JP4585487B2 - Pesticide residue measuring device - Google Patents

Pesticide residue measuring device Download PDF

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JP4585487B2
JP4585487B2 JP2006164673A JP2006164673A JP4585487B2 JP 4585487 B2 JP4585487 B2 JP 4585487B2 JP 2006164673 A JP2006164673 A JP 2006164673A JP 2006164673 A JP2006164673 A JP 2006164673A JP 4585487 B2 JP4585487 B2 JP 4585487B2
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vegetables
fruits
juice
mirror
measuring apparatus
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JP2007333513A (en
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久美子 中川
修一 清水
久也 山田
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Yanmar Co Ltd
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Yanmar Co Ltd
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Description

本発明は、収穫された青果物に含まれる残留農薬の、種類や量や濃度等を測定する残留農薬測定装置の技術に関する。   The present invention relates to a technique for a residual pesticide measuring apparatus that measures the type, amount, concentration, and the like of a residual pesticide contained in harvested fruits and vegetables.

収穫された青果物に付着した残留農薬については、該残留農薬が食品衛生法残留農薬基準値に適合しているか否かを測定する必要があるため、従来より、委託分析やELISA法を用いた簡易分析による破壊検査によって検査を行っていた(例えば、特許文献1参照。)。
特表2005−509158号公報
For residual agricultural chemicals attached to harvested fruits and vegetables, it is necessary to measure whether the residual agricultural chemicals meet the standard values for residual agricultural chemicals in the Food Sanitation Law. Inspection was performed by destructive inspection by analysis (for example, refer to Patent Document 1).
JP 2005-509158 A

しかし、前記委託分析においては、委託費用が高価であり、且つ分析結果が出るまでに長い時間がかかる等の問題点があった。一方のELISA法を用いた簡易分析においては、数時間で分析結果が出るものの、試料作成作業に時間がかかり面倒であった。そこで、本発明が解決しようとする課題は、試料の作成を短時間で行うことができ、残留農薬濃度等の測定結果が素早く得られる残留農薬測定装置を提供することにある。   However, the commissioned analysis has a problem that the commissioned cost is expensive and it takes a long time to obtain an analysis result. On the other hand, in the simple analysis using the ELISA method, although an analysis result is obtained in a few hours, the sample preparation work takes time and is troublesome. Therefore, the problem to be solved by the present invention is to provide a residual pesticide measuring apparatus capable of preparing a sample in a short time and quickly obtaining measurement results such as the residual pesticide concentration.

本発明の解決しようとする課題は以上の如くであり、次にこの課題を解決するための手段を説明する。   The problem to be solved by the present invention is as described above. Next, means for solving the problem will be described.

請求項1においては、赤外分光光度計を利用して青果物の残留農薬濃度を測定する残留農薬測定装置であって、該残留農薬測定装置(1)は赤外分光光度計(2)と、拡散反射装置(3)とから構成し、該拡散反射装置(3)は、干渉計(5)で合成されて投光される赤外線を導く2枚の照射用光路変更ミラー(11・12)と、該2枚の照射用光路変更ミラー(11・12)によって導かれた赤外線を反射して、支持台(20)上の搾汁容器(22)に貯溜された搾汁(9)の表面へと照射する照射用ミラー(13)と、該搾汁(9)表面で反射した赤外線を2枚の受光用光路変更ミラー(18・19)へと反射する受光用ミラー(17)とから構成し、該拡散反射装置(3)の下部には支持台(20)を水平に設け、該支持台(20)の後端には支持壁(21)を立設し、該支持台(20)上には、該搾汁容器(22)を載置し、該支持壁(21)には、前記の6枚のミラー(11・12・13・17・18・19)を正面視において回動自在に、若しくは上下左右方向へ摺動自在に、前方へ向けて立設し、照射される赤外線の焦点位置を該搾汁(9)の水面の表面に合わせて照射するように、前記照射用ミラー(13)及び受光用ミラー(17)はアクチュエータを用いて高さを調節可能とし、該照射用ミラー(13)及び受光用ミラー(17)の高さ調節に応じて、他の4枚のミラー(11・12・18・19)の角度を、他のアクチュエータを用いて自動的に調節可能に構成したものである。   In Claim 1, it is a residual pesticide measuring apparatus which measures the residual pesticide density | concentration of fruits and vegetables using an infrared spectrophotometer, This residual pesticide measuring apparatus (1) is an infrared spectrophotometer (2), The diffuse reflection device (3) is composed of two irradiating optical path changing mirrors (11, 12) for guiding the infrared rays synthesized and projected by the interferometer (5). The infrared rays guided by the two irradiation optical path changing mirrors (11, 12) are reflected to the surface of the juice (9) stored in the juice container (22) on the support base (20). And an irradiation mirror (13) for irradiating, and an infrared ray reflected on the surface of the juice (9) and two light receiving mirrors (17) for reflecting the two light receiving optical path changing mirrors (18, 19). The support base (20) is horizontally provided at the lower part of the diffuse reflector (3), and the support base (20) A support wall (21) is erected at the end, the juice container (22) is placed on the support base (20), and the six mirrors are placed on the support wall (21). (11 ・ 12 ・ 13 ・ 17 ・ 18 ・ 19) are erected forward so that they can be rotated in front view or slidable in the vertical and horizontal directions. The irradiation mirror (13) and the light receiving mirror (17) can be adjusted in height using an actuator so as to irradiate with the surface of the water surface of the juice (9), and the irradiation mirror (13) and According to the height adjustment of the light receiving mirror (17), the angles of the other four mirrors (11, 12, 18, 19) can be automatically adjusted using other actuators. .

請求項2においては、請求項1に記載の残留農薬測定装置において、前記支持台(20)上に載置する青果物(10)の載置台(23)を具備し、前記赤外線の焦点位置を、前記支持台(20)上に載置された載置台(23)上の該青果物(10)の上表面に対しても、調節可能としたものである。 In Claim 2, in the residual pesticide measuring apparatus of Claim 1, it comprises the mounting base (23) of the fruits and vegetables (10) mounted on the said support stand (20), and the focus position of the said infrared rays, The upper surface of the fruits and vegetables (10) on the mounting table (23) mounted on the support table (20) can also be adjusted.

本発明の効果として、以下に示すような効果を奏する。   As effects of the present invention, the following effects can be obtained.

