JP4523116B2 - Operation method of water electrolysis system - Google Patents
Operation method of water electrolysis system Download PDFInfo
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- JP4523116B2 JP4523116B2 JP2000159576A JP2000159576A JP4523116B2 JP 4523116 B2 JP4523116 B2 JP 4523116B2 JP 2000159576 A JP2000159576 A JP 2000159576A JP 2000159576 A JP2000159576 A JP 2000159576A JP 4523116 B2 JP4523116 B2 JP 4523116B2
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- water electrolysis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
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Description
【0001】
【発明の属する技術分野】
本発明は水電解システム,特に,複数の水電解セルよりなるセル群を有する水電解装置と,そのセル群の電源である太陽電池とを備えた水電解システムの運転方法に関する。
【0002】
【従来の技術】
水電解システムを効率良く運転するためには,太陽電池の最適動作点,つまりその出力が最大となるときの動作電流・動作電圧を用いることが必要であるが,その最適動作点は太陽電池の温度,日射量等によって変動する。そこで,従来は,太陽電池および水電解装置間にDC−DCコンバータを直列に接続して太陽電池の最適動作点の出力が得られるようにそのDC−DCコンバータを制御している。
【0003】
【発明が解決しようとする課題】
しかしながら,前記従来法によると,DC−DCコンバータを用いることからシステムの運転制御が複雑である上に,効率が80〜90%であって今一歩の向上が必要である,といった問題があり,また前記コンバータの採用に伴い水電解システムのコストが高くなる,という不具合もあった。
【0004】
【課題を解決するための手段】
本発明は,簡単な手段を採用することによって,太陽電池の最大出力を100%,またはそれに近い効率で水電解システムの運転に利用することができるようにした前記運転方法を提供することを目的とする。
【0005】
前記目的を達成するため本発明によれば,複数の水電解セルよりなるセル群を有する水電解装置と,そのセル群の電源である太陽電池とを備えた水電解システムを運転するに当り,前記太陽電池の出力を前記セル群に直接供給し得るように,前記太陽電池と前記セル群の複数の水電解セルとを,それら水電解セルの使用数を選択可能として電気的に直列に接続し,前記水電解セルの使用数を,前記太陽電池の最大出力を利用し得るように,前記水電解セルの前記使用数に応じたIV特性が前記太陽電池の最適動作点の電流及び電圧を含むか,或いは前記最適動作点近傍の電流及び電圧を含むように選定することを特徴とする,水電解システムの運転方法が提供される。
【0006】
太陽電池のIV(I:電流,V:電圧)特性は,例えば,その温度によって異なる。一方,セル群において,直列に接続されるa個の水電解セルの集合を(a)セルユニットとし,またa+1個の水電解セルの集合を(a+1)セルユニットとし,……a+n個の水電解セルの集合を(a+n)セルユニットとすると,IV特性は各セルユニットについて異なる。
【0007】
そこで,電圧をx軸に,また電流をy軸にそれぞれとって,或温度における太陽電池のIV特性,つまり1本の曲線を描き,また(a)セルユニット,(a+1)セルユニット……(a+n)セルユニットのIV特性,つまり複数の直線を描くと,それら直線の何本かが1本の曲線に交差し,各交点が,各セルユニットに対応する太陽電池の動作点となる。この場合,複数の交点のうち,太陽電池の最適動作点に合致するか,またはその近傍に存在する交点を持つセルユニットを選択して運転するようにすれば,即ち,水電解セルの使用数に応じてIV特性が異なるセルユニットの中から、そのIV特性が太陽電池の最適動作点の電流及び電圧を含むか,或いは最適動作点近傍の電流及び電圧を含むようなセルユニットを選定して運転するようにすれば,そのセルユニット,したがって水電解システムの運転に際し,或温度下における太陽電池の最大出力を100%,またはそれに近い効率で利用することが可能となる。
【0008】
【発明の実施の形態】
図1において,水電解システム1は,セル群2を有する水電解装置3と,そのセル群2の電源である太陽電池4とを備える。セル群2は,電気的に直列に接続される複数,実施例では第1〜第8水電解セルC1〜C8を有する。第1,第2水電解セルC1,C2の(−),(+)両端子間,第2,第3水電解セルC2,C3の(−),(+)両端子間……第6,第7水電解セルC6,C7の(−),(+)両端子間および第7,第8水電解セルC7,C8の(−),(+)両端子間はそれぞれ接続線5を介して接続される。相隣る両水電解セルC1,C2間……C7,C8間の接続線5に第1〜第7スイッチS1〜S7の一方のリード線6が,また第8水電解セルC8の(−)端子に第8スイッチS8の一方のリード線6がそれぞれ接続される。第1および第8スイッチS1,S8の他方のリード線7は接続線8の両端に接続され,また第2〜第7スイッチS2〜S7の他方のリード線7は接続線8の中間部にそれぞれ接続される。
