JP4436348B2 - Hot-rolled steel sheet excellent in paint bake-hardening performance and room temperature aging resistance and method for producing the same - Google Patents

Hot-rolled steel sheet excellent in paint bake-hardening performance and room temperature aging resistance and method for producing the same Download PDF

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JP4436348B2
JP4436348B2 JP2006239441A JP2006239441A JP4436348B2 JP 4436348 B2 JP4436348 B2 JP 4436348B2 JP 2006239441 A JP2006239441 A JP 2006239441A JP 2006239441 A JP2006239441 A JP 2006239441A JP 4436348 B2 JP4436348 B2 JP 4436348B2
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直樹 吉永
学 高橋
夏子 杉浦
明博 宮坂
昌章 杉山
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Nippon Steel Corp
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本発明は、塗装焼付硬化性能(BH)、常温遅時効性、成形性を兼ね備えた鋼板及びその製造方法に関するものである。本発明が係わる鋼板とは、自動車、家庭電気製品、建物などに使用されるものである。そして、表面処理をしない狭義の熱延鋼板と、防錆のために合金化溶融Znめっき、電気めっきなどの表面処理を施した広義の熱延鋼板を含むものである。   The present invention relates to a steel sheet having paint bake hardening performance (BH), room temperature slow aging, and formability, and a method for producing the same. The steel sheet according to the present invention is used for automobiles, home appliances, buildings, and the like. And it includes a hot-rolled steel sheet in a narrow sense not subjected to surface treatment and a hot-rolled steel sheet in a broad sense subjected to surface treatment such as alloying hot-dip Zn plating and electroplating for rust prevention.

本発明による鋼板は、塗装焼付硬化性能を有する鋼板であるので、使用に当たっては、今までの鋼板より板厚を減少できる、すなわち、軽量化が可能となる。したがって、地球環境保全に寄与できるものと考えられる。さらに、本発明による鋼板は、衝突エネルギー吸収特性にも優れているので、自動車の安全性の向上にも寄与するものである。   Since the steel plate according to the present invention is a steel plate having paint bake hardening performance, in use, the plate thickness can be reduced as compared with conventional steel plates, that is, the weight can be reduced. Therefore, it is thought that it can contribute to global environmental conservation. Furthermore, since the steel plate according to the present invention is excellent in the collision energy absorption characteristic, it contributes to the improvement of the safety of the automobile.

溶鋼の真空脱ガス処理の最近の進歩により、極低炭素鋼の溶製が容易になった現在、良好な加工性を有する極低炭素鋼板の需要は益々増加しつつある。この中でも、例えば、特許文献1等に開示されているTiとNbを複合添加した極低炭素鋼板は、極めて良好な加工性を有し、塗装焼付硬化(BH)性を兼備し、溶融亜鉛めっき特性にも優れているので、重要な位置を占めつつある。   With the recent progress in vacuum degassing of molten steel, it has become easier to produce ultra-low carbon steel, and now the demand for ultra-low carbon steel sheets with good workability is increasing. Among these, for example, the ultra-low carbon steel sheet combined with Ti and Nb disclosed in Patent Document 1 has extremely good workability and has paint bake hardening (BH) properties, and is hot dip galvanized. It is also occupying an important position because of its excellent properties.

しかしながら、そのBH量は通常のBH鋼板のレベルを超えるものではなく、さらなるBH量を付与しようとすると、常温非時効性が確保できなくなるという欠点を有する。高BH性と常温遅時効性とを兼ね備えた鋼板に関する技術については、例えば、特許文献2がある。   However, the amount of BH does not exceed the level of a normal BH steel sheet, and if a further amount of BH is to be imparted, there is a disadvantage that normal temperature non-aging cannot be ensured. For example, Patent Document 2 discloses a technique related to a steel sheet having both high BH properties and room temperature slow aging properties.

これは、極低炭素鋼に多量のNbとB、さらにはTiを複合添加して、焼鈍後の組織をフェライト相と低温変態生成相との複合組織とし、高r値、高BH、高延性及び常温非時効性を兼ね備えた冷延鋼板を得るものである。   This is because a large amount of Nb and B, and further Ti are added to ultra low carbon steel, and the structure after annealing becomes a composite structure of a ferrite phase and a low temperature transformation generation phase, and has a high r value, high BH, and high ductility. And a cold-rolled steel sheet having non-aging properties at room temperature.

しかしながら、この技術には、以下、1)及び、2)のような実操業上の問題点があることが明らかとなった。   However, it has been clarified that this technique has problems in actual operation such as 1) and 2) below.

1)多量のNb、BさらにはTiを含有する成分の鋼では、α→γ変態点が低下するわけではなく、複合組織を得るためには、極めて高い温度の焼鈍が必須となり、連続焼鈍時に板破断等のトラブルの原因となる。   1) In steels containing a large amount of Nb, B, and even Ti, the α → γ transformation point does not decrease, and in order to obtain a composite structure, annealing at an extremely high temperature is essential. It causes troubles such as plate breakage.

2)α+γの温度領域が極めて狭いため、板幅方向に組織が変化し、結果として材質が大きくばらついたり、数℃の焼鈍温度の変化によって、複合組織になる場合とならない場合があり、製造がきわめて不安定である。   2) Since the temperature range of α + γ is extremely narrow, the structure changes in the plate width direction. As a result, the material may vary greatly, or the annealing temperature of several degrees C. may not result in a composite structure. Very unstable.

また、特許文献3には、Nbを添加した極低炭素冷延鋼板において、焼鈍後の冷却速度を制御することによって粒界中の炭素濃度を高めて、高BHと常温遅時効性との両立が可能であることが示されている。しかしながら、これによっても高BHと常温遅時効性とのバランスは十分とは言えない。   In Patent Document 3, in an ultra-low carbon cold-rolled steel sheet to which Nb is added, the carbon concentration in the grain boundary is increased by controlling the cooling rate after annealing, thereby achieving both high BH and room temperature slow aging. Has been shown to be possible. However, the balance between high BH and room temperature slow aging is not sufficient.

さらに、従来のBH鋼板では、BHの熱処理条件が170℃−20分であれば所定のBH量を得ることができるが、この条件が、160℃−10分や150℃−10分ではBHが低下してしまうという問題がある。   Furthermore, in the conventional BH steel sheet, a predetermined amount of BH can be obtained if the heat treatment condition of BH is 170 ° C.-20 minutes, but if this condition is 160 ° C.-10 minutes or 150 ° C.-10 minutes, BH is There is a problem that it falls.

