not be possible using a general-purpose filling device. The ratio is preferably 0.2% by weight or more and 15% by weight or less, and more preferably 1% by weight or more and 10% by weight or less.

本発明の濃厚なソース類は、主として野菜および/または果実の搾汁、煮出し汁、ピューレ等と調味料、香辛料等を原料とする。このようなソースとしては、例えばウスターソース類、トンカツソース、デミグラスソース、ハンバーグソース、トマトソース、お好み焼きソース、焼きそばソースなどを代表的なものとして挙げることができる。   The rich sauces of the present invention are mainly made from vegetable and / or fruit juice, boiled juice, puree and the like, seasonings, spices and the like. Typical examples of such sauces include Worcester sauces, tonkatsu sauce, demiglace sauce, hamburg sauce, tomato sauce, okonomiyaki sauce, and fried noodle sauce.

本発明の濃厚なソース類は、野菜、果実、果菜を洗浄、選別し、破砕蒸煮した後、裏漉し、加熱・攪拌・濃縮しながら、砂糖、食塩、食酢,調味料、香辛料、カラメル等を添加し、その後、加熱・裏漉して作る方法など一般的な製造方法で得ることができる。その後殺菌工程を経て容器に詰めることもできる。   The rich sauces of the present invention are prepared by washing, selecting, crushing and steaming vegetables, fruits and fruit vegetables, adding sugar, salt, vinegar, seasonings, spices, caramel, etc. while heating, stirring and concentrating. Then, it can be obtained by a general production method such as a method of heating and backing. Thereafter, the container can be packed through a sterilization process.

本発明の濃厚なソース類には、易分散安定剤の他に食感や流動性に影響しない範囲で、増粘安定剤や澱粉等、その他副原料の適量を添加することができ、これら易分散安定剤等は、ソース製造工程において、調味料等を加える前あるいは調味料等を加えた後、あるいは調味料等と一緒に加えて更に攪拌すればよい。   In the thick sauces of the present invention, in addition to the easy dispersion stabilizer, an appropriate amount of other auxiliary materials such as a thickening stabilizer and starch can be added within a range not affecting the texture and fluidity. The dispersion stabilizer or the like may be further stirred in the sauce production process before adding the seasoning or the like, after adding the seasoning or the like, or together with the seasoning or the like.

以下、実施例、比較例を用いて本発明を詳細に説明するが、本発明は、これらの具体的態様に限定されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example and a comparative example, this invention is not limited to these specific aspects.

[実施例1]
(ソースの製造)
80℃の温水150gを鍋に入れ、トマトピューレ190gを加えて、加熱しながらヘラで良くかき混ぜた後、予め混合しておいた易分散安定剤(商品名セオラス(登録商標)のDX−1、旭化成ケミカルズ(株)製)5g、砂糖9g、粉末チキンコンソメ5g、オニオンパウダー5g、食塩4g、バジリコ0.5g、ガーリックパウダー0.5g、ホワイトペッパー0.25gを加え、温度を80℃に保ちながら、20分間ヘラで攪拌した。更にオリーブオイル20gを加え更にヘラで攪拌した後、約90gの水で溶いたタピオカ加工澱粉12.5gを加え攪拌した。85℃まで加温し、85℃で3分間更に攪拌しソース重量を500gに調整した後、加熱を止め、5分間プロペラ攪拌(700rpm)した後、袋に充填した。袋詰めしたソースは、90℃温水中に30分間浸し殺菌した後、冷却してトマトソースを得た。
[Example 1]
(Manufacture of sauce)
150 g of warm water of 80 ° C. is put in a pan, 190 g of tomato puree is added, and after stirring well with a spatula while heating, a pre-mixed easy-dispersing stabilizer (trade name DX-1, Asahi Kasei Chemicals Co., Ltd.) 5g, sugar 9g, powdered chicken consomme 5g, onion powder 5g, salt 4g, basilco 0.5g, garlic powder 0.5g, white pepper 0.25g, while keeping the temperature at 80 ° C And stirred with a spatula for 20 minutes. Further, 20 g of olive oil was added and further stirred with a spatula, and then 12.5 g of tapioca-processed starch dissolved in about 90 g of water was added and stirred. After heating to 85 ° C. and further stirring at 85 ° C. for 3 minutes to adjust the source weight to 500 g, heating was stopped and propeller stirring (700 rpm) was performed for 5 minutes, and then the bag was filled. The packaged sauce was soaked in 90 ° C. warm water for 30 minutes for sterilization, and then cooled to obtain a tomato sauce.

(評価)
このトマトソースを60℃に加温した後、共軸二重円筒形回転粘度計(TV−10M形回転粘度計、東機産業製)を用いて、低ずり速度(0.14/秒)における応力を降伏値とした。
降伏値が大きいほど静置時に流れにくく、ソースの食材への付着性が良好と言え、湯がいたスパゲッティの上に60℃に加温したトマトソースを掛け、トマトソースの流下状態を観察した。トマトソースがしたたり落ちずにスパゲッティ上にあるものを付着性が良(○)とし、トマトソースがしたたり落ちて皿に溜まるものを付着性が不良(×)とした。
トマトケチャップ粘度が汎用の充填装置を用いる限界濃度であることが知られており、高ずり速度(14.0/秒)における粘度をトマトケチャップの粘度と比較することで充填装置の適性を判断した。高ずり速度での粘度が、トマトケチャップ粘度より小さいものを適性あり(○)とし、トマトケチャップ粘度より大きいものを適性なし(×)とした。結果を表1に示す。
(Evaluation)
After heating this tomato sauce to 60 ° C., using a coaxial double cylindrical rotational viscometer (TV-10M rotational viscometer, manufactured by Toki Sangyo Co., Ltd.) at a low shear rate (0.14 / second) The stress was taken as the yield value.
It can be said that the higher the yield value, the less likely it is to flow at rest, and the better the adherence of the sauce to the ingredients. The tomato sauce heated to 60 ° C. was placed on the spaghetti with hot water, and the flow of the tomato sauce was observed. A tomato sauce that did not drop or fall on the spaghetti was rated as good (O), and a tomato sauce that fell or accumulated on the plate was considered poor (X).
It is known that the viscosity of tomato ketchup is the limiting concentration using a general-purpose filling device, and the suitability of the filling device was judged by comparing the viscosity at high shear rate (14.0 / sec) with the viscosity of tomato ketchup. . When the viscosity at a high shear rate was smaller than the tomato ketchup viscosity, it was judged as suitable (◯), and when it was larger than the tomato ketchup viscosity, it was judged as unsuitable (x). The results are shown in Table 1.

