JP4765325B2 - Pack cosmetic - Google Patents
Pack cosmetic Download PDFInfo
- Publication number
- JP4765325B2 JP4765325B2 JP2005016703A JP2005016703A JP4765325B2 JP 4765325 B2 JP4765325 B2 JP 4765325B2 JP 2005016703 A JP2005016703 A JP 2005016703A JP 2005016703 A JP2005016703 A JP 2005016703A JP 4765325 B2 JP4765325 B2 JP 4765325B2
- Authority
- JP
- Japan
- Prior art keywords
- skin
- mass
- clay mineral
- component
- pack
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title claims description 76
- 239000002734 clay mineral Substances 0.000 claims description 40
- 239000003945 anionic surfactant Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 229920000591 gum Polymers 0.000 claims description 7
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 235000010417 guar gum Nutrition 0.000 claims description 4
- 239000000665 guar gum Substances 0.000 claims description 4
- 229960002154 guar gum Drugs 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 235000010493 xanthan gum Nutrition 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- 244000215068 Acacia senegal Species 0.000 claims description 3
- 235000017788 Cydonia oblonga Nutrition 0.000 claims description 3
- 229920000084 Gum arabic Polymers 0.000 claims description 3
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 3
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000000205 acacia gum Substances 0.000 claims description 3
- 235000010418 carrageenan Nutrition 0.000 claims description 3
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 3
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- 150000001875 compounds Chemical class 0.000 description 26
- -1 etc.) Inorganic materials 0.000 description 25
- 230000003750 conditioning effect Effects 0.000 description 20
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- 229950004354 phosphorylcholine Drugs 0.000 description 3
- PYJNAPOPMIJKJZ-UHFFFAOYSA-N phosphorylcholine chloride Chemical compound [Cl-].C[N+](C)(C)CCOP(O)(O)=O PYJNAPOPMIJKJZ-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
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- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 239000000783 alginic acid Substances 0.000 description 2
- 229960001126 alginic acid Drugs 0.000 description 2
- 150000004781 alginic acids Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical group OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical class C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
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- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910000275 saponite Inorganic materials 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
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- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
本発明はパック化粧料に関し、さらに詳しくは、使用時ののび、肌をひきしめる効果、使用後の洗い流し性、および整肌効果に優れ、かつ使用後に肌をすべすべにして肌にみずみずしさを与え、さらに優れた保存安定性を有するフェイス用、ボディ用などのパック化粧料に関する。 The present invention relates to pack cosmetics, and more specifically, spreads during use, has an effect of squeezing the skin, is excellent in rinsing properties after use, and a skin conditioning effect, and smoothes the skin after use to give the skin freshness, Further, the present invention relates to pack cosmetics for face and body having excellent storage stability.
パック化粧料は、一般的にデイリースキンケアとは別にスペシャルケア製品として週に1〜2回程度使用され、フェイス、ボディなどの肌の状態を整えることを主目的とする製品である。 In general, pack cosmetics are used about 1 to 2 times a week as a special care product separately from daily skin care, and are mainly intended to condition the skin such as the face and body.
パック化粧料は機能面から、「肌に潤いを与えて肌を整える(皮膚の保湿および賦活)」ことを目的とするタイプおよび「肌の汚れを除去しながら肌を整える(皮膚表面の汚垢除去、皮膚の保湿および賦活)」ことを目的とするタイプの2つに大別される。 From the functional aspect, pack cosmetics are of a type that aims to "moisturize and condition the skin (moisturizing and activating the skin)" and "preparing the skin while removing dirt from the skin (stain on the skin surface). Removal, moisturization and activation of the skin) ”.
前者のパック化粧料は紙、フィルムなどに塗布されシート状に加工された肌に貼り付けて剥がすタイプ(貼付けタイプ)である。そして後者のパック化粧料は、使用者が自ら肌に適度な厚さで化粧料を塗布し、一定時間放置した後、肌から化粧料を除去するタイプである。パック化粧料はデイリースキンケアでは除去し難い汚れを除去し、さらに整肌効果も有するため、スキンケアにとって必要不可欠である。後者のタイプのパック化粧料には、具体的には、乾燥させて剥がし落とすタイプ(ピールオフタイプ)、擦り落とすタイプ(ピーリングタイプ)、拭き取るタイプ、洗い流すタイプ(ウォッシャブルタイプ)などのタイプがある。これらの中で、肌への負担などを考慮すると洗い流すタイプが最も有用な製品であり、肌を労わりながらケアすることが可能である。 The former pack cosmetic is a type (paste type) that is applied to paper, film, etc. and applied to the skin processed into a sheet shape and then peeled off. The latter pack cosmetic is a type in which the user himself / herself applies the cosmetic to the skin with an appropriate thickness and leaves it for a certain period of time before removing the cosmetic from the skin. Pack cosmetics are indispensable for skin care because they remove stains that are difficult to remove in daily skin care and also have a skin conditioning effect. Specific examples of the latter type of pack cosmetic include a dry type that peels off (peel-off type), a rub-off type (peeling type), a wiping type, and a wash-out type (washable type). Of these, the washing type is the most useful product in consideration of the burden on the skin and the like, and it is possible to care for the skin while working.
洗い流すタイプとして、最も広く使用されているパック化粧料には「泥パック」がある。「泥パック」は、泥(粘土)の吸着力を利用して肌の汚れを除去するとともに、ミネラルの付加などによる整肌効果を期待するパック化粧料である。例えば、特許文献1には、粘土鉱物、粉末および低級アルコールを含有する皮脂コントロール化粧料が開示され、特許文献2には、ベントナイトおよびシリコン油を含有する化粧料が開示され、特許文献3には、水膨潤性粘土鉱物および合成樹脂エマルジョンを含有するクレイ状パック化粧料が開示され、そして特許文献4には、水膨潤性粘土鉱物を有効成分とする皮膚保護剤が開示されている。 The most widely used pack cosmetic as a type to be washed away is a “mud pack”. “Mud pack” is a pack cosmetic that removes dirt on the skin using the adsorption power of mud (clay) and expects a skin conditioning effect by adding minerals. For example, Patent Document 1 discloses a sebum control cosmetic containing clay mineral, powder and lower alcohol, Patent Document 2 discloses a cosmetic containing bentonite and silicone oil, and Patent Document 3 discloses. A clay-like pack cosmetic containing a water-swellable clay mineral and a synthetic resin emulsion is disclosed, and Patent Document 4 discloses a skin protective agent containing a water-swellable clay mineral as an active ingredient.
