JP4558415B2 - Hair dye composition - Google Patents

Description

  The present invention relates to a hair dye composition for dyeing or decoloring hair, and more specifically, it is excellent in dyeing property, leveling property, fastness or decoloring property, and further prevents hair damage and repairs hair. The present invention relates to a hair dye composition which is excellent in effect and excellent in touch such as gloss and touch.

Conventionally, as a hair dye, a two-component type hair dye comprising a first agent containing an oxidative dye and a second agent containing an oxidant, or a semi-permanent hair dye containing a direct dye such as an acid dye Are widely used (see, for example, Non-Patent Document 1). An oxidative hair dye is a dye that produces and dyes a dye by allowing a colorless low-molecular oxidative dye to penetrate into the hair and causing oxidative polymerization in the hair. These oxidative hair dyes can dye hair in various colors according to demand. The semi-permanent hair dye is for dyeing hair by directly adsorbing the dye to the hair, and can obtain a vivid color tone. In addition, in hair cosmetics such as shampoos and styling agents, it is known to use polyglycerin-modified silicone in order to impart a conditioning effect to hair (for example, see Patent Document 1).
Edited by Takeo Mitsui, “New Cosmetics”, Nanzan-do Co., Ltd., January 12, 1993, p. 443-452 Japanese Patent Laid-Open No. 10-316540

  However, when a conventional oxidative hair dye is used, the hair may be damaged, and the gloss and moisture of the hair may be lost. For example, it is caused by oxidative degradation of hair cortex or keratin by an oxidizing agent. In particular, when the hair dyeing process is performed once and then the hair dyeing process is performed again by fading or the like, the hair that has already been subjected to the hair dyeing process (already dyed hair) is further damaged, and the hair is further improved. There was a problem that the luster and moisture disappeared. In response to this problem, hair damage has been prevented by dyeing with a semi-permanent hair dye. However, semi-permanent hair dyes have a higher hair dyeing power and more robustness than oxidative hair dyes. It was not enough. Furthermore, the effect of imparting leveling and gloss to damaged hair is not sufficient.

  The present invention has been made paying attention to the problems existing in the prior art as described above. The purpose of the dyeing is excellent in dyeability, level dyeing, fastness or decolorization, and further prevents hair damage, has excellent hair repair effects, and has excellent gloss and touch feeling. It is to provide an agent composition.

In order to achieve the above object, the hair dye composition of the invention according to claim 1 is a branch selected from (A) polyglyceryl-3.disiloxane dimethicone and polyglyceryl-3.polydimethylsiloxyethyl dimethicone. A polyglycerin-modified silicone, and (B) a hydrolyzate of marine collagen and derivatives thereof.

  The hair dye composition of the invention described in claim 2 is characterized in that in the invention described in claim 1, it further contains (C) a sucrose fatty acid ester.

  The hair dye composition of the invention described in claim 3 is characterized in that, in the invention described in claim 1 or 2, it further comprises (D) deep ocean water.

According to the present invention, the following effects can be exhibited.
In the hair dye composition of the invention according to claim 1, by blending the component (A) and the component (B), the hair dye composition is excellent in dyeability, leveling property, fastness or decoloring property, and further, hair damage. Is effective in repairing hair, and in excellent touch feeling such as gloss and touch.

  In the hair dye composition of the invention described in claim 2, by further adding the component (C), in addition to the effects of the invention described in claim 1 or 2, the hair gloss and feel are improved. be able to.

  In the hair dye composition of the invention according to claim 3, by further blending the component (D), in addition to the effects of the invention according to claim 1 or 2, leveling, fastness or uniformity. And the feel of hair can be improved.

Hereinafter, embodiments of the hair dye composition of the present invention will be described in detail.
The branched polyglycerin-modified silicone of component (A) is a branched silicone compound having a polyglycerin chain as a hydrophilic group as shown in the general formula (1).

  Specific examples of the branched polyglycerin-modified silicone represented by the general formula (1) include polyglyceryl-3 disiloxane dimethicone, polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Polyglyceryl). -3 Polydimethylsiloxyethyl Dimethicone) and compounds described in the CTFA Dictionary (International Cosmetic Ingredient Dictionary and Handbook).

  The amount of component (A) is preferably 0.005 to 10% by mass, more preferably 0.01 to 5% by mass, and still more preferably 0.05 to 2% by mass. If the content is less than 0.005% by mass, sufficient leveling and fastness properties cannot be obtained, and gloss and feel effects may not be sufficiently obtained. On the other hand, if it exceeds 10% by mass, the hair may become sticky.

  Component (B) is a hydrolyzate of marine collagen and derivatives thereof. Marine collagen is collagen originating from fish, shellfish or sponges.

