JP4602712B2 - Spacer for slime removal container - Google Patents
Spacer for slime removal container Download PDFInfo
- Publication number
- JP4602712B2 JP4602712B2 JP2004228766A JP2004228766A JP4602712B2 JP 4602712 B2 JP4602712 B2 JP 4602712B2 JP 2004228766 A JP2004228766 A JP 2004228766A JP 2004228766 A JP2004228766 A JP 2004228766A JP 4602712 B2 JP4602712 B2 JP 4602712B2
- Authority
- JP
- Japan
- Prior art keywords
- spacer
- container
- slime
- hole
- inlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 229940079593 drug Drugs 0.000 claims description 17
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- 230000000844 anti-bacterial effect Effects 0.000 description 13
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- 229940121375 antifungal agent Drugs 0.000 description 8
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- 230000005540 biological transmission Effects 0.000 description 6
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- 239000011230 binding agent Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
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- -1 phenyl- 2-cyano-2-chlorovinyl Chemical group 0.000 description 4
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- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 1
- VMSAZQFOVQLLSK-UHFFFAOYSA-N 2-fluoro-4-[1,2,2-tris(3-fluoro-4-hydroxyphenyl)ethyl]phenol Chemical compound C1=C(F)C(O)=CC=C1C(C=1C=C(F)C(O)=CC=1)C(C=1C=C(F)C(O)=CC=1)C1=CC=C(O)C(F)=C1 VMSAZQFOVQLLSK-UHFFFAOYSA-N 0.000 description 1
- YMVICGPFTOKTIL-UHFFFAOYSA-N 4,5-dichlorodithiolan-3-one Chemical compound ClC1SSC(=O)C1Cl YMVICGPFTOKTIL-UHFFFAOYSA-N 0.000 description 1
- HDPBBNNDDQOWPJ-UHFFFAOYSA-N 4-[1,2,2-tris(4-hydroxyphenyl)ethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)C(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 HDPBBNNDDQOWPJ-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- CUMPQIIAQMODFR-UHFFFAOYSA-N 5-chloro-4-phenyldithiolan-3-one Chemical compound ClC1SSC(=O)C1C1=CC=CC=C1 CUMPQIIAQMODFR-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- WJLVQTJZDCGNJN-UHFFFAOYSA-N Chlorhexidine hydrochloride Chemical compound Cl.Cl.C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 WJLVQTJZDCGNJN-UHFFFAOYSA-N 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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- 206010040880 Skin irritation Diseases 0.000 description 1
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- SGWRWDCSSFPSPP-UHFFFAOYSA-N [Na].[N+]=1(C(=CC=CC1)S)[O-].[N+]=1(C(=CC=CC1)S)[O-] Chemical compound [Na].[N+]=1(C(=CC=CC1)S)[O-].[N+]=1(C(=CC=CC1)S)[O-] SGWRWDCSSFPSPP-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
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- 125000000217 alkyl group Chemical group 0.000 description 1
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- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- PQRDTUFVDILINV-UHFFFAOYSA-N bcdmh Chemical compound CC1(C)N(Cl)C(=O)N(Br)C1=O PQRDTUFVDILINV-UHFFFAOYSA-N 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
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- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
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- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- XAAHAAMILDNBPS-UHFFFAOYSA-L calcium hydrogenphosphate dihydrate Chemical compound O.O.[Ca+2].OP([O-])([O-])=O XAAHAAMILDNBPS-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
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- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 229960003333 chlorhexidine gluconate Drugs 0.000 description 1
- YZIYKJHYYHPJIB-UUPCJSQJSA-N chlorhexidine gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.C1=CC(Cl)=CC=C1NC(=N)NC(=N)NCCCCCCNC(=N)NC(=N)NC1=CC=C(Cl)C=C1 YZIYKJHYYHPJIB-UUPCJSQJSA-N 0.000 description 1
- 229960004504 chlorhexidine hydrochloride Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
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- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
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Description
本発明は、排水口部分に設置するためには、形状や大きさが合わないヌメリ取り容器を簡便に固定することができるヌメリ取り容器用スペーサーに関する。 The present invention relates to a slime removing container spacer capable of simply fixing a slime removing container whose shape and size are not suitable for installation at a drain outlet.
台所流し台や風呂場の排水口のヌメリの主成分は、食材、界面活性剤、石鹸、人の垢等が細菌の栄養源となり、そのとき細菌から分泌されるポリサッカライドであることが知られている。本出願人らは、これらのヌメリ防除剤として、5−クロロ−2−メチル−4−イソチアゾリン−3−オンと多分子系ホスト化合物とからなる包接化合物を加圧成形してなるヌメリ防除剤(特許文献1)や、有機ヨード系抗菌剤と固体酸とを加圧成形してなるヌメリ防除剤(特許文献2)を提案している。また、これらのヌメリ防除剤の収納容器に関しても提案している(特許文献3、4)。ところで、最近は、様々な種類の流し台が提案され、それに応じて排水口の形状や大きさも変化している。
上記ヌメリ防除剤の収納容器を様々な種類の形状や大きさの排水口に設置するためには、容器の形状や大きさを改良する必要がある。ところで、上記ヌメリ防除剤を適度な溶解速度でヌメリ防除効果を効果的に発揮させるためには、該容器中に排水流入孔や排水流出孔等を設けたり、それらの位置や大きさ等を調節することでヌメリ防除剤を適度な溶解速度にコントロールする必要がある。そして、容器の形状や大きさを改良する場合は、同時に排水流入孔や排水流出孔等の位置や大きさ等も改良しなければならなく、様々な種類の排水口の形状や大きさ等に合わせるヌメリ防除剤の収納容器の改良には多大な時間と労力が必要であった。 In order to install the storage container for the slime control agent in drains of various types and sizes, it is necessary to improve the shape and size of the container. By the way, in order to effectively exert the slime control effect at a moderate dissolution rate, the above-mentioned slime control agent is provided with drainage inflow holes, drainage outflow holes, etc. in the container, and their positions and sizes are adjusted. Therefore, it is necessary to control the slime control agent to an appropriate dissolution rate. And when improving the shape and size of the container, the position and size of the drainage inlet and drainage outlet must be improved at the same time. It took a lot of time and effort to improve the storage container for the slime control agent.
