JP4737467B2 - Aseptic filling of carbon dioxide containing liquid - Google Patents

Aseptic filling of carbon dioxide containing liquid Download PDF

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JP4737467B2
JP4737467B2 JP2009046828A JP2009046828A JP4737467B2 JP 4737467 B2 JP4737467 B2 JP 4737467B2 JP 2009046828 A JP2009046828 A JP 2009046828A JP 2009046828 A JP2009046828 A JP 2009046828A JP 4737467 B2 JP4737467 B2 JP 4737467B2
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filling
carbon dioxide
gas
liquid
sterilized
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JP2010202206A (en
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慎治 山本
健 岩下
光雄 谷岡
史章 渡部
武広 浅川
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Toyo Seikan Kaisha Ltd
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Priority to PCT/JP2010/052260 priority patent/WO2010098231A1/en
Priority to CN201080009387.7A priority patent/CN102333719B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B67C3/04Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus without applying pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B67C3/22Details
    • B67C2003/228Aseptic features

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  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Non-Alcoholic Beverages (AREA)

Description

本発明は、炭酸ガス入り内容液の無菌充填方法、特に果汁入り炭酸飲料等の低炭酸飲料の無菌充填に好適な炭酸ガス入り内容液の無菌充填方法に関する。   TECHNICAL FIELD The present invention relates to a method for aseptic filling of a content liquid containing carbon dioxide gas, and more particularly to a method for aseptic filling of a content liquid containing carbon dioxide gas suitable for aseptic filling of a low carbonated beverage such as a carbonated beverage containing fruit juice.

近年、殺菌を要する飲料の容器への充填密封方法において、加熱殺菌を必要とする充填方法に加えて、加熱によるフレーバーの低下等を防ぎ、高品質の飲料を得る充填方法として無菌充填法が広く採用されてきている。しかしながら、無菌充填技術は、果汁飲料などの酸性飲料、コーヒー・茶飲料などの低酸性飲料、ミネラルウォーター等の無炭酸飲料においては確立されているが、果汁入り炭酸飲料や乳成分入り炭酸飲料等の炭酸飲料においては、前記無炭酸飲料と同程度に高度な無菌充填技術は未だ確立に至っていない。その理由は、無菌充填は、充填バルブから容器の汚染を防ぐために充填バルブと容器口が非接触状態で充填する必要があるが、炭酸飲料の場合、充填バルブと容器口とが非接触で容器内が外気に導通している状態で充填すると、容器内圧と充填タンク内圧との相違により液中の炭酸ガスが分離して充填時に泡の噴き零れが生じるので、炭酸飲料の充填は容器内圧と充填タンクが等圧状態でないと良好に充填できないからである。そのため、従来果汁入り炭酸飲料等の殺菌を要する炭酸飲料をPETボトル等の容器に充填する場合、内容液と炭酸ガスを混合して接触型充填バルブで容器に充填密封し、密封後に容器ごと内容液が65℃、10分以上になるようにパストライザーにてボトル外面から加熱殺菌を行っている。従って、その場合無菌充填に比べて加熱による味の劣化が起こり、且つボトルは耐熱圧性の高コストボトルを採用しなければならないという問題点がある。   In recent years, in the filling and sealing method of beverages that require sterilization, in addition to the filling method that requires heat sterilization, aseptic filling method is widely used as a filling method to prevent flavor reduction due to heating and to obtain high quality beverages. Has been adopted. However, aseptic filling technology has been established for acidic beverages such as fruit juice beverages, low acid beverages such as coffee and tea beverages, and non-carbonated beverages such as mineral water, but carbonated beverages containing fruit juice and carbonated beverages containing milk components, etc. As for carbonated beverages, aseptic filling technology as high as that of the non-carbonated beverages has not yet been established. The reason for this is that aseptic filling requires that the filling valve and the container mouth be in a non-contact state to prevent contamination of the container from the filling valve, but in the case of carbonated beverages, the filling valve and the container mouth are not in contact with each other. When filling with the inside being connected to the outside air, the carbon dioxide gas in the liquid is separated due to the difference between the container internal pressure and the filling tank internal pressure, and foam spilling occurs at the time of filling. This is because the filling tank cannot be satisfactorily filled unless it is in an equal pressure state. Therefore, when filling carbonated beverages such as carbonated beverages containing fruit juice into containers such as PET bottles, the contents liquid and carbon dioxide gas are mixed and sealed in a container with a contact-type filling valve. The paste is heated and sterilized from the outer surface of the bottle so that the liquid is at 65 ° C. for 10 minutes or longer. Therefore, in this case, there is a problem that taste deterioration due to heating occurs as compared with aseptic filling, and a high-cost bottle with heat and pressure resistance must be adopted.

前記問題点を解決するために、本出願人は炭酸飲料であっても加熱殺菌を必要としない充填方法及び装置として、内部上方に充填バルブを有する充填チャンバー体の下端にボトルネックリング又は口頚部基部を密着させて密封の充填チャンバーを形成し、該充填チャンバー内で充填バルブの下方にボトル口(容器口)を非接触状態で位置させ、充填チャンバー内に充填タンクから加圧ガスを導入してボトル内と充填タンク内の圧力を同圧にした状態で、炭酸飲料を重力により流下させてボトルに充填する充填方法及び装置を提供した(特許文献1参照)。また、同様な炭酸飲料の無菌充填技術として、充填バルブ本体の下面にリング状のシールパッキンを設けて、容器首部全周を把持するグリッパとでノズル口端と容器口との間をガスシールして充填するようにした無菌充填装置も提案されている(特許文献2参照)。これらの従来技術は、何れも充填バルブと容器口部との間に密閉空間を形成して、ガスシールした状態で炭酸飲料を無菌充填するようにした点では共通している。   In order to solve the above-mentioned problems, the present applicant, as a filling method and apparatus that does not require heat sterilization even for carbonated drinks, has a bottleneck ring or a neck-and-mouth part at the lower end of a filling chamber body having a filling valve inside and above. The base is brought into close contact with each other to form a sealed filling chamber, the bottle mouth (container mouth) is positioned in a non-contact state below the filling valve in the filling chamber, and pressurized gas is introduced into the filling chamber from the filling tank. Thus, a filling method and apparatus for filling a bottle by causing a carbonated beverage to flow down by gravity in a state where the pressure in the bottle and the filling tank are the same are provided (see Patent Document 1). As a similar carbonated beverage aseptic filling technique, a ring-shaped seal packing is provided on the lower surface of the filling valve body, and a gas seal is provided between the nozzle mouth end and the container mouth with a gripper that grips the entire circumference of the container neck. An aseptic filling device has also been proposed (see Patent Document 2). All of these conventional techniques are common in that a closed space is formed between the filling valve and the container mouth and the carbonated beverage is aseptically filled in a gas-sealed state.