【0009】
第1水電解セルC1の(+)端子は接続線9を介して太陽電池4の(+)端子に接続され,一方,第8スイッチS8側に在る接続線8の他端は接続線10を介して太陽電池4の(−)端子に接続される。これにより第8スイッチS8を閉じて,他のスイッチを開いておくことにより,太陽電池4の出力がセル群2に直接供給される。
【0010】
太陽電池4に,その温度を検知する測温器11が付設され,その測温器11からの温度情報は各スイッチS1〜S8を開閉制御するスイッチ制御器12に伝達される。これにより,太陽電池4の温度情報に基づき,その太陽電池4の最大出力を利用し得るように,スイッチ制御器12によって水電解セルC1〜C8の使用数の選定が行われる。この場合,太陽電池4の温度は,その太陽電池4への日射量に略比例するもので,日射量(W/m2
)をxとし,温度(℃)をyとすると,温度yは,一例として,y≒35.489x+1.9118と表わされる。
【0011】
例えば,第1〜第6水電解セルC1〜C6を使用する場合を6セルユニットとすると,その6セルユニットは第6スイッチ6を閉じ,残りのスイッチを開いておくことによって現出する。同様に7セルユニットは第7スイッチS7を閉じ,残りのスイッチを開いておくことによって現出し,さらに8セルユニットは第8スイッチS8を閉じ,残りのスイッチを開いておくことによって現出する。
【0012】
図2において,1本の曲線L1は,太陽電池4の25℃(日射量:0.65W/m2 )におけるIV特性を示し,また他の1本の曲線L2はその太陽電池4の出力特性を示す。この場合,太陽電池4の最適動作点Pは,相対出力が最大となる,動作電圧16.7V,動作電流90Aの点である。
【0013】
一方,図2において,動作電圧11.6V,動作電流0Aの点P1を通る直線L3は6セルユニットのIV特性を,また動作電圧14.3V,動作電流0Aの点P2を通る直線L4は7セルユニットのIV特性を,さらに動作電圧17.2V,動作電流0Aの点P3を通る直線L5は8セルユニットのIV特性をそれぞれ示す。
【0014】
この場合,太陽電池4のIV特性を示す曲線L1に6〜8セルユニットのIV特性を示す3本の直線L3〜L5が交差し,また曲線L1と7セルユニットに関する直線L4との交点は太陽電池4の最適動作点Pである。
【0015】
このような状況下においては,測温器11が太陽電池4の温度25℃を検知し,その測温器11からの温度情報はスイッチ制御器12に伝達される。これにより,太陽電池4の温度情報に基づき,その太陽電池4の最大出力を利用し得るように,スイッチ制御器12によって水電解セルC1〜C8の使用数の選定が行われる。即ち,第7スイッチS7を閉じ,残りのスイッチを開いておくことによって7セルユニットが現出される。
【0016】
図3は,太陽電池4の温度が80℃(日射量:2.20W/m2 )のときの,そのIV特性と,6〜8セルユニットのIV特性との関係を示す。
【0017】
この場合には太陽電池4の最適動作点Pは動作電圧13.5V,動作電流90Aの点であり,その点Pで曲線L1に6セルユニットのIV特性を示す直線L3が交差する。
【0018】
このような状況下においては測温器11およびスイッチ制御器12の協働で,第6スイッチS6を閉じ,残りのスイッチを開いておくことによって6セルユニットが現出される。
【0019】
【発明の効果】
本発明によれば,太陽電池の出力をセル群に直接供給し得るように,太陽電池とセル群の複数の水電解セルとを,それら水電解セルの使用数を選択可能として電気的に直列に接続し,水電解セルの使用数を,水電解セルの使用数に応じたIV特性が太陽電池の最適動作点の電流及び電圧を含むか,或いは前記最適動作点近傍の電流及び電圧を含むように選定することによって,太陽電池の最大出力を100%またはそれに近い効率で水電解システムの運転に利用することが可能な運転方法を提供することができる。また,太陽電池の出力をセル群の複数の水電解セルに直接供給し得るようにしたので,従来必須のDC−DCコンバータは不要であるからシステムの運転制御が簡単であり,その上,水電解システムも安価となる。
【図面の簡単な説明】
【図1】 水電解システムの説明図である。
【図2】 太陽電池および6〜8セルユニットに関するIV特性の一例を示すグラフである。
【図3】 太陽電池および6〜8セルユニットに関するIV特性の他例を示すグラフである。
【符号の説明】
1………………水電解システム
2………………セル群
3………………水電解装置
4………………太陽電池
C1〜C8……第1〜第8水電解セル[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a water electrolysis system, and more particularly to an operation method of a water electrolysis system including a water electrolysis apparatus having a cell group composed of a plurality of water electrolysis cells, and a solar battery as a power source of the cell group.