しかし、これらの化粧料は、使用時に化粧料ののびが悪い場合があり、皮脂を過剰に除去してしまうことによってつっぱり感および刺激を与えたり、乾燥肌を誘発させたりすることがある。また、粘土鉱物などは皮膚への付着性および残存性が強く、洗い流し性が悪くなるという問題がある。さらに、たれを生じるおそれおよび分離するなどの保存安定性が不良となるおそれがある。 However, these cosmetics may have poor spread of the cosmetics when used, and may give a feeling of irritation and irritation by causing excessive removal of sebum and may induce dry skin. In addition, clay minerals and the like have a problem that the adhesion and persistence to the skin are strong, and the washability is deteriorated. Further, there is a risk of causing dripping and storage stability such as separation may be deteriorated.
特許文献5には、特定の増粘剤および粘土鉱物を含有するパック化粧料が開示されている。このパック化粧料は、使用時ののびおよびたれの問題は解消されているが、つっぱり感、使用後の肌の潤い、および洗い流し性については十分ではない。さらに肌をひきしめる効果および肌のすべすべ感も十分とはいえない。 Patent Document 5 discloses a pack cosmetic containing a specific thickener and clay mineral. Although this pack cosmetic has solved the problems of spreading and dripping at the time of use, it is not sufficient with respect to the feeling of stickiness, moisturization of the skin after use, and washability. Furthermore, it cannot be said that the effect of tightening the skin and the smoothness of the skin are sufficient.
特許文献6には、海藻をアルカリで溶解したペーストおよび粘土鉱物を含有する皮膚外用剤が開示されている。この皮膚外用剤はつっぱり感、刺激性および洗い流し性が改善されているが、その効果は十分とはいえない。さらに、肌をひきしめる効果、肌のすべすべ感、および肌の潤いも十分とはいえず、保存安定性も不良となる場合がある。 Patent Document 6 discloses a skin external preparation containing a paste obtained by dissolving seaweed with an alkali and a clay mineral. This external preparation for skin has improved feeling of tightness, irritation and washability, but the effect is not sufficient. Furthermore, the effect of tightening the skin, the smoothness of the skin, and the moisture of the skin may not be sufficient, and the storage stability may be poor.
したがって、粘土鉱物の有する十分な効果(肌をひきしめる効果など)を発揮させることができないのが現状である。
本発明の目的は、使用時ののび、肌をひきしめる効果、使用後の洗い流し性、および整肌効果に優れ、かつ使用後に肌をすべすべにして肌にみずみずしさを与え、さらに優れた保存安定性を有するパック化粧料を提供することにある。 The object of the present invention is to provide excellent spreading stability during use, excellent skin squeezing effect, wash-out after use, and skin conditioning effect, and smoothness of the skin after use to give the skin freshness and excellent storage stability. It is in providing the pack cosmetic which has.
上記課題を解決するために研究を重ねたところ、粘土鉱物、陰イオン界面活性剤、油性成分、水溶性高分子化合物および2価アルコールを特定の比率で組み合わせることにより、目的とするパック化粧料が得られることを見出し、本発明を完成させるに至った。 As a result of repeated research to solve the above-mentioned problems, a desired pack cosmetic can be obtained by combining clay minerals, anionic surfactants, oil components, water-soluble polymer compounds and dihydric alcohols in specific ratios. The inventors have found that the present invention can be obtained and have completed the present invention.
すなわち、本発明のパック化粧料は、粘土鉱物(a)、陰イオン性界面活性剤(b)、油性成分(c)、水溶性高分子化合物(d)および炭素数2〜6の2価アルコール(e)を含むパック化粧料であって、該油性成分が常温で液状の油性成分であり、該化粧料中に、該粘土鉱物(a)が20〜50質量%、該陰イオン性界面活性剤(b)が0.5〜5質量%、該油性成分(c)が1〜10質量%、該水溶性高分子化合物(d)が0.2〜3質量%および該2価アルコール(e)が1〜10質量%の割合で含有される。 That is, the pack cosmetic of the present invention comprises a clay mineral (a), an anionic surfactant (b), an oil component (c), a water-soluble polymer compound (d), and a dihydric alcohol having 2 to 6 carbon atoms. A cosmetic pack containing (e), wherein the oil component is a liquid oil component at room temperature, and the clay mineral (a) is 20 to 50% by mass in the cosmetic composition, and the anionic surfactant The agent (b) is 0.5 to 5% by mass, the oily component (c) is 1 to 10% by mass, the water-soluble polymer compound (d) is 0.2 to 3% by mass and the dihydric alcohol (e ) Is contained at a ratio of 1 to 10% by mass.
好ましい実施態様においては、上記粘土鉱物(a)は水膨潤性粘土鉱物(a1)と非水膨潤性粘土鉱物(a2)との混合物であり、該水膨潤性粘土鉱物(a1)と該非水膨潤性粘土鉱物(a2)との質量比(a1/a2)が1/4〜1/30である。 In a preferred embodiment, the clay mineral (a) is a mixture of a water-swellable clay mineral (a1) and a non-water-swellable clay mineral (a2), and the water-swellable clay mineral (a1) and the non-water-swellable The mass ratio (a1 / a2) to the functional clay mineral (a2) is 1/4 to 1/30.
本発明のパック化粧料は、使用時ののび、肌をひきしめる効果、使用後の洗い流し性、および整肌効果に優れ、かつ使用後に肌をすべすべにして肌にみずみずしさを与え、さらに優れた保存安定性を有する。 The pack cosmetic of the present invention is excellent in the effect of spreading during use, the effect of squeezing the skin, the washability after use and the skin conditioning effect, and the skin is smooth after use and gives freshness to the skin. Has stability.