特開昭59−31827号公報JP 59-31827 A 特公平3−2224号公報Japanese Patent Publication No. 3-2224 特開平7−300623号公報JP-A-7-300623

上述のとおり、従来のBH鋼板は、安定的な製造が困難であったり、BH量を増加させると同時に常温遅時効性が失われるという欠点を有していた。また、塗装焼付の温度が現状の170℃に対して160℃ないし150℃のような低温になると、十分なBH量が得られないという問題がある。   As described above, the conventional BH steel sheet has drawbacks that it is difficult to produce stably, and that the amount of BH is increased and at the same time the room temperature slow aging is lost. Further, when the coating baking temperature is as low as 160 ° C. to 150 ° C. with respect to the current 170 ° C., there is a problem that a sufficient amount of BH cannot be obtained.

本発明は、高BH性と常温遅時効性とを兼ね備え、また、BHの温度が低温となっても十分なBH量を有する熱延鋼板及びその製造方法を提供するものである。   The present invention provides a hot-rolled steel sheet having both high BH properties and room temperature slow aging, and having a sufficient amount of BH even when the temperature of BH is low, and a method for producing the same.

本発明者らは、上記の目標を達成するために、鋭意、研究を遂行し、以下に述べるような従来にはない知見を得た。即ち、固溶Nの残存する鋼にCr、Mo、V等を添加することにより、高BHで常温遅時効性を有し、かつ、塗装焼付条件が低温短時間となっても、高BH性を確保することが可能であることを見いだしたものである。   The inventors of the present invention diligently conducted research to achieve the above-described goal, and gained knowledge that has not existed in the past as described below. That is, by adding Cr, Mo, V, etc. to the steel in which solute N remains, even if it has a high BH and room temperature slow aging, and the coating baking conditions are low temperature and short time, it has a high BH property. It has been found that it is possible to ensure.

本発明は、このような思想と新知見に基づいて構築された、従来にはない全く新しい熱延鋼板及びその製造方法であり、その要旨とするところは以下のとおりである。   The present invention is a completely new hot-rolled steel sheet and a method for producing the same, which have been constructed based on such a concept and new knowledge, and the gist thereof is as follows.

(1)質量%で、C=0.0001〜0.20%、Si=2.0%以下、Mn=3.0%以下、P=0.15%以下、S=0.015%以下、Al=0.20%以下、N=0.001〜0.10%、固溶N=0.0005〜0.004%、及び、0.52Al/N<10を満たすようにAlとN含有し、かつ、Cr、Mo、Vのうち1種又は2種以上を、それぞれ、Cr=2.5%以下、Mo=1.0%以下、V=0.1%以下、及び、(Cr+3.5Mo+39V)≧0.1を満たすように含有し、残部Fe及び不可避的不純物からなり、2%引張変形後170℃にて20分間の熱処理を施すことによって評価されるBH170が45MPa以上で、かつ、2%引張変形後160℃にて10分間の熱処理を施すことによって評価されるBH160及び2%引張変形後150℃にて10分間の熱処理を施すことによって評価されるBH150がいずれも35MPa以上で、さらに、100℃にて1時間の熱処理を施した後の引張試験における降伏点伸びが0.6%以下であることを特徴とする塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 (1) in mass%, C = 0.0001~0.20%, Si = 2.0% or less, Mn = 3.0% or less, P = 0.15% or less, S = 0.015% hereinafter , Al = 0.20% or less, N = 0.001 to 0.10%, solute N = .0005-0.004%, and, Al and N so as to satisfy the 0.52Al / N <10 And one or more of Cr, Mo, and V, respectively, Cr = 2.5% or less, Mo = 1.0% or less, V = 0.1% or less, and (Cr + 3 .5Mo + 39V) ≧ 0.1, comprising the balance Fe and unavoidable impurities, BH170 evaluated by heat treatment at 170 ° C. for 20 minutes after 2% tensile deformation is 45 MPa or more, and B evaluated by heat treatment at 160 ° C. for 10 minutes after 2% tensile deformation BH150 evaluated by performing heat treatment at 150 ° C. for 10 minutes after H160 and 2% tensile deformation is 35 MPa or more, and further yield point in tensile test after heat treatment at 100 ° C. for 1 hour. A hot-rolled steel sheet excellent in paint bake-hardening performance and room temperature aging resistance, characterized by an elongation of 0.6% or less.

)質量%で、Caを0.0005〜0.01%含有することを特徴とする前記(1)記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 (2) in mass%, the characterized in that it contains Ca 0.0005 to 0.01% (1) Symbol placement bake hardenability performance and anti-aging properties superior hot-rolled steel sheet.

)質量%で、Bを0.0001〜0.001%含有することを特徴とする前記(1)又は2)記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 ( 3 ) The hot-rolled steel sheet excellent in paint bake hardening performance and room temperature aging resistance as described in (1) or ( 2), wherein B is contained in an amount of 0.0001 to 0.001% by mass.

)質量%で、Nbを0.001〜0.03%含有することを特徴とする前記(1)〜()のいずれかに記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 ( 4 ) Mass% and Nb is contained in an amount of 0.001 to 0.03%, which is excellent in paint bake-hardening performance and room temperature aging resistance according to any one of the above (1) to ( 3 ) Hot rolled steel sheet.

)質量%で、Ti=0.0001〜0.10%、及び、N−0.29Ti>0.0005を満たすようにTiを含有することを特徴とする前記(1)〜()のいずれかに記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 ( 5 ) The above (1) to ( 4 ), characterized by containing Ti so as to satisfy Ti = 0.0001 to 0.10% and N−0.29Ti> 0.0005 by mass%. A hot-rolled steel sheet having excellent bake hardening performance and room temperature aging resistance.

)質量%で、Sn、Cu、Ni、Co、Zn、W、Zr及びMgの1種又は2種以上を、合計で0.001〜1.0%含有することを特徴とする前記(1)〜()のいずれかに記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 ( 6 ) The above-mentioned, characterized by containing one or more of Sn, Cu, Ni, Co, Zn, W, Zr and Mg in 0.001 to 1.0% in total (% by mass). A hot-rolled steel sheet excellent in paint bake hardening performance and room temperature aging resistance according to any one of 1) to ( 5 ).