本発明の課題は、排水口の入口部又は上部に設置するには形状や大きさが合わない、ヌメリ取り用の固形薬剤が収納された容器を、簡便に固定することにある。 An object of the present invention is to simply fix a container containing a solid medicine for removing slime, which does not fit in the shape and size to be installed at the inlet or upper part of a drain outlet.
本発明者らは、既に形状等が定まっているヌメリ取り用の固形薬剤が収納された現行の容器の改良を行わないで、該容器に対して、若干大きくなった排水口の入口部又は上部に固定できないかを検討した結果、該容器と排水口の入口部又は上部の間にスペーサーを設けることで、現行の容器自体の改良を行わなくても適度な薬剤溶解速度を維持でき、簡便に排水口の入口部又は上部に固定できることを見い出し、本発明を完成するに至った。 The present inventors do not improve the current container in which the solid medicine for removing slime that has already been determined in shape and the like. As a result of examining whether it can be fixed to the container, by providing a spacer between the container and the inlet or upper part of the drain, it is possible to maintain an appropriate drug dissolution rate without improving the current container itself, and easily It was found that it can be fixed to the inlet or the upper part of the drain outlet, and the present invention has been completed.
すなわち、本発明は、
(1)ヌメリ取り用の固形薬剤が収納された容器と、排水口の入口部又は上部の間に設けられるスペーサーであって、該容器を、排水口の入口部又は上部に固定するために、該スペーサーの外径が、排水口の入口部又は上部の孔の内径よりも大きく、該スペーサーの内径が、該容器の外径よりも小さい形状を有し、かつ該スペーサーの上部に該容器と嵌合する嵌合部が設けられたことを特徴とする、ヌメリ取り用の固形薬剤が収納された容器を様々な種類の形状や大きさの排水口に設置するためのヌメリ取り容器用スペーサーに関し、
(2)嵌合部に突起が設けられたことを特徴とする(1)記載のヌメリ取り容器用スペーサーに関し、
(3)スペーサーの内径が、該容器の内径よりも小さいことを特徴とする(1)又は(2)記載のヌメリ取り容器用スペーサーに関し、
(4)スペーサーの上部に内周に沿って土手部が設けられたことを特徴とする(1)〜(3)いずれか記載のヌメリ取り容器用スペーサーに関し、
(5)スペーサーに溶解液流入孔及び溶解液流出孔が設けられたことを特徴とする(1)〜(4)いずれか記載のヌメリ取り容器用スペーサーに関し、
(6)溶解液流入孔及び溶解液流出孔がスリット孔であることを特徴とする(5)記載のヌメリ取り容器用スペーサーに関し、
(7)溶解液流入孔及び溶解液流出孔が溝孔であることを特徴とする(5)記載のヌメリ取り容器用スペーサーに関し、
(8)スペーサーに溶解液流入孔及び溶解液流出孔が設けられる場合、溶解液流入孔及び溶解液流出孔を設けた個所の該スペーサーの下部に、さらに溶解液伝達リブが設けられたことを特徴とする(5)〜(7)いずれか記載のヌメリ取り容器用スペーサーに関し、
(9)容器が排水口に設けられる蓋であることを特徴とする(1)〜(8)いずれか記載のヌメリ取り容器用スペーサーに関する。
That is, the present invention
(1) A spacer provided between a container in which a solid medicine for removing slime is stored and an inlet part or upper part of a drain outlet, and for fixing the container to the inlet part or upper part of the drain outlet, The outer diameter of the spacer is larger than the inner diameter of the inlet port or upper hole of the drain port, the inner diameter of the spacer is smaller than the outer diameter of the container, and the container is formed on the upper portion of the spacer. A slime-removing container spacer for installing a container containing a solid medicine for slime removal in various kinds of shapes and sizes of drainage ports, characterized in that a fitting part for fitting is provided. ,
(2) With respect to the slime-removing container spacer according to (1), wherein the protrusion is provided in the fitting portion.
(3) The spacer for a slime removing container according to (1) or (2), wherein the inner diameter of the spacer is smaller than the inner diameter of the container,
(4) The slime removing container spacer according to any one of (1) to (3), wherein a bank portion is provided along the inner periphery of the upper portion of the spacer.
(5) The spacer for a slime removing container according to any one of (1) to (4), wherein the spacer is provided with a solution inflow hole and a solution outflow hole.
(6) The slime removing container spacer according to (5), wherein the solution inflow hole and the solution outflow hole are slit holes,
(7) The slime removing container spacer according to (5), wherein the solution inflow hole and the solution outflow hole are groove holes,
(8) When the solution inflow hole and the solution outflow hole are provided in the spacer, a solution transmission rib is further provided below the spacer where the solution inflow hole and the solution outflow hole are provided. Regarding the spacer for slime removing container according to any one of (5) to (7),
(9) The present invention relates to the slime removing container spacer according to any one of (1) to (8), wherein the container is a lid provided at a drain outlet.
また、本発明は、
(10)(1)〜(9)いずれか記載のヌメリ取り容器用スペーサーと、ヌメリ取り用の固形薬剤が収納された容器とからなり、該容器に該スペーサーの嵌合部と嵌合する被嵌合を設け、該容器と該スペーサーが着脱自在に取りつけられたことを特徴とするヌメリ取り容器に関する。
The present invention also provides:
(10) A slime-removing container spacer according to any one of (1) to (9), and a container in which a solid medicine for slime-removing is stored, and the container fitted with the fitting portion of the spacer. The present invention relates to a slime removing container characterized in that a fitting is provided and the container and the spacer are detachably attached.