本発明のパック化粧料は、下記の粘土鉱物(a)(以下、化合物a、a成分などという場合がある)、陰イオン界面活性剤(b)(以下、化合物b、b成分などという場合がある)、油性成分(c)(以下、化合物c、c成分などという場合がある)、水溶性高分子化合物(d)(以下、化合物d、d成分などという場合がある)、および炭素数2〜6の2価アルコール(e)(以下、化合物e、e成分などという場合がある)を含み、必要に応じて、添加剤および水などの溶媒を含む。以下、これらについて順次説明する。 The pack cosmetic of the present invention may be the following clay mineral (a) (hereinafter sometimes referred to as compound a, component a), anionic surfactant (b) (hereinafter referred to as compound b, component b). ), Oily component (c) (hereinafter sometimes referred to as compound c, component c), water-soluble polymer compound (d) (hereinafter also referred to as compound d, component d), and 2 carbon atoms To 6 dihydric alcohol (e) (hereinafter sometimes referred to as compound e, e component, etc.), and optionally contains a solvent such as an additive and water. Hereinafter, these will be sequentially described.
(粘土鉱物(a))
本発明のパック化粧料に用いられる粘土鉱物(a)は、ケイ酸塩鉱物、タルクおよびマイカであり、これらの中で少なくとも1種以上が用いられる。ケイ酸塩鉱物としては、例えば、フィロケイ酸塩鉱物(カオリン族、モンモリロナイト族、粘土雲母族、緑泥石族、蛇紋石族など)、テクトケイ酸塩鉱物(ゼオライト族など)などが挙げられる。粘土鉱物の具体的な例としては、パイロフィライト、タルク、緑泥石、クリソタイル、アンチゴライト、リザダイト、カオリナイト、デッカイト、ナクライト、ハロサイト、モンモリロナイト、ノントロナイト、サポナイト、ソーコナイト、ペントナイト、ソーダ沸石族(ソーダ沸石、中沸石、スコレス沸石、トムソン沸石など)、輝沸石族(輝沸石、束沸石、剥沸石など)、ゼオライト(方沸石、重十字沸石、灰十字沸石、菱沸石、グメリン沸石など)、ライトなどが挙げられる。
(Clay mineral (a))
The clay mineral (a) used in the pack cosmetic of the present invention is a silicate mineral, talc and mica, and at least one of them is used. Examples of silicate minerals include phyllosilicate minerals (kaolin group, montmorillonite group, clay mica group, chlorite group, serpentine group, etc.), tectosilicate minerals (zeolite group, etc.) and the like. Specific examples of clay minerals include pyrophyllite, talc, chlorite, chrysotile, antigolite, lizardite, kaolinite, decaitite, nacrite, halosite, montmorillonite, nontronite, saponite, sauconite, pentonite, Sodalite group (sodalite, mesolite, scolesite, Thomsonite, etc.), pyroxenite group (Pyroxene, zeolitite, exfoliate, etc.), zeolite (calcite, zeolithite, asphaltite, chabazite, gmelin Zeolite) and light.
粘土鉱物は、その性質によって水膨潤性粘土鉱物(a1)(以下、化合物a1、a1成分などという場合がある)および非水膨潤性粘土鉱物(a2)(以下、化合物a2、a2成分などという場合がある)に分けられる。 Depending on the nature of the clay mineral, the water-swellable clay mineral (a1) (hereinafter sometimes referred to as compound a1, a1 component, etc.) and the non-water-swellable clay mineral (a2) (hereinafter referred to as compound a2, a2 component, etc.) Is divided).
水膨潤性粘土鉱物は、ケイ酸マグネシウム・アルミニウムおよびケイ酸マグネシウム・ナトリウムを主成分とする粘土鉱物である。一般的に、水膨潤性粘土鉱物としては、スメクタイト族鉱物が好ましく、例えばモンモリロナイト、ヘクトライト、サポナイトなどが挙げられる。 The water-swellable clay mineral is a clay mineral mainly composed of magnesium silicate / aluminum and magnesium silicate / sodium. In general, the water-swellable clay mineral is preferably a smectite group mineral, and examples thereof include montmorillonite, hectorite, and saponite.
上記の粘土鉱物は、天然品および合成品のいずれでもよい。 The clay mineral may be a natural product or a synthetic product.
本発明のパック化粧料では、整肌効果および使用後の洗い流し性をより向上させるために、水膨潤性粘土鉱物(a1)および非水膨潤性粘土鉱物(a2)を併用することが好ましい。併用する場合、水膨潤性粘土鉱物と非水膨潤性粘土鉱物との質量比(a1/a2)は、1/4〜1/30の範囲で用いることが好ましく、さらに好ましくは1/5〜1/25である。質量比が1/30より小さい場合、整肌効果および肌をすべすべにする効果が弱くなる。質量比が1/4より大きい場合、肌のひきしめ効果が弱くなるとともに使用後の洗い流し性に劣る傾向がある。 In the pack cosmetic of the present invention, it is preferable to use the water-swellable clay mineral (a1) and the non-water-swellable clay mineral (a2) in combination in order to further improve the skin conditioning effect and the wash-out property after use. When used in combination, the mass ratio (a1 / a2) between the water-swellable clay mineral and the non-water-swellable clay mineral is preferably in the range of 1/4 to 1/30, more preferably 1/5 to 1. / 25. When the mass ratio is less than 1/30, the skin conditioning effect and the effect of smoothing the skin are weakened. When the mass ratio is greater than 1/4, the skin-squeezing effect is weakened and the washability after use tends to be inferior.
(陰イオン界面活性剤(b))
本発明のパック化粧料に用いられる陰イオン界面活性剤(b)は、分子内に親油基および親水基を有し、親水基がカルボキシル基、硫酸基、リン酸基などの陰イオン性基である界面活性剤である。陰イオン界面活性剤の例としては、高級脂肪酸のアルカリ金属塩である石ケン、アルキル硫酸エステル塩、アルキルエーテル硫酸エステル塩、アミドエーテル硫酸エステル塩、アシルアルキルタウリン塩、アシルザルコシン塩、アシルイセチオン酸塩、アシルグルタミン酸塩、アルキルリン酸エステル塩などが挙げられる。これらの中で、使用後の洗い流し性および保存安定性をより向上させるために、硫酸基を有する陰イオン界面活性剤が好ましい。
(Anionic surfactant (b))
The anionic surfactant (b) used in the pack cosmetic of the present invention has a lipophilic group and a hydrophilic group in the molecule, and the hydrophilic group is an anionic group such as a carboxyl group, a sulfate group, or a phosphate group. Is a surfactant. Examples of anionic surfactants include soaps that are alkali metal salts of higher fatty acids, alkyl sulfate esters, alkyl ether sulfate esters, amide ether sulfate salts, acylalkyl taurine salts, acyl sarcosine salts, acyl isethionate salts, Examples include acyl glutamate and alkyl phosphate ester salts. Among these, an anionic surfactant having a sulfate group is preferable in order to further improve the washability and storage stability after use.
