JP4503285B2 - Milk component-containing coffee beverage in sealed container and method for producing the same - Google Patents
Milk component-containing coffee beverage in sealed container and method for producing the same Download PDFInfo
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- JP4503285B2 JP4503285B2 JP2003434818A JP2003434818A JP4503285B2 JP 4503285 B2 JP4503285 B2 JP 4503285B2 JP 2003434818 A JP2003434818 A JP 2003434818A JP 2003434818 A JP2003434818 A JP 2003434818A JP 4503285 B2 JP4503285 B2 JP 4503285B2
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- Prior art keywords
- milk
- coffee
- acid
- gel
- weight
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Landscapes
- Dairy Products (AREA)
- Tea And Coffee (AREA)
- Non-Alcoholic Beverages (AREA)
Description
本発明は、缶等の保存密封容器に充填されて市場に流通する密封容器入り乳成分含有コーヒー飲料及びその製造方法に関する。詳細には、本発明は、生豆換算で5%以上のコーヒー分及び無脂乳固形分換算で0.8%以上の乳成分を含有するコーヒーであって、殺菌処理及び長期保存に際してもゲル状沈殿を生じず、品質保持、安定性に優れた密封容器入り乳成分含有コーヒー飲料及びその製造方法に関する。 The present invention relates to a milk beverage containing a milk component in a sealed container that is filled in a storage sealed container such as a can and distributed in the market, and a method for producing the same. Specifically, the present invention is a coffee containing a coffee component of 5% or more in terms of green beans and a milk component of 0.8% or more in terms of solid content of non-fat milk, and gels for sterilization and long-term storage. The present invention relates to a milk beverage containing a milk component containing a sealed container that is excellent in quality maintenance and stability without causing a precipitate, and a method for producing the same.
従来、密封容器入り乳成分含有コーヒー飲料を製造する場合、加熱殺菌工程後に多量のゲル状沈殿が発生し品質が損なわれることがある。特に、コーヒーや乳成分を多く含むコーヒー飲料に関してはその傾向が顕著であり、更には、近年ホットコーヒー用としてホットベンダーでの高温状態での保存が頻繁に行われるようになり、更に、その傾向に拍車をかけることとなっている。 Conventionally, when producing a milk component-containing coffee beverage in a sealed container, a large amount of gel-like precipitate is generated after the heat sterilization step, and the quality may be impaired. In particular, the tendency is remarkable with respect to coffee beverages containing a large amount of coffee and milk components. Furthermore, in recent years, storage at a high temperature in a hot bender has been frequently performed for hot coffee, and the tendency is further increased. To spur.
ゲル状沈殿が生じる原因の詳細は不明であるが、当該ゲル状沈殿はコーヒー抽出液又は乳成分に含まれる多糖類、蛋白質及びカルシウムイオンからなるものと推定されている。 Although the details of the cause of the gel precipitate are unknown, it is presumed that the gel precipitate is composed of polysaccharides, proteins and calcium ions contained in the coffee extract or milk component.
従来、製造時あるいは保存時のゲル状沈殿の生成を抑制する方法としては、コーヒー抽出液に炭酸水素ナトリウムを添加する方法(特許文献1、特許文献2等)、有機酸塩を添加する方法(特許文献3、特許文献4、特許文献5)、リン酸3アルカリ金属塩を添加する方法(特許文献6)等、種々の方法が検討されてはいる。しかし、処理が煩雑でありコーヒーの工業的生産に不向きであったり、また、ゲル状沈殿を抑制する効果は未だ充分でなく、コーヒー缶詰の風味に悪影響を与えたり、長期保管中においても沈殿が生じない方法は知られていなかった。 Conventionally, as a method for suppressing the formation of gel-like precipitates during production or storage, a method of adding sodium bicarbonate to a coffee extract (Patent Document 1, Patent Document 2, etc.), a method of adding an organic acid salt ( Various methods such as Patent Document 3, Patent Document 4, and Patent Document 5) and a method of adding a trialkali metal phosphate (Patent Document 6) have been studied. However, the treatment is complicated and unsuitable for industrial coffee production, and the effect of suppressing gel-like precipitation is not yet sufficient, adversely affecting the flavor of canned coffee, and precipitation even during long-term storage. The method that does not occur was not known.
また、酸を添加することより、沈殿やフロックを生じさせ、それを除去することによりコーヒー抽出液を処理する方法も知られている(特許文献7、特許文献8、特許文献9、特許文献10等)。しかし、この方法は、酸を添加することによりpHを低くし、沈殿物を生成させ、それを除去することにより、沈殿のない安定なコーヒー抽出液を得るというものである。 Moreover, the method of processing a coffee extract by producing precipitation and floc by adding an acid and removing it is also known (patent document 7, patent document 8, patent document 9, patent document 10). etc). However, in this method, the pH is lowered by adding an acid, a precipitate is formed, and the precipitate is removed to obtain a stable coffee extract having no precipitate.
一方、本格化志向より、缶コーヒーにもコーヒーリッチなものが求められるようになっているが、これら市場のニーズに反して、前記のような問題点よりコーヒーの含有量をそれ以上増やせないといった状況にある。 On the other hand, since the trend toward full-scale production, canned coffee is required to be rich in coffee, but contrary to the needs of these markets, the content of coffee cannot be increased further due to the above problems. Is in the situation.
このように、従来のコーヒー分及び乳成分を多く含む乳成分含有コーヒー飲料は、その製造工程での過酷な殺菌処理等によるゲル状沈殿等のため、長期間の品質保持が困難であり、安定した品質を有する商品の提供ができないといった問題を有しており、これらの改善、解決が強く望まれていた。 As described above, conventional dairy ingredient-containing coffee beverages containing a large amount of coffee and dairy ingredients are difficult to maintain for a long period of time due to gel-like precipitation due to severe sterilization treatment in the production process, and are stable. Therefore, there is a problem that it is impossible to provide a product having the improved quality.
