JP4524740B2 - Luminous bracelet - Google Patents

Description

The present invention is, in capacity plastic container having a flexible, and fluorescent solution, houses an ampoule fracture split of encapsulating oxide solution, by Yabuwari the ampoule from the outside of the plastic container, The present invention relates to a light-emitting bracelet using a chemiluminescent material that emits light using a chemical reaction generated by mixing two types of solutions of a fluorescent solution and an oxidizing solution.

  Conventionally, a breakable glass ampule filled with an oxidizing solution and a fluorescent solution are sealed in a flexible synthetic resin container, and the glass ampule is broken by an external force, whereby two types of fluorescent solution and oxidizing solution are used. A chemiluminescent material that emits light by mixing and reacting with a solution is known, and is widely used as a party goods at night or in a dark place such as candles, muddlers, penlights, and sticks (see Patent Document 1). .

  Moreover, although the luminous bracelet is shown as a decoration using a chemiluminescent body (refer patent document 2 and patent document 3), as shown in FIG. 11, they are the thin rod shape generally used conventionally conventionally. The band 41 in which the chemiluminescent tubes are juxtaposed in the width direction is bent into a ring shape, and a connecting tool 42 is attached to both ends thereof to fix the ring shape (see Patent Documents 2 and 3). .

  Therefore, it merely presents a ring shape with the same width over the entire circumference, and there are few decorative elements.

Also, the chemical and the strip 41 comprising a light-emitting tube composed of coupling 42 emitting bracelet Ri Do the caliber certain size formed since the band member 41 is a ring shape having a certain length, the child's wrist It is too small for adults to wear, and it is too large for adults' wrists. In order to solve this problem, it is possible to make different luminescent bracelets of different sizes for adults and children, but it takes time and money to make multiple sized bracelets. It is not suitable for commercial use.
JP 2001-202801 A JP-A-8-280421 JP-A-10-99108

  The present invention has been made in view of the above problems, and allows the design of the shape of light emission, and allows the development of various decorative variations of the light emitting chamber and the bracelet body, from small children to adults. An object of the present invention is to provide a light-emitting bracelet that can be adjusted to be worn.

The light emitting bracelet according to the present invention includes a plurality of flexible materials each enclosing a fluorescent solution that causes a chemiluminescent phenomenon by mixing with each other and an oxidizing solution enclosed in a breakable ampoule formed by a glass tube. A light emitting bracelet in which a light emitting chamber made of a synthetic resin container having translucency is juxtaposed in a longitudinal direction through a connecting body to form a ring shape, and the axis of the breakable ampoule is the length of the connecting body It is arranged so as to intersect the direction .

  By arranging a plurality of independent light-emitting chambers in the length direction, the light-emitting chambers can be designed as desired, and each light-emitting chamber has a fluorescent solution and an oxidizing solution sealed in a splitting ampule. Since it is enclosed, for example, it is possible to change the light emission conditions for each light emitting chamber, such as the light emission color and the light emission amount, and extremely high decorativeness can be exhibited as compared with a conventional bar or strip.

  Further, the connecting body for forming the plurality of light emitting chambers in a ring shape may be provided by arranging the light emitting chambers in parallel along the length direction using a ring-shaped strip having flexibility, or The number of the light emitting chambers forming the ring is changed as a connecting member having the connecting body interposed between the plurality of light emitting chambers, and further, the connecting member is used as a connecting member having the connecting body interposed between the plurality of light emitting chambers. The diameter of the ring can be adjusted by making at least one extendable, so that it can be worn according to the thickness of the wrist from children to adults.

  According to the present invention, it is possible to provide a light emitting bracelet with higher decorativeness by enriching the light emitting color and design variations of each light emitting chamber. In addition, a light-emitting bracelet having a size range that can be used by everyone from children to adults can be provided.

It will be described in detail with reference to the accompanying drawings, embodiments of the light-emitting bracelet present invention.

  1 to 3 show a first embodiment of a luminescent bracelet 1 according to the present invention. The luminescent bracelet according to the present invention is chemically mixed with each other as shown in a development view shown in FIG. It is formed by a thin tube made of glass, for example, in which a fluorescent substance 21 that causes a luminescence phenomenon, a fluorescent liquid 21 made of oxalate ester, a catalyst, and dibutyl phthalate, and an oxidizing liquid 22 made of hydrogen peroxide, a catalyst, and dimethyl phthalate are enclosed. A light emitting chamber 31a... 31i made of a synthetic resin container having a triangular plate shape having an appropriate thickness and having a plurality of flexibility and translucency, each enclosing a splitting ampule 12 is provided. -It is formed in a state of being integrally arranged along the length direction along the band-shaped connecting body 11 formed of the same material as 31i, as shown in FIGS. It is obtained by bending to the size of the ring-shaped attachable to the wrist.

