JP4044934B2 - Chemiluminescent for fishing - Google Patents

Description

  The present invention relates to a chemiluminescent material for fishing used in fishing, for example, in the case of improving a fish collection effect by using a light emitting function, or in a case where a position such as a float can be easily visually recognized.

  In general, fish have the property of gathering in light. However, when it is desired to enhance the fish collection effect and the like by using such habits, a chemiluminescent body is attached to the device. In addition, when fishing at night or the like is desired to make it easy to visually recognize the position of floating or the like, a chemiluminescent body is attached to the floating head. Thus, chemiluminescent bodies have come to be used in a wide range of applications in fishing.

Conventionally, as this type of fishing chemiluminescent material, for example, the one shown in FIG. 6 exists (see Patent Document 1).
No. 25069984 (2nd page, FIG. 1).

  That is, in this conventional product, a solution 12 is sealed in a transparent synthetic resin container 11 having flexibility, and a glass ampule 13 is built therein, and the ampule 13 reacts with the solution 12. Then, a chemiluminescent solution 14 is enclosed.

  In actual use, when the container 11 is bent substantially at the center, the ampoule 13 is broken, and the solution 14 is mixed with the solution 12 to emit chemiluminescence. Used by attaching to the thread.

  However, in the conventional chemiluminescent body for fishing, since light is emitted by mixing the solution 12 and the solution 14, that is, because of the reaction between the liquids, both of them immediately after the ampoule 13 is broken. The liquid mixing was completed. For this reason, the luminance of light emission becomes very large immediately after mixing and emits light more brightly than necessary, but thereafter the luminance decreases rapidly in a short time, which is necessary and sufficient for this type of light emitter. There was a problem that the light emission time could not be secured. As a result, it was necessary to prepare a large number of light emitters for fishing.

  On the other hand, in order to ensure the light emission time of the illuminant, for example, it is conceivable to increase the amount of each of the solutions 12 and 14, but this increases the size of the container 11 and the ampoule 13 itself, thereby reducing the cost. As a result, there arises a new problem that not only the handling is hindered but also the usage is limited.

  Further, since the solution 12 is a liquid as described above, the concentration of the reactant contained in the solution 12 is saturated at about 14% by weight, so that there is a difficulty in that the concentration cannot be further increased. This makes the emission intensity unstable and contributes to the inability to maintain the above-described emission time.

  Furthermore, the luminous intensity of this type of illuminant is easily affected by the use temperature, and when the use temperature is low, there is a disadvantage that the illuminant cannot ensure sufficient brightness. No consideration was given, and there was a lack of consideration for use in cold environments such as cold regions.

  The present invention has been made in view of such circumstances, and an object of the present invention is to greatly contribute to fishing by providing a light-emitting body that can secure a sufficient light emission time and has a stable light emission intensity. .

  The fishing chemiluminescent body according to claim 1, wherein the solution is enclosed in a flexible translucent container, and an ampoule having a splitting property is provided therein, and the ampoule reacts with the solution. It is characterized by containing a powdery body that emits light.

  In the invention according to claim 1, when the light-transmitting container having flexibility is bent, the ampule having breakability incorporated in the container is broken, and thereby the ampule is broken. The powdery body reacts with the solution in the container to emit light.

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The fishing chemiluminescent body according to claim 2 , wherein the solution is enclosed in a flexible translucent container, and an ampoule having a splitting property is provided therein, and the ampoule reacts with the solution. And a solid body that emits light is stored.

In the invention described in claim 2, when the light-transmitting container having flexibility is bent, the ampoule having breakability incorporated in the container is broken, and thereby the ampoule is broken. The inner solid body reacts with the solution in the container to emit light.

Fishing chemiluminescers according to claim 3, in fishing chemiluminescence body according to any one of claims 1 to 3, wherein the powder-like body or oxalic acid ester is contained in the solid body and the oxalate The ester is characterized by being set to 50 to 99.9% by weight.