硫酸基を有する陰イオン界面活性剤には、一般に硫酸エステル塩(サルフェート)とスルホン酸塩(スルホネート)と称される化合物がある。硫酸エステル塩の例としては、アルキル硫酸エステル塩、アルキルエーテル硫酸エステル塩、アミドエーテル硫酸エステル塩などが挙げられる。一方、スルホン酸塩の例としては、アシルイセチオン酸塩、アシルアルキルタウリン酸塩などが挙げられる。特に陰イオン界面活性剤は限定されないが、硫酸基を有する陰イオン界面活性剤の中でも、スルホン酸塩型の陰イオン界面活性剤がさらに好ましい。 Examples of the anionic surfactant having a sulfate group include compounds generally referred to as a sulfate ester salt (sulfate) and a sulfonate salt (sulfonate). Examples of the sulfate ester salts include alkyl sulfate ester salts, alkyl ether sulfate ester salts, amide ether sulfate ester salts, and the like. On the other hand, examples of the sulfonate include acyl isethionate and acylalkyl taurate. The anionic surfactant is not particularly limited, but among the anionic surfactants having a sulfate group, a sulfonate type anionic surfactant is more preferable.
本発明のパック化粧料に用いられる油性成分(c)は、常温で液状の油性成分である。例えば、自然界から得られる動植物油脂および炭化水素油、常温で液状である合成油などが挙げられる。油性成分の例としては、流動パラフィン、流動イソパラフィン、スクワラン、オリーブ油、米胚芽油、大豆油、ゴマ油、菜種油、ひまわり油、タラ肝油、エステル油(パルミチン酸オクチル、トリカプリン酸グリセリルなど)などが挙げられる。これらの中で、使用時ののびおよび使用後の感触の点から流動パラフィン、流動イソパラフィン、スクワランおよびエステル油が好ましい。 The oil component (c) used in the pack cosmetic of the present invention is an oil component that is liquid at room temperature. For example, animal and vegetable fats and oils and hydrocarbon oils obtained from the natural world, synthetic oils that are liquid at room temperature, and the like can be mentioned. Examples of oily components include liquid paraffin, liquid isoparaffin, squalane, olive oil, rice germ oil, soybean oil, sesame oil, rapeseed oil, sunflower oil, cod liver oil, ester oil (octyl palmitate, glyceryl tricaprate, etc.) . Among these, liquid paraffin, liquid isoparaffin, squalane and ester oil are preferred from the viewpoint of spreading during use and feeling after use.
本発明のパック化粧料に用いられる水溶性高分子化合物(d)は、植物、微生物、動物などに由来する天然高分子化合物(多糖類、タンパク質など)、半合成高分子化合物(セルロース系、デンプン系、アルギン酸系など)および合成高分子化合物(アクリル系、ビニル系など)に分類される。さらに、電気的性質により陰イオン性、陽イオン性、両性および非イオン性に分けられる。これらの水溶性高分子化合物は、レオロジー的性質の改善(増粘作用など)、界面活性作用、皮膜形成作用、保湿作用、包接作用など多岐にわたる機能を有している。天然高分子化合物としては、例えば、アラビアガム、カラーギナン、クインスシードガム、グアガム、ローストビーンガム、ペクチン、トラガント、デンプン、キサンタンガム、デキストリン、フルクタン、プルラン、ヒアルロン酸ナトリウム、コンドロイチン硫酸ナトリウムなどの多糖類、ゼラチン、カゼインなどのタンパク質などが挙げられる。セルロース系の半合成高分子化合物としては、エチルセルロース、カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース、ニトロセルロース、カチオン化セルロースなどが挙げられる。アルギン酸系の半合成高分子化合物としては、アルギン酸ナトリウム、アルギン酸プロピレングリコールなどが挙げられる。アクリル系の合成高分子化合物としては、ポリアクリル酸ナトリウム、カルボキシビニルポリマー、アルキル変性カルボキシビニルポリマー、ポリアクリル酸アミド、アクリルアミド/アクリル酸共重合体などが挙げられる。ビニル系の合成高分子化合物としては、ポリビニルピロリドン、ポリビニルアルコールなどが挙げられる。その他ポリエチレングリコール、ポリグリセリン、カチオン化グアガム、ポリメタクリロイルオキシエチルホスホリルコリンなどが挙げられる。さらに、これらの高分子化合物の誘導体、あるいはこれらの高分子化合物と適切なモノマーとの共重合体で、水溶性のものなどが挙げられる。 The water-soluble polymer compound (d) used in the pack cosmetic of the present invention includes natural polymer compounds (polysaccharides, proteins, etc.) derived from plants, microorganisms, animals, etc., semi-synthetic polymer compounds (cellulose-based, starch) Type, alginic acid type, etc.) and synthetic polymer compounds (acrylic type, vinyl type, etc.). Furthermore, it can be divided into anionic, cationic, amphoteric and nonionic according to electrical properties. These water-soluble polymer compounds have various functions such as improvement of rheological properties (thickening action and the like), surface active action, film forming action, moisturizing action and inclusion action. Examples of the natural polymer compound include gum arabic, carrageenan, quince seed gum, guar gum, roast bean gum, pectin, tragacanth, starch, xanthan gum, dextrin, fructan, pullulan, sodium hyaluronate, chondroitin sulfate and the like, Examples thereof include proteins such as gelatin and casein. Examples of the cellulose semisynthetic polymer compound include ethyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, nitrocellulose, and cationized cellulose. Examples of the alginic acid semisynthetic polymer compound include sodium alginate and propylene glycol alginate. Examples of the acrylic synthetic polymer compound include sodium polyacrylate, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, polyacrylic acid amide, acrylamide / acrylic acid copolymer, and the like. Examples of vinyl-based synthetic polymer compounds include polyvinyl pyrrolidone and polyvinyl alcohol. Other examples include polyethylene glycol, polyglycerin, cationized guar gum, and polymethacryloyloxyethyl phosphorylcholine. Furthermore, derivatives of these polymer compounds, or copolymers of these polymer compounds and appropriate monomers, such as water-soluble ones can be mentioned.
