JP4646553B2 - Shoe toe sheet - Google Patents
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- JP4646553B2 JP4646553B2 JP2004179342A JP2004179342A JP4646553B2 JP 4646553 B2 JP4646553 B2 JP 4646553B2 JP 2004179342 A JP2004179342 A JP 2004179342A JP 2004179342 A JP2004179342 A JP 2004179342A JP 4646553 B2 JP4646553 B2 JP 4646553B2
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Description
本発明は、靴のつま先シートの改良に関するものである。 The present invention relates to an improvement in a toe sheet of a shoe.
靴を長時間履き続けると、靴の内部は通気性が悪いため、足の発汗等により温度及び湿度が上がり、足が蒸れて細菌類の繁殖を招き、悪臭の発生原因となる。このため、靴の内部の抗菌、消臭を目的とした各種製品、例えば靴用の消臭中敷、消臭スプレーなどが市販されている。前者の消臭中敷の場合、通常裏面に剥離紙付きの粘着シート等を付設し、剥離紙を剥した後、粘着剤により中敷を靴内部に貼り付け靴に固定する。しかしながら、強い粘着力のため、例えば使用後中敷を剥すのが困難で、無理に剥すと靴の内部部材を損傷させる恐れがある。
かかる問題点を解決する試みとして、特開２０００−１３５１０２号公報には、全面もしくは部分的に樹脂を塗布して靴の内部に仮固定できる下シート部材と、消臭剤を介在させた上シート部材とを順次積層してなる靴用部分消臭シートが開示されている。この消臭シートは、粘着剤の使用を止めて仮固定可能な構成に変えたものであるが、つま先のべたつき解消や使用性等が改善されたものでなかった。
If the shoe is worn for a long time, the inside of the shoe is poorly breathable, so the temperature and humidity rise due to sweating of the foot, and the foot becomes stuffy, causing bacterial growth and causing bad odor. For this reason, various products for the purpose of antibacterial and deodorizing inside shoes, for example, a deodorizing insole for shoes, a deodorizing spray, etc. are marketed. In the case of the former deodorant insole, an adhesive sheet with release paper is usually attached to the back side, and after peeling off the release paper, the insole is attached inside the shoe with an adhesive and fixed to the shoe. However, due to the strong adhesive force, for example, it is difficult to remove the insole after use, and there is a risk of damaging the internal members of the shoe if it is forcibly removed.
As an attempt to solve such problems, Japanese Patent Application Laid-Open No. 2000-135102 discloses a lower sheet member that can be temporarily fixed to the inside of a shoe by applying resin entirely or partially, and an upper sheet having a deodorant interposed therebetween. A partial deodorizing sheet for shoes formed by sequentially laminating members is disclosed. Although this deodorizing sheet was changed to a configuration in which the use of the pressure-sensitive adhesive was stopped and temporarily fixed, the stickiness of the toes and the usability were not improved.
そこで本発明者らは、先に、レーヨンを素材とする不織布製シートに抗菌・防臭剤を保持させ、滑り止め加工としてアクリル樹脂を部分的に塗布してなる靴のつま先シートに関して特許出願を行った（特願２００３−５９５４）。しかしながら、レーヨン素材を使用するのみでは堅牢性や吸水性が必ずしも十分満足とは言えず、またアクリル樹脂を例えばエアゾールを用いて部分的に塗布する方法によると、製造上塗布にバラツキを生じることがあり改良の余地が残されていた。
本発明は、すぐれた抗菌・防臭効果を奏し、滑り止めの点で有効なことはもちろん、つま先のべたつきを抑え、しかも薄型でありながら、よれたり、シワになったりせず、窮屈感を与えない実用的な靴のつま先シートを提供することを目的とする。 The present invention has excellent antibacterial and deodorizing effects, is effective in terms of anti-slip, of course, suppresses stickiness of the toes, and is thin but does not twist or wrinkle, giving a tight feeling Aim to provide not practical shoe toe sheet.
