JP4639609B2 - Film-like lid with excellent piercing and opening properties - Google Patents
Film-like lid with excellent piercing and opening properties Download PDFInfo
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- JP4639609B2 JP4639609B2 JP2004065020A JP2004065020A JP4639609B2 JP 4639609 B2 JP4639609 B2 JP 4639609B2 JP 2004065020 A JP2004065020 A JP 2004065020A JP 2004065020 A JP2004065020 A JP 2004065020A JP 4639609 B2 JP4639609 B2 JP 4639609B2
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- aluminum foil
- polypropylene
- unstretched
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- -1 polypropylene Polymers 0.000 claims description 92
- 239000004743 Polypropylene Substances 0.000 claims description 82
- 229920001155 polypropylene Polymers 0.000 claims description 82
- 239000011888 foil Substances 0.000 claims description 51
- 229910052782 aluminium Inorganic materials 0.000 claims description 50
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 50
- 239000000463 material Substances 0.000 claims description 35
- 239000004840 adhesive resin Substances 0.000 claims description 20
- 229920006223 adhesive resin Polymers 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 229920001225 polyester resin Polymers 0.000 claims description 11
- 239000004645 polyester resin Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 2
- 239000005025 cast polypropylene Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 89
- 229920000728 polyester Polymers 0.000 description 11
- 239000010902 straw Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 5
- 238000003475 lamination Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000009820 dry lamination Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007610 electrostatic coating method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Closures For Containers (AREA)
- Laminated Bodies (AREA)
Description
本発明は、フランジ付容器にヒートシールにより適用されるフィルム状蓋材に関し、より詳細には、蓋材をヒートシール性よく容器に接着し得ると共に、ストロー等で容易に突き刺し貫通することが可能な、突き刺し開口性に優れたフィルム状蓋材に関する。 The present invention relates to a film-like lid material applied to a flanged container by heat sealing, and more specifically, the lid material can be adhered to the container with good heat sealability and can be easily pierced and penetrated with a straw or the like. The present invention also relates to a film-like lid material excellent in piercing and opening properties.
従来より、プラスチックや、プラスチックと軽金属箔等から成る積層体を熱成形して成るフランジ付容器においては、フィルム状の蓋材がカップ状容器やトレー状容器のフランジ部にヒートシールされることにより密封されている。
このようなフィルム状蓋材としては、一般に容器から引き剥がされて開封されるピーラブルタイプの蓋材の他、蓋材を容器から取外すことなく、ストローやオーバーキャップ等により直接蓋材に開口を形成して、内容物を取出すタイプの蓋材があり、種々の提案がなされている。
Conventionally, in a flanged container formed by thermoforming a laminated body made of plastic or plastic and light metal foil, the film-like lid material is heat-sealed to the flange part of the cup-shaped container or tray-shaped container. Sealed.
As such a film-like cover material, in addition to the peelable-type cover material that is generally peeled off and opened from the container, the cover material is directly opened by a straw or an overcap without removing the cover material from the container. There are types of lids that are formed and take out the contents, and various proposals have been made.
例えば、下記特許文献１には、延伸プラスチックフィルムとポリオレフィン系プラスチックフィルムから成り、ストロー差込用開口を設けた積層フィルムと、金属箔とヒートシール性樹脂から成る積層フィルムを溶融押出しされたオレフィン系樹脂層を介して押出しラミネートして成る蓋材が提案されている。
また下記特許文献２には、蓋材を容器から取外すことなく、ストロー等を突き刺して内容物を取出すタイプの蓋材において、外面側から一方向性を有する易裂性樹脂フィルム／印刷層／アルミ箔／シーラント層を、接着剤を介してドライラミネーションにより貼り合せたものが提案されている。
For example, in the following Patent Document 1, an olefin-based material obtained by melt-extrusion of a laminated film made of a stretched plastic film and a polyolefin-based plastic film, provided with a straw insertion opening, and a laminated film made of a metal foil and a heat-sealable resin. A lid material formed by extrusion lamination through a resin layer has been proposed.
Further, in Patent Document 2 below, an easily tearable resin film / printing layer / aluminum that has unidirectionality from the outer surface side in a lid material that pierces a straw or the like to take out the contents without removing the lid material from the container. It has been proposed that a foil / sealant layer is bonded by dry lamination via an adhesive.
