JP4624831B2 - External preparation for skin and cosmetics containing inositol derivative - Google Patents
External preparation for skin and cosmetics containing inositol derivative Download PDFInfo
- Publication number
- JP4624831B2 JP4624831B2 JP2005089259A JP2005089259A JP4624831B2 JP 4624831 B2 JP4624831 B2 JP 4624831B2 JP 2005089259 A JP2005089259 A JP 2005089259A JP 2005089259 A JP2005089259 A JP 2005089259A JP 4624831 B2 JP4624831 B2 JP 4624831B2
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- JP
- Japan
- Prior art keywords
- extract
- oil
- acid
- polyoxyethylene
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims description 38
- 239000002537 cosmetic Substances 0.000 title claims description 23
- 150000004001 inositols Chemical class 0.000 title claims description 15
- CDAISMWEOUEBRE-UHFFFAOYSA-N inositol Chemical class OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 claims description 42
- 229960000367 inositol Drugs 0.000 claims description 36
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 33
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 claims description 31
- 229920000858 Cyclodextrin Polymers 0.000 claims description 9
- 108010025880 Cyclomaltodextrin glucanotransferase Proteins 0.000 claims description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000284 extract Substances 0.000 description 138
- -1 phosphate ester Chemical class 0.000 description 138
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 47
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 40
- 235000014113 dietary fatty acids Nutrition 0.000 description 40
- 229930195729 fatty acid Natural products 0.000 description 40
- 239000000194 fatty acid Substances 0.000 description 40
- 239000003921 oil Substances 0.000 description 31
- 235000019198 oils Nutrition 0.000 description 31
- 150000004665 fatty acids Chemical class 0.000 description 30
- 239000011734 sodium Substances 0.000 description 24
- 229910052708 sodium Inorganic materials 0.000 description 24
- 229940083542 sodium Drugs 0.000 description 24
- 235000019864 coconut oil Nutrition 0.000 description 23
- 239000003240 coconut oil Substances 0.000 description 23
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 21
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 16
- 125000002252 acyl group Chemical group 0.000 description 16
- 150000001720 carbohydrates Chemical class 0.000 description 15
- 240000007594 Oryza sativa Species 0.000 description 13
- 235000007164 Oryza sativa Nutrition 0.000 description 13
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 13
- 229920001451 polypropylene glycol Polymers 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- 235000009566 rice Nutrition 0.000 description 13
- 239000002202 Polyethylene glycol Substances 0.000 description 12
- 229960003237 betaine Drugs 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 229920001223 polyethylene glycol Polymers 0.000 description 12
- 239000002253 acid Substances 0.000 description 10
- 238000007796 conventional method Methods 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 9
- 235000019482 Palm oil Nutrition 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 9
- 235000019438 castor oil Nutrition 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 9
- 229920001542 oligosaccharide Polymers 0.000 description 9
- 239000002540 palm oil Substances 0.000 description 9
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 229930195712 glutamate Natural products 0.000 description 8
- 239000004220 glutamic acid Substances 0.000 description 8
- 235000013922 glutamic acid Nutrition 0.000 description 8
- 239000006210 lotion Substances 0.000 description 8
- 150000002482 oligosaccharides Chemical class 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000011591 potassium Substances 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 235000000346 sugar Nutrition 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000006071 cream Substances 0.000 description 6
- 239000003925 fat Substances 0.000 description 6
- 235000019197 fats Nutrition 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 6
- 229960004418 trolamine Drugs 0.000 description 6
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 5
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 240000008067 Cucumis sativus Species 0.000 description 5
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 5
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 5
- 239000001116 FEMA 4028 Substances 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- 108010076876 Keratins Proteins 0.000 description 5
- 102000011782 Keratins Human genes 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 5
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 5
- 229960004853 betadex Drugs 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229960001031 glucose Drugs 0.000 description 5
- 239000008103 glucose Substances 0.000 description 5
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 238000004895 liquid chromatography mass spectrometry Methods 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 244000068988 Glycine max Species 0.000 description 4
- 229920002907 Guar gum Polymers 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- 244000269722 Thea sinensis Species 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
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- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 4
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- 201000006747 infectious mononucleosis Diseases 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- 150000002772 monosaccharides Chemical class 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- LXNHXLLTXMVWPM-UHFFFAOYSA-N pyridoxine Chemical compound CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
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- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 3
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- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 3
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- 240000006891 Artemisia vulgaris Species 0.000 description 3
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- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 3
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- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 3
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- 238000004458 analytical method Methods 0.000 description 3
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- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
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- 239000000047 product Substances 0.000 description 3
- RADKZDMFGJYCBB-UHFFFAOYSA-N pyridoxal hydrochloride Natural products CC1=NC=C(CO)C(C=O)=C1O RADKZDMFGJYCBB-UHFFFAOYSA-N 0.000 description 3
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- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
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- 150000003721 vitamin K derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
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- 239000000230 xanthan gum Substances 0.000 description 1
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- 239000001018 xanthene dye Substances 0.000 description 1
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- 229940012185 zinc palmitate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- 229940118257 zinc undecylenate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 description 1
Description
本発明はイノシトールと糖類とが結合したイノシトール誘導体を含有する皮膚外用剤に関する。さらに詳しくは皮膚を健康に保つ効果を有する皮膚外用剤、化粧料に関する。 The present invention relates to a skin external preparation containing an inositol derivative in which inositol and a saccharide are bound. More specifically, the present invention relates to an external preparation for skin and a cosmetic having an effect of keeping the skin healthy.
イノシトールはフィチンの構成成分の一つであって、米糠にこのフィチンが約10%と非常の多く含まれていることが知られている。そこで従来からイノシトールを含む米糠抽出物は、油脂やビタミンB、ミネラルなどが含まれることと相まって、皮膚に油分、水分、栄養分を与え、潤いや保湿性の向上、弾力性の低下防止効果がある抽出物として皮膚化粧料に添加されてきた。 Inositol is one of the components of phytin, and it is known that rice bran contains about 10% of this phytin. Therefore, rice bran extract containing inositol has been combined with oils, fats, vitamin B, minerals, etc. to give oil, moisture and nutrients to the skin, and has the effect of improving moisture and moisture retention and preventing the decrease in elasticity. It has been added to skin cosmetics as an extract.
これらの効果を高めるために米糠から抽出した多糖類を有効成分とすることを特徴とする化粧料や、米糠から得られた水溶性抗酸化物質を含有していることを特徴とする化粧料などが知られている(例えば、特許文献1および特許文献2参照。)。 Cosmetics characterized by containing a polysaccharide extracted from rice bran as an active ingredient to enhance these effects, and cosmetics characterized by containing a water-soluble antioxidant obtained from rice bran Is known (see, for example, Patent Document 1 and Patent Document 2).
また米糠からの抽出物は独特の臭いがあることから、イノシトールのみを抽出、あるいは化学合成によって得ることで臭いのない成分として添加した化粧料なども知られている(例えば、特許文献3参照。)。 Moreover, since the extract from rice bran has a unique odor, cosmetics added as a component having no odor by extracting only inositol or by chemical synthesis are also known (see, for example, Patent Document 3). ).
更には化粧料のべたつきを感を防止するために、糖アルコールであるイノシトールを含有させた化粧料なども知られている(例えば、特許文献4参照。)。
イノシトールは人間の体内でも合成されるが、必要量を合成出来ないことからビタミンの1種として扱われている化合物であり、また一般に体内に摂取することで肝硬変や脂肪肝の予防、動脈硬化の予防、成長促進作用などの生理活性作用があると言われている。その使用方法としては化粧料以外にも飲料に含有させることなどが知られている(例えば、特許文献5参照。)。
Furthermore, a cosmetic containing inositol, which is a sugar alcohol, is known in order to prevent the cosmetic from feeling sticky (see, for example, Patent Document 4).
Although inositol is synthesized in the human body, it is a compound that is treated as a kind of vitamin because it cannot synthesize the required amount, and ingestion into the body generally prevents cirrhosis, fatty liver, and arteriosclerosis. It is said to have physiological activity such as prevention and growth promotion. As its usage, it is known to contain it in beverages other than cosmetics (see, for example, Patent Document 5).
一方、近年様々な糖修飾化合物が製造出来るようになり、イノシトールにおいてもグルコオリゴ糖化することで生化学試薬や微生物増殖促進物質として利用することなども知られている(例えば、特許文献6参照。)。
イノシトールの供給源として米糠は有用であるが、その独特の臭いがあるためにそのまま皮膚外用剤へと配合すると製品に独特の臭いを残し欠点となる。臭いのマスキングとして他の香料を皮膚外用剤へと添加することも試みられているが、香料の刺激により皮膚へ悪影響を及ぼす可能性や香料の個人の好みによる差が大きいという問題もある。 Rice bran is useful as a source of inositol. However, when it is formulated into a skin external preparation as it is because of its unique smell, it leaves a unique smell in the product and becomes a drawback. Although attempts have been made to add other fragrances to the skin external preparation as masking of odors, there is a problem that there is a possibility that the fragrances may have an adverse effect on the skin and there is a large difference depending on individual preference of the fragrance.
さらに米糠の抽出物はしばしば皮膚外用剤中へ不溶成分が出現して、使用時の肌へのざらつき感をもたらす欠点もある。イノシトールの純粋抽出物や化学合成物は、不溶成分の析出が抑えられてるが、逆に脂質に富む皮膚表面への付着性や親和性の点から、皮膚外用
剤に配合する有効成分として必ずしも有用な形態となっていないという欠点がある。このように米糠抽出物も化学合成物も皮膚外用剤に配合して、その効果を発揮するにはまだ十分ではない。
In addition, rice bran extract often has the disadvantage that an insoluble component appears in the external preparation for skin, resulting in a rough feeling on the skin during use. Inositol pure extracts and chemical compounds are less effective in precipitating insoluble components, but on the other hand, they are always useful as active ingredients in skin preparations due to their adhesion and affinity to lipid-rich skin surfaces. There is a disadvantage that it is not in a form. In this way, rice bran extract and chemical composition are not yet enough to be incorporated into the external preparation for skin and exert their effects.
本発明は、上記のような問題点、欠点を解決するイノシトール誘導体を含む皮膚外用剤及び化粧料を提供することを課題の一つとする。より詳しくは、糖類の結合したイノシトールを含有する皮膚外用剤及び化粧料を提供することを課題の一つとする。 An object of the present invention is to provide a skin external preparation and a cosmetic containing an inositol derivative that solve the above problems and drawbacks. More specifically, an object of the present invention is to provide an external preparation for skin and a cosmetic containing inositol with a saccharide bonded thereto.
本発明では、上記課題を解決すべく鋭意検討を行った結果、イノシトールに糖類を修飾した誘導体は溶解性に優れるので、皮膚外用剤に含有させても不溶成分の析出が抑えられること、また、上記皮膚外用剤は皮膚への付着性や親和性が著しく改善するので、肌の潤い感が著しく向上して皮膚の感触が良好となることを見出し、本発明を完成するに至った。 In the present invention, as a result of diligent studies to solve the above problems, a derivative obtained by modifying a sugar to inositol is excellent in solubility, so that precipitation of insoluble components can be suppressed even if it is included in a skin external preparation, Since the above-mentioned external preparation for skin is remarkably improved in adhesion and affinity to the skin, it has been found that the moist feeling of the skin is remarkably improved and the feel of the skin is improved, and the present invention has been completed.
すなわち、本発明は以下の事項に関する。
(1)イノシトールと糖類とが結合したイノシトール誘導体を含有することを特徴とする皮膚外用剤。
That is, the present invention relates to the following matters.
(1) A skin external preparation characterized by containing an inositol derivative in which inositol and a saccharide are bound.
(2)糖類が、単糖及び/またはオリゴ糖であることを特徴とする上記(1)に記載の皮膚外用剤。
(3)単糖及び/またはオリゴ糖が、グルコースを構成単位として有することを特徴とする上記(2)に記載の皮膚外用剤。
(2) The external preparation for skin according to (1) above, wherein the saccharide is a monosaccharide and / or an oligosaccharide.
(3) The external preparation for skin according to (2) above, wherein the monosaccharide and / or oligosaccharide has glucose as a structural unit.
(4)イノシトール誘導体を構成するイノシトールが、myo−イノシトールであることを特徴とする上記(1)〜(3)のいずれかに記載の皮膚外用剤。
(5)イノシトールと糖類とが結合したイノシトール誘導体の含有量が0.01〜50質量%であることを特徴とする上記(1)〜(4)のいずれかに記載の皮膚外用剤。
(4) The external preparation for skin according to any one of (1) to (3) above, wherein the inositol constituting the inositol derivative is myo-inositol.
(5) The skin external preparation according to any one of (1) to (4) above, wherein the content of the inositol derivative in which inositol and saccharide are bound is 0.01 to 50% by mass.
(6)上記(1)〜(5)のいずれかに記載の皮膚外用剤を含有してなる化粧料。 (6) Cosmetics containing the skin external preparation in any one of said (1)-(5).
皮膚外用剤に対して糖類の結合したイノシトール誘導体を配合することにより、皮膚に滑らかさを伴って十分な潤い感を与え、皮膚を健やかに保つ効果のある優れた皮膚外用剤を提供することが出来る。 By providing an inositol derivative with a saccharide bonded to an external preparation for skin, it is possible to provide an excellent external preparation for skin with an effect of imparting a sufficient moist feeling with smoothness and keeping the skin healthy. I can do it.