[0002]
[Prior art]
In order to operate the water electrolysis system efficiently, it is necessary to use the optimal operating point of the solar cell, that is, the operating current and operating voltage when the output is maximized. It varies depending on temperature, amount of solar radiation, etc. Therefore, conventionally, a DC-DC converter is connected in series between the solar cell and the water electrolysis device, and the DC-DC converter is controlled so as to obtain an output at the optimum operating point of the solar cell.
[0003]
[Problems to be solved by the invention]
However, according to the conventional method, since the DC-DC converter is used, there is a problem that the operation control of the system is complicated and the efficiency is 80 to 90% and further improvement is necessary. There was also a problem that the cost of the water electrolysis system increased with the adoption of the converter.
[0004]
[Means for Solving the Problems]
An object of the present invention is to provide the operation method in which the maximum output of the solar cell can be used for the operation of the water electrolysis system at an efficiency of 100% or close to it by adopting simple means. And
[0005]
In order to achieve the above object, according to the present invention, in operating a water electrolysis system comprising a water electrolysis apparatus having a cell group composed of a plurality of water electrolysis cells and a solar cell as a power source of the cell group, The solar battery and a plurality of water electrolysis cells in the cell group are electrically connected in series so that the number of use of the water electrolysis cells can be selected so that the output of the solar battery can be directly supplied to the cell group. and, the number of use of said water electrolysis cell, so as to utilize the maximum output of the solar cell, the current and voltage of the optimum operating point of the IV characteristics in accordance with the number of use of said water electrolysis cell the solar cell There is provided a method for operating a water electrolysis system, characterized in that it is selected to include or include current and voltage in the vicinity of the optimum operating point .
[0006]
The solar cell of IV (I: current, V: voltage) characteristic, for example, it varies depending on the temperature. On the other hand, in the cell group, a set of a water electrolysis cells connected in series is defined as (a) cell unit, and a set of a + 1 water electrolysis cells is defined as (a + 1) cell unit. If the set of electrolytic cells is an (a + n) cell unit, the IV characteristics are different for each cell unit.
[0007]
Therefore, taking the voltage on the x-axis and the current on the y-axis, draw the IV characteristics of the solar cell at a certain temperature, that is, a single curve, and (a) cell unit, (a + 1) cell unit ... a + n) When the IV characteristics of the cell unit, that is, a plurality of straight lines are drawn, some of the straight lines intersect with one curve, and each intersection becomes an operating point of the solar cell corresponding to each cell unit. In this case, it is possible to select and operate a cell unit having an intersection that meets or is close to the optimum operating point of the solar cell among a plurality of intersections, that is, the number of water electrolysis cells used. Depending on the cell unit, select a cell unit whose IV characteristic includes the current and voltage at the optimum operating point of the solar cell or the current and voltage near the optimum operating point. When operated, the maximum output of the solar cell at a certain temperature or at a temperature close to 100% can be used when operating the cell unit, and hence the water electrolysis system.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
In FIG. 1, a
[0009]
The (+) terminal of the first water electrolysis cell C1 is connected to the (+) terminal of the
[0010]
A
) Is x, and temperature (° C.) is y, the temperature y is expressed as y≈35.489x + 1.9118 as an example.
[0011]
For example, when the first to sixth water electrolysis cells C1 to C6 are used as a 6-cell unit, the 6-cell unit appears by closing the
[0012]
In FIG. 2, one curve L1 indicates the IV characteristics of the
[0013]
On the other hand, in FIG. 2, the straight line L3 passing through the point P1 of the operating voltage 11.6V and the operating current 0A indicates the IV characteristic of the 6-cell unit, and the straight line L4 passing through the point P2 of the operating voltage 14.3V and the operating current 0A is 7 The straight line L5 passing through the point P3 of the cell unit IV characteristics and further the operating voltage 17.2V and the operating current 0A indicates the IV characteristics of the 8-cell unit.