上述したような蓋材を容器口部から取外すことなくストロー等により内容物を取出すタイプの蓋材においては、一般に蓋材を容器フランジ部に強固にヒートシールする必要があることから、一般に最内層を構成するヒートシール層は無延伸状態の樹脂フィルムが用いられており、このためストロー等で蓋材を突き刺し開口を形成させる際、最内層の無延伸フィルムに伸びが生じてスムーズに開口形成できないという問題がある。 In the case of the type of the lid that takes out the contents with a straw or the like without removing the lid from the container mouth as described above, it is generally necessary to firmly heat-seal the lid to the container flange. The heat-seal layer that comprises a non-stretched resin film is used, and therefore when the lid is pierced with a straw or the like to form an opening, the innermost unstretched film stretches and cannot be smoothly formed. There is a problem.
従って本発明の目的は、容器へのヒートシール性に優れていると共に、ストロー等による突き刺し開口性に優れたフィルム状蓋材を提供することである。 Accordingly, an object of the present invention is to provide a film-like lid material that is excellent in heat sealability to a container and excellent in piercing opening performance with a straw or the like.
本発明によれば、フランジ付容器にヒートシールにより適用されるフィルム状蓋材であって、少なくとも内面から外面に向かって、無延伸ポリプロピレン層、アルミニウム箔層及び易引裂き性を有する二軸延伸ポリエステル樹脂層の順で構成され、無延伸ポリプロピレン層とアルミニウム箔層の間が粉末状変性ポリプロピレンから成る接着剤樹脂を用いて接合されていると共に、ポリプロピレンの融点近傍の温度で加熱処理に付されていることを特徴とする突き刺し開口性に優れたフィルム状蓋材が提供される。 According to the present invention, a biaxially stretched polyester having a non-stretched polypropylene layer, an aluminum foil layer, and an easily tearable film, which is applied to a flanged container by heat sealing, at least from the inner surface toward the outer surface It is composed in the order of the resin layer, and between the unstretched polypropylene layer and the aluminum foil layer is bonded using an adhesive resin made of powdered modified polypropylene and subjected to heat treatment at a temperature near the melting point of polypropylene. it was excellent in openability piercing, characterized in that there film cover material Ru is provided.
本発明によればまた、少なくとも無延伸ポリプロピレン層、アルミニウム箔層及び易引裂き性を有する二軸延伸ポリエステル樹脂層から成る積層体から成るフィルム状蓋材の製造方法であって、無延伸ポリプロピレン層とアルミニウム箔層の間を粉末状変性ポリプロピレンから成る接着剤樹脂を固体状の粉末のままアルミニウム箔表面に塗布付着して接合した後、ポリプロピレンの融点近傍の温度で加熱圧着することを特徴とするフィルム状蓋材の製造方法が提供される。
本発明のフィルム状蓋材の製造方法においては、
１．粉末状変性ポリプロピレンをアルミニウム箔上で予備加熱した後無延伸ポリプロピレンをアルミニウム箔と接合させること、
２．加熱圧着の温度が１６０乃至１７０℃であること、
が好適である。
According to the present invention, there is also provided a method for producing a film-like cover material comprising a laminate comprising at least an unstretched polypropylene layer, an aluminum foil layer, and an easily tearable biaxially stretched polyester resin layer, A film characterized in that an adhesive resin made of powdered modified polypropylene is applied between and adhered to the surface of the aluminum foil between the aluminum foil layers and bonded to the surface of the aluminum foil , followed by thermocompression bonding at a temperature near the melting point of the polypropylene. A method of manufacturing a lid member is provided.
In the manufacturing method of the film-like lid material of the present invention,
1 . Causing a powdery powder form modified polypropylene is bonded to unstretched polypropylene was preheated on aluminum foil and aluminum foil,
2 . When the temperature of the pressurized heat crimping Dearuko 160 to 170 ° C.,
Is preferred.