本発明に用いられるイノシトール誘導体は、糖類とイノシトールとが結合した化合物である。
本発明で用いられる糖類については特に制限はなく、例えば、マンニトール、ソルビトール、キシリトール、マルチトール、エリスリトール、ペンタエリスリトール、グルコース、ショ糖、果糖、乳糖、マルトース、キシロース、トレハロース、α−シクロデキストリン、β−シクロデキストリン、γ−シクロデキストリンなどを用いることができる。
The inositol derivative used in the present invention is a compound in which a saccharide and inositol are bound.
The saccharide used in the present invention is not particularly limited. For example, mannitol, sorbitol, xylitol, maltitol, erythritol, pentaerythritol, glucose, sucrose, fructose, lactose, maltose, xylose, trehalose, α-cyclodextrin, β -Cyclodextrin, gamma-cyclodextrin and the like can be used.
これら糖類の中では、単糖類、オリゴ糖およびこれらの混合物であることが好ましく、特にグルコース及び/またはグルコースを構成単位として有するオリゴ糖であることが好ましい。 Among these saccharides, monosaccharides, oligosaccharides and mixtures thereof are preferable, and in particular, oligosaccharides having glucose and / or glucose as a constituent unit are preferable.
本発明で用いられるイノシトールとは、C6H6(OH)6で表される環状六価アルコール
であり、9つの立体異性体が存在する。本発明にはいずれの異性体を用いてもよいが、こ
れらイノシトールの異性体の中では、特にmyo−イノシトールといわれる天然型のものが好ましい。また、本発明に用いるイノシトールは、米糠から抽出する方法、化学合成法、発酵法などにより合成することができる。
Inositol used in the present invention is a cyclic hexahydric alcohol represented by C 6 H 6 (OH) 6 , and there are nine stereoisomers. Any isomer may be used in the present invention, but among these isomers of inositol, a natural type called myo-inositol is particularly preferable. Inositol used in the present invention can be synthesized by a method of extracting from rice bran, a chemical synthesis method, a fermentation method or the like.
本発明で用いられるイノシトール誘導体は、イノシトールの水酸基に対して単糖あるいはオリゴ糖などの糖類が結合した化合物である。糖類は、6つあるイノシトールの水酸基にいずれか一つまたは複数に結合していても構わないが、通常、一つに結合している化合物が用いられる。また、本発明に用いるイノシトール誘導体は、一つの糖類に対してイノシトールが複数個結合していてもよい。 The inositol derivative used in the present invention is a compound in which a saccharide such as a monosaccharide or an oligosaccharide is bound to the hydroxyl group of inositol. The saccharide may be bonded to any one or more of the six inositol hydroxyl groups, but usually a compound bonded to one is used. In the inositol derivative used in the present invention, a plurality of inositols may be bonded to one saccharide.
これらイノシトール誘導体の合成方法としては、特に制限はなく、従来知られている方法が適用できる。例えば、イノシトールとオリゴ糖の一種であるシクロデキストリンをシクロデキストリングルカノトランスフェラーゼの存在下に反応させてイノシトール残基が結合した糖あるいはオリゴ糖を得る方法(特開昭63−196596公報)、グルコシル亜リン酸エステルを糖供与体として用いてグルコシル体を得る方法(特開平6−298783公報)などが例示できる。 The method for synthesizing these inositol derivatives is not particularly limited, and conventionally known methods can be applied. For example, a method of reacting inositol and cyclodextrin, which is a kind of oligosaccharide, in the presence of cyclodextrin glucanotransferase to obtain a sugar or oligosaccharide having an inositol residue bound thereto (JP-A 63-196596), Examples thereof include a method for obtaining a glucosyl derivative using a phosphate ester as a sugar donor (Japanese Patent Laid-Open No. Hei 6-298783).
イノシトールと糖類とが結合したイノシトール誘導体の皮膚外用剤への配合方法としては、固体、粉体、半固体として混合して皮膚外用剤を製造する方法、水溶液として混合して皮膚外用剤を製造する方法、アルコール類、あるいは、適当な溶媒の溶液として混合して皮膚外用剤を製造する方法、その他に公知の方法で混合あるいは添加して皮膚外用剤を添加する方法などが挙げられるが、特にこれに限定されるものではない。 The inositol derivative in which inositol and saccharide are bound to the skin external preparation is mixed as a solid, powder or semi-solid to produce a skin external preparation, and mixed as an aqueous solution to produce a skin external preparation. Methods, alcohols, or a method of producing a skin external preparation by mixing as a solution of an appropriate solvent, and other methods including mixing or adding by a known method and adding a skin external preparation, etc. It is not limited to.
本発明で用いられるイノシトール誘導体は白色の粉末状として単離できるが、製造工程中で得られる水溶液などをそのまま皮膚外用剤に配合することも出来る。
イノシトールと糖類とが結合したイノシトール誘導体の配合量は、皮膚外用剤、化粧料の形態として配合可能な量であれば特に制限はないが、0.01質量%〜50質量%配合することが好ましく、さらに好ましくは0.1質量%〜10質量%である。前記イノシトール誘導体の配合量が上記範囲内にあると、皮膚での保湿感などの感触が十分であり、粘度が適切であるので皮膚用外用剤本来の機能が十分に発揮される。
Although the inositol derivative used in the present invention can be isolated as a white powder, an aqueous solution obtained in the production process can be directly incorporated into the external preparation for skin.
The amount of the inositol derivative in which inositol and saccharide are combined is not particularly limited as long as it is an amount that can be blended in the form of a topical skin preparation or cosmetic, but is preferably blended in an amount of 0.01% by mass to 50% by mass. More preferably, it is 0.1 mass%-10 mass%. When the blended amount of the inositol derivative is within the above range, the skin feels moisturized and the like is sufficient, and the viscosity is appropriate.
本発明でいう皮膚外用剤は、特に限定されるものではないが、直接皮膚に触れる化粧料、洗浄剤、入浴剤、石鹸などを含み、化粧料として使用することが特に好ましい。
これら皮膚外用剤には、例えば、スキンミルク、スキンクリーム、ファンデーションクリーム、マッサージクリーム、クレンジングクリーム、シェービングクリーム、クレンジングフォーム、化粧水、ローション、パック、口紅、頬紅、アイシャドー、マニキュア、石鹸、ボディーシャンプー、ハンドソープ、シャンプー、リンス、ヘアトニック、トリートメント、ヘアクリーム、ヘアスプレー、育毛剤、養毛剤、染毛剤、整髪料、脱毛剤、歯磨、うがい剤、パーマネントウェーブ剤、軟膏、入浴剤、等が広義には含まれ、使用時に皮膚に接触させるものなら種類を問わない。また使用者の性別、老若を問わない。
The external preparation for skin referred to in the present invention is not particularly limited, but includes cosmetics, cleaning agents, bathing agents, soaps and the like that directly touch the skin, and is particularly preferably used as cosmetics.
These skin external preparations include, for example, skin milk, skin cream, foundation cream, massage cream, cleansing cream, shaving cream, cleansing foam, lotion, lotion, pack, lipstick, blusher, eye shadow, nail polish, soap, body shampoo. , Hand soap, shampoo, rinse, hair tonic, treatment, hair cream, hair spray, hair restorer, hair nourishing agent, hair dye, hair conditioner, hair remover, toothpaste, mouthwash, permanent wave agent, ointment, bath preparation, etc. It does not matter if it is included in a broad sense and is in contact with the skin during use. Regardless of the gender and age of the user.
本発明に係る皮膚外用剤の形状は、固体、半固体、液体、気体のいずれであってもよい。また、本発明に係る皮膚外用剤の形態は特に制限はされないが、粉体、顆粒、錠形、ゲル状、泡状などの形態が挙げられる。 The shape of the external preparation for skin according to the present invention may be any of solid, semi-solid, liquid and gas. The form of the external preparation for skin according to the present invention is not particularly limited, and examples thereof include powders, granules, tablets, gels, and foams.
本発明の皮膚外用剤は、糖類の結合したイノシトール誘導体以外の成分として、必要に応じてこの発明の効果を損なわない範囲内で一般に皮膚外用剤に用いられる成分を配合することができる。 In the external preparation for skin of the present invention, as a component other than the inositol derivative to which a saccharide is bound, if necessary, a component generally used for an external preparation for skin can be blended within a range not impairing the effects of the present invention.
このような成分としては、例えば、
オゾケライト、α−オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、スクワレン、スクワラン、合成スクワラン、植物性スクワラン、セレシン、パラフィン、ポリエチレン末、ポリブテン、マイクロクリスタリンワックス、流動イソパラフィン、流動パラフィン、ミネラル油、ワセリン、等の炭化水素類;
ホホバ油、カルナウバロウ、キャンデリラロウ、コメヌカロウ、セラック、ラノリン、ミンク皮脂ロウ、鯨ロウ、サトウキビロウ、マッコウクジラ油、ミツロウ、モンタンロウ等の天然ロウ類、アボガド油、アルモンド油、オリーブ油、エクストラバージンオリーブ油、ゴマ油、コメヌカ油、米油、コメ胚芽油、コーン油、サフラワー油、大豆油、トウモロコシ油、ナタネ油、パーシック油、パーム核油、パーム油、ヒマシ油、ヒマワリ油、ハイオレイックヒマワリ油、グレープシード油、綿実油、ヤシ油、水添ヤシ油、牛脂、硬化油、馬油、ミンク油、卵黄油、卵黄脂肪油、ローズヒップ油、ククイナッツ油、月見草油、小麦胚芽油、落花生油、ツバキ油、サザンカ油、カカオ脂、モクロウ、牛骨脂、牛脚油、豚脂、馬脂、羊脂、シアバター、マカデミアナッツ油、メドウホーム油等の天然油脂類;
ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸、リノール酸、リノレン酸、γ−リノレン酸、イソステアリン酸、12−ヒドロキシステアリン酸、ウンデシレン酸、ヤシ油脂肪酸等の脂肪酸類;
イソステアリルアルコール、オクチルドデカノール、ヘキシルデカノール、コレステロール、フィトステロール、ラウリルアルコール、ミリスチルアルコール、セタノール、ステアリルアルコール、オレイルアルコール、ベヘニルアルコール、セトステアリルアルコール等の高級アルコール類;
バチルアルコール、キミルアルコール、セラキルアルコール、イソステアリルグリセリルエーテル等のアルキルグリセリルエーテル類;
ミリスチン酸イソプロピル、ミリスチン酸ブチル、パルミチン酸イソプロピル、ステアリン酸エチル、ステアリン酸ブチル、オレイン酸エチル、リノール酸エチル、リノール酸イソプロピル、カプリル酸セチル、ラウリン酸ヘキシル、ミリスチン酸イソオクチル、ミリスチン酸デシル、ミリスチン酸ミリスチル、ミリスチン酸セチル、ミリスチン酸オクタデシル、パルミチン酸セチル、ステアリン酸ステアリル、オレイン酸デシル、オレイン酸オレイル、リシノール酸セチル、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸イソセチル、ミリスチン酸イソステアリル、ミリスチン酸オクチルドデシル、パルミチン酸2-エチルヘキシル、パルミチン酸イソセチル、パルミチン酸イソス
テアリル、ステアリン酸2-エチルヘキシル、ステアリン酸イソセチル、オレイン酸イソ
デシル、オレイン酸オクチルドデシル、リシノール酸オクチルドデシル、イソステアリン酸エチル、イソステアリン酸イソプロピル、2-エチルヘキサン酸セチル、2-エチルヘキサン酸セトステアリル、2-エチルヘキサン酸ステアリル、イソステアリン酸ヘキシル、
ジオクタン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジ(カプリル・カプリン酸)プロピレングリコール、ジカプリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、トリカプリル酸グリセリル、トリ2-エ
チルヘキサン酸グリセリル、トリ(カプリル・カプリン酸) グリセリル、トリ(カプリル酸・カプリン酸・ステアリン酸) グリセリル、トリウンデシル酸グリセリル、トリイソパルミチン酸グリセリル、トリイソステアリン酸グリセリル、トリ2-エチルヘキサン酸トリ
メチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ2-エチル
ヘキサン酸ペンタエリスリチル、テトラミリスチン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリスリチル、テトライソステアリン酸ジグリセリル、ネオペンタン酸オクチルドデシル、オクタン酸イソセチル、オクタン酸イソステアリル、イソぺラルゴン酸2-エチルヘキシル、ジメチルオクタン酸ヘキシルデシル、ジメチルオクタン酸オクチ
ルドデシル、イソパルミチン酸2-エチルヘキシル、イソステアリン酸イソセチル、イソ
ステアリン酸イソステアリル、イソステアリン酸オクチルドデシル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸オクチルドデシル、クエン酸トリエチル、クエン酸アセチ
