JP4431083B2 - Compound twisted yarn - Google Patents

Compound twisted yarn Download PDF

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JP4431083B2
JP4431083B2 JP2005154943A JP2005154943A JP4431083B2 JP 4431083 B2 JP4431083 B2 JP 4431083B2 JP 2005154943 A JP2005154943 A JP 2005154943A JP 2005154943 A JP2005154943 A JP 2005154943A JP 4431083 B2 JP4431083 B2 JP 4431083B2
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yarn
water
spun
composite twisted
soluble
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JP2006328593A (en
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宏一 手島
雅己 浅野
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ASANONENSHI CO., LTD.
Kuraray Trading Co Ltd
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ASANONENSHI CO., LTD.
Kuraray Trading Co Ltd
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/404Yarns or threads coated with polymeric solutions
    • D02G3/406Yarns or threads coated with polymeric solutions where the polymeric solution is removable at a later stage, e.g. by washing

Description

本発明は複合撚糸およびその複合撚糸を用いて製造した織編物に関する。より詳細には、本発明は、紡績糸の2本以上と水溶性糸を撚り合わせた複合撚糸、並びに該複合撚糸から作製した織編物から水溶性糸を水で溶解除去した織編物に関する。   The present invention relates to a composite twisted yarn and a woven or knitted fabric manufactured using the composite twisted yarn. More specifically, the present invention relates to a composite twisted yarn obtained by twisting two or more spun yarns and a water-soluble yarn, and a woven or knitted fabric obtained by dissolving and removing a water-soluble yarn from water in a woven or knitted fabric produced from the composite twisted yarn.

紡績糸を用いた織編物では、織編物に伸縮性を付与するために、紡績糸とポリウレタン弾性糸を組み合わせた複合糸が広く用いられている。代表的なものとしては、ポリウレタン弾性糸からなる芯糸の周りを紡績用綿で被覆して撚を与えたコアスパンヤーン、ポリウレタン弾性糸からなる芯糸の周りに紡績糸を単層または複層に巻き付けたシングルカバードヤーンやダブルカバードヤーン、2本以上の紡績糸とポリウレタン弾性糸を撚り合わせたプライヤーンがあり、これらの複合糸を用いて伸縮性の織編物を作製することが一般に行われている。   In knitted and knitted fabrics using spun yarns, composite yarns combining spun yarns and polyurethane elastic yarns are widely used to impart stretchability to the woven or knitted fabrics. Typical examples are core spun yarn in which the core yarn made of polyurethane elastic yarn is covered with spinning cotton and twisted, and the spun yarn is wound around the core yarn made of polyurethane elastic yarn as a single layer or multiple layers There are single-covered yarn and double-covered yarn wound around two yarns, and pliers in which two or more spun yarns and polyurethane elastic yarns are twisted together, and it is a common practice to produce elastic knitted fabrics using these composite yarns. ing.

しかしながら、上記した従来の複合糸は、伸縮性の大きなポリウレタン弾性糸を用いているため、糸の取り扱い時や製編織時に特殊な装置および高い技術を必要とする。また、ポリウレタン弾性糸は熱や光などによって経時劣化を引き起こし易いため、ポリウレタン弾性糸を用いた複合糸やそれからなる織編物は伸縮性が徐々に失われ易い。更に、ポリウレタン複合糸を用いて作製した織編物は、柔軟性、ふっくらとした風合、軽量性などが不足することが多い。   However, since the above-mentioned conventional composite yarn uses a polyurethane elastic yarn having a large stretchability, a special device and a high technique are required at the time of handling the yarn and weaving. In addition, since polyurethane elastic yarns are likely to deteriorate over time due to heat, light, etc., composite yarns using polyurethane elastic yarns and woven or knitted fabrics made from such yarns tend to lose their elasticity. Furthermore, the woven or knitted fabric produced using the polyurethane composite yarn often lacks flexibility, plump texture, lightness and the like.

上記の点から、ポリウレタン弾性糸を用いずに伸縮性の羊毛織編物を製造する方法が提案されている(特許文献1を参照)。この特許文献1の方法では、羊毛繊維と水溶性ポリビニルアルコール繊維よりなる混用紡績糸から織編物を形成し、その織編物を水中に浸漬し撹拌下に昇温して水溶性ポリビニルアルコール繊維を収縮させた後に水溶性ポリビニルアルコール繊維を溶解除去して羊毛繊維のみの織編物とし、その織編物をセット処理して、伸縮性の羊毛織編物を製造している。しかしながら、この方法で用いている羊毛繊維と水溶性ポリビニルアルコール繊維よりなる混用紡績糸は、糸強力が十分ではなく、高速の織機や編機を使用して製編織した際に糸切れなどのトラブルが発生し易い。また、該混用紡績糸から形成した織編物から水溶性ポリビニルアルコール繊維を除去して得られる伸縮性の羊毛織編物は、伸縮性が未だ十分ではなく、しかも強度などが不足している。さらに、羊毛の代わりに例えば木綿や合成繊維などの他の繊維を用いてこの方法を実施した場合には、伸縮性の織編物が得られにくい。   From the above point, a method for producing a stretchable woolen knitted fabric without using a polyurethane elastic yarn has been proposed (see Patent Document 1). In the method of Patent Document 1, a woven or knitted fabric is formed from a mixed spun yarn composed of wool fibers and water-soluble polyvinyl alcohol fibers, and the woven or knitted fabric is immersed in water and heated with stirring to shrink the water-soluble polyvinyl alcohol fibers. Then, the water-soluble polyvinyl alcohol fiber is dissolved and removed to make a woven or knitted fabric only of wool fiber, and the woven or knitted fabric is set to produce a stretchable wool knitted or knitted fabric. However, the mixed spun yarn made of wool fiber and water-soluble polyvinyl alcohol fiber used in this method does not have sufficient yarn strength, and troubles such as yarn breakage occur when knitting and weaving using a high-speed loom or knitting machine. Is likely to occur. In addition, a stretchable woolen knitted fabric obtained by removing water-soluble polyvinyl alcohol fibers from a woven or knitted fabric formed from the mixed spun yarn is not yet sufficiently stretchable and lacks strength and the like. Further, when this method is carried out using other fibers such as cotton and synthetic fibers instead of wool, it is difficult to obtain a stretchable woven or knitted fabric.

また、カシミヤ糸の製編織性を向上させて、カシミヤ製の織編物を円滑に製造することを目的として、カシミヤ糸と弱酸性水溶液に溶解性の糸を組み合わせて複合糸とし、その複合糸を製編織して織編物を作製し、該織編物から前記した弱酸溶解性の糸を酸で溶解除去してカシミヤ100%の織編物を製造する方法が提案されている(特許文献2を参照)。しかしながら、この方法により得られるカシミヤ100%の織編物も、伸縮性が未だ十分であるとはいえず、しかも酸により一方の糸を除去しているため、残留する糸の劣化などを生じ易い。   In addition, for the purpose of improving the knitting and weaving properties of cashmere yarn and smoothly producing cashmere woven or knitted fabric, a composite yarn is obtained by combining cashmere yarn and yarn soluble in a weakly acidic aqueous solution. A method for producing a woven or knitted fabric of 100% cashmere by producing a woven or knitted fabric by weaving and knitting, and dissolving and removing the weak acid-soluble yarn from the woven or knitted fabric with an acid (see Patent Document 2). . However, the 100% cashmere knitted or knitted fabric obtained by this method is still not sufficiently stretchable, and one of the yarns is removed by an acid, so that the remaining yarn is likely to deteriorate.

特開平11−241269号公報JP-A-11-241269 欧州特許第1061162B1号明細書European Patent No. 1061162B1

本発明の目的は、ポリウレタン弾性糸を使用しなくても高い伸縮性を有し、しかも軽量性、柔軟性、風合などの特性にも優れる織編物を得ることのできる複合糸を提供することである。
さらに、本発明の目的は、高速の織機や編機を使用した際にも糸切れなどのトラブルの発生がなくて製編織性に優れ、天然繊維製の紡績糸、合成繊維製の紡績糸、半合成繊維製の紡績糸などの種々の紡績糸を使用でき、小ロット多品種に高い生産性で対応でき、しかも細番手から太番手まで任意の太さの複合糸を得ることができる、伸縮性の織編物の製造に有用な、ポリウレタン弾性糸不使用の複合糸を提供することである。
そして、本発明の目的は、前記した複合糸から形成した、高い伸縮性を有し、軽量性、風合、柔軟性などの特性に優れ、しかも織編物を構成している紡績糸からの繊維の素抜けがなくて強力に優れる、ポリウレタン弾性糸不使用の織編物を提供することである。
An object of the present invention is to provide a composite yarn that can obtain a woven or knitted fabric having high stretchability without using a polyurethane elastic yarn and having excellent properties such as lightness, flexibility, and texture. It is.
Furthermore, the object of the present invention is that the occurrence of troubles such as yarn breakage does not occur even when a high-speed loom or knitting machine is used, and it is excellent in knitting and weaving, natural fiber spun yarn, synthetic fiber spun yarn, Various kinds of spun yarns such as semi-synthetic fiber spun yarns can be used, it is possible to respond to small lots and many types with high productivity, and it is possible to obtain composite yarns of any thickness from fine counts to thick counts. It is an object of the present invention to provide a composite yarn that does not use a polyurethane elastic yarn, which is useful in the production of a woven or knitted fabric.
An object of the present invention is a fiber from a spun yarn that is formed from the above-described composite yarn, has high stretchability, is excellent in properties such as lightness, texture, and flexibility, and constitutes a woven or knitted fabric. It is an object of the present invention to provide a woven or knitted fabric not using polyurethane elastic yarns, which is excellent in strength and has no looseness.