In the present embodiment, since the connecting body 11 having the light emitting chambers 31a... 31i arranged in a ring shape is sold, the light emitting chambers 31a, 31b, 31c,. It is conceivable that 31d itself is in a curved state together with the connecting body 11. Therefore, there is a concern that the splitting ampoule 12 in which the oxidizing solution 22 sealed in each light emitting chamber 31a... 31i is sealed will break along with the formation of the ring shape. Prevent breakage of the breakable ampoule 12 by arranging the axis line so as to cross the length direction of the connection body 11 so that it does not face the length direction of the connection body 11, that is, the bending direction. Can do.

In order to use this embodiment, in the state of FIG. 2 and FIG. 3, both free end portions 11a and 11b of the connecting body 11 are bent against the elasticity of the connecting body 11 and expanded to be inserted into the wrist. can be mounted to return to the state in which the original closed by the elastic if releasing the or or expansion force (not shown) can the child very easily mounted because.

Further, the elasticity after mounting with the coupling body 11, both the free end portion 11a, and the this to provide because 11b is kept closed the emission bracelet 1 having a caliber available to everyone from children to adults it can.

  In addition, in order to make each light emission chamber 31a ... 31i light-emit, after attaching to the wrist, or after attachment, pressure is applied from the outside to each light emission chamber 31a ... 31i, and conventional stick-shaped chemiluminescence. Like the body, the breakable ampoule 12 is folded to break the broken glass ampoule 12, and the oxidizing solution 22 and the fluorescent solution 21 sealed in the broken glass ampoule 11 are mixed.

Therefore, each of the bracelets bets whole emits light to one over conventional entire longitudinal band-shaped as shown in FIG. 10 since each light emitting chamber 31a · · · 31i designed in its own shape emits light independently Compared with this, it is possible to exhibit extremely excellent decorativeness.

  In this embodiment, each of the light emitting chambers 31a... 31i has a triangular plate shape. However, other shapes may be used, and different shapes may be provided side by side without making all the same shape. In these cases, the decorativeness is further enhanced. Further, since the light emitting chambers 31a. In addition, it is possible to emit light for a long time by causing any one of them to emit light while being shifted with time. In the present embodiment, each light emitting chamber 31a... 31i is formed integrally with the band-shaped connecting body 11, but each light emitting chamber 31a. Alternatively, they may be juxtaposed by welding, and in this case, manufacture is easy (not shown).

  FIG. 4 shows a second embodiment of the present invention, and the overall configuration, mounting method, operation and effect are substantially the same, but the light emitting chambers 31a. The difference is that some of 31i are vacant chambers 32b, 32d, 32f, and 32h.

  By providing these vacant chambers 32b, 32d, 32f, and 32h, the amount of synthetic resin to be used can be reduced, the weight can be reduced by not enclosing the luminescent solution, and a part of the coupling body 11 can be made flexible. Therefore, the broken glass ampoule 12 can be easily broken. Furthermore, when a part of the vacant room 32 is opened, an open part 33 can be formed in the vacant rooms 32b, 32d, 32f, and 32h, and a printed matter or a decoration 34 can be inserted to increase decorativeness. If the advertising wording is used, the advertising effect can be easily improved.

  FIG. 5 shows a third embodiment of the present invention. Unlike the first and second embodiments, the connecting body 11 is not an elongated rectangular shape, and the connecting body 11 itself has a desired shape. Shows an example of the design. In this case, it is possible to design not only the light emitting chambers 31a, 31b, 31c, and 31d but also the entire bracelet 1, and further enhance the decorativeness.

  FIG. 6 shows a fourth embodiment of the present invention, which is substantially the same as the embodiment shown in FIG. 1, except that the connecting body 11 is not bent into a ring shape and is entirely flat. Thus, locking members 13a and 13b that can be engaged and disengaged with each other are connected to both the free portions 11a and 11b. Therefore, this embodiment is advantageous at the time of transportation and sale because it is not bulky when stacked. At the time of mounting, the connecting body 11 may be wound around the wrist and the locking members 13a and 13b may be locked together to form a ring shape. In addition, what is necessary is just to cancel | release engagement of locking member 13a, 13b when removing.

  FIG. 7 shows a fifth embodiment of the present invention. The configuration and usage of the light emitting chambers 31a, 31b, 31c, 31d, and 31e are the same as those of the above-described embodiments. 31a, 31b, 31c, 31d, 31e are formed in a state of being connected to each other by a strip-like connecting body 11 made of the same material as the light emitting chambers 31a, 31b, 31c, 31d, 31e, and the light emitting chambers at both ends. Locking members 13a and 13b that can be engaged and disengaged with each other are connected to 31a and 31e.

  Since this embodiment is not bulky when stacked as in the fourth embodiment of the present invention shown in FIG. 6, it is advantageous at the time of transportation and sale, and the bracelet 1 is wound around the wrist to lock the locking member 13a. , 13b are attached to each other in the form of a ring and released by disengaging the engaging members 13a, 13b. In particular, most of the present embodiment is formed by the light emitting chambers 31a, 31b, 31c, 31d, and 31e, so that it can be formed with a low material cost.