これらの化合物の中で、肌へののび、整肌効果、使用後の感触などを考慮すると、多糖類、ポリメタクリロイルオキシエチルホスホリルコリンあるいはこのポリメタクリロイルオキシエチルホスホリルコリンと他のモノマーとの共重合体が好ましい。これらの中でも、クインスシードガム、グアガム、キサンタンガム、アラビアガム、カラーギナン、ローストビーンガムなどの天然ガム多糖類がさらに好ましい。 Among these compounds, taking into account the spread on skin, skin conditioning effect, feel after use, polysaccharides, polymethacryloyloxyethyl phosphorylcholine or copolymers of this polymethacryloyloxyethyl phosphorylcholine and other monomers are preferable. Among these, natural gum polysaccharides such as quince seed gum, guar gum, xanthan gum, gum arabic, carrageenan, and roast bean gum are more preferable.
本発明のパック化粧料に用いられる炭素数2〜6の2価アルコール(e)は、分子内に2個の水酸基を有する炭素数が2〜6の水溶性のアルコールである。具体的には、エチレングリコール、プロピレングリコール、ジエチレングリコール、1,3−ブチレングリコール、イソプレングリコール、1,2−ペンタンジオール、ヘキシレングリコール、ジプロピレングリコールなどが挙げられる。これらの中で、使用時ののび、洗い流し性および使用後の感触の点から、プロピレングリコール、1,3−ブチレングリコール、イソプレングリコール、1,2−ペンタンジオール、ジプロピレングリコールが好ましい。 The C2-6 dihydric alcohol (e) used in the pack cosmetic of the present invention is a water-soluble alcohol having 2-6 carbon atoms and having 2 hydroxyl groups in the molecule. Specific examples include ethylene glycol, propylene glycol, diethylene glycol, 1,3-butylene glycol, isoprene glycol, 1,2-pentanediol, hexylene glycol, and dipropylene glycol. Among these, propylene glycol, 1,3-butylene glycol, isoprene glycol, 1,2-pentanediol, and dipropylene glycol are preferable from the viewpoints of spreading during use, washability, and feel after use.
(添加剤)
本発明のパック化粧料に含まれ得る添加剤は、本発明の効果を阻害しない範囲内でパック化粧料に含有させることができる。添加剤としては、例えばエタノール、イソプロピルアルコールなどの低級アルコール類;グリセリン、ジグリセリン、ポリエチレングリコール、ソルビトール、マルチトール、イソマルチトールなどの多価アルコール類;乳糖、果糖、ショ糖、マルトース、トレハロース、イソマルトオリゴ糖などの糖類;ワセリン、固形パラフィンなどの炭化水素系油;牛脂、豚脂などの天然油脂類;ラウリン酸、ミリスチン酸、パルチミン酸、ステアリン酸、オレイン酸などの脂肪酸類;ミツロウ、カルナバロウなどのロウ類;高重合ジメチルポリシロキサン、ポリエーテル変性ジメチルポリシロキサン、アミノ変性ジメチルポリシロキサンなどのシリコーン誘導体;セラミド、コレステロール、タンパク誘導体、ラノリン、ラノリン誘導体、レシチンなどの油性基剤;アミドアミノ酸塩、アミドプロピルジメチルアミノ酢酸ベタインなどの両性界面活性剤;ポリオキシエチレンアルキルエーテル、ポリエチレングリコールの脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、グリセリンモノ脂肪酸エステル、アルキルポリグルコシド、アルカノールアミドなどの非イオン性界面活性剤;塩化アルキルトリメチルアンモニウムなどの陽イオン界面活性剤;アルキルジメチルアミンオキシドなどの半極性界面活性剤;ピロリドンカルボン酸塩、クエン酸塩、リンゴ酸塩、食塩などの有機または無機塩類;pH調製剤としての酸およびアルカリ;殺菌剤;キレート剤;抗酸化剤;血行促進剤;紫外線吸収剤;紫外線散乱剤;動植物由来の天然エキス;アスコルビン酸およびその誘導体;アントシアニンなどのフラボノイド類およびその誘導体;ビタミン類;アミノ酸類;感光素;色素;顔料;香料などが挙げられる。
(Additive)
Additives that can be included in the pack cosmetic of the present invention can be contained in the pack cosmetic within a range that does not impair the effects of the present invention. Examples of additives include lower alcohols such as ethanol and isopropyl alcohol; polyhydric alcohols such as glycerin, diglycerin, polyethylene glycol, sorbitol, maltitol, and isomaltitol; lactose, fructose, sucrose, maltose, trehalose, Sugars such as isomaltoligosaccharides; Hydrocarbon oils such as petrolatum and solid paraffin; Natural fats and oils such as beef tallow and lard; Fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid and oleic acid; beeswax and carnauba wax Waxes such as: highly polymerized dimethylpolysiloxane, polyether-modified dimethylpolysiloxane, amino-modified dimethylpolysiloxane and other silicone derivatives; ceramide, cholesterol, protein derivatives, lanolin, lanolin derivatives, lecithin Oily bases; amphoteric surfactants such as amide amino acid salts and amidopropyldimethylaminoacetic acid betaines; polyoxyethylene alkyl ethers, polyethylene glycol fatty acid esters, polyoxyethylene hydrogenated castor oil, polyglycerin fatty acid esters, polyoxyethylene glycerin Nonionic surfactants such as fatty acid esters, glycerin monofatty acid esters, alkylpolyglucosides, alkanolamides; cationic surfactants such as alkyltrimethylammonium chloride; semipolar surfactants such as alkyldimethylamine oxide; pyrrolidone carboxylic acid Organic or inorganic salts such as salts, citrates, malates and salt; acids and alkalis as pH adjusters; bactericides; chelating agents; antioxidants; blood circulation promoters; Turbulent agent; flavonoids and their derivatives, such as anthocyanins; vitamins; ascorbic acid and derivatives thereof; natural extracts derived from animals and plants amino acids; and the like perfumes; photosensitizer; dyes; pigments.