上記課題を解決するため、本発明は以下の構成を採用する。
（１）アクリル樹脂及び酢酸ビニル樹脂を含むプラスチック樹脂とノニオン系界面活性剤を成分として含有し、かつ前記各成分の組成が、アクリル樹脂０．５〜５部／酢酸ビニル樹脂０．２〜２部／ノニオン系界面活性剤０．０５〜０．５部である混合エマルジョンで浸漬処理を施し堅牢性ならびに親水性を高めた不織布製シートに、抗菌・防臭剤を保持させるとともに、滑り止め加工として前記不織布製シートの片面の略全面にわたりアクリル酸エステル共重合樹脂をドット状に塗布した靴のつま先シート。
（２）抗菌・防臭剤が天然産のキチンキトサンである（１）に記載の靴のつま先シート。
In order to solve the above problems, the present invention adopts the following configuration.
(1) A plastic resin containing an acrylic resin and a vinyl acetate resin and a nonionic surfactant are contained as components, and the composition of each component is 0.5 to 5 parts of an acrylic resin / 0.2 to 2 of a vinyl acetate resin. Part / nonionic surfactant 0.05-0.5 part as a non-slip finish while retaining antibacterial and deodorant on a non-woven sheet that has been dipped in a mixed emulsion to improve fastness and hydrophilicity A shoe toe sheet in which an acrylate copolymer resin is applied in a dot shape over substantially the entire surface of one side of the nonwoven fabric sheet.
( 2 ) The toe sheet for shoes according to (1), wherein the antibacterial / deodorant is a natural chitin chitosan.
本発明の靴のつま先シートは、パンプスやサンダル、紳士靴等のつま先に挿入すると、すぐれた抗菌・防臭効果を奏することはもちろん、つま先のべたつきを抑え、しかも薄型で窮屈感を与えずに滑り止めの作用を有することから極めて実用的である。 The toe sheet of the shoes of the present invention, when inserted into toes such as pumps, sandals, men's shoes, etc., not only exhibits excellent antibacterial and deodorizing effects, but also suppresses stickiness of the toes and is thin and slips without giving a tight feeling It is extremely practical because it has a stopping effect.
本発明の靴のつま先シートに用いる不織布製シートとしては、種々の材質のものを使用できるが、吸湿性がよく発汗によるべたつきを抑えるのに効果的なレーヨン素材が好ましい。もちろんレーヨン単繊維でもよいが、吸湿性や強度の面で支障を来たさない限りにおいて、これとパルプ、ポリエステル繊維、ポリプロピレン繊維、ポリアミド繊維等との複合繊維又はこれらの共重合繊維としても構わない。不織布製シートの形状は、任意であるが、厚さが０．１ｍｍ〜１．０ｍｍ程度の薄くて通気性のよいものが好適に用いられる。必要ならば多数の小孔を設け通気性を一層付与するようにしてもよい。 As the nonwoven fabric sheet used for the toe sheet of the shoe of the present invention, various materials can be used, but a rayon material that has good moisture absorption and is effective in suppressing stickiness due to sweating is preferable. Of course, a single rayon fiber may be used, but as long as it does not hinder hygroscopicity and strength, it may be a composite fiber of this with pulp, polyester fiber, polypropylene fiber, polyamide fiber or the like, or a copolymer fiber thereof. Absent. Although the shape of the nonwoven fabric sheet is arbitrary, a thin sheet having a thickness of about 0.1 mm to 1.0 mm and good air permeability is preferably used. If necessary, a large number of small holes may be provided to further impart air permeability.
このようなレーヨン素材の薄いシートは、使用時に窮屈姓を与えない利点を有するものの、靴の中でよれたり、シワを生じることがある。そこで、本発明の靴のつま先シートは、堅牢性ならびに親水性をより高めるために、前記不織布製シート、好ましくはレーヨン不織布を、プラスチック樹脂とノニオン系界面活性剤を含む混合エマルジョンに浸漬させたことに特徴を有する。 Although such a thin sheet of rayon material has the advantage of not giving a cramped surname when used, it may hang or wrinkle in the shoe. Therefore, in the toe sheet of the shoe of the present invention, in order to further improve fastness and hydrophilicity, the non-woven fabric sheet, preferably a rayon non-woven fabric, was immersed in a mixed emulsion containing a plastic resin and a nonionic surfactant. It has the characteristics.