In the invention according to claim 3 , since the oxalate ester is set to 50 to 99.9% by weight, that is, the concentration of the oxalate ester is set to a relatively high concentration, The reaction with the solution proceeds in a stable state.

Fishing chemiluminescers according to claim 4, and characterized in that the fishing chemiluminescence body according to any one of claims 1 to 3, powdered material or formed by sodium salicylate is contained in the solid body To do.

In the invention described in claim 4, powdery material or to become by the additional inclusion of sodium salicylate or salicylate lithium solid body, powder body or a solid body is a pre-alkaline environment, thus The reaction with the solution proceeds in this alkaline environment.

Fishing chemiluminescers according to claim 5, in fishing chemiluminescence body according to any one of claims 1 to 4, and wherein the powder body or salicylic acid lithium solid body formed by containing To do.

In the invention of claim 5, for powdery material or formed by the additional inclusion of salicylic acid lithium solid body, similar to the invention described in claim 5, powdery material or solid bodies previously alkali Thus, the reaction with the solution proceeds in this alkaline environment.

The powdered material or solid bodies of the solution and the ampoule in the container in fishing chemiluminescence body according to the above claims, also powder-like body reacts in accordance with the solid body is impregnated gradually into the solution Exhibits luminescence.

  The fishing chemiluminescent body according to claim 1 is configured to emit light by the reaction between the powdery body in the ampoule and the solution in the container. While maintaining the brightness, the reaction between the two gradually proceeds as compared with the conventional phosphors made of solutions. Therefore, the light emission time can be secured at least twice that of the conventional one.

  As a result, the number of light emitters consumed during fishing may be small, which can contribute to cost reduction.

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The fishing chemiluminescent body according to claim 2 is configured to emit light by the reaction between the solid body in the ampoule and the solution in the container. Also in this case, the reaction between the solid body and the solution is gradually performed. Thus, the same effect as that of the chemiluminescent body for fishing according to claim 1 is obtained.

Fishing chemiluminescers according to claim 3, for the oxalate in the powder-like body or a solid body is formed by setting the contained and the oxalic acid ester in 50 to 99.9 wt%, i.e. Since the concentration of the oxalate ester is set to a relatively high concentration, the reaction with the solution becomes reliable and good, so that stable emission intensity can be obtained.

Fishing chemiluminescers according to Claim 4, in order pulverulent body or formed by the additional inclusion of sodium salicylate to a solid body, that is, the ampoule in advance to alkaline environment, and the powder-like material or the like The onset of the reaction with the solution is fast, and it emits light immediately after the ampoule breaks.

Fishing chemiluminescers according to claim 5, powdery material or to become by the additional inclusion of salicylic acid lithium solid body, i.e. similar to the invention described in claim 4, in advance and in an alkaline environment in the ampoule Therefore, the reaction between the powdery body and the solution proceeds smoothly without difficulty and emits light immediately after the ampoule breaks. Further, by using such lithium salicylate, there is an advantage that the reaction with the solution is satisfactorily performed even under low temperature use conditions, and as a result, sufficient light emission intensity can be ensured even in a cold region.

  Next, one embodiment of a fishing chemiluminescent material according to the present invention will be described with reference to the drawings.

  In FIG. 1, 1 shows a cylindrical container and consists of a synthetic resin which has flexibility and translucency. Reference numeral 2 denotes an ampule made of glass having breakability, and is housed in the container 1.

  In the figure, 3 is a solution sealed in the container 1, which is composed of dimethyl phthalate, tert-butyl alcohol, hydrogen peroxide and sodium salicylate. The blending ratio is 85% by weight of dimethyl phthalate, tert-butyl alcohol. Is set to 10% by weight, and hydrogen peroxide is set to about 4 to 5% by weight. 4 is a powdery material housed in an ampoule 2, which is formed into a solid state, and salicylic acid for smoothly advancing peroxalate, dye and light emission so that it reacts with the solution 3 to emit light. The composition ratio is set to 99% by weight of peroxalate (CPPO), about 1% by weight of dye, and 0.01% by weight of sodium salicylate.