)前記(1)〜()のいずれかに記載の熱延鋼板に溶融亜鉛めっき、合金化溶融亜鉛めっき又は電気亜鉛めっきを施したことを特徴とする塗装焼付硬化性能と耐常温時効性に優れた亜鉛めっき熱延鋼板。 ( 7 ) Paint bake-hardening performance and room temperature aging resistance, characterized in that hot-rolled steel sheet according to any one of (1) to ( 6 ) is subjected to hot dip galvanizing, alloying hot dip galvanizing, or electrogalvanizing. Galvanized hot rolled steel sheet with excellent properties.

)前記(1)〜()のいずれかに記載の化学成分を有するスラブを、(Ar3点−100)℃以上の温度で熱間圧延し、熱間圧延終了温度から600℃以下の温度までを平均冷却速度10℃/s以上で冷却し、次いで、550℃以下の温度で巻き取ることを特徴とする塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板の製造方法。 ( 8 ) The slab having the chemical component according to any one of (1) to ( 6 ) above is hot-rolled at a temperature of (Ar 3 points-100) ° C. or higher and 600 ° C. or lower from the hot rolling end temperature. A method for producing a hot-rolled steel sheet excellent in paint bake-hardening performance and room temperature aging resistance, characterized in that it is cooled at an average cooling rate of 10 ° C./s or higher and then wound up at a temperature of 550 ° C. or lower.

本発明により、高BH性と常温遅時効性とを兼ね備え、また、BHの温度が低温となっても、十分なBH量を有する熱延鋼板及び亜鉛めっき鋼板を得ることができた。   According to the present invention, a hot-rolled steel sheet and a galvanized steel sheet having both a high BH property and a normal temperature slow aging property and having a sufficient amount of BH can be obtained even when the BH temperature is low.

ここに、本発明において鋼組成及び製造条件を上述のように限定する理由についてさらに説明する。なお、%は質量%を意味する。   Here, the reason why the steel composition and production conditions are limited as described above in the present invention will be further described. In addition,% means the mass%.

Cは、安価に強度を増加させる元素であるので、その添加量は狙いとする強度レベルに応じて変化するが、Cを0.0001%未満とするのは製鋼技術上困難で、コストアップとなるばかりか、溶接部の疲労特性が劣化するので、C添加量は、0.0001%を下限とする。   Since C is an element that increases the strength at a low cost, the amount of addition varies depending on the target strength level, but it is difficult to make C less than 0.0001% in terms of steelmaking technology, resulting in an increase in cost. In addition, since the fatigue characteristics of the welded portion deteriorate, the lower limit of the C addition amount is 0.0001%.

一方、C量が0.20%を超えると成形性の劣化を招いたり、溶接性を損なうだけでなく、本発明で重要な高BH性と常温非時効性を両立することが困難となるので、C添加量は、0.20%を上限とする。深絞り成形性を必要とする部材に本発明を適用する場合には、C量を0.0001〜0.0020%、又は、0.012〜0.024%の範囲とすることが好ましい。   On the other hand, if the amount of C exceeds 0.20%, not only deterioration of formability will be caused or weldability will be impaired, but it will also be difficult to achieve both high BH properties and room temperature non-aging properties important in the present invention. The upper limit of the amount of C added is 0.20%. When the present invention is applied to a member that requires deep drawability, the C content is preferably in the range of 0.0001 to 0.0020% or 0.012 to 0.024%.

固溶C量は0.0020%以下とすることが好ましい。本発明においては、主としてNによって、高BH性と常温遅時効性とを確保するので、固溶C量が多すぎると、常温遅時効性を確保することが困難となる。固溶Cは0.0010%未満とすることとが、より好ましい。固溶C量の調整は、全C量を上述の上限以下としてもよいし、巻取温度や、過時効処理条件によって、所定のレベルまで低減してもよい。   The amount of solute C is preferably 0.0020% or less. In the present invention, high BH property and room temperature slow aging are ensured mainly by N. Therefore, if the amount of dissolved C is too large, it is difficult to secure room temperature slow aging. The solute C is more preferably less than 0.0010%. The adjustment of the solid solution C amount may be the total C amount not more than the above upper limit, or may be reduced to a predetermined level depending on the coiling temperature and the overaging treatment conditions.

Siは、固溶体強化元素として強度を増加させる働きがある他、マルテンサイトやベイナイト、さらには残留γ等を含む組織を得るためにも有効である。Si添加量は、狙いとする強度レベルに応じて変化するが、2.0%超となると、プレス成形性が劣悪となったり、化成処理性の低下を招いたりするので、Si添加量は、2.0%を上限とする。   In addition to increasing the strength as a solid solution strengthening element, Si is effective for obtaining a structure containing martensite, bainite, and residual γ. The Si addition amount varies depending on the target strength level. However, if it exceeds 2.0%, the press formability is deteriorated or the chemical conversion property is deteriorated. The upper limit is 2.0%.

合金化溶融亜鉛めっきを施す場合には、めっき密着性の低下、合金化反応の遅延による生産性の低下などの問題が生ずるので、0.8%以下とする。下限は、特に設けないが、0.001%以下とすると、製造コストが高くなるので、0.001%が実質的な下限である。また、Al量の制御の観点で、Al脱酸を行うことが困難な場合には、Siで脱酸することもあり得、この場合には0.04%以上のSiが含有されることになる。   When alloying hot dip galvanizing is performed, problems such as a decrease in plating adhesion and a decrease in productivity due to a delay in the alloying reaction occur. A lower limit is not particularly provided, but if it is 0.001% or less, the manufacturing cost increases, so 0.001% is a substantial lower limit. In addition, when it is difficult to perform Al deoxidation from the viewpoint of controlling the amount of Al, it may be deoxidized with Si. In this case, 0.04% or more of Si is contained. Become.

Mnは、固溶体強化元素として有用である他、MnSを形成し、熱延時のSによる耳割れを抑制したり、熱延板組織を微細にしたり、マルテンサイトやベイナイト、さらには、残留γ等を含む組織を得るためにも有効である。さらに、Mnは固溶Nに起因する常温時効を抑制する効果を有するので、0.3%以上を添加することが好ましい。   In addition to being useful as a solid solution strengthening element, Mn forms MnS, suppresses ear cracking due to S during hot rolling, refines the hot rolled sheet structure, martensite, bainite, and residual γ. It is also effective to obtain a tissue that contains it. Further, since Mn has an effect of suppressing normal temperature aging caused by solid solution N, it is preferable to add 0.3% or more.

