JP4596475B2 - Taste improving agent - Google Patents

Taste improving agent Download PDF

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JP4596475B2
JP4596475B2 JP2005306667A JP2005306667A JP4596475B2 JP 4596475 B2 JP4596475 B2 JP 4596475B2 JP 2005306667 A JP2005306667 A JP 2005306667A JP 2005306667 A JP2005306667 A JP 2005306667A JP 4596475 B2 JP4596475 B2 JP 4596475B2
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taste
fats
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JP2007110984A (en
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亮 竹内
陽一郎 西澤
忠浩 平本
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Takasago International Corp
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本発明は呈味改善剤、その呈味改善剤を含有する香料組成物、およびそれらを含有する飲食品に関する。とくに、酸化処理された動植物油脂から取り出される高沸点成分混合物からなる呈味改善剤、その呈味改善剤を含有する香料組成物、およびそれらを含有する飲食品に関する。   The present invention relates to a taste improver, a fragrance composition containing the taste improver, and a food or drink containing them. In particular, the present invention relates to a taste improver comprising a high-boiling component mixture extracted from oxidized animal and vegetable fats and oils, a fragrance composition containing the taste improver, and a food or drink containing them.

従来から、飲食品に対する味の向上を満足するために、さまざまな工夫がなされている。
例えば、動物油脂を酸化処理した結果生成する種々の脂肪族アルデヒド類を有効成分とする、飲食品をよりおいしいと感じさせることができる配合剤が報告されている(特許文献1)。これらの配合剤を配合した飲食品を飲食すると、確かにおいしいと感じることができるが、おいしさを感じる程度は未だ十分とはいえず、さらに動植物油脂を酸化処理する際に酸化安定剤を共存させておくなどの不都合さが指摘されている。
この点を改める技術として、穏やかな酸化処理条件で酸化処理した結果生成する有効成分を回収する部分に工夫を加える技術が報告されている(特許文献2)。この技術も、配合剤を配合した飲食品を飲食すると、確かにおいしいと感じることができるが、おいしさを感じる程度は未だ十分とはいえず、近年の味覚に対する高度の要求に対応するには未だ改善される余地が残されている。
Conventionally, various ideas have been made in order to satisfy the taste improvement for food and drink.
For example, there has been reported a compounding agent that can make foods and drinks more delicious, using various aliphatic aldehydes produced as a result of oxidation treatment of animal fats and oils as active ingredients (Patent Document 1). If you eat or drink foods and drinks that contain these ingredients, you can feel that they are delicious, but the level of taste is still not enough, and there is also an oxidative stabilizer when you oxidize animal and vegetable oils and fats. Inconveniences such as leaving them are pointed out.
As a technique for correcting this point, a technique has been reported in which a device is devised for recovering an active ingredient produced as a result of oxidation treatment under mild oxidation treatment conditions (Patent Document 2). Although this technology can also be surely delicious when you eat or drink foods and drinks that contain a compounding agent, the level of taste is still not enough, and to meet the recent high demands for taste There is still room for improvement.

その点、肉類等の腐臭等オフフレーバーの原因物質とされてきた、アラキドン酸、ドコサヘキサエン酸、エイコサペンタエン酸等の長鎖高度不飽和脂肪酸及び/又はそのエステル体の分解物の抽出物を配合剤とし、コク味等の味を付与、増強、改善する配合剤が報告されている(例えば、特許文献3)。この配合剤は、コク味等の味をそれなりに付与することができるものの、有効成分は上記特許文献1や2と同様の低沸点成分であり、おいしさを感じる程度は未だ十分とはいえず、近年の味覚に対する高度の要求に対応するには未だ改善される余地が残されている。   In this regard, it contains a long-chain highly unsaturated fatty acid such as arachidonic acid, docosahexaenoic acid, eicosapentaenoic acid and / or an extract of its degradation product, which has been considered a causative agent of off-flavors such as meat and other odors. In addition, a compounding agent that imparts, enhances, and improves a taste such as richness has been reported (for example, Patent Document 3). Although this compounding agent can impart a taste such as richness as it is, the active ingredient is a low-boiling component similar to those of Patent Documents 1 and 2 described above, and it cannot be said that the degree of taste is still sufficient. However, there is still room for improvement in response to the recent high demand for taste.

特開平4−229151号公報JP-A-4-229151 特開平8−131116号公報JP-A-8-131116 国際公開WO2005/4634パンフレット(とくに実施例)International publication WO2005 / 4634 pamphlet (especially example)

本発明は、甘味、塩味、苦味、酸味、旨味で示される基本5味だけでは表現できないコク味等の味をさらに付与、増強、改善し、コク味、味の厚み、ボリューム感、舌ざわりなど口腔内で感じられる風味や感触を十分に増強し、しかも飲食したときに十分満足することができる新規な呈味改善剤を提供することを課題とし、近年の味覚に対する要求に対応できる程度の美味さを有する飲食品、およびその美味しさを飲食品に付与することができる新規な呈味改善剤を提供することを課題とする。とくに酸化処理された動植物油脂に存在する高沸点成分混合物からなる新規な呈味改善剤を提供することを課題とする。   The present invention further provides, enhances, and improves a taste such as sweetness, salty taste, bitterness, sourness, and savory taste that cannot be expressed only by the five basic tastes. The objective is to provide a new taste improver that sufficiently enhances the flavor and feel that can be felt inside, and that can be fully satisfied when eating and drinking, and is delicious enough to meet the recent demands for taste It is an object of the present invention to provide a food / beverage product having a taste and a novel taste improving agent capable of imparting the taste to the food / beverage product. In particular, it is an object of the present invention to provide a novel taste improver comprising a high-boiling component mixture present in an oxidized animal and vegetable oil.

本発明者らは、前記課題を解決すべく鋭意研究する最中、酸化処理した油脂からのフレーバーの製造工程で廃棄されることが多かった高沸点成分混合物に着目し、その高沸点成分混合物を飲食品に添加したところ、意外にも格段に優れた呈味を有する飲食品が得られるという知見を得、その知見に基づきさらに研究を重ね、ついに本発明を完成させた。   In the course of earnest research to solve the above problems, the present inventors paid attention to a high-boiling component mixture that was often discarded in the manufacturing process of flavors from oxidized oils and fats. When it was added to foods and drinks, the knowledge that a food and drink having a remarkably excellent taste was obtained unexpectedly, and further research was conducted based on the knowledge, and the present invention was finally completed.