本発明者らは、前記した目的を達成するために鋭意検討を重ねてきた。そして、紡績糸1本と水溶性糸を用いて、両者を紡績糸の撚り方向とは逆の撚り方向に特定の撚数で撚り合わせて複合撚糸を製造し、その複合撚糸から織編物を作製して該織編物中の水溶性糸を水に溶解除去した。その結果、ポリウレタン弾性糸を使用していないにも拘わらず、紡績糸の糸長が水溶性糸に比べて長いために、水溶解処理後に、その長い分、伸縮性が得られ、更に水溶性糸が溶け出たところに隙間が生じ、その隙間を埋めようと更に糸に縮む力が生じて、高い伸縮性が付与され、しかもふっくらとしていて良好な感触および風合を有し、軽量性、通気性などの特性に優れる織編物を得ることができた。   The present inventors have intensively studied to achieve the above-described object. Then, using one spun yarn and a water-soluble yarn, both are twisted in a twist direction opposite to the twist direction of the spun yarn to produce a composite twisted yarn, and a woven or knitted fabric is produced from the composite twisted yarn. The water-soluble yarn in the woven or knitted fabric was dissolved and removed in water. As a result, although the polyurethane elastic yarn is not used, the spun yarn has a longer length than the water-soluble yarn. A gap is created where the yarn has melted, and a force to shrink the yarn further to fill the gap, giving high stretchability, and being plump and having a good feel and texture, light weight, A woven or knitted fabric having excellent properties such as air permeability could be obtained.

そこで、本発明者らは、上記で得られた複合撚糸および織編物をベースにして更に研究を続けてきた。そして、1本の紡績糸を用いる代りに、2本以上の紡績糸を使用して、該2本以上の紡績糸と水溶性糸を紡績糸の撚り方向と逆の方向に撚り合わせて複合撚糸を新たに製造し、この複合撚糸を用いて織編物をつくり、該織編物中の水溶性糸を水で溶解除去する実験を行った。その結果、水溶性糸と撚り合わせる紡績糸の数を2本以上にして複合撚糸を製造すると、複合撚糸を製造する際の撚数を、1本の紡績糸と水溶性糸から複合撚糸を製造する場合に比べて少なくしても、製編織時などでの取り扱い性、強度に優れる複合撚糸が得られること、しかも複合撚糸を製造する際の撚数を少なくすることで、複合撚糸製造時の撚糸効率が向上して、生産性が上がることを見出した。   Therefore, the present inventors have continued further research based on the composite twisted yarn and the woven / knitted fabric obtained above. Then, instead of using one spun yarn, two or more spun yarns are used, and the two or more spun yarns and the water-soluble yarn are twisted in a direction opposite to the twisted direction of the spun yarn. Was newly produced, and a woven or knitted fabric was made using this composite twisted yarn, and an experiment was conducted in which water-soluble yarn in the woven or knitted fabric was dissolved and removed with water. As a result, when a composite twisted yarn is manufactured with two or more spun yarns twisted together with a water-soluble yarn, the number of twists when manufacturing the composite twisted yarn is manufactured from one spun yarn and a water-soluble yarn. Even if it is less than the case where it is done, it is possible to obtain a composite twisted yarn excellent in handleability and strength at the time of weaving and weaving, and by reducing the number of twists in producing the composite twisted yarn, It has been found that the efficiency of twisting is improved and the productivity is increased.

さらに、本発明者らは、2本以上の紡績糸と水溶性糸を撚り合わせて製造した複合撚糸から織編物を作製して、織編物中に含まれる水溶性糸を水で溶解除去して得られる織編物では、複合撚糸を製造する際の撚数が少ないにも拘わらず、最終的に得られた織編物では紡績糸からの繊維の素抜けが生じず、糸の強力、ひいては織編物の強力が良好に維持されることを見出した。また、水溶性糸を溶解除去して得られた織編物は、1本の紡績糸と水溶性糸を撚り合わせて製造した複合撚糸から得られた織編物と同様に、高い伸縮性、ふっくらとした良好な感触および風合を有し、しかも軽量性、通気性などの特性にも優れることを見出した。
また、本発明者らは、紡績糸の2本以上と水溶性糸を撚り合わせた複合撚糸では、複合撚糸を構成している2本以上の紡績糸の種類(例えば、繊維素材の種類、紡績糸の太さ、その他の物性など)を変えることで、該複合撚糸から作製した織編物中の水溶性糸を溶解除去して得られる織編物に、前記した高い伸縮性、ふっくらとして感触や風合、軽量性、通気性などの特性と併せて、多種多様の特性や外観などを発現させ得ることを見出し、それらの種々の知見に基づいて本発明を完成した。
Furthermore, the present inventors prepared a woven or knitted fabric from a composite twisted yarn produced by twisting two or more spun yarns and a water-soluble yarn, and dissolved and removed the water-soluble yarn contained in the woven or knitted fabric with water. In the resulting woven or knitted fabric, although the number of twists when producing the composite twisted yarn is small, in the finally obtained woven or knitted fabric, the fiber does not come off from the spun yarn, and the strength of the yarn, and consequently the woven or knitted fabric It was found that the strength of is maintained well. In addition, the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn is highly stretchable and plump, as is the case with the woven or knitted fabric obtained by twisting a single spun yarn and a water-soluble yarn. It has been found that it has a good feel and feel and is excellent in properties such as lightness and breathability.
Further, the present inventors have made a composite twisted yarn obtained by twisting two or more spun yarns and a water-soluble yarn, and the types of the two or more spun yarns constituting the composite twisted yarn (for example, the type of fiber material, spinning By changing the thickness of the yarn, other physical properties, etc.), the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn in the woven or knitted fabric produced from the composite twisted yarn has the above-mentioned high stretchability, fluffy feel and wind. In other words, it has been found that various characteristics and appearances can be exhibited together with characteristics such as lightness and air permeability, and the present invention has been completed based on these various findings.

すなわち、本発明は、
(1)(i) 撚り方向を同じくする紡績糸の2本以上と水溶性糸を撚り合わせた複合撚糸であって;
(ii) 複合撚糸の撚り方向が紡績糸の撚り方向と逆であり;
(iii) 複合撚糸の撚数が、2本以上の紡績糸のそれぞれの撚数のいずれに対しても、0.3〜2倍の範囲にあり;且つ、
(iv) 複合撚糸の質量に基づいて、紡績糸の割合が98〜40質量および水溶性糸の割合が2〜60質量%である;
ことを特徴とする複合撚糸である。
そして、本発明は、
(2) 水溶性糸が、水溶性のフィラメント糸である前記(1)の複合撚糸である。
That is, the present invention
(1) (i) A composite twisted yarn obtained by twisting two or more spun yarns having the same twist direction and a water-soluble yarn;
(Ii) the twist direction of the composite twist yarn is opposite to the twist direction of the spun yarn;
(Iii) the number of twists of the composite twisted yarn is in the range of 0.3 to 2 times the number of twists of each of the two or more spun yarns; and
(Iv) based on the mass of the composite twisted yarn, the proportion of spun yarn is 98-40 mass and the proportion of water-soluble yarn is 2-60 mass%;
This is a composite twisted yarn.
And this invention,
(2) The composite twisted yarn of (1), wherein the water-soluble yarn is a water-soluble filament yarn.

さらに、本発明は、
(3) 前記(1)または(2)の複合撚糸を含む織編物から、複合撚糸中の水溶性糸を水で溶解除去したことを特徴とする織編物;および、
(4) 前記(1)または(2)の複合撚糸を10質量%以上の割合で含む織編物から、複合撚糸中の水溶性糸を水で溶解除去してなる前記(3)の織編物;
である。
Furthermore, the present invention provides
(3) A woven or knitted fabric obtained by dissolving and removing water-soluble yarn in the composite twisted yarn with water from the woven or knitted fabric containing the composite twisted yarn of (1) or (2); and
(4) The woven or knitted fabric according to (3), wherein the water-soluble yarn in the composite twisted yarn is dissolved and removed from the woven or knitted fabric containing the composite twisted yarn of (1) or (2) at a ratio of 10% by mass or more;
It is.