特開平7−187292号公報JP-A-7-187292 特開2007−302325号公報JP 2007-302325 A

前記特許文献1、2で提案されている技術は、内容液が接触する容器開口端が直接充填ヘッドに接触しないで充填できる点では、従来の炭酸飲料の充填方法と比べて無菌性を維持できるが、ボトルと充填ヘッドとが完全な非接触ではなく、充填バルブ下端と容器のネックリングや口頚部基部を密着させて、充填チャンバーを形成する点では、従来の炭酸飲料充填方法の延長上の技術であり、非炭酸飲料の無菌充填方法と同様な高度の無菌充填方法を実現するに至っていない。また、前記提案の充填方法は、特別な専用ノズルを必要とし、従来の無菌充填ラインに適用することができずコスト高となるため、改良の必要性があった。   The techniques proposed in Patent Documents 1 and 2 can maintain sterility compared to the conventional carbonated beverage filling method in that the container opening end in contact with the liquid content can be filled without directly contacting the filling head. However, the bottle and the filling head are not completely non-contact, but the lower end of the filling valve and the neck ring of the container or the base of the mouth and neck are closely attached to form a filling chamber, which is an extension of the conventional carbonated beverage filling method. It is a technology and has not yet achieved an advanced aseptic filling method similar to the non-carbonated beverage aseptic filling method. In addition, the proposed filling method requires a special nozzle and cannot be applied to a conventional aseptic filling line, resulting in high costs. Therefore, there is a need for improvement.

そこで、本発明はこれまで実現していない、炭酸飲料、特に果汁入り炭酸飲料等の低炭酸飲料を充填バルブと容器を完全に非接触状態で充填でき、高度の無菌充填を可能にし、且つ既存の無菌充填装置を用いることができ、新たな装置コストを必要とすることなく、炭酸飲料の無菌充填を可能にし、それにより容器も耐熱圧性等を有する特別な容器を用いることなく容器コストが低減でき、しかも高品質の味を維持できる炭酸ガス入り内容液の無菌充填方法を提供することを目的とする。   Therefore, the present invention has not been realized so far, and carbonated beverages, particularly low carbonated beverages such as carbonated beverages with fruit juice, can be filled in a completely non-contact state with the filling valve and the container, enabling highly aseptic filling, and existing Aseptic filling equipment can be used, enabling aseptic filling of carbonated beverages without the need for new equipment costs, thereby reducing container costs without using special containers with heat and pressure resistance. Another object of the present invention is to provide a method for aseptic filling of a liquid solution containing carbon dioxide gas that can maintain high quality taste.

本発明者は、前記問題点を解決するために、種々研究した結果、炭酸ガス入り内容液であっても特定の条件を満たせば、容器と充填バルブが非接触状態で充填可能であることを見出し本発明に到達したものである。
即ち、前記課題を解決するための本発明の炭酸ガス入り内容液の無菌充填方法は、容器、内容液、炭酸ガスを殺菌し、充填密封後の目標炭酸ガスボリュームより高めの炭酸ガスボリュームの炭酸ガス入り内容液を作り、該炭酸ガス入り内容液を充填タンクから保温又は冷却構造となっている経路を介して充填バルブに供給して、該炭酸ガス入り内容液を殺菌された容器に無菌雰囲気で前記充填バルブが容器口上方に位置し容器口と完全に離れた非接触状態で充填することを特徴とするものである。充填密封後の目標ガスボリュームより高めの炭酸ガスボリュームの炭酸ガス入り内容液を作り、それを非接触型充填バルブで充填することによって、充填バルブと容器が非接触状態で充填する際に失われる炭酸ガス量を補填して製品規格通りの炭酸感が得られる炭酸飲料を得ることができる。
As a result of various studies to solve the above problems, the present inventor has confirmed that even if the content liquid contains carbon dioxide gas, the container and the filling valve can be filled in a non-contact state if a specific condition is satisfied. Heading The present invention has been reached.
That is, the aseptic filling method of the content liquid containing carbon dioxide gas of the present invention for solving the above-described problem is to sterilize the container, the content liquid, and carbon dioxide gas, and the carbon dioxide gas volume higher than the target carbon dioxide volume after filling and sealing. A gas-containing content liquid is prepared, and the carbon dioxide-containing content liquid is supplied from the filling tank to the filling valve through a heat insulation or cooling path, and the carbon dioxide-containing content liquid is placed in a sterile atmosphere in a sterilized container. in is characterized in that the filling valve is filled with a non-contact state apart completely and positioned container mouth upwards container mouth. By making the content liquid containing carbon dioxide gas with a volume of carbon dioxide gas higher than the target gas volume after filling and sealing it with a non-contact type filling valve, it is lost when filling the filling valve and container in a non-contact state A carbonated beverage can be obtained in which the amount of carbon dioxide gas is supplemented to obtain a carbonic sensation according to product specifications.

前記炭酸ガス入り内容液を充填温度1〜6℃の低温で容器に充填することによって、泡の発生を抑制して良好に充填できる。炭酸ガス入り内容液の充填温度は、低い方が充填時の炭酸ガスの分離が起き難く噴き零れを抑制でき、6℃以上になると分離量が多くなるので、前記範囲が望ましい。また、充填温度が低すぎると炭酸ガス入り内容液が固まり始め送液時等に問題が起きるため、1℃以上とすることが望ましい。   By filling the content liquid containing carbon dioxide into a container at a low temperature of 1 to 6 ° C., it is possible to satisfactorily fill by suppressing generation of bubbles. The lower the filling temperature of the content liquid containing carbon dioxide gas, the separation of the carbon dioxide gas at the time of filling is less likely to be suppressed, and spilling can be suppressed. In addition, if the filling temperature is too low, the content liquid containing carbon dioxide gas starts to solidify, causing problems when the liquid is fed.

また、前記炭酸ガス入り内容液は、充填密封後の目標ガスボリュームに対して、前記充填タンクでのガスボリュームを15〜25%高めに設定することによって、目標ガスボリュームの炭酸飲料、即ち、炭酸感が良好な飲料を得ることができる。充填タンクでのガスボリュームを前記範囲より高めに設定すると、内容液のガスボリュームが高くなり過ぎて充填時に噴き零れが生じ易く、逆に低くすると噴き零れは生じないが、充填密封後に規格通りのガスボリュームを得ることができない。そして、本発明は、特に、充填密封後のガスボリュームが2.0以下の低炭酸飲料の無菌充填に好適に適用できる。充填密封後のガスボリュームが2.0を超えると、非接触状態で充填する場合、充填時の噴き零れが生じやすいので、2.0以下の低酸性飲料への適用が望ましい。
前記炭酸ガス入り内容液は、調合シロップと水を混合して殺菌した混合液に除菌炭酸ガスを気液混合して作り、充填タンクに供給する方法、又は殺菌済みの水に除菌炭酸ガスを気液混合した炭酸水を、殺菌済み調合シロップに混合して作り、充填タンクに供給する方法の何れを採用してもよい。
In addition, the content liquid containing carbon dioxide is set to 15 to 25% higher than the target gas volume after filling and sealing, so that the carbonated beverage of the target gas volume, that is, carbonic acid. A beverage with a good feeling can be obtained. If the gas volume in the filling tank is set higher than the above range, the gas volume of the content liquid becomes too high and spilling easily occurs during filling, and conversely, if it is lowered, spilling does not occur. The gas volume cannot be obtained. The present invention is particularly applicable to aseptic filling of low carbonated beverages having a gas volume after filling and sealing of 2.0 or less. If the gas volume after filling and sealing exceeds 2.0, when filling in a non-contact state, spilling of the liquid during filling tends to occur, so application to a low acid beverage of 2.0 or less is desirable.
The carbon dioxide-containing content liquid is prepared by mixing liquid sterilized water with sterilized mixed sterilized gas and liquid-sterilized carbon dioxide and supplying it to a filling tank, or sterilized carbon dioxide in sterilized water. Any method may be employed in which carbonated water mixed with gas and liquid is mixed with a sterilized blended syrup and supplied to a filling tank.