すなわち、本発明の請求項1の発明は、酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣を有効成分とすることを特徴とする呈味改善剤である。ここで、低沸点成分は45〜75℃、13.33〜93.33hPaでの減圧蒸留法あるいは減圧水蒸気蒸留法、又は常圧水蒸気蒸留法により回収できる成分をいう。
請求項2の発明は、酸化処理した動植物油脂を45〜75℃、13.33〜93.33hPaで減圧蒸留処理あるいは減圧水蒸気蒸留処理して得た蒸留残渣、又は常圧水蒸気蒸留処理して得た蒸留残渣を有効成分とすることを特徴とする呈味改善剤である。
請求項3の発明は、請求項1又は2の発明において、蒸留物残渣又は蒸留残渣の精製処理物を有効成分とすることを特徴とする呈味改善剤でもある。また、請求項3の発明は、請求項1の発明において、蒸留物残渣の精製処理物を有効成分とすることを特徴とする呈味改善剤であり、請求項2の発明において、蒸留残渣の精製処理物を有効成分とすることを特徴とする呈味改善剤でもある。
請求項4の発明は、香料組成物の発明であり、請求項1〜3記載のいずれかの呈味改善剤と香料とを含有する香料組成物である。
請求項5の発明は、飲食品の発明であり、請求項1〜3記載のいずれかの呈味改善剤を含有する飲食品である。
That is, the invention according to claim 1 of the present invention is a taste improver characterized by comprising, as an active ingredient, a distillate residue obtained by removing low-boiling components from oxidized animal and vegetable fats and oils. Here, the low boiling point component means a component that can be recovered by a vacuum distillation method, a vacuum steam distillation method, or an atmospheric steam distillation method at 45 to 75 ° C. and 13.33 to 93.33 hPa.
The invention of claim 2 is obtained by subjecting oxidized animal and vegetable oils and fats to distillation residues obtained by vacuum distillation treatment or vacuum steam distillation treatment at 45 to 75 ° C. and 13.33 to 93.33 hPa, or atmospheric steam distillation treatment. It is a taste improving agent characterized by using a distillation residue as an active ingredient.
The invention of claim 3 is also a taste improver characterized in that, in the invention of claim 1 or 2, the distillate residue or a purified product of the distillation residue is used as an active ingredient. The invention of claim 3 is a taste improver characterized in that, in the invention of claim 1, a refined product of the distillate residue is used as an active ingredient. It is also a taste improver characterized by comprising a purified product as an active ingredient.
Invention of Claim 4 is invention of a fragrance | flavor composition, It is a fragrance | flavor composition containing the taste improving agent in any one of Claims 1-3, and a fragrance | flavor.
Invention of Claim 5 is invention of food / beverage products, and is food / beverage products containing the taste improving agent in any one of Claims 1-3.

以下に本発明を詳しく説明する。
本発明で用いられる動植物油脂は、動物由来の油脂および植物由来の油脂から選ばれ、とくに限定されない。それら動植物油脂単独でもよいが、二種類以上の動植物油脂を混合してもよい。
動物油脂としては、例えば豚脂、牛脂、乳脂肪、鶏油、羊油、卵脂肪、イワシ油、サバ油、鯨油、サケ油、タラ油などが好ましく、植物油脂としては、落花生油、コ−ン油、オリ−ブ油、ゴマ油、ヒマワリ油、ココナッツ油、パ−ム油、パ−ム核油、サフラワ−油、大豆油、ア−モンド油、菜種油、米ぬか油、ヤシ油、小麦胚芽油、綿実油、つばき油、ヒマシ油、カカオ脂などが好ましい。これらの中でも、とくに動物油脂を用いると好ましい結果をもたらす。
これら動植物油脂を極性溶媒中に存在させておくことが有利である。極性溶媒としては、エチレングリコール、プロピレングリコール、グリセロールなどのポリオール、それらポリオールに塩化ナトリウム、塩化カリウムなどの塩類を溶解した水溶液を混合した溶剤、水などが挙げられる。それらのなかでも水を用いることが有利である。動植物油脂に対する極性溶媒の使用量は、使用する動植物油脂の種類にもよるので一概に規定できないが、動植物油脂に対して約0.05〜5倍重量の範囲で使用されると好ましい結果をもたらすことができる。
The present invention is described in detail below.
The animal and vegetable oils and fats used in the present invention are selected from animal-derived oils and fats and plant-derived oils and fats, and are not particularly limited. These animal and vegetable oils and fats may be used alone, or two or more kinds of animal and vegetable oils and fats may be mixed.
Preferred animal fats are, for example, pork fat, beef fat, milk fat, chicken oil, sheep oil, egg fat, sardine oil, mackerel oil, whale oil, salmon oil, cod oil and the like, and vegetable fats and oils include peanut oil, Oil, olive oil, sesame oil, sunflower oil, coconut oil, palm oil, palm kernel oil, safflower oil, soybean oil, almond oil, rapeseed oil, rice bran oil, coconut oil, wheat germ oil Cottonseed oil, camellia oil, castor oil, cacao butter and the like are preferable. Of these, particularly preferable results are obtained when animal fats are used.
It is advantageous to have these animal and vegetable oils and fats present in a polar solvent. Examples of the polar solvent include polyols such as ethylene glycol, propylene glycol, and glycerol, a solvent obtained by mixing an aqueous solution in which salts such as sodium chloride and potassium chloride are dissolved in these polyols, and water. Among them, it is advantageous to use water. The amount of polar solvent used for animal and vegetable oils and fats depends on the type of animal and vegetable oils and fats to be used, and thus cannot be defined unconditionally. However, when used in a range of about 0.05 to 5 times the weight of animal and vegetable oils and fats, preferable results are obtained. be able to.

上記動植物油脂に、他の物質を共存させておいてもよい。他の物質の具体例としては、パルミチン酸などの高級飽和脂肪酸、リノール酸、リノレイン酸、オレイン酸などの高級不飽和脂肪酸、グルコ−ス、キシロ−ス、アラビノ−ス、リボ−ス、フラクト−スのような単糖類、シュクロ−ス、ラクト−スなどのような二糖類、グリシン、アラニン、バリン、ヒスチジン、リジン、スレオニン、グルタミン類、ロイシン、イソロイシン、セリン、システイン、シスチン、アルギニン、アスパラギン酸、プロリンのようなアミノ酸類:酢酸、乳酸、リンゴ酸、クエン酸、イノシン酸、グアニル酸またはそれらの塩などのような有機酸類、ジアセチル、ピルビンアルデヒド、ピルビン酸、ヒドロキシアセトン、ジヒドロキシアセトン、アセチルメチルカルビノ−ルなどのカルボニル化合物類、乳清、酵母エキス等のタンパク質混合物、玉葱、トマト、にんにく、白菜、にんじん、キャべツ、ニラ等の野菜エキス、りんご、パイナップル、レモン、オレンジ、グレープフルーツ、グレープ等の果汁、バジル、ブラックペッパー、ホワイトペッパー、クミン、コリアンダー、カルダモン、フェヌグリーク、ターメリック、しょうがなどの香辛料を挙げることができる。
本発明では、動植物油脂の代わりに、脂肪酸誘導体を用いることができる。脂肪酸誘導体としては、脂肪酸のナトリウム塩、脂肪酸のカリウム塩などに代表される脂肪酸の金属塩、脂肪酸のエステルなどを挙げることができる。これら脂肪酸誘導体の中でも、とくに脂肪酸のトリグリセリド、モノグリセリド、ジグリセリドが好ましく、それら単独、あるいは二種以上の混合物を用いることもできる。脂肪酸としては、炭素数が4〜28の高級脂肪酸が用いられるが、動植物油脂を構成する脂肪酸から選ぶのか好ましい。脂肪酸としては、特定の脂肪酸を単独で用いてもよいが、二種以上の脂肪酸混合物を用いることが好ましい。
Other substances may be allowed to coexist with the animal and vegetable fats and oils. Specific examples of other substances include higher saturated fatty acids such as palmitic acid, higher unsaturated fatty acids such as linoleic acid, linolenic acid, oleic acid, glucose, xylos, arabinose, ribose, and fructose. Monosaccharides such as sucrose, disaccharides such as sucrose, lactose, glycine, alanine, valine, histidine, lysine, threonine, glutamines, leucine, isoleucine, serine, cysteine, cystine, arginine, aspartic acid , Amino acids such as proline: organic acids such as acetic acid, lactic acid, malic acid, citric acid, inosinic acid, guanylic acid or their salts, diacetyl, pyrubinaldehyde, pyruvic acid, hydroxyacetone, dihydroxyacetone, acetylmethyl Carbonyl compounds such as carbinol, whey, yeast Protein mixtures such as trout, onions, tomatoes, garlic, Chinese cabbage, carrots, cabbage, leek and other vegetable extracts, apples, pineapples, lemons, oranges, grapefruits, grape juices, basil, black peppers, white peppers, cumin , Coriander, cardamom, fenugreek, turmeric, ginger and other spices.
In the present invention, fatty acid derivatives can be used in place of animal and vegetable fats and oils. Examples of the fatty acid derivatives include fatty acid metal salts such as fatty acid sodium salts and fatty acid potassium salts, and fatty acid esters. Among these fatty acid derivatives, fatty acid triglycerides, monoglycerides, and diglycerides are particularly preferable, and these can be used alone or as a mixture of two or more. As the fatty acid, a higher fatty acid having 4 to 28 carbon atoms is used, and it is preferably selected from fatty acids constituting animal and vegetable fats and oils. As the fatty acid, a specific fatty acid may be used alone, but a mixture of two or more fatty acids is preferably used.