本発明のヌメリ取り容器用スペーサーは、排水口の入口部又は上部に設置するには形状や大きさが合わない、ヌメリ取り用の固形薬剤が収納された容器を、簡便に固定することができ、既に形状等が定まっている現行の容器の改良を行わなくても適度な薬剤溶解速度を維持できるので、簡便な改良で様々な種類の排水口に該容器を設置するために使用できる。 The spacer for slime removal container of the present invention can easily fix a container containing a solid medicine for slime removal that does not fit in shape or size to be installed at the inlet or upper part of the drainage port. Since an appropriate drug dissolution rate can be maintained without improving the current container whose shape has already been determined, it can be used to install the container at various types of drainage outlets with simple improvement.
本発明のヌメリ取り容器用スペーサーは、該スペーサーの外径が排水口の入口部又は上部の孔の内径よりも大きく、該スペーサーの内径が、ヌメリ取り用の固形薬剤が収納された容器の外径よりも小さい形状を有し、かつ該スペーサーの上部に該容器と嵌合する嵌合部が設けられたことを特徴とし、排水口の入口部又は上部の孔の内径よりも該容器の外径が小さい場合に、該容器を排水口の入口部又は上部に固定するために使用できる。 The spacer for the slime removing container of the present invention has an outer diameter larger than the inner diameter of the inlet port or upper hole of the drain, and the inner diameter of the spacer is outside the container in which the solid medicine for slime removal is stored. It has a shape smaller than the diameter, and is provided with a fitting part that fits the container at the upper part of the spacer. The outer part of the container is larger than the inner diameter of the inlet part of the drain outlet or the upper hole. When the diameter is small, it can be used to fix the container at the inlet or upper part of the drain.
また、該嵌合部としては、該容器の被嵌合部に回転させて嵌合できるように突起を設けるのが好ましい。このように該嵌合部に突起を設け、該容器の被嵌合部に回転させて嵌合することで、該スペーサーと該容器をしっかり固定でき、かつ該スペーサーと該容器とを容易に着脱可能にすることができる。 Moreover, as this fitting part, it is preferable to provide a protrusion so that it can be rotated and fitted to the to-be-fitted part of this container. Thus, by providing a protrusion on the fitting portion and rotating and fitting the fitting portion of the container, the spacer and the container can be firmly fixed, and the spacer and the container can be easily attached and detached. Can be possible.
また、本発明のヌメリ取り容器用スペーサーは、排水口の入口部又は上部の孔の内径よりもヌメリ取り用の固形薬剤が収納された容器の外径が小さい場合に、該容器を排水口の入口部又は上部に固定するために使用できる。従って、このような場合は、必然的に該スペーサーの内径が、排水口の入口部又は上部の孔の内径よりも小さな形状になっている。そして、該容器から流出してくる薬剤溶解液は該スペーサーの内側及び外側の両側から、排水口の入口部又は上部の孔に流出することになる。内側から流出する薬剤溶解液は、排水口のヌメリ発生面に接触しないで流出する薬剤溶解液が生じてくる。このような場合は、薬剤溶解液をヌメリ発生面により効率的に接触させるために、該スペーサーの内側を高くし、外側が低くなるように傾斜を設けたり、該スペーサーの上部に内周に沿って土手部を設けることで該スペーサーの外側から薬剤溶解液を排水口に流出することができる。 In addition, the slime removing container spacer of the present invention can be used when the outer diameter of the container in which the solid medicine for removing slime is stored is smaller than the inner diameter of the inlet or upper hole of the drain. Can be used to secure at the entrance or top. Accordingly, in such a case, the inner diameter of the spacer is inevitably smaller than the inner diameter of the inlet portion of the drain port or the upper hole. Then, the drug solution flowing out from the container flows out from both the inside and outside of the spacer to the inlet port or the upper hole of the drainage port. The drug solution that flows out from the inner side generates a drug solution that flows out without contacting the slime generation surface of the drainage port. In such a case, in order to make the drug solution come into contact more efficiently with the slime generation surface, the inner side of the spacer is raised and the outer side is lowered, or the upper part of the spacer is along the inner circumference. By providing the bank portion, the drug solution can be discharged from the outside of the spacer to the drain port.
また、本発明のヌメリ取り容器用スペーサーは、ヌメリ取り用の固形薬剤が収納された容器を排水口の入口部又は上部に固定できる形状であれば、薬剤溶解液を排水口のヌメリ発生面に広がらせることができるが、該スペーサーにさらに溶解液流入孔及び溶解液流出孔を設けたほうがより効率的に溶解液を排水口のヌメリ発生面に広がらせることができ好ましい。このような溶解液流入孔及び溶解液流出孔は、1又は2以上設けることができる。 In addition, the slime removing container spacer of the present invention has a shape that can fix the container containing the solid medicine for removing slime to the inlet part or the upper part of the drain outlet, and the drug solution is applied to the slime generation surface of the drain outlet. Although it is possible to spread the solution, it is preferable to further provide a solution inflow hole and a solution outflow hole in the spacer because the solution can be more efficiently spread on the slime generation surface of the drain outlet. One or two or more such solution inflow holes and solution outflow holes can be provided.