本発明によれば、炭酸飲料、特に果汁入り炭酸飲料や乳成分入り炭酸飲料等の低炭酸飲料を充填バルブと容器を完全に非接触状態で充填でき、従来実現できなかった炭酸飲料の高度の無菌充填を可能にし、且つ既存の無菌充填装置を用いることができ、また容器も耐熱圧性等の機能を有する特別な容器を用いることなく容器コストが低減でき、しかも高品質の味を維持できるという格別な効果を奏する。   According to the present invention, carbonated beverages, particularly low carbonated beverages such as carbonated beverages containing fruit juice and carbonated beverages containing milk components, can be filled completely in a non-contact state with the filling valve and the container. Aseptic filling is possible, existing aseptic filling equipment can be used, and the container cost can be reduced without using a special container having functions such as heat and pressure resistance, and high quality taste can be maintained. Has a special effect.

本発明の実施形態に係る炭酸飲料の無菌充填方法を実現するための炭酸飲料無菌充填システム構成図である。It is a carbonated beverage aseptic filling system block diagram for implement | achieving the aseptic filling method of the carbonated beverage which concerns on embodiment of this invention. 本発明の他の実施形態に係る炭酸飲料の無菌充填方法を実現するための炭酸飲料無菌充填システム構成図である。It is a carbonated beverage aseptic filling system block diagram for implement | achieving the aseptic filling method of the carbonated beverage which concerns on other embodiment of this invention. 本発明の実施形態に係る炭酸飲料の無菌充填方法において、非接触型充填バルブで容器に炭酸ガス入り内容液を充填している状態を示す模式図である。In the aseptic filling method of carbonated beverages according to an embodiment of the present invention, it is a schematic diagram showing a state in which a container is filled with a content liquid containing carbon dioxide gas by a non-contact filling valve. 圧入温度(炭酸ガスと内容液を混合溶解する温度)の違いによる、貯液タンクと充填タンク送液工程間のガスボリュームの変化を示す線図である。It is a diagram which shows the change of the gas volume between a storage tank and a filling tank liquid feeding process by the difference in press injection temperature (temperature which mixes and melt | dissolves a carbon dioxide gas and a content liquid). 充填バルブと容器とを非接触状態で炭酸飲料を充填した場合の充填タンク内での内容液ガスボリュームと充填密封後の容器内のガスボリュームの変化を示す線図である。It is a diagram which shows the change of the content liquid gas volume in the filling tank at the time of filling a carbonated beverage in a non-contact state with a filling valve and a container, and the gas volume in the container after filling sealing.

本発明者は、非接触型バルブで炭酸ガス入り内容液の充填を可能にするために、炭酸ガス入り内容液の充填時の噴き零れ現象について種々実験した結果、噴き零れ現象は内容液内の炭酸ガスボリューム(GV)(以下、単にガスボリュームという)が影響し、ガスボリュームが高い程噴き零れ現象が生じるが、充填温度も大きく影響することが分かった。なお、ガスボリュームとは、内容液中に溶解している炭酸ガス体積と内容液全体の体積との比で表わされる。   The present inventor conducted various experiments on the spilling phenomenon during filling of carbon dioxide containing liquid in order to enable filling of the liquid containing carbon dioxide with a non-contact type valve. It was found that carbon dioxide volume (GV) (hereinafter simply referred to as gas volume) has an effect, and the higher the gas volume, the more spilling phenomenon occurs, but the filling temperature also has a significant effect. The gas volume is represented by a ratio between the volume of carbon dioxide dissolved in the content liquid and the volume of the entire content liquid.

図5は、従来の無菌充填で採用される非接触型バルブで充填タンクからボトルに充填する工程での充填タンク内での果汁入り炭酸飲料のガスボリュ−ム(充填タンクガスボリューム,充填時のガスボリューム)とボトル充填密封後のガスボリューム(容器内ガスボリューム)の関係を、果汁入り炭酸飲料の温度を3℃と6℃の場合について実験した結果を示し、横軸が充填タンク内でのガスボリューム、縦軸が充填密封後のガスボリュームを表している。そして、曲線aが充填温度3℃、曲線bが充填温度6℃で前記充填タンクガスボリュームに対する前記容器内ガスボリュームの変化を示し、直線cが前記充填タンクガスボリュームと前記容器内ガスボリュームがガスロスなく充填された場合を直線で表し、該図から明らかなように、充填工程で図示のようにΔqだけガスボリュームの減少が生じているが、充填温度3℃の場合は6℃の場合と比べてガスボリュームの減少が少ない。このことは充填温度が高い程充填時のガスロスが多く、充填温度を低くすることによってガスロスを少なくできることを意味している。また、本実験においては、充填温度が3℃の場合、充填時のガスボリューム1.8〜2.4の範囲ではガスロスは生じても噴き零れが生じることなく、非接触型バルブで充填することができたが、2.4を超えると噴き零れが生じて充填が不可能であった。一方、充填温度が6℃の場合は、充填時のガスボリュームが2.1までは噴き零れが生じることなく充填できたが、2.1を越えると噴き零れが生じて充填することができなかった。以上のことにより、充填温度は1〜6℃が、前述したように炭酸ガス入り内容液の固まり防止、及び充填時の炭酸ガスの分離量が多くなることを防止の点で望ましいが、後に記載する実施例中の表1(実施例3)の結果と併せると、低炭酸飲料における充填密封後のガスボリュームを2.0まで確実に充填するには充填温度は1〜3℃にすることが特に好ましい。   FIG. 5 shows a gas volume of a carbonated beverage containing fruit juice in a filling tank in a process of filling a bottle from a filling tank with a non-contact type valve employed in conventional aseptic filling (filling tank gas volume, gas at filling). Volume) and the gas volume after bottle filling and sealing (gas volume in the container), the results of the experiment for the case of carbonated beverages containing fruit juice at 3 ° C and 6 ° C, the horizontal axis is the gas in the filling tank Volume and vertical axis represent gas volume after filling and sealing. The curve a shows the change in the gas volume in the container with respect to the filling tank gas volume when the filling temperature is 3 ° C. and the curve b is 6 ° C., and the straight line c shows the gas loss between the filling tank gas volume and the gas volume in the container. As shown in the figure, the gas volume is reduced by Δq as shown in the figure, but when the filling temperature is 3 ° C., compared with the case of 6 ° C. There is little decrease in gas volume. This means that the higher the filling temperature, the more gas loss during filling, and the lowering the filling temperature can reduce the gas loss. Also, in this experiment, when the filling temperature is 3 ° C., filling with a non-contact type valve is possible even if a gas loss occurs in the range of gas volume 1.8 to 2.4 at the time of filling without causing spilling. However, when it exceeded 2.4, spilling occurred and filling was impossible. On the other hand, when the filling temperature was 6 ° C., the gas volume at the time of filling could be filled up to 2.1 without causing spilling, but when it exceeded 2.1, spilling occurred and the filling could not be performed. It was. As described above, the filling temperature is preferably 1 to 6 ° C. from the viewpoint of preventing the content liquid containing carbon dioxide from clumping and preventing the amount of carbon dioxide from being separated at the time of filling as described above. When combined with the results of Table 1 (Example 3) in the working examples, the filling temperature should be 1 to 3 ° C. in order to reliably fill the gas volume after filling and sealing in the low carbonated beverage up to 2.0. Particularly preferred.