本発明では、市販の精製油脂を酸化処理することが好ましいが、精製処理を施していない油脂を酸化処理してもよい。ここでいう精製処理とは、脱色処理、脱酸処理、脱臭処理などの通常行われる処理をいう。
ここでいう酸化処理とは、この技術分野で知られている方法を適用すればよいのであり、とくに制限されない。
具体的な酸化処理としては、動植物油脂を水などの極性溶媒で希釈した後、空気中で撹拌処理する方法、酸素ガスあるいは空気を油脂中に通気する方法、油脂中に酵素を添加して、混合する方法などが挙げられる。通気する方法としては、例えば動植物油脂100g当たり、空気を1〜2000ml/分、より好ましくは5〜1000ml/分の割合で、撹拌しながら動植物油脂中を通過させる。上記酵素としては、リパーゼ、リポキシゲナ−ゼなどが挙げられる他、大豆粗酵素など酵素混合物あるいは動植物由来の酵素含有抽出物も利用可能である。
油脂の酸化処理に際して、油脂を加熱しなければならないということではないが、酵素を用いない場合には、80〜180℃程度に加熱しながら酸化処理することが好ましい。なお、用いる動植物油脂によっては、80〜150℃程度がより好ましく、80〜120℃程度に加熱しながら酸化処理することがさらに好ましい。酵素を用いる場合には酵素の最適な温度条件で加熱することが望ましい。
酸化処理時間は、用いる油脂の種類、加熱温度、希望する酸化油脂の性状、製造規模などにより異なり必ずしも限定できるものではなく、通常、1〜48時間程度であるが、酸化処理した油脂の過酸化物価が10.0meq/kg〜120以上meq/kgとすることが好ましく、10.0meq/kg〜40以上meq/kgとすることがより好ましい。
この過酸化物値の測定法は、いろいろあるが、例えば 基準油脂分析試験法2.5.2.1(日本油脂学会編)がある。
In the present invention, it is preferable to oxidize commercially available refined fats and oils, but fats and oils that have not been subjected to refining treatments may be oxidized. The refinement | purification process here means the process performed normally, such as a decoloring process, a deoxidation process, and a deodorizing process.
The oxidation treatment here may be any method known in this technical field, and is not particularly limited.
As a specific oxidation treatment, after diluting animal and vegetable fats and oils with a polar solvent such as water, a method of stirring in air, a method of ventilating oxygen gas or air into the fats and oils, adding an enzyme in the fats and oils, The method of mixing etc. is mentioned. As a method of aeration, for example, per 100 g of animal and vegetable oils and fats, air is passed through the animal and vegetable oils and fats with stirring at a rate of 1 to 2000 ml / min, more preferably 5 to 1000 ml / min. Examples of the enzyme include lipase, lipoxygenase and the like, and enzyme mixtures such as soybean crude enzyme or enzyme-containing extracts derived from animals and plants can also be used.
In the oxidation treatment of fats and oils, it is not necessary to heat the fats and oils, but when an enzyme is not used, the oxidation treatment is preferably performed while heating at about 80 to 180 ° C. In addition, depending on the animal and vegetable oil used, about 80-150 degreeC is more preferable, and it is still more preferable to oxidize, heating at about 80-120 degreeC. When using an enzyme, it is desirable to heat it under the optimum temperature conditions for the enzyme.
The oxidation treatment time varies depending on the type of oil and fat to be used, the heating temperature, the desired property of the oxidized oil and fat, the production scale, etc., and is not necessarily limited, and is usually about 1 to 48 hours. The price is preferably 10.0 meq / kg to 120 or more meq / kg, and more preferably 10.0 meq / kg to 40 or more meq / kg.
There are various methods for measuring the peroxide value. For example, there is a standard oil analysis method 2.5.2.1 (edited by the Japan Oil and Fat Society).

かくして得られた動植物油脂の酸化処理物から高沸点成分混合物を調製する。高沸点成分混合物の代表例は酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣、その蒸留物残渣の精製処理物であり、酸化処理した動植物油脂の精製処理物から低沸点成分を除去した蒸留物残渣、その蒸留物残渣の精製処理物である。それら蒸留物残渣やその蒸留物残渣の精製処理物およびをそれらを調製する方法については下記に示す。
ここでいう高沸点成分混合物は、動植物油脂の酸化処理物から低沸点成分を除去した成分の混合物である。低沸点成分については後述する。
A high-boiling component mixture is prepared from the oxidation-treated product of animal and vegetable fats and oils thus obtained. Typical examples of high-boiling component mixtures are distillate residues from which low-boiling components have been removed from oxidized animal and vegetable fats and oils, and purified products of the distillate residues. Low-boiling components are removed from purified products of oxidized animal and vegetable oils and fats. The distillate residue is a purified product of the distillate residue. The distillate residue, the purified product of the distillate residue, and a method for preparing them will be described below.
The high-boiling component mixture here is a mixture of components obtained by removing low-boiling components from an oxidized product of animal and vegetable fats and oils. The low boiling point component will be described later.