ルトリエチル、クエン酸アセチルトリブチル、クエン酸トリオクチル、クエン酸トリイソセチル、クエン酸トリオクチルドデシル、リンゴ酸ジイソステアリル、ヒドロキシステアリン酸2-エチルヘキシル、コハク酸ジ2-エチルヘキシル、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、アジピン酸ジオクチル、アジピン酸ジヘプチルウンデシル、セバシン酸ジエチル、セバシン酸ジイソプロピル、セバシン酸ジオクチル、ステアリン酸コレステリル、イソステアリン酸コレステリル、ヒドロキシステアリン酸コレステリル、オレイン酸コレステリル、オレイン酸ジヒドロコレステリル、イソステアリン酸フィトステリル、オレイン酸フィトステリル、12−ステアロイルヒドロキシステアリン酸イソセチル、12−ステアロイルヒドロキシステアリン酸ステアリル、12−ステアロイルヒドロキシステアリン酸イソステアリル、酢酸ポリオキシエチレン(3)ポリオキシプロピレン(1)セチルエーテル、酢酸ポリオキシエチレン(3)ポリオキシプロピレン(1)イソセチルエーテル、イソノナン酸イソノニル、イソノナン酸オクチル、イソノナン酸トリデシル、イソノナン酸イソトリデシル、等のエステル類;
メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、メチルシクロポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、テトラデカメチルヘキサシロキサン、高重合メチルポリシロキサン、ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン・メチル(ポリオキシプロピレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポリオキシプロピレン)シロキサン共重合体、ジメチルシロキサン・メチルセチルオキシシロキサン共重合体、ジメチルシロキサン・メチルステアロキシシロキサン共重合体、ポリエーテル変性シリコーン、アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン等のシリコーン油類;
エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、ペンタンジオール、グリセリン、ジグリセリン、ポリグリセリン、イソプレングリコール、1,3−ブチレングリコール、3−メチル−1,3−ブタンジオール、1,3−ブタンジオール、1,2−ペンタンジオール、1,2−ヘキサンジオール、等の多価アルコール類;
マンニトール、ソルビトール、キシリトール、マルチトール、エリスリトール、ペンタエリスリトール、グルコース、ショ糖、果糖、乳糖、マルトース、キシロース、トレハロース、等の糖類;
アルギン酸ナトリウム、カラギーナン、寒天、ファーセレラン、グアーガム、クインスシード、コンニャクマンナン、タマリンドガム、タラガム、デキストリン、デンプン、ローカストビーンガム、アラビアガム、ガッティガム、カラヤガム、トラガカントガム、アラビノガラクタン、ペクチン、マルメロ、キトサン、デンプン、カードラン、キサンタンガム、ジェランガム、シクロデキストリン、デキストラン、プルラン、微結晶セルロース、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロース、カルボキシデンプン、カチオン化セルロース、デンプンリン酸エステル、カチオン化グアーガム、カルボキシメチル・ヒドロキシプロピル化グアーガム、ヒドロキシプロピル化グアーガム、アルブミン、カゼイン、ゼラチン、ポリアクリル酸ナトリウム、ポリアクリル酸アミド、カルボキシビニルポリマー、ポリエチレンイミン、高重合ポリエチレングリコール、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルエーテル、ポリアクリルアミド、アクリル酸共重合体、メタクリル酸共重合体、マレイン酸共重合体、ビニルピリジン共重合体、エチレン/アクリル酸共重合体、ビニルピロリドン系ポリマー、ビニル
アルコール/ビニルピロリドン共重合体、窒素置換アクリルアミド系ポリマー、アミノ変
性シリコーン、カチオン化ポリマー、ジメチルアクリルアンモニウム系ポリマー、アクリル酸系アニオンポリマー、メタクリル酸系アニオンポリマー、変性シリコーン、アクリル
酸メタクリル酸アルキル(C10〜30)共重合体、ポリオキシエチレン/ポリオキシプロピ
レン共重合体、等の高分子類;
エタノール、イソプロピルアルコール、1−ブタノール、2-ブタノール、ベンジルア
ルコール、等のアルコール類;
ヤシ油脂肪酸カリウム、ヤシ油脂肪酸ナトリウム、ヤシ油脂肪酸トリエタノールアミン、ラウリン酸カリウム、ラウリン酸ナトリウム、ラウリン酸トリエタノールアミン、ミリスチン酸カリウム、ミリスチン酸ナトリウム、ミリスチン酸イソプロパノールアミン、パルミチン酸カリウム、パルミチン酸ナトリウム、パルミチン酸イソプロパノールアミン、ステアリン酸カリウム、ステアリン酸ナトリウム、ステアリン酸トリエタノールアミン、オレイン酸カリウム、オレイン酸ナトリウム、ヒマシ油脂肪酸ナトリウム、ウンデシレン酸亜鉛、ラウリン酸亜鉛、ミリスチン酸亜鉛、ミリスチン酸マグネシウム、パルミチン酸亜鉛、ステアリン酸亜鉛、ステアリン酸カルシウム、ステアリン酸マグネシウム、ステアリン酸アルミニウム、ミリスチン酸カルシウム、ミリスチン酸マグネシウム、ジミリスチン酸アルミニウム、イソステアリン酸アルミニウム、ポリオキシエチレンラウリルエーテル酢酸、ポリオキシエチレンラウリルエーテル酢酸ナトリウム、ポリオキシエチレントリデシルエーテル酢酸、ポリオキシエチレントリデシルエーテル酢酸ナトリウム、ステアロイル乳酸ナトリウム、イソステアロイル乳酸ナトリウム、ラウロイルサルコシンナトリウム、ヤシ油脂肪酸サルコシン、ヤシ油脂肪酸サルコシンナトリウム、ヤシ油脂肪酸サルコシントリエタノールアミン、ラウロイルサルコシン、ラウロイルサルコシンカリウム、ラウロイルサルコシントリエタノールアミン、オレオイルサルコシン、ミリストイルサルコシンナトリウム、ステアロイルグルタミン酸ナトリウム、ヤシ油脂肪酸アシルグルタミン酸、ヤシ油脂肪酸アシルグルタミン酸カリウム、ヤシ油脂肪酸アシルグルタミン酸ナトリウム、ヤシ油脂肪酸アシルグルタミン酸トリエタノールアミン、ラウロイルアシルグルタミン酸、ラウロイルアシルグルタミン酸カリウム、ラウロイルアシルグルタミン酸ナトリウム、ラウロイルアシルグルタミン酸トリエタノールアミン、ミリストイルアシルグルタミン酸、ミリストイルアシルグルタミン酸カリウム、ミリストイルアシルグルタミン酸ナトリウム、ステアロイルアシルグルタミン酸、ステアロイルアシルグルタミン酸カリウム、ステアロイルアシルグルタミン酸二ナトリウム、硬化牛脂脂肪酸アシルグルタミン酸ナトリウム、ヤシ油脂肪酸・硬化牛脂脂肪酸アシルグルタミン酸ナトリウム、ヤシ油脂肪酸メチルアラニンナトリウム、ラウロイルメチルアラニン、ラウロイルメチルアラニンナトリウム、ラウロイルメチルアラニントリエタノールアミン、ミリストイルメチルアラニンナトリウム、ラウロイルメチルタウリンナトリウム、ヤシ油脂肪酸メチルタウリンカリウム、ヤシ油脂肪酸メチルタウリンナトリウム、ヤシ油脂肪酸メチルタウリンマグネシウム、ミリストイルメチルタウリンナトリウム、パルミトイルメチルタウリンナトリウム、ステアロイルメチルタウリンナトリウム、オレオイルメチルタウリンナトリウム、アルカンスルホン酸ナトリウム、テトラデセンスルホン酸ナトリウム、スルホコハク酸ジオクチルナトリウム、スルホコハク酸ラウリル二ナトリウム、ヤシ油脂肪酸エチルエステルスルホン酸ナトリウム、ラウリル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン、セチル硫酸ナトリウム、アルキル(11,13,15)硫酸トリエタノールアミン、アルキル(12,13)硫酸ナトリウム、アルキル(12,13)硫酸トリエタノールアミン、アルキル(12,14,16)硫酸アンモニウム、アルキル(12〜13)硫酸ジエタノールアミン、アルキル(12〜14)硫酸トリエタノールアミン、アルキル(12〜15)硫酸トリエタノールアミン、ヤシ油アルキル硫酸マグネシウム・トリエタノールアミン、ラウリル硫酸アンモニウム、ラウリル硫酸カリウム、ラウリル硫酸マグネシウム、ラウリル硫酸モノエタノールアミン、ラウリル硫酸ジエタノールアミン、ミリスチル硫酸ナトリウム、ステアリル硫酸ナトリウム、オレイル硫酸ナトリウム、オレイル硫酸トリエタノールアミン、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン、ポリオキシエチレン(1)アルキル(11,13,15)エーテル硫酸ナトリウム、ポリオキシエチレン(1)アルキル(11,13,15)エーテル硫酸トリエタノールアミン、ポリオキシエチレン(3)アルキル(11〜15)エーテル硫酸ナ
トリウム、ポリオキシエチレン(2)アルキル(12,13)エーテル硫酸ナトリウム、ポリオキシエチレン(3)アルキル(12〜14)エーテル硫酸ナトリウム、ポリオキシエチレン(3)アルキル(12〜15)エーテル硫酸ナトリウム、ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム、ポリオキシエチレン(3)ミリスチルエーテル硫酸ナトリウム、高級脂肪酸アルカノールアミド硫酸エステルナトリウム、ラウリルリン酸、ラウリルリン酸ナトリウム、セチルリン酸カリウム、セチルリン酸ジエタノールアミン、ポリオキシエチレンオレイルエーテルリン酸、ポリオキシエチレンラウリルエーテルリン酸、ポリオキシエチレンラウリルエーテルリン酸ナトリウム、ポリオキシエチレンセチルエーテルリン酸、ポリオキシエチレンセチルエーテルリン酸ナトリウム、ポリオキシエチレンステアリルエーテルリン酸、ポリオキシエチレンオレイルエーテルリン酸、ポリオキシエチレンオレイルエーテルリン酸ナトリウム、ポリオキシエチレンアルキルフェニルエーテルリン酸、ポリオキシエチレンアルキルフェニルエーテルリン酸ナトリウム、ポリオキシエチレンアルキルフェニルエーテルリン酸トリエタノールアミン、ポリオキシエチレンオクチルエーテルリン酸、ポリオキシエチレン(10)アルキル(12,13)エーテルリン酸、ポリオキシエチレンアルキル(12〜15)エーテルリン酸、ポリオキシエチレンアルキル(12〜16)エーテルリン酸、ポリオキシエチレンラウリルエーテルリン酸トリエタノールアミン、ポリオキシエチレンオレイルエーテルリン酸ジエタノールアミン、等の陰イオン界面活性剤;
ジオクチルアミン、ジメチルステアリルアミン、トリラウリルアミン、ステアリン酸ジエチルアミノエチルアミド、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、セチルトリメチルアンモニウムサッカリン、塩化ステアリルトリメチルアンモニウム、塩化アルキル(20〜22)トリメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、塩化アルキル(16,18)トリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、ステアリルトリメチルアンモニウムサッカリン、塩化アルキル(28)トリメチルアンモニウム、塩化ジ(ポリオキシエチレン)オレイルメチルアンモニウム(2EO)、塩化ジポリオキシエチレンステアリルメチルアンモニウム、塩化ポリオキシエチレン(1)ポリオキシプロピレン(
25)ジエチルメチルアンモニウム、塩化トリ(ポリオキシエチレン)ステアリルアンモ
ニウム(5EO)、塩化ジステアリルジメチルアンモニウム、塩化ジアルキル(12〜15)ジメチルアンモニウム、塩化ジアルキル(12〜18)ジメチルアンモニウム、塩化ジアルキル(14〜18)ジメチルアンモニウム、塩化ジココイルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化イソステアリルラウリルジメチルアンモニウム、塩化ベンザルコニウム、塩化ミリスチルジメチルベンジルアンモニウム、塩化ラウリルジメチル(エチルベンジル)アンモニウム、塩化ステアリルジメチルベンジルアンモニウム、塩化ラウリルピリジニウム、塩化セチルピリジニウム、塩化ラウロイルコラミノホルミルメチルピリジニウム、塩化ステアロイルコラミノホルミルメチルピリジニウム、臭化アルキルイソキノリウム、塩化メチルベンゼトニウム、塩化ベンゼトニウム、等の陽イオン界面活性剤;
2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、塩酸アルキルジアミノエチルグリシン、ラウリルジアミノエチルグリシンナトリウム、ウンデシルヒドロキシエチルイミダゾリイウムベタインナトリウム、ウンデシル−N−カルボキシメチルイミダゾリイウムベタイン、ヤシ油脂肪酸アシル−N−カルボキシエチル−N−ヒドロキシエチルエチレンジアミン二ナトリウム、ヤシ油脂肪酸アシル−N−カルボキシエトキシエチル−N−カルボキシエチルエチレンジアミン二ナトリウム、ヤシ油脂肪酸アシル−N−カルボキシメトキシエチル−N−カルボキシメチルエチレンジアミン二ナトリウム、ラウリルアミノプロピオン酸ナトリウム、ラウリルアミノジプロピオン酸ナトリウム、ラウリルアミノプロピオン酸トリエタノールアミン、パーム油脂肪酸アシル−N−カルボキシエチル−N−ヒドロキシエチルエチレンジアミンナトリウム、ラウリルジメチルアミノ酢酸ベタイン、ヤシ油アルキルジメチルアミノ酢酸ベタイン、ステアリルジメチルアミノ酢酸ベタイン、ステアリルジメチルベタインナトリウム、ヤシ油脂肪酸ア
ミドプロピルベタイン、パーム油脂肪酸アミドプロピルベタイン、ラウリン酸アミドプロピル酢酸ベタイン、リシノレイン酸アミドプロピルベタイン、ステアリルジヒドロキシエチルベタイン、ラウリルヒドロキシスルホベタイン、等の両性界面活性剤;
ポリオキシエチレン(10)アルキル(12,13)エーテル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレン(3,7,12)アルキル(12〜14)エーテル、ポリオキシエチレントリデシルエーテル、ポリオキシエチレンミリスチルエーテル、ポリオキシエチレン−sec−アルキル(14)エーテル、ポリオキシエチレンイソセチルエーテル、ポリオキシエチレンセトステアリルエーテル、ポリオキシエチレン(2,10,20)イソステアリルエーテル、ポリオキシエチレンオレイルセチルエーテル、ポリオキシエチレン(20)アラキルエーテル、ポリオキシエチレンオクチルドデシルエーテル、ポリオキシエチレンベヘニルエーテル、ポリオキシエチレンオクチルフェニルエーテル、ポリオキシエチレンノニルフェニルエーテル、ポリオキシエチレンジノニルフェニルエーテル、ポリオキシエチレン(1)ポリオキシプロピレン(1,2,4,8)セチルエーテル、ポリオキシエチレン(5)ポリオキシプロピレン(1,2,4,8)セチルエーテル、ポリオキシエチレン(10)ポリオキシプロピレン(1,2,4,8)セチルエーテル、ポリオキシエチレン(20)ポリオキシプロピレン(1,2,4,8)セチルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシエチレン(3)ポリオキシプロピレン(34)ステアリルエーテル、ポリオキシエチレン(4)ポリオキシプロピレン(30)ステアリルエーテル、ポリオキシエチレン(34)ポリオキシプロピレン(23)ステアリルエーテル、ポリオキシエチレンポリオキシプロピレンセチルエーテル、ポリオキシエチレンポリオキシプロピレンデシルテトラデシルエーテル、モノラウリン酸ポリエチレングリコール、モノステアリン酸エチレングリコール、モノステアリン酸ポリエチレングリコール、モノオレイン酸ポリエチレングリコール、エチレングリコール脂肪酸エステル、自己乳化型モノステアリン酸エチレングリコール、ラウリン酸ジエチレングリコール、ミリスチン酸ポリエチレングリコール、パルミチン酸ポリエチレングリコール、ステアリン酸ジエチレングリコール、自己乳化型モノステアリン酸ポリエチレングリコール(2)、イソステアリン酸ポリエチレングリコール、ジオクタン酸エチレングリコール、ジラウリン酸ジエチレングリコール、ジラウリン酸ポリエチレングリコール、ジパルミチン酸ポリエチレングリコール(150)、ジステアリン酸エチレングリコール、ジステアリン酸ジエチレングリコール、ジステアリン酸ポリエチレングリコール、ジオレイン酸エチレングリコール、ジオレイン酸ポリエチレングリコール、ジリシノレイン酸ポリエチレングリコール、モノラウリン酸ポリオキシエチレン(20)ソルビタン、モノパルミチン酸ポリオキシエチレン(20)ソルビタン、モノステアリン酸ポリオキシエチレン(6)ソルビタン、モノステアリン酸ポリオキシエチレン(20)ソルビタン、トリステアリン酸ポリオキシエチレン(20)ソルビタン、モノオレイン酸ポリオキシエチレン(6)ソルビタン、モノオレイン酸ポリオキシエチレン(20)ソルビタン、トリオレイン酸ポリオキシエチレン(20)ソルビタン、ポリオキシエチレン(20)ヤシ油脂肪酸ソルビタン、モノラウリン酸ポリオキシエチレン(10〜80)ソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、イソステアリン酸ポリオキシエチレン(20)ソルビタン、トリステアリン酸ポリオキシエチレン(150)ソルビタン、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン(10)硬化ヒマシ油、ポリオキシエチレン(20)硬化ヒマシ油、ポリオキシエチレン(40)硬化ヒマシ油、ポリオキシエチレン(50)硬化ヒマシ油、ポリオキシエチレン(60)硬化ヒマシ油、親油型モノステアリン酸グリセリン、親油型モノオレイン酸グリセリン、自己乳化型モノステアリン酸グリセリン、ヤシ油脂肪酸グリセリル、ラウリン酸グリセリン、ミリスチン酸グリセリル、イソステアリン酸グリセリル、リシノレイン酸グリセリル、モノヒドロキシステアリン酸グリセリル、オレイン酸グリセリン、リノール酸グリセリル、エルカ酸グリセリル、ベヘン酸グリセリル、小麦胚芽油脂肪酸グリセリド、サフラワー油脂肪酸グリセリル、水素添加大豆脂肪酸グリセリル、
飽和脂肪酸グリセリド、綿実油脂肪酸グリセリル、モノイソステアリン酸モノミリスチン酸グリセリル、モノ牛脂肪酸グリセリド、モノラノリン脂肪酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセリル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリル、モノラウリン酸ソルビタン、モノパルミチン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノオレイン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、トリステアリン酸ソルビタン、トリオレイン酸ソルビタン、ヤシ油脂肪酸ソルビタン、イソステアリン酸ソルビタン、セスキイソステアリン酸ソルビタン、ジステアリン酸ソルビタン、イソパルミチン酸ジグリセリル、モノラウリン酸ポリ(4〜10)グリセリル、モノミリスチン酸ポリ(10)グリセリル、モノステアリン酸ポリ(2〜10)グリセリル、モノイソステアリン酸ポリ(2〜10)グリセリル、モノオレイン酸ポリ(2〜10)グリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ(2〜10)グリセリル、ジステアリン酸ポリ(6〜10)グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ(10)グリセリル、トリオレイン酸ポリ(10)グリセリル、テトライソステアリン酸ポリ(2)グリセリル、ペンタステアリン酸デカグリセリル、ペンタオレイン酸ポリ(6〜10)グリセリル、ヘプタステアリン酸ポリ(10)グリセリル、デカステアリン酸デカグリセリル、デカオレイン酸ポリ(10)グリセリル、縮合リシノレイン酸ポリ(6)グリセリル、ショ糖脂肪酸エステル、ヤシ油脂肪酸ショ糖エステル、アルキルグルコシド、ヤシ油アルキルジメチルアミンオキシド、ラウリルジメチルアミンオキシド、ジヒドロキシエチルラウリルジメチルアミンオキシド、ステアリルジメチルアミンオキシド、オレイルジメチルアミンオキシド、ポリオキシエチレンヤシ油アルキルジメチルアミンオキシド、等の非イオン界面活性剤;