以上のことから、炭酸ガス入り内容液はある一定のガスボリュームまでは非接触型充填バルブでも充填可能であり、充填温度を低くすることによって、充填可能なガスボリュームをより高くできることが判った。従って、所望のガスボリュームの炭酸飲料を得るには、充填温度を低温にコントロールし、図5のグラフに示す充填タンクでのガスボリュームと充填後のガスボリュームとの差Δqだけ高いガスボリュームで充填することによって、充填密封後の目標ガスボリュームを2.0以下、確実には1.9以下、より確実には1.8以下とすることにより、非接触状態で充填した際に噴き零れを生じることなく、確実に充填することが可能であり、炭酸ガス入り内容液をより高度の無菌充填で得ることができる。従来無菌充填を必要とする炭酸飲料は、果汁入り炭酸飲料等の低炭酸飲料であり、充填密封後のガスボリュームが2.5を超える高炭酸飲料の場合は一般的に果汁、乳性分等を含まないために高度の無菌充填を必要としないので、本方法によって、高度の無菌充填が求められる低炭酸飲料を非接触型バルブによる高度の無菌充填が実用可能であることが分かる。   From the above, it was found that the carbon dioxide-containing content liquid can be filled up to a certain gas volume even with a non-contact filling valve, and that the filling gas volume can be increased by lowering the filling temperature. Therefore, in order to obtain a carbonated beverage having a desired gas volume, the filling temperature is controlled to a low temperature, and filling is performed with a gas volume that is higher by a difference Δq between the gas volume in the filling tank and the gas volume after filling as shown in the graph of FIG. As a result, the target gas volume after filling and sealing is set to 2.0 or less, surely 1.9 or less, and more reliably 1.8 or less, so that spilling occurs when filling in a non-contact state. Therefore, it is possible to reliably fill, and the content liquid containing carbon dioxide gas can be obtained by a higher degree of aseptic filling. Conventional carbonated beverages that require aseptic filling are low-carbonated beverages such as carbonated beverages containing fruit juice. In the case of high-carbonated beverages that have a gas volume of more than 2.5 after filling and sealing, generally fruit juice, milky components, etc. Therefore, it can be seen that the present method is practical for highly aseptic filling with a non-contact type valve for a low carbonated beverage that requires high aseptic filling.

以下、本発明の実施形態に係る炭酸ガス入り内容液を非接触バルブによって無菌充填する場合について、詳細に説明する。
本発明では、炭酸ガス入り内容液の無菌充填を達成するために、非接触での充填技術の外に所望のガスボリュームの無菌炭酸ガス入り内容液を得るための内容液と炭酸ガスの無菌混合(圧入)技術、容器の無菌化技術、装置の無菌化技術が求められる。
内容液と炭酸ガスの無菌混合技術として、調合シロップと水を混合して殺菌した混合液に、除菌炭酸ガスを攪拌混合して溶解させ、飲料の規格ガスボリュームよりも高めに設定し、且つ所定温度に冷却制御した炭酸ガス入り内容液を作り、充填タンクに供給する方法(混合方法1)と、除菌炭酸ガスと殺菌済みの水を混合した無菌炭酸水に、殺菌済み調合シロップを混合して飲料の規格ガスボリュームよりも高めに設定した所定温度に制御した炭酸ガス入り内容液を作り、充填タンクに供給する方法(混合方法2)との2方法を創出した。また、他の内容液と炭酸ガスの無菌混合技術として、殺菌済み調合シロップと殺菌済みの水と除菌炭酸ガスを直接容器に供給して混合する方法も考えられる。本実施形態では、混合方法1と混合方法2を採用した場合について説明する。
Hereinafter, the case where the content liquid containing carbon dioxide according to the embodiment of the present invention is aseptically filled with a non-contact valve will be described in detail.
In the present invention, in order to achieve aseptic filling of the carbon dioxide-containing content liquid, in addition to the non-contact filling technique, aseptic mixing of the content liquid and carbon dioxide gas to obtain the desired liquid volume of the sterile carbon dioxide-containing content liquid (Press-fit) technology, container sterilization technology, and device sterilization technology are required.
Aseptic mixing technology of content liquid and carbon dioxide gas, sterilized carbon dioxide gas is stirred and mixed in the mixed liquid sterilized by mixing the mixed syrup and water, set higher than the standard gas volume of the beverage, and Mixing the sterilized compound syrup with the method of making the content liquid containing carbon dioxide cooled to the specified temperature and supplying it to the filling tank (mixing method 1) and aseptic carbonated water mixed with sterilized carbon dioxide and sterilized water Then, two methods of creating a content liquid containing carbon dioxide gas controlled to a predetermined temperature set higher than the standard gas volume of the beverage and supplying it to the filling tank (mixing method 2) were created. In addition, as another aseptic mixing technique of the content liquid and carbon dioxide, a method in which sterilized preparation syrup, sterilized water, and sterilized carbon dioxide are directly supplied to the container and mixed is also conceivable. This embodiment demonstrates the case where the mixing method 1 and the mixing method 2 are employ | adopted.