本発明では、酸化処理した動植物油脂の高沸点成分混合物を呈味改善飲食品素材とすることができ、呈味改善飲食品素材から、呈味改善飲食品を常法により製造することができる。呈味改善飲食品の具体例としては、各種ス−プ類、各種調味料類を挙げることができる。
本発明では、前記酸化処理した動植物油脂の高沸点成分混合物を呈味改善剤の有効成分とすることもできる。また、前記酸化処理した動植物油脂の高沸点成分混合物を呈味改善剤の有効成分とするともいえる。その呈味改善剤については後述する。
In this invention, the high boiling-point component mixture of the oxidized animal and vegetable fats and oils can be made into a taste improvement food-drinks material, and a taste improvement food-drinks can be manufactured by a conventional method from a taste improvement food-drinks material. Specific examples of the taste-improving food and drink include various types of soups and various seasonings.
In the present invention, the oxidized high-boiling-component mixture of animal and vegetable oils and fats can be used as an active ingredient of the taste improver. It can also be said that the high-boiling component mixture of the animal and vegetable oils and fats subjected to the oxidation treatment is used as an active ingredient of the taste improver. The taste improving agent will be described later.

本発明では、酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣を呈味改善剤の有効成分としてもよい。また、酸化処理した動植物油脂の精製処理物から低沸点成分を除去した蒸留物残渣を呈味改善剤の有効成分としてもよい。
酸化処理した動植物油脂から低沸点成分を除去する方法としては、例えば減圧蒸留法、水蒸気蒸留法あるいは減圧水蒸気蒸留法などが挙げられる。また、気液向流分配法を用いてもよい。なお、本発明では気液向流分配法を一つの水蒸気蒸留法として取り扱う。これらの方法により低沸点成分を留去すれば蒸留残渣が得られる。とくに水蒸気蒸留法あるいは減圧水蒸気蒸留法を用いて低沸点成分を留去した蒸留残渣が好ましい。ここで、低沸点成分は、蒸留処理温度を45〜75℃に設定し、13.33〜93.33hPa(10〜70mmHg)での減圧蒸留法あるいは減圧水蒸気蒸留法により回収した成分をいうが、また、低沸点成分は、常圧水蒸気蒸留法により回収した成分ということもできる。低沸点成分を留去した蒸留残渣とは、前記条件で蒸留処理して得た蒸留残渣をいう。
また、酸化処理した動植物油脂の精製処理については後述する。
In this invention, it is good also considering the distillate residue which removed the low boiling point component from the oxidized animal and vegetable fats and oils as an active ingredient of a taste improving agent. Moreover, it is good also considering the distillate residue which removed the low boiling point component from the refinement | purification processed product of the oxidized animal and vegetable fat as an active ingredient of a taste improving agent.
Examples of the method for removing low-boiling components from the oxidized animal and vegetable fats and oils include a vacuum distillation method, a steam distillation method, and a vacuum steam distillation method. A gas-liquid countercurrent distribution method may also be used. In the present invention, the gas-liquid countercurrent distribution method is treated as one steam distillation method. A distillation residue can be obtained by distilling off the low-boiling components by these methods. In particular, a distillation residue obtained by distilling off low-boiling components using a steam distillation method or a reduced pressure steam distillation method is preferred. Here, the low boiling point component refers to a component recovered by a vacuum distillation method or a vacuum steam distillation method at 13.33 to 93.33 hPa (10 to 70 mmHg) at a distillation treatment temperature of 45 to 75 ° C. The low boiling point component can also be referred to as a component recovered by atmospheric steam distillation. The distillation residue obtained by distilling off low-boiling components refers to a distillation residue obtained by distillation under the above conditions.
Moreover, the refinement | purification process of the oxidized animal and vegetable fats and oils is mentioned later.

上記減圧蒸留法、水蒸気蒸留法あるいは減圧水蒸気蒸留法は、この技術分野で用いられる普通の方法を採用すればよいのであって、とくに制限されない。
なお、本発明では、酸化処理した動植物油脂に、適宜配合剤を加えてから、蒸留処理をしてもよい。それら、配合剤は、段落番号0009に記載の動植物油脂に共存させてもよい他の物質と同様である。
The above-mentioned vacuum distillation method, steam distillation method or vacuum steam distillation method is not particularly limited and may be any ordinary method used in this technical field.
In addition, in this invention, you may distill after adding a compounding agent suitably to the oxidized animal and vegetable fats and oils. These compounding agents are the same as other substances that may coexist in the animal and vegetable oils and fats described in paragraph 0009.

本発明では、上記低沸点成分を除去した蒸留物残渣、即ち高沸点成分混合物をさらに精製処理することが、いくつかある特徴の一つである。とくに、低沸点成分を除去した蒸留物残渣には、酸化処理に際して副生する過酸化物が含まれており、保存安定性ならびに食品の安全性といった点から、これらの過酸化物を除去することが好ましい。可能な限り過酸化物を除去することが好ましいが、低沸点成分を除去した蒸留物残渣を精製する事により、例えば過酸化物の含有量が低い高沸点成分混合物を得ることができる。精製処理は常法を採用すればよいのであり、とくに制限されないが、例えばカラムクロマトグラフィー法での処理や、例えば吸着剤混合法で処理することなどが好ましい。
カラムクロマトグラフィー法で用いる、カラム、充填剤、溶媒等はとくに制限されないのであり、適宜使用できる。
In the present invention, it is one of several characteristics that the distillate residue from which the low-boiling components are removed, that is, the high-boiling component mixture is further purified. In particular, distillate residues from which low-boiling components have been removed contain peroxides that are by-produced during the oxidation treatment. These peroxides should be removed from the standpoints of storage stability and food safety. Is preferred. It is preferable to remove peroxide as much as possible, but by purifying the distillate residue from which low-boiling components have been removed, for example, a high-boiling component mixture having a low peroxide content can be obtained. The purification treatment may be carried out by a conventional method, and is not particularly limited. For example, treatment by a column chromatography method or treatment by an adsorbent mixing method is preferable.
The column, filler, solvent, etc. used in the column chromatography method are not particularly limited and can be used as appropriate.