このような溶解液流入孔及び溶解液流出孔としては、例えば、スリット孔又は溝孔を挙げることができる。スリット孔を設ける場合は、スペーサー外側より中心部に向かい、該スペーサーの上部から下部に向けて貫通孔を設けることであり、薬剤溶解液がスペーサー上部から流入し、スペーサーの下部から流出することで、排水口のヌメリ発生面に効率的に広がらせることができる。スリット孔の幅は、通常0.5〜5.0mm、好ましくは0.5〜4.0mm、より好ましくは0.5〜3.0mmの範囲である。また、スリット孔の長さは、排水口の入口部又は上部の孔の内側にスリット孔が出るように適宜調節する。その際のスリット孔の長さは、排水口の入口部又は上部の孔の内側から、通常0.01〜4.0mm、好ましくは0.05mm〜3.0mm、特に好ましくは0.1〜2.0mmの範囲に適宜調節する。 Examples of such a solution inflow hole and a solution outflow hole include a slit hole or a groove hole. When the slit hole is provided, the through hole is provided from the outside of the spacer toward the center and from the top to the bottom of the spacer, and the drug solution flows from the top of the spacer and flows out from the bottom of the spacer. , It can be efficiently spread on the surface of the drainage outlet. The width | variety of a slit hole is 0.5-5.0 mm normally, Preferably it is 0.5-4.0 mm, More preferably, it is the range of 0.5-3.0 mm. Further, the length of the slit hole is appropriately adjusted so that the slit hole appears inside the inlet part of the drain outlet or the upper hole. In this case, the length of the slit hole is usually 0.01 to 4.0 mm, preferably 0.05 mm to 3.0 mm, particularly preferably 0.1 to 2, from the inside of the inlet or upper hole of the drain port. Adjust as appropriate within the range of 0.0 mm.
また、溝孔を設ける場合は、スペーサー外側より中心部に向かい、スペーサーの下部から上部に貫通しない程度の孔を設けることであり、薬剤溶解液がスペーサー側面から流入し、スペーサーの下部から流出することで、排水口のヌメリ発生面に効率的に広がらせることができる。溝孔の幅は、通常0.5〜5.0mm、好ましくは0.5〜4.0mm、より好ましくは0.5〜3.0mmの範囲である。また、溝孔の長さは、排水口の入口部又は上部の孔の内側に溝孔が出るように適宜調節する。その際の溝孔の長さは、排水口の入口部又は上部の孔の内側から、通常0.05〜5.0mm、好ましくは0.1mm〜4.0mm、特に好ましくは0.5〜3.0mmの範囲に適宜調節する。また、溝孔の深さは、用いるスペーサーの厚さにもよるが、通常0.1〜2.0mm、好ましくは0.2〜1.5mm、より好ましくは0.3〜1.0mmの範囲である。 In addition, when providing a groove hole, it is to provide a hole from the outside of the spacer toward the center and not penetrating from the lower part of the spacer to the upper part. The drug solution flows from the side of the spacer and flows out from the lower part of the spacer. Thus, it can be efficiently spread on the slime generation surface of the drain outlet. The width | variety of a slot is 0.5-5.0 mm normally, Preferably it is 0.5-4.0 mm, More preferably, it is the range of 0.5-3.0 mm. Further, the length of the groove hole is appropriately adjusted so that the groove hole appears inside the inlet portion of the drain outlet or the upper hole. The length of the groove hole at that time is usually 0.05 to 5.0 mm, preferably 0.1 mm to 4.0 mm, particularly preferably 0.5 to 3 from the inside of the inlet portion of the drain outlet or the upper hole. Adjust as appropriate within the range of 0.0 mm. Moreover, although the depth of a groove hole is based also on the thickness of the spacer to be used, it is 0.1-2.0 mm normally, Preferably it is 0.2-1.5 mm, More preferably, it is the range of 0.3-1.0 mm. It is.
また、本発明のヌメリ取り容器用スペーサーに排水流入孔及び排水流出孔を設ける場合は、溶解液流入孔及び溶解液流出孔を設けた個所のスペーサーの下部に、排水口の入口部又は上部のヌメリ発生面に薬剤溶解液をさらに効率的に広がらせる目的で溶解液伝達リブを設けることができる。溶解液伝達リブの幅は、通常0.1mm〜5.0mm、好ましくは0.3〜3.0mm、より好ましくは0.5〜2.0mmの範囲である。また、溶解液伝達リブの長さは、通常0.1〜3.0mm、好ましくは0.3〜2.5mm、より好ましくは0.5〜2.0mmの範囲である。 In addition, when the drainage inlet and drainage holes are provided in the slime removing container spacer of the present invention, the lower part of the spacer where the solution inlet and outlet holes are provided, the inlet or upper part of the drain outlet For the purpose of spreading the drug solution more efficiently on the slime generation surface, a solution transfer rib can be provided. The width | variety of a solution transmission rib is 0.1 mm-5.0 mm normally, Preferably it is 0.3-3.0 mm, More preferably, it is the range of 0.5-2.0 mm. Moreover, the length of the solution transmission rib is usually in the range of 0.1 to 3.0 mm, preferably 0.3 to 2.5 mm, more preferably 0.5 to 2.0 mm.
また、排水口の入口部又は上部には、通常排水口用のゴミ取り籠が設けられるが、そのような場合は、排水口の入口部又は上部の孔とは、ゴミ取り籠を設けたときの孔を意味する。 In addition, a waste bin for drainage is usually provided at the inlet or upper part of the drainage port. In such a case, the inlet or upper hole of the drainage port is defined as a garbage collector. Means the hole.