図1は、前記混合方法1を採用した場合の本発明の果汁入り炭酸飲料の無菌充填方法の実施形態に係る無菌充填システム構成図である。
図中1は、内容液を貯留する送液タンクであり、2は送液ポンプ、3は加熱殺菌機、4は冷却機、5は炭酸ガスをろ過して除菌する除菌フィルタ、6は炭酸ガスと内容液を攪拌して内容液内に炭酸ガスを溶解させる気液混合器であり、本実施形態ではスタティックミキサーを採用している。気液混合器6で炭酸ガスが溶解された炭酸ガス入り内容液は、その後貯液タンク10、充填タンク12を経て充填バルブ14にて容器15に充填されるが、その間の経路は全て保温又は冷却構造となっており、炭酸ガス入り内容液の温度上昇を防止している。それは、前述したように炭酸ガス入り内容液を噴き零れなく容器に充填するためには、炭酸ガス入り内容液の温度管理が重要な要件となるからである。そのため、気液混合器6と貯液タンク10間は、冷却用二重管又は保温材で外周面を被覆されたホールディングチューブ7で連結され、該ホールディングチューブで一定時間保持して所定温度に冷却して安定させて貯液タンク10に供給するようにし、且つ貯液タンク10と充填タンク12間、及び充填タンク12と充填バルブ14間の配管は、冷却用二重管で連結され、貯液タンク10と充填タンク12は外周面がそれぞれ冷却用ジャケット9、11で被覆され、内容液を所定温度に維持するようにしている。
FIG. 1 is a configuration diagram of an aseptic filling system according to an embodiment of an aseptic filling method for a carbonated beverage containing fruit juice of the present invention when the mixing method 1 is employed.
In the figure, 1 is a liquid feed tank for storing the content liquid, 2 is a liquid feed pump, 3 is a heat sterilizer, 4 is a cooler, 5 is a sterilization filter for filtering and sterilizing carbon dioxide gas, 6 is This is a gas-liquid mixer in which carbon dioxide gas and the content liquid are stirred to dissolve the carbon dioxide gas in the content liquid. In this embodiment, a static mixer is employed. The carbon dioxide-containing content liquid in which the carbon dioxide gas is dissolved in the gas-liquid mixer 6 is then filled into the container 15 by the filling valve 14 via the liquid storage tank 10 and the filling tank 12, but all the paths between them are kept warm. The cooling structure prevents the temperature rise of the liquid containing carbon dioxide. This is because, as described above, the temperature management of the carbon dioxide-containing content liquid is an important requirement in order to fill the container without spilling the carbon dioxide-containing content liquid. Therefore, the gas-liquid mixer 6 and the liquid storage tank 10 are connected by a cooling double tube or a holding tube 7 whose outer peripheral surface is covered with a heat insulating material, and held at the holding tube for a predetermined time to be cooled to a predetermined temperature. The liquid tank 10 is stabilized and supplied to the liquid storage tank 10, and the pipes between the liquid storage tank 10 and the filling tank 12 and between the filling tank 12 and the filling valve 14 are connected by a double cooling pipe. The outer peripheral surfaces of the tank 10 and the filling tank 12 are respectively covered with cooling jackets 9 and 11 so as to maintain the content liquid at a predetermined temperature.

充填バルブは、炭酸ガス入り内容液でありながら、通常の無菌充填用の非接触型充填バルブを採用できるのが本発明の特徴であり、実施形態に係る非接触型充填バルブの模式図が図3に示されている。この非接触型充填バルブ14は、通常の非接触型充填バルブが採用でき、充填ヘッド31が容器口と完全に離れた状態で炭酸ガス入り内容液を充填できるようになっており、充填タンク12から内容液供給管33を介して供給される炭酸ガス入り内容液をバルブ32が間欠駆動することによって、その下方に位置する容器15に向けて流下させて所定量を非接触で充填できるようになっている。   The filling valve is a carbon dioxide-containing content liquid, but a normal non-contact filling valve for aseptic filling can be adopted as a feature of the present invention, and a schematic diagram of the non-contact filling valve according to the embodiment is illustrated. 3. As this non-contact type filling valve 14, a normal non-contact type filling valve can be adopted, and the filling head 31 can be filled with the content liquid containing carbon dioxide gas in a state of being completely separated from the container port. The valve 32 is intermittently driven with the content liquid containing carbon dioxide supplied from the liquid via the content liquid supply pipe 33 so that the liquid flows down toward the container 15 positioned below the liquid so that a predetermined amount can be filled in a non-contact manner. It has become.

以上のシステム構成において、本発明は炭酸ガス入り内容液を無菌充填可能とするために、少なくとも充填バルブ14及び図示していない密封装置までは無菌室に配置され、また図示してないが、通常の例えばPETボトルへの無菌充填ラインと同様に容器供給ラインとして容器を温水又は薬剤等で殺菌して充填密封装置に供給する容器供給ライン、及び蓋供給ラインとして蓋を温水、薬剤又はUV等で殺菌して充填密封装置に供給する蓋供給ラインを有し、殺菌済み容器及び殺菌済み蓋が無菌状態を維持した状態で、無菌雰囲気内で充填密封が行なわれる。   In the above system configuration, in order to enable aseptic filling of the carbon dioxide containing liquid, at least the filling valve 14 and the sealing device (not shown) are disposed in the aseptic chamber. For example, the container supply line is sterilized with warm water or chemicals as a container supply line in the same manner as the aseptic filling line to PET bottles, and the lid is supplied with hot water, chemicals or UV as the lid supply line. A lid supply line for sterilizing and supplying to the filling and sealing device is provided, and filling and sealing are performed in an aseptic atmosphere with the sterilized container and the sterilized lid maintained in a sterile state.

本実施形態では、果汁調合シロップと水とを混合した内容液23を送液タンク1に貯留し、加熱殺菌装置3として、たとえば超高温瞬間殺菌装置(UHT)により瞬間的に殺菌して、冷却機4を通過させることにより1〜6℃の所定温度に冷却し、一方、気液混合器6の直前に炭酸ガスを除菌フィルタ5を通して供給配管21内に供給する。前記炭酸ガスは除菌フィルタ5を通過することによって無菌化された除菌炭酸ガスとなり、内容液と共に気液混合器6に送られ、内容液と混合され、内容液に所定のガスボリュームとなるように所定圧力で圧入されて溶解する。尚、気液混合器6は、本実施形態では装置が簡単でより無菌性維持が容易なスタティックミキサーを採用しているが、それに限るものでない。気液混合器6から下流側は、炭酸ガスが圧入した炭酸飲料から炭酸ガスの分離を抑制するように、前記したように全て保冷又は冷却構造になっており、炭酸飲料は一定温度に保温されている状態を保って、充填バルブ14に供給される。   In the present embodiment, the content liquid 23 obtained by mixing the fruit juice preparation syrup and water is stored in the liquid feeding tank 1 and is instantly sterilized by, for example, an ultra-high temperature instantaneous sterilization apparatus (UHT) as the heat sterilization apparatus 3 and cooled. By passing the machine 4, it is cooled to a predetermined temperature of 1 to 6 ° C., while carbon dioxide is supplied into the supply pipe 21 through the sterilization filter 5 immediately before the gas-liquid mixer 6. The carbon dioxide gas is sterilized by passing through the sterilization filter 5 to be sterilized carbon dioxide gas, sent to the gas-liquid mixer 6 together with the content liquid, mixed with the content liquid, and the content liquid has a predetermined gas volume. As shown in FIG. In the present embodiment, the gas-liquid mixer 6 employs a static mixer that has a simple apparatus and can maintain sterility more easily, but is not limited thereto. As described above, the downstream side of the gas-liquid mixer 6 has a cooling or cooling structure so as to suppress the separation of carbon dioxide from the carbonated beverage into which carbon dioxide has been injected, and the carbonated beverage is kept at a constant temperature. In this state, the filling valve 14 is supplied.