  As described above, since the peroxalate (CPPO) is housed in the container 2 housed in the container 1 instead of the container 1, the peroxalate (CPPO) is placed between the outside air and the peroxalate (CPPO). Since the triple barrier of the container 2, the solution 3 in the container 1 and the container 1 is formed, it does not react with the outside air and oxidize and deteriorate, but also deteriorates due to the outside air humidity. Therefore, a good state can be maintained for a long time.

  The fishing chemiluminescent body H according to the present embodiment is configured as described above. The light emitter H emits light as follows, for example.

  First, as shown in FIG. 2, when the container 1 is bent in an inverted V shape at substantially the center while grasping both sides, the ampule 2 in the container 1 is also broken due to its force.

  Thereby, the said solution 3 and the said powdery body 4 of the said ampule 2 react, and the said powdery body 4 melt | dissolves and exhibits light emission. That is, a part of the powdery body 4 moves from the ampoule 2 to the container 1 and develops color, while the solution 3 gradually impregnates the ampoule 2, In order to react, color development over a long period of time is possible while maintaining the brightness required for this type of illuminant. In this case, since the powdery body 4 contains sodium salicylate, that is, since the ampoule 2 is set in an alkaline environment in advance, the reaction between the powdery body 4 and the solution 3 is performed. The start-up is quick and light is emitted immediately after the ampoule 2 is broken.

  Further, since the color is generated by the reaction between the powder 4 and the solution 3 as described above, the luminous time of the luminous body H is 2 as compared with the case where the solutions are mixed to emit light. It can be held more than twice.

  In addition, FIG. 3 is a graph showing the relationship between the luminance of the illuminant and time. In the conventional illuminant, the luminance rises immediately after the reaction of the two liquids and emits light brighter than necessary. The luminance is greatly reduced within 1 hour after light emission, and the rate of reduction thereafter is also very large. On the other hand, the luminous body H in the present embodiment is smaller than the luminance of the conventional luminous body immediately after the reaction between the solution 3 and the powdery body 4, but the subsequent luminance reduction rate is also small. It can be seen that a sufficient light emission time can be secured while maintaining the luminance required for this type of light emitter H.

  Regarding the fact that such a luminescent state can be exhibited, the concentration of the peroxalate (CPPO) in the powdery body 4 is set to a high concentration of 99% by weight. A stable light emission intensity can be secured.

  As a result, the number of light emitters H to be used for fishing can be reduced, so that the cost can be reduced.

  Note that the luminous body H that emits light as described above is used by being attached to a road thread using, for example, an attachment holder 5 as shown in FIGS. 4 (a) and 4 (b).

  The mounting holder 5 is made of a synthetic resin capable of transmitting light emitted from the light emitter H, and a notch 7 is formed in the center of the upper surface along the longitudinal direction of the insertion portion 6 provided at one end thereof. The inner diameter of the insertion portion 6 is set slightly smaller than the outer diameter of the light emitter H.

  The mounting holder 5 has a mounting portion 8 connected to the insertion portion 6. A mounting hole 9 formed at the center of the upper surface along the longitudinal direction has a wide width portion 9 a and the other end of the mounting holder 5. A narrow portion 9b located on the side of the portion and an intermediate portion 9c disposed between the two, so that the width L of the narrow portion 9b is larger than the width l of the cut 7 of the insertion portion 6. Is set. The inner surface of the mounting hole 9 is chamfered.

  First, in FIG. 5 (a), with the thread 10 inserted through the notch 7 and the mounting hole 9 of the mounting holder 5, the light emitting body H is slightly inclined and one end thereof is inserted into the mounting holder 5. Insert into part 6. Since the cut portion 7 is formed in the insertion portion 6, the one end portion side of the light emitter H can be easily inserted so that the cut portion 7 is opened.

  Next, when the other end side of the light emitter H is pressed toward the mounting hole 9 side of the mounting holder 5 in this state, the mounting hole 9 is opened by the pressing force as shown in FIG. The other end side is fitted to the mounting portion 8 so that the light emitter H can be mounted in the attachment holder main body 1, and the light emitter H is attached to the road thread 10.