  As fish, skipjack, tuna, marlin, cod, horse mackerel, mackerel, salmon, trout, saury, eel, tilapia, riverfish, grouper, halibut, flounder, flounder, herring, sardine, shark, ray, pufferfish, yellowtail, scorpion, Among them, skipjack, tuna, cod, tilapia, halibut and salmon are preferable. These fish skin, fish bone and fish scale collagen are used as raw materials.

  Examples of the shellfish include pearl oysters, mussel, mussels, mussel, oyster scallops, scallops, and oysters. Among these, pearl oysters are preferred. These shells, shellfish and mucus are used as raw materials.

  Examples of the sponges include lime sponge rope, six-band sponge rope, common sponge rope, and teleost sponge rope. Among them, common sponge rope (square siliceous sponge, fresh water sponge, mineral sponge, subspecies Levant sponge) , Dimokka sponge, elephant ear sponge, horse sponge).

  Of these marine collagens, fish are preferred. The hydrolyzate of marine collagen can be obtained by hydrolysis with acid, alkali or enzyme. In addition, as derivatives thereof, acylated products, silylated derivatives, quaternary ammonium derivatives, esters, and the like can be given. The molecular weight of these marine collagen hydrolysates and derivatives thereof is preferably 200 to 5,000. If the molecular weight is less than 200, the adsorptivity to hair is low, and if it exceeds 5000, the water solubility decreases and the adsorptivity decreases. As the compounding quantity, it is 0.01-10 mass% with respect to the composition whole quantity. When the amount is less than 0.01% by mass, the amount of hair adsorbed is small, a sufficient hair dyeing effect cannot be obtained, and a hair repair effect can hardly be expected. On the other hand, when the amount is more than 10% by mass, the amount of adsorption does not increase, and further improvement of the effect cannot be expected. In addition, about the minimum of a compounding quantity, 0.05 mass% is preferable, and sufficient hair dyeing effect and the repair effect of hair are acquired by mix | blending 0.05 mass% or more. The upper limit is preferably 5% by mass, and if it exceeds 5% by mass, the increase in the hair dyeing effect and the hair repair effect is reduced.

［式中、Ｒ^１、Ｒ^２、Ｒ^３は、それぞれ飽和もしくは不飽和の炭素数８〜２２、好ましくは１０〜１８のアシル基もしくは水素原子を表し、Ｒ^４〜Ｒ^８はそれぞれアセチル基もしくは水素原子を表す。ショ糖脂肪酸エステルは一般にＲ^１〜Ｒ^３に関してはモノ、ジ、トリエステルの混合物が用いられる。Ｒ^４〜Ｒ^８に関してはアセチル化度は任意である。］ The sucrose fatty acid ester of component (C) is represented by the following general formula (2).

[Wherein R ¹ , R ² and R ³ each represent a saturated or unsaturated acyl group having 8 to 22 carbon atoms, preferably 10 to 18 carbon atoms, or a hydrogen atom, and R ^{4 to} R ⁸ each represents an acetyl group or Represents a hydrogen atom. As the sucrose fatty acid ester, a mixture of mono-, di- and triesters is generally used for R ^{1 to} R ³ . Regarding R ^{4 to} R ⁸ , the degree of acetylation is arbitrary. ]

  Specific examples of sucrose fatty acid esters include series such as DK esters S-160 and S-L18A sold by Daiichi Kogyo Seiyaku Co., Ltd., Sugar Wax S-10E and A-10E, Mitsubishi Chemical Foods Co., Ltd. ) Series such as Ryoto Sugar Esters POS-135, S-1170, P-1570, LWA-1570, etc., and Sunfact SE-11, etc. released from Taiyo Kagaku Co., Ltd. These sucrose fatty acid esters can be used alone or in combination of two or more.

  0.01-5 mass% is preferable with respect to the composition whole quantity, and, as for the compounding quantity of a component (C), 0.05-2 mass% is more preferable. If it is less than 0.01% by mass, the effect of gloss and feel may not be sufficiently obtained. On the other hand, if it exceeds 5% by mass, the hair may become sticky.

  The deep sea water of component (D) is formed by forming a layer by submerging the surface seawater, and is low temperature, clean and natural water rich in nutrient salts. The water intake depth is 200 m or more, preferably 300 ~ 400m. Typical water intake areas are off Muroto City, Kochi Prefecture, Yaizu City, Shizuoka Prefecture, Namerikawa City, Toyama Prefecture, and Itoman City, Okinawa Prefecture.

  The component (D) of the present invention is seawater that has been taken from a depth of 200 m or more and has not been subjected to any treatment other than the physical filtration step. Depending on the situation of use, water having the required salt concentration can also be obtained by using it together with the seawater that has been desalted with an ion exchange resin or a reverse osmosis membrane. Similarly, combined use with general purified water using tap water or groundwater is also possible.

Although content of the component (D) in this invention is not specifically limited, Preferably, it is 0.1-0.1.
It is 98 mass%, More preferably, it is 1-90 mass%.