サポニン、レシチン、大豆リン脂質、水素添加大豆リン脂質、大豆リゾリン脂質、水素添加大豆リゾリン脂質、卵黄レシチン、水素添加卵黄リゾホスファチジルコリン、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルセリン、スフィンゴリン脂質、スフィンゴミエリン、ガングリオシド、胆汁酸、コール酸、デオキシコール酸、コール酸ナトリウム、デオキシコール酸ナトリウム、スピクリスポール酸、ラムノリピッド、トレハロースリピッド、ソホロリピッド、マンノシルエリスリトールリピッド、等の天然系界面活性剤;
パラアミノ安息香酸、パラアミノ安息香酸エチル、パラアミノ安息香酸グリセリル、パラジメチルアミノ安息香酸アミル,パラジメチルアミノ安息香酸2−エチルヘキシル等のパラアミノ安息香酸誘導体、ケイ皮酸ベンジル、ジパラメトキシケイ皮酸モノ−2−エチルヘキサン酸グリセリル、2,4−ジイソプロピルケイ皮酸メチル、2,4−ジイソプロピルケイ皮酸エチル、パラメトキシケイ皮酸カリウム、パラメトキシケイ皮酸ナトリウム、パラメトキシケイ皮酸イソプロピル、パラメトキシケイ皮酸2−エチルヘキシル、パラメトキシケイ皮酸2−エトキシエチル、パラエトキシケイ皮酸エチル等のケイ皮酸誘導体、ウロカニン酸、ウロカニン酸エチル等のウロカニン酸誘導体、2,4−ジヒドロキシベンゾフェノン、2,2’,4,4’−テトラヒドロキシベンゾフェノン、2−ヒドロキシ−4−メトキシ−5−スルホベンゾフェノンナトリウム、2−ヒドロキシ−4−メトキシベンゾフェノン−5−スルホン酸、2−ヒドロキシ−4−メトキシベンゾフェノン、2,2’−ジヒドロキシ−4,4’−ジメトキシベンゾフェノン、2,2’−ジヒドロキシ−4,4’−ジメトキシ−5−スルホベンゾフェノンナトリウム等のベンゾフェノン誘導体、サリチル酸エチレングリコール、サリチル酸−2−エチルヘキシル、サリチル酸フェニル、サリチル酸ベンジル、サリチル酸p−tert−ブチルフェニル、サリチル酸ホモメンチル、サリチル酸−3,3,5−トリメチルシクロヘキシル等のサリチル酸誘導体、2−(2’−ヒドロキシ−5’−メトキシフェニル)ベンゾトリアゾール、4−tert−ブチル−4’−メトキシベンゾイルメタン、等の紫外線吸収剤;
カオリン、無水ケイ酸、ケイ酸アルミニウムマグネシウム、セリサイト、タルク、窒化ホウ素、マイカ、モンモリロナイト、麻セルロース末、小麦デンプン、シルク末、トウモロコシデンプン、ニトロ系色素、アゾ系色素、ニトロソ系色素、トリフェニルメタン系色
素、キサンテン系色素、キノリン系色素、アントラキノン系色素、インジゴ系色素、ピレン系色素、フタロシアニン系色素、フラボノイド、キノン、ポルフィリン、水溶性アナトー、イカスミ末、カラメル、グアイアズレン、クチナシ青、クチナシ黄、コチニール、シコニン、銅クロロフィリンナトリウム、パプリカ色素、ベニバナ赤、ベニバナ黄、ラッカイン酸、リボフラビン酪酸エステル等の天然色素、カーボンブラック、黄酸化鉄、黒酸化鉄、ベンガラ、コンジョウ、群青、酸化亜鉛、酸化クロム、酸化チタン、黒酸化チタン、酸化ジルコニウム、水酸化クロム、アルミナ、酸化マグネシウム、硫酸バリウム、水酸化アルミニウム、炭酸カルシウム、チタン酸リチウムコバルト、マンガンバイオレット、パール顔料、等の粉体類および色材類;
アシタバエキス、アセンヤクエキス、アボガドエキス、アマチャエキス、アマチャズルエキス、アルテアエキス、アルニカエキス、油溶性アルニカエキス、アルモンドエキス、アロエエキス、アンソッコウエキス、イチョウエキス、イラクサエキス、イリス根エキス、ウイキョウエキス、ウコンエキス、エイジツエキス、エチナシ葉エキス、オウゴンエキス、オウバクエキス、オウレンエキス、オオムギエキス、オクラエキス、オトギリソウエキス、油溶性オトギリソウエキス、オドリコソウエキス、油溶性オドリコソウエキス、オノニスエキス、オランダカラシエキス、オレンジエキス、オレンジフラワー水、海藻エキス、カキタンニン、カッコンエキス、カノコソウエキス、ガマエキス、カモミラエキス、油溶性カモミラエキス、カモミラ水、カラスムギエキス、カロットエキス、油溶性カロットエキス、カロット油、カワラヨモギエキス、カンゾウエキス、カンゾウ抽出末、カンゾウフラボノイド、カンタリスチンキ、キイチゴエキス、キウイエキス、キナエキス、キューカンバーエキス、キョウニンエキス、クインスシードエキス、クチナシエキス、クマザサエキス、クララエキス、クルミ殻エキス、グレープフルーツエキス、クレマティスエキス、、黒砂糖エキス、クロレラエキス、クワエキス、ケイヒエキス、ゲンチアナエキス、ゲンノショウコエキス、紅茶エキス、コウホネエキス、ゴボウエキス、油溶性ゴボウエキス、コムギ胚芽エキス、加水分解コムギ末、コメヌカエキス、コメヌカ発酵エキス、コンフリーエキス、サイシンエキス、サフランエキス、サボンソウエキス、油溶性サルビアエキス、サンザシエキス、サンショウエキス、シイタケエキス、シイタケエキス末、ジオウエキス、シコンエキス、油溶性シコンエキス、シソエキス、シナノキエキス、油溶性シナノキエキス、シモツケソウエキス、シャクヤクエキス、ジュズダマエキス、ショウキョウエキス、油溶性ショウキョウエキス、ショウキョウチンキ、ショウブ根エキス、シラカバエキス、油溶性シラカバエキス、シラカバ樹液、スイカズラエキス、スギナエキス、油溶性スギナエキス、スコルジニン、ステビアエキス、セイヨウキズタエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セイヨウネズエキス、セイヨウノコギリソウエキス、油溶性セイヨウノコギリソウエキス、セイヨウハッカエキス、セージエキス、油溶性セージエキス、セージ水、ゼニアオイエキス、セロリエキス、センキュウエキス、センキュウ水、センブリエキス、ダイズエキス、タイソウエキス、タイムエキス、チャエキス、チャ乾留液、チャ実エキス、チョウジエキス、チンピエキス、ツバキエキス、ツボクサエキス、油溶性テウチグルミエキス、デュークエキス、テルミナリアエキス、トウガラシチンキ、トウキエキス、油溶性トウキエキス、トウキ水、トウキンセンカエキス、油溶性トウキンセンカエキス、豆乳末、トウニンエキス、トウヒエキス、ドクダミエキス、トマトエキス、トルメンチラエキス、納豆エキス、ニンジンエキス、油溶性ニンジンエキス、ニンニクエキス、ノバラエキス、油溶性ノバラエキス、バクガエキス、バクガ根エキス、バクモンドウエキス、パセリエキス、ハダカムギ葉汁濃縮物、蒸留ハッカ水、ハマメリス水、ハマメリス抽出液、バラエキス、パリエタリアエキス、ヒキオコシエキス、ビワ葉エキス、油溶性ビワ葉エキス、フキタンポポエキス、ブクリョウエキス、ブッチャーブルームエキス、ブッチャーブルームエキス末、ブドウエキス、ブドウ葉エキス、ブドウ水、ヘイフラワーエキス、ヘチマエキス、ヘチマ水、ベニバナエキス、油溶性ボダイジュエキス、ボダイジュ水、ボタンエキス、ホップエキス、油溶性ホップエキス、マツエキス、マリアアザミエキス、マロニエエキス、油溶性マロニエエキス、ムクロジエキス、メリッサエキス、メリロートエキス、モモ葉エキス、油溶性モモ葉エキス、モヤシエキス、ヤグルマギ
クエキス、ヤグルマギク水、ユーカリエキス、ユキノシタエキス、ユリエキス、ヨクイニンエキス、油溶性ヨクイニンエキス、ヨモギエキス、ヨモギ水、ラベンダーエキス、ラベンダー水、リンゴエキス、レイシエキス、レタスエキス、レモンエキス、レンゲソウエキス、ローズ水、ローズマリーエキス、油溶性ローズマリーエキス、ローマカミツレエキス、ワレモコウエキス、等の植物抽出物;
グリシン、アラニン、バリン、ロイシン、イソロイシン、セリン、トレオニン、フェニルアラニン、チロシン、トリプトファン、シスチン、システイン、メチオニン、プロリン、ヒドロキシプロリン、アスパラギン酸、アスパラギン、グルタミン酸、グルタミン、アルギニン、ヒスチジン、リシン、γ−アミノ酪酸、DL−ピロリドンカルボン酸、ε−アミノカプロン酸、加水分解エラスチン、水溶性エラスチン、加水分解コラーゲン、水溶性コラーゲン、カゼイン、グルタチオン、小麦ペプチド、大豆ペプチド、等のアミノ酸類及びペプチド類;
レチノール、レチナール、レチノイン酸、酢酸レチノール、パルミチン酸レチノール等のビタミンA類、α−カロチン、β−カロチン、γ−カロチン、δ−カロチン、リコピン、ゼアキサンチン、クリプトキサンチン、エキネノン、アスタキサンチン等のカロテノイド類、チアミン類等のビタミンB1類、リボフラビン等のビタミンB2類、ピリドキシン、ピリドキサール、ピリドキサミン等のビタミンB6類、シアノコバラミン等のビタミンB12類、葉酸類、ニコチン酸、ニコチン酸アミド、パントテン酸類、ビオチン類、L−アスコルビン酸、L−アスコルビン酸ナトリウム、ステアリン酸L−アスコルビル、パルミチン酸L−アスコルビル、ジパルミチン酸L−アスコルビル、テトライソパルミチン酸L−アスコルビル、L−アスコルビン酸硫酸エステル二ナトリウム、L−アスコルビルマグネシウム、リン酸L−アスコルビルナトリウム、L−アスコルビン酸−2−グルコシド、L−アスコルビン酸−2−リン酸マグネシウム等のビタミンC類、エルゴカルシフェロール、コレカルシフェロール等のビタミンD類、d−α−トコフェロール、DL−α−トコフェロール、酢酸dl−α−トコフェロール、コハク酸dl−α−トコフェロール、β−トコフェロール、γ−トコフェロール、d−δ−トコフェロール等のビタミンE類、ユビキノン類、ビタミンK類、カルニチン、フェルラ酸、γ−オリザノール、α−リポ酸、オロット酸等のビタミン類及びビタミン様作用因子類;
安息香酸、安息香酸ナトリウム、ウンデシレン酸、サリチル酸、ソルビン酸、ソルビン酸カリウム、デヒドロ酢酸、デヒドロ酢酸ナトリウム、パラオキシ安息香酸イソブチル、パラオキシ安息香酸イソプロピル、パラオキシ安息香酸エチル、パラオキシ安息香酸ブチル、パラオキシ安息香酸プロピル、パラオキシ安息香酸ベンジル、パラオキシ安息香酸メチル、パラオキシ安息香酸メチルナトリウム、フェノキシエタノール、感光素101号、感光素201号、感光素401号、等の防腐剤;
ブチルヒドロキシアニソール、ブチルヒドロキシトルエン、没食子酸プロピル、エリソルビン酸、エリソルビン酸ナトリウム、パラヒドロキシアニソール、没食子酸オクチル、等の酸化防止剤;
エチレンジアミンヒドロキシエチル三酢酸三ナトリウム、エデト酸、エデト酸二ナトリウム、エデト酸三ナトリウム、エデト酸四ナトリウム、クエン酸ナトリウム、グルコン酸、フィチン酸、ポリリン酸ナトリウム、メタリン酸ナトリウム、等の金属イオン封鎖剤;
ヒアルロン酸、ヒアルロン酸ナトリウム、コンドロイチン硫酸ナトリウム、乳酸ナトリウム、ピロリドンカルボン酸ナトリウム、ベタイン、乳酸菌培養液、酵母エキス、セラミド、等の保湿剤;
グリチルリチン酸、グリチルリチン酸三ナトリウム、グリチルリチン酸ジカリウム、グリチルリチン酸モノアンモニウム、β−グリチルレチン酸、グリチルレチン酸グリセリン、グリチルレチン酸ステアリル、塩化リゾチーム、ヒドロコルチゾン、アラントイン、等の抗炎症剤;
水酸化ナトリウム、水酸化カリウム、トリエタノールアミン、等のpH調整剤;
塩化ナトリウム、塩化カリウム、塩化マグネシウム、硫酸ナトリウム、等の塩類;
クエン酸、グリコール酸、酒石酸、乳酸等のα−ヒドロキシ酸類;
アルブチン、α−アルブチン、プラセンタエキス、等の美白剤;
アンゼリカ油、イランイラン油、エレミ油、オレンジ油、カミツレ油、ローマカミツレ油、カルダモン油、カラムス油、ガルバナム油、カンファー油、キャロットシード油、クラリーセージ油、グレープフルーツ油、チョウジ油、ケイヒ油、コリアンダー油、サイプレス油、サンダルウッド油、シダーウッド油、シトロネラ油、シナモンリーフ油、ジャスミンアブソリュート、ジュニパーベリー油、ジンジャーエクストラクト、スペアミント油、セージ油、セダー油、ゼラニウム油、タイム油、ティーツリー油、ナツメグ油、ニアウリ油、ネロリ油、パイン油、バジル油、ハッカ油、パチュリー油、パルマローザ油、フェンネル油、プチグレン油、ブラックペッパー油、フランキンセンス油、ベチバ油、ペパーミント油、ベルガモット油、ベンゾイン油、ボアドローズ油、マジョラム油、マンダリン油、ミルラ油、メリッサ油、ユーカリ油、ゆず油、ライム油、ラベンサラ油、ラバンジン油、ラベンダー油、リンデン油、レモン油、レモングラス油、ローズ油、ローズウッド油、ローズマリー油、ロベージ油、等の精油類;
リモネン、ピネン、テルピネン、テルピノーレン、ミルセン、ロンギフィーレン等のテルペン類;
香料、水等が挙げられる。
As such a component, for example,
Ozokerite, α-olefin oligomer, light isoparaffin, light liquid isoparaffin, squalene, squalane, synthetic squalane, vegetable squalane, ceresin, paraffin, polyethylene powder, polybutene, microcrystalline wax, liquid isoparaffin, liquid paraffin, mineral oil, petroleum jelly, etc. Hydrocarbons;
Jojoba oil, carnauba wax, candelilla wax, rice bran wax, shellac, lanolin, mink sebum wax, whale wax, sugar cane wax, sperm whale oil, beeswax, montan wax and other natural waxes, avocado oil, almond oil, olive oil, extra virgin olive oil, Sesame oil, rice bran oil, rice oil, rice germ oil, corn oil, safflower oil, soybean oil, corn oil, rapeseed oil, persic oil, palm kernel oil, palm oil, castor oil, sunflower oil, high oleic sunflower oil, Grape seed oil, cottonseed oil, palm oil, hydrogenated palm oil, beef tallow, hardened oil, horse oil, mink oil, egg yolk oil, egg yolk fat oil, rosehip oil, cucumber nut oil, evening primrose oil, wheat germ oil, peanut oil, camellia oil Oil, sasanqua oil, cacao butter, molasses, beef bone fat, beef leg oil, pork fat, horse fat, sheep fat, sheabata , Macadamia nut oil, natural fats and oils of meadowfoam oil, and the like;
Fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, γ-linolenic acid, isostearic acid, 12-hydroxystearic acid, undecylenic acid, coconut oil fatty acid;
Higher alcohols such as isostearyl alcohol, octyldodecanol, hexyldecanol, cholesterol, phytosterol, lauryl alcohol, myristyl alcohol, cetanol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cetostearyl alcohol;
Alkyl glyceryl ethers such as batyl alcohol, chimyl alcohol, ceralkyl alcohol, isostearyl glyceryl ether;
Isopropyl myristate, butyl myristate, isopropyl palmitate, ethyl stearate, butyl stearate, ethyl oleate, ethyl linoleate, isopropyl linoleate, cetyl caprylate, hexyl laurate, isooctyl myristate, decyl myristate, myristic acid Myristyl, cetyl myristate, octadecyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, oleyl oleate, cetyl ricinoleate, isostearyl laurate, isotridecyl myristate, isocetyl myristate, isostearyl myristate, myristic acid Octyldodecyl, 2-ethylhexyl palmitate, isocetyl palmitate, isos palmitate
Thearyl, 2-ethylhexyl stearate, isocetyl stearate, isooleate
Decyl, octyldodecyl oleate, octyldodecyl ricinoleate, ethyl isostearate, isopropyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, stearyl 2-ethylhexanoate, hexyl isostearate,
Ethylene glycol dioctanoate, ethylene glycol dioleate, propylene glycol dicaprylate, di (capryl / capric) propylene glycol, propylene glycol dicaprate, propylene glycol dioleate, neopentyl glycol dicaprate, neopentyl glycol dioctanoate, glyceryl tricaprylate , Tri 2-E
Glyceryl tilhexanoate, tri (capryl / capric acid) glyceryl, tri (caprylic acid / capric acid / stearic acid) glyceryl, glyceryl triundecylate, glyceryl triisopalmitate, glyceryl triisostearate, tri-2-ethylhexanoic acid tri
Methylolpropane, trimethylolpropane triisostearate, tetra-2-ethyl