本発明は、かかる事情に鑑みて開発されたもので、製造工程及び長期保存によっても、ゲル状沈殿を生じず、リングもなく安定して長期にわたり品質が保持されてなる密封容器入り乳成分含有コーヒー飲料を提供することを目的とするものである。更に、本発明は、製造工程の殺菌処理によっても品質を損なわず、長期保存においても良好な品質を保ち得る上記密封容器入り乳成分含有コーヒー飲料の製造方法を提供することを目的とする。 The present invention has been developed in view of such circumstances, and does not cause gel-like precipitation even during the manufacturing process and long-term storage, and contains milk components in a sealed container in which quality is stably maintained over a long period without a ring. The purpose is to provide a coffee drink. Furthermore, this invention aims at providing the manufacturing method of the said milk component containing coffee component containing a sealed container which does not impair quality also by the sterilization process of a manufacturing process, and can maintain favorable quality also in long-term storage.
本発明者らは、上記従来技術の問題点に鑑み鋭意研究を重ねていたところ、偶然にも、生豆換算5%以上のコーヒー分及び無脂乳固形分換算で0.8%以上の乳成分を含む密封容器入り乳成分含有コーヒー飲料の製造に際して、乳成分の量や添加する炭酸水素ナトリウムの添加量に応じて、特定の有機酸及び又は無機酸、好ましくはクエン酸を、適宜添加量を調整して添加することにより、コーヒー分及び乳成分の多く含む系のコーヒー飲料であってもゲル状沈殿を生じず、さらには長期保存によってもゲル状沈殿が起こらないことを見いだした。 The inventors of the present invention have made extensive studies in view of the above-mentioned problems of the prior art. As a result, by chance, the coffee content of 5% or more in terms of green beans and the milk of 0.8% or more in terms of solid content of non-fat milk are coincidental. When producing a milk component-containing coffee beverage in a sealed container containing the components, depending on the amount of the milk component and the amount of sodium bicarbonate to be added, a specific organic acid and / or inorganic acid, preferably citric acid, is appropriately added. It was found that no gel-like precipitation occurs even in a coffee beverage containing a large amount of coffee and milk components, and further no gel-like precipitation occurs even after long-term storage.
そして、さらに研究を重ねることにより、殺菌処理前に、コーヒー調合液中に特定の有機酸や無機酸と、炭酸水素ナトリウムとを共存させておくことが、ゲル状沈殿発生のに有効であることを確認して本発明を完成するに至った。 And by further research, it is effective for the occurrence of gel-like precipitation to have a specific organic acid or inorganic acid and sodium hydrogen carbonate coexist in the coffee preparation before the sterilization treatment. As a result, the present invention was completed.
なお、本発明において「ゲル状沈殿を実質的に含有しない」とは、コーヒー溶液を目視によって観察した場合に、白色〜茶褐色の軟らかなゲル状の沈殿の存在が認められないことを意味する。 In the present invention, “substantially free of gel-like precipitate” means that the presence of a soft gel-like precipitate of white to brown color is not observed when the coffee solution is visually observed.
本発明により、製造工程及び長期保存によっても、ゲル状沈殿を生じず、リングもなく安定して長期にわたり品質が保持されてなる密封容器入り乳成分含有コーヒー飲料を提供できるようになった。 According to the present invention, it has become possible to provide a milk component-containing coffee beverage in a sealed container that does not cause gel-like precipitation even in the production process and is stored for a long period of time, and has no ring, and the quality is stably maintained over a long period of time.
本発明の対象となるコーヒー飲料は、生豆換算5%以上のコーヒー分及び無脂乳固形分換算で0.8%以上の乳成分を含有する、コーヒー含量及び乳成分含量が高い密封容器入り乳成分含有コーヒー飲料である。 The coffee beverage that is the subject of the present invention contains a coffee container with a high coffee content and a high milk component content, containing a coffee component of 5% or more in terms of green beans and a milk component of 0.8% or more in terms of solid content of non-fat milk It is a milk component-containing coffee drink.
本発明において「生豆換算〜%」とは、乳成分含有コーヒー飲料の内容量100重量部中に含まれるコーヒー含量を表すものであり、例えば「生豆換算5%のコーヒー分を含有する」とは、内容量100重量部中にコーヒー豆から抽出又は溶出したコーヒー分をコーヒー生豆量に換算して5重量部含むことをいう。 In the present invention, “green beans equivalent to%” represents the coffee content contained in 100 parts by weight of the content of the milk component-containing coffee beverage. For example, “contains a coffee content of 5% green beans” The term “contains 5 parts by weight of a coffee component extracted or eluted from coffee beans in an amount of 100 parts by weight in terms of the amount of green coffee beans”.
また「密封容器」とは、乳成分含有コーヒー飲料を充填後、密封・密閉するものであれば特に限定されず、具体的には缶、ビン、紙パック、ペットボトル、ラミネートパック等、種々の保存容器が例示される。 The “sealed container” is not particularly limited as long as it is sealed and sealed after filling with a milk component-containing coffee beverage. Specifically, various kinds of cans, bottles, paper packs, plastic bottles, laminate packs, etc. A storage container is illustrated.
本発明で用いられるコーヒーは、豆の種類、品質、焙煎方法、焙煎度合等によって特に制限されず、また、コーヒ−豆から直接抽出されたものの他、インスタントコーヒー、コーヒーエキスを用いてもよい。豆の種類としては、アラビカ種、ロブスタ種、リベリア種などの原料樹に由来するものが例示されるが、特に、ロブスタ種を用いる場合はゲル状沈殿を発生しやすく、また焙煎後の粉砕粒度が小さいほどゲル状沈殿が発生しやすいという傾向があり、このような場合に本発明の効果が特に有用となる。 The coffee used in the present invention is not particularly limited by the type, quality, roasting method, roasting degree, etc. of the bean, and it is possible to use instant coffee or coffee extract in addition to those extracted directly from coffee beans. Good. Examples of bean types include those derived from raw tree such as Arabica, Robusta, Liberia, etc. Especially when Robusta is used, gel-like precipitation is likely to occur, and grinding after roasting The smaller the particle size, the more likely the gel-like precipitation occurs. In such a case, the effect of the present invention is particularly useful.