  The hair dye composition of the present invention can be applied to any hair dye composition such as a hair bleaching agent, an oxidative hair dye, and a semi-permanent hair dye.

  The hair bleaching agent comprises a first agent containing an alkaline agent and a second agent containing an oxidizing agent. The oxidative hair dye is composed of a first agent containing an alkali agent and an oxidative dye, and a second agent containing an oxidant.

  Examples of the alkaline agent contained in the first agent of the hair bleaching agent and the oxidative hair dye include ammonia, alkanolamines, ammonium salts, and organic amines (2-amino-2-methyl-1,3-propanediol, guanidine). Etc.), inorganic alkalis (sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate etc.), basic amino acids (arginine, lysine etc.) and salts thereof. Specific examples of the alkanolamine include monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, isopropanolamine, dipropanolamine, tripropanolamine, 2-amino-2-methyl-1,3-propanediol, 2- Examples include amino-2-methyl-1-propanol and 2-amino-2-hydroxymethyl-1,3-propanediol. Specific examples of the ammonium salt include ammonium halide, inorganic ammonium salt, organic ammonium salt and the like. Ammonium halides such as ammonium chloride, inorganic ammonium salts such as ammonium carbonate, ammonium hydrogen carbonate, ammonium sulfate, ammonium phosphate, and ammonium hydrogen phosphate, and organic ammonium salts such as ammonium lactate, ammonium citrate, and ammonium glycolate Etc.

  These alkaline agents may be blended singly or in combination of two or more. Among these alkali agents, it is preferable to contain at least ammonia because the lightness of the hair is good and the dyeing property or decoloring property can be sufficiently exhibited.

  The content of the alkaline agent in the first agent is preferably 0.1 to 10% by mass, more preferably 0.2 to 9.6% by mass, still more preferably 0.6 to 9% by mass, and most preferably 0. .7-8% by mass. If the content is less than 0.1% by mass, sufficient brightness may not be obtained. On the other hand, if it exceeds 10% by mass, it may be difficult to obtain a good feel in the finished hair.

  The oxidative dye contained in the first agent of the oxidative hair dye indicates a compound that can develop color by oxidative polymerization with an oxidant. This oxidation dye is classified into a main intermediate and a coupler, and the first agent contains at least a main intermediate. Major intermediates include phenylenediamines (excluding metaphenylenediamine), aminophenols (excluding metaaminophenol, 2,4-diaminophenol, and paramethylaminophenol), toluylenediamines. (Excluding toluene-3,4-diamine and toluene-2,4-diamine), diphenylamines, diaminophenylamines, N-phenylphenylenediamines, diaminopyridines (however, 2,6-diaminopyridine) And the salts thereof. Examples of the salt include hydrochloride, sulfate, acetate and the like.

  As couplers, resorcin, pyrogallol, catechol, metaaminophenol, metaphenylenediamine, 2,4-diaminophenol, 1,2,4-benzenetriol, toluene-3,4-diamine, toluene-2,4-diamine, Hydroquinone, α-naphthol, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, paramethylaminophenol, 2,4-diaminophenoxyethanol, gallic acid, tannic acid, ethyl gallate, gallic acid Examples include methyl, propyl gallate, pentaploid, 5- (2-hydroxyethylamino) -2-methylphenol, and salts thereof.

  These oxidation dyes may be blended singly or in combination. Among the main intermediates, because of its strong hair dyeing power, paraphenylenediamine, paratoluylenediamine, N, N-bis (2-hydroxyethyl) -paraphenylenediamine, N-phenyl-paraphenylenediamine, 4,4 ′ -At least one selected from diaminodiphenylamine, 2-chloroparaphenylenediamine, N, N-dimethylparaphenylenediamine, paraaminophenol, orthoaminophenol, 2,6-dichloroparaphenylenediamine, paraaminophenylsulfamic acid and salts thereof. preferable.

  The content of the oxidation dye in the first agent of the oxidation hair dye is preferably 0.01 to 15.0% by mass. If this content is less than 0.01% by mass, it is difficult to obtain sufficient hair coloring power. On the other hand, even if it exceeds 15.0 mass%, it is difficult to obtain a higher hair dyeing power.