ただし、深絞り性を必要とする場合には、0.15%以下、さらには、0.10%未満とすることが好ましい。一方、添加量が3.0%を超えると、強度が高くなりすぎて延性が低下したり、亜鉛めっきの密着性が阻害されたりするので、Mn添加量は、3.0%を上限とする。   However, when deep drawability is required, it is preferably 0.15% or less, and more preferably less than 0.10%. On the other hand, if the addition amount exceeds 3.0%, the strength becomes too high and the ductility is lowered, or the adhesion of galvanization is hindered, so the Mn addition amount has an upper limit of 3.0%. .

Pは、Siと同様に、安価に、強度を上昇する元素として知られており、強度を増加する必要がある場合には、さらに、積極的に添加する。また、Pは、熱延組織を微細にし、加工性を向上する効果も有する。   Like Si, P is known as an element that increases the strength at a low cost, and when it is necessary to increase the strength, P is further actively added. P also has the effect of making the hot-rolled structure fine and improving workability.

ただし、添加量が0.15%を超えると、スポット溶接後の疲労強度が劣悪となったり、降伏強度が増加し過ぎて、プレス時に面形状不良を引き起こす。さらに、連続溶融亜鉛めっき時に、合金化反応が極めて遅くなり、生産性が低下する。また、2次加工性も劣化する。したがって、P添加量の上限を0.15%とする。   However, if the addition amount exceeds 0.15%, the fatigue strength after spot welding becomes poor, or the yield strength increases excessively, causing surface shape defects during pressing. Furthermore, during continuous hot dip galvanization, the alloying reaction becomes extremely slow and productivity is reduced. Also, the secondary workability is deteriorated. Therefore, the upper limit of the P addition amount is set to 0.15%.

Sは、0.015%超では、熱間割れの原因となったり、加工性を劣化させるので、S添加量は、0.015%を上限とする。   If S exceeds 0.015%, it causes hot cracking or deteriorates workability. Therefore, the upper limit of S addition is 0.015%.

Alは、脱酸調製剤として使用してもよい。ただし、Alは、Nと結合しAlNを形成し、BH性を低下せしめるので、その添加は、製造技術上無理のない範囲で、必要最小限にとどめることが望ましい。   Al may be used as a deoxidation preparation agent. However, since Al combines with N to form AlN and lowers the BH property, it is desirable to add it to the minimum necessary within a range that is not unreasonable in terms of manufacturing technology.

熱延鋼板の場合には、Alが、Nに対して原子比で1以上であっても、熱延後急冷すれば、固溶Nを確保することが可能であるので、Alの上限は0.20%でよい。Alが、0.05以下、さらには0.02%以下となれば、製造がより一層容易となる。   In the case of a hot-rolled steel sheet, even if Al has an atomic ratio of 1 or more with respect to N, it is possible to ensure solid solution N if it is rapidly cooled after hot rolling, so the upper limit of Al is 0. 20% is sufficient. If Al is 0.05 or less, further 0.02% or less, the production becomes even easier.

Nは、本発明において重要な元素である。即ち、本発明においては、主として、Nによって高BH性を達成する。したがって、0.001%以上の添加が必須である。一方で、Nが多すぎると、常温遅時効性を確保し難くなったり、加工性が劣化したりするので、0.10%を上限とする。好ましくは、0.002〜0.020%、より好ましくは、0.002〜0.008%である。   N is an important element in the present invention. That is, in the present invention, high BH property is achieved mainly by N. Therefore, addition of 0.001% or more is essential. On the other hand, when N is too much, it becomes difficult to ensure the room temperature slow aging property or the workability deteriorates, so the upper limit is made 0.10%. Preferably, it is 0.002 to 0.020%, more preferably 0.002 to 0.008%.

さらに、NはAlと結合してAlNを形成し易いので、BHに寄与するNを確保するために、0.52Al/Nを一定値以下とする必要がある。熱延鋼板においては、以下のように限定する。   Further, since N easily bonds to Al to form AlN, it is necessary to set 0.52 Al / N to a certain value or less in order to secure N that contributes to BH. In a hot-rolled steel sheet, it limits as follows.

0.52Al/Nが10以上となると、熱延後の冷却過程や巻取中に、容易にAlNが析出するので、0.52Al/Nは、10未満を上限とする。0.52Al/Nが10未満であれば、熱延後の冷却速度や巻取温度に配慮して、AlNの過度の析出を避けることができるので、高BH性を得ることができる。0.52Al/Nのより好ましい上限は5である。   When 0.52 Al / N is 10 or more, AlN easily precipitates during the cooling process after hot rolling or during winding, so 0.52 Al / N has an upper limit of less than 10. If 0.52 Al / N is less than 10, it is possible to avoid excessive precipitation of AlN in consideration of the cooling rate and coiling temperature after hot rolling, so that high BH properties can be obtained. A more preferable upper limit of 0.52Al / N is 5.

Cr、Mo、Vは、本発明において重要な元素である。これらの元素の中から1種又は2種類以上を添加することが必須である。これらの元素の添加によって、初めて、高BH性と耐常温時効性とを両立させることが可能となる。   Cr, Mo, and V are important elements in the present invention. It is essential to add one or more of these elements. For the first time, the addition of these elements makes it possible to achieve both high BH properties and room temperature aging resistance.

Nは、Cよりも拡散速度が大きいため、所定量以上のNが存在すると、耐常温時効性を確保することが困難であることが知られている。このため、自動車の外板パネル等、外観が重視される部材には、Nを活用したBH鋼板は適用されていない。   Since N has a higher diffusion rate than C, it is known that it is difficult to ensure normal temperature aging resistance if a predetermined amount or more of N is present. For this reason, the BH steel plate using N is not applied to a member whose appearance is important, such as an outer panel of an automobile.

しかしながら、Cr、Mo、Vを積極的に添加することで、常温遅時効性を、BH性を損なうことなく得ることが可能であることを、新たに見いだした。これらの元素によって耐常温時効性が向上する機構は、必ずしも明らかではないが、以下のように推察される。   However, it has been newly found that by adding Cr, Mo and V positively, it is possible to obtain room temperature slow aging without impairing BH properties. The mechanism for improving the normal temperature aging resistance by these elements is not necessarily clear, but is presumed as follows.