プラスチック樹脂としては、アクリル樹脂と、酢酸ビニル樹脂あるいはＰＶＡ樹脂等の親水性樹脂を併用するのがよい。本処理に使用するアクリル樹脂としては、一般的に紙、繊維製品用として使用されるアクリルエマルジョンが代表的で、例えば、ボンコートＡＮ−１８０Ｈ（大日本インキ化学工業株式会社製）等を例示できる。通常、こうした一般的なアクリル樹脂のみで加工を施した不織布は、堅牢性が付与されるものの撥水性をも示す傾向があるので、本発明では、親水性や吸水性能を高めるためにアクリル樹脂に酢酸ビニル樹脂あるいはＰＶＡ樹脂等の親水性樹脂を加え、更に後記するノニオン系界面活性剤を添加してなる混合エマルジョンで処理するのが好ましい。本発明で使用する酢酸ビニル樹脂は、一般的な繊維処理用の酢酸ビニル樹脂でよく、例えば、ビニゾール８０２（大同化成工業株式会社製）があげられる。 As the plastic resin, an acrylic resin and a hydrophilic resin such as a vinyl acetate resin or a PVA resin are preferably used in combination. The acrylic resin used in this treatment is typically an acrylic emulsion generally used for paper and textile products, and examples thereof include Boncoat AN-180H (Dainippon Ink Chemical Co., Ltd.). Normally, nonwoven fabrics processed only with such general acrylic resins tend to exhibit water repellency although they are fastened. Therefore, in the present invention, acrylic resins are used to improve hydrophilicity and water absorption performance. It is preferable to treat with a mixed emulsion obtained by adding a hydrophilic resin such as vinyl acetate resin or PVA resin and further adding a nonionic surfactant described later. The vinyl acetate resin used in the present invention may be a general vinyl acetate resin for fiber treatment, and examples thereof include vinylol 802 (manufactured by Daido Kasei Kogyo Co., Ltd.).
本発明では、前記したように親水性向上のために、プラスチック樹脂のエマルジョンに、ノニオン系界面活性剤を添加して用いる。添加されるノニオン系界面活性剤としては、特に限定されず通常入手できる一般的なものでよいが、ポリオキシエチレンアルキルエーテルや、ポリオキシエチレン・ポリオキシプロピレンブロックコポリマー、あるいはそのＥＯ付加物等が好適であり、不織布シートの材質や加工後の堅牢性、親水性等を考慮して適宜決定される。 In the present invention, as described above, a nonionic surfactant is added to the plastic resin emulsion to improve hydrophilicity. The nonionic surfactant to be added is not particularly limited and may be a commonly available general one. However, polyoxyethylene alkyl ether, polyoxyethylene / polyoxypropylene block copolymer, or an EO adduct thereof may be used. It is suitably determined in consideration of the material of the nonwoven fabric sheet, fastness after processing, hydrophilicity, and the like.