本発明で用いるクロマトグラフィー法はすでに公知であり、本発明ではそれらを適宜使用すればよい。とくにカラムクロマトグラフィー法、その中でも好ましい充填剤としてシリカゲル、酸性白土、ケイ酸マグネシウム、活性炭、活性白土や、それら充填剤の1種または2種以上を併用したものなどを用いるカラムクロマトグラフィー法が有利であるが、その方法に限定されない。
具体的に説明すると、適宜の容量のカラムにシリカゲルや活性炭、活性白土などを充填し、そこに上記高沸点成分混合物あるいは低沸点成分を除去した蒸留物残渣自体、もしくは分液や乾燥剤を混合することにより水分を除去した蒸留物残渣を注ぎ込むか、さらにはヘキサン、酢酸エチル、エタノール、2-プロパノールなどの各種溶媒での希釈物を注ぎ込み吸着させる。その直後、あるいは一定時間経過後、ヘキサン、酢酸エチル、エタノール、2-プロパノールなどの溶媒を注ぎ込み、展開させ、不要分を除去し、精製物を得ることができる。
本発明で用いる吸着剤添加処理もすでに公知であり、この分野で使用する吸着剤であればどのような吸着剤でも採用可能である。好ましい吸着剤としては、シリカゲル、活性白土、酸性白土、珪酸マグネシウム、および活性炭等を挙げることができ、それら吸着剤の1種または2種以上を併用して用いてもよい。これらの吸着剤を高沸点成分混合物、あるいは酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣に混合し、一定時間経過後、もしくはその直後に吸着剤を濾別することにより,不要分を吸着剤に吸着させ、除去し、精製物を得ることが出来る。
これらの処理により、とくに過酸化物価が5.0meq/kg以下となるように精製処理することが好ましい。この過酸化物価の測定法はすでに説明してある方法を適宜使用すればよい。
The chromatographic methods used in the present invention are already known and may be used as appropriate in the present invention. In particular, column chromatography methods, and column chromatography methods using silica gel, acidic clay, magnesium silicate, activated carbon, activated clay, or a combination of one or more of these fillers as preferred fillers are particularly advantageous. However, it is not limited to that method.
Specifically, silica gel, activated carbon, activated clay, etc. are packed in a column with an appropriate volume, and the distillate residue itself from which the above high-boiling component mixture or low-boiling component has been removed, or a liquid separation and desiccant are mixed. Then, the distillate residue from which moisture has been removed is poured, or further diluted with various solvents such as hexane, ethyl acetate, ethanol and 2-propanol are poured and adsorbed. Immediately after that, or after a certain period of time, a solvent such as hexane, ethyl acetate, ethanol, 2-propanol and the like is poured and developed to remove unnecessary components to obtain a purified product.
The adsorbent addition treatment used in the present invention is already known, and any adsorbent can be used as long as it is used in this field. Preferred examples of the adsorbent include silica gel, activated clay, acidic clay, magnesium silicate, activated carbon, and the like, and one or more of these adsorbents may be used in combination. These adsorbents are mixed with high-boiling component mixtures or distillate residues obtained by removing low-boiling components from oxidized animal and vegetable fats and oils, and the adsorbents are filtered off after or after a certain period of time. Can be adsorbed on an adsorbent and removed to obtain a purified product.
By these treatments, it is particularly preferred to carry out purification treatment so that the peroxide value is 5.0 meq / kg or less. As the method for measuring the peroxide value, the method already described may be used as appropriate.

かくして製造される低沸点成分を留去した蒸留残渣の精製処理物を呈味改善剤の有効成分とすることが、本発明のいくつかある特徴の一つである。
本発明の呈味改善剤は、それ自体各種の飲食品の呈味改善剤として使用できるが、脂肪酸トリグリセリド溶液などの溶液として使用できる。また、各種の被膜剤で処理して粉末状、顆粒状などにして使用することもできる。粉末状、顆粒状などとするには一般的に使用される被膜剤と混合し、例えば噴霧乾燥、凍結乾燥などの手段を用いればよい。被膜剤としては、例えばアラビアガム、トラガントガム、サイクロデキストリン、デキストリン、ゼラチン、加工でんぷんなどが例示される。さらに、本発明の呈味改善剤は、ペースト状、乳化物状など任意の形態で利用できる。また、本発明の呈味改善剤は、各種配合剤と各種の公知のフレーバー素材と混合して使用することができ、また他の食品用調合香料組成物と適宜混合して使用することもできる。さらに、フレーバー製造において、公知の糖−アミノ反応の一素材として利用することもできる。
本発明の呈味改善剤に、植物タンパクエキスなどの植物抽出物、カプロン酸、酪酸などの有機酸、公知のカルボニル化合物やアルデヒド化合物を配合してもよい。また、ジメチルスルファイド、ジフルフリルジスルファイド、テトラヒドロチオフェン−3−オン、フルフリルメルカプタン、チアゾ−ル類、チオベンゾイルフラン類などの含硫黄化合物を本発明の呈味改善剤に共存させると呈味改善効果がさらに向上する。
One of the characteristics of the present invention is that the purified product of the distillation residue obtained by distilling off the low-boiling components thus produced is used as an active ingredient of the taste improver.
The taste improving agent of the present invention can itself be used as a taste improving agent for various foods and drinks, but can be used as a solution such as a fatty acid triglyceride solution. Also, it can be used in the form of powder or granules by treating with various coating agents. In order to obtain a powder, granule or the like, it is mixed with a commonly used coating agent, and for example, means such as spray drying or freeze drying may be used. Examples of the coating agent include gum arabic, gum tragacanth, cyclodextrin, dextrin, gelatin, processed starch and the like. Furthermore, the taste improving agent of this invention can be utilized with arbitrary forms, such as a paste form and an emulsion form. In addition, the taste improving agent of the present invention can be used by mixing with various compounding agents and various known flavor materials, and can also be used by appropriately mixing with other food preparation flavoring compositions. . Furthermore, in flavor manufacture, it can also utilize as one raw material of well-known sugar-amino reaction.
You may mix | blend plant extracts, such as a plant protein extract, organic acids, such as a caproic acid and a butyric acid, a well-known carbonyl compound, and an aldehyde compound with the taste improving agent of this invention. In addition, when a sulfur-containing compound such as dimethylsulfide, difurfuryl disulfide, tetrahydrothiophen-3-one, furfuryl mercaptan, thiazol, thiobenzoylfuran is coexisted in the taste improver of the present invention, it is exhibited. The taste improving effect is further improved.

かくして調製された呈味改善剤を、飲食品に配合すると、飲食品の呈味を改善することができる。
呈味改善剤を配合する飲食品はとくに限定されないのであり、例えば、畜肉類、鳥肉、魚貝類などを原料とする加工食品類、ス−プ類、調味料類、ふりかけ類、インスタント食品やスナック食品類、かんずめ食品類、乳製品類、菓子類、冷菓類、茶、コーヒー、野菜ジュース、青汁などの飲料を例示できる。本発明の呈味改善剤の使用量は、呈味改善剤の種類、飲食品の種類、呈味改善剤の適用方法、使用方法などによっても異なるが、例えば食品調合香料組成物の素材として用いる場合は、約0.02〜40重量%程度の使用が一般的である。
When the taste improver thus prepared is blended with food or drink, the taste of the food or drink can be improved.
There are no particular limitations on the food or drink containing the taste improver, such as processed foods made from livestock, poultry, fish and shellfish, soups, seasonings, sprinkles, instant foods, Examples include snack foods, canned foods, dairy products, confectionery, frozen confectionery, tea, coffee, vegetable juice, and green juice. The amount of the taste improving agent of the present invention varies depending on the type of the taste improving agent, the type of food and drink, the application method of the taste improving agent, the method of use, and the like. For example, the taste improving agent is used as a raw material for a food preparation flavor composition. In such a case, the use of about 0.02 to 40% by weight is common.