  Further, FIG. 8 shows a sixth embodiment of the present invention, and the overall configuration and method of use are substantially the same as those of the fifth embodiment of the present invention shown in FIG. The strip-shaped connecting body 11 in which the light emitting chambers 31a, 31b, 31c, 31d, and 31e are formed of the same material as the light emitting chambers 31a, 31b, 31c, 31d, and 31e is shown in FIG. (B) differs in that it is formed in a semi-annular shape and has elasticity in the connecting direction, and can be attached regardless of the thickness of the wrist.

According to the present embodiment, since the connecting body 11 that connects the light emitting chambers 31a, 31b, 31c, 31d, and 31e has elasticity, the light emitting bracelet has a size range suitable for everyone from children to adults. 1 can and provide child a.

  In addition, the connection body 11 should just have a fixed elasticity, and a rubber body, a spring body, etc. can also be utilized.

  Furthermore, FIG. 9 shows a seventh embodiment of the present invention, and the overall configuration and method of use are substantially the same as the sixth embodiment of the present invention shown in FIG. As shown in FIG. 9A, the light emitting chambers 31a, 31b, 31c, and 31d are sequentially connected by an extendable connecting body 11 to form a ring shape, and the connecting body 11 is extended as it is. Since the ring-shaped bracelet 1 can be opened and detached from the wrist, handling is easy. In particular, when the connecting body 11 is formed relatively thin, the ring-shaped bracelet 1 can be folded in a plane by folding the connecting body 11 as shown in FIG. Convenient for storage and even carrying.

Concepts juxtaposed light emitting chamber in a ring shape via the connecting member also includes polygonal ring as shown in FIG. 1 0. In this embodiment , the breakable ampoule 12 can be arranged such that its axis is in the length direction of the coupling body 11.

  When encapsulating the oxalic acid ester and the fluorescent substance, which are components of the fluorescent solution, in the breakable ampoule as a solid, the solid may be granular, powdery, or lump, but when mixed with the oxidizing solution, Light emission starts when dissolved in a solvent, and the light emission brightness decreases when left standing, but when the whole bracelet is shaken, the undissolved precipitate dissolves and the light emission becomes stronger. Can be used for a long time.

  As shown in FIG. 2 and FIG. 10, when the light emitting chamber is integrated with the coupling body or when the wall thickness of the light emitting chamber is increased to 1 mm to 1.5 mm, the glass child ampoule is broken by hand pressure in the infant. If it becomes impossible to split, a simple folding tool (auxiliary) may be provided with the product.

The expanded view which shows 1st embodiment of this invention. The perspective view which shows 1st embodiment of this invention. 1 is a cross-sectional view showing a first embodiment of the present invention. The expanded view which shows 2nd embodiment of this invention. The expanded view which shows 3rd embodiment of this invention. The perspective view which shows 4th embodiment of this invention. The perspective view which shows 5th embodiment of this invention. The expanded view which shows the 6th Embodiment of this invention. The cross-sectional view which shows the 7th Embodiment of this invention. The perspective view which shows 8th embodiment of this invention. The perspective view which shows a prior art example.

  DESCRIPTION OF SYMBOLS 1 Light-emitting bracelet, 11 Connection body, 11a, 11b Free end part, 12 Ampoule, 13a, 13b Locking tool, 21 Fluorescent liquid, 22 Oxidizing liquid, 31a ... 31i Light-emitting room, 32 Empty room, 34 Decoration, 41 Band 42 couplings

Claims (6)

A plurality of flexible and translucent synthetic resin containers each encapsulating a fluorescent solution causing a chemiluminescence phenomenon by mixing with each other and an oxidizing solution encapsulated in a breakable ampule formed by a glass tube the emission chamber comprising a through connection body a light-emitting bracelet has a ring shape and arranged in the longitudinal direction, the axis of the split ampoule broken is arranged so as to intersect the longitudinal direction of the coupling body A luminous bracelet characterized by that. A plurality of flexible and translucent synthetic resin containers each encapsulating an oxidizing solution causing a chemiluminescence phenomenon by mixing with each other and a fluorescent solution sealed in a breakable ampoule formed by a glass tube A light emitting bracelet having a light emitting chamber made of a ring-like structure arranged in parallel in a length direction via a connecting body , wherein the breakable ampoule is arranged so that an axis intersects the length direction of the connecting body A luminous bracelet characterized by that. Multiple flexible and translucent materials each containing a mixture of an oxalate ester and a fluorescent material encapsulated in a breakable ampoule formed by a glass tube and an oxidizing solution that causes a chemiluminescence phenomenon when mixed with each other A light-emitting bracelet having a light- emitting chamber made of a synthetic resin container having a ring shape arranged in parallel in a longitudinal direction via a coupling body , the axis of the splitting ampoule intersecting the length direction of the coupling body Luminous bracelet characterized by being arranged to .   The luminescent bracelet according to any one of claims 1, 2, and 3, wherein the connecting body has a band shape.   The luminescent bracelet according to any one of claims 1, 2, 3, and 4, wherein some of the luminescent chambers are vacant chambers.   The light-emitting bracelet according to any one of claims 1, 2, 3, 4, and 5, wherein at least one of the coupling bodies can be expanded and contracted in a coupling direction.

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