本発明のヌメリ取り容器用スペーサーの材質は特に制限はされないが、プラスチック、ゴム、金属等各種公知のものが使用可能である。また、これらスペーサーの材質として、抗菌処理が施されたものを用いることもできる。抗菌処理の方法としては、従来公知の抗菌処理方法であれば特に制限されないが、例えば抗菌剤を材質の一部として含有させたり、表面にコーティングする処理方法を挙げることができる。抗菌処理に用いられる抗菌剤としては、バクテリアやカビ等に対する広範囲な抗菌スペクトルを有し、水に対する溶解度が小さいものであればどのようなものでもよいが、樹脂成形時の熱に耐えられる2−ピリジンチオール−1−オキシド亜鉛等が好ましい。 The material for the slime removing container spacer of the present invention is not particularly limited, but various known materials such as plastic, rubber, and metal can be used. In addition, a material subjected to antibacterial treatment can be used as a material for these spacers. The antibacterial treatment method is not particularly limited as long as it is a conventionally known antibacterial treatment method. Examples of the antibacterial treatment method include a treatment method in which an antibacterial agent is contained as a part of the material or the surface is coated. The antibacterial agent used for the antibacterial treatment may be any antibacterial spectrum as long as it has a broad antibacterial spectrum against bacteria and fungi and has low solubility in water, but can withstand heat during resin molding. Pyridine thiol-1-oxide zinc and the like are preferable.
本発明のヌメリ取り容器用スペーサーの厚さは特に制限されないが、通常0.2mm〜5.0mm、好ましくは0.3mm〜4.0mm、より好ましくは0.5mm〜3.0mmの範囲である。また、形状は、円形であっても四角形であっても特に制限はされなく、排水口の入口部又は上部の孔の形状によって適宜選択され、スペンサーの大きさも排水口の入口部又は上部の孔の形状によって適宜選択される。 The thickness of the slime removing container spacer of the present invention is not particularly limited, but is usually in the range of 0.2 mm to 5.0 mm, preferably 0.3 mm to 4.0 mm, more preferably 0.5 mm to 3.0 mm. . The shape is not particularly limited, whether it is circular or square, and is appropriately selected according to the shape of the inlet or upper hole of the drain, and the size of the spencer is also the hole of the inlet or upper of the drain. It is appropriately selected depending on the shape.
本発明のヌメリ取り容器用スペーサーは、その上部にヌメリ取り用の固形薬剤が収納された容器を、排水口の入口部又は上部に固定するために使用するが、ヌメリ取り用の固形薬剤としては、殺菌剤、抗菌剤、防黴剤を含むものであり、殺菌剤、抗菌剤、防黴剤としては、塩素系酸化剤、過酸化物、ヨウ素系殺菌剤、亜硫酸塩抗菌剤等いずれのものであってもよいが、刺激性のガスを発生せず人体に安全であり、殺菌力があり充分なヌメリ取り効果が得られ、皮膚刺激性がなく、水に容易に溶解して薬用効果が持続されるものが好ましい。このような殺菌剤、抗菌剤、防黴剤としては、例えば、塩素系酸化剤としては、ジクロロジメチルヒダントイン、ブロモクロルジメチルヒダントイン、ジクロルイソシアヌル酸ナトリウム及びトリクロルイソシアヌル酸、次亜塩素酸カルシウム等を例示することができ、また、塩素系酸化剤以外の薬剤としては、過炭素ナトリウム、過硫酸カリウム、過ほう酸ナトリウム、オルトフェニルフェノール、ジフェニル、2−イソプロピル−5−メチルフェノール、パラクロロメタキシレノール、パラヒドロキシ安息香酸n−ブチル、塩化ベンザルコニウム、塩化ベンゼトニウム、塩酸クロルへキシジン、グルコン酸クロルヘキシジン、メチレンビスチオシアネート、2−ピリジンチオール−1−オキシド、2−ピリジンチオール−1−オキシド亜鉛、2−ピリジンチオール−1−オキシドナトリウム、N,N′−ヘキサメチレンビス(4−カルバモイル−1−デシルピリジニウムブロマイド)、4,4′−(テトラメチレンジアミノ)ビス(1−デシルピリジニウムブロマイド)、2−ブロモ−2−ニトロプロパン−1,3−ジオール等を例示することができる。また、2,3,3−トリヨードアリルアルコール類、2,3,3−トリヨードアリルエーテル類等の有機ヨード系抗菌剤も抗菌スペクトルが広く、人体に安全な点で好適である。 The slime-removing container spacer of the present invention is used to fix a container containing a slime-removing solid medicine at the upper part thereof to the inlet or upper part of the drainage port. , Including bactericides, antibacterial agents, and antifungal agents. As bactericides, antibacterial agents, and antifungal agents, any of chlorine-based oxidants, peroxides, iodine-based bactericides, sulfite antibacterial agents, etc. However, it does not generate irritating gas, is safe for the human body, has sterilizing power, has a sufficient slime-removing effect, has no skin irritation, and easily dissolves in water and has medicinal effects. What is sustained is preferred. Examples of such bactericides, antibacterial agents, and antifungal agents include chlorinated oxidants such as dichlorodimethylhydantoin, bromochlorodimethylhydantoin, sodium dichloroisocyanurate, trichloroisocyanuric acid, calcium hypochlorite, and the like. Examples of agents other than chlorinated oxidants include sodium percarbonate, potassium persulfate, sodium perborate, orthophenylphenol, diphenyl, 2-isopropyl-5-methylphenol, parachlorometaxylenol, N-butyl parahydroxybenzoate, benzalkonium chloride, benzethonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, methylenebisthiocyanate, 2-pyridinethiol-1-oxide, 2-pyridinethiol-1-oxide 2-pyridinethiol-1-oxide sodium, N, N′-hexamethylenebis (4-carbamoyl-1-decylpyridinium bromide), 4,4 ′-(tetramethylenediamino) bis (1-decylpyridinium bromide), Examples thereof include 2-bromo-2-nitropropane-1,3-diol. Organic iodine antibacterial agents such as 2,3,3-triiodoallyl alcohols and 2,3,3-triiodoallyl ethers are also suitable in view of their broad antibacterial spectrum and safety to the human body.