浸漬処理方法としては、例えばアクリル樹脂０．５〜５部／酢酸ビニル樹脂０．２〜２部／ノニオン系界面活性剤０．０５〜０．５部程度からなる混合エマルジョンに、不織布を浸漬し、乾燥工程を経る方法が一般的である。こうして、例えばプラスチック樹脂を不織布面積あたり、０．１〜１０ｇ／ｍ2程度固着させてなるレーヨン不織布は、レーヨン不織布本来の強度を高め堅牢性に優れたシートを提供するとともに、親水性も一層良好となり、靴の中に入れて使用しても、よれたりシワになったりせず、かつ、靴の中の湿気を有効に吸い取ることが可能となる。 As an immersion treatment method, for example, a non-woven fabric is immersed in a mixed emulsion composed of about 0.5 to 5 parts of an acrylic resin / 0.2 to 2 parts of a vinyl acetate resin / about 0.05 to 0.5 part of a nonionic surfactant. A method of passing through a drying step is common. Thus, for example, a rayon nonwoven fabric in which a plastic resin is fixed to about 0.1 to 10 g / m 2 per area of the nonwoven fabric provides a sheet that increases the original strength of the rayon nonwoven fabric and is excellent in fastness, and has better hydrophilicity. Therefore, even if it is used in a shoe, it does not wrinkle or wrinkle, and it is possible to effectively absorb moisture in the shoe.
さらに、本発明のシートは、抗菌・防臭剤を保持させることによって抗菌防臭効果を付与する。不織布製シートに保持させる抗菌・防臭剤としては、天然産のキチンキトサン、植物抽出物系消臭成分、カプサイシン、ポリフェノール、イオウ、５−クロロ−２−メチル−４−イソチアゾリン−３−オン（以降、化合物Ａ）、グルコン酸銅、酸化チタン、金属銀、備長炭、活性炭、ゼオライト、セラミックなど、各種のものをあげることができるが、なかでもキチンキトサンが抗菌・防臭効力と天然由来であることから好ましい。また、イオウのコロイダル粒子を保持させれば、水虫の原因となる白癬菌やニキビの原因となるアクネ菌に対して抗菌作用を奏しえるし、備長炭入り不織布製シートは、遠赤外線による温熱効果を期待できる。 Furthermore, the sheet | seat of this invention provides an antimicrobial deodorizing effect by hold | maintaining an antimicrobial and deodorizing agent. Antibacterial and deodorant agents to be retained on the non-woven sheet include natural chitin chitosan, plant extract-based deodorant ingredients, capsaicin, polyphenol, sulfur, 5-chloro-2-methyl-4-isothiazolin-3-one , Compound A), copper gluconate, titanium oxide, metallic silver, Bincho charcoal, activated carbon, zeolite, ceramic, etc., but chitin chitosan is naturally derived from antibacterial and deodorizing effects. To preferred. In addition, if the colloidal particles of sulfur are retained, the antibacterial effect can be exerted against ringworm fungus causing acne and acne causing acne. Can be expected.
抗菌・防臭剤を不織布製シートに保持させるにあたっては従来公知の方法を適宜採用できる。例えば、キチンキトサンのような粉末状の抗菌・防臭剤成分を保持させる場合、溶解した繊維素材もしくは不織布素材に、粉末成分をそのまま練り込んだり若しくは溶液として混合してもよいし、あるいは１００〜１０００ミクロンの粉末状抗菌・防臭剤と粉末状のホットメルト系接着剤とを混合し、不織布製シートに散布後、熱処理、熱プレスなどで接着・一体化する方法も例示できる。また、前記混合エマルジョンと混和可能な抗菌・防臭剤であれば、不織布製シートを該混合エマルジョンで浸漬処理する際に同時に行っても構わない。抗菌・防臭剤の不織布製シートへの付着量についても、抗菌・防臭剤の種類や使用用途に応じ、０．００１〜５ｇ／ｍ2、好ましくは０．０１〜０．５ｇ／ｍ2の範囲で任意に決定すればよい。
また、他の活性成分や、安定剤、固着剤、色素、香料等の補助成分を適宜加えてもよく、更に抗菌・防臭剤を保持させる場合に、水、界面活性剤、分散剤等を必要に応じ使用してもよいことはもちろんである。
For holding the antibacterial / deodorant on the nonwoven fabric sheet, a conventionally known method can be appropriately employed. For example, when a powdery antibacterial / deodorant component such as chitin chitosan is retained, the powder component may be kneaded as it is or mixed as a solution into a dissolved fiber material or nonwoven fabric material, or 100 to 1000 An example is a method in which a micron powdered antibacterial / deodorant and a powdered hot melt adhesive are mixed and dispersed on a non-woven fabric sheet and then bonded and integrated by heat treatment, hot pressing, or the like. Moreover, as long as it is an antibacterial and deodorizing agent that is miscible with the mixed emulsion, it may be performed simultaneously when the nonwoven fabric sheet is immersed in the mixed emulsion. For even deposition amount of the nonwoven fabric sheet of antibacterial agents, depending on the antibacterial agent type and intended use, 0.001 to 5 g / m 2, the range preferably from 0.01 to 0.5 g / m 2 It can be arbitrarily determined.
