JP4642451B2 - Contact resistance measurement method - Google Patents

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JP4642451B2
JP4642451B2 JP2004354880A JP2004354880A JP4642451B2 JP 4642451 B2 JP4642451 B2 JP 4642451B2 JP 2004354880 A JP2004354880 A JP 2004354880A JP 2004354880 A JP2004354880 A JP 2004354880A JP 4642451 B2 JP4642451 B2 JP 4642451B2
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liquid developer
contact resistance
resistance value
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則康 竹内
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Ricoh Co Ltd
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この発明は、潜像担持体の潜像を液体現像剤を用いて現像する現像装置の現像ニップにおける液体現像剤層の接触抵抗値を測定する接触抵抗値測定方法に関する。 This invention relates to contact resistance measuring method for measuring the contact resistance of the liquid developer layer a latent image of the latent image bearing member at the developing nip of a developing device performing development using a liquid developer.

特許文献1、特許文献2及び特許文献3には、感光体表面を帯電手段で均一に帯電してから書込手段により画像データに従って感光体表面を露光して静電潜像を形成し、高粘度、高濃度の液体現像剤を用いた現像装置により静電潜像を現像して可視化する画像形成装置が提案されている。   In Patent Document 1, Patent Document 2 and Patent Document 3, an electrostatic latent image is formed by uniformly charging the surface of a photoconductor with a charging unit and then exposing the surface of the photoconductor with a writing unit according to image data. There has been proposed an image forming apparatus that develops and visualizes an electrostatic latent image by a developing device using a liquid developer having a high viscosity and a high concentration.

特許文献1、特許文献2及び特許文献3のような画像形成装置が備える高粘度、高濃度の液体現像剤を用いた現像装置では、例えば、ジメチルポリシロキサンオイル等の絶縁性液体からなる現像液溶媒中に顕像化粒子であるトナーを高濃度に分散し50〜10000mPa・sの高粘度の液体現像剤を用いられる。貯蔵タンクに貯蔵した液体現像剤は、現像ローラや現像ベルトに均一な厚さで塗布されて液体現像剤薄層を形成し、現像ローラや現像ベルトに塗布された液体現像剤薄層が感光体に近接して現像領域を通るとき、液体現像剤の薄層のトナーにより感光体の静電潜像を現像してトナー像を形成する。現像領域を通過した現像ローラや現像ベルトに残留している液体現像剤は、掻き取りブレードで除去されて貯蔵タンクに回収される。   In a developing device using a high-viscosity, high-concentration liquid developer provided in image forming apparatuses such as Patent Document 1, Patent Document 2, and Patent Document 3, for example, a developer made of an insulating liquid such as dimethylpolysiloxane oil A high-viscosity liquid developer having a viscosity of 50 to 10,000 mPa · s obtained by dispersing toner in a high concentration in a solvent. The liquid developer stored in the storage tank is applied to the developing roller and the developing belt with a uniform thickness to form a liquid developer thin layer, and the liquid developer thin layer applied to the developing roller and the developing belt is the photoreceptor. When the toner passes through the development region in the vicinity of the toner, the electrostatic latent image on the photosensitive member is developed with a thin toner layer of a liquid developer to form a toner image. The liquid developer remaining on the developing roller and the developing belt that has passed through the developing region is removed by a scraping blade and collected in a storage tank.

液体現像剤は、絶縁性液体であるキャリア液中に樹脂及び顔料からなる固形分を分散して形成される。現像時には帯電したトナーが絶縁性液体中を静電気の力によって移動して静電潜像を現像する。トナーの移動距離が短いほど現像効率が向上する。トナーの移動距離を短くするためには、現像ローラ等の現像剤担持体上に液体現像剤のミクロン単位の薄層を形成し、薄層化された液体現像剤を感光体に接触させて現像することが望ましく、特に50〜10000mPa・sの高粘度の液体現像剤を用いる場合により顕著である。   The liquid developer is formed by dispersing a solid content of a resin and a pigment in a carrier liquid that is an insulating liquid. At the time of development, the charged toner moves in the insulating liquid by electrostatic force to develop the electrostatic latent image. The development efficiency improves as the moving distance of the toner is shorter. In order to shorten the moving distance of the toner, a thin layer of a micron unit of liquid developer is formed on a developer carrier such as a developing roller, and the thinned liquid developer is brought into contact with the photosensitive member for development. It is desirable to use a liquid developer having a high viscosity of 50 to 10,000 mPa · s.

液体現像剤の薄層により現像を行う場合、薄層の厚さにより濃度が決定されるため、薄層を均一に形成することが重要な課題となる。   When developing with a thin layer of a liquid developer, the density is determined by the thickness of the thin layer, so that it is important to form the thin layer uniformly.

特許文献4には、表面に彫刻溝を形成した塗布ローラにドクタブレードを接触させることにより液体現像剤の量を計量し、現像ローラに形成する液体現像剤の薄層を均一にする画像形成装置が提案されている。特許文献5や特許文献6には、塗布ローラと現像ローラの間に中間ローラを入れることにより、仕様が厳しく選択の幅が狭く高耐久の部品を作ることが困難な現像ローラの寿命を向上させるとともに、中間ローラと塗布ローラのニップ間を通過した液体現像剤を現像ローラに塗布することにより、塗布ローラへのドクタブレードの当接をなくして異物の目詰まりによるすじの発生を防止できる現像装置が提案されている。   Patent Document 4 discloses an image forming apparatus that measures the amount of liquid developer by bringing a doctor blade into contact with a coating roller having engraved grooves formed on the surface thereof, and makes a thin layer of the liquid developer formed on the developing roller uniform. Has been proposed. In Patent Document 5 and Patent Document 6, by inserting an intermediate roller between the application roller and the developing roller, the life of the developing roller whose specifications are strict and the selection range is narrow and it is difficult to make a highly durable part is improved. In addition, by applying to the developing roller the liquid developer that has passed between the nip between the intermediate roller and the coating roller, the developing device can eliminate streaks due to clogging of foreign matter by eliminating contact of the doctor blade to the coating roller. Has been proposed.

特許文献7には、現像ローラの体積抵抗率を0〜107Ω・cmの範囲にして、現像時の電界強度の不安定に起因した現像後の可視像における濃度ムラの発生を防止する現像装置が提案されている。 In Patent Document 7, the volume resistivity of the developing roller is set in a range of 0 to 10 7 Ω · cm to prevent density unevenness in a visible image after development due to instability of electric field strength during development. Development devices have been proposed.