本発明によれば、酸化処理した動植物油脂の高沸点成分混合物から優れた呈味改善効果を有する呈味改善剤を提供できる。この呈味改善剤を配合して飲食品を飲食すると、コク味、味の厚み、ボリューム感、舌ざわりなど口腔内で感じられる風味や感触をなどが一段と増し、美味しい飲食品であると感じられるようになり、極めた実用的な効果をもたらす。   ADVANTAGE OF THE INVENTION According to this invention, the taste improving agent which has the outstanding taste improvement effect from the high boiling-point component mixture of the animal and vegetable fats and oils which were oxidized can be provided. When you eat and drink foods and drinks with this taste improver, the flavor and feel that you can feel in the mouth, such as richness, thickness of taste, volume, and texture, will increase further, and you will feel that they are delicious foods and drinks. And brings about an extremely practical effect.

以下、実施例に基づき本発明を詳細に説明するが、本発明はこれら実施例になんら限定されるものではない。
(実施例1)ラード由来呈味改善剤
豚脂100g(機関油脂工業(株)製)を120℃で1.5時間攪拌し、加熱処理を停止した。過酸化物価は18.87meq/kg であった。得られた加熱処理豚脂に蒸留水50gを加え、フラスコ内温度が97℃での水蒸気蒸留を行い、留分を30g回収した。水蒸気蒸留処理後の分かれた二層から油脂層を分液して低沸点成分を除去した蒸留物残渣を得た。その油脂状の蒸留物残渣10gをヘキサン/酢酸エチル混合溶液を用いたシリカゲルカラムクロマトグラフィーにより精製し、加熱処理豚脂由来呈味改善剤を9.72g(過酸化物価0.32meq/kg )得た。
EXAMPLES Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited to these Examples at all.
(Example 1) Lard-derived taste improver 100 g of pork fat (manufactured by Engine Oil & Fat Co., Ltd.) was stirred at 120 ° C. for 1.5 hours, and the heat treatment was stopped. The peroxide value was 18.87 meq / kg. Distilled water (50 g) was added to the obtained heat-treated pork fat, and steam distillation was performed at a flask internal temperature of 97 ° C. to recover 30 g of a fraction. The oil and fat layer was separated from the two separated layers after the steam distillation treatment to obtain a distillate residue from which low-boiling components were removed. 10 g of the oily distillate residue was purified by silica gel column chromatography using a mixed solution of hexane / ethyl acetate to obtain 9.72 g (peroxide value 0.32 meq / kg) of a taste improving agent derived from heat-treated pork fat.

(実施例2)牛脂由来呈味改善剤
精製牛脂(横関油脂工業(株)製)100gを120度で加熱、200ml/分の空気を通気しながら1時間攪拌し、加熱処理を停止した。過酸化物価は16.2meq/kg であった。得られた加熱処理牛脂に蒸留水50gを加え、フラスコ内温度が97℃での水蒸気蒸留を行い、留分を30g回収した。水蒸気蒸留処理後の分かれた二層から油脂層を分液して低沸点成分を除去した蒸留物残渣を得た。その油脂状の蒸留物残渣10gに1重量%の活性白土を添加し、60℃で2時間攪拌を行った。攪拌後、濾過により活性白土を除去し、加熱処理牛脂由来呈味改善剤を得た(9.50g、過酸化物価4.01meq/kg ) 。
(Example 2) Tallow-derived taste improving agent 100 g of refined beef tallow (manufactured by Yokoseki Yushi Kogyo Co., Ltd.) was heated at 120 ° C. and stirred for 1 hour while ventilating air at 200 ml / min to stop the heat treatment. The peroxide value was 16.2 meq / kg. Distilled water (50 g) was added to the heat-treated beef tallow obtained, and steam distillation was performed at a temperature in the flask of 97 ° C. to recover 30 g of a fraction. The oil and fat layer was separated from the two separated layers after the steam distillation treatment to obtain a distillate residue from which low-boiling components were removed. 1% by weight of activated clay was added to 10 g of the oily distillate residue and stirred at 60 ° C. for 2 hours. After stirring, the activated clay was removed by filtration to obtain a heat-treated beef tallow-derived taste improver (9.50 g, peroxide value 4.01 meq / kg).

(実施例3)チキンオイル由来呈味改善剤
チキンオイル(横関油脂工業(株)製)100gを120℃で1.5時間加熱攪拌し、加熱処理を停止した。過酸化物価は18.02meq/kg であった。得られた加熱処理チキンオイルを実施例2と同じ操作により処理し、加熱処理チキンオイル由来呈味改善剤を得た(9.3g、過酸化物価3.8meq/kg )
(Example 3) Chicken oil-derived taste improver 100 g of chicken oil (manufactured by Yokoseki Oil & Fat Co., Ltd.) was heated and stirred at 120 ° C for 1.5 hours, and the heat treatment was stopped. The peroxide value was 18.02 meq / kg. The obtained heat-treated chicken oil was treated in the same manner as in Example 2 to obtain a heat-treated chicken oil-derived taste improver (9.3 g, peroxide value 3.8 meq / kg).

(実施例4)落花生油由来の呈味改善剤
落花生油(コスモ油化学(株)製)100gを100℃で1時間攪拌し、加熱処理を停止した。過酸化物価は20.48meq/kg であった。得られた加熱処理落花生油に蒸留水50gを加え、66.66hPa(50mmHg)、70℃で減圧水蒸気蒸留を行い留分30g回収した。この後は実施例1と同様の方法により処理し、加熱処理落花生油由来呈味改善剤9.01g(過酸化物価0.37meq/kg )を得た。
(Example 4) Taste improving agent derived from peanut oil 100 g of peanut oil (manufactured by Cosmo Oil Chemical Co., Ltd.) was stirred at 100 ° C for 1 hour, and the heat treatment was stopped. The peroxide value was 20.48 meq / kg. Distilled water (50 g) was added to the heat-treated peanut oil obtained, and vacuum distillation was performed at 66.66 hPa (50 mmHg) and 70 ° C. to recover 30 g of a fraction. Thereafter, the mixture was treated in the same manner as in Example 1 to obtain 9.01 g (peroxide value 0.37 meq / kg) of a heat-treated peanut oil-derived taste improver.

(実施例5)オリーブオイル由来の呈味改善剤
オリーブオイル(日清オイリオ(株)製)100gを140℃で1.5時間攪拌し、加熱処理を停止した。過酸化物価は15.45meq/kg であった。得られた加熱オリーブオイルを実施例1と同様の方法により処理し、過酸化物を除去した加熱オリーブオイル由来呈味改善剤8.91g(過酸化物価0.30meq/kg )を得た。
(Example 5) Taste improving agent derived from olive oil 100 g of olive oil (manufactured by Nisshin Oilio Co., Ltd.) was stirred at 140 ° C for 1.5 hours, and the heat treatment was stopped. The peroxide value was 15.45 meq / kg. The obtained heated olive oil was treated in the same manner as in Example 1 to obtain 8.91 g (peroxide value 0.30 meq / kg) of a taste improving agent derived from heated olive oil from which peroxide was removed.