In addition, other active ingredients and auxiliary ingredients such as stabilizers, fixing agents, pigments, fragrances, etc. may be added as appropriate, and water, surfactants, dispersants, etc. are required to retain antibacterial and deodorant agents. Of course, it may be used depending on the case.
本発明は、滑り止め加工として前記不織布製シートの片面の略全面にわたり、アクリル酸エステル共重合樹脂をドット状に塗布したことに特徴を有する。すなわち、不織布製シートに更に樹脂シートを積層するのではなく、アクリル酸エステル共重合樹脂を略全面にわたりドット状に塗布することによって、満足のいく滑り止め効果の達成が可能となったものである。これに対し、特開２０００−１３５１０２号公報に開示された消臭シートでは、消臭剤を介在させる上シート部材の材質と仮固定用の樹脂との組み合わせについて何ら検討されておらず、両部材をシート状にして積層せざるを得ない結果、厚みが増してつま先の窮屈感が免れえず、またべたつきの問題もほとんど解消されなかった。本発明で用いるアクリル酸エステル共重合樹脂は、例えばグラビア印刷工法に準じ、エマルジョン化した
後ローラー等を用いて直径０．１〜５ｍｍ程度のドット状にコートされる。
The present invention is characterized in that an acrylic ester copolymer resin is applied in a dot shape over substantially the entire surface of one side of the nonwoven fabric sheet as a non-slip process. That is, instead of further laminating a resin sheet on a non-woven sheet, a satisfactory anti-slip effect can be achieved by applying an acrylic ester copolymer resin in a dot shape over substantially the entire surface. . On the other hand, in the deodorizing sheet disclosed in Japanese Patent Application Laid-Open No. 2000-135102, the combination of the material of the upper sheet member interposing the deodorant and the resin for temporary fixing has not been studied. As a result, it was inevitable that the toes were cramped and the stickiness of the toes could not be avoided, and the stickiness problem was hardly solved. The acrylic ester copolymer resin used in the present invention is coated into dots having a diameter of about 0.1 to 5 mm using a roller after emulsification, for example, according to a gravure printing method.
本発明の靴のつま先シートは、通常の靴のつま先に相応して半楕円形状のものが使いやすい。また、不織布製シートの通気性をより高めるために、多数の小孔を設けても良い。更に、ドライ感を付与させる目的で不織布製シートの表面に、疎水性の繊維からなる薄いシート状部材を貼付するようにしてもよい。 The shoe toe sheet of the present invention is easy to use in a semi-elliptical shape corresponding to a normal shoe toe. Moreover, in order to improve the air permeability of a nonwoven fabric sheet, you may provide many small holes. Furthermore, you may make it stick the thin sheet-like member which consists of hydrophobic fibers on the surface of a nonwoven fabric sheet in order to provide a dry feeling.
こうして得られた本発明の靴のつま先シートは、パンプスやサンダル、紳士靴等のつま先に挿入すると、すぐれた抗菌・防臭効果を奏することはもちろん、つま先のべたつきを抑え、しかも薄型で窮屈感を与えず、かつ、よれたり、シワになったりせず、極めて実用的である。 The toe sheet of the shoes of the present invention thus obtained, when inserted into the toes of pumps, sandals, men's shoes, etc., not only exhibits excellent antibacterial and deodorizing effects, but also suppresses stickiness of the toes, and is thin and tight It is extremely practical without giving, twisting and wrinkling.