次に、本発明のコーヒ−飲料に含有される乳成分とは、牛乳及びその加工品であり、加工品としては、例えば全脂練乳、脱脂練乳、全脂粉乳、脱脂粉乳、生クリームなどが挙げられる。これらは単独もしくは2種以上を組み合わせて使用される。乳成分のコーヒー飲料に対する含有量は、通常は、無脂乳固形分で0.8重量%以上、好ましくは、0.8〜5重量%の範囲である。 Next, the milk component contained in the coffee beverage of the present invention is milk and processed products thereof, and examples of processed products include full-fat condensed milk, defatted condensed milk, full-fat powdered milk, defatted powdered milk, and fresh cream. Can be mentioned. These are used alone or in combination of two or more. The content of the milk component in the coffee beverage is usually 0.8% by weight or more, preferably in the range of 0.8 to 5% by weight in terms of the non-fat milk solid content.
本発明に係る乳成分含有コーヒー飲料は、前記の通りコーヒー分及び乳成分含量が高いコーヒー飲料であって、クエン酸、リンゴ酸、酒石酸、乳酸及びリン酸から選ばれる1種又は2種以上(以下「特定有機酸及び又は無機酸」という)を0.005〜0.2重量%、及び炭酸水素ナトリウムを0.075〜0.25重量%含有することにより、ゲル状沈殿を実質的に含有しない密封容器入り乳成分含有コーヒー飲料となることが特徴である。本発明では、別途沈殿を起こさせてそれを除去するという工程が必要なく、前記特定有機酸及び又は無機塩を一定量添加すると、ゲル状沈殿の起こらない安定なコーヒー飲料が得られるものである。
The milk component-containing coffee beverage according to the present invention is a coffee beverage having a high coffee content and a high milk component content as described above, and one or more selected from citric acid, malic acid, tartaric acid, lactic acid and phosphoric acid ( (Hereinafter referred to as “specific organic acid and / or inorganic acid”) in an amount of 0.005 to 0.2% by weight and sodium bicarbonate in an amount of 0.075 to 0.25% by weight, thereby substantially containing a gel-like precipitate. It is characterized in that it becomes a milk beverage containing a milk component in a sealed container. In the present invention, there is no need for a step of separately causing precipitation and removing it, and when a certain amount of the specific organic acid and / or inorganic salt is added, a stable coffee beverage that does not cause gel precipitation is obtained. .
本発明は、クエン酸、リンゴ酸、酒石酸、乳酸及びリン酸から選ばれる1種又は2種以上を使用することが特徴であり、中でも、クエン酸、リンゴ酸、酒石酸、乳酸及びリン酸から選ばれる1種又は2種以上が挙げられる。これら特定有機酸及び無機酸から選ばれる1種又は2種以上を適宜選択して用いることができるが、更に好ましくは、クエン酸を用いるのがよい。 The present invention is characterized by using one or more selected from citric acid, malic acid, tartaric acid, lactic acid and phosphoric acid , and among them, selected from citric acid, malic acid, tartaric acid, lactic acid and phosphoric acid. 1 type, or 2 or more types. One or more selected from these specific organic acids and inorganic acids can be appropriately selected and used, but citric acid is more preferably used.
なお、本発明の乳成分含有コーヒー飲料に添加される特定有機酸及び又は無機酸の量は、添加する乳成分及び炭酸水素ナトリウムの量にて後述の通り調整するのが好ましい。以下、その態様について説明する。 It should be noted that the amount of the specific organic acid and / or inorganic acid added to the milk component-containing coffee beverage of the present invention is preferably adjusted as described later by the amount of the milk component and sodium bicarbonate added. Hereinafter, the aspect is demonstrated.
1)乳成分を無脂乳固形分換算で1〜2%と比較的高含量含み、また、コーヒー分を生豆換算7〜10%と多く含む場合には、炭酸水素ナトリウムを0.125〜0.2重量%含有する必要がある。その場合、特定有機酸及び又は無機酸を0.03〜0.2重量%、好ましくは、0.03〜0.1重量%、より好ましくは、0.03〜0.05重量%含有することが好ましい。 1) When the milk component contains a relatively high content of 1 to 2% in terms of non-fat milk solids, and when the coffee component contains a large amount of 7 to 10% in terms of green beans, sodium bicarbonate is added at 0.125 to It is necessary to contain 0.2% by weight. In that case, 0.03-0.2% by weight, preferably 0.03-0.1% by weight, more preferably 0.03-0.05% by weight of the specific organic acid and / or inorganic acid is contained. Is preferred.
2)乳成分を無脂乳固形分換算で1〜2%と比較的多く含み、また、コーヒー分を生豆換算5〜7%程度の添加量である場合には、炭酸水素ナトリウムを0.075〜0.125重量%程度の添加量でよい。その場合、特定有機酸及び又は無機酸を0.005〜0.2重量%、好ましくは、0.01〜0.1重量%、より好ましくは、0.01〜0.05重量%含有することが好ましい。 2) When the milk component is relatively large as 1 to 2% in terms of non-fat milk solid content and the coffee content is about 5 to 7% in terms of green beans, sodium bicarbonate is added in an amount of 0.00. The addition amount may be about 075 to 0.125% by weight. In that case, the specific organic acid and / or inorganic acid is contained in an amount of 0.005 to 0.2% by weight, preferably 0.01 to 0.1% by weight, more preferably 0.01 to 0.05% by weight. Is preferred.
3)乳成分を無脂乳固形分換算で0.8〜1%程度の比較的少量の添加量である場合の炭酸水素ナトリウムの添加量は0.075〜0.2重量%である。その場合、特定有機酸及び又は無機酸を0.005〜0.2重量%、好ましくは、0.01〜0.1重量%、より好ましくは、0.03〜0.05重量%添加するのが好ましい。 3) The amount of sodium bicarbonate added is 0.075 to 0.2% by weight when the milk component is added in a relatively small amount of about 0.8 to 1% in terms of non-fat milk solid content. In that case, the specific organic acid and / or inorganic acid is added in an amount of 0.005 to 0.2% by weight, preferably 0.01 to 0.1% by weight, more preferably 0.03 to 0.05% by weight. Is preferred.