請求項1においては、赤外分光光度計を利用して青果物の残留農薬濃度を測定する残留農薬測定装置であって、該残留農薬測定装置(1)は赤外分光光度計(2)と、拡散反射装置(3)とから構成し、該拡散反射装置(3)は、干渉計(5)で合成されて投光される赤外線を導く2枚の照射用光路変更ミラー(11・12)と、該2枚の照射用光路変更ミラー(11・12)によって導かれた赤外線を反射して、支持台(20)上の搾汁容器(22)に貯溜された搾汁(9)の表面へと照射する照射用ミラー(13)と、該搾汁(9)表面で反射した赤外線を2枚の受光用光路変更ミラー(18・19)へと反射する受光用ミラー(17)とから構成し、該拡散反射装置(3)の下部には支持台(20)を水平に設け、該支持台(20)の後端には支持壁(21)を立設し、該支持台(20)上には、該搾汁容器(22)を載置し、該支持壁(21)には、前記の6枚のミラー(11・12・13・17・18・19)を正面視において回動自在に、若しくは上下左右方向へ摺動自在に、前方へ向けて立設し、照射される赤外線の焦点位置を該搾汁(9)の水面の表面に合わせて照射するように、前記照射用ミラー(13)及び受光用ミラー(17)はアクチュエータを用いて高さを調節可能とし、該照射用ミラー(13)及び受光用ミラー(17)の高さ調節に応じて、他の4枚のミラー(11・12・18・19)の角度を、他のアクチュエータを用いて自動的に調節可能に構成したので、青果物から搾汁を搾り出すだけで残留農薬濃度等を測定することができるようになる。つまり、高価な委託分析の必要が無くなり、ELISA法のように試料の作成に多くの時間を割く必要も無くなる。換言すれば、試料の作成を短時間で行うことができ、残留農薬濃度等の測定結果が素早く得られるようになるのである。   In Claim 1, it is a residual pesticide measuring apparatus which measures the residual pesticide density | concentration of fruits and vegetables using an infrared spectrophotometer, This residual pesticide measuring apparatus (1) is an infrared spectrophotometer (2), The diffuse reflection device (3) is composed of two irradiating optical path changing mirrors (11, 12) for guiding the infrared rays synthesized and projected by the interferometer (5). The infrared rays guided by the two irradiation optical path changing mirrors (11, 12) are reflected to the surface of the juice (9) stored in the juice container (22) on the support base (20). And an irradiation mirror (13) for irradiating, and an infrared ray reflected on the surface of the juice (9) and two light receiving mirrors (17) for reflecting the two light receiving optical path changing mirrors (18, 19). The support base (20) is horizontally provided at the lower part of the diffuse reflector (3), and the support base (20) A support wall (21) is erected at the end, the juice container (22) is placed on the support base (20), and the six mirrors are placed on the support wall (21). (11 ・ 12 ・ 13 ・ 17 ・ 18 ・ 19) are erected forward so that they can be rotated in front view or slidable in the vertical and horizontal directions. The irradiation mirror (13) and the light receiving mirror (17) can be adjusted in height using an actuator so as to irradiate with the surface of the water surface of the juice (9), and the irradiation mirror (13) and The angle of the other four mirrors (11, 12, 18, 19) can be automatically adjusted by using other actuators according to the height adjustment of the light receiving mirror (17). Residual pesticide concentration etc. can be measured simply by squeezing juice fromIn other words, there is no need for expensive commissioned analysis, and there is no need to spend much time on sample preparation as in the ELISA method. In other words, the preparation of the sample can be performed in a short time, and measurement results such as residual agricultural chemical concentration can be obtained quickly.

請求項2においては、請求項1に記載の残留農薬測定装置において、前記支持台(20)上に載置する青果物(10)の載置台(23)を具備し、前記赤外線の焦点位置を、前記支持台(20)上に載置された載置台(23)上の該青果物(10)の上表面に対しても、調節可能としたので、青果物表面に付着した残留農薬濃度等を測定する場合に、青果物を破壊することなく青果物表面の残留農薬濃度等を測定することができる。これによって、時間をかければ全数検査もできるようになる。 In Claim 2, in the residual pesticide measuring apparatus of Claim 1, it comprises the mounting base (23) of the fruits and vegetables (10) mounted on the said support stand (20), and the focus position of the said infrared rays, Since the upper surface of the fruits and vegetables (10) on the mounting table (23) mounted on the support table (20) can be adjusted, the concentration of residual agricultural chemicals attached to the surface of the fruits and vegetables is measured. In this case, the concentration of pesticide residue on the surface of fruits and vegetables can be measured without destroying the fruits and vegetables. As a result, 100% inspection can be performed over time.

次に、発明の実施の形態を説明する。   Next, embodiments of the invention will be described.

図1は本発明の一実施例に係る搾汁容器22使用時の残留農薬測定装置1を示す正面図、図2は同じく斜視図である。   FIG. 1 is a front view showing a residual pesticide measuring apparatus 1 when using a squeeze container 22 according to one embodiment of the present invention, and FIG. 2 is a perspective view of the same.

図3は受光した赤外線のスペクトルを示すグラフ、図4は載置台23使用時の残留農薬測定装置1を示す正面図、図5は同じく斜視図である。   FIG. 3 is a graph showing the spectrum of received infrared rays, FIG. 4 is a front view showing the residual pesticide measuring apparatus 1 when the mounting table 23 is used, and FIG. 5 is a perspective view.

本発明に係る残留農薬測定装置1は、赤外線を利用して青果物10に含まれる残留農薬の種類や量や濃度等(以下、「残留農薬濃度等」とする。)の測定を行うものであり、以下では、図1乃至図3を用いて本発明の残留農薬測定装置1の実施の一形態について説明する。   The pesticide residue measuring apparatus 1 according to the present invention measures the type, amount, concentration, etc. (hereinafter referred to as “residual pesticide concentration, etc.”) of the residual pesticide contained in the fruits and vegetables 10 using infrared rays. Hereinafter, an embodiment of the residual pesticide measuring apparatus 1 according to the present invention will be described with reference to FIGS. 1 to 3.

残留農薬測定装置1で取り扱う青果物10は、イチゴ・蜜柑・オレンジ・メロン・トマトその他の果物類または野菜類の総称であり、残留農薬濃度等や糖度(甘味)や酸度(酸味)等の品質によって選別されるものである。そして、残留農薬測定装置1を用いて残留農薬濃度等により適合個体(残留農薬濃度等が基準値以内の青果物10)と不適合個体(残留農薬濃度等が基準値超の青果物10)に、糖度や酸度等の内部品質によって階級別に選別されるものである。   The fruits and vegetables 10 handled by the pesticide residue measuring apparatus 1 is a generic name for strawberries, tangerines, oranges, melons, tomatoes and other fruits or vegetables, depending on the residual pesticide concentration, quality of sugar (sweetness), acidity (acidity), etc. It is what is selected. Then, by using the residual pesticide measuring apparatus 1, depending on the residual pesticide concentration, etc., the sugar content or Sorted by rank according to internal quality such as acidity.