本発明の複合撚糸は、ポリウレタン弾性糸を使用していないにも拘らず、該複合撚糸から織編物を作製し、その織編物中の水溶性糸を水に溶解して除去することにより、高い伸縮性を有し、しかもふっくらとしていて良好な感触および風合を有し、且つ軽量性、通気性などの特性にも優れる織編物を得ることができる。
本発明の複合撚糸では、紡績糸として、羊毛繊維よりなる紡績糸だけではなく、他の天然繊維製の紡績糸、合成繊維製の紡績糸、半合成繊維製の紡績糸などの種々の紡績糸を使用できる。
2本以上の紡績糸を水溶性糸と特定の撚数で、紡績糸の撚り方向と逆の方向に撚り合わせてなる本発明の複合撚糸は、その撚数が1本の紡績糸を水溶性糸と撚り合わせた複合撚糸に比べて少なくても、複合撚糸の強力、製編織時の取り扱い性などに優れている。しかも、本発明の複合撚糸は撚数を少なくできることから、複合撚糸を製造する際の撚糸を効率良く行うことができ、生産性の向上を図ることができる。
The composite twisted yarn of the present invention is high by preparing a woven or knitted fabric from the composite twisted yarn, even though no polyurethane elastic yarn is used, and dissolving and removing the water-soluble yarn in the woven or knitted fabric in water. A knitted or knitted fabric that has stretchability, is plump, has a good touch and feel, and is excellent in properties such as lightness and breathability can be obtained.
In the composite twisted yarn of the present invention, various spun yarns such as spun yarns made of wool fibers as well as spun yarns made of other natural fibers, spun yarns made of synthetic fibers, spun yarns made of semi-synthetic fibers, etc. Can be used.
The composite twisted yarn of the present invention in which two or more spun yarns are twisted together with a water-soluble yarn with a specific twist number in the direction opposite to the twist direction of the spun yarn. Compared to a composite twisted yarn twisted with a yarn, the composite twisted yarn has excellent strength and handling at the time of weaving and weaving. Moreover, since the composite twisted yarn of the present invention can reduce the number of twists, it is possible to efficiently perform the twisted yarn when producing the composite twisted yarn, and to improve the productivity.

本発明の複合撚糸は、糸中に水溶性糸が存在するために毛羽が少なく、しかも水溶性糸が補強の役割を果たす。その上、紡績糸を2本以上用いている点からも強度に優れる。そのため、本発明の複合撚糸は、高速の織機や編機を使用して、糸切れなどのトラブルを発生することなく、更には整経の際に糊付け処理を行わなくても、織編物を高い生産性で円滑に製造することができる。
本発明の複合撚糸は、細番手から太番手まで任意の紡績糸を使用して製造でき、しかも2本以上で用いられる紡績糸の種類や組み合わせなどを選択することで、最終的に得られる水溶性糸を溶解除去した後の織編物に多種多様の性質、風合、外観などを発現させることができる。
本発明の複合撚糸および伸縮性の織編物は、ポリウレタン弾性糸を含まないため、ポリウレタン弾性糸の使用に起因する熱や光などによる経時劣化がない。
The composite twisted yarn of the present invention has less fuzz due to the presence of the water-soluble yarn in the yarn, and the water-soluble yarn plays a reinforcing role. In addition, the strength is excellent in that two or more spun yarns are used. Therefore, the composite twisted yarn of the present invention has a high woven or knitted fabric without using a high-speed loom or knitting machine, without causing trouble such as yarn breakage, and even without performing a gluing process during warping. It can be manufactured smoothly with productivity.
The composite twisted yarn of the present invention can be manufactured using any spun yarn from fine count to thick count, and the final water-soluble product can be obtained by selecting the type or combination of spun yarn used in two or more. A variety of properties, texture, appearance, and the like can be exhibited in the woven or knitted fabric after dissolving and removing the sex yarn.
Since the composite twisted yarn and stretchable woven or knitted fabric of the present invention do not contain polyurethane elastic yarn, there is no deterioration over time due to heat, light, etc. due to the use of polyurethane elastic yarn.

本発明の複合撚糸を含む織編物を水で処理して複合撚糸中の水溶性糸を水で溶解除去して得られる本発明の織編物は、紡績糸の糸長が水溶性糸に比べて長いため、水溶解処理後の織編物では、その長い分、伸縮性が得られ、さらに水溶性糸が溶け出たところに隙間が生じ、その隙間を埋めようとして糸に縮む力が生ずることにより、高い伸縮性を有し、しかも外観、感触、通気性、軽量性に優れる。
さらに、本発明の複合撚糸から作製した織編物中の水溶性糸を水で溶解除去して得られる織編物では、2本以上の紡績糸が互いに合撚した状態になっているため、布帛を構成している紡績糸からの繊維の素抜けが生じず、強力、耐久性に優れる。
そのため、本発明の織編物は、前記した特性を活かして、衣類用途、医療用途、工業資材などの広範な分野に有効に使用することができる。
The woven or knitted fabric of the present invention obtained by treating the woven or knitted fabric containing the composite twisted yarn of the present invention with water and dissolving and removing the water-soluble yarn in the composite twisted yarn with water has a spun yarn length that is longer than that of the water-soluble yarn. Because it is long, in the woven or knitted fabric after the water-dissolving treatment, stretchability can be obtained for a long time. It has high stretchability and is excellent in appearance, feel, breathability and lightness.
Furthermore, in the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn in the woven or knitted fabric produced from the composite twisted yarn of the present invention with water, two or more spun yarns are in a state of being twisted together. The fiber does not come off from the composed spun yarn and is excellent in strength and durability.
Therefore, the woven or knitted fabric of the present invention can be effectively used in a wide range of fields such as clothing use, medical use, and industrial materials, taking advantage of the above-described properties.

以下に本発明について詳細に説明する。
本発明の複合撚糸は、紡績糸2本以上と水溶性糸から構成されている。
本発明の複合撚糸では、複合撚糸を構成する2本以上の紡績糸の撚り方向が同じであること、および複合撚糸の撚り方向が該2本以上の紡績糸の撚り方向と逆になっていることが必要である。2本以上の紡績糸の撚り方向が同じであることにより、該2本以上の紡績糸と水溶性糸を紡績糸の撚り方向と逆の方向に撚り合わせた本発明の複合撚糸では、全ての紡績糸が部分的にまたは完全に解撚されて元の紡績糸よりも長くなった状態になっている。そのため、本発明の複合撚糸を用いて作製した織編物から水溶性糸を水で溶解除去して得られる織編物に高い伸縮性が付与される。
The present invention is described in detail below.
The composite twisted yarn of the present invention is composed of two or more spun yarns and a water-soluble yarn.
In the composite twisted yarn of the present invention, the twist direction of two or more spun yarns constituting the composite twisted yarn is the same, and the twist direction of the composite twisted yarn is opposite to the twist direction of the two or more spun yarns. It is necessary. In the composite twisted yarn of the present invention in which the twist direction of two or more spun yarns is the same, the two or more spun yarns and the water-soluble yarn are twisted in the direction opposite to the twist direction of the spun yarn. The spun yarn is partially or completely untwisted so that it is longer than the original spun yarn. Therefore, high stretchability is imparted to the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn with water from the woven or knitted fabric produced using the composite twisted yarn of the present invention.