貯液タンク10は、充填タンク12が常に一定の液レベルを保ち、充填バルブ14に常に一定圧で供給できるように、内容液を貯留しておくためのタンクである。前記工程において、炭酸飲料は、途中で僅かながらガスの分離が生じるので、充填タンク12での炭酸飲料が前記図5のグラフで求まるような充填密封後の目標ガスボリュームよりΔqだけ高くなるように、充填タンク12までの経路のガス分離量を考慮にいれ、気液混合器でのガス圧入量を決定する。なお、充填作業に先立って、予め図5に示すデータを確保するための実験を行い、製品規格のガスボリュームを得るための充填温度と充填タンク内における炭酸ガス入り内容液のガスボリュ−ムを決定し、該ガスボリュームから気液混合器での圧入炭酸ガス量を決定する。本発明者の実験によれば、前記実施形態のシステムにおいて、貯液タンク10から充填タンク12までの送液工程では、図4に示すように炭酸ガス入り内容液の温度によらず略0.2ガスボリュームの低減があった。   The liquid storage tank 10 is a tank for storing the content liquid so that the filling tank 12 always maintains a constant liquid level and can always be supplied to the filling valve 14 at a constant pressure. In the above process, the carbonated beverage has a slight gas separation in the middle, so that the carbonated beverage in the filling tank 12 is higher by Δq than the target gas volume after filling and sealing as found in the graph of FIG. In consideration of the gas separation amount of the path to the filling tank 12, the gas injection amount in the gas-liquid mixer is determined. Prior to the filling operation, an experiment for securing the data shown in FIG. 5 was conducted in advance to determine the filling temperature for obtaining the gas volume of the product standard and the gas volume of the content liquid containing carbon dioxide in the filling tank. Then, the amount of injected carbon dioxide gas in the gas-liquid mixer is determined from the gas volume. According to the experiment by the present inventor, in the system of the above embodiment, in the liquid feeding process from the liquid storage tank 10 to the filling tank 12, as shown in FIG. There was a reduction of 2 gas volumes.

図2は、前記混合方法2を採用した場合の本発明の実施形態に係る無菌充填システム構成図である。
前記実施形態と同様な部所については同一の符号を付し、相違点のみについて説明する。本実施形態では、調合済みシロップ26を送液タンク1から送って、加熱殺菌機3で殺菌し、冷却機4で冷却し、液混合器20に送る。一方調合済みシロップと混合するための無菌炭酸水供給工程として、デアレーター16で水を脱気して脱気水27を製造し、それを調合済みシロップと同様に加熱殺菌機18で加熱殺菌し、冷却機19で冷却した脱気水27に、除菌フィルタ5で除菌した除菌炭酸ガスを脱気水送液管22に気液混合器6の直前に導入して、気液混合器6で前記脱気水と炭酸ガスを混合して所定ガスボリュームの炭酸水を得る。得られた炭酸水をホールディングチューブ7で一定時間保持冷却して調合シロップの送液管21と合流し、液混合器20で混合して所定のガスボリュームの炭酸ガス入り内容液を製造し、貯液タンク10に送る。以下、図1に示す実施形態と同様にして、充填タンクから非接触の充填バルブ14により容器15に所定量の炭酸ガス入り内容液を無菌雰囲気下で充填し、密封する。
FIG. 2 is a configuration diagram of an aseptic filling system according to an embodiment of the present invention when the mixing method 2 is employed.
The same parts as those in the above embodiment are denoted by the same reference numerals, and only different points will be described. In this embodiment, the prepared syrup 26 is sent from the liquid feeding tank 1, sterilized by the heat sterilizer 3, cooled by the cooler 4, and sent to the liquid mixer 20. On the other hand, as a sterile carbonated water supply process for mixing with the prepared syrup, deaerator 16 is used to deaerate water to produce deaerated water 27, which is heat sterilized with heat sterilizer 18 in the same manner as the prepared syrup, The sterilized carbon dioxide sterilized by the sterilizing filter 5 is introduced into the degassed water 27 cooled by the cooler 19 into the degassed water feed pipe 22 immediately before the gas-liquid mixer 6. The deaerated water and carbon dioxide are mixed to obtain carbonated water having a predetermined gas volume. The obtained carbonated water is held and cooled for a certain period of time in the holding tube 7 and merged with the liquid feeding pipe 21 of the blended syrup, and mixed in the liquid mixer 20 to produce a carbon dioxide gas-containing content liquid having a predetermined gas volume. Send to liquid tank 10. Thereafter, in the same manner as in the embodiment shown in FIG. 1, the container 15 is filled with a predetermined amount of carbon dioxide-containing content liquid in a sterile atmosphere by a non-contact filling valve 14 and sealed.

以下の実施例及び比較例における炭酸ガス入り内容液の無菌充填方法における泡の噴き零れ、味覚の評価は次のように行なった。
1.泡の噴き零れ
炭酸ガス入り内容液を、ボトルに充填した際の炭酸ガスによる泡の噴き零れ状態を目視で確認し評価した。
2.味覚(爽快感)
充填後のボトル詰め飲料のキャップを開封し、炭酸ガス入り内容液を試飲して爽快感を確認した。製品規格通りの炭酸感が得られ、特に炭酸感に優れていたものを◎、製品規格通りの炭酸感が得られていたものを○、製品規格に対して炭酸感がやや得られていないもの(炭酸が弱いもの)を△、製品規格に対して炭酸感が得られていないものを×と評価した。
In the following Examples and Comparative Examples, evaluation of bubble spilling and taste in the aseptic filling method of carbon dioxide-containing content liquid was performed as follows.
1. Foam spilling The content liquid containing carbon dioxide was visually confirmed and evaluated for the state of foam spilling with carbon dioxide when the bottle was filled.
2. Taste (exhilaration)
The cap of the bottled beverage after filling was opened, and the content liquid containing carbon dioxide gas was sampled to confirm a refreshing feeling. Carbon dioxide feeling that is in accordance with product standards, especially those that were excellent in carbon dioxide feeling, ◎ that that carbon dioxide feeling was obtained in accordance with product standards, and that carbon dioxide feeling was not obtained somewhat to product standards (A weak carbonic acid) was evaluated as Δ, and a carbonic acid feeling that was not obtained with respect to the product standard was evaluated as ×.