このように、乳成分及び炭酸水素ナトリウムの含有量により、適宜特定有機酸及び又は無機酸の含有量を調整する。その含有量が少なすぎると、沈殿の生成を抑制する効果が不十分となり、逆に多すぎると酸自体の味が感じられるようになり、それを好まない人もでてくるため、これらを勘案して前記の適当な範囲に設定することが好ましくなるからである。 Thus, content of a specific organic acid and / or an inorganic acid is suitably adjusted with content of a milk component and sodium hydrogencarbonate. If the content is too small, the effect of suppressing the formation of precipitates will be insufficient, and conversely if it is too large, the taste of the acid itself will be felt, and some people will not like it. This is because it is preferable to set the value within the appropriate range.
なお、本発明の乳成分含有コーヒー飲料には、上記の原料の他に、食品の分野で広く用いられている糖類、香料、中和剤、カラメル、乳化剤、食塩、食用油脂、安定剤、酸化防止剤、保存料、色素などが含まれていてもよい。また、本発明の乳成分含有コーヒー飲料はpH5.5〜8.0、好ましくはpH5.8〜6.8、より好ましくはpH6.4〜6.6の範囲で調整されていることが望ましい。 In addition to the above ingredients, the milk component-containing coffee beverage of the present invention includes sugars, fragrances, neutralizers, caramels, emulsifiers, salt, edible oils and fats, stabilizers, stabilizers that are widely used in the field of food. Inhibitors, preservatives, pigments and the like may be included. In addition, the milk component-containing coffee beverage of the present invention is desirably adjusted in the range of pH 5.5 to 8.0, preferably pH 5.8 to 6.8, and more preferably pH 6.4 to 6.6.
本発明の乳成分含有コーヒー飲料は、生豆換算5%以上の高濃度のコーヒー分及び無脂乳固形分換算で0.8%以上の乳成分といった、比較的コーヒー分及び乳成分を多く含む系であっても、製造工程で過酷な条件で殺菌してもゲル状沈殿を生じず品質を損なうことなく、また高温で長期保存してもゲル状沈殿が発生することなく、安定状態を維持することができる。 The milk component-containing coffee beverage of the present invention contains a relatively large amount of coffee and milk components such as a high concentration coffee component of 5% or more in terms of green beans and a milk component of 0.8% or more in terms of solid content of non-fat milk. Even if it is a system, even if it is sterilized under severe conditions in the manufacturing process, it does not cause gel-like precipitation and does not impair quality. can do.
ゲル状沈殿は、まず製造工程中の加熱殺菌処理で生じるものであるため、上記の効果を十分発揮するためには、本発明の乳成分含有コーヒー飲料は、殺菌処理より前にコーヒー調合液に特定有機酸及び又は無機酸と炭酸水素ナトリウムを添加してから、これらを含む存在下で殺菌処理され製造されることが好ましい。 Since the gel-like precipitation is first caused by heat sterilization during the manufacturing process, the milk component-containing coffee beverage of the present invention is applied to the coffee preparation before the sterilization in order to fully exhibit the above effects. It is preferable that a specific organic acid and / or inorganic acid and sodium hydrogen carbonate are added and then sterilized and produced in the presence of these.
かかる観点から、本発明はまた、製造工程においても沈殿を生じず、また商品として長期保存した場合でも沈殿を生じない品質安定性に優れた商品価値の高い密封容器入り乳成分含有コーヒー飲料の製造方法を提供するものである。 From this point of view, the present invention also produces a milk component-containing coffee beverage in a sealed container having a high commercial value, which does not cause precipitation even in the production process and does not cause precipitation even when stored as a product for a long period of time. A method is provided.
一般に密封容器入り乳成分含有コーヒー飲料は、コーヒー抽出液及び乳原料等の十分な混合溶解、水配合による調整、均質機での均質化、例えばプレートヒーター上での加温、密封容器への注入・充填、巻締め、殺菌処理及び冷却といった一連の工程により製造される。 Generally, a milk beverage containing a milk component in a sealed container is sufficient for mixing and dissolving the coffee extract and milk ingredients, adjusting with water, homogenizing with a homogenizer, eg heating on a plate heater, pouring into a sealed container -Manufactured by a series of processes such as filling, winding, sterilization and cooling.
本発明は、この製造工程中、殺菌処理を、特定有機酸及び又は無機酸と炭酸水素ナトリウムとの存在下で行うことを特徴とする、生豆換算5%以上のコーヒー分及び無脂乳固形分換算で0.8%以上の乳成分を含有する密封容器入り乳成分含有コーヒー飲料の製造方法である。本発明の方法は、殺菌処理前に、コーヒー調合液に、有機酸及び又は無機塩と、炭酸水素ナトリウムとを配合し、その条件下で殺菌処理を行うことにより達成される。 The present invention is characterized in that during this production process, sterilization is performed in the presence of a specific organic acid and / or inorganic acid and sodium hydrogen carbonate, and the coffee content and nonfat milk solids of 5% or more in terms of green beans This is a method for producing a milk component-containing coffee beverage in a sealed container containing a milk component of 0.8% or more in terms of minutes. The method of this invention is achieved by mix | blending an organic acid and / or an inorganic salt, and sodium hydrogencarbonate with a coffee liquid preparation before sterilization treatment, and performing a sterilization treatment on the conditions.
これらの、特定有機酸及び又は無機酸と、炭酸水素ナトリウムとを配合する工程・時期は、殺菌処理前であれば特に規定されず、特定有機酸及び又は無機酸と炭酸水素ナトリウムとが少なくとも殺菌処理時にコーヒー調合液中に含まれていればよい。殺菌処理は、上記条件を満たせば、殺菌条件や殺菌装置等によって特に制限されず、一般的に使用される殺菌条件が広く採用できる。通常は、約120〜125℃で約20〜40分処理するレトルト殺菌が用いられるが、特にこれに限定されず、プレート殺菌、オートクレーブ殺菌等、食品に採用される種々の殺菌処理を挙げることができる。 The process / timing of blending the specific organic acid and / or inorganic acid and sodium hydrogen carbonate is not particularly defined as long as it is before sterilization treatment, and the specific organic acid and / or inorganic acid and sodium hydrogen carbonate are at least sterilized. What is necessary is just to be contained in the coffee compounding liquid at the time of a process. The sterilization treatment is not particularly limited by sterilization conditions, sterilization apparatuses, or the like as long as the above conditions are satisfied, and generally used sterilization conditions can be widely adopted. Usually, retort sterilization that is performed at about 120 to 125 ° C. for about 20 to 40 minutes is used. it can.