(実施例6)魚油由来呈味改善剤
マグロ魚油(横関油脂工業(株)製)20gと蒸留水10gの混合物に大豆粗酵素(昭和産業株式会社)を魚油に対し0.8%重量添加し、37℃で5時間攪拌した。過酸化物価28meq/kg であることを確認した後、酵素処理マグロ魚油に蒸留水50gを加え、フラスコ内温度が97℃での水蒸気蒸留を行い、留分5gを回収した。水蒸気蒸留処理後の分かれた二層から油脂層を分液して低沸点成分を除去した蒸留物残渣を得た。その油脂状の蒸留物残渣をシリカゲルカラムクロマトグラフィーで処理することにより過酸化物を除去し、呈味改善剤18.3g(過酸化物価 4.2meq/kg )を得た。
(Example 6) Fish oil-derived taste improver 0.8% by weight of crude soybean enzyme (Showa Sangyo Co., Ltd.) with respect to fish oil was added to a mixture of 20 g of tuna fish oil (manufactured by Yokoseki Oil & Fat Co., Ltd.) and 10 g of distilled water. Stir at 5 ° C. for 5 hours. After confirming that the peroxide value was 28 meq / kg, 50 g of distilled water was added to the enzyme-treated tuna fish oil, and steam distillation was performed at a temperature in the flask of 97 ° C. to recover 5 g of a fraction. The oil and fat layer was separated from the two separated layers after the steam distillation treatment to obtain a distillate residue from which low-boiling components were removed. The oily and fat-like distillate residue was treated with silica gel column chromatography to remove the peroxide, thereby obtaining 18.3 g of a taste improver (peroxide value 4.2 meq / kg).

(実施例7) 呈味改善味噌汁の調製
実施例1で、調製した呈味改善剤(サンプル)7.5mgを50℃に暖めた市販味噌汁40mlに添加し、呈味改善味噌汁を得た。
(Example 7) Preparation of taste-improved miso soup 7.5 mg of the taste improver (sample) prepared in Example 1 was added to 40 ml of commercial miso soup warmed to 50 ° C to obtain a taste-improved miso soup.

(試験例1) 官能評価
以下の手順に従って、実施例7の呈味改善味噌汁の官能評価を行った。
(手順)
実施例7の呈味改善味噌汁、および無添加サンプル(呈味改善剤が配合されていない味噌汁)を試飲し、下記評価基準に従って実施例7の呈味改善味噌汁を官能評価した。評価は専門パネル5名で行った。なお、味は、コク味、ボリューム感、舌ざわり感を総合評価した味である。
官能評価結果を表1に示した。
(Test Example 1) Sensory evaluation Sensory evaluation of the taste-improved miso soup of Example 7 was performed according to the following procedure.
(procedure)
The taste-improved miso soup of Example 7 and an additive-free sample (a miso soup containing no taste-improving agent) were sampled, and the taste-improved miso soup of Example 7 was subjected to sensory evaluation according to the following evaluation criteria. The evaluation was conducted by 5 specialist panels. In addition, the taste is a taste that comprehensively evaluates the richness, volume and feeling of tongue.
The sensory evaluation results are shown in Table 1.

(評価基準)
5点: 極めて大きく味が改善されている
4点: 大きく味が改善されている
3点: かなり味が改善されている
2点: 少し味が改善されている
1点: 味が改善されていない(無添加サンプルと変わらない)
表1

Figure 0004596475
表1の数字は専門パネル5名の評価点の平均値である。(以下、同様) (Evaluation criteria)
5 points: Taste is greatly improved 4 points: Taste is greatly improved 3 points: Taste is considerably improved 2 points: Taste is slightly improved 1 point: Taste is not improved (It is not different from the additive-free sample)
Table 1
Figure 0004596475
The numbers in Table 1 are the average values of the evaluation scores of five specialist panels. (Hereinafter the same)

(実施例8) 呈味改善中華スープの調製(サンプル)7.5mgを50℃に暖めた市販中華スー
実施例2で調製した呈味改善剤プ40mlに添加し、呈味改善中華スープを得た。
(Example 8) Preparation of taste-improved Chinese soup (sample) 7.5 mg of commercial Chinese soot warmed to 50 ° C was added to 40 ml of taste-improving agent prepared in Example 2 to obtain a taste-improved Chinese soup. .

(試験例2) 官能評価
試験例1と同様な手順で、実施例2で調製した呈味改善剤を配合した中華スープの官能評価を行った。なお、無添加サンプルは実施例2で調製した呈味改善剤が配合されていない中華スープである。
その官能評価結果を表2に示した。
表2

Figure 0004596475
(Test Example 2) Sensory Evaluation In the same procedure as Test Example 1, sensory evaluation of Chinese soup containing the taste improver prepared in Example 2 was performed. The additive-free sample is a Chinese soup that does not contain the taste improver prepared in Example 2.
The sensory evaluation results are shown in Table 2.
Table 2

Figure 0004596475

(実施例9) 呈味改善コンソメスープの調製
実施例3で調製した呈味改善剤(サンプル)7.5mgを50℃に暖めた市販コンソメスープ40mlに添加し、呈味改善コンソメスープを得た。
(Example 9) Preparation of taste improving consomme soup 7.5 mg of the taste improving agent (sample) prepared in Example 3 was added to 40 ml of commercial consomme soup warmed to 50 ° C to obtain a taste improving consomme soup.

(試験例3) 官能評価
試験例1と同様な手順で、実施例3で調製した呈味改善剤を配合したコンソメスープの官能評価を行った。なお、無添加サンプルは実施例3で調製した呈味改善剤が配合されていないコンソメスープである。
その官能評価結果を表3に示した。
表3

Figure 0004596475
(Test Example 3) Sensory Evaluation In the same procedure as Test Example 1, sensory evaluation of consomme soup containing the taste improver prepared in Example 3 was performed. In addition, an additive-free sample is the consomme soup in which the taste improving agent prepared in Example 3 is not mix | blended.
The sensory evaluation results are shown in Table 3.
Table 3

Figure 0004596475

(実施例10) 呈味改善コンソメスープの調製
実施例4で調製した呈味改善剤(サンプル)7.5mgを50℃に暖めた市販コンソメスープ40mlに添加し、呈味改善コンソメスープを得た。
(Example 10) Preparation of taste improving consomme soup 7.5 mg of the taste improving agent (sample) prepared in Example 4 was added to 40 ml of commercial consomme soup warmed to 50 ° C to obtain a taste improving consomme soup.

(試験例4) 官能評価
試験例1と同様な手順で、実施例4で調製した呈味改善剤を配合したコンソメスープの官能評価を行った。なお、無添加サンプルは実施例4で調製した呈味改善剤が配合されていないコンソメスープである。
その官能評価結果を表4に示した。
表4

Figure 0004596475
(Test Example 4) Sensory evaluation In the same procedure as in Test Example 1, sensory evaluation of the consomme soup containing the taste improver prepared in Example 4 was performed. In addition, the additive-free sample is a consomme soup that is not blended with the taste improver prepared in Example 4.
The sensory evaluation results are shown in Table 4.
Table 4

Figure 0004596475

(実施例11) 呈味改善コンソメスープの調製
実施例5で、調製した呈味改善剤(サンプル)7.5mgを50℃に暖めた市販コンソメスープ40mlに添加し、呈味改善コンソメスープを得た。
(Example 11) Preparation of taste-improving consomme soup In Example 5, 7.5 mg of the taste-improving agent (sample) prepared was added to 40 ml of commercial consomme soup warmed to 50 ° C to obtain a taste-improved consomme soup. .