本発明のフィルム状蓋材においては、少なくとも内面から外面に向かって、無延伸ポリプロピレン層、アルミニウム箔層及び二軸延伸ポリエステル樹脂層の順で構成され、無延伸ポリプロピレン層とアルミニウム箔層の間が粉末状変性ポリプロピレンから成る接着剤樹脂を用いて接合されていると共に、ポリプロピレンの融点近傍の温度で加熱圧着されていることにより、アルミニウム箔層と無延伸ポリプロピレン層の密着性が顕著に改善されると共に、無延伸ポリプロピレン層の結晶化度が向上して、無延伸ポリプロピレン層の伸びが著しく低減され、ストローやオーバーキャップ等による突き刺し開口性を顕著に向上させることができる。 In the film-like lid material of the present invention, at least from the inner surface toward the outer surface, the unstretched polypropylene layer, the aluminum foil layer, and the biaxially stretched polyester resin layer are configured in this order, and the space between the unstretched polypropylene layer and the aluminum foil layer is The adhesiveness between the aluminum foil layer and the unstretched polypropylene layer is remarkably improved by being bonded using an adhesive resin made of powdered modified polypropylene and being heat-pressed at a temperature near the melting point of polypropylene. At the same time, the degree of crystallinity of the unstretched polypropylene layer is improved, the elongation of the unstretched polypropylene layer is remarkably reduced, and the piercing opening property by a straw or an overcap can be remarkably improved.
本発明のフィルム状蓋材においては、少なくとも内面から外面に向かって、無延伸ポリプロピレン層、アルミニウム箔層及び二軸延伸ポリエステル樹脂層の順で構成され、無延伸ポリプロピレン層とアルミニウム箔層の間の接合が粉末状変性ポリプロピレンから成る接着剤樹脂が用いられ、しかもこれらがポリプロピレンの融点近傍の温度で加熱圧着されていることが重要な特徴である。 In the film-like lid material of the present invention, at least from the inner surface toward the outer surface, an unstretched polypropylene layer, an aluminum foil layer, and a biaxially stretched polyester resin layer are configured in this order, and between the unstretched polypropylene layer and the aluminum foil layer. It is an important feature that an adhesive resin made of powdered modified polypropylene is used for bonding, and that these are thermocompression bonded at a temperature near the melting point of polypropylene.
前述した通り、蓋材を容器のフランジ部に接合するために最内面に設けるヒートシール層として、ヒートシール性に優れる無延伸のポリプロピレン層を用いる場合、無延伸ポリプロピレンフィルムの弾性が大きいため、ストロー等を突き刺す際にフィルムに伸びが生じてスムーズに突き刺すことができず、開口性に劣っていた。
本発明のフィルム状蓋材においては、ヒートシール性に優れる無延伸ポリプロピレン層を最内層に設けた場合にも、ポリプロピレン層とアルミニウム箔層の間が粉末状変性ポリプロピレンから成る接着性樹脂を用いて接合され、しかもポリプロピレンの融点近傍の温度で加熱処理に付されていることにより、ポリプロピレン層として無延伸ポリプロピレンフィルムを用いた場合にもポリプロピレン層の伸びが有効に抑制され、ストロー等による突き刺し開口性が顕著に改善されている。
As described above, when an unstretched polypropylene layer having excellent heat sealability is used as the heat seal layer provided on the innermost surface in order to join the lid to the flange portion of the container, the stretch of the unstretched polypropylene film is large. When piercing etc., the film was stretched and could not be pierced smoothly, and the opening property was inferior.
In the film-like cover material of the present invention, even when an unstretched polypropylene layer excellent in heat sealability is provided in the innermost layer, an adhesive resin made of powdered modified polypropylene is used between the polypropylene layer and the aluminum foil layer. Bonded and subjected to heat treatment at a temperature in the vicinity of the melting point of polypropylene, the elongation of the polypropylene layer is effectively suppressed even when an unstretched polypropylene film is used as the polypropylene layer, and the piercing opening by a straw or the like Has been significantly improved.
本発明において、無延伸ポリプロピレン層及びアルミニウム箔層の間を粉末状変性ポリプロピレンからなる接着剤樹脂を用いることにより、積層体の突き刺し開口性が改良されることは、後述する実施例の結果から明らかである。
すなわち、同一の層構成であっても、ウレタン系接着剤を用いたドライラミネーションにより積層されたフィルム状蓋材は、突き刺し開口性に劣っているのに対し（比較例１）、アルミニウム箔層と無延伸ポリプロピレン層の間を粉末状変性ポリプロピレンから成る接着剤樹脂を用いて接合したフィルム状蓋材は、突き刺し開口性に優れていることが明らかである（実施例１〜４）。
In the present invention, the use of an adhesive resin made of powdered modified polypropylene between the unstretched polypropylene layer and the aluminum foil layer improves the piercing opening property of the laminate, which is apparent from the results of Examples described later. It is.