常温付近では、これらの元素とNとがペアやクラスターを形成し、Nの拡散を抑えるので、耐常温時効性が確保される。これに対し、150〜170℃での塗装焼付処理においては、Nが、これらのペアやクラスターから脱出し、転位を固着するので、高BH性が発現する。   In the vicinity of normal temperature, these elements and N form a pair or cluster and suppress the diffusion of N, so that normal temperature aging resistance is ensured. On the other hand, in the coating baking process at 150 to 170 ° C., N escapes from these pairs and clusters and fixes dislocations, so that a high BH property is exhibited.

Cr、Mo、Vの添加量の上限は、加工性の確保とコストの点から決定され、それぞれ、2.5%、1.0%、0.1%である。   The upper limit of the addition amount of Cr, Mo, V is determined from the viewpoint of ensuring workability and cost, and is 2.5%, 1.0%, and 0.1%, respectively.

Vは、添加量が多すぎると窒化物を形成し、固溶Nの確保が困難となるので、0.04%以下とするのが好ましい。耐常温時効性を確保するためには、Cr、Mo、Vを、(Cr+3.5Mo+39V)≧0.1を満たすように添加しなければならない。(Cr+3.5Mo+39V)≧0.4が、より好ましい範囲である。   V is preferably 0.04% or less because if V is added in an excessive amount, nitrides are formed and it is difficult to ensure solid solution N. In order to ensure normal temperature aging resistance, Cr, Mo, and V must be added so as to satisfy (Cr + 3.5Mo + 39V) ≧ 0.1. (Cr + 3.5Mo + 39V) ≧ 0.4 is a more preferable range.

また、耐常温時効性を確保するためには、Cr、Mo、Vを単独で添加するよりも、2種類以上を組み合わせて添加することが、より一層効果的である。   Moreover, in order to ensure normal temperature aging resistance, it is much more effective to add two or more types in combination than to add Cr, Mo, and V alone.

固溶Nは、合計で0.0005〜0.004%とする。ここで、固溶Nとは、単独でFe中に存在するNだけでなく、Cr、Mo、V、Mn、Si、Pなどの置換型固溶元素とペアやクラスターを形成するNも含む。   The total amount of solute N is 0.0005 to 0.004%. Here, the solid solution N includes not only N present alone in Fe but also N forming a pair or cluster with a substitutional solid solution element such as Cr, Mo, V, Mn, Si, and P.

固溶N量は、水素気流中加熱抽出法によって求めるのがよい。この方法は試料を200〜500℃程度の温度域に加熱し、固溶Nと水素とを反応させてアンモニアとし、アンモニアを質量分析し、その分析値を換算して固溶N量を求めるものである。   The amount of solute N is preferably obtained by a heat extraction method in a hydrogen stream. In this method, a sample is heated to a temperature range of about 200 to 500 ° C., and solid solution N and hydrogen are reacted to form ammonia. Ammonia is mass analyzed, and the analysis value is converted to obtain the amount of solid solution N. It is.

さらに、固溶N量は、全N量から、AlN、NbN、VN、TiN、BN等などの化合物として存在するN量(抽出残査の化学分析から定量)を差し引いた値から求めることもできる。また、内部摩擦法やFIM(Field Ion Microscopy)によって求めてもよい。   Furthermore, the amount of solute N can also be obtained from a value obtained by subtracting the amount of N existing as a compound such as AlN, NbN, VN, TiN, BN, etc. (quantitative analysis from the chemical analysis of the extraction residue) from the total N amount. . Further, it may be determined by an internal friction method or FIM (Field Ion Microscopy).

固溶Nが0.0005%未満では、十分なBH性を得ることができない。また、固溶Nが0.004%を超えると、BH性は向上しても、常温遅時効性を得ることが困難となる。固溶N量は、より好ましくは、0.0012〜0.003%である。   If the solute N is less than 0.0005%, sufficient BH property cannot be obtained. On the other hand, if the solid solution N exceeds 0.004%, it becomes difficult to obtain a normal aging property even if the BH property is improved. The amount of solute N is more preferably 0.0012 to 0.003%.

Caは、脱酸元素として有用であるほか、硫化物の形態制御にも効果を奏する元素であるので、0.0005〜0.01%の範囲で添加してもよい。0.0005%未満では、添加効果が十分でなく、0.01%を超えて添加すると、加工性が劣化するので、Caの添加量は、0.0005〜0.01%の範囲とする。   Ca is not only useful as a deoxidizing element but also an element that has an effect on the form control of sulfides, so Ca may be added in the range of 0.0005 to 0.01%. If it is less than 0.0005%, the effect of addition is not sufficient, and if it exceeds 0.01%, the workability deteriorates, so the amount of Ca added is in the range of 0.0005 to 0.01%.

Bは、2次加工脆化の防止に有効な元素であるので、必要に応じて、0.0001〜0.001%の範囲で添加する。添加量が0.0001%未満では添加効果がほとんどなく、0.001%を超えて添加しても、添加効果が飽和するだけでなく、BNが形成され易くなり、固溶Nを確保することが困難となる。0.0001〜0.0004%が、より望ましい範囲である。   Since B is an element effective for preventing secondary work embrittlement, it is added in the range of 0.0001 to 0.001% as necessary. When the amount added is less than 0.0001%, there is almost no effect of addition, and even if added over 0.001%, not only the effect of addition is saturated, but also BN is easily formed and solid solution N is secured. It becomes difficult. 0.0001 to 0.0004% is a more desirable range.

Nbは、加工性の向上や高強度化、さらには組織の微細化と均一化に有効な元素であるので、必要に応じて、0.001〜0.03%の範囲で添加する。しかし、その添加量が0.001%未満では、添加効果が発現せず、一方、0.03%を超えて添加すると、NbNを形成し易くなり、固溶Nの確保が困難となる。0.001〜0.012%が、より好ましい範囲である。   Nb is an element effective for improving workability, increasing strength, and further miniaturizing and homogenizing the structure. Therefore, Nb is added in a range of 0.001 to 0.03% as necessary. However, when the addition amount is less than 0.001%, the effect of addition does not appear. On the other hand, when the addition amount exceeds 0.03%, NbN is easily formed, and it is difficult to secure solid solution N. 0.001 to 0.012% is a more preferable range.