  Further, the first agent of the oxidative hair dye may be blended with a direct dye as a dye other than the oxidative dye intermediate and the coupler. When a direct dye is blended, the hair dyeing effect can be further enhanced. Examples of the direct dye include 4-nitro-m-phenylenediamine, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine, picramic acid, 1-amino-4-methylanthraquinone, 1,4 -Diaminoanthraquinone, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol and their salts, and "Ministerial ordinance for determining tar dyes that can be used in pharmaceuticals" (1960 notification, Ministry of Health and Welfare ) And acid-soluble dyes and oil-soluble dyes. The acid dyes include Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Red No. 201, Red No. 227, and Red 230. No. (1), Red No. 230 (2), Red No. 231, Red No. 232, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506, Yellow No. 4, Yellow No. 5, Yellow 202 (1), Yellow 202 (2), Yellow 203, Yellow 402, Yellow 403 (1), Yellow 406, Yellow 407, Daigo 205, Daido 207, Orange No. 402, Green No. 3, Green No. 204, Green No. 205, Green No. 401, Green No. 402, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 202, Blue No. 203, Blue No. 205, Bra There are color 201, black 401, etc. Oil-soluble dyes include red 215, red 218, red 225, orange 201, orange 206, yellow 201, yellow 204, green 202, purple 201, red 501 and red 505, orange 403, yellow 404, yellow 405, blue 403 and the like. Furthermore, Basic Blue 3, Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41, Basic Blue 47, Basic Blue 99, Basic Brown 4, Basic Brown 16, Basic Brown17, Basic Green 1, Basic Green 4, Basic Orange 1, Basic Orange 2, Basic Orange 31, Basic Red 1, Basic Red 2, Basic Red 22, Basic Red 46, Basic Red 51, Basic Red 76, Basic Red 118, Basic Violet 1, Basic Violet 3, Basic Violet 4, Basic Violet 10, Basic Violet 11: 1, Basic Violet 14, Basic Violet 16, Basic Yellow 11, Basic Yellow 28, Basic Yellow 57, Basic Yellow 87, HC Blue No.2, HC Blue No. 4, HC Blue No.5, HC Blue No.6, HC Blue No.7, HC Blue No.8, HC Blue No.9, HC Blue No.10, HC Blue No.11, HC Blue No.12, HC Blue No.13, HC Blue No.14, HC Brown No.1, HC Brown No.2, HC Green No.1, HC Orange No.1, HC Orange No.2, HC Orange No.3, HC Orange No.5, HC Red No.1, HC Red No.3, HC Red No.7, HC Red No.8, HC Red No.9, HC Red No.10, HC Red No.11, HC Red No. 13, HC Red No. 14, HC Violet No. 1, HC Violet No. 2, HC Yellow No. 2, HC Yellow No. 4, HC Yellow No.5, HC Yellow No.6, HC Yellow No.7, HC Yellow No.8, HC Yellow No.9, HC Yellow No.10, HC Yellow No.11, HC Yellow No.12, HC Yellow No.13, HC Yellow No.14, HC Yellow No.15, Disperse Black 9, Disperse Blue 1, Disperse Blue 3, Disperse Brown 4, Disperse Orange 3, Disperse Red 11, Disperse Red 15, Disperse Red 17, Disperse Violet 1, Disperse Violet 4, Disperse Violet 15 etc. are mentioned. These direct dyes may be blended singly or in combination of two or more.

  Examples of the oxidizing agent contained in the second agent of the hair bleaching agent and oxidative hair dye include hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, and potassium perborate. , Ammonium persulfate, sodium peroxide, potassium peroxide, magnesium peroxide, barium peroxide, calcium peroxide, strontium peroxide, hydrogen peroxide adduct of persulfate, hydrogen peroxide adduct of phosphate, pyrophosphoric acid Examples include hydrogen peroxide adducts of salts and sodium bromate. Among them, hydrogen peroxide is preferable. These oxidizing agents may be blended singly or in combination of two or more.

  The hair bleaching agent and the oxidative hair dye are used by mixing the first agent and the second agent at the time of use. At this time, the first agent and the second agent are preferably mixed at a mass ratio of 1: 3 to 2: 1, more preferably 1: 2 to 1: 1.

  The first agent and the second agent of the hair bleaching agent and the oxidative hair dye can further contain at least one selected from a surfactant, an oily component, a polymer compound, a solvent, and the like.

  Specific examples of the surfactant include an anionic surfactant, a cationic surfactant, a nonionic surfactant, and an amphoteric surfactant.

  Specific examples of the anionic surfactant include sodium lauryl sulfate, polyoxyethylene (hereinafter referred to as POE) sodium lauryl ether sulfate, sodium stearoylmethyl taurate, triethanolamine dodecylbenzenesulfonate, sodium tetradecenesulfonate, and POE lauryl. Ether phosphoric acid and its salt etc. are mentioned.

  Specific examples of the cationic surfactant include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, ethyl Examples include lanolin sulfate fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin and the like.

  Specific examples of nonionic surfactants include POE alkyl ethers, POE alkenyl ethers, POE alkyl phenyl ethers, POE polyoxypropylene (hereinafter referred to as POP) alkyl ethers, POE fatty acids, POE sorbitan fatty acids. Esters, POE castor oil, POE hydrogenated castor oil, POE sorbitol tetra fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, alkyl polyglycoside, N-alkyldimethylamine oxide, POE propylene glycol fatty acid ester, etc. It is done. Among these, POE alkyl ethers, POE alkenyl ethers, POE alkyl phenyl ethers, POE / POP alkyl ethers and the like are preferable because they are strong against acids and alkali agents, and POE alkyl ethers and POE alkenyl ethers are more preferable. Specific examples of POE alkyl ethers include POE lauryl ether, POE cetyl ether, POE isocetyl ether, POE stearyl ether, POE isostearyl ether, POE behenyl ether, etc. Specific examples of POE alkenyl ethers include POE oleyl ether etc. are mentioned.