Pentaerythrityl hexanoate, pentaerythrityl tetramyristate, pentaerythrityl tetraisostearate, diglyceryl tetraisostearate, octyldodecyl neopentanoate, isocetyl octoate, isostearyl octoate, 2-ethylhexyl isoperargonate, dimethyloctane Hexyldecyl acid, octyl dimethyloctanoate
Ludodecyl, 2-ethylhexyl isopalmitate, isocetyl isostearate, iso
Isostearyl stearate, octyl dodecyl isostearate, lauryl lactate, myristyl lactate, cetyl lactate, octyl dodecyl lactate, triethyl citrate, acetyl citrate
Rutriethyl, acetyltributyl citrate, trioctyl citrate, triisocetyl citrate, trioctyldodecyl citrate, diisostearyl malate, 2-ethylhexyl hydroxystearate, di-2-ethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, adipine Dioctyl acid, diheptyl undecyl adipate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, cholesteryl stearate, cholesteryl isostearate, cholesteryl hydroxystearate, cholesteryl oleate, dihydrocholesteryl oleate, phytosteryl isostearate, oleic acid Phytosteryl, 12-stearoyl hydroxystearate isocetyl, 12-stearoyl hydride Stearyl xyl stearate, isostearyl 12-stearoylhydroxystearate, polyoxyethylene acetate (3) polyoxypropylene (1) cetyl ether, polyoxyethylene acetate (3) polyoxypropylene (1) isocetyl ether, isononyl isononanoate Esters of octyl isononanoate, tridecyl isononanoate, isotridecyl isononanoate, etc .;
Methylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, tetradeca Methyl hexasiloxane, highly polymerized methyl polysiloxane, dimethyl siloxane methyl (polyoxyethylene) siloxane methyl (polyoxypropylene) siloxane copolymer, dimethyl siloxane methyl (polyoxyethylene) siloxane copolymer, dimethyl siloxane methyl (Polyoxypropylene) siloxane copolymer, dimethylsiloxane / methylcetyloxysiloxane copolymer, dimethylsiloxane / Chill stearoxysiloxane copolymer, polyether-modified silicones, alcohol-modified silicones, alkyl-modified silicones, silicone oils such as amino-modified silicone;
Ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, pentanediol, glycerin, diglycerin, polyglycerin, isoprene glycol, 1,3-butylene glycol, 3-methyl-1,3 Polyhydric alcohols such as butanediol, 1,3-butanediol, 1,2-pentanediol, 1,2-hexanediol;
Sugars such as mannitol, sorbitol, xylitol, maltitol, erythritol, pentaerythritol, glucose, sucrose, fructose, lactose, maltose, xylose, trehalose;
Sodium alginate, carrageenan, agar, fur celerin, guar gum, quince seed, konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, gati gum, karaya gum, tragacanth gum, arabinogalactan, pectin, quince, chitosan, starch , Curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan, microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, carboxy starch, cationized cellulose, starch phosphate ester, cation Guar gum, carboxymethyl Roxypropylated guar gum, hydroxypropylated guar gum, albumin, casein, gelatin, sodium polyacrylate, polyacrylate amide, carboxyvinyl polymer, polyethyleneimine, highly polymerized polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl ether, polyacrylamide, Acrylic acid copolymer, methacrylic acid copolymer, maleic acid copolymer, vinylpyridine copolymer, ethylene / acrylic acid copolymer, vinylpyrrolidone polymer, vinyl
Alcohol / vinyl pyrrolidone copolymer, nitrogen-substituted acrylamide polymer, amino modification
Silicone, cationized polymer, dimethylacrylammonium polymer, acrylic acid anion polymer, methacrylic acid anion polymer, modified silicone, acrylic
Acid alkyl methacrylate (C Ten ~ 30 ) Copolymer, polyoxyethylene / polyoxypropy
Polymers such as lencopolymers;
Ethanol, isopropyl alcohol, 1-butanol, 2-butanol, benzyl alcohol
Alcohols such as lecoles;
Palm oil fatty acid potassium, coconut oil fatty acid sodium, coconut oil fatty acid triethanolamine, potassium laurate, sodium laurate, triethanolamine laurate, potassium myristate, sodium myristate, isopropanolamine myristate, potassium palmitate, palmitic acid Sodium, isopropanolamine palmitate, potassium stearate, sodium stearate, triethanolamine stearate, potassium oleate, sodium oleate, castor oil fatty acid sodium, zinc undecylenate, zinc laurate, zinc myristate, magnesium myristate, Zinc palmitate, zinc stearate, calcium stearate, magnesium stearate, aluminum stearate, myristi Calcium oxide, magnesium myristate, aluminum dimyristate, aluminum isostearate, polyoxyethylene lauryl ether acetic acid, sodium polyoxyethylene lauryl ether acetate, polyoxyethylene tridecyl ether acetic acid, sodium polyoxyethylene tridecyl ether acetate, stearoyl lactic acid Sodium, isostearoyl sodium lactate, lauroyl sarcosine sodium, coconut oil fatty acid sarcosine, coconut oil fatty acid sarcosine sodium, coconut oil fatty acid sarcosine triethanolamine, lauroyl sarcosine, lauroyl sarcosine potassium, lauroyl sarcosine triethanolamine, oleoyl sarcosine, myristoyl sarcosine sodium , Sodium stearoyl glutamate, Oil fatty acid acyl glutamic acid, coconut oil fatty acid potassium acyl glutamate, coconut oil fatty acid acyl glutamic acid sodium, coconut oil fatty acid acyl glutamic acid triethanolamine, lauroyl acyl glutamic acid, lauroyl acyl glutamic acid potassium, lauroyl acyl glutamic acid sodium, lauroyl acyl glutamic acid triethanolamine, myristoyl Acyl glutamate, potassium myristoyl acyl glutamate, sodium myristoyl acyl glutamate, stearoyl acyl glutamate, potassium stearoyl acyl glutamate, disodium stearoyl acyl glutamate, hardened beef tallow fatty acid acyl glutamate, coconut oil fatty acid / hardened tallow fatty acid acyl glutamate sodium, coconut oil fatty acid me Sodium tilalanine, lauroylmethylalanine, sodium lauroylmethylalanine, lauroylmethylalanine triethanolamine, sodium myristoylmethylalanine, sodium lauroylmethyltaurine, coconut oil fatty acid methyltaurine potassium, coconut oil fatty acid methyltaurine sodium, coconut oil fatty acid methyltaurine magnesium , Myristoyl methyl taurine sodium, palmitoyl methyl taurine sodium, stearoyl methyl taurine sodium, oleoyl methyl taurine sodium, sodium alkane sulfonate, sodium tetradecene sulfonate, dioctyl sodium sulfosuccinate, disodium lauryl sulfosuccinate, palm oil fatty acid ethyl ester sulfone Acid sodium, lauryl sulfate Thorium, triethanolamine lauryl sulfate, sodium cetyl sulfate, alkyl (11,13,15) triethanolamine sulfate, alkyl (12,13) sodium sulfate, alkyl (12,13) triethanolamine sulfate, alkyl (12,14) , 16) Ammonium sulfate, alkyl (12-13) diethanolamine sulfate, alkyl (12-14) triethanolamine sulfate, alkyl (12-15) triethanolamine sulfate, palm oil alkyl magnesium sulfate / triethanolamine, ammonium lauryl sulfate, lauryl Potassium sulfate, magnesium lauryl sulfate, monoethanolamine lauryl sulfate, diethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, triethanol sulfate Min, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene lauryl ether triethanolamine, polyoxyethylene (1) alkyl (11, 13, 15) ether sodium sulfate, polyoxyethylene (1) alkyl (11, 13, 15) ether sulfate triethanolamine, polyoxyethylene (3) alkyl (11-15) ether sulfate sodium
Thorium, polyoxyethylene (2) alkyl (12,13) ether sodium sulfate, polyoxyethylene (3) alkyl (12-14) sodium ether sulfate, polyoxyethylene (3) alkyl (12-15) sodium ether sulfate, Polyoxyethylene (2) sodium lauryl ether sulfate, polyoxyethylene (3) sodium myristyl ether sulfate, higher fatty acid alkanolamide sodium sulfate ester, lauryl phosphate, sodium lauryl phosphate, potassium cetyl phosphate, diethanolamine cetyl phosphate, polyoxyethylene Oleyl ether phosphate, polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene lauryl ether phosphate, polyoxyethylene cetyl ether phosphate, polyoxyethylene Sodium ethylene cetyl ether phosphate, polyoxyethylene stearyl ether phosphate, polyoxyethylene oleyl ether phosphate, polyoxyethylene oleyl ether sodium phosphate, polyoxyethylene alkylphenyl ether phosphate, polyoxyethylene alkylphenyl ether sodium phosphate , Polyoxyethylene alkylphenyl ether phosphate triethanolamine, polyoxyethylene octyl ether phosphate, polyoxyethylene (10) alkyl (12,13) ether phosphate, polyoxyethylene alkyl (12-15) ether phosphate, Polyoxyethylene alkyl (12-16) ether phosphate, polyoxyethylene lauryl ether triethanolamine, polyoxyethylene oleyl Terurin acid diethanolamine, anionic surfactants and the like;
Dioctylamine, dimethylstearylamine, trilaurylamine, diethylaminoethylamide stearate, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, cetyltrimethylammonium saccharin, stearyltrimethylammonium chloride, alkyl chloride (20-22) Trimethylammonium, lauryltrimethylammonium bromide, alkyl (16,18) trimethylammonium chloride, stearyltrimethylammonium bromide, stearyltrimethylammonium saccharin, alkyl (28) trimethylammonium chloride, di (polyoxyethylene) oleylmethylammonium chloride (2EO) ), Dipolyoxyethylene stearylmethylammonium chloride Polyoxyethylene chloride (1) polyoxypropylene (