(パック化粧料)
本発明のパック化粧料は、上述のように粘土鉱物(a成分)、陰イオン界面活性剤(b成分)、油性成分(c成分)、水溶性高分子化合物(d成分)、および炭素数2〜6の2価アルコール(e成分)を特定の割合で含み、必要に応じて、添加剤および溶媒(例えば水)などを含む。
(Pack cosmetic)
As described above, the pack cosmetic of the present invention comprises a clay mineral (component a), an anionic surfactant (component b), an oil component (component c), a water-soluble polymer compound (component d), and a carbon number of 2 -6 dihydric alcohol (e component) is contained in a specific ratio, and an additive, a solvent (for example, water) etc. are included as needed.
a成分は、パック化粧料に20〜50質量%、好ましくは25〜45質量%、さらに好ましくは30〜45質量%の割合で含まれる。20質量%未満の場合は、肌をひきしめる効果および整肌効果が弱く、そして肌のすべすべ感が得られない。50質量%を超える場合は、使用時ののびが悪くなる。a成分は単独で用いてもよいし、2種類以上を併用してもよい。さらに、上記のように水膨潤性粘土鉱物(a1)と非水膨潤性粘土鉱物(a2)とを特定の割合で含むことがより好ましい。 The component a is contained in the pack cosmetic in an amount of 20 to 50% by mass, preferably 25 to 45% by mass, and more preferably 30 to 45% by mass. When the amount is less than 20% by mass, the effect of tightening the skin and the skin conditioning effect are weak, and the smooth feeling of the skin cannot be obtained. When it exceeds 50 mass%, the spread at the time of use worsens. A component may be used independently and may use 2 or more types together. Furthermore, as described above, it is more preferable that the water-swellable clay mineral (a1) and the non-water-swellable clay mineral (a2) are contained at a specific ratio.
b成分は、パック化粧料に0.5〜5質量%、好ましくは1〜4質量%、さらに好ましくは1〜3質量%の割合で含まれる。0.5質量%未満の場合は、洗い流し性および保存安定性が悪くなる。5質量%を超える場合は、整肌効果が弱くなり、かつ肌のみずみずしさが得られなくなる。b成分は単独で用いてもよいし、2種類以上を併用してもよい。 The component b is contained in the pack cosmetic in a proportion of 0.5 to 5% by mass, preferably 1 to 4% by mass, and more preferably 1 to 3% by mass. When it is less than 0.5% by mass, the washing out property and the storage stability are deteriorated. When it exceeds 5% by mass, the skin conditioning effect is weakened, and freshness of the skin cannot be obtained. b component may be used independently and may use 2 or more types together.
c成分は、パック化粧料に1〜10質量%、好ましくは2〜8質量%、さらに好ましくは2〜6質量%の割合で含まれる。1質量%未満の場合は、整肌効果が弱くなり、かつ肌のみずみずしさが得られなくなる。10質量%を超える場合は、べたつくことによって洗い流し性が悪くなり、そして保存安定性も悪くなる場合がある。c成分は単独で用いてもよいし、2種類以上を併用してもよい。 The component c is contained in the pack cosmetic in an amount of 1 to 10% by mass, preferably 2 to 8% by mass, and more preferably 2 to 6% by mass. When the amount is less than 1% by mass, the skin conditioning effect is weakened and skin freshness cannot be obtained. When it exceeds 10% by mass, the washability may deteriorate due to stickiness, and the storage stability may also deteriorate. c component may be used independently and may use 2 or more types together.
d成分は、パック化粧料に0.2〜3質量%、好ましくは0.5〜2質量%、さらに好ましくは0.7〜2質量%の割合で含まれる。0.2質量%未満の場合は、使用時ののびおよび保存安定性が悪くなり、さらに肌のみずみずしさが得られなくなる。3質量%を超える場合は、肌のすべすべ感、みずみずしさなど使用後に良好な感触が得られず、さらに化粧料を調製する際、配合が困難になることがある。d成分は単独で用いてもよいし、2種類以上を併用してもよい。 The component d is contained in the pack cosmetic in a proportion of 0.2 to 3% by mass, preferably 0.5 to 2% by mass, and more preferably 0.7 to 2% by mass. When the amount is less than 0.2% by mass, the spread and storage stability during use are deteriorated, and the skin is not fresh. When it exceeds 3% by mass, a good feeling such as smooth skin feeling and freshness cannot be obtained after use, and the formulation may be difficult when preparing a cosmetic. d component may be used independently and may use 2 or more types together.
e成分は、パック化粧料に1〜10質量%、好ましくは2〜8質量%、さらに好ましくは3〜8質量%の割合で含まれる。1質量%未満の場合は、肌のすべすべ感およびみずみずしさが得られず、かつ洗い流し性が悪くなる。10質量%を超える場合は、保存安定性が悪くなる。e成分は単独で用いてもよいし、2種類以上を併用してもよい。 The component e is contained in the pack cosmetic in an amount of 1 to 10% by mass, preferably 2 to 8% by mass, and more preferably 3 to 8% by mass. When the amount is less than 1% by mass, the smooth feeling and freshness of the skin cannot be obtained, and the washability is deteriorated. When it exceeds 10 mass%, storage stability will worsen. e component may be used independently and may use two or more types together.
次に実施例によって、本発明をさらに詳細に説明する。 Next, the present invention will be described in more detail by way of examples.
(実施例1)
表1に示すように、a成分としてベントナイトを2質量%およびカオリン40質量%、b成分としてラウリル硫酸ナトリウムを2質量%、c成分としてスクワランを3質量%、d成分としてキサンタンガムを1質量%、e成分としてジプロピレングリコールを5質量%および精製水を47質量%の割合で配合し、パック化粧料を調製した。
Example 1
As shown in Table 1, 2 mass% bentonite and 40 mass% kaolin as component a, 2 mass% sodium lauryl sulfate as component b, 3 mass% squalane as component c, 1 mass% xanthan gum as component d, As a component e, 5% by mass of dipropylene glycol and 47% by mass of purified water were blended to prepare a pack cosmetic.
調製したパック化粧料について、(1)使用時ののび、(2)肌のひきしめ感、(3)洗い流し性、(4)整肌効果、(5)肌のすべすべ感、(6)肌のみずみずしさ、および(7)保存安定性について、下記の方法によって評価した。 About the prepared pack cosmetics, (1) spreading when used, (2) feeling of skin tightening, (3) washability, (4) skin conditioning effect, (5) smoothness of skin, (6) freshness of skin (7) Storage stability was evaluated by the following method.