  Specific examples of amphoteric surfactants include 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, Examples include 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, cocoamidopropyl betaine, lauryldimethylaminoacetic acid betaine, and lauramidopropyl betaine.

  These surfactants may be blended singly or in combination of two or more.

  Specific examples of the oil component include hydrocarbons, fats and oils, waxes, higher fatty acids, alkyl glyceryl ethers, esters, silicone derivatives, and the like.

  Examples of hydrocarbons include α-olefin oligomer, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, polybutene, liquid isoparaffin, liquid paraffin, ozokerite, ceresin, paraffin, polyethylene powder, microcrystalline wax, petrolatum, etc. Can be mentioned.

  Oils include olive oil, camellia oil, tea seed oil, sasanqua oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, beef fat, cocoa butter, corn oil, peanut oil, rapeseed oil, rice bran oil, rice germ oil Wheat germ oil, barley oil, grape seed oil, almond oil, avocado oil, carrot oil, macadamia nut oil, castor oil, flaxseed oil, coconut oil, mink oil, egg yolk oil and the like.

  Examples of waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.

  Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid, undecylenic acid, linoleic acid, ricinoleic acid, and lanolin fatty acid.

  Examples of the alkyl glyceryl ether include batyl alcohol (monostearyl glyceryl ether), chimyl alcohol (monocetyl glyceryl ether), selachyl alcohol (monooleyl glyceryl ether), and isostearyl glyceryl ether.

  Esters include diisopropyl adipate, diisobutyl adipate, dioctyl adipate, di-2-hexyldecyl adipate, diisostearyl adipate, isopropyl myristate, cetyl octanoate, cetyl isooctanoate, isononyl isononanoate, isononanoic acid Isodecyl, isotridecyl isononanoate, diisopropyl sebacate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, stearyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, triisodecyl myristate, myristic Isostearyl acid, 2-ethylhexyl palmitate, lauryl lactate, cetyl lactate, myristyl lactate, octyl dodecyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, cetyl caprate, glyceryl tricaprylate, Examples thereof include neopentyl glycol dicaprate, diisostearyl malate, and lanolin derivatives.

  Examples of silicone derivatives include dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, polyether-modified silicone, highly polymerized silicone having an average degree of polymerization of 650 to 10,000, amino-modified silicone, and betaine-modified silicone. , Alkyl-modified silicone, alkoxy-modified silicone, mercapto-modified silicone, carboxy-modified silicone, fluorine-modified silicone, polyglycerin-modified silicone other than component (A), and the like.

  These oil components may be blended singly or in combination of two or more.

  Examples of the polymer compound include a cationic polymer compound, an amphoteric polymer compound, an anionic polymer compound, and a nonionic polymer compound.

  The cationic polymer compound includes an amino group or an ammonium group bonded to a polymer chain, or an aqueous solution containing at least dimethyldiallylammonium halide as a constituent unit, such as a cationized cellulose derivative, a cationic starch, Examples thereof include cationized guar gum derivatives, dimethyldiallyl quaternary ammonium salt polymers, dimethyldiallyl quaternary ammonium salt / acrylamide copolymers, and quaternized polyvinylpyrrolidone derivatives. Examples of the cationized cellulose derivative include O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, and commercially available products include Leogard G and GP from Lion Corporation, and polymer JR from Union Carbide. -125, JR-400, JR-30M, LR-400, LR-30M and the like. Examples of other cationized cellulose derivatives include hydroxyethyl cellulose dimethyl diallylammonium chloride, and examples of commercially available products include Cellcoat H-100 and L-200 manufactured by National Starch and Chemical Co., Ltd. Examples of the cationized guar gum derivative are described in, for example, JP-B-58-35640, JP-B-60-46158, and JP-A-58-53996, Jaguar C-13S and -14S of RHONE-POULENC. It is commercially available as -17, -210, -162, and HI-CARE1000. Examples of commercially available dimethyldiallyl quaternary ammonium salt polymers include Marcote 100 manufactured by Ondeo Nalco. Commercially available products of dimethyldiallyl quaternary ammonium salt / acrylamide copolymer include Marcote 550 manufactured by Ondeo Nalco. As the quaternized polyvinyl pyrrolidone derivative, those having a molecular weight of 10,000 to 2,000,000 are preferable, and commercially available products include Guff Coat 734, 755, and 755N manufactured by ISP Japan. Other useful ingredients include Ciba Specialty Chemicals' Salcare SC95,96.