また、コーヒー調合液には、特定有機酸及び又は無機酸及び炭酸水素ナトリウム以外にコーヒー抽出液(もしくはインスタントコーヒー、コーヒーエキス)及び乳原料が含有されてればよいが、その他に糖類、増粘多糖類、乳化剤、中和剤、カラメル、香料、食塩、食用油脂、安定剤、酸化防止剤、保存料、色素、酸味料などが含まれていてもよい。 In addition to the specific organic acid and / or inorganic acid and sodium hydrogen carbonate, the coffee preparation liquid may contain a coffee extract (or instant coffee, coffee extract) and a milk raw material. Polysaccharides, emulsifiers, neutralizers, caramels, fragrances, salt, edible oils and fats, stabilizers, antioxidants, preservatives, pigments, acidulants and the like may be included.
糖類としては、砂糖、果糖、ブドウ糖、水飴、還元水飴、はちみつ、異性化糖、転化糖、オリゴ糖(イソマルトオリゴ糖、還元キシロオリゴ糖、還元ゲンチオオリゴ糖、キシロオリゴ糖、ゲンチオオリゴ糖、ニゲロオリゴ糖、テアンデオリゴ糖、大豆オリゴ糖等)、トレハロース、糖アルコール(マルチトール、エリスリトール、ソルビトール、パラチニット、キシリトール、ラクチトール等)、砂糖結合水飴(カップリングシュガー)等をあげることができる。 Sugars include sugar, fructose, glucose, starch syrup, reduced starch syrup, honey, isomerized sugar, invert sugar, oligosaccharide (isomalto-oligosaccharide, reduced xylo-oligosaccharide, reduced gentio-oligosaccharide, xylo-oligosaccharide, gentio-oligosaccharide, nigerooligosaccharide, theande-oligosaccharide And soy oligosaccharides), trehalose, sugar alcohols (maltitol, erythritol, sorbitol, palatinit, xylitol, lactitol, etc.), sugar-bound starch syrup (coupling sugar), and the like.
また、従来公知若しくは将来知られ得る甘味成分も糖類の代わりに用いることができ、具体的には、アスパルテーム、アセスルファムカリウム、スクラロース、アリテーム、ネオテーム、カンゾウ抽出物(グリチルリチン)、サッカリン、サッカリンナトリウム、ステビア抽出物、ステビア末、等の甘味成分を用いてもよい。 In addition, conventionally known or future known sweetening ingredients can also be used in place of saccharides, specifically, aspartame, acesulfame potassium, sucralose, alitame, neotame, licorice extract (glycyrrhizin), saccharin, saccharin sodium, stevia extract Sweet ingredients such as foods and stevia powder may be used.
増粘多糖類としては、乳飲料に一般的に用いられている増粘多糖類であればよい。具体的には、カラギナン(イオタ、ラムダ、カッパ)、キサンタンガム、アラビアガム、グァーガム、ローカストビーンガム、タラガム、ジェランガム、ネイティブ型ジェランガム、カルボキシルメチルセルロース、発酵セルロース、水溶性大豆多糖類等を挙げることができ、これらから選ばれる1種又は2種以上の増粘多糖類を使用することができる。 The thickening polysaccharide may be any thickening polysaccharide generally used in milk beverages. Specific examples include carrageenan (iota, lambda, kappa), xanthan gum, gum arabic, guar gum, locust bean gum, tara gum, gellan gum, native gellan gum, carboxymethylcellulose, fermented cellulose, water-soluble soybean polysaccharide, etc. 1 type, or 2 or more types of thickening polysaccharide chosen from these can be used.
乳化剤は一般的に用いられているものでよく、具体的には、カゼインナトリウム、グリセリン脂肪酸エステル(モノグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル、有機酸モノグリセライド、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル)、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸塩(ナトリウム塩、カルシウム塩)、ユッカ抽出物、サポニン、レシチン、ポリソルベート等を挙げることができる。 The emulsifier may be a commonly used one. Specifically, sodium caseinate, glycerin fatty acid ester (monoglycerin fatty acid ester, diglycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester. ), Sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, stearoyl lactate (sodium salt, calcium salt), yucca extract, saponin, lecithin, polysorbate and the like.
加熱殺菌処理時のコーヒー調合液のpHは、殺菌後の製品がpH5.5〜8程度の範囲、好ましくはpH5.8〜6.8程度 、より好ましくはpH6.4〜6.6程度の範囲になるように適宜調整されればよいが、具体的な加熱殺菌処理時のpHとしては、通常pH5.5〜8.5程度の範囲、好ましくはpH5.8〜7.3程度の範囲、より好ましくはpH6.4〜7.1程度の範囲が挙げられる。 The pH of the coffee mixture at the time of the heat sterilization is such that the product after sterilization is in the range of about pH 5.5 to 8, preferably about 5.8 to 6.8, more preferably about 6.4 to 6.6. The pH during the specific heat sterilization treatment is usually in the range of about pH 5.5 to 8.5, preferably in the range of about pH 5.8 to 7.3. Preferably, the range of about pH 6.4-7.1 is mentioned.
本発明により、比較的コーヒー分及び乳成分の多い密封容器入り乳成分含有コーヒー飲料であってもゲル状沈殿を生じず、さらには長期保存によってもゲル状沈殿及びリングが起こらなくなった。また、製造工程で過酷な条件で殺菌してもゲル状沈殿を生じず品質を損なうことなく、また高温で長期保存してもリングやゲル状沈殿が発生することなく、安定状態を維持することができるようになった。 According to the present invention, gelled precipitation does not occur even in a milk component-containing coffee beverage in a sealed container having a relatively large coffee content and milk component, and further, gelled precipitation and ring do not occur even after long-term storage. In addition, even if sterilized under harsh conditions in the manufacturing process, it does not cause gel precipitation and does not impair quality, and even when stored at high temperatures for a long period of time, it maintains a stable state without ring or gel precipitation. Can now.