(1)使用時ののび
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に塗布してもらった。塗布したときののびについて、下記の基準で判定してもらった。
2点:使用時ののびが軽くスムーズに肌にのびると感じた場合。
1点:使用時ののびがやや悪いと感じた場合。
0点:使用時ののびが非常に悪いと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(使用時ののびが良好なパック化粧料)。
×:合計点が30点未満(使用時ののびが悪いパック化粧料)。
(1) Spread during use Twenty women (21 to 37 years old) were panelists, and the obtained pack cosmetic (about 10 g) was applied to the face. About spreading when applied, it was judged according to the following criteria.
2 points: When you feel that the skin spreads lightly and smoothly on use.
1 point: When the feel of use is slightly bad.
0 points: When feeling that the spread during use is very bad.
The total score of 20 people was calculated and evaluated as follows.
○: The total score is 30 points or more (pack cosmetic with good spreading during use).
X: Total score is less than 30 (pack cosmetics with poor spread during use).
(2)肌のひきしめ感
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に塗布してもらった。塗布後5分間放置したときの肌の感触について、下記の基準で判定してもらった。
2点:十分強いひきしめ感を感じた場合。
1点:ややひきしめ感が弱いと感じた場合。
0点:ほとんどひきしめ感がないと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(肌をひきしめる効果に優れたパック化粧料)。
×:合計点が30点未満(肌をひきしめる効果が悪いパック化粧料)。
(2) Feeling of skin tightening 20 women (21 to 37 years old) were panelists, and the obtained pack cosmetic (about 10 g) was applied to the face. The skin feel when allowed to stand for 5 minutes after application was judged according to the following criteria.
2 points: When a strong feeling of tightness is felt.
1 point: When it is felt that the feeling of tightening is somewhat weak.
0 point: When it is felt that there is almost no feeling of being tight.
The total score of 20 people was calculated and evaluated as follows.
◯: Total score of 30 points or more (pack cosmetics with excellent skin irritating effect).
X: The total score is less than 30 (pack cosmetics that have a poor effect of tightening the skin).
(3)洗い流し性
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に塗布してもらった。次いで、塗布したパック化粧料を洗い流したときの感触について、下記の基準で判定してもらった。
2点:スムーズに洗い流せたと感じた場合。
1点:やや洗い流し性が悪いと感じた場合。
0点:洗い流し難く、洗い流し性が悪いと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(洗い流し性が良好なパック化粧料)。
×:合計点が30点未満(洗い流し性が悪いパック化粧料)。
(3) Rinseability 20 women (21 to 37 years old) were panelists, and the obtained pack cosmetic (about 10 g) was applied to the face. Next, the touch when the applied pack cosmetic was washed away was judged according to the following criteria.
2 points: When feeling that it was washed away smoothly.
1 point: When it is felt that the washability is slightly poor.
0 point: When it is difficult to wash away and it feels that the washability is poor.
The total score of 20 people was calculated and evaluated as follows.
○: The total score is 30 points or more (pack cosmetics with good washability).
X: The total score is less than 30 (pack cosmetics with poor washability).
(4)整肌効果
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に使用してもらった。使用後の肌の状態について、下記の基準で判定してもらった。
2点:肌のキメが整い、透明感のある肌になったと感じた場合。
1点:肌のキメがやや粗く、透明感もやや少ないと感じた場合。
0点:肌のキメが粗く、整肌効果が弱いと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(整肌効果に優れたパック化粧料)。
×:合計点が30点未満(整肌効果が悪いパック化粧料)。
(4) Skin conditioning effect 20 women (21 to 37 years old) were used as panelists, and the obtained pack cosmetic (about 10 g) was used on their faces. The condition of the skin after use was judged according to the following criteria.
2 points: When the skin feels smooth and clear.
1 point: When the texture of the skin is somewhat rough and the feeling of transparency is slightly less.
0 point: When the texture of the skin is rough and the skin conditioning effect is weak.
The total score of 20 people was calculated and evaluated as follows.
A: The total score is 30 points or more (pack cosmetics excellent in skin conditioning effect).
X: The total score is less than 30 (pack cosmetics with poor skin conditioning effect).
(5)肌のすべすべ感
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に使用してもらった。使用後の肌の状態について、下記の基準で判定してもらった。
2点:肌が十分すべすべになったと感じた場合。
1点:肌がややすべすべになったと感じた場合。
0点:肌にすべすべ感がないと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(肌をすべすべにするパック化粧料)。
×:合計点が30点未満(肌をすべすべにしないパック化粧料)。
(5) Skin smoothness 20 females (21 to 37 years old) were panelists, and the obtained pack cosmetic (about 10 g) was used on their faces. The condition of the skin after use was judged according to the following criteria.
2 points: When the skin feels smooth.
1 point: When the skin feels smooth and smooth.
0 point: When the skin feels not smooth.
The total score of 20 people was calculated and evaluated as follows.
○: The total score is 30 points or more (pack cosmetic that makes the skin smooth).
X: The total score is less than 30 (pack cosmetic that does not make the skin smooth).
(6)肌のみずみずしさ
20名の女性(21〜37歳)をパネラーとし、得られたパック化粧料(約10g)を顔に使用してもらった。使用後の肌の状態について、下記の基準で判定してもらった。
2点:肌に潤い感があり、みずみずしいと感じた場合。
1点:肌にやや潤い感があり、ややみずみずしいと感じた場合。
0点:肌にみずみずしさがないと感じた場合。
20名の合計点を求め、以下のように評価した。
○:合計点が30点以上(肌にみずみずしさを与えるパック化粧料)。
×:合計点が30点未満(肌にみずみずしさを与えないパック化粧料)。
(6) Freshness of the skin 20 women (21 to 37 years old) were panelists, and the obtained pack cosmetic (about 10 g) was used on their face. The condition of the skin after use was judged according to the following criteria.
2 points: When the skin feels moist and fresh.
1 point: When the skin feels slightly moist and feels slightly fresh.
0 points: When the skin feels not fresh.
The total score of 20 people was calculated and evaluated as follows.
○: Total score of 30 points or more (pack cosmetic that gives freshness to the skin).
X: The total score is less than 30 (pack cosmetic that does not give freshness to the skin).