  Examples of amphoteric polymer compounds include N-methacryloylethyl N, N-dimethylammonium α-N-methylcarboxybetaine / butyl methacrylate copolymer (commercial name; Yucaformer AM-75; manufactured by Mitsubishi Chemical Corporation), acrylic acid Hydroxypropyl / butylaminoethyl methacrylate / octylamide copolymer (commercial name; Amphomer 28-4910; manufactured by National Starch), dimethyldiallylammonium chloride / acrylic acid copolymer (commercial name; MERCOAT 280,295) Ondeo Narco), dimethyldiallylammonium chloride / acrylamide / acrylic acid terpolymer (commercial name; Marquat Plus 3330, 3331; Ondeo Narco), acrylic acid / methyl acrylate / methacrylamide chloride Le trimethylammonium copolymer (trade name; Merquat 2001; manufactured by Ondeo Nalco Co.) and the like.

  Examples of the anionic polymer compound include acrylic acid / acrylic acid amide / ethyl acrylate copolymer, acrylic acid / acrylic acid amide / ethyl acrylate copolymer potassium salt solution, acrylic acid alkyl ester / methacrylic acid alkyl ester Acetone acrylamide / methacrylic acid copolymer liquid, acrylic acid / alkyl methacrylate copolymer, acrylic resin alkanolamine liquid, carboxyvinyl polymer, hydroxypropyl acrylate, butylaminoethyl methacrylate, octylamide acrylate copolymer, acetic acid Vinyl / crotonic acid copolymer, vinyl acetate / crotonic acid / vinyl neodecanoate copolymer, vinyl acetate / crotonic acid / vinyl propionate copolymer, methyl vinyl ether / maleic acid monobutyl ester copolymer, etc. It is.

  Nonionic polymer compounds include natural, semi-synthetic and synthetic compounds. Examples of natural nonionic polymer compounds include cellulose, guar gum, agar, starch, hydrolyzed starch, and dextrin. Examples of the semisynthetic nonionic polymer compound include methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethyldextran, and carboxymethylchitin. Further, synthetic nonionic polymer compounds include polyethyl acrylate, polyacrylic amide, polyethylene glycol, polypropylene glycol, polyoxyethylene (hereinafter referred to as POE) polyoxypropylene (hereinafter referred to as POP) copolymer. , POE / POP butyl ether, POE / POP hexylene glycol ether, POP butyl ether, polyvinylpyrrolidone and the like.

  Other useful ingredients include gum arabic, carrageenan, galactan, quince seed gum, locust bean gum, tragacanth gum, pectin, mannan, xanthan gum, dextran, curdlan, gellan gum, succinoglucan, gelatin, tamarind gum, casein, etc. Examples include natural polymer compounds.

  These polymer compounds may be blended singly or in combination of two or more.

  Examples of the solvent include water, ethanol, isopropanol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, isoprene glycol, hexylene glycol, ethyl carbitol, glycerin, diglycerin, polyethylene glycol, and polypropylene glycol. These solvents may be blended singly or in combination of two or more.

  Furthermore, as other additive components, a hydrolyzate obtained by hydrolyzing proteins such as collagen, keratin, elastin, fibroin, conchiolin, soy protein, casein, gelatin and the like other than the component (a) with acid, alkali, enzyme, and the like, and Polypeptides such as cation-denatured proteins quaternized from these; moisturizers such as sodium pyrrolidone carboxylate, sodium lactate, sorbitol, hyaluronic acid; benzyl alcohol, phenethyl alcohol, benzyloxyethanol, N-methylpyrrolidone, N-ethylpyrrolidone Dyeing aids such as ethylene carbonate and propylene carbonate; preservatives such as paraben; chelating agents such as EDTA-Na; phenacetin, EDTA, 8-oxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid urine Stabilizers such as tannic acid and phenoxyethanol; pH adjusters such as phosphoric acid, citric acid, sulfuric acid, acetic acid, lactic acid and tartaric acid; antioxidants such as thioglycolic acid and sulfite; liquefied petroleum gas, dimethyl ether, nitrogen, Propellants such as carbon dioxide; other amino acids, plant extracts, herbal extracts, vitamins, dyes, fragrances, pigments, UV absorbers, etc., and “Quasi-drug raw material standards” (issued June 1991, Pharmaceutical Affairs) You may mix | blend at least 1 type chosen from what is listed in the daily report company). The blending amount of the other additive components is determined according to the conventional methods for hair bleaching agents and oxidative hair dyes.

  The dosage form of the hair bleaching agent and the oxidative hair dye can be liquid, emulsion, cream, foam, gel, paste or the like.

  Next, when the hair dye composition of the present invention is applied as a semi-permanent hair dye, the direct dye is contained.