25) Diethylmethylammonium chloride, tri (polyoxyethylene) stearyl ammonium
Ni (5EO), distearyldimethylammonium chloride, dialkyl (12-15) dimethylammonium chloride, dialkyl (12-18) dimethylammonium chloride, dialkyl (14-18) dimethylammonium chloride, dicocoyldimethylammonium chloride, dicetyl chloride Dimethyl ammonium, isostearyl lauryl dimethyl ammonium chloride, benzalkonium chloride, myristyl dimethyl benzyl ammonium chloride, lauryl dimethyl (ethyl benzyl) ammonium chloride, stearyl dimethyl benzyl ammonium chloride, lauryl pyridinium chloride, cetyl pyridinium chloride, lauroyl colaminoformyl methyl chloride Pyridinium, stearoylcholaminoformylmethylpyridinium chloride, alkylisoquinolium bromide, Methyl benzethonium, benzethonium chloride, cationic surfactants and the like;
2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, alkyldiaminoethylglycine hydrochloride, sodium lauryldiaminoethylglycine, sodium undecylhydroxyethylimidazolium betaine, undecyl-N-carboxymethylimidazolium betaine Coconut oil fatty acid acyl-N-carboxyethyl-N-hydroxyethylethylenediamine disodium, coconut oil fatty acid acyl-N-carboxyethoxyethyl-N-carboxyethylethylenediamine disodium, coconut oil fatty acid acyl-N-carboxymethoxyethyl-N -Carboxymethylethylenediamine disodium, sodium laurylaminopropionate, sodium laurylaminodipropionate, laurylaminopropyl Triethanolamine pionate, palm oil fatty acid acyl-N-carboxyethyl-N-hydroxyethylethylenediamine sodium, lauryldimethylaminoacetic acid betaine, coconut oil alkyldimethylaminoacetic acid betaine, stearyldimethylaminoacetic acid betaine, stearyldimethylbetaine sodium, coconut oil Fatty acid
Amphoteric surfactants such as midpropyl betaine, palm oil fatty acid amidopropyl betaine, lauric acid amidopropyl acetic acid betaine, ricinoleic acid amidopropyl betaine, stearyl dihydroxyethyl betaine, lauryl hydroxysulfo betaine;
Polyoxyethylene (10) alkyl (12,13) ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene (3, 7, 12) alkyl ( 12-14) ether, polyoxyethylene tridecyl ether, polyoxyethylene myristyl ether, polyoxyethylene-sec-alkyl (14) ether, polyoxyethylene isocetyl ether, polyoxyethylene cetostearyl ether, polyoxyethylene (2 , 10, 20) Isostearyl ether, polyoxyethylene oleyl cetyl ether, polyoxyethylene (20) aralkyl ether, polyoxyethylene octyldodecyl ether Polyoxyethylene behenyl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene dinonyl phenyl ether, polyoxyethylene (1) polyoxypropylene (1,2,4,8) cetyl ether, poly Oxyethylene (5) polyoxypropylene (1,2,4,8) cetyl ether, polyoxyethylene (10) polyoxypropylene (1,2,4,8) cetyl ether, polyoxyethylene (20) polyoxypropylene (1,2,4,8) cetyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxyethylene (3) polyoxypropylene (34) stearyl ether, polyoxyethylene (4) polyoxypropylene (30) Allyl ether, polyoxyethylene (34) polyoxypropylene (23) stearyl ether, polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene decyl tetradecyl ether, polyethylene glycol monolaurate, ethylene glycol monostearate, mono Polyethylene glycol stearate, polyethylene glycol monooleate, ethylene glycol fatty acid ester, self-emulsifying ethylene glycol monostearate, diethylene glycol laurate, polyethylene glycol myristate, polyethylene glycol palmitate, diethylene glycol stearate, polyethylene monostearate self-emulsifying Glycol (2), polyethylene isostearate Recall, ethylene glycol dioctanoate, diethylene glycol dilaurate, polyethylene glycol dilaurate, polyethylene glycol dipalmitate (150), ethylene glycol distearate, diethylene glycol distearate, polyethylene glycol distearate, ethylene glycol dioleate, polyethylene glycol dioleate, diglycol Polyethylene glycol ricinoleate, polyoxyethylene (20) sorbitan monolaurate, polyoxyethylene (20) sorbitan monopalmitate, polyoxyethylene (6) sorbitan monostearate, polyoxyethylene (20) sorbitan monostearate, tristearin Acid polyoxyethylene (20) sorbitan, monooleic acid polyoxy Tylene (6) sorbitan, polyoxyethylene monooleate (20) sorbitan, polyoxyethylene trioleate (20) sorbitan, polyoxyethylene (20) coconut oil fatty acid sorbitan, polyoxyethylene monolaurate (10-80) sorbitan , Polyoxyethylene sorbitan tristearate, polyoxyethylene (20) sorbitan isostearate, polyoxyethylene (150) sorbitan tristearate, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene (10) cured Castor oil, polyoxyethylene (20) hydrogenated castor oil, polyoxyethylene (40) hydrogenated castor oil, polyoxyethylene (50) hydrogenated castor oil, polyoxyethylene (60) hydrogenated castor oil, lipophilic monos Glyceryl allate, glyceryl monooleate, glyceryl monostearate, self-emulsifying glyceryl monostearate, glyceryl coconut fatty acid, glyceryl laurate, glyceryl myristate, glyceryl isostearate, glyceryl ricinoleate, glyceryl monohydroxystearate, glyceryl oleate Glyceryl linoleate, glyceryl erucate, glyceryl behenate, wheat germ oil fatty acid glyceride, safflower oil fatty acid glyceryl, hydrogenated soybean fatty acid glyceryl,
Saturated fatty acid glyceride, cottonseed oil fatty acid glyceryl, monoisostearate monomyristate glyceryl, mono-bovine fatty acid glyceride, monolanolin fatty acid glyceryl, sesquioleate glyceryl, distearate glyceryl, diisostearate glyceryl, diarachiate glyceryl, monolaurate sorbitan, monopalmitate Sorbitan, sorbitan monostearate, sorbitan monoisostearate, sorbitan monooleate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan tristearate, sorbitan trioleate, sorbitan palm oil fatty acid, sorbitan isostearate, sorbitan sesquiisostearate Sorbitan distearate, diglyceryl isopalmitate, monolaurate poly (4-10) glyceryl, poly (10) glyceryl monomyristate, poly (2-10) glyceryl monostearate, poly (2-10) glyceryl monoisostearate, poly (2-10) glyceryl monooleate, sesqui Diglyceryl oleate, poly (2-10) glyceryl diisostearate, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) glyceryl tristearate, poly (10) glyceryl trioleate, tetra Poly (2) glyceryl isostearate, decaglyceryl pentastearate, poly (6-10) glyceryl pentaoleate, poly (10) glyceryl heptearate, decaglyceryl decastearate, poly (10) glyceryl decaoleate, condensed Poly (6) glyceryl ricinoleate, sucrose fatty acid ester, coconut oil fatty acid sucrose ester, alkyl glucoside, coconut oil alkyl dimethylamine oxide, lauryl dimethylamine oxide, dihydroxyethyl lauryl dimethylamine oxide, stearyl dimethylamine oxide, oleyldimethylamine Nonionic surfactants such as oxides, polyoxyethylene coconut oil alkyldimethylamine oxides;
Saponin, lecithin, soybean phospholipid, hydrogenated soybean phospholipid, soybean lysophospholipid, hydrogenated soybean lysophospholipid, egg yolk lecithin, hydrogenated egg yolk lysophosphatidylcholine, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingophospholipid, sphingomyelin, ganglioside Natural surfactants such as bile acid, cholic acid, deoxycholic acid, sodium cholate, sodium deoxycholate, spicrispolic acid, rhamnolipid, trehalose lipid, sophorolipid, mannosylerythritol lipid;
Paraaminobenzoic acid, ethyl paraaminobenzoate, glyceryl paraaminobenzoate, amyl paradimethylaminobenzoate, paraaminobenzoic acid derivatives such as 2-ethylhexyl paradimethylaminobenzoate, benzyl cinnamate, diparamethoxycinnamic acid mono-2 -Glyceryl ethylhexanoate, methyl 2,4-diisopropylcinnamate, ethyl 2,4-diisopropylcinnamate, potassium paramethoxycinnamate, sodium paramethoxycinnamate, isopropyl paramethoxycinnamate, paramethoxycinnamate Cinnamic acid derivatives such as 2-ethylhexyl cinnamate, 2-ethoxyethyl paramethoxycinnamate, ethyl paraethoxycinnamate, urocanic acid derivatives such as urocanic acid, ethyl urocanate, 2,4-dihydroxybenzophenone, 2, 2 ', 4, 4 '-Tetrahydroxybenzophenone, 2-hydroxy-4-methoxy-5-sulfobenzophenone sodium, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, 2-hydroxy-4-methoxybenzophenone, 2,2'-dihydroxy- Benzophenone derivatives such as sodium 4,4'-dimethoxybenzophenone and 2,2'-dihydroxy-4,4'-dimethoxy-5-sulfobenzophenone, ethylene glycol salicylate, 2-ethylhexyl salicylate, phenyl salicylate, benzyl salicylate, salicylic acid p -Salicylic acid derivatives such as tert-butylphenyl, homomenthyl salicylate, salicylic acid-3,3,5-trimethylcyclohexyl, 2- (2'-hydroxy-5'-methoxyphenyl) benzotriazole, UV absorbers such as 4-tert-butyl-4′-methoxybenzoylmethane;
Kaolin, anhydrous silicic acid, magnesium aluminum silicate, sericite, talc, boron nitride, mica, montmorillonite, hemp cellulose powder, wheat starch, silk powder, corn starch, nitro dye, azo dye, nitroso dye, triphenyl Methane color