以下、本発明の内容を以下の実施例、比較例を用いて具体的に説明するが、本発明はこれらに何ら限定されるものではない。また、特に記載のない限り「部」とは、「重量部」を意味するものとする。文中「*」印のものは、三栄源エフ・エフ・アイ株式会社製、文中「※」印は三栄源エフ・エフ・アイ株式会社の登録商標であることを示す。 Hereinafter, the content of the present invention will be specifically described with reference to the following examples and comparative examples, but the present invention is not limited thereto. Unless otherwise specified, “parts” means “parts by weight”. Those marked with “*” in the text indicate that they are registered trademarks of San-Ei Gen FFI Co., Ltd., and “*” marks in the text indicate that they are registered trademarks of San-Ei Gen FFI Co., Ltd.
実験例1:ミルクコーヒーの調製
下記ミルクコーヒー処方のうち、粗挽きしたL値18コーヒー豆に、6倍量の95℃熱湯を加え、濾過を行った後、10分後、得られたコーヒーエキスをもう一度コーヒー豆に加え、濾過する。更に20℃まで冷却し、ダブルドリップのコーヒーエキスを調製した。このコーヒーエキスに、表1に掲げる有機酸(クエン酸;実施例1)、クエン酸三ナトリウム(比較例1)、リン酸塩(比較例2)を添加混合しておく。
Experimental Example 1: Preparation of milk coffee Among the following milk coffee formulas, 6 times the amount of 95 ° C hot water was added to coarsely ground L value 18 coffee beans, filtered, and 10 minutes later, the obtained coffee extract Is added to the coffee beans again and filtered. Furthermore, it cooled to 20 degreeC and prepared the coffee extract of a double drip. To this coffee extract, an organic acid listed in Table 1 (citric acid; Example 1), trisodium citrate (Comparative Example 1), and phosphate (Comparative Example 2) are added and mixed.
また、乳化剤を、乳化剤の10倍量の55℃イオン交換水に加え、加熱して、80℃10分間加熱溶解後、室温まで冷却して乳化剤溶液を調製した。また、砂糖と等量のイオン交換水を秤量し激しく攪拌しながら、砂糖を加え、加熱し、50℃10分間加熱攪拌溶解後、室温まで冷却し、全量調整して、砂糖溶液を調製した。 Further, the emulsifier was added to 55 ° C. ion-exchanged water, 10 times the amount of the emulsifier, heated, heated and dissolved at 80 ° C. for 10 minutes, and then cooled to room temperature to prepare an emulsifier solution. Moreover, sugar was added while heating and stirring and dissolving at 50 ° C. for 10 minutes, followed by cooling to room temperature and adjusting the total amount to prepare a sugar solution.
調製した乳化剤溶液に牛乳を添加混合して、予め調製した砂糖溶液及び10%炭酸水素ナトリウム溶液を加え、更に予め調製した前記コーヒーエキスを加え、イオン交換水にて全量補正したのち、混合したコーヒー調合液を70℃まで加温し、更に全量補正して、150/50(トータル200)kg/cm2にてホモゲナイズし、缶容器に充填密封後、123℃20分間レトルト殺菌して、缶入りミルクコーヒーを調製した(無脂乳固形分換算1.6%)。 After adding milk to the prepared emulsifier solution, adding the sugar solution and 10% sodium bicarbonate solution prepared in advance, adding the coffee extract prepared in advance, correcting the total amount with ion-exchanged water, and mixing the coffee Heat the preparation to 70 ° C, correct the total amount, homogenize at 150/50 (total 200) kg / cm 2 , fill and seal the can, retort sterilize at 123 ° C for 20 minutes, and fill the can Milk coffee was prepared (non-fat milk solid content conversion 1.6%).
ミルクコーヒー飲料処方 部
粗挽きコーヒー豆(L値:焙煎度18、生豆換算) 7.1
砂糖 6
牛乳 20
乳化剤(ホモゲン※NO.1511*) 0.18
10%炭酸水素ナトリウム溶液 1
クエン酸/クエン酸三ナトリウム/リン酸3ナトリウム/リン酸 表1記載
清水にて 100
Milk coffee beverage prescription part coarsely ground coffee beans (L value: roasting degree 18, raw beans equivalent) 7.1
Sugar 6
Milk 20
Emulsifier (homogen * NO.1511 *) 0.18
10% sodium bicarbonate solution 1
Citric acid / trisodium citrate / trisodium phosphate / phosphoric acid listed in Table 1 in fresh water 100
得られた実施例及び比較例のミルクコーヒーを、60℃で2週間保存し、保存後のゲル状沈殿物の状態をみた。なお、ゲル状沈殿物の定義として、乳成分含有コーヒー飲料をレトルト殺菌(121℃以上、15分以上)を行い製造したものであり、保存中に生じる弱いゲル状の沈殿物のことを言う。ゲル状沈殿物の状態として、沈殿率を求めて示すこととした。沈殿率(%)=((缶と缶の底にたまっている沈殿の重さ)―(缶の重さ))/((缶とコーヒー(沈殿を含む)の重さ)―(缶の重さ))×100の値を求めた。結果を表1に記す。ゲル状沈殿物が多いほど、沈殿率の値は高くなる。 The obtained milk coffee of Examples and Comparative Examples was stored at 60 ° C. for 2 weeks, and the state of gel-like precipitate after storage was observed. In addition, as a definition of a gel-like precipitate, a milk component-containing coffee beverage is produced by retort sterilization (121 ° C. or more, 15 minutes or more), and refers to a weak gel-like precipitate generated during storage. As the state of the gel precipitate, the precipitation rate was determined and shown. Precipitation rate (%) = ((Weight of precipitation accumulated in can and bottom of can)-(Weight of can)) / (Weight of can and coffee (including precipitation))-(Weight of can )) X100 was determined. The results are shown in Table 1. The more gelled precipitate, the higher the precipitation rate value.