それに対して、2本以上の紡績糸の撚り方向が互いに異なる場合(例えばS撚の紡績糸1本とZ撚の紡績糸1本の合計2本の紡績糸を用いた場合、S撚の紡績糸1本とZ撚の紡績糸2本の合計3本の紡績糸を用いる場合、S撚の紡績糸2本とZ撚の紡績糸1本の合計3本の紡績糸を用いる場合など)には、複合撚糸を製造するための紡績糸と水溶性糸の撚り合わせ(以下これを「上撚り」ということがある)をS方向またはZ方向のいずれにしても、2本以上の紡績糸のうちの1部の紡績糸(上撚りと逆の撚り方向を有する紡績糸)は解撚するが、残りの紡績糸(上撚りと同じ撚り方向を有する紡績糸)では上撚りをかける前よりも同じ方向に撚りが強くかかった状態になる。そのため、そのような複合撚糸を用いて織編物を作製して該織編物から水溶性糸を水で溶解除去しても、伸縮性の高い織編物が得られず、織編物の風合が硬くなり、しかも軽量性、通気性などが不足したものになる。   On the other hand, when two or more spun yarns are twisted in different directions (for example, when using a total of two spun yarns, one S spun yarn and one Z twist spun yarn, S twist spun When using a total of three spun yarns of one yarn and two Z-twisted yarns, when using a total of three spun yarns of two S-twisted yarns and one Z-twisted spun yarn, etc.) Is a combination of two or more spun yarns, regardless of whether the spun yarn and water-soluble yarn for producing the composite twisted yarn are twisted together (hereinafter sometimes referred to as “upside twist”) in the S direction or the Z direction. One part of the spun yarn (spun yarn having a twist direction opposite to the top twist) is untwisted, but the remaining spun yarn (spun yarn having the same twist direction as the top twist) is more than before applying the top twist. The twist is strongly applied in the same direction. Therefore, even when a woven or knitted fabric is prepared using such a composite twisted yarn and the water-soluble yarn is dissolved and removed from the woven or knitted fabric with water, a highly stretchable woven or knitted fabric cannot be obtained, and the texture of the woven or knitted fabric is hard. In addition, lightness and air permeability are insufficient.

本発明の複合撚糸を構成する紡績糸は、水(熱水、温水、冷水)に溶解しない繊維から形成されている限りは、紡績糸を形成する繊維の種類は特に制限されない。
本発明の複合撚糸を構成する紡績糸は、例えば、木綿、麻、絹、ウールなどの天然繊維、ポリエステル繊維、ポリアミド繊維、ポリプロピレン繊維、アクリル繊維、水(熱水)不溶性のポリビニルアルコール系繊維、ポリ塩化ビニリデン繊維などの合成繊維、アセテートなどの半合成繊維、レーヨン、キュプラなどの再生繊維などから選ばれる1種の繊維からなる単独紡績糸、前記した繊維の2種以上からなる混紡紡績糸のいずれであってもよい。複合撚糸およびそれを用いて製造する織編物の用途などに応じて、適当な紡績糸を選択して使用すればよい。
本発明の複合撚糸を構成する2本以上の紡績糸は、同じ繊維から形成されていてもよいし、または異なった繊維から形成されていてもよい。何ら限定されるものではないが、例えば、2本以上の全ての紡績糸が綿紡績糸であってもよいし、2本以上の紡績糸のすべてが同じ合成繊維よりなる紡績糸であってもよいし、2本以上の紡績糸のうちの一部の紡績糸が綿紡績糸で残りの紡績糸がウール紡績糸、合成繊維製紡績糸および/または綿と合成繊維の混紡糸であってもよいし、2本以上の紡績糸のうちの一部の紡績糸が特定の合成繊維よりなる紡績糸で残りの紡績糸がそれとは異なる合成繊維よりなる紡績糸であってもよい。
As long as the spun yarn constituting the composite twisted yarn of the present invention is formed from fibers that do not dissolve in water (hot water, hot water, cold water), the type of fiber forming the spun yarn is not particularly limited.
The spun yarn constituting the composite twisted yarn of the present invention includes, for example, natural fibers such as cotton, hemp, silk, and wool, polyester fibers, polyamide fibers, polypropylene fibers, acrylic fibers, water (hot water) insoluble polyvinyl alcohol fibers, A single spun yarn composed of one type of fiber selected from synthetic fibers such as polyvinylidene chloride fiber, semi-synthetic fiber such as acetate, regenerated fiber such as rayon and cupra, and a mixed spun yarn composed of two or more of the above-mentioned fibers Either may be sufficient. An appropriate spun yarn may be selected and used according to the use of the composite twisted yarn and the woven or knitted fabric produced using the same.
Two or more spun yarns constituting the composite twisted yarn of the present invention may be formed of the same fiber or may be formed of different fibers. Although not limited in any way, for example, all the two or more spun yarns may be cotton spun yarns, or all of the two or more spun yarns may be spun yarns made of the same synthetic fiber. Even if some of the two or more spun yarns are cotton spun yarns and the remaining spun yarns are wool spun yarns, synthetic fiber spun yarns and / or mixed yarns of cotton and synthetic fibers. Alternatively, some of the two or more spun yarns may be spun yarns made of a specific synthetic fiber, and the remaining spun yarns may be spun yarns made of a different synthetic fiber.

本発明の複合撚糸を構成する2本以上の紡績糸は、単糸、双糸または3本以上の合撚糸のいずれであってもよい。例えば、2本以上の紡績糸の全てが単糸であってもよいし、全てが双糸であってもよいし、または全てが3本以上の合撚糸であってもよい。また、例えば、2本以上の紡績糸の一部の紡績糸が単糸で他の紡績糸が双糸または3本以上の合撚糸であってもよいし、2本以上の紡績糸の一部の紡績糸が双糸で他の紡績糸が3本以上の合撚糸であってもよい。
そのうちでも、本発明の複合撚糸を構成する2本以上の紡績糸は、いずれも単糸であることが、複合撚糸を製造する際に工程を省略化できる点、紡績糸の解撚に伴う自由度が大きく、そのことが伸縮性に大きく寄与する点から好ましい。
The two or more spun yarns constituting the composite twisted yarn of the present invention may be either a single yarn, a double yarn or three or more twisted yarns. For example, all of the two or more spun yarns may be single yarns, all may be twin yarns, or all may be three or more twisted yarns. Further, for example, some spun yarns of two or more spun yarns may be single yarns, and other spun yarns may be twin yarns or three or more spun yarns, or part of two or more spun yarns These spun yarns may be twin yarns and the other spun yarns may be three or more twisted yarns.
Among them, the two or more spun yarns constituting the composite twisted yarn of the present invention are all single yarns, the process can be omitted when producing the composite twisted yarn, and the freedom associated with the untwisting of the spun yarn The degree is preferable because it greatly contributes to stretchability.

本発明の複合撚糸を構成する2本以上の紡績糸の撚数は特に制限されないが、撚数をT(単位:回/2.54cm)、綿番手をS(単位:番手)とすると、K=T/√Sで表される撚係数Kが2〜4の紡績糸が、紡績糸の品質安定性、複合撚糸製造時の生産性、紡績糸の入手容易性などの点から好ましく用いられる。
但し、本発明では、「複合撚糸の撚数が、2本以上の紡績糸のそれぞれの撚数のいずれに対しても、0.3〜2倍の範囲にある」という要件を満たすことが必要であり、そのために2本以上の紡績糸は前記の要件を満たす撚数を有している必要がある。
例えば、2本の紡績糸A,Bを用いる場合に、紡績糸Aの撚数が50回/m、紡績糸Bの撚数が500回/mであると、紡績糸Aの撚数の0.3〜2倍は15〜100回/m、紡績糸Bの撚数の0.3〜2倍は150〜1000回/mとなり、紡績糸Aの撚数の0.3〜2倍の値と紡績糸Bの撚数の0.3〜2倍の値に共通する部分(共通する数値範囲)がなく、このような撚数の紡績糸Aと紡績糸Bを用いた場合には、複合撚糸の撚数(上撚りの数)が本発明で規定する上記の要件を満たさなくなる。かかる点から、本発明では、2本以上の紡績糸の各紡績糸の撚数を0.3〜2倍したときに共通する数値(数値範囲)が存在しない紡績糸同士は併用できない。
The number of twists of two or more spun yarns constituting the composite twisted yarn of the present invention is not particularly limited, but when the number of twists is T (unit: times / 2.54 cm) and the cotton count is S (unit: count), K A spun yarn having a twist coefficient K of 2 to 4 represented by = T / √S is preferably used from the viewpoints of quality stability of the spun yarn, productivity at the time of producing the composite twisted yarn, availability of the spun yarn, and the like.
However, in the present invention, it is necessary to satisfy the requirement that “the number of twists of the composite twisted yarn is in the range of 0.3 to 2 times the number of twists of each of the two or more spun yarns”. Therefore, it is necessary that two or more spun yarns have a twist number satisfying the above requirements.
For example, when two spun yarns A and B are used, if the number of twists of the spun yarn A is 50 times / m and the number of twists of the spun yarn B is 500 times / m, the number of twists of the spun yarn A is 0. .3 to 2 times is 15 to 100 times / m, 0.3 to 2 times the twist number of the spun yarn B is 150 to 1000 times / m, and is 0.3 to 2 times the number of twists of the spun yarn A There is no common part (common numerical range) in the value of 0.3 to 2 times the twist number of the spun yarn B, and when the spun yarn A and spun yarn B of such a twist number are used, The number of twists of the twisted yarn (number of top twists) does not satisfy the above-mentioned requirements defined in the present invention. From this point, in the present invention, spun yarns having no common numerical value (numerical value range) when the number of twists of each spun yarn of two or more spun yarns is 0.3 to 2 times cannot be used together.