Tiも、Nbと同様の効果を有する元素であるので、必要に応じて、0.0001〜0.10%の範囲で添加する。しかし、その添加量が0.0001%未満では、添加効果が発現せず、一方、0.10%を超えて添加すると、多量のNがTiNとして析出又は晶出して、固溶Nの確保が困難となる。0.001〜0.020%が好ましく、0.001〜0.012%がより好ましい範囲である。   Since Ti is an element having the same effect as Nb, it is added in a range of 0.0001 to 0.10% as necessary. However, when the addition amount is less than 0.0001%, the effect of addition does not appear. On the other hand, when the addition amount exceeds 0.10%, a large amount of N precipitates or crystallizes as TiN, and the solid solution N is ensured. It becomes difficult. 0.001 to 0.020% is preferable, and 0.001 to 0.012% is a more preferable range.

さらに、Tiは、固溶Nを確保するために、N−0.29Ti>0.0005を満たす範囲内で添加しなければならない。より好ましくは、N−0.29Ti>0.0010である。   Furthermore, in order to secure solid solution N, Ti must be added within a range satisfying N−0.29Ti> 0.0005. More preferably, N−0.29Ti> 0.0010.

これらを主成分とする鋼に、Sn、Cu、Ni、Co、Zn、W、Zr及びMgの1種又は2種以上を、合計で0.001〜1.0%の範囲で含有しても構わない。しかしながら、ZrはZrNを形成するので、Zrの添加量は0.01%以下とすることが好ましい。次に、製造条件の限定理由について述べる。   Even if steel which has these as a main component contains 1 type or 2 types or more of Sn, Cu, Ni, Co, Zn, W, Zr, and Mg in the range of 0.001-1.0% in total. I do not care. However, since Zr forms ZrN, the amount of Zr added is preferably 0.01% or less. Next, the reasons for limiting the manufacturing conditions will be described.

熱間圧延に供するスラブは、特に、製造条件で限定されるものではない。即ち、連続鋳造スラブや薄スラブキャスターなどで製造したものであればよい。また、鋳造後に、直ちに熱間圧延を行う連続鋳造−直接圧延(CC−DR)のようなプロセスで製造したスラブも本発明に適合する。熱延鋼板を最終製品とする場合には、以下のように、製造条件を限定する必要がある。   The slab to be subjected to hot rolling is not particularly limited by the production conditions. That is, what was manufactured with the continuous casting slab, the thin slab caster, etc. should just be used. A slab manufactured by a process such as continuous casting-direct rolling (CC-DR) in which hot rolling is performed immediately after casting is also suitable for the present invention. When a hot-rolled steel sheet is used as a final product, it is necessary to limit production conditions as follows.

即ち、熱延の仕上げ温度は、(Ar3−100)℃以上とする。(Ar3−100)℃未満では、加工性を確保するのが困難であったり、板厚精度の問題を生じたりする。Ar3点以上がより好ましい範囲である。熱延の仕上げ温度の上限は特に定めないが、結晶粒の粗大化を防止したり、熱延ロールを保護する観点から、1100℃以下とすることが好ましい。 That is, the finishing temperature of hot rolling is (Ar 3 -100) ° C. or higher. If it is less than (Ar 3 -100) ° C., it is difficult to ensure workability, and a problem of plate thickness accuracy occurs. Ar 3 or more is a more preferable range. Although the upper limit of the hot rolling finishing temperature is not particularly defined, it is preferably 1100 ° C. or lower from the viewpoint of preventing the coarsening of crystal grains and protecting the hot rolling roll.

なお、熱延の加熱温度は特に限定するものではないが、固溶Nを確保するためにAlNを溶解させる必要がある場合には、1200℃以上とすることが望ましい。   In addition, although the heating temperature of hot rolling is not particularly limited, when it is necessary to dissolve AlN in order to secure solid solution N, the heating temperature is preferably set to 1200 ° C. or higher.

熱延後は、熱間圧延終了温度から少なくとも600℃までは、平均冷却速度が10℃/sとなるように冷却する必要がある。これは、AlNの析出を抑制するためである。   After hot rolling, it is necessary to cool from the hot rolling end temperature to at least 600 ° C. so that the average cooling rate is 10 ° C./s. This is for suppressing precipitation of AlN.

また、NがAlに対して過剰に添加されている場合、即ち、0.52Al/N<1の場合にも、この冷却速度は、10℃/s以上とすることが、高BH性と耐常温時効性とを確保するために重要であることを見いだした。冷却速度が30℃/s以上であれば、BH性と耐常温時効性に対して、より一層好ましい。冷却速度の上限は特に定めないが、生産性の観点から、200℃/s以下とすることが好ましい。   In addition, when N is excessively added to Al, that is, when 0.52 Al / N <1, the cooling rate should be 10 ° C./s or more to achieve high BH resistance and resistance. It has been found that it is important to ensure normal temperature aging. A cooling rate of 30 ° C./s or more is even more preferable for BH properties and normal temperature aging resistance. The upper limit of the cooling rate is not particularly defined, but is preferably 200 ° C./s or less from the viewpoint of productivity.

巻取温度は、AlNの析出を抑制するために、550℃以下とする。好ましくは、450℃以下である。本発明によって得られる熱延鋼板の組織は、フェライト又はベイナイトを主相とするが、両相が混在していても構わないし、これらに、マルテンサイト、オーステナイト、炭化物、窒化物が存在していてもよい。すなわち、要求特性に応じて組織を作り分ければよい。   The winding temperature is set to 550 ° C. or lower in order to suppress the precipitation of AlN. Preferably, it is 450 degrees C or less. The structure of the hot-rolled steel sheet obtained by the present invention has ferrite or bainite as the main phase, but both phases may be mixed, and martensite, austenite, carbide, and nitride exist in these. Also good. That is, it is only necessary to create an organization according to required characteristics.

熱延後は、必要に応じて酸洗し、その後、インライン又はオフラインで、圧下率10%以下のスキンパス、又は、圧下率40%程度までの冷間圧延を施しても構わない。   After hot rolling, pickling may be performed as necessary, and then, in-line or off-line, a skin pass with a reduction rate of 10% or less or cold rolling to a reduction rate of about 40% may be performed.