  Moreover, in order to improve dyeing property, it is preferable to contain a dyeing assistant. Examples of the dyeing assistant include benzyl alcohol, phenethyl alcohol, γ-phenylpropyl alcohol, cinnamyl alcohol, anise alcohol, p-methylbenzyl alcohol, α-dimethylphenethyl alcohol, α-phenylethanol, phenoxyethanol, phenoxyisopropanol, 2- Examples include aromatic alcohols such as benzyloxyethanol, alkylpyrrolidones such as N-methylpyrrolidone and N-ethylpyrrolidone, and lower alkylene carbonates such as ethylene carbonate and propylene carbonate. These dyeing assistants may be blended alone or in combination of two or more.

  The pH of the semipermanent hair dye is appropriately adjusted depending on the type of dye used. When an acid dye is used as the direct dye, it is preferably adjusted to pH 1.5 to 5.

  An acid can be used to adjust the pH. Specific examples include acetic acid, lactic acid, tartaric acid, malic acid, citric acid, glycolic acid, pyrrolidone carboxylic acid, levulinic acid, fumaric acid, succinic acid, butyric acid, valeric acid, oxalic acid, maleic acid, mandelic acid, aspartic acid, Examples thereof include organic acids such as adipic acid and nicotinic acid, and inorganic acids such as phosphoric acid, hydrochloric acid, sulfuric acid and nitric acid. Moreover, buffering ability can also be given to these acids by combining alkanolamine salts such as sodium salts, potassium salts, ammonium salts and triethanolamine salts of the acids.

  Moreover, when using another direct dye, it adjusts to pH 5-10, for example, the dyeing power of the dye is most effectively exhibited. The pH is adjusted with the acid as described above or the alkali agent as described above.

  Furthermore, the semi-permanent hair dye can be blended with other components selected from the surfactants, oily components, polymer compounds, solvents, and other components mentioned above as other components. .

  The dosage form of the semi-permanent hair dye can be liquid, emulsion, cream, foam, gel, paste or the like.

Next, the embodiment will be described more specifically with reference to examples and comparative examples.
(Examples 1-4 and Comparative Examples 1-3)
In Examples 1 to 2 and Comparative Examples 1 to 3 as two-component hair bleaching agents, first and second agents were prepared as shown in Table 1. In addition, the numerical value in Table 1 shows the mass%.

  About the hair bleaching agent of each row | line | column of Table 1, after mixing 1st agent and 2nd agent by mass ratio 1: 1, it apply | coated to the hair | bristle bundle. The hair bundle was left in a constant temperature layer at 37 ° C. for 30 minutes, washed thoroughly with a shampoo, wiped with a towel, and then dried with a dryer. Ten panelists evaluated decolorization, uniformity, hair gloss and hair feel as shown below. The evaluation results are shown in Table 1.

<Decolorization>
The evaluation was made in four stages: excellent brightness (4 points), good brightness (3 points), slightly insufficient brightness (2 points), and insufficient brightness (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.
<Uniformity>
Evaluation was made in four stages: uniform and well decolored (4 points), nearly uniformly decolored (3 points), slightly uneven (2 points), and uneven (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.
<Hair of hair>
The evaluation was made in four grades: very shiny (4 points), slightly shiny (3 points), not shiny (2 points), and not shiny (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.
<Hair feel>
The evaluation was based on four levels: very good (4 points), good (3 points), slightly bad (2 points), and bad (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.

  As is clear from the results in Table 1, in Examples 1 to 4, sufficient results were obtained with respect to decolorization, uniformity, hair gloss, and hair feel. Since Example 2 does not contain the component (D), Example 1 is superior to Example 2 in terms of uniformity and hair feel. Since Example 3 does not contain the component (C), Example 1 is superior to Example 3 in terms of decolorization and hair gloss. Since Example 4 does not contain component (C) and component (D), Example 1 is superior to Example 4 in terms of decolorization, uniformity, hair gloss, and hair feel. .

  On the other hand, since Comparative Example 1 does not contain the component (A), sufficient results are not obtained with respect to decolorization and hair feel. Since Comparative Example 2 does not contain the component (B), sufficient results are not obtained with respect to uniformity, hair gloss and hair feel. Since Comparative Example 3 does not contain the component (A) and the component (B), sufficient results have not been obtained with respect to decolorization, uniformity, hair gloss and hair feel.

(Examples 5-8 and Comparative Examples 4-6)
In Examples 5 to 8 and Comparative Examples 4 to 6 as two-component oxidative hair dyes, the first agent and the second agent were prepared as shown in Table 2. In addition, the numerical value of Table 2 shows the mass%.

  About the oxidation hair dye of each row | line | column of a table | surface, after mixing 1st agent and 2nd agent by mass ratio 1: 1, it apply | coated to the hair | bristle bundle. The hair bundle was left in a constant temperature layer at 37 ° C. for 30 minutes, washed thoroughly with a shampoo, wiped with a towel, and then dried with a dryer. Ten panelists evaluated hair gloss and hair feel in the same manner as described above. Further, the dyeability, levelness and fastness were evaluated as shown below. The evaluation results are shown in Table 2.