クエン酸とリン酸3ナトリウムの効果について比較する。表1より、実1−2と比較例1−1は、クエン酸とリン酸3ナトリウムを同量添加しているが、クエン酸添加品である実施例1−2のミルクコーヒーの方が、ゲル状沈殿物生成を抑制する効果が明らかに高かった。 Compare the effects of citric acid and trisodium phosphate. From Table 1, in Example 1-2 and Comparative Example 1-1, citric acid and trisodium phosphate are added in the same amount, but the milk coffee of Example 1-2, which is a citric acid-added product, The effect of suppressing the formation of gel-like precipitate was obviously high.
次に、クエン酸とクエン酸3ナトリウムを比較した。実1−2及び比1−2は、添加量を同量としたが、クエン酸添加品の実施例1−2のコーヒー飲料が、ゲル状沈殿物生成を抑制する効果が明らかに高かった。 Next, citric acid and trisodium citrate were compared. Although the actual amount 1-2 and the ratio 1-2 were the same amount, the citric acid-added product of Example 1-2 coffee beverage clearly had a high effect of suppressing the formation of gel-like precipitate.
また、実1−2及び比1−3は、クエン酸とクエン酸3ナトリウムのクエン酸イオンを同量含む品の比較であるが、クエン酸添加品の実1−2のコーヒー飲料が、ゲル状沈殿物生成を抑制する効果が明らかに高かった。 In addition, the actual 1-2 and the ratio 1-3 are comparisons of products containing the same amount of citric acid and trisodium citrate citrate ions. The effect of suppressing the formation of stagnate precipitate was obviously high.
更に、実1−2及び比1−4は、クエン酸とクエン酸3ナトリウムのナトリウムイオンを同量含む品の比較であるが、クエン酸添加品の実1−2のコーヒー飲料が、ゲル状沈殿物生成を抑制する効果が明らかに高かった。 Furthermore, the actual 1-2 and the ratio 1-4 are comparisons of products containing the same amount of citric acid and trisodium citrate sodium ions. The effect of suppressing the precipitate formation was obviously high.
実験例2
表2〜3のとおりにクエン酸と重曹(炭酸水素ナトリウム)の添加量を代えた以外は実験例1と同様にして、ミルクコーヒーを調製し(無脂乳固形分換算1.6%)、60℃2週間、37℃4週間及び常温(25℃)4週間で保存後のゲル状沈殿物の状態を沈殿率で見た。結果を表2〜3に示す。
Experimental example 2
Milk coffee was prepared in the same manner as in Experimental Example 1 except that the addition amounts of citric acid and sodium bicarbonate (sodium bicarbonate) were changed as shown in Tables 2 to 3 (1.6% in terms of nonfat milk solid content), The state of the gel-like precipitate after storage at 60 ° C. for 2 weeks, 37 ° C. for 4 weeks and room temperature (25 ° C.) for 4 weeks was observed in terms of the precipitation rate. The results are shown in Tables 2-3.
表2〜3より、重曹(炭酸水素ナトリウム)の添加量が低すぎると(500ppm、実2−1〜9)。クエン酸の添加によるゲル状沈殿物生成を抑制する効果は低かった。また、重曹の添加量が1000ppmの時、クエン酸の添加量が50ppm以上で明らかなゲル状沈殿物生成を抑制する効果が見られた(実2−10〜18)。更に、重曹の添加量が1250ppmでは、重曹の添加量が100ppm以上でゲル状沈殿物生成を抑制する効果が見られた(実2−28〜36)。また、1500ppm、2000ppmであると、クエン酸の添加量が50〜10ppm程度では、ゲル状沈殿物生成を抑制する効果は低く、150ppm以上でゲル状沈殿物生成を抑制する効果が見られ、300ppmで更に良好であった。しかし、クエン酸の添加量を増やしすぎると(2000〜3000ppm)少量のゲル状沈殿物が見られた(実2−37〜54)。 From Tables 2-3, when the addition amount of sodium hydrogencarbonate (sodium hydrogencarbonate) is too low (500 ppm, actual 2-1-9). The effect of suppressing the formation of gel-like precipitates by the addition of citric acid was low. Moreover, when the addition amount of sodium bicarbonate was 1000 ppm, the effect of suppressing the apparent gel-like precipitate formation was seen when the addition amount of citric acid was 50 ppm or more (actual 2-10 to 18). Furthermore, when the addition amount of sodium bicarbonate was 1250 ppm, the effect of suppressing the formation of gel-like precipitate was observed when the addition amount of sodium bicarbonate was 100 ppm or more (ex. 2-28 to 36). Further, when the addition amount of citric acid is about 1500 ppm and 2000 ppm, the effect of suppressing the formation of gel-like precipitate is low, and the effect of suppressing the formation of gel-like precipitate is seen at 150 ppm or more. It was even better. However, when the amount of citric acid added was excessively increased (2000 to 3000 ppm), a small amount of gel-like precipitate was observed (actual 2-37 to 54).
実験例3
表4のとおりにクエン酸と重曹(炭酸水素ナトリウム)の添加量を代えた以外は、実験例1と同様にして、ミルクコーヒーを調製し、60℃2週間、37℃4週間及び常温(25℃)4週間で保存後のゲル状沈殿物の状態を沈殿率で見た。結果を表4に示す。
Experimental example 3
Milk coffee was prepared in the same manner as in Experimental Example 1 except that the addition amounts of citric acid and sodium bicarbonate (sodium bicarbonate) were changed as shown in Table 4, and 60 ° C for 2 weeks, 37 ° C for 4 weeks, and room temperature (25 C.) The state of the gel-like precipitate after storage for 4 weeks was observed in terms of the precipitation rate. The results are shown in Table 4.
表4より、クエン酸と同様に、リンゴ酸、乳酸、酒石酸、リン酸を使用しても、クエン酸と同等のゲル状沈殿物生成を抑制する効果が得られた。 From Table 4, even if malic acid, lactic acid, tartaric acid, and phosphoric acid were used similarly to citric acid, the effect of suppressing gel-like precipitate formation equivalent to citric acid was obtained.