特開平7−152254号公報JP 7-152254 A 特開平7−209922号公報Japanese Patent Laid-Open No. 7-209922 特開平7−219355号公報JP 7-219355 A 特開平11−265122号公報Japanese Patent Laid-Open No. 11-265122 特開2002−287513号公報JP 2002-287513 A 特開2003−156938号公報JP 2003-156938 A 特開2001−194912号公報JP 2001-194912 A

現像ニップのトナーの移動に有効に作用する現像電界は、現像ローラ表面と感光体表面との間に形成される電界である。現像ローラ表面と感光体表面との間に形成される電界強度は、印加電圧が同じであっても、現像ローラの導電層の厚さや、現像される液体現像剤層の抵抗に依存して変化する。さらに、抵抗値は経時、環境などにより変化し、初期状態やある条件下では十分であっても、状況に応じて変動する恐れがある。実質的な現像電界の強度はローラの厚さや液体現像剤層の抵抗値によって変化し、現像ローラの体積抵抗率を規定するのみでは、安定して十分な電界強度を得られない。   The developing electric field that effectively acts on the movement of the toner in the developing nip is an electric field formed between the developing roller surface and the photoreceptor surface. The strength of the electric field formed between the surface of the developing roller and the surface of the photoconductor varies depending on the thickness of the conductive layer of the developing roller and the resistance of the liquid developer layer to be developed even when the applied voltage is the same. To do. Furthermore, the resistance value varies with time and the environment, and may vary depending on the situation even if the initial state or a certain condition is sufficient. The substantial strength of the developing electric field varies depending on the thickness of the roller and the resistance value of the liquid developer layer, and a sufficient electric field strength cannot be obtained stably only by defining the volume resistivity of the developing roller.

本発明は、現像装置の現像ニップにおける液体現像剤層の接触抵抗値を測定する接触抵抗値測定方法を提供することを目的とする。 The present invention aims at providing a contact resistance measuring method for measuring the contact resistance of the liquid developer layer in the developing nip of the current image device.

この発明の接触抵抗値測定方法は、表面に潜像を担持する潜像担持体に、液体現像剤を担持する現像剤担持体を対向させ、潜像担持体の表面及び現像剤担持体の表面を移動させながら、現像剤担持体と潜像担持体との間に電圧を印加し、現像剤担持体と潜像担持体との間に形成された液体現像剤層に現像電界を印加して潜像を現像する現像装置において、液体現像剤層の接触抵抗値を測定する接触抵抗値測定方法であって、潜像担持体を帯電させずに全面露光し、全面露光された潜像担持体と現像剤担持体との間に流れる電流を計測し、現像剤担持体と潜像担持体との間に印加された電圧を、計測された電流で除して求めた抵抗値に、現像ニップのニップ幅と全長とをかけて現像剤担持体と液体現像剤層とを含む領域の接触抵抗値を求め、現像剤担持体と液体現像剤層とを含む領域の接触抵抗値から、現像剤担持体の接触抵抗値を引いて現像ニップにおける液体現像剤層の接触抵抗値を求める。   The contact resistance value measuring method of the present invention is such that a developer carrier carrying a liquid developer is opposed to a latent image carrier carrying a latent image on the surface, and the surface of the latent image carrier and the surface of the developer carrier While applying a voltage, a voltage is applied between the developer carrier and the latent image carrier, and a developing electric field is applied to the liquid developer layer formed between the developer carrier and the latent image carrier. A contact resistance value measuring method for measuring a contact resistance value of a liquid developer layer in a developing device for developing a latent image, wherein the latent image carrier is exposed on the whole surface without being charged, and the latent image carrier is exposed on the whole surface. The current flowing between the developer carrier and the developer carrier is measured, and the voltage applied between the developer carrier and the latent image carrier is divided by the measured current to obtain the resistance value obtained by dividing The contact resistance value of the area including the developer carrier and the liquid developer layer is obtained by multiplying the nip width and the total length of the Contact resistance of a region including a carrying member and the liquid developer layer, obtaining the contact resistance of the liquid developer layer in the developing nip by subtracting the contact resistance value of the developer carrying member.

の発明の接触抵抗測定方法によれば、潜像担持体は帯電されずに全面露光されていることにより、測定した電流値から帯電の影響によるものを差し引く煩雑さをなくして接触抵抗値を簡便に測定できる。 According to the contact resistance measuring method of this invention, by a latent image bearing member is entirely exposed without being charged, the contact resistance value by eliminating the complexity of the measured current value subtracting the impact of charging It can be measured easily.

第1の実施形態の画像形成装置1は、図1の構成図に示すように、感光体10の周りに順に、帯電器11と露光装置12と現像装置13と感光体スイープ装置14と中間転写体15と除電ランプ16と感光体クリーニング装置17とを配置され、中間転写体15の周りに、二次転写ローラ18と中間転写体クリーニング装置19とを配置され、さらに、給紙部20と定着装置21と排紙部22とを備える。なお、画像形成装置1は、以下に説明する電子写真複写機に限らず、印刷装置、複写装置、FAX、複合機等の各種の画像形成装置であってもよい。また、反転現像を用いるものにも限られない。   As shown in the configuration diagram of FIG. 1, the image forming apparatus 1 according to the first embodiment sequentially includes a charger 11, an exposure device 12, a developing device 13, a photoconductor sweep device 14, and an intermediate transfer around the photoconductor 10. The body 15, the charge-removing lamp 16, and the photoconductor cleaning device 17 are disposed. The secondary transfer roller 18 and the intermediate transfer body cleaning device 19 are disposed around the intermediate transfer body 15. A device 21 and a paper discharge unit 22 are provided. The image forming apparatus 1 is not limited to the electrophotographic copying machine described below, but may be various image forming apparatuses such as a printing apparatus, a copying apparatus, a FAX, and a multifunction machine. Moreover, it is not restricted to what uses reversal development.