Element, xanthene dye, quinoline dye, anthraquinone dye, indigo dye, pyrene dye, phthalocyanine dye, flavonoid, quinone, porphyrin, water soluble anato, carp, guaiazulene, gardenia blue, gardenia yellow, cochineal , Shikonin, copper chlorophyllin sodium, paprika dye, safflower red, safflower yellow, laccaic acid, riboflavin butyrate, and other natural dyes, carbon black, yellow iron oxide, black iron oxide, red rose, conger, ultramarine, zinc oxide, chromium oxide, Powders such as titanium oxide, black titanium oxide, zirconium oxide, chromium hydroxide, alumina, magnesium oxide, barium sulfate, aluminum hydroxide, calcium carbonate, lithium cobalt titanate, manganese violet, pearl pigment, and the like Wood like;
Ashitaba extract, Acacia catechu extract, Avocado extract, Achacha extract, Achachazul extract, Altea extract, Arnica extract, Oil-soluble Arnica extract, Almond extract, Aloe extract, Anchovy extract, Ginkgo biloba extract, Nettle extract, Iris root extract, Fennel extract , Turmeric extract, Ages extract, Echinacea leaf extract, Ogon extract, Oat extract, Prunus extract, Barley extract, Okra extract, Hypericum extract, Oil-soluble Hypericum extract, Adriatic extract, Oil-soluble extract , Orange flower water, seaweed extract, oyster tannin, cuckoo extract, valerian extract, cattail extract, chamomile extract, oil-soluble chamomile extract, chamomile Water, oat extract, carrot extract, oil-soluble carrot extract, carrot oil, pearl millet extract, licorice extract, licorice extract powder, licorice flavonoids, cantalis tincture, raspberry extract, kiwi extract, quina extract, cucumber extract, kyonin extract, quince seed extract , Gardenia extract, Kumazasa extract, Clara extract, walnut shell extract, grapefruit extract, clematis extract, brown sugar extract, chlorella extract, mulberry extract, cinnamon extract, gentian extract, gentian pepper extract, black tea extract, citrus extract, burdock extract, oil-soluble Burdock extract, wheat germ extract, hydrolyzed wheat powder, rice bran extract, rice bran fermented extract, comfrey extract, saicin extract, saffron extract, savonso Extract, oil-soluble salvia extract, hawthorn extract, salamander extract, shiitake extract, shiitake extract powder, shiroi extract, shikon extract, oil-soluble shikon extract, perilla extract, linden extract, oil-soluble linden extract, shimotake extract, peonies extract, juniper extract, ginger Extract, Oil-soluble Pepper extract, Pepper tincture, Ginger root extract, Birch extract, Oil-soluble birch extract, Birch sap, Honeysuckle extract, Japanese horsetail extract, Oil-soluble Japanese horse chestnut extract, Scorginin, Stevia extract, Atlantic kizuta extract, Hawthorn extract , Elderberry extract, black mouse extract, yarrow extract, oil-soluble yarrow extract, mint extract, sage extract, oil-soluble Sage extract, sage water, mallow extract, celery extract, senkyu extract, senkyu water, senbu extract, soybean extract, taisou extract, thyme extract, tea extract, tea dry extract, tea seed extract, clove extract, chimpi extract, camellia extract, camellia extract, oil Soluble Teuchigurumi extract, Duke extract, Terminaria extract, Capsicum tincture, Toki extract, Oil-soluble Toki extract, Toki water, Toki-senka extract, Oil-soluble Toki-senka extract, Soy milk powder, Tonin extract, Spruce extract, Dokudami extract, Tomato extract, Toll Mentilla extract, natto extract, carrot extract, oil-soluble carrot extract, garlic extract, wild rose extract, oil-soluble wild rose extract, buckthorn extract, buckthorn root extract, buckthorn extract, parsley ki , Leafhopper concentrate, distilled mint water, hamamelis water, hamamelis extract, rose extract, parietalia extract, buffalo extract, loquat leaf extract, oil-soluble loquat leaf extract, dandelion extract, butterfly extract, butcher bloom extract, butcher bloom extract Powder, Grape extract, Grape leaf extract, Grape water, Hayflower extract, Loofah water, Safflower water, Safflower extract, Oil-soluble bodai extract, Bodaiju water, Button extract, Hop extract, Oil-soluble hop extract, Pine extract, Maria thistle extract, Maronnier extract, oil-soluble Marronnier extract, mugwort extract, Melissa extract, Merirot extract, peach leaf extract, oil-soluble peach leaf extract, coconut extract, cornflower
Cucumber extract, cornflower water, eucalyptus extract, saxifrage extract, lily extract, cucumber extract, oil-soluble cucumber extract, mugwort extract, mugwort water, lavender extract, lavender water, apple extract, litchi extract, lettuce extract, lemon extract, forsythia extract, rose water , Rosemary extract, oil-soluble rosemary extract, roman chamomile extract, bitumen extract, etc .;
Glycine, alanine, valine, leucine, isoleucine, serine, threonine, phenylalanine, tyrosine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, asparagine, glutamic acid, glutamine, arginine, histidine, lysine, γ-aminobutyric acid Amino acids and peptides such as DL-pyrrolidone carboxylic acid, ε-aminocaproic acid, hydrolyzed elastin, water-soluble elastin, hydrolyzed collagen, water-soluble collagen, casein, glutathione, wheat peptide, soybean peptide;
Vitamin A such as retinol, retinal, retinoic acid, retinol acetate, retinol palmitate, etc., carotenoids such as α-carotene, β-carotene, γ-carotene, δ-carotene, lycopene, zeaxanthin, cryptoxanthine, echinone, astaxanthin, Vitamin B1 such as thiamine, vitamin B2 such as riboflavin, vitamin B6 such as pyridoxine, pyridoxal, pyridoxamine, vitamin B12 such as cyanocobalamin, folic acid, nicotinic acid, nicotinamide, pantothenic acid, biotins, L -Ascorbic acid, sodium L-ascorbate, L-ascorbyl stearate, L-ascorbyl palmitate, L-ascorbyl dipalmitate, L-ascorbyl tetraisopalmitate, L-ascorb Vitamin C such as disodium acid sulfate ester, magnesium L-ascorbyl, sodium L-ascorbyl phosphate, L-ascorbic acid-2-glucoside, L-ascorbic acid-2-magnesium phosphate, ergocalciferol, cholecalci Vitamins D such as ferrol, vitamins such as d-α-tocopherol, DL-α-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol succinate, β-tocopherol, γ-tocopherol, d-δ-tocopherol Vitamins and vitamin-like agents such as E, ubiquinones, vitamin K, carnitine, ferulic acid, γ-oryzanol, α-lipoic acid, orotic acid;
Benzoic acid, sodium benzoate, undecylenic acid, salicylic acid, sorbic acid, potassium sorbate, dehydroacetic acid, sodium dehydroacetate, isobutyl paraoxybenzoate, isopropyl paraoxybenzoate, ethyl paraoxybenzoate, butyl paraoxybenzoate, propyl paraoxybenzoate , Preservatives such as benzyl paraoxybenzoate, methyl paraoxybenzoate, methyl sodium paraoxybenzoate, phenoxyethanol, photosensitive element 101, photosensitive element 201, photosensitive element 401, and the like;
Antioxidants such as butylhydroxyanisole, butylhydroxytoluene, propyl gallate, erythorbic acid, sodium erythorbate, parahydroxyanisole, octyl gallate;
Metal ion sequestering agents such as trisodium ethylenediaminehydroxyethyl triacetate, edetic acid, disodium edetate, trisodium edetate, tetrasodium edetate, sodium citrate, gluconic acid, phytic acid, sodium polyphosphate, sodium metaphosphate ;
Moisturizers such as hyaluronic acid, sodium hyaluronate, sodium chondroitin sulfate, sodium lactate, sodium pyrrolidonecarboxylate, betaine, lactic acid bacteria culture solution, yeast extract, ceramide, etc .;
Anti-inflammatory agents such as glycyrrhizic acid, trisodium glycyrrhizinate, dipotassium glycyrrhizinate, monoammonium glycyrrhizinate, β-glycyrrhetinic acid, glyceryl retinoic acid, stearyl glycyrrhetinate, lysozyme chloride, hydrocortisone, allantoin, etc .;
PH adjusters such as sodium hydroxide, potassium hydroxide, triethanolamine;
Salts such as sodium chloride, potassium chloride, magnesium chloride, sodium sulfate;
Α-hydroxy acids such as citric acid, glycolic acid, tartaric acid, lactic acid;
Whitening agents such as arbutin, α-arbutin, placenta extract, etc .;
Angelica oil, Ylang-Ylang oil, Elemi oil, Orange oil, Chamomile oil, Roman chamomile oil, Cardamom oil, Calamus oil, Galvanum oil, Camphor oil, Carrot seed oil, Clarage sage oil, Grapefruit oil, Clove oil, Keihi oil, Coriander oil , Cypress oil, Sandalwood oil, Cedarwood oil, Citronella oil, Cinnamon leaf oil, Jasmine absolute, Juniper berry oil, Ginger extract, Spearmint oil, Sage oil, Cedar oil, Geranium oil, Thyme oil, Tea tree oil, Nutmeg oil , Near uri oil, neroli oil, pine oil, basil oil, peppermint oil, patchouli oil, palmarosa oil, fennel oil, petitgren oil, black pepper oil, frankincense oil, vetiver oil, peppermint oil, bergamot oil Zoin oil, Boad Rose oil, Marjoram oil, Mandarin oil, Myrrh oil, Melissa oil, Eucalyptus oil, Yuzu oil, Lime oil, Lavensara oil, Lavandin oil, Lavender oil, Linden oil, Lemon oil, Lemongrass oil, Rose oil, Rose Essential oils such as wood oil, rosemary oil, lobe oil;
Terpenes such as limonene, pinene, terpinene, terpinolene, myrcene, longiferin, etc .;
A fragrance | flavor, water, etc. are mentioned.