具体的には、本発明に係る残留農薬測定装置1においては、測定対象たる青果物10に対して、その表面に付着した残留農薬濃度等を測定することが難しい場合、青果物10を搾ったり押しつぶしたりすることによって青果物10の搾汁9を取り出し、該搾汁9に含まれる残留農薬濃度等を測定できる構成になっている。つまり、青果物10の表面に対して焦点が定め難い場合や青果物10の内部に浸透してしまうような成分を含む残留農薬濃度等を測定することが可能な構成になっている。焦点を定め難い青果物としてはパセリや春菊等の葉菜類や表面に凹凸や毛があるクワ、キーウィフルーツ、レイシ等が挙げられる。具体的には、後述するように、作業者等によって青果物10から得られた搾汁9や粉砕体含有溶液が搾汁容器22に注入され、該搾汁容器22が残留農薬測定装置1の支持台20上に載置されて、赤外線によって搾汁9表面近傍の残留農薬濃度等の測定が行われるものである。   Specifically, in the residual pesticide measuring apparatus 1 according to the present invention, when it is difficult to measure the concentration of residual pesticide attached to the surface of the target fruit 10, the fruit 10 is squeezed or crushed. By doing so, the juice 9 of the fruits and vegetables 10 is taken out, and the concentration of residual agricultural chemicals contained in the juice 9 can be measured. In other words, it is possible to measure the concentration of residual agricultural chemicals and the like including components that may penetrate the inside of the fruits and vegetables 10 when it is difficult to focus on the surface of the fruits and vegetables 10. Fruits and vegetables that are difficult to focus on include leafy vegetables such as parsley and spring chrysanthemum, mulberry with unevenness and hair on the surface, kiwifruit, and litchi. Specifically, as will be described later, the juice 9 and the crushed body-containing solution obtained from the fruits and vegetables 10 are poured into the juice container 22 by an operator or the like, and the juice container 22 supports the residual agricultural chemical measuring apparatus 1. It is placed on the table 20 and the residual pesticide concentration in the vicinity of the surface of the juice 9 is measured by infrared rays.

図1及び図2に示すように、本発明の残留農薬測定装置1は赤外分光光度計2と、該赤外分光光度計2に付設した拡散反射装置3とから成るものである。該赤外分光光度計2は、投光部4と、該投光部4にて発した赤外線を分割し合成(干渉)して拡散反射装置3へと投光する干渉計5と、拡散反射装置3からの光を受光して検知する検知手段6と、該検知手段6から得られた出力信号をデジタル信号に変換するAD変換器7と、該AD変換器7から送られてくる光の情報をスペクトル分析し残留農薬濃度等を演算する演算記憶部8aと、該演算記憶部8aで演算された分析結果等を表示する表示部8b、などから構成されている。   As shown in FIG. 1 and FIG. 2, the residual pesticide measuring apparatus 1 of the present invention comprises an infrared spectrophotometer 2 and a diffuse reflector 3 attached to the infrared spectrophotometer 2. The infrared spectrophotometer 2 includes a light projecting unit 4, an interferometer 5 that divides and synthesizes (interferes) the infrared rays emitted from the light projecting unit 4, and projects the light to the diffuse reflection device 3. Detection means 6 that receives and detects light from the device 3, an AD converter 7 that converts an output signal obtained from the detection means 6 into a digital signal, and light that is sent from the AD converter 7 A calculation storage unit 8a for spectrally analyzing information and calculating a residual pesticide concentration and the like, a display unit 8b for displaying an analysis result calculated by the calculation storage unit 8a, and the like.

前記拡散反射装置3は、前記干渉計5で合成されて投光される赤外線を下記照射用ミラー13へと導く光路変更手段14と、照射用光路変更ミラー11・12と、該照射用光路変更ミラー11・12によって導かれた該赤外線を反射して後述する支持台20上の搾汁容器22に貯溜された搾汁9表面へと照射する照射用ミラー13と、該搾汁9表面で反射した赤外線を受光用光路変更ミラー18・19へと反射する受光用ミラー17と、該受光用光路変更ミラー18・19から投光されてくる赤外線を前記検知手段6へと投光する光路変更手段15、などから構成されている。   The diffuse reflection device 3 includes an optical path changing means 14 for guiding infrared rays synthesized and projected by the interferometer 5 to the following irradiation mirror 13, irradiation optical path changing mirrors 11 and 12, and the irradiation optical path changing. Reflecting the infrared rays guided by the mirrors 11 and 12 to irradiate the surface of the juice 9 stored in the juice container 22 on the support 20 described later, and reflected on the surface of the juice 9 Light receiving mirror 17 for reflecting the received infrared rays to the light receiving optical path changing mirrors 18 and 19, and optical path changing means for projecting the infrared rays projected from the light receiving optical path changing mirrors 18 and 19 to the detecting means 6. 15 and so on.

拡散反射装置3下部には支持台20が水平に設けられており、該支持台20の後端には支持壁21が立設されている。該支持台20は青果物10の搾汁9が貯溜された搾汁容器22が載置されるものであり、該支持壁21には、後述するように、前記ミラー11・12・13・17・18・19が正面視において回動自在に、若しくは上下左右方向へ摺動自在に前方へと立設されている。   A support base 20 is horizontally provided at the lower part of the diffuse reflector 3, and a support wall 21 is erected at the rear end of the support base 20. The support table 20 is used to place a squeeze container 22 in which the squeezed juice 9 of the fruits and vegetables 10 is stored. As described later, the support wall 21 has the mirrors 11, 12, 13, 17, 18 and 19 are erected forward so as to be rotatable in front view or slidable in the vertical and horizontal directions.

前記搾汁容器22は、上部に青果物10から得られた搾汁9が貯溜されるものであって、上方が開放された容器である。詳しくは、該搾汁容器22は、作業者等により測定対象たる青果物10を絞って得られた搾汁9が注入されて貯溜されるものであって、該搾汁9表面の残留農薬濃度等の測定時に残留農薬測定装置1の支持台20上に載置されるものである。   The squeeze container 22 is a container in which the squeeze 9 obtained from the fruits and vegetables 10 is stored in the upper part, and the upper part is opened. Specifically, the squeeze container 22 is filled with squeezed 9 obtained by squeezing the fruits and vegetables 10 to be measured by an operator and the like, and the residual pesticide concentration on the surface of the squeezed 9 and the like Is placed on the support 20 of the residual pesticide measuring apparatus 1 during the measurement.