[実施例1]
図1に示すシステムを用い、レモン果汁10重量%、ショ糖10重量%及び水80重量%の割合で調合した果汁入り飲料を、95℃−40秒で殺菌後、冷却した。
次いで、前記殺菌済み果汁飲料と除菌した炭酸ガスを、混合、冷却し、充填バルブへの供給時の果汁入り炭酸飲料の炭酸ガス圧をガスボリューム2.1とした。この果汁入り炭酸飲料を、温水殺菌済みの内容量500mlのポリエステル樹脂製ボトルに非接触型充填バルブで充填後、殺菌済みプラスチックキャップで密封し、製品規格炭酸ガス圧であるガスボリューム1.8の果汁入り炭酸飲料ボトル詰めを製造した。尚、前記冷却温度は4℃、充填温度は6℃とした。
前記ボトル詰め飲料の製造における果汁入り炭酸飲料充填時の泡の噴き零れ、前記飲料の充填後の味覚(爽快感)の評価を行なった。
[Example 1]
Using the system shown in FIG. 1, a beverage containing fruit juice prepared at a ratio of 10% by weight of lemon juice, 10% by weight of sucrose and 80% by weight of water was sterilized at 95 ° C. for 40 seconds and then cooled.
Next, the sterilized fruit juice drink and the sterilized carbon dioxide were mixed and cooled, and the carbon dioxide pressure of the fruit-containing carbonated drink at the time of supply to the filling valve was set to gas volume 2.1. After filling this carbonated beverage with fruit juice into a 500 ml polyester resin bottle sterilized with warm water with a non-contact filling valve, it is sealed with a sterilized plastic cap, and the gas volume of 1.8 is the product standard carbon dioxide pressure A bottle of carbonated beverage with fruit juice was produced. The cooling temperature was 4 ° C. and the filling temperature was 6 ° C.
In the production of the bottled beverage, the bubble spilled when filling the carbonated beverage containing fruit juice, and the taste (exhilaration) after filling the beverage was evaluated.

[実施例2]
冷却温度3℃、充填温度を5℃とした以外は、実施例1と同様にボトル詰め飲料を製造し評価を行った。
[Example 2]
A bottled beverage was produced and evaluated in the same manner as in Example 1 except that the cooling temperature was 3 ° C and the filling temperature was 5 ° C.

[実施例3]
充填バルブへの供給時の果汁入り炭酸飲料の炭酸ガス圧をガスボリューム2.3、冷却温度を1℃、充填温度を3℃とし、充填密封後の製品規格炭酸ガス圧であるガスボリューム1.9の果汁入り炭酸飲料のボトル詰め飲料を製造した以外は、実施例1と同様にボトル詰め飲料を製造し評価を行った。
[Example 3]
The carbon dioxide pressure of the carbonated beverage containing fruit juice at the time of supply to the filling valve is set to gas volume 2.3, the cooling temperature is set to 1 ° C., the filling temperature is set to 3 ° C. A bottled beverage was produced and evaluated in the same manner as in Example 1 except that a bottled beverage of 9 carbonated beverage containing fruit juice was produced.

[実施例4]
果汁入り炭酸飲料の製造に際して、図2に示すシステムで除菌した炭酸水を使用した以外は、実施例1と同様な条件でボトル詰め飲料を製造し評価を行った。
[Example 4]
When producing carbonated beverages containing fruit juice, bottled beverages were produced and evaluated under the same conditions as in Example 1 except that carbonated water sterilized by the system shown in FIG. 2 was used.

[比較例1]
充填バルブへの供給時の果汁入り炭酸飲料の炭酸ガス圧(ガスボリューム)を、充填密封後の製品規格の炭酸ガス圧ガスボリューム1.8と同じガスボリュームとした以外は、実施例1と同様な方法・条件でボトル詰め飲料を製造し評価を行った。
[Comparative Example 1]
Example 1 except that the carbon dioxide pressure (gas volume) of the carbonated beverage containing fruit juice at the time of supply to the filling valve is the same gas volume as the carbon dioxide pressure gas volume 1.8 of the product standard after filling and sealing. Bottled beverages were manufactured and evaluated using various methods and conditions.

[比較例2]
充填バルブへの供給時の果汁入り炭酸飲料の炭酸ガス圧(ガスボリューム)を、充填密封後の製品規格の1.8と同じとし、冷却温度8℃、充填温度を10℃とした以外は、実施例1と同様にボトル詰め飲料を製造し評価を行った。
[Comparative Example 2]
The carbon dioxide pressure (gas volume) of the carbonated beverage containing fruit juice at the time of supply to the filling valve is the same as 1.8 in the product standard after filling and sealing, except that the cooling temperature is 8 ° C and the filling temperature is 10 ° C. A bottled beverage was produced and evaluated in the same manner as in Example 1.

[比較例3]
充填バルブへの供給時の果汁入り炭酸飲料の炭酸ガス圧(ガスボリューム)を、充填密封後の製品規格の1.8と同じとし、冷却温度6℃、充填温度を8℃とした以外は、実施例1と同様にボトル詰め飲料を製造し評価を行った。
以上の実施例、比較例の結果を表1に示す。なお、表1において、充填タンクガスボリュームの列における括弧内の数値は、充填密封後のガスボリュームに対する充填タンクでのガスホリューム割増率を表している。
[Comparative Example 3]
The carbon dioxide pressure (gas volume) of the carbonated beverage containing fruit juice at the time of supply to the filling valve is the same as the product standard 1.8 after filling and sealing, except that the cooling temperature is 6 ° C and the filling temperature is 8 ° C. A bottled beverage was produced and evaluated in the same manner as in Example 1.
The results of the above examples and comparative examples are shown in Table 1. In Table 1, the numerical value in parentheses in the column of the filling tank gas volume represents the gas volume premium rate in the filling tank with respect to the gas volume after filling and sealing.