感光体10は、表面をa-SiやOPC等により形成され、モータ等の駆動手段により複写時に一定速度で矢印方向に回転駆動され、反転現像により画像を形成する潜像担持体として機能する。感光体10は、表面をアモルファスシリコンで形成したものであることが望ましく、表面をアモルファスシリコンで形成した感光体10は、有機感光体(OPC)に比較して電気特性が安定しているので繰り返し使用しても帯電特性が変化せず、安定した現像電界を形成できる。帯電器11は、ローラやチャージャ等により感光体10の表面を暗中で一様に帯電する。露光装置12は、LEDやレーザー走査光学系等により、帯電した感光体10に原稿光像を照射結像して静電潜像を形成する。   The surface of the photoconductor 10 is formed of a-Si, OPC, or the like, and is driven to rotate in the direction of the arrow at a constant speed during copying by a driving unit such as a motor, and functions as a latent image carrier that forms an image by reversal development. The photoreceptor 10 is desirably formed of amorphous silicon on the surface, and the photoreceptor 10 formed of amorphous silicon on the surface is more stable than the organic photoreceptor (OPC) because it has stable electrical characteristics. Even if it is used, the charging characteristics do not change, and a stable developing electric field can be formed. The charger 11 uniformly charges the surface of the photoreceptor 10 in the dark with a roller, a charger, or the like. The exposure device 12 forms an electrostatic latent image by irradiating an original light image onto the charged photoreceptor 10 with an LED, a laser scanning optical system, or the like.

現像装置13は、収容タンク30と攪拌スクリュ31と塗布装置32と現像ローラ33とを有し、現像ローラ33と感光体10との対向部分に液体現像剤を供給して、現像ローラ33を通過する静電潜像からトナー像を現像する。   The developing device 13 includes a storage tank 30, a stirring screw 31, a coating device 32, and a developing roller 33. The developing device 13 supplies liquid developer to a portion where the developing roller 33 and the photoconductor 10 face each other, and passes through the developing roller 33. The toner image is developed from the electrostatic latent image.

収容タンク30は、液体現像剤を収容している。液体現像剤には、例えば、着色剤と樹脂とで構成される結着剤を主成分とし電荷制御剤を添加したトナーを、高絶縁性かつ低誘電率の溶媒を主成分とするキャリア液体中に分散したものを用い、従来のようなIsopar(商標)をキャリアとした1cSt程度の低粘性で、1%程度の低濃度の液体現像剤ではなく、粘度が50〜10000mPa・S、濃度が5%〜40%程度の高粘性高濃度の液体現像剤を使用することが好ましく、揮発性または不揮発性のものを目的に合わせて選択し、トナーの粒径としてサブミクロンから6μm程度までのものを目的に合わせて選択する。キャリア液は、シリコーンオイル、ノルマルパラフィン、IsoparM(商標)、植物油、鉱物油等の絶縁性が高いものを使用する。攪拌スクリュ31は、収容タンク30に収容された液体現像剤を攪拌している。   The storage tank 30 stores a liquid developer. Liquid developers include, for example, a toner composed mainly of a binder composed of a colorant and a resin, and a charge control agent added in a carrier liquid mainly composed of a solvent having a high insulating property and a low dielectric constant. It is not a liquid developer with a low viscosity of about 1 cSt and a low concentration of about 1% using Isopar (trademark) as a carrier, but a viscosity of 50 to 10,000 mPa · S and a concentration of 5 It is preferable to use a high-viscosity and high-concentration liquid developer of about 40% to 40%. A volatile or non-volatile liquid developer is selected according to the purpose, and the toner particle size is from submicron to about 6 μm. Select according to your purpose. As the carrier liquid, a highly insulating material such as silicone oil, normal paraffin, IsoparM (trademark), vegetable oil, mineral oil or the like is used. The stirring screw 31 is stirring the liquid developer stored in the storage tank 30.

塗布装置32は、塗布ローラ34と中間ローラ35とクリーニング部材36とをもつ。塗布ローラ34は、収容タンク30に収容された液体現像剤を回転しながら汲み上げて中間ローラ35に塗布する。塗布ローラ34は、図2(a)の正面図に示すように、表面に均一なパターンの彫刻溝をもつアニロクスローラで構成されることが望ましく、彫刻溝のパターンには、例えば図2(b)に示すような斜線型、図2(c)に示すような亀甲型、図2(d)に示すような格子型等を適宜用いるとよい。塗布ローラ34の表面についた液体現像剤の余剰分をドクタブレードやドクタローラによってかきおとす等することにより、彫刻溝によって液体現像剤を正確に計量して中間ローラ35に転写することで液体現像剤の均一な薄層を形成できる。   The coating device 32 includes a coating roller 34, an intermediate roller 35, and a cleaning member 36. The application roller 34 draws up and applies the liquid developer stored in the storage tank 30 to the intermediate roller 35 while rotating. As shown in the front view of FIG. 2A, the application roller 34 is preferably composed of an anilox roller having a uniform pattern of engraving grooves on the surface. An oblique line type as shown in b), a turtle shell type as shown in FIG. 2C, a lattice type as shown in FIG. The excess liquid developer on the surface of the coating roller 34 is scraped off by a doctor blade or a doctor roller, and the liquid developer is accurately measured by the engraving groove and transferred to the intermediate roller 35 to transfer the liquid developer. A uniform thin layer can be formed.

中間ローラ35は、塗布ローラ34とのニップ部において、塗布ローラ34の彫刻溝の容積に応じて計量された液体現像剤を乗せ、現像ローラ33に対して表面の移動方向を逆にしたリバース方向に、現像ローラ33の周速以上の周速で回転させ、塗布ローラ34から液体現像剤を転写される際に中間ローラ35に残った彫刻溝のパターンの目を均して現像ローラ33の表面に均一な薄層を形成する。中間ローラ35を設けることにより、塗布ローラ34を直接現像ローラ33に接触させて塗布する場合に比較して、現像ローラ33の表面に機械的な負荷が加えられて現像34ローラの寿命を短くすることを防止できる。   The intermediate roller 35 carries a liquid developer measured according to the volume of the engraving groove of the application roller 34 at the nip portion with the application roller 34, and the reverse direction in which the moving direction of the surface is reversed with respect to the development roller 33. The surface of the developing roller 33 is rotated at a peripheral speed equal to or higher than the peripheral speed of the developing roller 33, and the pattern of the engraving groove remaining on the intermediate roller 35 when the liquid developer is transferred from the coating roller 34 is leveled. To form a uniform thin layer. By providing the intermediate roller 35, a mechanical load is applied to the surface of the developing roller 33 and the life of the developing roller 34 is shortened as compared with the case where the coating roller 34 is directly brought into contact with the developing roller 33 for coating. Can be prevented.