図1に戻って、演算記憶部8a及び表示部8bから成る制御手段8は残留農薬測定装置1の動作を制御するものであって、これらの動作を制御するためのプログラムが格納されている。つまり、拡散反射装置3から種々の情報を取得したり、該取得した情報をスペクトル分析等によって解析したり、該拡散反射装置3等へ電力を供給したりすることが可能である。換言すれば、該演算記憶部8aは、拡散反射装置3から送信されてきた反射光に関する出力信号を受信して、該出力信号をスペクトルに変換するものであって、詳しくは、前記検知手段6で受光した反射光の情報がAD変換器7を介して演算記憶部8aへと送信され、該演算記憶部8aにおいて、受信した反射光の時間関数としての波形を周波数の関数としてのスペクトルへとフーリエ変換を行う。   Returning to FIG. 1, the control means 8 comprising the calculation storage unit 8a and the display unit 8b controls the operation of the residual pesticide measuring apparatus 1, and stores a program for controlling these operations. That is, it is possible to acquire various information from the diffuse reflection device 3, analyze the acquired information by spectrum analysis or the like, and supply power to the diffuse reflection device 3 or the like. In other words, the calculation storage unit 8a receives an output signal related to the reflected light transmitted from the diffuse reflection device 3, and converts the output signal into a spectrum. The information of the reflected light received at is transmitted to the calculation storage unit 8a via the AD converter 7, and the calculation storage unit 8a converts the waveform of the received reflected light as a time function into a spectrum as a function of frequency. Perform Fourier transform.

該フーリエ変換の結果は、図3に示すような赤外線スペクトルとして表示部8bにて表示される。そして、該表示されたスペクトルを作業者等が目視で判断して、若しくは、演算記憶部8aによって演算されたスペクトルを画像処理して自動で、搾汁9毎に求められた残留農薬濃度等が基準値以内であるか否かを判断する。該判断結果を該表示部8bに表示することによって、作業者等が青果物10・・・を適合個体(基準値以内の青果物10)と不適合個体(基準値超の青果物10)に選別することができる。具体的には、演算記憶部8aが、該スペクトルと残留農薬の種類ごとに予め実験的に得られた変換テーブルに基いて、残留農薬の種類が判別されて、残留農薬濃度等が求められ、残留農薬濃度等が基準値以内であるか否か(適合個体であるか、不適合個体であるか)判断されて、該判断結果が表示部8bに表示される構成になっている。   The result of the Fourier transform is displayed on the display unit 8b as an infrared spectrum as shown in FIG. Then, the operator can visually determine the displayed spectrum, or the spectrum calculated by the calculation storage unit 8a is automatically processed and the residual pesticide concentration obtained for each juice 9 is automatically determined. It is determined whether it is within the reference value. By displaying the determination result on the display unit 8b, an operator or the like can select the fruits and vegetables 10... As the suitable individuals (the fruits and vegetables 10 within the reference value) and the non-conforming individuals (the fruits and vegetables 10 exceeding the reference value). it can. Specifically, the arithmetic storage unit 8a determines the type of residual pesticide based on a conversion table obtained experimentally in advance for each spectrum and type of residual pesticide, and determines the residual pesticide concentration and the like. It is determined whether the residual agricultural chemical concentration or the like is within a reference value (whether it is a compatible individual or a non-conforming individual), and the determination result is displayed on the display unit 8b.

本発明の残留農薬測定装置1は、赤外線による残留農薬測定装置1を用いて青果物10表面に付着した、または、浸透した残留農薬濃度等を測定するものであるため、測定対象たる青果物10から得られた搾汁9の表面を最適な位置(以下、焦点位置とする。)に調節しなければ、正確な搾汁9表面のスペクトルを得ることができない。詳しくは、測定される搾汁9の表面の位置が最適でない場合は、検知手段6で受ける反射光の強度が弱くなるため、スペクトルの波形において波長に応じた強度の違い(スペクトルの凹凸)がはっきりと識別できなくなり、その結果搾汁9に含まれる残留農薬濃度等が正確に判断できなくなるのである。   The residual pesticide measuring apparatus 1 of the present invention measures the residual pesticide concentration adhered to or penetrates the surface of the fruits and vegetables 10 using the residual pesticide measuring apparatus 1 by infrared rays, and thus obtained from the fruits and vegetables 10 to be measured. Unless the surface of the squeezed juice 9 is adjusted to an optimum position (hereinafter referred to as a focal position), an accurate spectrum of the surface of the squeezed 9 cannot be obtained. Specifically, when the position of the surface of the juice 9 to be measured is not optimal, the intensity of the reflected light received by the detection means 6 becomes weak, and therefore there is a difference in intensity (spectrum unevenness) according to the wavelength in the spectrum waveform. As a result, it becomes impossible to discriminate clearly, and as a result, the concentration of residual agricultural chemicals contained in the juice 9 cannot be accurately determined.

そこで、該搾汁9が注入された該搾汁容器22を残留農薬測定装置1の支持台20上に載置する。そして、制御手段8によって、例えば、照射用ミラー13及び受光用ミラー17の高さ調節を行い、前記ミラー11・12・18・19の角度調節を行って、赤外線の焦点位置を搾汁9の表面に一致させてスペクトル分析を行う。   Therefore, the squeeze container 22 into which the squeezed juice 9 has been injected is placed on the support table 20 of the residual pesticide measuring apparatus 1. Then, for example, the height of the irradiation mirror 13 and the light receiving mirror 17 is adjusted by the control means 8, the angle of the mirrors 11, 12, 18, and 19 is adjusted, and the focal position of the infrared rays is adjusted to the juice 9. Spectral analysis is performed on the surface.

具体的には、演算記憶部8aにおいては、フーリエ変換後の前記スペクトルを基に、該スペクトルのエネルギー若しくは強度若しくは強度の凹凸が小さい場合に、前記ミラー11・12・13・17・18・19等の高さや角度を調節しても良いし、前記コンテナ等から他の青果物10を取り出して搾汁9を作り直してから、スペクトル分析を行っても良い。そして、スペクトルのエネルギー若しくは強度若しくは強度の凹凸が大きい場合には、該制御手段8の演算記憶部8aにて、該スペクトルに基いて残留農薬の種類を判断して残留農薬濃度等を演算し、該残留農薬濃度等が食品衛生法残留農薬基準値に適合しているか否かの判断を行うのである。   Specifically, in the calculation storage unit 8a, when the energy, intensity, or intensity unevenness of the spectrum is small based on the spectrum after Fourier transform, the mirrors 11, 12, 13, 17, 18, 19 are used. The height or angle may be adjusted, or another fruit and vegetables 10 may be taken out of the container or the like to recreate the juice 9, and then the spectrum analysis may be performed. If the spectrum energy or intensity or the intensity unevenness is large, the calculation storage unit 8a of the control means 8 determines the type of residual agricultural chemical based on the spectrum and calculates the residual agricultural chemical concentration, Judgment is made as to whether the residual agricultural chemical concentration and the like conform to the standard values of residual agricultural chemicals in the Food Sanitation Law.