That is, even in the same layer configuration, the film-like lid member laminated by dry lamination using a urethane-based adhesive is inferior in piercing and opening properties (Comparative Example 1), while the aluminum foil layer and It is clear that the film-like lid material in which the unstretched polypropylene layers are joined using an adhesive resin made of powdered modified polypropylene is excellent in piercing and opening properties (Examples 1 to 4).
本発明において、アルミニウム箔層と無延伸ポリプロピレン層の間を粉末状変性ポリプロピレンから成る接着剤樹脂を用いた積層体が、フィルム状蓋材として優れた突き刺し開口性を有するためには、粉末状変性ポリプロピレンから成る接着剤樹脂を用いると共に、積層体全体をポリプロピレンの融点近傍の温度で加熱圧着することが重要である。
これによりアルミニウム箔と無延伸ポリプロピレン層の密着性が向上すると共に、無延伸ポリプロピレン層の結晶化度が上昇し、無延伸ポリプロピレン層の弾性が低下して突き刺しにより開口形成する際の無延伸ポリプロピレン層の伸びが抑制され、フィルム状蓋材の突き刺し開口性を顕著に向上することが可能となるのである。
In the present invention, in order that the laminate using an adhesive resin made of powder-modified polypropylene between the aluminum foil layer and the unstretched polypropylene layer has excellent piercing opening properties as a film-like lid material, While using an adhesive resin made of polypropylene, it is important to heat-press the entire laminate at a temperature near the melting point of polypropylene.
This improves the adhesion between the aluminum foil and the unstretched polypropylene layer, increases the crystallinity of the unstretched polypropylene layer, reduces the elasticity of the unstretched polypropylene layer, and forms an opening by piercing. Is suppressed, and the piercing opening property of the film-like lid material can be remarkably improved.
本発明のフィルム状蓋材は、前述した通り、無延伸ポリプロピレン層、アルミニウム箔及び二軸延伸ポリエステル樹脂層から成り、無延伸ポリプロピレン層とアルミニウム箔層の間が粉末状変性ポリプロピレンから成る接着剤樹脂を用いるものであり、その接合の順序としては、先に二軸延伸ポリエステル層とアルミニウム箔を後述する従来公知の方法により積層し、次いでこの二層積層体のアルミニウム箔表面に粉末状変性ポリプロピレンから成る接着剤樹脂を塗布した後、無延伸ポリプロピレン層を接合することが、無延伸ポリプロピレン層のヒートシール性及び弾性のバランスを調整する上で好ましいが、勿論、先にアルミニウム箔表面に粉末状変性ポリプロピレンから成る接着剤樹脂を塗布した後、無延伸ポリプロピレン層を接合し、この二層積層体のアルミニウム表面に従来公知の方法によって二軸延伸ポリエステル層を積層することもできる。 As described above, the film-like lid material of the present invention is composed of an unstretched polypropylene layer, an aluminum foil, and a biaxially stretched polyester resin layer, and an adhesive resin composed of powdered modified polypropylene between the unstretched polypropylene layer and the aluminum foil layer. The biaxially stretched polyester layer and the aluminum foil are first laminated by a conventionally known method, and then the powdery modified polypropylene is applied to the surface of the aluminum foil of the two-layer laminate. After applying the adhesive resin, it is preferable to join the non-stretched polypropylene layer to adjust the balance of heat sealability and elasticity of the non-stretched polypropylene layer. After the adhesive resin made of polypropylene is applied, the unstretched polypropylene layer is joined. By conventional methods known to the aluminum surfaces of the two-layer laminate may be laminated biaxially oriented polyester layer.
アルミニウム箔面への粉末状変性ポリプロピレンから成る接着剤樹脂の塗布は、静電塗装法等により固体状の粉体のままアルミニウム箔表面に塗布付着される。粉末状変性ポリプロピレンからなる接着剤樹脂のアルミニウム箔表面への塗布量は、一般に１．０乃至５．０ｇ／ｍ２、特に１．０乃至３．０ｇ／ｍ２の範囲にあることが好ましい。 Application of the adhesive resin made of powdered modified polypropylene to the aluminum foil surface is applied and adhered to the surface of the aluminum foil as a solid powder by an electrostatic coating method or the like. The coating amount of the adhesive resin made of powdered modified polypropylene on the surface of the aluminum foil is generally 1.0 to 5.0 g / m 2 , particularly preferably 1.0 to 3.0 g / m 2 .