クリーニング部材36は、金属ブレードやゴムブレード等により形成されたブレードやローラ等で構成されて、中間ローラ35に接触し、現像ローラ33との接触部分を通過して塗布ローラ34に再び接触するまでに中間ローラ35の表面に付着した液体現像剤を取り除く。   The cleaning member 36 is composed of a blade, a roller, or the like formed by a metal blade, a rubber blade, or the like, and comes into contact with the intermediate roller 35, passes through a contact portion with the developing roller 33, and again comes into contact with the application roller 34. The liquid developer adhering to the surface of the intermediate roller 35 is removed.

現像ローラ33に塗布された液体現像剤の厚さが、現像ローラ33の表面の1cm2当たりに担持されるトナー中の顔料含有分が3μgより小さくなる厚さでは、感光体10に形成された静電潜像の画像部に十分な量の顔料が移動できないため、画像部の画像濃度が薄くなる。一方、現像ローラ33に塗布された液体現像剤の厚さが、現像ローラ33の表面の1cm2当たりに担持されるトナー中の顔料含有分が60μgより大きくなるような厚さでは、現像後の感光体10の地肌部に余剰トナーが多く残留するため、感光体スイープ装置14による余剰トナーの除去が不完全になる。現像ローラ33の表面の1cm2当たりに担持されるトナー中の顔料含有分を3μg以上、60μg以下となるように、現像ローラ33の液体現像剤の薄膜を3〜12μmの厚さにすることが望ましい。 When the thickness of the liquid developer applied to the developing roller 33 is such that the pigment content in the toner carried per 1 cm 2 of the surface of the developing roller 33 is less than 3 μg, the liquid developer is formed on the photoreceptor 10. Since a sufficient amount of pigment cannot move to the image portion of the electrostatic latent image, the image density of the image portion is reduced. On the other hand, when the thickness of the liquid developer applied to the developing roller 33 is such that the pigment content in the toner carried per 1 cm 2 of the surface of the developing roller 33 is greater than 60 μg, Since a lot of excess toner remains on the background portion of the photoconductor 10, the removal of the excess toner by the photoconductor sweep device 14 becomes incomplete. The thin film of the liquid developer on the developing roller 33 may be 3 to 12 μm thick so that the pigment content in the toner carried per 1 cm 2 of the surface of the developing roller 33 is 3 μg or more and 60 μg or less. desirable.

塗布装置32を設けることにより、現像ローラ33の表面に液体現像剤の薄膜を均一に塗布して、現像ニップにおける液体現像剤層の厚さを均一にすることができ、トナー像の濃度変動を防止するとともに、液体現像剤層の接触抵抗値を安定させて現像ニップにおける電界強度の変動を防止することができる。   By providing the coating device 32, the liquid developer thin film can be uniformly applied to the surface of the developing roller 33, and the thickness of the liquid developer layer in the developing nip can be made uniform. In addition, the contact resistance value of the liquid developer layer can be stabilized and fluctuations in the electric field strength at the development nip can be prevented.

現像ローラ33は、芯金37と弾性体層38とを有する。弾性体層38は、芯金37の周囲の外周面にウレタンゴム等の導電性をもつ弾性体で形成されており、感光体10に適当な圧力で当接されて弾性変形することにより、感光体10との間に現像ニップを形成している。現像ローラ33と感光体10との間には現像バイアスが印加されている。中間ローラ35により現像ローラ33の表面に形成された液体現像剤の薄層は、現像ニップを通過して感光体10の静電潜像からトナー像を現像する。   The developing roller 33 has a cored bar 37 and an elastic body layer 38. The elastic body layer 38 is formed of an elastic body having conductivity such as urethane rubber on the outer peripheral surface around the core metal 37, and is elastically deformed by being brought into contact with the photoconductor 10 with an appropriate pressure. A developing nip is formed with the body 10. A developing bias is applied between the developing roller 33 and the photoreceptor 10. The thin layer of liquid developer formed on the surface of the developing roller 33 by the intermediate roller 35 passes through the developing nip and develops the toner image from the electrostatic latent image on the photoreceptor 10.

弾性体層38の表面硬度は、感光体10との間で効率的に現像ニップを形成できるようにJIS-A硬度で50度以下であることが望ましい。弾性体層38の材質は、導電性を有し、かつ、キャリア液を含む液体現像剤で膨潤及び溶解しない材質であれば、ウレタンゴムに限られない。ゴム部材の弾性体層38に導電性を付与する手段には、カーボンを添加させる電子導電タイプと、イオン導電タイプとがある。図3のイオン導電タイプの弾性体層38についての環境変動と電気抵抗との関係図に示すように、環境変動により抵抗値が大きく変動するイオン導電タイプの弾性体層38よりも、環境変動により現像電界の強度が影響を受けにくいカーボンを添加した電子導電タイプの弾性体層38を用いることが好ましい。   The surface hardness of the elastic layer 38 is desirably 50 degrees or less in terms of JIS-A hardness so that a developing nip can be efficiently formed with the photoreceptor 10. The material of the elastic layer 38 is not limited to urethane rubber as long as it is conductive and does not swell and dissolve with a liquid developer containing a carrier liquid. Means for imparting conductivity to the elastic layer 38 of the rubber member include an electronic conductivity type in which carbon is added and an ion conductivity type. As shown in the relationship diagram between the environmental variation and the electrical resistance of the ion conductive type elastic body layer 38 in FIG. 3, the resistance value is larger than that of the ion conductive type elastic body layer 38 whose resistance value largely varies due to the environmental variation. It is preferable to use an electron conductive type elastic body layer 38 to which carbon is added which is not easily affected by the strength of the developing electric field.

現像ニップを形成することにより、現像領域の現像電界によって液体現像剤のトナーが感光体10に移動して付着するために必要とされる一定の現像時間を確保できる。現像ニップにおける表面移動方向の幅であるニップ幅は、現像ローラ33と感光体10との当接する圧力を調整し、現像ローラ33の線速と現像時定数との積以上に設定する。現像時定数とは、現像量が飽和するまでに要する時間であり、必要最小ニップ幅をプロセス速度で除したものであり、例えば、必要最小ニップ幅5mm、プロセス速度500mm/秒の場合における現像時定数は10m秒となる。   By forming the developing nip, it is possible to secure a certain developing time required for the liquid developer toner to move and adhere to the photoconductor 10 by the developing electric field in the developing region. The nip width, which is the width of the developing nip in the direction of surface movement, is set to be equal to or greater than the product of the linear velocity of the developing roller 33 and the development time constant by adjusting the pressure at which the developing roller 33 and the photoreceptor 10 abut. The development time constant is the time required for the development amount to saturate, and is the minimum required nip width divided by the process speed. For example, during development when the required minimum nip width is 5 mm and the process speed is 500 mm / sec. The constant is 10 milliseconds.