ここで、本発明でいう「紡績糸の撚数」とは、紡績糸を製造するに当たって最後にかけられた撚りの撚数をいう。例えば、紡績糸が単糸である場合は単糸を製造するために紡績時にかけられた撚数をいい、双糸の場合は双糸を製造するために2本の糸を撚り合わせたときの撚数をいい、3本以上の合撚糸の場合は合撚糸を製造するために3本以上の糸を撚り合わせたときの撚数をいう。
紡績糸が双糸または3本以上の合撚糸である場合は、双糸または3本以上の合撚糸を製造した際の最後の撚りの撚方向が、双糸または合撚糸の製造に用いた単糸の撚方向と逆方向になっていること、また該最後の撚りの撚数(本発明でいう紡績糸の撚数;双糸または合撚糸を製造した際の撚数)が、双糸または合撚糸の製造に用いた単糸の撚数の0.3〜0.9倍であることが、撚糸の生産性、糸のハンドリング性、風合、紡績糸の入手容易性などの点から好ましい。
Here, the “twisted number of spun yarn” as used in the present invention refers to the number of twisted yarns applied last in the production of spun yarn. For example, when the spun yarn is a single yarn, it refers to the number of twists applied at the time of spinning to produce a single yarn, and in the case of a double yarn, when two yarns are twisted together to produce a double yarn This refers to the number of twists. In the case of three or more twisted yarns, the number of twists when three or more yarns are twisted together to produce a twisted yarn.
When the spun yarn is a twin yarn or three or more twisted yarns, the final twist direction when the twin yarn or three or more twisted yarns are manufactured is the single twisted yarn or the twisted yarn used in the production of the twin yarn or the twisted yarn. The twist direction of the yarn is opposite to that of the yarn, and the number of twists of the final twist (the number of twists of the spun yarn referred to in the present invention; the number of twists when the double yarn or the twisted yarn is manufactured) is double yarn or It is preferably 0.3 to 0.9 times the number of twists of the single yarn used for producing the twisted yarn from the viewpoints of the productivity of the twisted yarn, the handleability of the yarn, the texture, the availability of the spun yarn, and the like. .

また、紡績糸の番手としては、綿番手で5番〜200番、更には5番〜140番、特に10番〜120番のものが、複合撚糸を製造する際の工程性、紡績糸の入手の容易性、作製する生地に対する市場の要求などの点から好ましく用いられる。   In addition, as the yarn count of the spun yarn, the cotton count of 5 to 200, further 5 to 140, especially 10 to 120, the processability when producing the composite twisted yarn, the acquisition of the spun yarn It is preferably used from the viewpoints of ease of use and market demand for the fabric to be produced.

水溶性糸としては、大気圧下で、水の沸騰温度(約100℃)までの温度で水(熱水)に溶解する糸が、本発明の複合撚糸を用いて製造した織編物から水溶性糸を水で溶解除去する際の除去の容易性、取扱性などの点から好ましく用いられる。特に、水溶性糸としては、水溶性糸自体を単独で温度80℃以上の水に浸漬して30分放置したときに、浸漬前の水溶性糸の質量に対して、85質量%以上、特に95質量%以上が前記水に溶解する水溶性糸(水不溶性の残渣が15質量%未満、特に5質量%未満である水溶性糸)がより好ましく用いられる。水溶性糸の水溶解性が低いと、複合撚糸を用いて製造した織編物を水で処理して複合撚糸中の水溶性糸を溶解除去する際に、水溶性糸の除去が不十分となり、織編物に充分な伸縮性、軽量性などを付与しにくくなる。   As a water-soluble yarn, a yarn that dissolves in water (hot water) under atmospheric pressure at a temperature up to the boiling temperature of water (about 100 ° C.) is water-soluble from a woven or knitted fabric produced using the composite twisted yarn of the present invention. It is preferably used from the viewpoints of ease of removal and handling when the yarn is dissolved and removed with water. In particular, as the water-soluble yarn, when the water-soluble yarn itself is immersed in water having a temperature of 80 ° C. or more and left for 30 minutes, it is 85% by mass or more, particularly with respect to the mass of the water-soluble yarn before immersion. More preferably, 95% by mass or more of a water-soluble yarn that dissolves in water (water-soluble yarn having a water-insoluble residue of less than 15% by mass, particularly less than 5% by mass). If water solubility of the water-soluble yarn is low, when the woven or knitted fabric produced using the composite twisted yarn is treated with water to dissolve and remove the water-soluble yarn in the composite twisted yarn, the removal of the water-soluble yarn becomes insufficient, It becomes difficult to impart sufficient stretchability and light weight to the woven or knitted fabric.

水溶性糸を構成する繊維としては、前記した水溶解性を水溶性糸に与える繊維であればいずれも使用でき、例えば、水可溶性ポリビニルアルコール系繊維、水可溶性エチレン−ビニルアルコール系共重合体繊維、水可溶性ポリアミド繊維などを挙げることができる。そのうちでも、水可溶性ポリビニルアルコール系繊維、水可溶性エチレン−ビニルアルコール系共重合体繊維が、繊維強力、水(熱水)への高い溶解性、生分解性、入手容易性などの点から好ましく用いられる。水可溶性ポリビニルアルコール系繊維は、従来から広く知られており、例えば、水溶性ビニロンなどとして販売されている。特に、水可溶性ポリビニルアルコール系繊維は生分解性であるため、織編物からポリビニルアルコール系繊維を水で溶解除去した際に排出する廃液を微生物により円滑に処理して浄化することができる。   Any fiber can be used as the fiber constituting the water-soluble yarn as long as it is a fiber that imparts water solubility to the water-soluble yarn. For example, water-soluble polyvinyl alcohol fiber, water-soluble ethylene-vinyl alcohol copolymer fiber And water-soluble polyamide fibers. Among them, water-soluble polyvinyl alcohol fibers and water-soluble ethylene-vinyl alcohol copolymer fibers are preferably used in terms of fiber strength, high solubility in water (hot water), biodegradability, availability, and the like. It is done. Water-soluble polyvinyl alcohol fibers have been widely known, and are sold as, for example, water-soluble vinylon. In particular, since the water-soluble polyvinyl alcohol fiber is biodegradable, the waste liquid discharged when the polyvinyl alcohol fiber is dissolved and removed from the woven or knitted fabric with water can be smoothly treated and purified by microorganisms.

水溶性糸は、水溶性である限りは、フィラメント糸であってもまたは紡績糸であってもいずれでもよい。ただし、水溶性糸が紡績糸の場合は、その撚方向は、複合撚糸の撚方向と同じであることが、複合撚糸中における非水溶性の紡績糸の糸長を長くすることができ、生地の伸縮性が高くなる点から好ましい。水溶性糸としては、どちらかというと、フィラメント糸を用いることが、複合撚糸における水溶性糸の混率が低い場合にも複合撚糸から作製した織編物を水で処理して水溶性糸を溶解除去する際に水溶性糸の除去が速やかに且つ良好に行われる点、本発明の複合撚糸の糸強力が高くなる点、細い番手の紡績糸が使用し易い点、低混率で使用できコストを低減できる点などから好ましい。   The water-soluble yarn may be either a filament yarn or a spun yarn as long as it is water-soluble. However, when the water-soluble yarn is a spun yarn, the twisting direction is the same as the twisting direction of the composite twisted yarn, which can increase the length of the water-insoluble spun yarn in the composite twisted yarn, It is preferable from the point that the stretchability of the is high. As a water-soluble yarn, it is rather possible to use a filament yarn. Even when the mixing ratio of the water-soluble yarn in the composite twisted yarn is low, the woven or knitted fabric made from the composite twisted yarn is treated with water to dissolve and remove the water-soluble yarn. The water-soluble yarn is removed quickly and satisfactorily, the yarn strength of the composite twisted yarn of the present invention is increased, the spun yarn with a fine count is easy to use, and it can be used at a low blending rate to reduce the cost. It is preferable because it can be done.

水溶性糸の太さは、15〜200dtex、特に25〜100dtexであることが、紡績糸との撚り合わせの容易性、複合撚糸の強力、紡績毛羽の低減、複合撚糸から形成した織編物からの水溶性糸の溶解除去の容易性、水溶性糸を溶解した後の生地の伸縮性、水溶性糸の生産性などの点から好ましい。   The thickness of the water-soluble yarn is 15 to 200 dtex, particularly 25 to 100 dtex. The ease of twisting with the spun yarn, the strength of the composite twisted yarn, the reduction of the spinning fluff, and the woven or knitted fabric formed from the composite twisted yarn This is preferable from the viewpoints of ease of dissolution and removal of the water-soluble yarn, stretchability of the fabric after dissolving the water-soluble yarn, productivity of the water-soluble yarn, and the like.