(7)保存安定性
得られたパック化粧料を透明ガラス容器に密封して0℃、25℃および40℃で3ヶ月間保存した。3ヶ月後のそれぞれの外観を観察し、下記に示す3段階で評価した。
○:安定性良好(いずれの温度においても外観の変化がなかった場合)。
△:安定性やや不良(いずれかの温度において若干おりおよび沈殿が生じていた。または若干着色が見られた)。
×:安定性不良(いずれかの温度において、おりおよび沈殿が生じ、または分離していた。もしくは、著しい着色が見られた)。
(7) Storage stability The obtained cosmetic pack was sealed in a transparent glass container and stored at 0 ° C, 25 ° C and 40 ° C for 3 months. Each appearance after 3 months was observed and evaluated in the following three stages.
○: Stability is good (when there is no change in appearance at any temperature).
Δ: Slightly inferior (slightly or precipitated at any temperature, or slightly colored)
X: Stability poor (both at any temperature, precipitation and precipitation occurred or separated, or significant coloring was observed).
結果を表2に示す。 The results are shown in Table 2.
(実施例2〜7)
表1に示す各成分を表1に示す割合で配合し、パック化粧料を調製した。調製したパック化粧料について、実施例1と同様にして、上記(1)〜(7)の評価を行った。結果を表2に示す。
(Examples 2 to 7)
Each component shown in Table 1 was blended in the ratio shown in Table 1 to prepare a pack cosmetic. About the prepared pack cosmetics, it carried out similarly to Example 1, and evaluated said (1)-(7). The results are shown in Table 2.
(比較例1〜7)
表3に示す各成分を表3に示す割合で配合し、パック化粧料を調製した。調製したパック化粧料について、実施例1と同様にして、上記(1)〜(7)の評価を行った。結果を表4に示す。
(Comparative Examples 1-7)
Each component shown in Table 3 was blended at a ratio shown in Table 3 to prepare a pack cosmetic. About the prepared pack cosmetics, it carried out similarly to Example 1, and evaluated said (1)-(7). The results are shown in Table 4.
本発明のパック化粧料は、使用時ののび、肌をひきしめる効果、使用後の洗い流し性、および整肌効果に優れ、かつ使用後に肌をすべすべにして肌にみずみずしさを与え、さらに優れた保存安定性を有していた。 The pack cosmetic of the present invention is excellent in the effect of spreading during use, the effect of squeezing the skin, the washability after use and the skin conditioning effect, and the skin is smooth after use and gives freshness to the skin. It had stability.
一方、比較例1〜7では、十分な性能が得られなかった。比較例1では、a成分の含有量が本発明の範囲より多いため、使用時ののびが悪かった。比較例2では、b成分が含まれていないため、洗い流し性および保存安定性が悪かった。比較例3では、b成分の含有量が本発明の範囲より多いため、整肌効果が弱くなり、かつ肌のみずみずしさが得られなかった。比較例4では、c成分が含まれていないため、整肌効果が弱くなり、かつ肌のみずみずしさが得られなかった。比較例5では、d成分が含まれていないため、使用時ののびが悪く、さらに肌のみずみずしさが得られなかった。比較例6では、e成分が含まれていないため、肌のすべすべ感およびみずみずしさが得られず、かつ洗い流し性が悪かった。比較例7では、e成分の含有量が本発明の範囲より多いため、保存安定性が悪かった。 On the other hand, in Comparative Examples 1-7, sufficient performance was not obtained. In Comparative Example 1, since the content of the component a was larger than the range of the present invention, the spread during use was poor. In Comparative Example 2, since the component b was not included, the washability and storage stability were poor. In Comparative Example 3, since the content of the component b was larger than the range of the present invention, the skin conditioning effect was weakened, and freshness of the skin was not obtained. In Comparative Example 4, since the c component was not included, the skin conditioning effect was weak, and the skin was not fresh. In Comparative Example 5, since the d component was not included, the spread at the time of use was poor, and the skin was not fresh. In Comparative Example 6, since the e component was not included, the smooth feeling and freshness of the skin were not obtained, and the washability was poor. In Comparative Example 7, the storage stability was poor because the content of the e component was larger than the range of the present invention.
本発明のパック化粧料は、使用時ののび、肌をひきしめる効果、使用後の洗い流し性、および整肌効果に優れ、かつ使用後に肌をすべすべにして肌にみずみずしさを与え、さらに優れた保存安定性を有するので、フェイス用、ボディ用などのパック化粧料として利用できる。 The pack cosmetic of the present invention is excellent in the effect of spreading during use, the effect of squeezing the skin, the washability after use and the skin conditioning effect, and the skin is smooth after use and gives freshness to the skin. Since it has stability, it can be used as a pack cosmetic for face and body.
Claims (2)
該油性成分が常温で液状の油性成分であり、
該化粧料中に、該粘土鉱物(a)が25〜50質量%、該陰イオン性界面活性剤(b)が0.5〜5質量%、該油性成分(c)が1〜10質量%、該天然ガム多糖類(d)が0.2〜3質量%および該2価アルコール(e)が1〜10質量%の割合で含有される、パック化粧料。 Natural selected from the group consisting of clay mineral (a), sulfate- containing anionic surfactant (b), oil component (c), quince seed gum, guar gum, xanthan gum, gum arabic, carrageenan, roast bean gum A pack cosmetic comprising gum polysaccharide (d) and a dihydric alcohol (e) having 2 to 6 carbon atoms,
The oily component is a liquid oily component at room temperature;
In the cosmetic, the clay mineral (a) is 25 to 50% by mass, the anionic surfactant (b) is 0.5 to 5% by mass, and the oily component (c) is 1 to 10% by mass. A pack cosmetic comprising the natural gum polysaccharide (d) in a proportion of 0.2 to 3% by mass and the dihydric alcohol (e) in a proportion of 1 to 10% by mass.
該水膨潤性粘土鉱物(a1)と該非水膨潤性粘土鉱物(a2)との質量比(a1/a2)が1/4〜1/30である、請求項1に記載のパック化粧料。 The clay mineral is a mixture of a water-swellable clay mineral (a1) and a non-water-swellable clay mineral (a2);
The pack cosmetic according to claim 1, wherein a mass ratio (a1 / a2) between the water-swellable clay mineral (a1) and the non-water-swellable clay mineral (a2) is 1/4 to 1/30.
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