[0014]
In this case, the curve L1 indicating the IV characteristics of the
[0015]
Under such circumstances, the
[0016]
FIG. 3 shows the relationship between the IV characteristics when the temperature of the
[0017]
In this case, the optimum operating point P of the
[0018]
Under such a situation, the six-cell unit appears by closing the sixth switch S6 and opening the remaining switches in cooperation with the
[0019]
【The invention's effect】
According to the present invention , a solar battery and a plurality of water electrolysis cells of the cell group are electrically connected in series so that the number of use of these water electrolysis cells can be selected so that the output of the solar battery can be directly supplied to the cell group. The IV characteristics according to the number of water electrolysis cells used include the current and voltage at the optimum operating point of the solar cell, or include the current and voltage in the vicinity of the optimum operating point. By selecting in this way, it is possible to provide an operation method capable of utilizing the maximum output of the solar cell for the operation of the water electrolysis system with an efficiency of 100% or close thereto. In addition, since the output of the solar cell can be directly supplied to a plurality of water electrolysis cells in the cell group , the operation control of the system is simple because the conventionally required DC-DC converter is not necessary. Electrolysis systems are also inexpensive.
[Brief description of the drawings]
FIG. 1 is an explanatory diagram of a water electrolysis system.
FIG. 2 is a graph showing an example of IV characteristics related to a solar cell and 6 to 8 cell units.
FIG. 3 is a graph showing another example of IV characteristics related to a solar cell and 6 to 8 cell units.
[Explanation of symbols]
1 …………
Claims (1)
前記太陽電池(4)の出力を前記セル群(2)に直接供給し得るように,前記太陽電池(4)と前記セル群(2)の複数の水電解セル(C1〜C8)とを,それら水電解セル(C1〜C8)の使用数を選択可能として電気的に直列に接続し,
前記水電解セル(C1〜C8)の使用数を,前記太陽電池(4)の最大出力を利用し得るように,前記水電解セル(C1〜C8)の前記使用数に応じたIV特性が前記太陽電池の最適動作点の電流及び電圧を含むか,或いは前記最適動作点近傍の電流及び電圧を含むように選定することを特徴とする水電解システムの運転方法。A water electrolysis system comprising a water electrolysis device (3) having a cell group (2) comprising a plurality of water electrolysis cells (C1 to C8) and a solar cell (4) as a power source for the cell group (2). In driving,
The solar cell (4) and a plurality of water electrolysis cells (C1 to C8) of the cell group (2) so that the output of the solar cell (4) can be directly supplied to the cell group (2) . The number of water electrolysis cells (C1 to C8) used can be selected and electrically connected in series ,
The number of used the water electrolysis cell (C1 to C8), so as to utilize the maximum output of the solar cell (4), IV characteristics according to the number of use of said water electrolysis cell (C1 to C8) is the A method for operating a water electrolysis system, comprising selecting or including a current and voltage at or near an optimum operating point of a solar cell .
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US7510640B2 (en) * | 2004-02-18 | 2009-03-31 | General Motors Corporation | Method and apparatus for hydrogen generation |
JP4842577B2 (en) * | 2005-07-29 | 2011-12-21 | 本田技研工業株式会社 | Operation method of water electrolysis system |
JP2008063615A (en) * | 2006-09-07 | 2008-03-21 | Hitachi Zosen Corp | Water electrolytic apparatus |
US10337110B2 (en) * | 2013-12-04 | 2019-07-02 | Covestro Deutschland Ag | Device and method for the flexible use of electricity |
JP6323804B2 (en) * | 2014-02-12 | 2018-05-16 | 高砂熱学工業株式会社 | Hydrogen production apparatus and operation method thereof |
JP6919506B2 (en) | 2017-11-02 | 2021-08-18 | 富士通株式会社 | Electrolysis system, electrolysis control device and control method of electrolysis system |
JP7168541B2 (en) * | 2019-10-16 | 2022-11-09 | 株式会社豊田中央研究所 | water electrolysis system |
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JPH07331474A (en) * | 1994-06-13 | 1995-12-19 | Fuji Electric Co Ltd | Operation control system of water electrolysis device using solar battery as power source. |
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JPH07331474A (en) * | 1994-06-13 | 1995-12-19 | Fuji Electric Co Ltd | Operation control system of water electrolysis device using solar battery as power source. |
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