さらに本発明の皮膚外用剤には、既存の化粧品原料を一般的な濃度で添加することもできる。例えば、化粧品原料基準第二版注解、日本公定書教会編、1984(薬事日報社)、化粧品原料基準外成分規格、厚生省薬務局審査課監修、1993(薬事日報社)、化粧品原料基準外成分規格追補、厚生省薬務局審査課監修、1993(薬事日報社)、化粧品種別許可基準、厚生省薬務局審査課監修、1993(薬事日報社)、化粧品種別配合成分規格、厚生省薬務局審査課監修、1997(薬事日報社)、及び化粧品原料辞典、平成3年(日光ケミカルズ)等に記載されている全ての化粧品原料を使用することができる。 Furthermore, existing cosmetic raw materials can be added to the skin external preparation of the present invention at a general concentration. For example, Cosmetic Material Standards 2nd Edition Commentary, Japan Official Church Church, 1984 (Pharmaceutical Daily Report), Cosmetic Raw Material Standards Ingredient Standards, Supervision by Ministry of Health and Welfare Pharmaceutical Affairs Bureau Examination Division, 1993 (Pharmaceutical Daily Reports) Standards supplement, supervised by the Ministry of Health and Welfare Pharmacy Examination Division, 1993 (Pharmaceutical Daily), permission standards by cosmetics type, supervision by the Ministry of Health and Welfare Pharmacy Examination Division, 1993 (Pharmaceutical Daily Report), formulation standard by cosmetic variety, Ministry of Health and Welfare Pharmacy Examination Division All cosmetic raw materials described in supervision, 1997 (Pharmaceutical Daily), cosmetic raw material dictionary, 1991 (Nikko Chemicals), etc. can be used.
〔実施例〕
以下に、本発明を実施例に基づいて具体的に説明するが、本発明はこれらの実施例に限定されるものではない。なお、「%」は、特に断りのない限り「質量%」を意味する。
〔Example〕
EXAMPLES The present invention will be specifically described below based on examples, but the present invention is not limited to these examples. “%” Means “mass%” unless otherwise specified.
1gのmyo−イノシトールと1gのβ−シクロデキストリンとを20mLの50mMクエン酸ナトリウム緩衝液(pH5.5)によく溶解した。ここへ500Uのサイクロデキストリングルカノトランフェラーゼを添加し、55℃で48時間反応させた。生成反応物はLC−MSで分析し、48時間後の反応液中にβ−シクロデキストリンが消失していることを確認した。反応後、反応液を10分沸騰させることで酵素を失活させた。次に、この反応液を十分に冷却した後、濾過し、更に凍結後に凍結乾燥によりグルコシルイノシトールを含む白色粉末1.2g(以下、GI−1と称する。)を得た。LC−MSの分析結果より、GI−1の成分比は、イノシトールに結合するグルコース鎖のグルコース数が、1個が38%、2個が28%、3個が10%、4個が4%、5個が1%であった。またGI−1は無臭であり、水への溶解性が極めて高かった。 1 g of myo-inositol and 1 g of β-cyclodextrin were well dissolved in 20 mL of 50 mM sodium citrate buffer (pH 5.5). 500 U of cyclodextrin glucanotransferase was added thereto and reacted at 55 ° C. for 48 hours. The product reaction product was analyzed by LC-MS, and it was confirmed that β-cyclodextrin disappeared in the reaction solution after 48 hours. After the reaction, the enzyme was inactivated by boiling the reaction solution for 10 minutes. Next, the reaction solution was sufficiently cooled, filtered, and freeze-dried after freezing to obtain 1.2 g of a white powder containing glucosyl inositol (hereinafter referred to as GI-1). From the results of LC-MS analysis, the component ratio of GI-1 indicates that the number of glucose chains bound to inositol is 38% for one, 28% for two, 10% for three, and 4% for four. Five were 1%. Moreover, GI-1 was odorless and its solubility in water was extremely high.
表1に示す化粧水を常法に基づき作製した(サンプル1−1)。この化粧水を20歳から30歳の女性10人に使用してもらい、使用後の感想を聴取した。結果を表2に示した。GI−1を含むサンプル1−1を使用することでざらつき感がなく、特異臭もなく、肌の潤い感が増すことが示された。 The lotion shown in Table 1 was produced based on a conventional method (Sample 1-1). We asked 10 women aged 20 to 30 to use this lotion and listened to their impressions after use. The results are shown in Table 2. It was shown that the use of sample 1-1 containing GI-1 has no rough feeling, no specific odor, and a moist feeling of skin.
〔比較例1〜2〕
表1に示す化粧水を常法に基づき作製した(サンプル1−2および1−3)。実施例2と同様の試験を行い使用後の感想を聴取した。結果を表2に示した。
[Comparative Examples 1-2]
The lotions shown in Table 1 were prepared based on conventional methods (Samples 1-2 and 1-3). The test similar to Example 2 was done and the impression after use was listened. The results are shown in Table 2.
表3に示す乳液を常法に基づき作製した(サンプル2−1)。この乳液を20歳から30歳の女性10人に使用してもらい、使用後の感想を聴取した。結果を表4に示した。GI−1を含むサンプル2−1を使用することでざらつき感がなく、特異臭もなく、肌の潤い感が増すことが示された。 The emulsion shown in Table 3 was prepared based on a conventional method (Sample 2-1). This latex was used by 10 women between the ages of 20 and 30 and listened to their thoughts after use. The results are shown in Table 4. Using Sample 2-1 containing GI-1, it was shown that there was no rough feeling, no specific odor, and a moist feeling of skin increased.
〔比較例3〜4〕
表3に示す乳液を常法に基づき作製した(サンプル2−2および2−3)。実施例3と同様の試験を行い使用後の感想を聴取した。結果を表4に示した。
[Comparative Examples 3 to 4]
The emulsion shown in Table 3 was produced based on a conventional method (Samples 2-2 and 2-3). The test similar to Example 3 was done and the impression after use was listened. The results are shown in Table 4.
10gのmyo−イノシトールと10gのβ−シクロデキストリンとを200mLの50mMクエン酸ナトリウム緩衝液(pH5.5)によく溶解した。ここへ5000Uのサイクロデキストリングルカノトランフェラーゼを添加し、55℃で48時間反応させた。生成反応物はLC−MSで分析し、48時間後の反応液中にβ−シクロデキストリンが消失していることを確認した。反応後、反応液を15分沸騰させることで酵素を失活させた。次に、この反応液を十分に冷却した後、濾過し、更に凍結後に凍結乾燥によりグルコシルイノシトールの白色粉末13.7g(以下、GI−2と称する。)を得た。LC−MSの分析結果より、GI−2の成分比は、イノシトールに結合するグルコース鎖のグルコース数が、1個が42%、2個が30%、3個が9%、4個が3%、5個が1%であった。 10 g of myo-inositol and 10 g of β-cyclodextrin were well dissolved in 200 mL of 50 mM sodium citrate buffer (pH 5.5). 5000 U cyclodextrin glucanotransferase was added here, and it was made to react at 55 degreeC for 48 hours. The product reaction product was analyzed by LC-MS, and it was confirmed that β-cyclodextrin disappeared in the reaction solution after 48 hours. After the reaction, the enzyme was inactivated by boiling the reaction solution for 15 minutes. Next, this reaction solution was sufficiently cooled, filtered, and freeze-dried after freezing to obtain 13.7 g of a white powder of glucosyl inositol (hereinafter referred to as GI-2). From the results of LC-MS analysis, the component ratio of GI-2 is that the number of glucose chains bound to inositol is 42% for one, 30% for two, 9% for three, and 3% for four. Five were 1%.
次に12gのGI−2を5mlの精製水に溶解し、分取用液体クロマトグラフィーのサンプル溶液とした。分取用液体クロマトグラフィーの条件としては、カラムにShodex SUGAR KS−2002、ガードカラムにShodex SUGAR KS−LGを使用し、溶離液には精製水を用いて、流速5ml/分、カラム温度は80℃で分離を行い、検出器RIでピークをモニターして、イノシトール残基に結合したオリゴ糖のピークのみを分取、回収した。回収した液体を凍結後に、凍結乾燥によりグルコシルイノシトールの白色粉末8.5g(以下、GI−3と称する。)を得た。LC−MSの分析結果より、GI−3の成分比は、イノシトールに結合するグルコース鎖のグルコース数が、1個が51%、2個が35%、3個が10%、4個が3%、5個が1%であった。またGI−3は無臭であり、水への溶解性も極めて高かった。 Next, 12 g of GI-2 was dissolved in 5 ml of purified water to obtain a sample solution for preparative liquid chromatography. As conditions for preparative liquid chromatography, Shodex SUGAR KS-2002 is used as a column, Shodex SUGAR KS-LG is used as a guard column, purified water is used as an eluent, a flow rate is 5 ml / min, and a column temperature is 80. Separation was performed at 0 ° C., and the peak was monitored with a detector RI, and only the oligosaccharide peak bound to the inositol residue was collected and collected. After freezing the collected liquid, 8.5 g of white powder of glucosyl inositol (hereinafter referred to as GI-3) was obtained by lyophilization. From the results of LC-MS analysis, the component ratio of GI-3 is that the number of glucose chains bound to inositol is 1% 51%, 2% 35%, 3% 10%, 4% 3% Five were 1%. Moreover, GI-3 was odorless and its solubility in water was extremely high.
表5に示す化粧水を常法に基づき作製した(サンプル3−1)。この化粧水を30歳〜40歳の女性3名の前腕屈側部に朝夕1日2回、7日間塗布した。8日目朝の角質水分量を、インピーダンスメーター(IBS社製 SKICON−200)を用いた高周波インダクタンス法による伝導度測定を指標に比較した。結果を表6に示した。GI−3を含むサンプル3−1を使用することで伝導度の向上が見られ、角質水分量が増大して肌の潤いが増すことが示された。 The lotion shown in Table 5 was produced based on a conventional method (Sample 3-1). This lotion was applied to the forearm flexion side of three women aged 30 to 40 years twice a day for 7 days. The amount of horny water in the morning of the 8th day was compared with the conductivity measurement by the high frequency inductance method using an impedance meter (SKICON-200 manufactured by IBS) as an index. The results are shown in Table 6. It was shown that the conductivity was improved by using Sample 3-1 containing GI-3, and the amount of keratin moisture was increased to increase the moisture of the skin.
〔比較例5〜7〕
表5に示す化粧水を常法に基づき作製した(サンプル3−2〜3−4)。実施例5と同様の試験を行った。結果を表6に示した。
[Comparative Examples 5 to 7]
The lotions shown in Table 5 were prepared based on conventional methods (Samples 3-2 to 3-4). The same test as in Example 5 was performed. The results are shown in Table 6.
表7に示す乳液を常法に基づき作製した(サンプル4−1)。これを実施例5と同様に30歳〜40歳の女性3名の前腕屈側部に朝夕1日2回、7日間塗布して、8日目朝の角質水分量をインピーダンスメーターによる測定を指標に比較した。これら結果を表8に示した。GI−3を含むサンプル4−1を使用することで伝導度の向上が見られ、角質水分量が増大して肌の潤いが増すことが示された。 The emulsion shown in Table 7 was produced based on a conventional method (Sample 4-1). As in Example 5, this was applied to the forearm flexion side of three women aged 30 to 40 years twice a day in the morning and evening for 7 days, and the morning keratin water content was measured using an impedance meter as an index. Compared to. These results are shown in Table 8. It was shown that the conductivity was improved by using Sample 4-1 containing GI-3, and the amount of keratin moisture was increased to increase the moisture of the skin.
〔比較例8〜10〕
表7に示す乳液を常法に基づき作製した(サンプル4−2〜4−4)。実施例5と同様の試験を行った。結果を表8に示した。
[Comparative Examples 8 to 10]
The emulsion shown in Table 7 was produced based on a conventional method (Samples 4-2 to 4-4). The same test as in Example 5 was performed. The results are shown in Table 8.
表9に示すクリームを常法に基づき作製した(サンプル5−1)。これを実施例5と同様に30歳〜40歳の女性3名の前腕屈側部に朝夕1日2回、7日間塗布して、8日目朝の角質水分量をインピーダンスメーターによる測定を指標に比較した。これら結果を表10に示した。GI−3を含むサンプル5−1を使用することで伝導度の向上が見られ、角質水分量が増大して肌の潤いが増すことが示された。 The cream shown in Table 9 was produced based on a conventional method (Sample 5-1). As in Example 5, this was applied to the forearm flexion of three women aged 30 to 40 years twice a day for 7 days in the morning and evening, and the morning keratin water content was measured with an impedance meter as an indicator. Compared to. These results are shown in Table 10. It was shown that the conductivity was improved by using Sample 5-1 containing GI-3, and the amount of keratin moisture was increased to increase the moisture of the skin.
〔比較例11〜13〕
表9に示すクリームを常法に基づき作製した(サンプル5−2〜5−4)。実施例5と同様の試験を行った。結果を表10に示した。
[Comparative Examples 11 to 13]
Creams shown in Table 9 were prepared based on a conventional method (Samples 5-2 to 5-4). The same test as in Example 5 was performed. The results are shown in Table 10.
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WO2019045113A1 (en) | 2017-09-04 | 2019-03-07 | 昭和電工株式会社 | Mixture of inositol derivatives |
EP4197522A1 (en) | 2021-12-20 | 2023-06-21 | Clariant International Ltd | Composition comprising galactinol and use thereof |
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WO2019045113A1 (en) | 2017-09-04 | 2019-03-07 | 昭和電工株式会社 | Mixture of inositol derivatives |
US11384372B2 (en) | 2017-09-04 | 2022-07-12 | Showa Denko K.K. | Method for producing inositol derivative |
EP4197522A1 (en) | 2021-12-20 | 2023-06-21 | Clariant International Ltd | Composition comprising galactinol and use thereof |
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