(試験例5) 官能評価
試験例1と同様な手順で、実施例5で調製した呈味改善剤を配合したコンソメスープの官能評価を行った。なお、無添加サンプルは実施例5で調製した呈味改善剤が配合されていないコンソメスープである。
その官能評価結果を表5に示した。
表5

Figure 0004596475
(Test Example 5) Sensory evaluation In the same procedure as Test Example 1, sensory evaluation of the consomme soup containing the taste improver prepared in Example 5 was performed. The additive-free sample is a consomme soup prepared in Example 5 that does not contain the taste improver.
The sensory evaluation results are shown in Table 5.
Table 5

Figure 0004596475

(実施例12) 呈味改善緑茶の調製
実施例6で作成したサンプルをNikkol Dekaglyn1-SV及びグリセリンを用いて1%の乳化液を調製し、それをカテキン高含有緑茶にサンプルの最終濃度が1ppmになるように添加し、呈味改善緑茶を得た。
(Example 12) Preparation of taste-enhanced green tea The sample prepared in Example 6 was prepared using Nikkol Dekaglyn1-SV and glycerin to prepare a 1% emulsion, which was then added to catechin-rich green tea with a final concentration of 1 ppm. Was added to obtain a green tea with improved taste.

(試験例6) 官能評価
試験例1と同様な手順で、実施例6で調製した呈味改善剤を配合した緑茶の官能評価を行った。なお、無添加サンプルは実施例6で調製した呈味改善剤が配合されていない緑茶である。その官能評価試験例1と同様な官能評価を行った。
その結果を表6に示した。
表6

Figure 0004596475
(Test Example 6) Sensory evaluation In the same procedure as Test Example 1, sensory evaluation of green tea mixed with the taste improver prepared in Example 6 was performed. In addition, an additive-free sample is the green tea in which the taste improving agent prepared in Example 6 is not mix | blended. The same sensory evaluation as that sensory evaluation test example 1 was performed.
The results are shown in Table 6.
Table 6

Figure 0004596475

(実施例15) 呈味改善コーヒー飲料の調製
実施例4の呈味改善剤をモノステアリン酸デカグリセリルとグリセリンを用いて1%乳化製剤を調製し、以下のように作製したコーヒーへ1ppmとなるように添加し、コーヒー飲料を作製した。
より厚みのある味を有するコーヒー飲料が得られた。

レギュラーコーヒー 50
牛乳 100
砂糖 50
乳化剤 0.5
加水全量 1000
(Example 15) Preparation of taste-improved coffee beverage A 1% emulsion preparation was prepared using the taste improver of Example 4 using decaglyceryl monostearate and glycerin, and the resulting coffee was 1 ppm. So that a coffee beverage was prepared.
A coffee beverage having a thicker taste was obtained.

Regular coffee 50
Milk 100
Sugar 50
Emulsifier 0.5
Total amount of water 1000

(実施例15) 呈味改善茶飲料の調製
落花生油より作成したサンプルをモノステアリン酸デカグリセリルとグリセリンを用いて1%乳化製剤を調製し、これを緑茶飲料に100ppm添加した。
より厚みのある味を有する茶飲料が得られた。
(Example 15) Preparation of taste-improved tea beverage A sample prepared from peanut oil was used to prepare a 1% emulsion preparation using decaglyceryl monostearate and glycerin, and this was added to a green tea beverage at 100 ppm.
A tea beverage having a thicker taste was obtained.

(試験例6) 官能評価
試験例1と同様な手順で、実施例6で調製した呈味改善剤を配合した緑茶の官能評価を行った。なお、無添加サンプルは実施例6で調製した呈味改善剤が配合されていない緑茶である。その官能評価試験例1と同様な官能評価を行った。
その結果を表6に示した。
表6

Figure 0004596475
(Test Example 6) Sensory evaluation In the same procedure as Test Example 1, sensory evaluation of green tea mixed with the taste improver prepared in Example 6 was performed. In addition, an additive-free sample is the green tea in which the taste improving agent prepared in Example 6 is not mix | blended. The same sensory evaluation as that sensory evaluation test example 1 was performed.
The results are shown in Table 6.
Table 6

Figure 0004596475

本発明を次のように記載することができる。
酸化処理した動植物油脂の高沸点成分混合物からなることを特徴とする呈味改善剤、酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣の精製処理物、酸化処理した動植物油脂の精製処理物から低沸点成分を除去した処理物、または請求項4記載の香料組成物から選ばれる一種、あるいは二種以上を飲食品に添加することを特徴とする飲食品への呈味改善方法。


The present invention can be described as follows.
Taste improving agent comprising a mixture of high-boiling components of oxidized animal and vegetable oils and fats, purified product of distillate residue obtained by removing low-boiling components from oxidized animal and vegetable oils and fats, and purification treatment of oxidized animal and vegetable oils and fats A method for improving the taste of a food or drink, comprising adding one or two or more kinds selected from a processed product obtained by removing low-boiling components from a product, or a fragrance composition according to claim 4 to the food or drink.


Claims (5)

酸化処理した動植物油脂から低沸点成分を除去した蒸留物残渣を有効成分とすることを特徴とする呈味改善剤。ただし、前記低沸点成分は45〜75℃、13.33〜93.33hPaでの減圧蒸留法あるいは減圧水蒸気蒸留法、又は常圧水蒸気蒸留法により回収できる成分をいう。 A taste improver characterized by comprising, as an active ingredient, a distillate residue obtained by removing low boiling point components from oxidized animal and vegetable fats and oils. However, the low boiling point component refers to a component that can be recovered by a vacuum distillation method, a vacuum steam distillation method, or an atmospheric steam distillation method at 45 to 75 ° C. and 13.33 to 93.33 hPa. 酸化処理した動植物油脂を45〜75℃、13.33〜93.33hPaで減圧蒸留処理あるいは減圧水蒸気蒸留処理して得た蒸留残渣、又は常圧水蒸気蒸留処理して得た蒸留残渣を有効成分とすることを特徴とする呈味改善剤。 An active ingredient is a distillation residue obtained by subjecting oxidized animal and vegetable oils and fats to vacuum distillation treatment or reduced pressure steam distillation treatment at 45 to 75 ° C. and 13.33 to 93.33 hPa, or a distillation residue obtained by atmospheric steam distillation treatment. The taste improving agent characterized by carrying out. 蒸留物残渣又は蒸留残渣の精製処理物を有効成分とすることを特徴とする請求項1又は2記載の呈味改善剤。 3. The taste improver according to claim 1 or 2, wherein a distillate residue or a purified product of the distillation residue is used as an active ingredient. 請求項1〜3記載のいずれかの呈味改善剤を含有することを特徴とする香料組成物。 A fragrance composition comprising the taste improver according to claim 1. 請求項1〜3記載のいずれかの呈味改善剤、又は請求項4記載の香料組成物を含有することを特徴とする飲食品。 Food / beverage products containing the taste improving agent in any one of Claims 1-3, or the fragrance | flavor composition of Claim 4.
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