<Dyeability>
Evaluation was made in four stages: excellent dyeability (4 points), good dyeability (3 points), slightly poor dyeability (2 points), and poor dyeability (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.
<Uniformity>
Evaluation was made in four stages: uniformly dyed well (4 points), almost uniformly dyed (3 points), slightly uneven (2 points), and uneven (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.
<Robustness>
The dyed hair bundle was immersed in a 1% by mass sodium lauryl sulfate aqueous solution at 50 ° C. for 15 minutes after one day, and the hair bundle was then thoroughly washed with water and allowed to air dry. The degree of fading of the hair bundle at this time was compared with the hair bundle before the treatment.
The evaluation was made in four stages: almost no fading (4 points), little fading (3 points), slightly fading (2 points), and large fading (1 point). An average score is calculated for each paneler's scoring results, and an average value of 3.6 or higher is “excellent: ◎”, 2.6 to 3.5 is “good: ○”, 1.6 or higher 2 .5 points or less were evaluated as “slightly bad: Δ” and 1.5 points or less were evaluated as “bad: ×”.

  As is clear from the results of Table 2, in Examples 5 to 8, sufficient results were obtained with respect to dyeability, levelness, fastness, hair gloss and hair feel. Since Example 6 does not contain the component (D), Example 5 is superior to Example 6 in terms of leveling, fastness, and hair feel. Since Example 7 does not contain the component (C), Example 5 is superior to Example 7 in terms of dyeability and hair gloss. Since Example 8 does not contain component (C) and component (D), Example 1 is superior to Example 8 in terms of dyeability, levelness, fastness, hair gloss and hair feel. It is the result.

  On the other hand, since Comparative Example 4 does not contain the component (A), sufficient results have not been obtained for dyeability and hair feel. Since Comparative Example 5 does not contain the component (B), sufficient results have not been obtained with respect to levelness, fastness, hair gloss and hair feel. Since Comparative Example 6 does not contain the component (A) and the component (B), sufficient results have not been obtained with respect to dyeability, levelness, fastness, hair gloss and hair feel.

(Examples 9-12 and Comparative Examples 7-9)
Examples 9-12 and Comparative Examples 7-9 as semi-permanent hair dyes were prepared as shown in Table 3. After applying the semi-permanent hair dye of each example in Table 3 to the hair bundle, this hair bundle was allowed to stand in a constant temperature layer at 37 ° C. for 30 minutes, washed thoroughly with a shampoo, wiped with a towel, and then dried with a dryer. . Ten panelists evaluated the dyeability, levelness, fastness, gloss and feel of hair as described above. The evaluation results are shown in Table 3. In addition, the numerical value of Table 3 shows the mass%.

  As is clear from the results in Table 3, in Examples 9 to 12, sufficient results were obtained with respect to dyeability, levelness, fastness, hair gloss and hair feel. Since Example 10 does not contain the component (D), Example 9 is superior to Example 10 in terms of leveling property, fastness, and hair feel. Since Example 11 does not contain the component (C), Example 9 is superior to Example 11 in terms of dyeability and hair gloss. Since Example 12 does not contain component (C) and component (D), Example 9 is superior to Example 12 in terms of dyeability, levelness, fastness, hair gloss and hair feel. It is the result.

  On the other hand, since Comparative Example 7 does not contain the component (A), sufficient results are not obtained with respect to dyeability and hair feel. Since Comparative Example 8 does not contain the component (B), sufficient results have not been obtained with respect to levelness, fastness, hair gloss and hair feel. Since Comparative Example 9 does not contain the component (A) and the component (B), sufficient results have not been obtained with respect to dyeability, levelness, fastness, hair gloss and hair feel.

In addition, the said embodiment can also be changed and comprised as follows.
In addition to the first agent and the second agent of the hair bleaching agent of the above embodiment, a powdery or creamy third agent further containing an alkaline agent, a persulfate, an oil component, a surfactant, etc. You may apply to a hair-type bleaching agent of a formulation.
-Even if the two-component hair bleaching agent and the three-component hair bleaching agent in the above embodiment are used as a hair decoloring agent for returning hair dyed with a hair dye or the like to its original color Good.

Claims (3)

(A) Branched polyglycerin-modified silicone selected from polyglyceryl-3 · disiloxane · dimethicone and polyglyceryl-3 · polydimethylsiloxyethyl · dimethicone , and (B) hydrolyzate of marine collagen and derivatives thereof. A hair dye composition comprising at least one kind. Furthermore, (C) sucrose fatty acid ester is contained, The hair dye composition of Claim 1 characterized by the above-mentioned. Furthermore, (D) deep sea water is contained, The hair dye composition of Claim 1 or Claim 2 characterized by the above-mentioned.