更に、ヌメリ取り用の固形薬剤として、殺菌剤、抗菌剤、防黴剤等をゲスト化合物とし、ゲスト化合物と共に結晶性錯体を形成する多分子系ホスト化合物とからなる包接化合物は、殺菌剤、抗菌剤、又は防黴剤を経時に従って放出し、ヌメリ防除作用を持続して得ることができるため、好適に使用することができる。包接化合物のゲスト化合物に適用される殺菌剤、防黴剤又は抗菌剤としては、例えば、5−クロロ−2−メチル−4−イソチアゾリン−3−オン、2−メチル−4−イソチアゾリン−3−オン、4,5−ジクロロ−3−n−オクチル−イソチアゾリン−3−オン、1,2−ベンズイソチアゾリン−3−オン、2−メトキシカルボニルベンズイミダゾール、2,3,5,6−テトラクロロ−4−メタンスルホニルピリジン、2−チオシアノメチベンゾチアゾール、2,2−ジチオ−ビス−(ピリジン−1−オキサイド)、3,3,4,4−テトラハイドロチオフェン−1,1−ジオキサイド、4,5−ジクロロ−1,2−ジチオラン−3−オン、5−クロロ−4−フェニル−1,2−ジチオラン−3−オン、N−メチルピロリドン、フェニル−(2−シアノ−2−クロロビニル)スルホン、メチレンビスチオシアネート、2−ブロモ−2−ニトロプロパン−1,3−ジオール、2,2−ジブロモ−2−エタノール、2−ブロモ−4′−ヒドロキシアセトフェノン、ジブロモニトリルプロピオンアミド、2−ブロモ−2−ブロモメチルグルタルニトリル等を、また天然製油類としては、例えば、シネオール、ヒノキチオール、メントール、テルピネオール、チモール等を例示することができる。多分子系ホスト化合物としては、例えば、1,1,2,2−テトラキス(4−ヒドロキシフェニル)エタン、1,1,2,2−テトラキス(3−フルオロ−4−ヒドロキシフェニル)エタン等のテトラキスフェノ−ル類、1,1,6,6−テトラフェニル−2,4−ヘキサジイン−1,6−ジオール、1,6−ビス(2−クロロフェニル)−1,6−ジフェニルヘキサン−2,4−ジイン−1,6−ジオール等を例示することができる。 Furthermore, as a solid agent for removing slime, a clathrate compound comprising an antibacterial agent, an antibacterial agent, an antifungal agent and the like as a guest compound, and a multimolecular host compound that forms a crystalline complex with the guest compound, Since an antibacterial agent or an antifungal agent can be released over time and a slime control effect can be obtained continuously, it can be suitably used. Examples of the bactericidal agent, antifungal agent or antibacterial agent applied to the guest compound of the inclusion compound include 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazoline-3- ON, 4,5-dichloro-3-n-octyl-isothiazolin-3-one, 1,2-benzisothiazolin-3-one, 2-methoxycarbonylbenzimidazole, 2,3,5,6-tetrachloro-4 -Methanesulfonylpyridine, 2-thiocyanomethybenzothiazole, 2,2-dithio-bis- (pyridine-1-oxide), 3,3,4,4-tetrahydrothiophene-1,1-dioxide, 4, 5-dichloro-1,2-dithiolane-3-one, 5-chloro-4-phenyl-1,2-dithiolane-3-one, N-methylpyrrolidone, phenyl- 2-cyano-2-chlorovinyl) sulfone, methylenebisthiocyanate, 2-bromo-2-nitropropane-1,3-diol, 2,2-dibromo-2-ethanol, 2-bromo-4'-hydroxyacetophenone, Examples of dibromonitrile propionamide, 2-bromo-2-bromomethylglutaronitrile, and natural oils include cineol, hinokitiol, menthol, terpineol, and thymol. Examples of the multimolecular host compound include tetrakis such as 1,1,2,2-tetrakis (4-hydroxyphenyl) ethane and 1,1,2,2-tetrakis (3-fluoro-4-hydroxyphenyl) ethane. Phenols, 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol, 1,6-bis (2-chlorophenyl) -1,6-diphenylhexane-2,4- Examples include diyne-1,6-diol.
前記固形薬剤には、これらの抗菌剤、防黴剤、抗菌剤が排水と接触した際必要以上に薬剤が溶解されて流出することを防止し、適度な速度で接触した排水に溶解させるため、配合物と混合して加圧成形、加熱溶融混合、混練り押し出し成形等の公知の方法により適当な大きさに成形することができる。配合物としては、各種公知の賦形剤、溶解調整剤、結合剤、滑沢剤、界面活性剤、腐食防止剤等を例示することができる。特に界面活性剤は溶解液がヌメリ発生壁面に拡散され、容器が油で汚れることを防止するのに有効である。界面活性剤としては、アルキルアルカノールアミド類、ジアルキルスルホコハク酸ナトリウム、ラウリル硫酸ナトリウム等を例示することができ、これら界面活性剤は全固形薬剤重量に対して0.5〜10重量%の割合で使用することができる。 In the solid medicine, these antibacterial agents, antifungal agents, and antibacterial agents are prevented from dissolving and flowing out more than necessary when the antibacterial agent comes into contact with the wastewater, and dissolved in the wastewater contacted at an appropriate rate. It can be mixed with the compound and formed into an appropriate size by a known method such as pressure molding, heat-melt mixing, kneading and extrusion molding. Examples of the blend include various known excipients, dissolution regulators, binders, lubricants, surfactants, corrosion inhibitors, and the like. In particular, the surfactant is effective in preventing the solution from diffusing on the slime-generating wall and soiling the container with oil. Examples of the surfactant include alkyl alkanolamides, sodium dialkylsulfosuccinate, sodium lauryl sulfate, etc., and these surfactants are used at a ratio of 0.5 to 10% by weight based on the total solid drug weight. can do.