本発明によって得られる鋼板は、BH170が45MPa以上、BH160及びBH150が、いずれも35MPa以上である。BH170が60MPa以上、BH160及びBH150が50MPa以上が、より好ましい範囲である。BHの上限は特に限定しないが、BH170が140MPaを超え、また、BH160及びBH150が130MPaを超えると、耐常温時効性を確保することが困難となる。   In the steel sheet obtained by the present invention, BH170 is 45 MPa or more, and BH160 and BH150 are both 35 MPa or more. BH170 is 60 MPa or more, and BH160 and BH150 are more preferably 50 MPa or more. The upper limit of BH is not particularly limited, but when BH170 exceeds 140 MPa and BH160 and BH150 exceed 130 MPa, it becomes difficult to ensure normal temperature aging resistance.

なお、BH170とは、2%引張変形後170℃にて20分間の熱処理を施すことによって評価されるBH、BH160は2%引張変形後160℃にて10分間の熱処理を施すことによって評価されるBH、さらに、BH150は2%引張変形後150℃にて10分間の熱処理を施すことによって評価されるBHを表す。   BH170 is evaluated by heat treatment at 170 ° C. for 20 minutes after 2% tensile deformation, and BH160 is evaluated by heat treatment at 160 ° C. for 10 minutes after 2% tensile deformation. BH and BH150 represent BH evaluated by heat treatment at 150 ° C. for 10 minutes after 2% tensile deformation.

耐常温時効性は、人工時効後の降伏点伸びによって評価される。本発明によって得られる鋼板は、100℃にて1時間熱処理後の引張試験における降伏点伸びが0.6%以下である。好ましくは、0.4%以下、さらに好ましくは、0.3%以下である。また、40℃にて70日間の熱処理後の降伏点伸びは、0.5%以下、好ましくは、0.3%以下、さらに好ましくは、0.2%以下である。   Room temperature aging resistance is evaluated by the yield point elongation after artificial aging. The steel sheet obtained by the present invention has a yield point elongation of 0.6% or less in a tensile test after heat treatment at 100 ° C. for 1 hour. Preferably, it is 0.4% or less, more preferably 0.3% or less. The yield point elongation after heat treatment at 40 ° C. for 70 days is 0.5% or less, preferably 0.3% or less, and more preferably 0.2% or less.

次に、本発明を実施例にて説明する。   Next, an example explains the present invention.

<実施例1>
表1に示す組成を有する鋼を溶製し、表2に示す条件で熱間圧延を施した。このとき、加熱温度は全て1250℃とした。調質圧延率は1.0%とし、JIS5号引張試験片を採取して、BH及び人工時効後の降伏点伸びの測定を行った。得られた組織及び機械的性質を表2に示す。
<Example 1>
Steel having the composition shown in Table 1 was melted and hot rolled under the conditions shown in Table 2. At this time, all heating temperatures were 1250 ° C. The temper rolling ratio was 1.0%, JIS No. 5 tensile test specimens were collected, and the elongation of yield point after BH and artificial aging was measured. The obtained structure and mechanical properties are shown in Table 2.

これより明らかなとおり、本発明の化学成分を有する鋼を適正な条件で熱間圧延した場合には、高BH性と耐常温時効性とを両立させることができた。   As is clear from this, when the steel having the chemical component of the present invention was hot-rolled under appropriate conditions, both high BH properties and room temperature aging resistance could be achieved.

Figure 0004436348
Figure 0004436348

Figure 0004436348
Figure 0004436348

<参考例1>
表1の鋼のうちA、C、D、E、F、I、N、O及びPの鋼を、スラブ加熱温度1250℃、仕上げ温度930℃、巻取り温度650℃で熱間圧延し、4.0mm厚の鋼帯とした。
<Reference Example 1>
Among the steels in Table 1, A, C, D, E, F, I, N, O, and P steels were hot rolled at a slab heating temperature of 1250 ° C, a finishing temperature of 930 ° C, and a winding temperature of 650 ° C. A steel strip with a thickness of 0 mm was used.

酸洗後、80%の圧下率の冷間圧延を施し、0.8mm厚の冷延板とし、次いで、連続焼鈍設備にて、加熱速度10℃/s、最高到達温度800℃とする焼鈍を行い、その後、表3中に示す種々の冷却速度で冷却し、また、過時効処理温度も変化させた。   After pickling, cold rolling at a reduction rate of 80% is performed to obtain a cold-rolled sheet having a thickness of 0.8 mm, followed by annealing at a heating rate of 10 ° C./s and a maximum temperature of 800 ° C. in a continuous annealing facility. After that, it was cooled at various cooling rates shown in Table 3, and the overaging treatment temperature was also changed.

なお、過時効処理時間は、300秒(一定)とした。さらに、1.0%の圧下率の調質圧延をし、JIS5号引張試験片を採取し、BHと人工時効後の降伏点伸びの測定を行った。   The overaging treatment time was 300 seconds (constant). Furthermore, temper rolling was performed at a rolling reduction of 1.0%, and a JIS No. 5 tensile test piece was collected, and BH and elongation at yield point after artificial aging were measured.

結果を表3に示す。これより明らかなとおり、本発明の化学成分を有する鋼を適正な条件で焼鈍した場合には、高BH性と耐常温時効性とを両立させることができた。   The results are shown in Table 3. As is clear from this, when the steel having the chemical component of the present invention was annealed under appropriate conditions, both high BH properties and normal temperature aging resistance could be achieved.

Figure 0004436348
Figure 0004436348

<参考例2>
表1の鋼のうちA及びDの鋼を、スラブ加熱温度1250℃、仕上げ温度930℃、巻取り温度650℃で熱間圧延し、4.0mm厚の鋼帯とした。
<Reference Example 2>
Of the steels in Table 1, steels A and D were hot-rolled at a slab heating temperature of 1250 ° C, a finishing temperature of 930 ° C, and a winding temperature of 650 ° C to form a steel strip having a thickness of 4.0 mm.

酸洗後、80%の圧下率の冷間圧延を施し0.8mm厚の冷延板とし、次いで、連続溶融亜鉛めっき設備にて、加熱速度10℃/s、最高到達温度800℃とする焼鈍を行い、その後、表4中に示す種々の冷却速度で冷却し、460℃の亜鉛浴に浸漬させた後、15℃/sにて500℃まで再加熱し、15秒間保持を行った。   After pickling, cold rolling with a reduction rate of 80% is performed to obtain a cold-rolled sheet having a thickness of 0.8 mm, followed by annealing at a heating rate of 10 ° C./s and a maximum temperature of 800 ° C. in a continuous hot dip galvanizing facility. After that, it was cooled at various cooling rates shown in Table 4, immersed in a 460 ° C. zinc bath, reheated to 500 ° C. at 15 ° C./s, and held for 15 seconds.