ここで、弾性体層38の接触抵抗値(Ω・cm2)は、現像ニップにおける液体現像剤層の接触抵抗値を超えない。接触抵抗値は、感光体10と現像ローラ33との間の印加電圧及び電流値と、現像ニップにおける全長及びニップ幅とを用い、式(1)に基づいて得られる。接触抵抗値を弾性体層38の厚さで除すると、材料の物性値を示す体積抵抗率を得る。ここでは、厚さ方向の情報を含まない体積抵抗率を用いず、厚さ方向の情報を含む接触抵抗値を用いて弾性体層38と液体現像剤との抵抗を比較する。弾性体層38の接触抵抗値は、現像ローラ33の弾性体層38の厚さ及び材料の体積抵抗値を調整することにより設定できる。 Here, the contact resistance value (Ω · cm 2 ) of the elastic layer 38 does not exceed the contact resistance value of the liquid developer layer in the development nip. The contact resistance value is obtained based on the formula (1) using the applied voltage and current value between the photoconductor 10 and the developing roller 33 and the total length and nip width in the developing nip. When the contact resistance value is divided by the thickness of the elastic layer 38, a volume resistivity indicating the physical property value of the material is obtained. Here, the resistance between the elastic layer 38 and the liquid developer is compared using the contact resistance value including the information in the thickness direction without using the volume resistivity that does not include the information in the thickness direction. The contact resistance value of the elastic layer 38 can be set by adjusting the thickness of the elastic layer 38 of the developing roller 33 and the volume resistance value of the material.

接触抵抗値=(印加電圧/電流値)×全長×ニップ幅 … (1)   Contact resistance value = (applied voltage / current value) x total length x nip width (1)

弾性体層38の接触抵抗値の測定方法を説明する。図4に示すように黒べた画像を形成した感光体10に、現像ローラ33を現像時と同様に加圧しながら接触させた状態で、感光体10に対する正の電位を現像ローラ33の芯金37に与え、現像ニップを流れる電流を測定し、印加電圧と測定された電流値とを式(1)に代入して弾性体層38の接触抵抗値が得られる。現像ローラ33に与えられる感光体10に対する正の電位は、現像時における現像バイアスと同じである。   A method for measuring the contact resistance value of the elastic layer 38 will be described. As shown in FIG. 4, a positive potential with respect to the photosensitive member 10 is applied to the core 10 of the developing roller 33 in a state where the developing roller 33 is brought into contact with the photosensitive member 10 on which a solid image is formed in the same manner as during development. Then, the current flowing through the developing nip is measured, and the contact resistance value of the elastic layer 38 is obtained by substituting the applied voltage and the measured current value into the equation (1). The positive potential with respect to the photoreceptor 10 applied to the developing roller 33 is the same as the developing bias at the time of development.

次に、現像ニップにおける液体現像剤層の接触抵抗値の測定方法を説明する。液体現像剤の薄膜を形成した現像ローラ33を、現像時と同様に加圧しながら感光体10に接触させた状態で、感光体10に対する正の電位を現像ローラ33の芯金37に与え、現像ニップを流れる電流を測定し、印加電圧と測定された電流値とを式(1)に代入し、現像ニップにおける弾性体層38と液体現像剤層とを含む領域の接触抵抗値が得られる、得られた接触抵抗値から弾性体層38の接触抵抗値を引いて現像ニップにおける液体現像剤層の接触抵抗値を得る。   Next, a method for measuring the contact resistance value of the liquid developer layer at the development nip will be described. In a state where the developing roller 33 in which a thin film of liquid developer is formed is in contact with the photoconductor 10 while being pressed in the same manner as during development, a positive potential with respect to the photoconductor 10 is applied to the cored bar 37 of the developing roller 33 to develop. The current flowing through the nip is measured, and the applied voltage and the measured current value are substituted into Equation (1) to obtain the contact resistance value of the region including the elastic layer 38 and the liquid developer layer in the development nip. The contact resistance value of the liquid developer layer in the development nip is obtained by subtracting the contact resistance value of the elastic layer 38 from the obtained contact resistance value.

弾性体層38の接触抵抗比によって電圧比がどのように変化するかを図5に示す。接触抵抗比は、現像ニップにおける液体現像剤層の接触抵抗値に対する弾性体層38の接触抵抗値の比を示す。電圧比は、印加電圧に対する現像ニップにおける液体現像剤層に作用する電圧の比を示す。   FIG. 5 shows how the voltage ratio changes depending on the contact resistance ratio of the elastic layer 38. The contact resistance ratio indicates the ratio of the contact resistance value of the elastic layer 38 to the contact resistance value of the liquid developer layer in the development nip. The voltage ratio indicates the ratio of the voltage acting on the liquid developer layer in the development nip to the applied voltage.

弾性体層38の接触抵抗値を現像ニップにおける液体現像剤層の接触抵抗値より小さくして接触抵抗比を小さくすることにより、弾性体層38における電圧降下を小さくでき、液体現像剤層に作用する現像電界の強度不足による濃度ムラを防止できる。一方、弾性体層38の接触抵抗値を現像ニップにおける液体現像剤層の接触抵抗値より大きくして接触抵抗比を大きくすることにより、弾性体層38における電圧降下が大きくなり、現像ニップに発生する現像電界の強度が不十分となる。弾性体層38における電圧降下が電圧比にほとんど影響を与えないようにするためには、接触抵抗比を1/100以下にすることが望ましい。弾性体層38の接触抵抗値を現像ニップにおける液体現像剤層の接触抵抗値より小さくして接触抵抗比を小さくすることにより、現像ニップに必要な現像電界を発生させるために高電圧を印加する必要がなくなり、電源への負担を軽くすることができる。   By making the contact resistance value of the elastic body layer 38 smaller than the contact resistance value of the liquid developer layer in the developing nip and reducing the contact resistance ratio, the voltage drop in the elastic body layer 38 can be reduced, acting on the liquid developer layer. Density unevenness due to insufficient strength of the developing electric field can be prevented. On the other hand, when the contact resistance value of the elastic body layer 38 is made larger than the contact resistance value of the liquid developer layer in the development nip to increase the contact resistance ratio, the voltage drop in the elastic body layer 38 is increased and is generated in the development nip. The strength of the developing electric field is insufficient. In order to prevent the voltage drop in the elastic layer 38 from affecting the voltage ratio, it is desirable that the contact resistance ratio is 1/100 or less. By making the contact resistance value of the elastic layer 38 smaller than the contact resistance value of the liquid developer layer in the development nip and reducing the contact resistance ratio, a high voltage is applied to generate a development electric field necessary for the development nip. This eliminates the need to reduce the burden on the power supply.