  In this case, since the one end side of the light emitter H is inserted into the insertion portion 6 of the attachment holder 5, that is, the other end side can be attached to the attachment holder 1 with the one end portion side of the light emitter H as a fulcrum. There is an advantage that a series of mounting operations can be performed easily, reliably and accurately.

In the above embodiment, the powdery body 4 is compacted to be solidified and stored in the ampoule 2 in a solid state, but the powdery body 4 may be stored in the ampoule 2 in a powdery state. not good.

  Further, the blending ratio of each substance constituting the solution 3 is not limited to this embodiment, dimethyl phthalate is 50 to 99% by weight, tertiary butyl alcohol is 1 to 30% by weight, and hydrogen peroxide is 1%. It may be in the range of 10 to 10% by weight and sodium salicylate 0.01 to 1% by weight. However, the solution 3 can of course be composed of other than these substances.

  Further, the powdery body 4 and the like are not limited to the above embodiment, and the dye may be constituted within a range of 0.01 to 5% by weight and the sodium salicylate within a range of 0.01 to 1% by weight. In the case of use, if lithium salicylate is used instead of the sodium salicylate, the reaction between the powder 4 and the solution 3 proceeds smoothly and smoothly in the alkaline environment as in the case of sodium salicylate. As a matter of course, there is an advantage that the reaction with the solution becomes good even under low temperature use conditions, and as a result, sufficient luminescence intensity is obtained even in cold regions. It can be secured. The powdery body 4 or the like need not necessarily contain sodium salicylate or lithium salicylate.

  The powdery body 4 and the like can use so-called CIPO instead of the peroxalate (CPPO) of the above embodiment. However, the specific configurations of the powdery body 4 and the like are not limited to these, and any configuration that emits light when reacting with the solution 3 is essential.

  Furthermore, the container 1 should just have flexibility and translucency, and the specific material is not ask | required.

  Further, the ampoule 2 is not limited as long as it has a splitting property, and is not necessarily composed of a glass material as in the above embodiment.

  Furthermore, in the said embodiment, although the chemiluminescent body H was attached to the road line 10 using the attachment holder 5 in order to use it for fish collection, the chemiluminescent body for fishing which concerns on this invention is by no means limited to such an application. Of course, it is possible to use it so as to visually recognize the position of the float etc. by attaching it to the float etc.

  In addition, the specific shapes and sizes of the container 1 and the ampoule 2 can be arbitrarily changed within the range intended by the present invention.

It is a front view which shows one Embodiment of the chemiluminescent body for fishing which concerns on this invention. It is a front view which shows the same use condition. It is a graph which shows the relationship between the brightness | luminance and time in the chemiluminescent body for fishing which concerns on this invention, and the conventional chemiluminescent body for fishing. It is a perspective view which shows the attachment holder of the chemiluminescent body for fishing which concerns on this invention. It is a perspective view which shows the use condition. It is a perspective view which shows the chemiluminescent body for fishing of patent document 1.

Explanation of symbols

1 Container 2 Ampoule 4 Solution 5 Powder

Claims (5)

A solution is enclosed in a translucent container having flexibility, and an ampoule having a splitting property is embedded therein, and the ampoule contains a powdery body that emits light by reacting with the solution. A chemiluminescent body for fishing. A solution is enclosed in a light-transmitting container having flexibility, and an ampoule having a splitting property is embedded therein, and the ampoule contains a solid body that emits light by reacting with the solution; A chemiluminescent body for fishing. The powder-like body or oxalic acid ester is contained in the solid body and the oxalic acid ester fishing chemiluminescence body according to claim 1 or 2 comprising set to 50 to 99.9 wt%. Fishing chemiluminescence body according to any one of claims 1 to 3 sodium salicylate, which are contained in the powdery body or solid body. Fishing chemiluminescence body according to any one of claims 1 to 4 lithium salicylate is being contained in the powdery body or solid body.

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