アルミニウム箔表面に塗布された粉末状変性ポリプロピレンから成る接着剤樹脂は塗布された状態で予備加熱される。この予備加熱においては、先に接合された二軸延伸ポリエステルフィルムとアルミニウム箔の接着を阻害しないように短時間で均一に行うことが重要であり、そのため、高周波誘導加熱によりアルミニウム箔表面が１８０乃至３００℃となるように、０．１乃至１０秒間加熱することが望ましい。予備加熱により粉末状変性ポリプロピレンから成る接着剤樹脂が溶融された後、無延伸ポリプロピレンフィルムと接合或いはポリプロピレンの溶融物が押出ラミネートされる。 The adhesive resin made of powdered modified polypropylene applied to the aluminum foil surface is preheated in the applied state. In this preliminary heating, it is important to perform the heating uniformly in a short time so as not to inhibit the adhesion between the biaxially stretched polyester film and the aluminum foil previously bonded. It is desirable to heat for 0.1 to 10 seconds so that it may be 300 degreeC. After the adhesive resin made of powdery modified polypropylene is melted by preheating, the unstretched polypropylene film is joined to or melted by extrusion lamination.
その後無延伸ポリプロピレン層が接合された三層積層体の全体が、ポリプロピレンの融点近傍の温度となるように、１５０乃至３００℃の範囲の温度、０．５乃至３０ｋｇ／ｃｍ２、特に１乃至１０ｋｇ／ｃｍ２の範囲の圧力のヒータロール間で加熱圧着される。これにより前述した無延伸ポリプロピレンの伸びの抑制が可能になる。加熱圧着された積層体は冷却され、フィルム状蓋材のための積層体が形成される。
尚、先にアルミニウム箔と無延伸ポリプロピレン層の二層積層体を作成した後、二軸延伸ポリエステル層を積層した場合には、アルミニウム箔と無延伸ポリプロピレン層の二層積層体のみを加熱圧着し、その後二軸延伸ポリエステル層の積層を行ってもよいし、二軸延伸ポリエステル層を積層した三層積層体の状態で加熱圧着することもできる。
Thereafter, the temperature in the range of 150 to 300 ° C., 0.5 to 30 kg / cm 2 , especially 1 to 10 kg, so that the whole of the three-layer laminate to which the unstretched polypropylene layer is bonded has a temperature near the melting point of polypropylene. It is thermocompression bonded between heater rolls having a pressure in the range of / cm 2 . This makes it possible to suppress the elongation of the unstretched polypropylene described above. The laminated body heat-pressed is cooled, and the laminated body for a film-like cover material is formed.
In addition, after creating a two-layer laminate of an aluminum foil and an unstretched polypropylene layer first, when a biaxially stretched polyester layer is laminated, only the two-layer laminate of an aluminum foil and an unstretched polypropylene layer is thermocompression bonded. Then, the biaxially stretched polyester layer may be laminated, or heat-pressed in the state of a three-layer laminate in which the biaxially stretched polyester layer is laminated.
本発明において無延伸ポリプロピレン層及びアルミニウム箔の間の接着に用いられる粉末状変性ポリプロピレンから成る接着剤樹脂は、マレイン酸、フマル酸、クロトン酸、イタコン酸、シトラコン酸、アクリル酸等の有機酸又はそのエステル或いは金属塩、無水マレイン酸、無水シトラコン酸、テトラヒドロ無水フタル酸等の酸無水物をグラフト、ブロック或いはランダム共重合した変性ポリプロピレンから成るものである。また変性ポリプロピレンの融点は１５５乃至１６５℃の範囲にあることが望ましい。
粉末の粒径は、常温で０．１乃至２００μｍ、特に０．１乃至１００μｍの範囲にある粉末状であることが好ましい。
In the present invention, an adhesive resin composed of powdered modified polypropylene used for adhesion between the unstretched polypropylene layer and the aluminum foil is an organic acid such as maleic acid, fumaric acid, crotonic acid, itaconic acid, citraconic acid, acrylic acid, or the like. It consists of a modified polypropylene obtained by grafting, blocking, or randomly copolymerizing an acid anhydride such as an ester or metal salt thereof, maleic anhydride, citraconic anhydride, or tetrahydrophthalic anhydride. The melting point of the modified polypropylene is preferably in the range of 155 to 165 ° C.