さらに、0.8%の圧下率の調質圧延をし、JIS5号引張試験片を採取し、AI、BHと人工時効後の降伏点伸びの測定を行った。   Furthermore, temper rolling was performed at a reduction rate of 0.8%, JIS No. 5 tensile test specimens were collected, and AI, BH and elongation at yield point after artificial aging were measured.

結果を表4に示す。これより明らかなとおり、適正な条件で製造した場合には、高BH性と耐常温時効性とを両立させることができた。   The results are shown in Table 4. As apparent from this, when manufactured under appropriate conditions, both high BH properties and normal temperature aging resistance could be achieved.

Figure 0004436348
Figure 0004436348

Claims (8)

質量%で、
C=0.0001〜0.20%、Si=2.0%以下、
Mn=3.0%以下、 P=0.15%以下、
S=0.015%以下、 Al=0.20%以下、
N=0.001〜0.10%、固溶N=0.0005〜0.004%、及び、0.52Al/N<10を満たすようにAlとN含有し、かつ、Cr、Mo、Vのうち1種又は2種以上を、それぞれ、Cr=2.5%以下、Mo=1.0%以下、V=0.1%以下、及び、(Cr+3.5Mo+39V)≧0.1を満たすように含有し、残部Fe及び不可避的不純物からなり、2%引張変形後170℃にて20分間の熱処理を施すことによって評価されるBH170が45MPa以上で、かつ、2%引張変形後160℃にて10分間の熱処理を施すことによって評価されるBH160及び2%引張変形後150℃にて10分間の熱処理を施すことによって評価されるBH150がいずれも35MPa以上で、さらに、100℃にて1時間の熱処理を施した後の引張試験における降伏点伸びが0.6%以下であることを特徴とする塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。
% By mass
C = 0.0001 to 0.20%, Si = 2.0% or less,
Mn = 3.0% or less, P = 0.15% or less,
S = 0.015% or less, Al = 0.20% or less,
N = 0.001 to 0.10%, solute N = from .0005 to .004%, and containing Al and N so as to satisfy the 0.52Al / N <10, and, Cr, Mo, One type or two or more types of V satisfy Cr = 2.5% or less, Mo = 1.0% or less, V = 0.1% or less, and (Cr + 3.5Mo + 39V) ≧ 0.1, respectively. BH170 is 45MPa or more and is evaluated by performing heat treatment at 170 ° C for 20 minutes after 2% tensile deformation and at 160 ° C after 2% tensile deformation. BH160 evaluated by performing heat treatment for 10 minutes and BH150 evaluated by performing heat treatment for 10 minutes at 150 ° C. after 2% tensile deformation are both 35 MPa or more, and further, at 100 ° C. for 1 hour. Heat of Bake hardenability performance and anti-aging properties superior hot-rolled steel sheet, characterized in that the yield point elongation at a tensile test after applying a physical is 0.6% or less.
質量%で、Caを0.0005〜0.01%含有することを特徴とする請求項1記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 By mass%, bake hardenability performance and anti-aging properties superior hot-rolled steel sheet according to claim 1 Symbol mounting, characterized in that it contains Ca 0.0005 to 0.01%. 質量%で、Bを0.0001〜0.001%含有することを特徴とする請求項1又は2記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 The hot-rolled steel sheet excellent in paint bake hardening performance and room temperature aging resistance according to claim 1 or 2 , characterized by containing 0.0001 to 0.001% B in mass%. 質量%で、Nbを0.001〜0.03%含有することを特徴とする請求項1〜のいずれか1項に記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 The hot-rolled steel sheet excellent in paint bake hardening performance and room temperature aging resistance according to any one of claims 1 to 3 , characterized by containing 0.001 to 0.03% of Nb in mass%. 質量%で、Ti=0.0001〜0.10%、及び、N−0.29Ti>0.0005を満たすようにTiを含有することを特徴とする請求項1〜のいずれか1項に記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 By mass%, Ti = 0.0001~0.10%, and, N-0.29Ti> 0.0005 in any one of claims 1 to 4, characterized in that it contains Ti so as to satisfy the Hot rolled steel sheet with excellent paint bake hardening performance and room temperature aging resistance. 質量%で、Sn、Cu、Ni、Co、Zn、W、Zr及びMgの1種又は2種以上を、合計で0.001〜1.0%含有することを特徴とする請求項1〜のいずれか1項に記載の塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板。 By mass%, Sn, Cu, Ni, Co, Zn, W, claim the one or more of Zr and Mg, characterized in that it contains 0.001 to 1.0% in total 1-5 A hot-rolled steel sheet excellent in paint bake-hardening performance and normal temperature aging resistance according to any one of the above. 請求項1〜のいずれか1項に記載の熱延鋼板に溶融亜鉛めっき、合金化溶融亜鉛めっき又は電気亜鉛めっきを施したことを特徴とする塗装焼付硬化性能と耐常温時効性に優れた亜鉛めっき熱延鋼板。 The hot-rolled steel sheet according to any one of claims 1 to 6 is hot-dip galvanized, alloyed hot-dip galvanized or electrogalvanized, and is excellent in paint bake hardening performance and room temperature aging resistance. Galvanized hot rolled steel sheet. 請求項1〜のいずれか1項に記載の化学成分を有するスラブを、(Ar3点−100)℃以上の温度で熱間圧延し、熱間圧延終了温度から600℃以下の温度までを平均冷却速度10℃/s以上で冷却し、次いで、550℃以下の温度で巻き取ることを特徴とする塗装焼付硬化性能と耐常温時効性に優れた熱延鋼板の製造方法。 The slab having the chemical component according to any one of claims 1 to 6 is hot-rolled at a temperature of (Ar 3 point-100) ° C or higher, and from the hot rolling end temperature to a temperature of 600 ° C or lower. A method for producing a hot-rolled steel sheet excellent in paint bake hardening performance and room temperature aging resistance, characterized by cooling at an average cooling rate of 10 ° C./s or higher and then winding at a temperature of 550 ° C. or lower.
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