賦形剤、結合剤、溶解調整剤としては、例えば、燐酸水素カルシウム2水和物、燐酸3カルシウム無水物、燐酸水素マグネシウム3水和物、燐酸水素マグネシウム8水和物、クエン酸カルシウム4水和物、硫酸カルシウム0.5水和物、アセト酢酸アニリド、アセト酢酸−o−トルイダイド、アセト酢酸−p−トルイダイド、アセト酢酸−o−アニシダイド、乳糖、ヒドロキシプロピルセルロース、アラビアゴム(粉末)、ポリビニルアルコール、ポリビニルピロリドン、デキストリン、C14〜C24の飽和脂肪酸類等を例示することができ、これらのものは加圧成形性を向上することができ、また、各種洗剤等が混入しても反応して有毒ガス等が発生することが無いので好ましく、これら賦形剤や結合剤、溶解調整剤は全固形薬剤重量に対して1〜99重量%の割合で添加することができる。また、滑沢剤としては、例えば、ステアリン酸マグネシウム、ステアリン酸カルシウム、ショ糖脂肪酸エステル、安息香酸ナトリウム、シリカ、タルク、ワックス類等を例示することができ、これら滑沢剤は全固形薬剤重量に対して0.01〜10重量%の割合で使用することができる。更に、腐食防止剤としては、アルキルチオ尿素系やトリアゾール系化合物を例示することができ、これらを使用すると配管などの金属部分の腐食を抑制することができる。
Examples of excipients, binders and dissolution regulators include calcium hydrogen phosphate dihydrate, tricalcium phosphate anhydrous, magnesium hydrogen phosphate trihydrate, magnesium hydrogen phosphate octahydrate,
前記固形薬剤を製造するには、前記の殺菌剤、抗菌剤、防黴剤、賦形剤、結合剤、溶解調整剤、界面活性剤、滑沢剤、防腐剤等に、適宜配合物を添加して加熱溶融混合や、混練り押し出し成形し、球状、錠剤状、円柱状、直方体状、角錐状、ドーナツ状等、いずれの形態にも形成することができる。 In order to produce the solid drug, an appropriate formulation is added to the bactericide, antibacterial agent, antifungal agent, excipient, binder, dissolution regulator, surfactant, lubricant, preservative, etc. Then, it can be formed by heating, melting and mixing, kneading and extrusion molding, and can be formed into any shape such as spherical shape, tablet shape, columnar shape, rectangular parallelepiped shape, pyramid shape, and donut shape.
また、ヌメリ取り用の固形薬剤が収納された容器には、着脱可能な排水口用の蓋が設けられていてもよい。 Moreover, the container in which the solid chemical | medical agent for slime removal was accommodated may be provided with the lid | cover for removable drain ports.
次に、本発明のヌメリ取り容器用スペーサー、及び脱着可能なヌメリ取り用の固形薬剤が収納された容器の下部にヌメリ取り容器用スペーサーを設置したヌメリ取り容器に関して、ゴミ取り籠が設けられた流し台の排水口に用いられる場合について具体的に説明するが、本発明の技術的範囲はこれらのものに何ら限定されるものではない。 Next, regarding the slime removing container according to the present invention and the slime removing container in which the spacer for the slime removing container is installed at the lower part of the container in which the removable solid medicine for removing the slime is stored, a garbage collecting container is provided. Although the case where it uses for the drain outlet of a sink is demonstrated concretely, the technical scope of this invention is not limited to these at all.
図1には、スペーサー1の上部に、ヌメリ取り用の固形薬剤が収納された容器を嵌合する突起が設けられた嵌合部2が複数個設けられた本発明のヌメリ取り容器用スペーサーが示されている。スペーサー1の外側側面には、溶解液流入孔及び溶解液流出孔としてスリット孔3が複数個設けられている。
FIG. 1 shows a spacer for a slime removing container according to the present invention in which a plurality of
図2には、図1に示されたヌメリ取り容器用スペーサーのうち、溶解液流入孔及び溶解液流出孔として、溝孔4が複数個設けられ、内周に沿って土手部5が設けられたた本発明のヌメリ取り容器用スペーサーが示されている。図3は、その裏側からの図である。スペーサー1の下部に溝孔6が設けられて位置と同じ個所に溶解液伝達リブ5が設けられている。
In FIG. 2, a plurality of
図4には、本発明のヌメリ取り容器用スペーサー1の突起が設けられた嵌合部2と嵌合する被嵌合部8が設けられたヌメリ取り用の固形薬剤が収納された容器7を本発明のヌメリ取り容器用スペーサー1に装着し、そして、排水口用ゴミ取り籠9に装着される。この際に嵌合部には突起が設けられているので、被嵌合部8に装着し、ヌメリ取り用の固形薬剤が収納された容器7を回転させることで、嵌合することができる。
FIG. 4 shows a container 7 containing a solid medicine for slime removal provided with a fitted part 8 fitted to the
ヌメリ取り容器用スペーサーとして、硬質塩化ビニール(株式会社メイバン社製、品名:エンビバン)を用い、円形(外径直径=約144.0mm、内径直径=約108.0mm、厚さ=約2.0mm)に作製し、上部にヌメリ取り用の固形薬剤が収納された容器(外径直径=約124.5mm、内径直径=約108.8mm)を嵌合し、排水口用ゴミ取り籠(ゴミ取り籠上部の平面:外径直径=約139.8mm、内径直径=約129.0mm)に設置した。なお、固形薬剤としては、試験用に、青色の色素5重量部、ヒドロキシプロピルセルロース8重量部、乳糖87重量部からなる混合物を、Φ10mm金型を設置した連続油圧打錠機に設置し、打錠圧2t/cm2で重量0.5gの打錠した。 Hard vinyl chloride (manufactured by Mayban Co., Ltd., product name: Enbiban) is used as a spacer for the slime removal container, and circular (outside diameter = about 144.0 mm, inside diameter = about 108.0 mm, thickness = about 2.0 mm). ), And a container (outer diameter = about 124.5 mm, inner diameter = about 108.8 mm) containing a solid medicine for removing slime in the upper part is fitted, and a garbage collector for drainage (dust removal) The upper surface of the ridge: outer diameter diameter = about 139.8 mm, inner diameter diameter = about 129.0 mm). As a solid drug, a mixture consisting of 5 parts by weight of a blue dye, 8 parts by weight of hydroxypropylcellulose and 87 parts by weight of lactose was placed in a continuous hydraulic tableting machine equipped with a Φ10 mm mold for testing. Tableting was performed with a weight of 0.5 g at a tableting pressure of 2 t / cm 2 .