The particle diameter of the powder is preferably 0.1 to 200 μm at room temperature, particularly preferably 0.1 to 100 μm.
また、無延伸ポリプロピレン層は、予め無延伸フィルムを形成し、巻き取られたものを、溶融状態の粉末状変性ポリプロピレンから成る接着剤樹脂が形成されたアルミニウム箔上に供給して接合することもできるが、溶融されたポリプロピレンを前記アルミニウム箔上に押出して積層する押出しラミネーションによることが好ましい。
無延伸ポリプロピレン層を構成するポリプロピレンとしては、これに限定されものではないが、融点１５５乃至１６５℃の範囲にあるものであることが好ましい。
The unstretched polypropylene layer may be formed by forming an unstretched film in advance and winding it on an aluminum foil on which an adhesive resin made of a powdered modified polypropylene in a molten state is formed. However, it is preferable to use extrusion lamination in which molten polypropylene is extruded and laminated on the aluminum foil.
The polypropylene constituting the unstretched polypropylene layer is not limited to this, but preferably has a melting point in the range of 155 to 165 ° C.
二軸延伸ポリエステル層及びアルミニウム箔の間の接合は、前述した通り従来公知方法により行うことができ、ドライラミネーションや押出しラミネーション等により行うことができる。また用いる接着剤としても従来これらの接合に用いられていたウレタン系接着剤、ポリエステル系接着剤等を用いることができる。 Bonding between the biaxially stretched polyester layer and the aluminum foil can be performed by a conventionally known method as described above, and can be performed by dry lamination, extrusion lamination, or the like. Also, as the adhesive to be used, urethane adhesives, polyester adhesives and the like that have been conventionally used for these joining can be used.
二軸延伸ポリエステル層を構成するポリエステル樹脂としては、ホモポリエチレンテレフタレートが最適であるが、エチレンテレフタレート単位の含有量が８０モル％以上の共重合ポリエステルも好適に使用することができる。
かかる共重合ポリエステルにおいて、テレフタル酸以外の二塩基酸としては、イソフタル酸、フタル酸、ナフタレンジカルボン酸等の芳香族ジカルボン酸；シクロヘキサンジカルボン酸等の脂環族ジカルボン酸；コハク酸、アジピン酸、セバチン酸、ドデカンジオン酸等の脂肪族ジカルボン酸；等の１種又は２種以上の組み合わせを例示することができ、エチレングリコール以外のジオール成分としては、プロピレングリコール、１，４−ブタンジオール、ジエチレングリコール、１，６−ヘキシレングリコール、シクロヘキサンジメタノール、ビスフェノールＡのエチレンオキサイド付加物等の１種又は２種以上を挙げることができる。
ポリエステル樹脂は、ガラス転移点（Ｔｇ）が４０乃至１００℃であり、且つ融点（Ｔｍ）が２００乃至２７５℃の範囲にあることが好ましい。
As the polyester resin constituting the biaxially stretched polyester layer, homopolyethylene terephthalate is optimal, but a copolymerized polyester having an ethylene terephthalate unit content of 80 mol% or more can also be suitably used.
In such a copolyester, dibasic acids other than terephthalic acid include aromatic dicarboxylic acids such as isophthalic acid, phthalic acid and naphthalenedicarboxylic acid; alicyclic dicarboxylic acids such as cyclohexanedicarboxylic acid; succinic acid, adipic acid, and sebatin. Examples of the diol component other than ethylene glycol can include propylene glycol, 1,4-butanediol, diethylene glycol, and the like. One or more of 1,6-hexylene glycol, cyclohexanedimethanol, ethylene oxide adduct of bisphenol A and the like can be mentioned.
The polyester resin preferably has a glass transition point (Tg) of 40 to 100 ° C. and a melting point (Tm) of 200 to 275 ° C.