換言すれば、搾汁容器22が支持台20上に載置されると、照射用ミラー13及び受光用ミラー17が上下左右に移動しながら、投光部4から干渉計5や照射用ミラー13を介して赤外線が搾汁9表面へと照射され、該搾汁9表面にて反射した反射光を受光用ミラー17や光路変更手段15を介して検知手段6にて吸収する。そして、吸収された赤外線の情報を制御手段8に送信する(すなわち、制御手段8は残留農薬測定装置1から青果物10の光学的情報を取得する)。演算記憶部8aでは、フーリエ変換後の前記スペクトルを基に、スペクトルのエネルギー若しくは強度若しくは強度の凹凸が演算されて、照射用ミラー13や受光用ミラー17が上下方向に摺動しつつ他のミラー11・12・18・19が回動して、赤外線の焦点位置が搾汁9表面に位置するような構成となっている。   In other words, when the squeeze container 22 is placed on the support table 20, the interferometer 5 and the irradiation mirror 13 are projected from the light projecting unit 4 while the irradiation mirror 13 and the light receiving mirror 17 move up and down and left and right. Infrared light is irradiated to the surface of the juice 9 through the light, and the reflected light reflected by the surface of the juice 9 is absorbed by the detection means 6 via the light receiving mirror 17 and the optical path changing means 15. Then, the absorbed infrared information is transmitted to the control means 8 (that is, the control means 8 acquires the optical information of the fruits and vegetables 10 from the residual pesticide measuring apparatus 1). In the calculation storage unit 8a, the spectrum energy, intensity, or intensity unevenness is calculated based on the spectrum after Fourier transform, and the other mirrors while the irradiation mirror 13 and the light receiving mirror 17 slide in the vertical direction. 11, 12, 18 and 19 are rotated so that the infrared focal point is positioned on the surface of the juice 9.

詳しくは、照射用ミラー13及び受光用ミラー17はシリンダ等のアクチュエータを用いて高さを調節可能とし、該照射用ミラー13及び受光用ミラー17の高さに応じてミラー11・12・18・19の角度がモータ等のアクチュエータを用いて自動で調節されるように構成することにより、前記スペクトルのエネルギー若しくは強度若しくは強度の凹凸が大きい位置にて搾汁9の残留農薬濃度等を測定して、該青果物10が適合個体か不適合個体か判断する構成となっている。この場合は、作業者等が表示部8bに表示されるスペクトルを見ながら照射用ミラー13及び受光用ミラー17の高さ調節を行うシステムでも良いし、照射用ミラー13及び受光用ミラー17が自動で上下する間に、演算記憶部8aにおいてスペクトルのエネルギー若しくは強度若しくは強度の凹凸が大きい焦点位置を探し(演算し)、該焦点位置において残留農薬の種類及び濃度を測定し、適合個体と不適合個体の判断を行うシステムであっても良い。   Specifically, the height of the irradiation mirror 13 and the light receiving mirror 17 can be adjusted by using an actuator such as a cylinder, and the mirrors 11, 12, 18, and so on can be adjusted according to the height of the irradiation mirror 13 and the light receiving mirror 17. By configuring the angle of 19 to be automatically adjusted using an actuator such as a motor, the residual pesticide 9 concentration in the juice 9 is measured at a position where the energy or intensity of the spectrum or the unevenness of the intensity is large. The fruit and vegetable 10 is configured to determine whether it is a compatible individual or an incompatible individual. In this case, a system in which an operator or the like adjusts the height of the irradiation mirror 13 and the light receiving mirror 17 while observing the spectrum displayed on the display unit 8b, or the irradiation mirror 13 and the light receiving mirror 17 are automatically set. In the calculation storage unit 8a, a focal position with a large spectrum energy or intensity or intensity unevenness is searched (calculated), and the type and concentration of the residual pesticide are measured at the focal position. It may be a system that makes the above determination.

また、予め、スペクトルのエネルギーが最大となる搾汁9の表面位置を、搾汁容器22にマーキングしておき、作業者が該マーカーの位置まで搾汁9を注入することによって搾汁9表面を赤外線の焦点位置に合わせる構成としても良い。ここで、該エネルギーとは、検知手段6等で測定した赤外線の反射光の強度であっても良いし、スペクトルの強度を波長で積分した値であっても良い。上記のように、前記残留農薬濃度等の測定の結果、適合個体が多いコンテナ等は、コンテナ等を適合個体である青果物10・10・・・の集合(ロット)であると推定して出荷したり、該コンテナ等の青果物10・10・・・について糖度の判定等の他の内部品質の測定を行うことができる。逆に、不適合個体が多いコンテナ等は、コンテナ等を不適合個体である青果物10・10・・・の集合(ロット)とすることができる。前記コンテナ1つに対して、複数個の青果物についてこのような測定を施すことが好ましい。   In addition, the surface position of the juice 9 where the energy of the spectrum is maximized is marked on the juice container 22 in advance, and the operator injects the juice 9 to the position of the marker so that the surface of the juice 9 is It is good also as a structure matched with the focus position of infrared rays. Here, the energy may be the intensity of reflected infrared light measured by the detecting means 6 or the like, or may be a value obtained by integrating the intensity of the spectrum with the wavelength. As described above, as a result of the measurement of the residual pesticide concentration and the like, containers and the like having a lot of compatible individuals are estimated to be a set (lot) of fruits and vegetables 10 · 10... Or other internal qualities such as determination of sugar content can be measured for the fruits and vegetables 10. On the other hand, a container or the like having many nonconforming individuals can be a set (lot) of fruits and vegetables 10, 10. It is preferable to perform such a measurement on a plurality of fruits and vegetables with respect to one container.

以下、搾汁容器22を用いた搾汁9表面の残留農薬濃度等の測定手順について説明する。図1乃至図3に示すように、残留農薬測定装置1は、例えば、作業者によって測定したい青果物10を搾ったり押しつぶしたり粉砕したりして、該青果物10から得られた搾汁9を搾汁容器22に注入する。そして、残留農薬測定装置1の支持台20上に搾汁容器22を載置して、投光部4より干渉計5や照射用ミラー13を介して該搾汁9表面に赤外線を照射して、該搾汁9表面で反射した反射光を受光用ミラー17や光路変更手段15を介して検知手段6で吸収する。   Hereinafter, measurement procedures such as residual agricultural chemical concentration on the surface of the juice 9 using the juice container 22 will be described. As shown in FIGS. 1 to 3, the residual pesticide measuring apparatus 1 squeezes, crushes, or pulverizes the fruits and vegetables 10 to be measured by an operator, and squeezes the juice 9 obtained from the fruits and vegetables 10. Inject into container 22. And the squeeze container 22 is mounted on the support stand 20 of the residual pesticide measuring apparatus 1, and infrared rays are irradiated to the surface of the squeeze 9 from the light projecting unit 4 via the interferometer 5 and the irradiation mirror 13. The reflected light reflected by the surface of the juice 9 is absorbed by the detecting means 6 via the light receiving mirror 17 and the optical path changing means 15.