本発明の複合撚糸において、除去用糸として、アルカリや酸に溶解または分解する糸ではなくて水に溶解する糸(水溶性糸)を使用した理由としては、織編物を形成している複合撚糸の一部を除去するためにアルカリや酸で処理した場合は、複合撚糸を構成している紡績糸の変質や分解などを生ずる恐れがあるが、水で処理した場合には紡績糸の変質や分解を生ずる恐れがないことが挙げられる。本発明では、複合撚糸を構成する除去用糸(織編物にした後に除去する糸)として、アルカリや酸により溶解または分解する糸ではなくて、水に溶解する水溶性糸を使用していることにより、複合撚糸を構成する紡績糸として広範囲の種々の紡績糸を使用することができる。すなわち、本発明では、複合撚糸を構成する紡績糸として、水に溶解しない糸である限りは、アルカリや酸によって溶解または分解し易い糸であっても使用することができ、複合撚糸を構成する紡績糸の種類や選択の幅が広がり、ひいては複合撚糸から形成される織編物の種類、特性、風合を色々なものにすることができる。   In the composite twisted yarn of the present invention, the reason why the yarn (water-soluble yarn) that dissolves in water rather than the yarn that dissolves or decomposes in alkali or acid is used as the removing yarn is that the composite twisted yarn forming a woven or knitted fabric is used. When treated with alkali or acid to remove a part of the yarn, the spun yarn constituting the composite twisted yarn may be altered or decomposed. However, when treated with water, There is no risk of decomposition. In the present invention, a water-soluble yarn that dissolves in water, not a yarn that dissolves or decomposes with an alkali or an acid, is used as a removal yarn constituting the composite twisted yarn (yarn that is removed after forming a woven or knitted fabric). Accordingly, a wide variety of spun yarns can be used as the spun yarn constituting the composite twisted yarn. That is, in the present invention, as the spun yarn constituting the composite twisted yarn, as long as it is a yarn that does not dissolve in water, even a yarn that is easily dissolved or decomposed by an alkali or acid can be used. The types of spun yarns and the range of selection can be expanded, and as a result, the types, characteristics, and textures of the woven or knitted fabric formed from the composite twisted yarn can be varied.

特に、水溶性糸として水可溶性ポリビニルアルコール系繊維または水可溶性エチレン−ビニルアルコール系共重合体繊維からなる糸を用いた場合には、水溶性ポリビニルアルコールまたは水可溶性エチレン−ビニルアルコール系共重合体繊維は生分解性を有するため、溶解後の廃液を微生物などにより分解して処理することができる。   Particularly when water-soluble polyvinyl alcohol fiber or water-soluble ethylene-vinyl alcohol copolymer fiber is used as the water-soluble yarn, water-soluble polyvinyl alcohol or water-soluble ethylene-vinyl alcohol copolymer fiber is used. Since it has biodegradability, the waste liquid after dissolution can be decomposed and treated with microorganisms.

本発明の複合撚糸は、複合撚糸の質量に基づいて、紡績糸を98〜40質量%(2本以上の紡績糸の合計質量)および水溶性糸を2〜60質量%の割合で含む。本発明の複合撚糸では、紡績糸が95〜50質量%および水溶性糸が5〜50質量%の割合であることが好ましく、紡績糸が90〜60質量%および水溶性糸が10〜40質量%であることがより好ましい。
紡績糸および水溶性糸の割合を前記範囲にすることによって、製編織性、糸強力、撚の安定性などに優れる複合撚糸が得られる。しかも、複合撚糸から作製した織編物から複合撚糸中の水溶性糸を水で溶解除去する際に、水溶性糸の除去が良好に行われ、しかも水溶性糸の除去された隙間を埋めようとする収縮力が織編物に働いて、伸縮性を向上させることができ、併せて織編物の風合、感触、軽量性、通気性なども向上する。
複合撚糸における水溶性糸の割合が上記範囲よりも少ないと(紡績糸の割合が上記範囲よりも多いと)、複合撚糸から製造した織編物から水溶性糸を除去した後の織編物の伸縮性、軽量性、通気性などが低下し、しかも硬くて劣った風合になり易い。一方、複合撚糸における水溶性糸の割合が上記範囲よりも多いと(紡績糸の割合が上記範囲よりも少ないと)、複合撚糸から製造した織編物から水溶性糸を除去した後の織編物は、形態安定性に劣るようになって、目寄れなどが生じ易くなる。
The composite twisted yarn of the present invention contains 98 to 40% by mass of spun yarn (total mass of two or more spun yarns) and 2 to 60% by mass of water-soluble yarn based on the mass of the composite twisted yarn. In the composite twisted yarn of the present invention, it is preferable that the spun yarn is 95 to 50% by mass and the water-soluble yarn is 5 to 50% by mass, the spun yarn is 90 to 60% by mass and the water-soluble yarn is 10 to 40% by mass. % Is more preferable.
By setting the ratio of the spun yarn and the water-soluble yarn within the above range, a composite twisted yarn excellent in knitting and weaving property, yarn strength, twist stability, and the like can be obtained. Moreover, when the water-soluble yarn in the composite twisted yarn is dissolved and removed from the woven or knitted fabric made from the composite twisted yarn with water, the water-soluble yarn is well removed and an attempt is made to fill the gap from which the water-soluble yarn has been removed. The shrinkage force acting on the woven or knitted fabric can improve the stretchability, and at the same time, the texture, feel, lightness, breathability, etc. of the woven or knitted fabric are also improved.
If the proportion of water-soluble yarn in the composite twisted yarn is less than the above range (if the proportion of spun yarn is more than the above range), the elasticity of the woven or knitted fabric after removing the water-soluble yarn from the woven or knitted fabric produced from the composite twisted yarn , Lightness, air permeability and the like are lowered, and the texture is hard and inferior. On the other hand, when the proportion of the water-soluble yarn in the composite twisted yarn is greater than the above range (if the proportion of the spun yarn is less than the above range), the woven or knitted fabric after removing the water-soluble yarn from the woven or knitted fabric produced from the composite twisted yarn is However, it becomes inferior in form stability, and it is easy to cause blindness.

本発明の複合撚糸を構成する紡績糸の本数(糸本数)は、2本以上であることが必要であり、撚糸機のクリル本数の制限、品質管理などの点から、2本または3本であることが好ましい。本発明の複合撚糸は、2本以上の紡績糸を用いて形成されていることにより、紡績糸の撚り方向と逆の方向の複合撚糸を製造する際の撚数(上撚りの数)を紡績糸の0.3〜2倍という小さい値に保ちながら、製編織時の取り扱い性や強力などに優れる複合撚糸を、高い撚糸効率で生産性良く製造することができる。しかも、本発明の複合撚糸から作製した織編物から水溶性糸を水で溶解除去して得られる織編物において、前記2本以上の紡績糸が合撚した状態になりながら解撚されているために、紡績糸を形成する繊維の素抜けが防止されて、紡績糸の強力、ひいては織編物の強力を高く保つことができる。
また、水溶性糸の本数は1〜3本、特に1〜2本であることが撚糸機のクリル本数を減らせる点で、また複合撚糸から作製した織編物からの水溶性糸の溶解除去の容易性などの点から好ましい。
The number of spun yarns (number of yarns) constituting the composite twisted yarn of the present invention needs to be 2 or more. From the viewpoint of limiting the number of krills of the twisting machine, quality control, etc., 2 or 3 Preferably there is. Since the composite twisted yarn of the present invention is formed using two or more spun yarns, the number of twists (the number of upper twists) when producing a composite twisted yarn in the direction opposite to the twisted direction of the spun yarn is spun. A composite twisted yarn excellent in handling property and strength at the time of weaving and weaving can be produced with high twisting efficiency and high productivity while maintaining a small value of 0.3 to 2 times that of the yarn. Moreover, in the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn with water from the woven or knitted fabric produced from the composite twisted yarn of the present invention, the two or more spun yarns are untwisted while being in a twisted state. In addition, it is possible to prevent the fibers forming the spun yarn from slipping out, and to maintain the strength of the spun yarn and, in turn, the strength of the woven or knitted fabric.
In addition, the number of water-soluble yarns is 1 to 3, particularly 1 to 2 in that the number of creels of the twisting machine can be reduced, and the water-soluble yarn can be dissolved and removed from the woven or knitted fabric made from the composite twisted yarn. It is preferable in terms of ease.