本発明においては二軸延伸ポリエステル樹脂として、特に易引裂き性を有するものであることが、突き刺し開口性を向上する上に好適である。
易引裂き性を有する二軸ポリエステルフィルムとしては、フィルム表面に傷が付けられたものや、フィルムの縦方向及び横方向の延伸倍率を変化させ、フィルムの縦横の分子配向のバランスを崩したもの等種々のものが提案されており、このような予め易引裂き性を有するフィルムを用いることもできるが、積層後の二軸延伸ポリエステルフィルムを白化結晶化させるような熱処理に付して脆くさせてもよい。
In the present invention, as the biaxially stretched polyester resin, it is particularly preferable that the biaxially stretched polyester resin has easy tearability in order to improve the piercing opening property.
Biaxial polyester film with easy tearability, such as those with scratches on the film surface, or those that break the balance of molecular orientation in the vertical and horizontal directions of the film by changing the stretching ratio in the vertical and horizontal directions of the film Various films have been proposed, and it is possible to use a film having such an easy tear property in advance. However, even if the biaxially stretched polyester film after lamination is subjected to a heat treatment to whiten and crystallize it, it may be made brittle. Good.
本発明のフィルム状蓋材において各層の厚さは、無延伸ポリプロピレン層が３０乃至１００μｍ、特に３０乃至７０μｍの範囲、アルミニウム箔が６乃至６０μｍ、特に６乃至３０μｍの範囲、二軸延伸ポリエステル樹脂層が９乃至１２μｍの範囲にあることが望ましい。 In the film-like cover material of the present invention, the thickness of each layer is 30 to 100 μm, particularly 30 to 70 μm for the unstretched polypropylene layer, 6 to 60 μm, particularly 6 to 30 μm for the aluminum foil, and the biaxially stretched polyester resin layer Is preferably in the range of 9 to 12 μm.
本発明のフィルム状蓋材は、前述した通り、少なくとも二軸延伸ポリエステル層、アルミニウム箔層、無延伸ポリプロピレン層から成り、無延伸ポリプロピレン層がアルミニウム箔層と接し且つヒートシール層となる限りものであるが、これ以外にも延伸ポリエチレンテレフタレート層の外面側に印刷層及び／又は保護層、或いは延伸ポリエチレンテレフタレート層とアルミニウム箔層の間に印刷層が形成されていてもよい。
本発明のフィルム状蓋材が適用されるフランジ付容器の形状としては、カップ状容器やトレー状容器、ボトル状容器等種々の形状を挙げることができる。
As described above, the film-like lid material of the present invention comprises at least a biaxially stretched polyester layer, an aluminum foil layer, and an unstretched polypropylene layer, as long as the unstretched polypropylene layer is in contact with the aluminum foil layer and becomes a heat seal layer. In addition to this, a printing layer and / or a protective layer or a printing layer may be formed between the stretched polyethylene terephthalate layer and the aluminum foil layer on the outer surface side of the stretched polyethylene terephthalate layer.
Examples of the shape of the flanged container to which the film-like lid material of the present invention is applied include various shapes such as a cup-shaped container, a tray-shaped container, and a bottle-shaped container.
（実施例１）
厚さ３０μｍのアルミニウム箔に厚さ９μｍの二軸延伸ポリエチレンテレフタレートフィルムをイソシアネート系接着剤を介して積層した二層積層体のアルミニウム箔表面に、変性ポリプロピレン粉末を２ｇ／ｍ２の塗布量で塗布し高周波誘導加熱によりアルミニウム表面の予備加熱を行った後、厚さ３０μｍの無延伸ポリプロピレンフィルムを接合した。この三層積層体をヒータロールで加熱圧着した後冷却し、フィルム状蓋材を作成した。
Example 1
A modified polypropylene powder is applied at a coating amount of 2 g / m 2 on the surface of a two-layer laminate in which a biaxially stretched polyethylene terephthalate film having a thickness of 9 μm is laminated on an aluminum foil having a thickness of 30 μm via an isocyanate adhesive. After preheating the aluminum surface by high frequency induction heating, an unstretched polypropylene film having a thickness of 30 μm was joined. This three-layer laminate was heat-pressed with a heater roll and then cooled to prepare a film-like lid material.
（実施例２）
厚さ２０μｍのアルミニウム箔を用いた以外は実施例１と同様にしてフィルム状蓋材を作成した。
(Example 2)
A film-like lid material was prepared in the same manner as in Example 1 except that an aluminum foil having a thickness of 20 μm was used.