実施例1でヌメリ取り容器用スペーサーにスリット孔(スリットの幅=約2.0mm、長さはゴミ取り籠上部の内側平面上端部先端より約0.2mmの長さ(スペーサーの外周から中心部側へ約7.7mm))を8個所設けた以外は、実施例1と同様にして排水口用ゴミ取り籠に設置した。 In Example 1, a slit hole (slit width = about 2.0 mm, length is about 0.2 mm from the tip of the upper end of the inner flat surface of the upper part of the dust collecting bowl (from the outer periphery of the spacer to the center). Except that eight 7.7 mm)) were provided on the side, it was installed in a waste bin for garbage collection in the same manner as in Example 1.
実施例1でヌメリ取り容器用スペーサーに溝孔(溝の幅=約2.0mm、溝の深さ=約0.5mm、長さはゴミ取り籠上部の内側平面上端部先端より約1.0mmの長さ(スペーサーの外周から中心部側へ約8.5mm))を8個所設けた以外は、実施例1と同様にして排水口用ゴミ取り籠に設置した。
試験例1
実施例1〜3で排水口用ゴミ取り籠に設置したヌメリ取り用の固形薬剤が収納された容器に温水(約37〜42℃)を使用して5L/分の割合で1分間流し、温水停止後の色素による、着色液のなだれ方を観察した。その結果、実施例1では、ゴミ取り籠内側と外側からランダムに着色液が流れた。また、実施例2及び3では、ヌメリがより発生するゴミ取り籠の内側の方に多く流れた。
In Example 1, a slime removing container spacer is provided with a slot (groove width = about 2.0 mm, groove depth = about 0.5 mm, length is about 1.0 mm from the tip of the upper end of the inner flat surface of the upper part of the dust catcher. Was installed in the waste bin garbage collector in the same manner as in Example 1 except that eight portions (about 8.5 mm from the outer periphery of the spacer to the center side) were provided.
Test example 1
Using warm water (about 37-42 ° C.) for 1 minute at a rate of 5 L / min to the container containing the solid medicine for slime removal installed in the waste bin for wastewater in Examples 1 to 3, warm water The avalanche of the colored liquid due to the pigment after stopping was observed. As a result, in Example 1, the colored liquid flowed randomly from the inside and outside of the dust collecting bowl. Further, in Examples 2 and 3, a large amount flowed toward the inner side of the dust bin where more slime was generated.
1 ヌメリ取り容器用スペーサー
2 突起が設けられた嵌合部
3 スリット孔
4 溝孔
5 土手部
6 溶解液伝達リブ
7 ヌメリ取り用の固形薬剤が収納された容器
8 排水口用ゴミ取り籠
DESCRIPTION OF
Claims (6)
It consists of a spacer for slime-removing containers according to any one of claims 1 to 5 and a container in which a solid medicine for slime-removing is stored, and is provided with a fitting to be fitted to the fitting portion of the spacer in the container. A slime removing container in which the container and the spacer are detachably attached.
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JPS5838872U (en) * | 1981-09-07 | 1983-03-14 | 株式会社伸晃 | Drain trap intake valve device |
JPS6285576U (en) * | 1985-11-13 | 1987-06-01 | ||
JPH11262676A (en) * | 1998-03-17 | 1999-09-28 | Nippon Esuko:Kk | Mounting structure of disposer |
JP2001355263A (en) * | 2000-06-13 | 2001-12-26 | Akiko Hiratsuka | Catch basin for gutter |
JP2002256605A (en) * | 2001-02-28 | 2002-09-11 | Nippon Soda Co Ltd | Slime removing instrument |
JP2003278209A (en) * | 2002-03-20 | 2003-10-02 | San-Ei Faucet Mfg Co Ltd | Slime removing member |
JP2004044275A (en) * | 2002-07-12 | 2004-02-12 | San-Ei Faucet Mfg Co Ltd | Lid |
-
2004
- 2004-08-05 JP JP2004228766A patent/JP4602712B2/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5838872U (en) * | 1981-09-07 | 1983-03-14 | 株式会社伸晃 | Drain trap intake valve device |
JPS6285576U (en) * | 1985-11-13 | 1987-06-01 | ||
JPH11262676A (en) * | 1998-03-17 | 1999-09-28 | Nippon Esuko:Kk | Mounting structure of disposer |
JP2001355263A (en) * | 2000-06-13 | 2001-12-26 | Akiko Hiratsuka | Catch basin for gutter |
JP2002256605A (en) * | 2001-02-28 | 2002-09-11 | Nippon Soda Co Ltd | Slime removing instrument |
JP2003278209A (en) * | 2002-03-20 | 2003-10-02 | San-Ei Faucet Mfg Co Ltd | Slime removing member |
JP2004044275A (en) * | 2002-07-12 | 2004-02-12 | San-Ei Faucet Mfg Co Ltd | Lid |
Also Published As
Publication number | Publication date |
---|---|
JP2006045918A (en) | 2006-02-16 |
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