次に、具体的実施例ならびに試験例をあげて本発明を更に詳しく説明するが、本発明はこれらに限定されるものではない。 Next, the present invention will be described in more detail with reference to specific examples and test examples, but the present invention is not limited thereto.
溶解させたレーヨン素材７０部と、パルプならびにキチンキトサンの液状混合物３０部を混合し、目付け８０ｇ／ｍ2、厚み０．５ｍｍで、キチンキトサンを０．２ｇ／ｍ2の割合で保持するレーヨン不織布製シートを調製した。この不織布製シートをアクリル樹脂エマルジョン（ボンコートＡＮ―１８０Ｈ、大日本インキ株式会社製）／酢酸ビニル樹脂エマルジョン（ビニゾール８０２大同化成工業株式会社製）／ノニオン系界面活性剤（マイネックスＳＯ明成化学工業株式会社製）（８：３：０．６）水溶液に浸漬した後、乾燥させ、不織布全体に樹脂加工［プラスチック樹脂固着量：約２ｇ／ｍ2］を施した。更に、不織布製シートの片面に、直径約１ｍｍのドット状のアクリル酸エステル共重合樹脂エマルジョンが１ｃｍ2当り３０個付着するようにコートした。この不織布シートをつま先の形状に裁断し、本発明の実施例とした。
このつま先シートをパンプスの内部に挿入して使用したところ、靴の中でよれたり、シワになったりすることはなく、つま先部分の汗を吸収してべたつきを抑え、しかも薄型で窮屈感がなかった。さらに、抗菌・防臭効果に、従来の消臭シートのように粘着剤を用いていないため、簡単に滑り止めの仮固定をでき、靴の内部を損傷することなく、何度もシートの位置を変更可能であった。更に、キチンキトサンは天然産の抗菌・防臭剤で安全性が高く、安心して使用できた。
A rayon nonwoven fabric in which 70 parts of the dissolved rayon material and 30 parts of a liquid mixture of pulp and chitin chitosan are mixed to hold chitin chitosan at a rate of 0.2 g / m 2 with a basis weight of 80 g / m 2 and a thickness of 0.5 mm. A sheet made was prepared. Acrylic resin emulsion (Boncoat AN-180H, manufactured by Dainippon Ink Co., Ltd.) / Vinyl acetate resin emulsion (Vinisol 802, manufactured by Daido Kasei Kogyo Co., Ltd.) / Nonionic surfactant (Mynex SO Meisei Chemical Co., Ltd.) (Made by company) (8: 3: 0.6) After being immersed in an aqueous solution, it was dried and subjected to resin processing [amount of fixed plastic resin: about 2 g / m 2 ] on the entire nonwoven fabric. Furthermore, it was coated on one side of the non-woven fabric sheet so that 30 dot-like acrylate copolymer resin emulsions having a diameter of about 1 mm were adhered per 1 cm 2 . This nonwoven fabric sheet was cut into the shape of a toe to make an example of the present invention.
When this toe sheet is inserted inside the pump, it does not get drunk or wrinkled in the shoes, absorbs sweat on the toe part, suppresses stickiness, and is thin and not cramped It was. Furthermore, the antibacterial and deodorant effects do not use an adhesive like conventional deodorant sheets, so it is possible to easily fix slips temporarily and position the sheet many times without damaging the inside of the shoe. It was possible to change. Furthermore, chitin chitosan is a natural antibacterial and deodorant that has high safety and can be used with peace of mind.
実施例１に準じて表1に示す種々のつま先シートを調製した。性能評価は下記の観点に基づいて行い、結果を表１に併せて示した。
（１）発汗時のべたつき感の解消：
○；良好、 △；普通、 ×；不良
（２）履き心地（よれ、シワの発生、臭い等）：
○；良好、 △；普通、 ×；不良
（３）滑り止め効果（シートの位置ずれ）：
○；良好、 △；普通、 ×；不良
In accordance with Example 1, various toe sheets shown in Table 1 were prepared. The performance evaluation was performed based on the following viewpoints, and the results are also shown in Table 1.