（実施例３）
実施例２で得られた積層体の二軸延伸ポリエチレンテレフタレート層側を更に加熱することにより表面を白化させた以外は実施例２と同様に、フィルム状蓋材を作成した。
(Example 3)
A film-like lid was prepared in the same manner as in Example 2 except that the biaxially stretched polyethylene terephthalate layer side of the laminate obtained in Example 2 was further heated to whiten the surface.
（実施例４）
二軸延伸ポリエチレンテレフタレートフィルムとして、厚さ１６μｍの市販の易引裂き性ポリエチレンテレフタレートフィルムを用いた以外は実施例２と同様にしてフィルム状蓋材を作成した。
Example 4
A film-shaped lid was prepared in the same manner as in Example 2 except that a commercially available easily tearable polyethylene terephthalate film having a thickness of 16 μm was used as the biaxially stretched polyethylene terephthalate film.
（比較例１）
厚さ３０μｍのアルミニウム箔に厚さ９μｍの二軸延伸ポリエチレンテレフタレートフィルムをイソシアネート系接着剤を介して積層した二層積層体のアルミニウム箔表面に、イソシアネート系接着剤を介して厚さ３０μｍの無延伸ポリプロピレンフィルムをドライラミネーションにより積層して、フィルム状蓋材を作成した。
(Comparative Example 1)
Non-stretched 30 μm thick via an isocyanate adhesive on the aluminum foil surface of a two-layer laminate obtained by laminating a 9 μm thick biaxially stretched polyethylene terephthalate film via an isocyanate adhesive on a 30 μm thick aluminum foil A polypropylene film was laminated by dry lamination to prepare a film-like lid material.
（突き刺し開口性）
実施例１乃至４及び比較例１により得られたフィルム状蓋材について、ＪＩＳ Ｚ １７０７の方法に準拠して、突き刺し強度を求めた。結果を表１に示す。
(Puncture opening)
The piercing strength was calculated | required about the film-form cover material obtained by Example 1 thru | or 4 and the comparative example 1 based on the method of JISZ1707. The results are shown in Table 1.
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| JP4940865B2 (en) * | 2006-09-29 | 2012-05-30 | 大日本印刷株式会社 | Beverage cup lid |
| JP5503348B2 (en) * | 2009-04-25 | 2014-05-28 | 東洋アルミニウム株式会社 | Lid with excellent piercing properties |
| WO2011027524A1 (en) * | 2009-09-02 | 2011-03-10 | 株式会社カネカ | Hot-melt adhesive material for induction heating |
| CN102736945B (en) | 2011-03-31 | 2016-05-18 | 国际商业机器公司 | A kind of method and system of the Multi-instance running application |
| JP6559467B2 (en) * | 2015-05-29 | 2019-08-14 | 株式会社Ｕａｃｊ製箔 | Press-through pack lid |
| JP2020022684A (en) * | 2018-08-08 | 2020-02-13 | 共同印刷株式会社 | Needle stick detection sheet |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62233241A (en) * | 1986-04-02 | 1987-10-13 | 東洋製罐株式会社 | Laminated cover material of vessel for pressure heating sterilization |
| JPH09323377A (en) * | 1996-06-07 | 1997-12-16 | Toppan Printing Co Ltd | Lid material to be easily pierced |
| JP2001121649A (en) * | 1999-10-27 | 2001-05-08 | Toppan Printing Co Ltd | Shading packaging material |
| JP2001353825A (en) * | 2000-06-13 | 2001-12-25 | Japan Polyolefins Co Ltd | Easy tear laminate and method for manufacturing the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6458676A (en) * | 1987-08-28 | 1989-03-06 | Hokkai Can | Preparation of lid material for container lid |
-
2004
- 2004-03-09 JP JP2004065020A patent/JP4639609B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62233241A (en) * | 1986-04-02 | 1987-10-13 | 東洋製罐株式会社 | Laminated cover material of vessel for pressure heating sterilization |
| JPH09323377A (en) * | 1996-06-07 | 1997-12-16 | Toppan Printing Co Ltd | Lid material to be easily pierced |
| JP2001121649A (en) * | 1999-10-27 | 2001-05-08 | Toppan Printing Co Ltd | Shading packaging material |
| JP2001353825A (en) * | 2000-06-13 | 2001-12-25 | Japan Polyolefins Co Ltd | Easy tear laminate and method for manufacturing the same |
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| JP2005255173A (en) | 2005-09-22 |
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