弾性体層38の接触抵抗値は、小さいほど好ましいが、電源を定電圧制御する場合には、液体現像剤切れ等の不測の事態において現像ローラ33が感光体10に接触してダメージを与えないレベルにすることが望ましい。なお、電源は、画像面積により電流値が変化して現像電界の強度が変化することを防止する制御方式、例えば、画像面積に応じて流れる電流値を制御するような制御方式をとれば定電流制御されるものであってもよい。   The contact resistance value of the elastic layer 38 is preferably as small as possible. However, when the power source is controlled at a constant voltage, the developing roller 33 does not contact the photoreceptor 10 and cause damage in an unexpected situation such as running out of liquid developer. It is desirable to make it a level. Note that the power source has a constant current if a control method that prevents the intensity of the developing electric field from changing due to a change in the current value depending on the image area, for example, a control method that controls the current value that flows according to the image area. It may be controlled.

画像形成装置1に現像装置13を搭載した状態で、弾性体層38の接触抵抗値と、現像ニップにおける液体現像剤層の接触抵抗値とを測定することにより、実際の作像時における接触状態や液体現像剤の塗布量を厳密に再現し、実施の作像時と測定時との誤差を少なくできる。なお、実際の作像時のように感光体10を帯電、露光及び現像して測定すると、測定した電流値から帯電の影響によるものを差し引く煩雑さがあるため、帯電させずに現像して電流値を測定してもよく、帯電させずに現像することにより接触抵抗値を簡便に評価できる。   With the developing device 13 mounted on the image forming apparatus 1, the contact resistance value of the elastic layer 38 and the contact resistance value of the liquid developer layer in the development nip are measured to thereby determine the contact state during actual image formation. In addition, the application amount of the liquid developer can be accurately reproduced, and errors between the actual image formation and the measurement can be reduced. Note that when the photoconductor 10 is measured by charging, exposing and developing as in actual image formation, there is the complexity of subtracting the effect of charging from the measured current value. The value may be measured, and the contact resistance value can be easily evaluated by developing without charging.

測定された現像ニップにおける液体現像剤層の接触抵抗値が107Ω・cm2である場合、測定された弾性体層38の接触抵抗値が107Ω・cm2である現像ローラAを使用して現像すると、現像特性が悪く、画像濃度が低く、画像ムラが発生した。測定された弾性体層38の接触抵抗値が106Ω・cm2である現像ローラBを使用して現像すると、やや現像電界強度不足による画像ムラが発生した。測定された弾性体層38の接触抵抗値が105Ω・cm2の現像ローラCを使用して現像すると、画像ムラの発生していない良好な画像を形成できた。 If the contact resistance of the liquid developer layer on the measured development nip is 10 7 Ω · cm 2, using a developing roller A contact resistance value of the measured elastic layer 38 is 10 7 Ω · cm 2 When developed, the development characteristics were poor, the image density was low, and image unevenness occurred. When development was performed using the developing roller B having a measured contact resistance value of the elastic layer 38 of 10 6 Ω · cm 2 , image unevenness due to slightly insufficient development electric field strength occurred. When development was performed using the developing roller C having a measured contact resistance value of the elastic layer 38 of 10 5 Ω · cm 2, a good image with no image unevenness could be formed.

なお、現像ニップのギャップや圧力を管理することにより、現像ニップにおける液体現像剤層の厚さを管理して液体現像剤層の接触抵抗値を一定にしたり、現像ニップに過剰な圧力をかけて現像ローラ33に形成した液体現像剤層が現像ニップを通過できなくなることを防止するため、設定した圧力値の上限を超えないように制御することが好ましい。   By managing the gap and pressure of the development nip, the thickness of the liquid developer layer in the development nip is controlled to make the contact resistance value of the liquid developer layer constant, or excessive pressure is applied to the development nip. In order to prevent the liquid developer layer formed on the developing roller 33 from passing through the developing nip, it is preferable to control so as not to exceed the upper limit of the set pressure value.

なお、現像装置13の現像剤担持体は、ローラ形態の現像ローラ33に限られず、ベルト形態の現像ベルト等の他の形態をもつものであってもよい。現像剤担持体が現像ベルトである場合、現像ベルトの表面抵抗(Ω/cm2)に、ベルト幅と、ベルトへ電圧を印加する電極ローラから現像部までの距離とをかけて得られる抵抗値が、液体現像剤層の接触部の抵抗値よりも低くなるように現像ベルトの材料の導電性を決める。ベルト形態の場合、ローラ形態のようにニップ幅をかけることに意味がないため、直接抵抗値で比較して材料の導電性を規定する。ローラ形態の場合やベルト形態の場合のいずれにおいても、現像する液体現像剤層に作用する現像電界が十分な強度であるように液体現像剤層の抵抗に対して、現像剤担持体に抵抗を規定する点で同じである。 The developer carrier of the developing device 13 is not limited to the roller-type developing roller 33, and may have other forms such as a belt-type developing belt. When the developer carrier is a developing belt, the resistance value obtained by multiplying the surface resistance (Ω / cm 2 ) of the developing belt by the belt width and the distance from the electrode roller that applies a voltage to the belt to the developing portion However, the conductivity of the material of the developing belt is determined so as to be lower than the resistance value of the contact portion of the liquid developer layer. In the case of the belt form, there is no point in applying the nip width as in the case of the roller form, so the conductivity of the material is defined by a direct resistance value comparison. In either the roller form or the belt form, the developer carrier is resisted against the resistance of the liquid developer layer so that the developing electric field acting on the liquid developer layer to be developed is sufficiently strong. It is the same in terms of defining.