実験例4
下記ミルクコーヒー処方を以下のように調製してミルクコーヒーを得る。即ち、粗挽きしたL値28.7のコーヒー豆に、6倍量の95℃熱湯を加え、濾過を行った後、10分後、得られたコーヒーエキスをもう一度コーヒー豆に加え、濾過する。更に20℃まで冷却し、ダブルドリップのコーヒーエキスを調製した。このコーヒーエキスに表5〜6に掲げる添加量クエン酸を添加混合しておく。
Experimental Example 4
The following milk coffee formula is prepared as follows to obtain milk coffee. That is, 6 times the amount of 95 ° C. hot water is added to coarsely ground L value 28.7 coffee beans, and after filtration, 10 minutes later, the obtained coffee extract is added again to the coffee beans and filtered. Furthermore, it cooled to 20 degreeC and prepared the coffee extract of a double drip. Addition amount citric acid listed in Tables 5 to 6 is added to and mixed with this coffee extract.
また、乳化剤を55℃に調整した乳化剤の10倍量のイオン交換水に加え、加熱して、80℃10分間加熱溶解後、室温まで冷却して乳化剤溶液を調製した。また、砂糖と等量のイオン交換水を秤量し激しく攪拌しながら、砂糖を加え、加熱し50℃10分間加熱攪拌溶解後、室温まで冷却し、全量調整して、砂糖溶液を調製した。 Further, an emulsifier was added to 10 times the amount of ion-exchanged water adjusted to 55 ° C., heated, dissolved by heating at 80 ° C. for 10 minutes, and then cooled to room temperature to prepare an emulsifier solution. Moreover, sugar was added while weighing ion-exchange water equal in amount to sugar and stirring vigorously, heated, dissolved by stirring with heating at 50 ° C. for 10 minutes, cooled to room temperature, and adjusted to the total amount to prepare a sugar solution.
乳化剤溶液に牛乳及び脱脂粉乳溶液を添加混合して、予め調製した砂糖溶液及び10%炭酸水素ナトリウム溶液を加え、更に予め調製した前記コーヒーエキスを加え、イオン交換水にて全量補正したのち、混合したコーヒー調合液を70℃まで加温し、更に全量補正して、150/50(トータル200)kg/cm2にてホモゲナイズし、缶容器に充填密封後、123℃20分間レトルト殺菌して、缶入りミルクコーヒーを調製した(コーヒー固形分1.94%、無脂乳固形分0.824%)。60℃2週間、37℃4週間及び常温(25℃)4週間で保存後のゲル状沈殿物の状態を沈殿率で見た。結果を表5〜6に示す。 Add the milk and skim milk solution to the emulsifier solution and mix, add the sugar solution and 10% sodium bicarbonate solution prepared in advance, add the coffee extract prepared in advance, and correct the total amount with ion-exchanged water, then mix The coffee mixture was heated to 70 ° C., further corrected, homogenized at 150/50 (total 200) kg / cm 2 , filled and sealed in a can container, retort sterilized at 123 ° C. for 20 minutes, Canned milk coffee was prepared (coffee solids 1.94%, non-fat milk solids 0.824%). The state of the gel-like precipitate after storage at 60 ° C. for 2 weeks, 37 ° C. for 4 weeks and room temperature (25 ° C.) for 4 weeks was observed in terms of the precipitation rate. The results are shown in Tables 5-6.
<処方> 部
粗挽きコーヒー豆(L値:28.7、生豆換算)9
牛乳 7
10%脱脂粉乳溶液 2.7
50%砂糖溶液 6
スクラロース 0.003
アセスルファムカリウム 0.007
10%重曹溶液 0.2
クエン酸 表4記載
乳化剤(ホモゲン※NO.1550*) 0.15
イオン交換水にて 100
<Prescription> Partially ground coffee beans (L value: 28.7, green beans equivalent) 9
Milk 7
10% non-fat dry milk solution 2.7
50% sugar solution 6
Sucralose 0.003
Acesulfame potassium 0.007
10% sodium bicarbonate solution 0.2
Citric acid listed in Table 4
Emulsifier (homogen * NO.1550 *) 0.15
100 with ion exchange water
表5〜6より、重曹の添加量が750ppm,1000ppmではクエン酸の添加量が50ppm以上でゲル状沈殿物生成を有意に抑制できた。また、重曹の添加量1250ppm、1500ppmでは、クエン酸の添加量が150ppm以上でゲル状沈殿物生成を有意に抑制できた。更には、重曹の添加量が2000ppmでは、クエン酸の添加量が300〜500ppmでゲル状沈殿物生成を抑制する効果が得られた。しかし、重曹の添加量がいずれの系であっても、クエン酸の添加量が2000ppmを超えると少量の沈殿が見られるものがあった。 From Tables 5-6, when the addition amount of sodium bicarbonate was 750 ppm and 1000 ppm, the formation of gel-like precipitate could be significantly suppressed when the addition amount of citric acid was 50 ppm or more. In addition, when the amount of sodium bicarbonate added was 1250 ppm and 1500 ppm, the amount of citric acid added was 150 ppm or more, and gel-like precipitate formation could be significantly suppressed. Furthermore, when the addition amount of sodium bicarbonate was 2000 ppm, the effect of suppressing the formation of gel-like precipitate was obtained when the addition amount of citric acid was 300 to 500 ppm. However, even if the amount of sodium bicarbonate added is any system, a small amount of precipitation was observed when the amount of citric acid added exceeded 2000 ppm.
製造工程及び長期保存によっても、ゲル状沈殿を生じず、リングもなく安定して長期にわたり品質が保持されてなる密封容器入り乳成分含有コーヒー飲料を提供する。
Provided is a dairy ingredient-containing coffee beverage in a sealed container that does not cause gel-like precipitation even during the production process and long-term storage, has no ring and is stably maintained for a long period of time.
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JP2007215451A (en) * | 2006-02-15 | 2007-08-30 | Matsutani Chem Ind Ltd | Milk beverage added with salt, and beverage flavor improving method |
JP2009142206A (en) * | 2007-12-14 | 2009-07-02 | Ito En Ltd | Packed coffee drink controlled in formation of precipitates |
US8158183B2 (en) * | 2008-12-15 | 2012-04-17 | Pepsico, Inc. | Unsaturated acids for fading protection of colors derived from natural sources used in beverage products |
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