[実施例2]
易分散安定剤(商品名セオラス(登録商標)のDX−1、旭化成ケミカルズ(株)製)を20gとし、タピオカ加工澱粉を8gとした以外は、実施例1と同様にしてトマトソースを得た。このトマトソースを実施例1と同様にして評価した。結果を表1に示す。
[実施例3]
易分散安定剤(商品名セオラス(登録商標)のDX−1、旭化成ケミカルズ(株)製)を75gとし、タピオカ加工澱粉を2gとした以外は、実施例1と同様にしてトマトソースを得た。このトマトソースを実施例1と同様にして評価した。結果を表1に示す
[Example 2]
A tomato sauce was obtained in the same manner as in Example 1 except that 20 g of the easy-dispersing stabilizer (trade name: DX-1 of Seolas (registered trademark), manufactured by Asahi Kasei Chemicals Co., Ltd.) and 8 g of tapioca processed starch were used. . This tomato sauce was evaluated in the same manner as in Example 1. The results are shown in Table 1.
[Example 3]
A tomato sauce was obtained in the same manner as in Example 1 except that 75 g of the easy-dispersing stabilizer (trade name: DX-1 of Theolas (registered trademark), manufactured by Asahi Kasei Chemicals Co., Ltd.) and 2 g of tapioca processed starch were used. . This tomato sauce was evaluated in the same manner as in Example 1. The results are shown in Table 1.

[比較例1]
易分散安定剤(商品名セオラス(登録商標)のDX−1、旭化成ケミカルズ(株)製)を除き、タピオカ加工澱粉を10gとした以外は、実施例1と同様にしてトマトソースを得た。このトマトソースを実施例1と同様にして評価した。結果を表1に示す。
[比較例2]
易分散安定剤(商品名セオラス(登録商標)のDX−1、旭化成ケミカルズ(株)製)を除き、タピオカ加工澱粉を20gとした以外は、実施例1と同様にしてトマトソースを得た。このトマトソースを実施例1と同様にして評価した。結果を表1に示す。
[比較例3]
易分散安定剤を結晶セルロース(商品名セオラス(登録商標)のRC−N81、旭化成ケミカルズ(株)製)に変えた以外は、実施例2と同様にしてトマトソースを得た。このトマトソースを実施例1と同様にして評価した。結果を表1に示す。
[比較例4]
市販トマトソース(トマトミックスソース、カゴメ(株)製)を60℃に加温した後、実施例1と同様にして評価した。結果を表1に示す。
[Comparative Example 1]
A tomato sauce was obtained in the same manner as in Example 1 except that 10 g of tapioca-processed starch was used except for an easy dispersion stabilizer (trade name: DX-1 of Theolas (registered trademark), manufactured by Asahi Kasei Chemicals Corporation). This tomato sauce was evaluated in the same manner as in Example 1. The results are shown in Table 1.
[Comparative Example 2]
A tomato sauce was obtained in the same manner as in Example 1 except that 20 g of tapioca-processed starch was used except for the easy dispersion stabilizer (trade name: DX-1 of SEOLUS (registered trademark), manufactured by Asahi Kasei Chemicals Corporation). This tomato sauce was evaluated in the same manner as in Example 1. The results are shown in Table 1.
[Comparative Example 3]
A tomato sauce was obtained in the same manner as in Example 2 except that the easy-dispersing stabilizer was changed to crystalline cellulose (trade name: Theolas (registered trademark) RC-N81, manufactured by Asahi Kasei Chemicals Corporation). This tomato sauce was evaluated in the same manner as in Example 1. The results are shown in Table 1.
[Comparative Example 4]
A commercial tomato sauce (tomato mix sauce, manufactured by Kagome Co., Ltd.) was heated to 60 ° C. and then evaluated in the same manner as in Example 1. The results are shown in Table 1.

Figure 0004791407
Figure 0004791407

本発明は、濃厚なソース類において、製造工程中に高圧ホモジナイザーや、高速攪拌機など高剪断力を有する装置を使うことなく、プロペラ攪拌やパドル攪拌程度の弱い剪断力の攪拌装置を用いて製造する濃厚なソース類に有用である。   In the present invention, in dense sauces, a high shearing device such as a high pressure homogenizer or a high speed stirrer is used during the manufacturing process, and a stirrer with weak shearing force such as propeller stirring or paddle stirring is used. Useful for rich sauces.

Claims (2)

易分散安定剤を0.05重量%以上20重量%以下の割合で含有し、高ずり速度が14.0/秒時の粘度が3.6〜4.3Pa・sであるソース組成物。 A source composition containing an easily dispersing stabilizer in a proportion of 0.05% by weight or more and 20% by weight or less and having a high shear rate of 14.0 / sec and a viscosity of 3.6 to 4.3 Pa · s . 降伏値が31.8から46.3Paである請求項1記載のソース組成物。The source composition according to claim 1, wherein the yield value is 31.8 to 46.3 Pa.
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