Figure 0004737467
Figure 0004737467

以上の実施例1〜4において、何れも泡の噴き零れがなく充填でき、且つ充填密封後の内容液のガスボリュームも目標値が得られ、爽快感も満足のいくものが得られ、本発明により炭酸飲料の非接触バルブにより無菌充填が可能であることが確認された。実施例2では実施例1より充填温度を低くして同じガスボリュームを充填したが、製品規格である所望の充填後のガスボリューム1.8を良好に得ることが出来た。実施例3では目標値を1.9として、充填タンクでのガスボリュームをそれより21.1%に高めに設定し、充填温度を実施例1より低くすることで、実施例1よりも高いガスボリュームの炭酸飲料を製造することができた。また、実施例4は混合方法2によっても、同様な効果が得られることが確認された。一方、比較例では、実施例1と同様のシステムを用い、充填バルブへの供給時のガスボリューム(充填タンク内でのガスボリューム)を充填密封後のガスボリュームの目標値(製品規格)と同じガスボリューム1.8として充填した。比較例1では、充填タンクでの果汁入り炭酸飲料のガスボリュームも目標値1.8に設定して、実施例1と同様に6℃で行なった結果、充填時の泡の噴き零れはなく良好に充填できたが、製品規格である所望のガスボリューム1.8が得られず、爽快感がやや不足したものとなった。また、比較例2では、充填温度10℃と比較例1よりも高めにして行なった結果、充填時に噴き零れが発生し、且つ比較例1よりもかなり低いガスボリュームしか得られず、爽快感は全く足りないものとなった。また、比較例3は、比較例2よりも低い充填温度8℃とした以外は同様の条件で行ったが、充填時に若干噴き零れが発生し、かつ製品規格である所望のガスボリュームが得られず、爽快感の悪いものとなった。   In the above Examples 1 to 4, all can be filled without spilling of bubbles, the gas volume of the content liquid after filling and sealing can be set to a target value, and a refreshing feeling can be obtained. As a result, it was confirmed that aseptic filling was possible with a non-contact valve for carbonated beverages. In Example 2, the same gas volume was filled at a lower filling temperature than in Example 1. However, a desired gas volume 1.8 after filling, which is a product standard, was successfully obtained. In the third embodiment, the target value is set to 1.9, the gas volume in the filling tank is set to 21.1% higher than that, and the filling temperature is set lower than that in the first embodiment. A volume of carbonated beverage could be produced. In addition, it was confirmed that the same effect was obtained in Example 4 also by the mixing method 2. On the other hand, in the comparative example, the same system as in Example 1 is used, and the gas volume (gas volume in the filling tank) at the time of supply to the filling valve is the same as the target value (product standard) of the gas volume after filling and sealing. Filled as gas volume 1.8. In Comparative Example 1, the gas volume of the carbonated beverage containing fruit juice in the filling tank was also set to the target value of 1.8, and was carried out at 6 ° C. as in Example 1. However, the desired gas volume of 1.8, which is the product standard, was not obtained, and the refreshing feeling was slightly insufficient. In Comparative Example 2, the filling temperature was 10 ° C. and higher than Comparative Example 1. As a result, spilling occurred at the time of filling, and only a gas volume much lower than that of Comparative Example 1 was obtained. It was completely lacking. Comparative Example 3 was carried out under the same conditions except that the filling temperature was 8 ° C., which was lower than that of Comparative Example 2. However, a slight spilling occurred during filling, and a desired gas volume that was a product standard was obtained. The feeling of exhilaration was poor.

本発明は、炭酸飲料を非接触型充填バルブを使用して無菌充填するのに広く利用でき、特に、果汁入り炭酸飲料や乳成分入り炭酸飲料等の殺菌を必要とする炭酸飲料の充填密封に好適に適用でき、容器はボトル、缶、その他の容器が適用でき、加熱処理を必要としないので、耐熱圧性容器でなくても適用可能である。   INDUSTRIAL APPLICABILITY The present invention can be widely used for aseptic filling of carbonated beverages using a non-contact filling valve, and particularly for filling and sealing carbonated beverages that require sterilization, such as carbonated beverages containing fruit juice or carbonated beverages containing milk components. The container can be suitably applied, and a container such as a bottle, can, or other container can be applied, and since heat treatment is not required, the container can be applied even if it is not a heat and pressure resistant container.

1 送液タンク 2 送液ポンプ
3 加熱殺菌機 4 冷却機
5 除菌フィルタ 6 気液混合器
7 ホールディングチューブ 8 冷却用二重管又は保温材
9 冷却用ジャケット 10 貯液タンク
11 冷却用ジャケット 12 充填タンク
13 冷却用二重管 14 充填バルブ
15 容器 16 デアレーター
17 送水ポンプ 18 加熱殺菌機
19 冷却機 20 液混合器
21 供給配管 22 脱気水送液管
23 調合シロップと水との混合液 25 果汁入り炭酸飲料
26 調合シロップ 27 脱気水
30 バルブ本体 31 充填ヘッド
33 内容液供給管
DESCRIPTION OF SYMBOLS 1 Liquid feed tank 2 Liquid feed pump 3 Heat sterilizer 4 Cooler 5 Disinfection filter 6 Gas-liquid mixer 7 Holding tube 8 Cooling double tube or heat insulating material 9 Cooling jacket 10 Liquid storage tank 11 Cooling jacket 12 Filling Tank 13 Cooling double pipe 14 Fill valve 15 Container 16 Dealer 17 Water pump 18 Heat sterilizer 19 Cooler 20 Liquid mixer 21 Supply pipe 22 Deaerated water liquid pipe 23 Mixed liquid of mixed syrup and water 25 Contains fruit juice Carbonated beverage 26 Compound syrup 27 Deaerated water 30 Valve body 31 Filling head 33 Contents liquid supply pipe

Claims (3)

低炭酸飲料の無菌充填方法であって、
容器、内容液、炭酸ガスを殺菌し、
充填密封後の目標炭酸ガスボリュームより15〜25%高めの炭酸ガスボリュームの炭酸ガス入り内容液を作り、
該炭酸ガス入り内容液を充填タンクから保温又は冷却構造となっている経路を介して充填バルブに供給して、
該炭酸ガス入り内容液を殺菌された容器に無菌雰囲気で前記充填バルブが容器口上方に位置し容器口と完全に離れた非接触状態で充填温度1〜6℃で充填し、
充填密封後のガスボリュームが2.0以下であることを特徴とする
炭酸ガス入り内容液の無菌充填方法。
Aseptic filling method for low carbonated beverages ,
Sterilize containers, liquid contents, carbon dioxide,
Make a carbon dioxide containing liquid with a carbon dioxide volume 15-25% higher than the target carbon dioxide volume after filling and sealing,
Supplying the content liquid containing carbon dioxide gas from the filling tank to the filling valve via a path having a heat insulation or cooling structure,
Filling the sterilized container with the carbon dioxide containing liquid at a filling temperature of 1 to 6 ° C. in a non-contact state in which the filling valve is located above the container mouth and completely separated from the container mouth in an aseptic atmosphere,
A method for aseptic filling of a content liquid containing carbon dioxide gas , wherein the gas volume after filling and sealing is 2.0 or less .
前記炭酸ガス入り内容液は、果汁調合シロップと水を混合して殺菌した混合液に除菌炭酸ガスを気液混合して作り、充填タンクに供給されることを特徴とする請求項に記載の炭酸ガス入り内容液の無菌充填方法。 The carbon dioxide gas-filled liquid contents is claim 1, characterized in that made by gas-liquid mixing sterilized carbon dioxide gas mixture was sterilized by mixing the juice blended syrup and water, is supplied to the filling tank Aseptic filling method of content liquid containing carbon dioxide gas. 前記炭酸ガス入り内容液は、殺菌済みの脱気水に除菌炭酸ガスを気液混合して作った炭酸水と殺菌済み果汁調合シロップを混合して作り、充填タンクに供給されることを特徴とする請求項に記載の炭酸ガス入り内容液の無菌充填方法。 The content liquid containing carbon dioxide is prepared by mixing sterilized degassed water with sterilized fruit juice syrup mixed with carbonated water prepared by gas-liquid mixing of sterilized carbon dioxide, and supplied to a filling tank. The aseptic filling method of the content liquid containing carbon dioxide gas according to claim 1 .
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