感光体スイープ装置14は、スイープローラ40とクリーニング部材41とを有するスイープローラ40は、現像ローラ33と同様に、外周面に導電性を有する弾性体層を有し、現像ローラ33よりも感光体10の回転方向下流側で、現像されたトナー層を挟んで感光体10を押圧するように設置され、表面を感光体10の表面とほぼ等速で移動させる。スイープローラ40を感光体に適当な圧力で当接させると、スイープローラ40の弾性体の層が弾性変形し、除去ニップが形成される。当接圧力を調整することによりニップ部における表面移動方向の幅であるニップ幅を調整できる。ニップ幅は、現像ローラ33と同様に、スイープローラ40の線速と現像時定数との積以上に設定する。   In the photoconductor sweep device 14, the sweep roller 40 having the sweep roller 40 and the cleaning member 41 has an elastic layer having conductivity on the outer peripheral surface in the same manner as the development roller 33, and is more photosensitive than the development roller 33. 10 is disposed so as to press the photosensitive member 10 with the developed toner layer interposed therebetween, and the surface is moved with the surface of the photosensitive member 10 at a substantially constant speed. When the sweep roller 40 is brought into contact with the photosensitive member with an appropriate pressure, the elastic layer of the sweep roller 40 is elastically deformed to form a removal nip. By adjusting the contact pressure, the nip width that is the width in the surface moving direction at the nip portion can be adjusted. The nip width is set to be equal to or greater than the product of the linear speed of the sweep roller 40 and the development time constant, like the developing roller 33.

現像時、画像部ではトナーを感光体10に移動させる一方、地肌部(非画像部)では現像バイアス電位と感光体電位とによって形成される電界により現像ローラ33の表面にトナーを移動させることにより、地肌部にトナーを付着しないようにしている。スイープローラ40は、地肌部において現像ローラ33の表面に移動しきれず感光体10の表面に残留した、カブリの原因となるいわゆるカブリトナーを除去できる。   During development, toner is moved to the photoreceptor 10 in the image portion, while toner is moved to the surface of the developing roller 33 by the electric field formed by the developing bias potential and the photoreceptor potential in the background portion (non-image portion). The toner is prevented from adhering to the background portion. The sweep roller 40 can remove the so-called fog toner that causes the fog to remain on the surface of the photoreceptor 10 without moving to the surface of the developing roller 33 in the background portion.

クリーニング部材41は、金属ブレードやゴムブレード等により形成されたブレードやローラ等で構成されて、スイープローラ40に接触して表面に付着した液体現像剤を取り除く。スイープローラ40の液体現像剤を取り除くことにより、スイープローラ40のスイープ性能を維持できる。スイープローラ40から除去された液体現像剤は、調整タンクに集められ、濃度調整後に改めて現像装置13へ送られる。調整タンク内には調整タンク内の濃度を均一にする攪拌手段と、均一な状態の濃度を検知する濃度検知手段と、液量を検知する液量検知手段とが設けられており、新しい液体現像剤やキャリアの補給により濃度調整が行われる。調整タンクから現像ユニット内への液体現像剤の供給量は、液体現像剤の使用量より若干多く設定されているため、溢れた分を調整タンクへ戻すことにより液体現像剤を常に循環させている。   The cleaning member 41 is configured by a blade, a roller, or the like formed by a metal blade, a rubber blade, or the like, and removes the liquid developer attached to the surface in contact with the sweep roller 40. By removing the liquid developer from the sweep roller 40, the sweep performance of the sweep roller 40 can be maintained. The liquid developer removed from the sweep roller 40 is collected in the adjustment tank, and is sent again to the developing device 13 after the density adjustment. In the adjustment tank, a stirring means for making the concentration in the adjustment tank uniform, a concentration detection means for detecting the concentration in a uniform state, and a liquid amount detection means for detecting the liquid amount are provided. The concentration is adjusted by replenishment of the agent and carrier. The amount of liquid developer supplied from the adjustment tank into the developing unit is set slightly larger than the amount of liquid developer used, so the liquid developer is constantly circulated by returning the overflow to the adjustment tank. .

中間転写体15は、転写バイアスが印加されており感光体10と接触しながら連動して回転する。感光体10に形成されたトナー像は、中間転写体15との接触部分で中間転写体15に一次転写される。除電ランプ16は、一次転写後に感光体10に残留した残留電位を除去する。感光体クリーニング装置17は、一次転写後に感光体10に残留した液体現像剤を除去する。   The intermediate transfer member 15 is applied with a transfer bias and rotates in conjunction with the photosensitive member 10 while being in contact therewith. The toner image formed on the photoconductor 10 is primarily transferred to the intermediate transfer member 15 at a contact portion with the intermediate transfer member 15. The neutralization lamp 16 removes residual potential remaining on the photoconductor 10 after primary transfer. The photoconductor cleaning device 17 removes the liquid developer remaining on the photoconductor 10 after the primary transfer.

中間転写体15に対向して配置された二次転写ローラ18は、中間転写体15との間に転写材を挟んで搬送しながら、中間転写体15に形成されたトナー像を転写材上に二次転写する。中間転写体クリーニング装置19は、二次転写後に中間転写体15に残留した残留トナーを除去する。なお、二次転写の方式は、コロナ放電による方法、粘着転写法、熱転写法等を用いるものであってもよい。   The secondary transfer roller 18 disposed facing the intermediate transfer member 15 conveys the toner image formed on the intermediate transfer member 15 on the transfer material while conveying the transfer material with the intermediate transfer member 15 interposed therebetween. Secondary transfer. The intermediate transfer body cleaning device 19 removes residual toner remaining on the intermediate transfer body 15 after the secondary transfer. The secondary transfer method may be a method using a corona discharge, an adhesive transfer method, a thermal transfer method, or the like.

給紙部20は、給紙トレーに積載されたコピー用紙やOHPシート等の転写材を給紙ローラにより送り出し、レジストローラで一時停止させて中間転写体15のトナー像の位置とタイミングを合わせて、二次転写ローラ18と中間転写体15との接触部分に送り出す。定着装置21は、トナー像が二次転写された転写材を加熱及び加圧して、トナー像を転写材に定着させて排紙部22に排出する。定着装置21は、熱転写方式、溶剤定着、UV定着、加圧定着等を用いるものであってもよい。   The paper feed unit 20 feeds transfer materials such as copy sheets and OHP sheets loaded on the paper feed tray by paper feed rollers, temporarily stops them by registration rollers, and matches the position and timing of the toner image on the intermediate transfer member 15. Then, the secondary transfer roller 18 and the intermediate transfer member 15 are sent out to the contact portion. The fixing device 21 heats and pressurizes the transfer material onto which the toner image is secondarily transferred, fixes the toner image on the transfer material, and discharges it to the paper discharge unit 22. The fixing device 21 may use a thermal transfer method, solvent fixing, UV fixing, pressure fixing, or the like.