本発明の複合撚糸では、2本以上の紡績糸は同じ撚り方向を有していて且つ複合撚糸の撚り方向(紡績糸2本以上と水溶性糸を撚り合わせる際の撚り方向;上撚りの方向)が、紡績糸の撚り方向(以下紡績糸の撚りを「下撚」ということがある)と逆になっていることが必要である。さらに、本発明の複合撚糸では、複合撚糸の撚数(上撚りの撚数)が、2本以上の紡績糸のそれぞれの撚数のいずれに対しても、0.3〜2倍の範囲にあることが必要であり、0.3〜1.75倍の範囲にあることが好ましく、0.35倍以上で1.3倍未満の範囲にあることがより好ましい。
例えば、600回/m(Z撚)の紡績糸2本と水溶性糸を撚り合わせて(上撚りして)本発明の複合撚糸を製造する場合は、該2本の紡績糸と水溶性糸を600回/m×(0.3〜2倍)=180〜1200回/mの撚数でS方向に撚り合わせて本発明の複合撚糸にする。
また、例えば、500回/m(S撚)の紡績糸Aおよび800回/m(S撚)の紡績糸Bという撚数の異なる2本の紡績糸を水溶性糸とZ方向に撚り合わせて(上撚りして)本発明の複合撚糸を製造する場合は、500回/m×(0.3〜2倍)=150〜1000回/mと、800回/m×(0.3〜2倍)=240〜1600回/mの共通した数値範囲である240〜1000回/mの範囲のZ撚をかけて本発明の複合撚糸にする。
In the composite twisted yarn of the present invention, two or more spun yarns have the same twist direction and the twist direction of the composite twisted yarn (twist direction when twisting two or more spun yarns and a water-soluble yarn; the direction of the top twist) ) Is reverse to the twist direction of the spun yarn (hereinafter, the twist of the spun yarn is sometimes referred to as “bottom twist”). Furthermore, in the composite twisted yarn of the present invention, the number of twists of the composite twisted yarn (the number of twists of the upper twist) is in the range of 0.3 to 2 times with respect to any of the numbers of twists of two or more spun yarns. It is necessary to be within a range of 0.3 to 1.75 times, and more preferably within a range of 0.35 times or more and less than 1.3 times.
For example, in the case of producing the composite twisted yarn of the present invention by twisting (up twisting) two spun yarns of 600 times / m (Z twist) and a water-soluble yarn, the two spun yarns and the water-soluble yarn. Is twisted in the S direction at a twist number of 600 times / m × (0.3 to 2 times) = 180 to 1200 times / m to obtain the composite twisted yarn of the present invention.
Further, for example, two spun yarns having different twist numbers, that is, a spun yarn A of 500 times / m (S twist) and a spun yarn B of 800 times / m (S twist) are twisted together with a water-soluble yarn in the Z direction. When producing the composite twisted yarn of the present invention (by twisting), 500 times / m × (0.3-2 times) = 150-1000 times / m and 800 times / m × (0.3-2) Double) = Z twist in the range of 240 to 1000 times / m, which is a common numerical range of 240 to 1600 times / m, to obtain the composite twisted yarn of the present invention.

本発明では、2本以上の紡績糸と水溶性糸を紡績糸の撚り方向と逆の方向に且つ紡績糸の撚数の0.3〜2倍の範囲の撚数で撚り合わせて本発明の複合撚糸としていることにより、複合撚糸を製造するための合撚時(上撚を行った際)に、複合撚糸の形態安定性(撚りの安定性)を保ちながら、上撚が紡績糸の撚り(下撚)を解撚する方向に働き、その上撚の際に、紡績糸の糸長が長くなり、一方で水溶性糸は加撚されて糸長が短くなるため、紡績糸の撚が0からさらに加撚されるようになっても、紡績糸の糸長>水溶性糸の糸長の関係が保たれた状態で撚糸される。それによって複合撚糸から織編物を作製する際の製編織を良好に行うことができ、しかも製編織により得られた織編物から水溶性糸を水で溶解除去したときに、伸縮性が大きくなり、ふっくらとした風合を有し、軽量性、通気性に優れる織編物が得られる。   In the present invention, two or more spun yarns and a water-soluble yarn are twisted in a direction opposite to the twist direction of the spun yarn and with a twist number in the range of 0.3 to 2 times the twist number of the spun yarn. By using a composite twisted yarn, the upper twist is the twist of the spun yarn while maintaining the shape stability (twisting stability) of the composite twisted yarn at the time of twisting (when the upper twist is performed) to produce the composite twisted yarn. It works in the direction of untwisting (primary twist), and the yarn length of the spun yarn becomes longer during the upper twist, while the water-soluble yarn is twisted and the yarn length is shortened. Even if twisting is further started from 0, the yarn is twisted in a state where the relationship of the yarn length of the spun yarn> the yarn length of the water-soluble yarn is maintained. As a result, it is possible to satisfactorily perform weaving and knitting when preparing a woven or knitted fabric from a composite twisted yarn, and when the water-soluble yarn is dissolved and removed from the woven or knitted fabric obtained by knitting or wetting, the stretchability becomes large. A woven or knitted fabric having a fluffy texture and excellent in lightness and breathability can be obtained.

複合撚糸における上撚の撚数が下撚の撚数(紡績糸の撚数)の0.3倍未満であると、複合撚糸を製造するための合撚時に紡績糸の解撚が不十分であり、さらには水溶性糸の加撚も不十分であるため、複合撚糸を製造する際の撚糸工程が安定せず、得られた複合撚糸に斑が生じ、しかもそのような複合撚糸を用いて作製した織編物から水溶性糸を水で溶解除去しても伸縮性のある織編物が得られない。一方、複合撚糸における上撚の撚数が下撚の撚数(紡績糸の撚数)の2倍を超えると、上撚をかける際の撚糸工程(複合撚糸を製造するための合撚工程)で糸切れなどのトラブルを生じて、複合撚糸の生産性の低下、得られた複合撚糸の強度低下、複合撚糸を用いての織編時の工程不良などを招き易くなり、また撚糸効率が低くなり、複合撚糸を製造する際の生産性が低下する。
なお、本明細書における「複合撚糸の撚数」(上撚の撚数)とは、紡績糸の2本以上と水溶性糸を撚り合わせたときの撚数のことであり、実際には撚糸工程時の設定撚数に準じた値となる。
When the twist number of the upper twist in the composite twisted yarn is less than 0.3 times the twist number of the lower twist (twisted number of the spun yarn), the untwisting of the spun yarn is insufficient during the twisting to produce the composite twisted yarn. In addition, since twisting of the water-soluble yarn is insufficient, the twisting process at the time of producing the composite twisted yarn is not stable, and the resulting composite twisted yarn has spots, and the composite twisted yarn is used. Even if the water-soluble yarn is dissolved and removed from the produced woven or knitted fabric with water, a stretchable woven or knitted fabric cannot be obtained. On the other hand, when the number of twists of the upper twist in the composite twisted yarn exceeds twice the number of twists of the lower twist (twisted number of the spun yarn), a twisting process for applying the upper twist (a twisting process for producing a composite twisted yarn) This causes troubles such as yarn breakage, which tends to lead to reduced productivity of composite twisted yarn, reduced strength of the obtained composite twisted yarn, process failure during weaving and knitting using composite twisted yarn, and low twisting efficiency. Thus, the productivity in producing the composite twisted yarn is reduced.
In the present specification, the “twist number of composite twisted yarn” (twist number of upper twist) is a twist number when two or more spun yarns and a water-soluble yarn are twisted together. It becomes a value according to the set twist number at the time of the process.

紡績糸の2本以上と水溶性糸を撚り合わせて複合撚糸を製造する際の撚糸機の種類は特に制限されず、例えば、ダブルツイスター、リングツイスター、アップツイスターなどの従来汎用の撚糸機を使用することができる。   There are no particular restrictions on the type of twisting machine used to produce a composite twisted yarn by twisting two or more spun yarns and water-soluble yarns. For example, a conventional general-purpose twisting machine such as a double twister, ring twister, or up twister is used. can do.

本発明の複合撚糸はトルクを有していることがあるが、トルクを有していても製編織工程に支障を及ぼさない場合は、トルクを減ずることなくそのまま織編物の製造に使用することができる。もし、トルクを有していることにより製編織工程に支障を及ぼす場合は、熱処理を施してトルクを減じることが好ましい。その際の熱処理温度は、複合撚糸を構成する紡績糸および水溶性糸の種類、複合撚糸のトルクの強さになどによって決める必要がある。   The composite twisted yarn of the present invention may have torque, but if it does not interfere with the weaving and weaving process even if it has torque, it may be used as it is for the production of woven or knitted fabric without reducing the torque. it can. If the torque is hindered in the weaving and weaving process, heat treatment is preferably performed to reduce the torque. The heat treatment temperature at that time must be determined by the kind of spun yarn and water-soluble yarn constituting the composite twisted yarn, the torque strength of the composite twisted yarn, and the like.