詳しくは、支持台20の高さや前記ミラー11・12・13・17・18・19の高さや角度を調節することによって、搾汁9表面に赤外線の焦点位置を合わせつつ照射用ミラー13から搾汁容器22の搾汁9の上表面に赤外線を照射して、該赤外線が搾汁9の水面で反射して、該反射光が受光用ミラー17や光路変更手段15を介して検知手段6へと投光される。   Specifically, by adjusting the height of the support base 20 and the height and angle of the mirrors 11, 12, 13, 17, 18, and 19, the squeezed 9 is squeezed from the irradiation mirror 13 while adjusting the infrared focal point to the surface of the squeeze 9. The upper surface of the juice 9 of the juice container 22 is irradiated with infrared rays, the infrared rays are reflected by the water surface of the juice 9, and the reflected light is transmitted to the detection means 6 via the light receiving mirror 17 and the optical path changing means 15. It is projected.

そして、検知手段6に吸収された搾汁9水面における反射光の光学的情報は、AD変換器7にてデジタル信号に変換されて演算記憶部8aへと送信される。そして、演算記憶部8aにてスペクトル分析を行うことにより、搾汁容器22の搾汁9表面における残留農薬濃度等が測定され、該青果物10が適合個体であるか不適合個体であるかの判断が行われて、当該測定結果及び判断結果が表示部8bにて表示される。   Then, the optical information of the reflected light on the surface of the juice 9 absorbed by the detection means 6 is converted into a digital signal by the AD converter 7 and transmitted to the arithmetic storage unit 8a. Then, by performing spectrum analysis in the arithmetic storage unit 8a, the residual pesticide concentration and the like on the surface of the juice 9 of the juice container 22 are measured, and it is determined whether the fruit and vegetable 10 is a compatible individual or a non-compatible individual. The measurement result and the determination result are displayed on the display unit 8b.

このように、赤外分光光度計2を利用して青果物10の残留農薬濃度等を測定する残留農薬測定装置であって、該青果物10の搾汁9を溜める搾汁容器22と、該搾汁容器22が載置される支持台20と、を具備し、照射される赤外線の焦点位置を該搾汁9の水面に調節可能としたので、青果物10から搾汁9を搾り出すだけで残留農薬濃度等を測定することができるようになる。つまり、高価な委託分析の必要が無くなり、ELISA法のように試料の作成に多くの時間を割く必要も無くなる。換言すれば、試料9の作成を短時間で行うことができ、残留農薬濃度等の測定結果が素早く得られるようになるのである。   In this way, a residual pesticide measuring apparatus that measures the residual pesticide concentration and the like of the fruits and vegetables 10 using the infrared spectrophotometer 2, a squeeze container 22 for storing the juice 9 of the fruits and vegetables 10, and the squeezed juice And a support table 20 on which the container 22 is placed, and the focus position of the irradiated infrared rays can be adjusted to the water surface of the juice 9. It becomes possible to measure the concentration and the like. In other words, there is no need for expensive commissioned analysis, and there is no need to spend much time on sample preparation as in the ELISA method. In other words, the sample 9 can be created in a short time, and measurement results such as residual agricultural chemical concentration can be obtained quickly.

換言すれば、赤外分光光度計2を利用して青果物10の残留農薬濃度等を測定する残留農薬測定方法であって、該青果物10から搾汁9を取り出し、該搾汁9を容器22に注入し、該搾汁9表面に焦点位置を合わせて赤外線を照射し、該赤外線の反射光から得たスペクトルを基に青果物10の残留農薬濃度を測定するとしたので、青果物10から搾汁9を搾り出すだけで残留農薬濃度等を測定することができるようになる。つまり、高価な委託分析の必要が無くなり、ELISA法のように試料の作成に多くの時間を割く必要も無くなる。換言すれば、試料9の作成を短時間で行うことができ、残留農薬濃度等の測定結果が素早く得られるようになるのである。   In other words, it is a residual pesticide measurement method for measuring the residual pesticide concentration and the like of the fruits and vegetables 10 using the infrared spectrophotometer 2, which takes out the juice 9 from the fruits and vegetables 10 and puts the juice 9 into the container 22. Injecting, irradiating the surface of the juice 9 with an infrared ray and irradiating infrared rays, and measuring the residual pesticide concentration of the fruits and vegetables 10 based on the spectrum obtained from the reflected light of the infrared rays. Residual pesticide concentration etc. can be measured just by squeezing. In other words, there is no need for expensive commissioned analysis, and there is no need to spend much time on sample preparation as in the ELISA method. In other words, the sample 9 can be created in a short time, and measurement results such as residual agricultural chemical concentration can be obtained quickly.

次に、青果物10の表面に付着した残留農薬濃度等を測定するための構成について説明する。即ち、青果物10の表面に付着している残留農薬のみを測定する場合には、当該測定のために青果物10を搾ったり押しつぶす必要がないため、残留農薬測定装置1は青果物10を破壊することなくその表面の残留農薬濃度等の測定を行える構成を有していることが好ましい。   Next, a configuration for measuring the concentration of residual agricultural chemicals attached to the surface of the fruits and vegetables 10 will be described. That is, when measuring only the residual pesticide adhering to the surface of the fruits and vegetables 10, it is not necessary to squeeze or crush the fruits and vegetables 10 for the measurement, so the residual pesticide measuring apparatus 1 does not destroy the fruits and vegetables 10. It is preferable to have a configuration capable of measuring the concentration of residual agricultural chemicals on the surface.

具体的には、本発明に係る残留農薬測定装置1においては、前記支持台20上に載置された搾汁容器22を青果物10が載置された載置台23に取り替えて、即ち支持台20上に載置台23を載置して残留農薬濃度等の測定を行うのである。図4に示すように、測定すべき青果物10が載置台23上に載置されて残留農薬濃度等の測定が行われるものであり、該載置台23はトレイやパンといった搬送用容器の実施の一形態であって、青果物10の表面を傷めることなく青果物10を載置・搬送することができるものである。   Specifically, in the residual pesticide measuring apparatus 1 according to the present invention, the squeeze container 22 placed on the support table 20 is replaced with a placement table 23 on which the fruits and vegetables 10 are placed, that is, the support table 20. The mounting table 23 is placed on the top to measure the residual agricultural chemical concentration and the like. As shown in FIG. 4, the fruits and vegetables 10 to be measured are placed on a mounting table 23 and the concentration of residual agricultural chemicals is measured, and the mounting table 23 is used for carrying containers such as trays and pans. In one form, the fruits and vegetables 10 can be placed and transported without damaging the surface of the fruits and vegetables 10.