現像装置13を備える画像形成装置1によれば、現像電界不足による画像ムラを解消して高画質に画像を形成できる。   According to the image forming apparatus 1 including the developing device 13, it is possible to eliminate image unevenness due to insufficient development electric field and form an image with high image quality.

画像形成装置の構成図である。1 is a configuration diagram of an image forming apparatus. 塗布ローラの構成図及び彫刻溝パターンの例を示す図である。It is a figure which shows the example of a block diagram of an application | coating roller, and an engraving groove pattern. イオン導電タイプの弾性体層の環境変動と電気抵抗との関係図である。FIG. 5 is a relationship diagram between an environmental change and an electrical resistance of an ion conductive type elastic body layer. 現像ローラ及び感光体の断面図並びに電圧の印加状態を示す図である。FIG. 3 is a cross-sectional view of a developing roller and a photoreceptor, and a diagram illustrating a voltage application state. 弾性体層の接触抵抗比と電圧比との関係を示す図である。It is a figure which shows the relationship between the contact resistance ratio of an elastic body layer, and a voltage ratio.

符号の説明Explanation of symbols

1;画像形成装置、10;感光体、11;帯電器、12;露光装置、13;現像装置、
14;感光体スイープ装置、15;中間転写体、16;除電ランプ、
17;感光体クリーニング装置、18;二次転写ローラ、
19;中間転写体クリーニング装置、20;給紙部、21;定着装置、22;排紙部、
30;現像剤収容タンク、31;攪拌スクリュ、32;塗布装置、33;現像ローラ、
34;塗布ローラ、35;中間ローラ、36;クリーニング部材、37;芯金、
38;弾性体層、40;スイープローラ、41;クリーニング部材。
DESCRIPTION OF SYMBOLS 1; Image forming apparatus, 10; Photoconductor, 11: Charger, 12: Exposure apparatus, 13: Developing apparatus,
14; photoconductor sweep device, 15; intermediate transfer member, 16; static elimination lamp,
17; Photoconductor cleaning device, 18; Secondary transfer roller,
19; intermediate transfer member cleaning device; 20; paper feed unit; 21; fixing device; 22; paper discharge unit;
30; Developer storage tank, 31; Stir screw, 32; Coating device, 33; Developing roller,
34; coating roller, 35; intermediate roller, 36; cleaning member, 37; cored bar,
38; elastic layer, 40; sweep roller, 41; cleaning member.

Claims (1)

面に潜像を担持する潜像担持体に、液体現像剤を担持する現像剤担持体を対向させ、前記潜像担持体の表面及び前記現像剤担持体の表面を移動させながら、前記現像剤担持体と前記潜像担持体との間に電圧を印加し、前記現像剤担持体と前記潜像担持体との間に形成された前記液体現像剤層に現像電界を印加して前記潜像を現像する現像装置において、前記液体現像剤層の接触抵抗値を測定する接触抵抗値測定方法であって、
前記潜像担持体を帯電させずに全面露光し、
全面露光された前記潜像担持体と前記現像剤担持体との間に流れる電流を計測し、
前記現像剤担持体と前記潜像担持体との間に印加された電圧を、前記計測された電流で除して求めた抵抗値に、現像ニップのニップ幅と全長とをかけて前記現像剤担持体と前記液体現像剤層とを含む領域の接触抵抗値を求め、
前記現像剤担持体と前記液体現像剤層とを含む領域の接触抵抗値から、前記現像剤担持体の接触抵抗値を引いて前記現像ニップにおける前記液体現像剤層の接触抵抗値を求めることを特徴とする接触抵抗値測定方法。
The image bearing member configured to bear a latent image on the front surface, a developer carrying member for carrying the liquid developer is opposed, while moving the surface and the surface of the developer carrying member of the latent image carrier, the developing A voltage is applied between the developer carrier and the latent image carrier and a developing electric field is applied to the liquid developer layer formed between the developer carrier and the latent image carrier to In a developing device for developing an image, a contact resistance value measuring method for measuring a contact resistance value of the liquid developer layer,
Exposing the entire surface without charging the latent image carrier,
Measure the current flowing between the latent image carrier and the developer carrier that are exposed on the entire surface,
The developer is obtained by multiplying the resistance value obtained by dividing the voltage applied between the developer carrier and the latent image carrier by the measured current and the nip width and total length of the development nip. Obtain the contact resistance value of the region including the carrier and the liquid developer layer,
The contact resistance value of the liquid developer layer in the developing nip is obtained by subtracting the contact resistance value of the developer carrier from the contact resistance value of the region including the developer carrier and the liquid developer layer. A characteristic contact resistance value measuring method.
JP2004354880A 2004-12-08 2004-12-08 Contact resistance measurement method Expired - Fee Related JP4642451B2 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0293671A (en) * 1988-09-30 1990-04-04 Toshiba Corp Developing method
JPH07178952A (en) * 1993-12-24 1995-07-18 Casio Comput Co Ltd Electrostatic recorder
JPH11242382A (en) * 1998-02-26 1999-09-07 Sharp Corp One-component toner developing device
JP2001194912A (en) * 2000-01-11 2001-07-19 Ricoh Co Ltd Wet type developing device and wet type image forming device
JP2002287518A (en) * 2001-03-23 2002-10-03 Ricoh Co Ltd Liquid developing device and image forming apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0293671A (en) * 1988-09-30 1990-04-04 Toshiba Corp Developing method
JPH07178952A (en) * 1993-12-24 1995-07-18 Casio Comput Co Ltd Electrostatic recorder
JPH11242382A (en) * 1998-02-26 1999-09-07 Sharp Corp One-component toner developing device
JP2001194912A (en) * 2000-01-11 2001-07-19 Ricoh Co Ltd Wet type developing device and wet type image forming device
JP2002287518A (en) * 2001-03-23 2002-10-03 Ricoh Co Ltd Liquid developing device and image forming apparatus

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