(1) Eliminating stickiness when sweating:
○: Good, △: Normal, ×: Poor (2) Comfort (skin, wrinkle, odor, etc.):
○: Good, Δ: Normal, ×: Poor (3) Anti-slip effect (sheet misalignment):
○: Good, △: Normal, ×: Poor
試験の結果、不織布製シートに、プラスチック樹脂とノニオン系界面活性剤で浸漬処理を施すとともに抗菌・防臭剤を保持させ、その裏面にアクリル酸エステル共重合物樹脂をドット状にコートしてなる本発明の靴のつま先シートは、３評価項目（発汗時のべたつき感の解消、履き心地、滑り止め効果）のいずれも優れ実用性の高いことが認められた。
これに対し、浸漬処理を施していないシート（比較例１、５）や、施していてもアクリル樹脂のみ使用したもの（比較例２）は、べたつき感の解消や履き心地の点で劣った。また、比較例３のように、抗菌・防臭剤を保持させない場合、臭いやムレが不快で好ましくなかった。更に、滑り止め加工を本発明方式によらず、シート積層（比較例４）や部分スプレー方式（比較例５）により行った場合、滑り止め効果が十分でないか、又は改良の余地があった。
As a result of the test, the non-woven sheet is dipped with a plastic resin and a nonionic surfactant while retaining an antibacterial / deodorant, and the back surface is coated with an acrylic ester copolymer resin in the form of dots. The toe sheet of the shoe of the invention was found to be excellent and practical in all of the three evaluation items (elimination of stickiness during sweating, comfort, and anti-slip effect).
In contrast, sheets that were not subjected to immersion treatment (Comparative Examples 1 and 5) and those that were applied but only used an acrylic resin (Comparative Example 2) were inferior in terms of eliminating stickiness and wearing comfort. Further, as in Comparative Example 3, when the antibacterial / deodorant was not retained, the smell and stuffiness were unpleasant and undesirable. Further, when the anti-slip process is performed by the sheet lamination (Comparative Example 4) or the partial spray method (Comparative Example 5) regardless of the method of the present invention, the anti-slip effect is not sufficient or there is room for improvement.
Claims (2)
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| JP2004179342A JP4646553B2 (en) | 2004-01-23 | 2004-06-17 | Shoe toe sheet |
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| JP2004179342A JP4646553B2 (en) | 2004-01-23 | 2004-06-17 | Shoe toe sheet |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040440A (en) * | 2015-07-14 | 2015-11-11 | 宜兴市华联化工有限公司 | Anti-pilling cotton fabric softener |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101648953B1 (en) * | 2012-11-13 | 2016-08-17 | 주식회사 삼양사 | Nonwovens having slip resistance and method for producing the same |
| CN114501991B (en) * | 2019-10-25 | 2024-04-02 | 花王株式会社 | Deodorant composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05330004A (en) * | 1992-06-04 | 1993-12-14 | Koronbusu:Kk | Dot processed sheet |
| JP2000086411A (en) * | 1998-09-04 | 2000-03-28 | Daiwa Kagaku Kogyo Kk | Antimicrobial fiber |
| JP2001299409A (en) * | 2000-04-18 | 2001-10-30 | Dainippon Printing Co Ltd | Insole of shoe |
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2004
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05330004A (en) * | 1992-06-04 | 1993-12-14 | Koronbusu:Kk | Dot processed sheet |
| JP2000086411A (en) * | 1998-09-04 | 2000-03-28 | Daiwa Kagaku Kogyo Kk | Antimicrobial fiber |
| JP2001299409A (en) * | 2000-04-18 | 2001-10-30 | Dainippon Printing Co Ltd | Insole of shoe |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040440A (en) * | 2015-07-14 | 2015-11-11 | 宜兴市华联化工有限公司 | Anti-pilling cotton fabric softener |
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