以下、載置台23を用いた青果物10表面の残留農薬濃度等の測定手順について説明する。図4及び図5に示すように、例えば、作業者等によって青果物10がコンテナ等から抜き取られ、該青果物10が載置台23上に載置されて、該載置台23が残留農薬測定装置1の支持台20上にセットされる。そして、前述同様に、投光部4より干渉計5や照射用ミラー13を介して赤外線を照射し、該青果物10で反射した反射光を受光用ミラー17や光路変更手段15を介して検知手段6で吸収する。そして、検知手段6に吸収された赤外線を、AD変換器7にてデジタル出力信号に変換し、青果物10からの反射光の情報を制御手段8に送信する。そして、後述する制御手段8にて、スペクトル分析を行うことにより、残留農薬測定装置1に載置される青果物10に対して残留農薬の種類や濃度の検出、及び適合個体か不適合個体かの判断を実施する。   Hereinafter, measurement procedures such as the residual pesticide concentration on the surface of the fruits and vegetables 10 using the mounting table 23 will be described. As shown in FIGS. 4 and 5, for example, the fruits and vegetables 10 are extracted from the container or the like by an operator, the fruits and vegetables 10 are placed on the placing table 23, and the placing table 23 is used for the residual pesticide measuring apparatus 1. It is set on the support base 20. As described above, infrared light is emitted from the light projecting unit 4 via the interferometer 5 and the irradiation mirror 13, and the reflected light reflected by the fruits and vegetables 10 is detected via the light receiving mirror 17 and the optical path changing means 15. Absorb at 6. The infrared light absorbed by the detection means 6 is converted into a digital output signal by the AD converter 7, and information on the reflected light from the fruits and vegetables 10 is transmitted to the control means 8. Then, by performing spectrum analysis in the control means 8 to be described later, the type and concentration of the residual pesticide is detected with respect to the fruits and vegetables 10 placed on the residual pesticide measuring apparatus 1, and it is determined whether the individual is a suitable or non-matched individual. To implement.

前述同様、本発明に係る残留農薬測定装置1では、赤外線を用いて青果物10の表面に付着した残留農薬の濃度を測定するシステムであるため、測定される青果物10表面を最適な位置(以下、焦点位置とする。)に調節しなければ、正確な青果物10表面のスペクトルを得ることができない。詳しくは、測定される青果物10表面の位置が最適でない場合は、検知手段6で受ける反射光の強度が弱くなるため、スペクトルの波形において波長に応じた強度の違い(スペクトルの凹凸)がはっきりと識別できなくなり、その結果残留農薬濃度等が正確に判断できなくなるのである。   As described above, the pesticide residue measuring apparatus 1 according to the present invention is a system that measures the concentration of residual pesticides attached to the surface of the fruits and vegetables 10 using infrared rays. If the focus position is not adjusted, an accurate spectrum of the fruit and vegetable 10 surface cannot be obtained. Specifically, when the position of the surface of the fruits and vegetables 10 to be measured is not optimal, the intensity of the reflected light received by the detection means 6 becomes weak, so that the difference in intensity according to the wavelength (spectrum unevenness) is clearly observed in the spectrum waveform. As a result, it becomes impossible to accurately determine the residual pesticide concentration and the like.

そこで、作業者等がコンテナ等に載せられている青果物10の中から適宜選び出して次々と青果物10を取り出し、該青果物10が載置された載置台23を残留農薬測定装置1の支持台20上に載置してスペクトル分析を行い、表示部8bに表示されたスペクトルの波形において波長に応じた強度の違い(スペクトルの凹凸)がはっきりと識別できる青果物10に対してのみ残留農薬の種類や濃度を測定し、該残留農薬濃度等に基いて青果物10が適合個体であるか、不適合個体であるか判断を行うのである。ここで、予め、制御手段8には、スペクトルのエネルギーが最大となる赤外線の最適位置(焦点距離)を、青果物10の種類に応じた平均的な表面位置に設定しておくと好ましい。   Therefore, an operator or the like appropriately selects from the fruits and vegetables 10 placed on the container or the like, takes out the fruits and vegetables 10 one after another, and places the placement table 23 on which the fruits and vegetables 10 are placed on the support table 20 of the residual pesticide measuring apparatus 1. Species and concentration of pesticide residue only for fruits and vegetables 10 in which the difference in intensity according to the wavelength (spectrum unevenness) can be clearly identified in the waveform of the spectrum displayed on the display unit 8b. Is determined based on the residual pesticide concentration or the like to determine whether the fruit 10 is a suitable individual or a non-conforming individual. Here, it is preferable that the optimal infrared position (focal length) at which the energy of the spectrum is maximized is set in the control means 8 in advance to an average surface position corresponding to the type of fruit and vegetable 10.

但し、前述したように、照射用ミラー13及び受光用ミラー17はシリンダ等のアクチュエータを用いて高さ調節が可能であり、該照射用ミラー13及び受光用ミラー17の高さに応じてミラー12・18・19の角度がモータ等のアクチュエータを用いて自動で調節可能であるため、前記スペクトルのエネルギー若しくは強度若しくは強度の凹凸が大きい位置で残留農薬濃度等を測定して、該青果物10が適合個体か不適合個体か判断する構成としても良い。   However, as described above, the height of the irradiating mirror 13 and the light receiving mirror 17 can be adjusted using an actuator such as a cylinder, and the mirror 12 depends on the height of the irradiating mirror 13 and the light receiving mirror 17.・ Because the angles of 18 and 19 can be adjusted automatically using an actuator such as a motor, the residual pesticide concentration is measured at a position where the energy or intensity of the spectrum or the unevenness of the intensity is large. It is good also as a structure which judges whether it is an individual or a nonconforming individual.

この場合は、作業者等が表示部8bに表示されるスペクトルを見ながら照射用ミラー13及び受光用ミラーの高さ調節を行うシステムでも良いし、照射用ミラー13及び受光用ミラー17が自動で上下する間に、演算記憶部8aにおいてスペクトルのエネルギー若しくは強度若しくは強度の凹凸が大きい焦点位置を探し(演算し)、該焦点位置において残留農薬の種類及び濃度を測定し、適合個体と不適合個体の判断を行うシステムであっても良い。   In this case, a system in which an operator or the like adjusts the heights of the irradiation mirror 13 and the light receiving mirror while observing the spectrum displayed on the display unit 8b, or the irradiation mirror 13 and the light receiving mirror 17 are automatically set. While moving up and down, the calculation storage unit 8a searches for (calculates) a focal position where the spectrum energy or intensity or intensity unevenness is large, and measures the type and concentration of the pesticide residue at the focal position, It may be a system for making a judgment.

そして、前記残留農薬濃度等の測定の結果、適合個体が多いコンテナ等は、コンテナ等を適合個体である青果物10・10・・・の集合(ロット)とすることができる。逆に、不適合個体が多いコンテナ等は、コンテナ等を不適合個体である青果物10・10・・・の集合(ロット)とすることができる。前記コンテナ1つに対して、複数個の青果物についてこのような測定を施すことが好ましい。   As a result of the measurement of the residual pesticide concentration and the like, a container or the like having a large number of compatible individuals can be a set (lot) of fruits and vegetables 10 · 10. On the other hand, a container or the like having many nonconforming individuals can be a set (lot) of fruits and vegetables 10, 10. It is preferable to perform such a measurement on a plurality of fruits and vegetables with respect to one container.

このように、青果物10を載置する載置台23を具備し、前記赤外線の焦点位置を、前記支持台20上に載置された載置台23上の該青果物10の上表面に調節可能としたので、青果物10表面に付着した残留農薬濃度等を測定する場合に、青果物10を破壊することなく青果物10表面の残留農薬濃度等を測定することができる。これによって、時間をかければ全数検査もできるようになる。   Thus, the mounting table 23 for mounting the fruits and vegetables 10 is provided, and the focal position of the infrared light can be adjusted on the upper surface of the fruits and vegetables 10 on the mounting table 23 mounted on the support table 20. Therefore, when measuring the concentration of residual agricultural chemicals attached to the surface of the fruits and vegetables 10, the concentration of residual agricultural chemicals on the surface of the fruits and vegetables 10 can be measured without destroying the fruits and vegetables 10. As a result, 100% inspection can be performed over time.

本発明の一実施例に係る搾汁容器使用時の残留農薬測定装置を示す正面図。The front view which shows the residual pesticide measuring apparatus at the time of use of the squeeze container which concerns on one Example of this invention. 同じく斜視図。Similarly perspective view. 受光した赤外線のスペクトルを示すグラフ。The graph which shows the spectrum of the received infrared rays. 載置台使用時の残留農薬測定装置を示す正面図。The front view which shows the residual pesticide measuring apparatus at the time of mounting table use. 同じく斜視図。Similarly perspective view.

1 残留農薬測定装置
9 搾汁
10 青果物
20 支持台
21 支持壁
22 搾汁容器
23 載置台
DESCRIPTION OF SYMBOLS 1 Pesticide residue measuring apparatus 9 Juice 10 Fruits and vegetables 20 Support stand 21 Support wall 22 Juice container 23 Mounting stand

Claims (2)

赤外分光光度計を利用して青果物の残留農薬濃度を測定する残留農薬測定装置であって、該残留農薬測定装置(1)は赤外分光光度計(2)と、拡散反射装置(3)とから構成し、該拡散反射装置(3)は、干渉計(5)で合成されて投光される赤外線を導く2枚の照射用光路変更ミラー(11・12)と、該2枚の照射用光路変更ミラー(11・12)によって導かれた赤外線を反射して、支持台(20)上の搾汁容器(22)に貯溜された搾汁(9)の表面へと照射する照射用ミラー(13)と、該搾汁(9)表面で反射した赤外線を2枚の受光用光路変更ミラー(18・19)へと反射する受光用ミラー(17)とから構成し、該拡散反射装置(3)の下部には支持台(20)を水平に設け、該支持台(20)の後端には支持壁(21)を立設し、該支持台(20)上には、該搾汁容器(22)を載置し、該支持壁(21)には、前記の6枚のミラー(11・12・13・17・18・19)を正面視において回動自在に、若しくは上下左右方向へ摺動自在に、前方へ向けて立設し、照射される赤外線の焦点位置を該搾汁(9)の水面の表面に合わせて照射するように、前記照射用ミラー(13)及び受光用ミラー(17)はアクチュエータを用いて高さを調節可能とし、該照射用ミラー(13)及び受光用ミラー(17)の高さ調節に応じて、他の4枚のミラー(11・12・18・19)の角度を、他のアクチュエータを用いて自動的に調節可能に構成したことを特徴とする残留農薬測定装置。   A pesticide residue measuring apparatus for measuring the concentration of pesticide residue in fruits and vegetables using an infrared spectrophotometer, the residue pesticide measuring apparatus (1) comprising an infrared spectrophotometer (2) and a diffuse reflector (3) The diffuse reflection device (3) is composed of two irradiation optical path changing mirrors (11, 12) for guiding the infrared rays synthesized and projected by the interferometer (5), and the two irradiations. Irradiation mirror that reflects the infrared light guided by the optical path changing mirror (11, 12) and irradiates the surface of the juice (9) stored in the juice container (22) on the support base (20) (13) and the light receiving mirror (17) for reflecting the infrared light reflected on the surface of the juice (9) to the two light receiving optical path changing mirrors (18, 19). 3), a support base (20) is provided horizontally at the bottom of the support base (20), and a support wall (21) is provided at the rear end of the support base (20). The juice container (22) is placed on the support base (20), and the six mirrors (11, 12, 13, 17 are placed on the support wall (21). 18 and 19) are erected forward in a front view so as to be rotatable or slidable in the vertical and horizontal directions, and the focal position of the irradiated infrared rays is the surface of the surface of the juice (9) The height of the irradiation mirror (13) and the light receiving mirror (17) can be adjusted by using an actuator so that the height of the irradiation mirror (13) and the light receiving mirror (17) can be adjusted. Residual pesticide measuring apparatus, wherein the angle of the other four mirrors (11, 12, 18, 19) can be automatically adjusted using other actuators according to the adjustment. 請求項1に記載の残留農薬測定装置において、前記支持台(20)上に載置する青果物(10)の載置台(23)を具備し、前記赤外線の焦点位置を、前記支持台(20)上に載置された載置台(23)上の該青果物(10)の上表面に対しても、調節可能としたことを特徴とする残留農薬測定装置。 The apparatus for measuring residual agricultural chemicals according to claim 1, further comprising a mounting table (23) for fruits and vegetables (10) mounted on the support table (20) , wherein the focal point of the infrared rays is determined by the support table (20). Residual pesticide measuring apparatus, characterized in that it can be adjusted with respect to the upper surface of the fruits and vegetables (10) on the mounting table (23) mounted thereon.
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JPH0921748A (en) * 1995-07-05 1997-01-21 Mitsubishi Heavy Ind Ltd Method for determining composition of organic compound
JPH09304271A (en) * 1996-05-10 1997-11-28 Horiba Ltd Infrared microscopic spectrometry apparatus
JPH11108828A (en) * 1997-09-30 1999-04-23 Kubota Corp Device for spectroscopic analysis
JP2004325135A (en) * 2003-04-22 2004-11-18 Hiroaki Ishizawa Residual agricultural chemical analysis method
JP2005177627A (en) * 2003-12-19 2005-07-07 Yanmar Co Ltd Sorting method of vegetables and fruits

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Publication number Priority date Publication date Assignee Title
JPH0921748A (en) * 1995-07-05 1997-01-21 Mitsubishi Heavy Ind Ltd Method for determining composition of organic compound
JPH09304271A (en) * 1996-05-10 1997-11-28 Horiba Ltd Infrared microscopic spectrometry apparatus
JPH11108828A (en) * 1997-09-30 1999-04-23 Kubota Corp Device for spectroscopic analysis
JP2004325135A (en) * 2003-04-22 2004-11-18 Hiroaki Ishizawa Residual agricultural chemical analysis method
JP2005177627A (en) * 2003-12-19 2005-07-07 Yanmar Co Ltd Sorting method of vegetables and fruits

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