本発明の複合撚糸を用いることによって、高い伸縮性を有する織編物を製造することができ、織編物の種類や組織の内容などは特に制限されない。
織編物の製造に当っては、織編物の種類、用途、織編物に要求される伸縮の程度などに応じて、本発明の複合撚糸の使用割合を調節することができる。高い伸縮性を有する織編物を得るためには、織編物を形成している複合撚糸中の水溶性糸を水に溶解除去する前の織編物において、本発明の複合撚糸の使用割合を該織編物の質量に対して10質量%以上にすることが好ましく、20質量%以上にすることがより好ましい。それによって、該織編物を水(熱水)で処理して織編物を形成している複合撚糸中の水溶性糸を溶解除去したときに、高い伸縮性を有する織編物を得ることができる。織編物における複合撚糸の使用割合が低すぎると、織編物を水(熱水)で処理して織編物を形成している複合撚糸中の水溶性糸を溶解除去しても、伸縮性のある織編物が得られにくくなる。
By using the composite twisted yarn of the present invention, a woven or knitted fabric having high stretchability can be produced, and the type of woven or knitted fabric and the content of the structure are not particularly limited.
In the production of the woven or knitted fabric, the use ratio of the composite twisted yarn of the present invention can be adjusted according to the type and use of the woven or knitted fabric, the degree of expansion and contraction required for the woven or knitted fabric, and the like. In order to obtain a woven or knitted fabric having high stretchability, the use ratio of the composite twisted yarn of the present invention in the woven or knitted fabric before dissolving and removing the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric in water is determined. It is preferable to set it as 10 mass% or more with respect to the mass of a knitted fabric, and it is more preferable to set it as 20 mass% or more. Accordingly, when the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric is dissolved and removed by treating the woven or knitted fabric with water (hot water), a woven or knitted fabric having high stretchability can be obtained. If the ratio of the composite twisted yarn used in the woven or knitted fabric is too low, even if the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric is dissolved and removed by treating the woven or knitted fabric with water (hot water), it is stretchable. It becomes difficult to obtain a woven or knitted fabric.

本発明の複合撚糸を用いて作製した織編物から、複合撚糸中の水溶性糸を水で溶解除去する処理は、織編物を染色する工程の前および織編物に樹脂を付着する工程の前に行うのがよい。染色工程や樹脂付着工程中またはこれらの工程の後に複合撚糸を構成している水溶性糸の水溶解処理を行うと、染色工程や樹脂付着工程に支障を与え易くなり、しかも水溶性糸の溶解除去が充分に行われにくくなる。織編物を形成する複合撚糸中の水溶性糸を水で溶解除去する処理は、通常、最初の段階で行うことが、次に続く生産工程の円滑性、織編物の品質の点から好ましい。
織編物を形成している複合撚糸中の水溶性糸を水で溶解除去する際の水の温度は、水溶性糸を構成する水溶性繊維の種類や水に対する溶解度、糸の形態や太さなどに応じて調節できる。水溶性糸が水溶性ポリビニルアルコール系繊維から形成されている場合は、通常、温度70〜100℃の水を用いて処理を行うと、水溶性糸を短い時間で速やかに織編物から溶解除去することができる。
The treatment of dissolving and removing the water-soluble yarn in the composite twisted yarn with water from the woven or knitted fabric produced using the composite twisted yarn of the present invention is performed before the step of dyeing the woven or knitted fabric and before the step of attaching the resin to the woven or knitted fabric. Good to do. If the water-soluble yarn constituting the composite twisted yarn is subjected to water dissolution treatment during or after the dyeing step or resin adhesion step, the dyeing step or resin adhesion step is likely to be hindered, and the water-soluble yarn is dissolved. It becomes difficult to remove sufficiently. The treatment for dissolving and removing the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric with water is usually preferable in the first stage from the viewpoint of the smoothness of the subsequent production process and the quality of the woven or knitted fabric.
The temperature of the water when dissolving and removing the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric with water is the type of water-soluble fiber constituting the water-soluble yarn, the solubility in water, the shape and thickness of the yarn, etc. Can be adjusted according to. When the water-soluble yarn is formed from water-soluble polyvinyl alcohol fibers, usually, when the treatment is performed using water at a temperature of 70 to 100 ° C., the water-soluble yarn is quickly dissolved and removed from the woven or knitted fabric in a short time. be able to.

本発明の複合撚糸を用いて作製した織編物から、織編物を形成している複合撚糸中の水溶性糸を水で溶解除去して得られる織編物は、水溶性糸が存在していた部分に生じた空間および逆方向の上撚りによって解撚された紡績糸の糸長の増加と自由度の増加などの相乗効果によって、高い伸縮性とふくらみのある良好な感触を有し、しかも軽量性、通気性などにも優れている。
しかも、水溶性糸を水で溶解除去した後の織編物では、複合撚糸を構成していた2本以上の紡績糸が互いに合撚された合撚糸の形態で織編物中に残るため、紡績糸を形成している繊維の素抜けが生じず、強力が維持される。
そのため、本発明の複合撚糸から作製した織編物から水溶性糸を水で溶解除去して得られた織編物は、上記した優れた特性を活かして、例えば、スポーツ衣料、肌着、ファンデーション、その他の衣料用、弾性包帯などの医療用途、車輛内装材、ベルトコンベア用生地、その他の工業資材などに有効に使用することができる。
The woven or knitted fabric obtained by dissolving and removing the water-soluble yarn in the composite twisted yarn forming the woven or knitted fabric with water from the woven or knitted fabric produced using the composite twisted yarn of the present invention is a portion where the water-soluble yarn was present. It has a good feel with high elasticity and swell due to synergistic effects such as increased yarn length and increased flexibility of the spun yarn untwisted by the space created in the reverse direction and the upper twist in the reverse direction, and it is lightweight Excellent breathability.
In addition, in the woven or knitted fabric after the water-soluble yarn is dissolved and removed with water, the two or more spun yarns constituting the composite twisted yarn remain in the woven or knitted fabric in the form of a twisted yarn that is twisted together. The fiber forming the fiber is not removed, and the strength is maintained.
Therefore, the woven or knitted fabric obtained by dissolving and removing the water-soluble yarn with water from the woven or knitted fabric produced from the composite twisted yarn of the present invention, taking advantage of the above-described excellent characteristics, for example, sports clothing, underwear, foundations, other It can be effectively used for clothing, medical applications such as elastic bandages, vehicle interior materials, belt conveyor fabrics, and other industrial materials.

以下に、実施例などにより本発明を具体的に説明するが、本発明は以下の例に何ら限定されるものではない。
以下の実施例および比較例において、生地(平織生地)の伸長率は次のようにして測定した。
Hereinafter, the present invention will be specifically described with reference to examples and the like, but the present invention is not limited to the following examples.
In the following Examples and Comparative Examples, the elongation rate of the fabric (plain woven fabric) was measured as follows.

[生地の伸長率]
(1) 以下の例で製造した生地から、生地の経方向の寸法が15cm(長さ)で緯方向の寸法が2.5cm(幅)である試験片(a)と、生地の経方向の寸法が2.5cm(幅)で緯方向の寸法が15cm(長さ)である試験片(b)をそれぞれ切り取った。
(2) 上記(1)で切り取った試験片(a)の長さ方向の一方の端部の中央(幅方向の中央)に1gの重りを取り付けて、重りを付けた端部を下にして試験片を垂直に吊してその状態で1分間放置し、その時の試験片(a)の長さ(La1)を測定した。
次いで、前記1gの重りを試験片(a)の端部から取り去り、代わりに300gの重りを同じ箇所に取り付けて垂直に吊してその状態で3分間放置し、その時の試験片(a)の長さ(La2)(cm)を測定して、下記の数式(i)から生地の経方向の伸長率(%)を求めた。
経方向の伸長率(%)={(La2−La1)/La1}×100 (i)
(3) 上記(1)で切り取った試験片(b)の長さ方向の一方の端部の中央(幅方向の中央)に1gの重りを取り付けて、重りを付けた端部を下にして試験片を垂直に吊してその状態で1分間放置し、その時の試験片(b)の長さ(Lb1)を測定した。
次いで、前記1gの重りを試験片(b)の端部から取り去り、代わりに300gの重り取りを同じ箇所に取り付けて垂直に吊してその状態で3分間放置し、その時の試験片(b)の長さ(Lb2)(cm)を測定して、下記の数式(ii)から生地の緯方向の伸長率(%)を求めた。
緯方向の伸長率(%)={(Lb2−Lb1)/Lb1}×100 (ii)
[Elongation rate of fabric]
(1) From a fabric manufactured in the following example, a test piece (a) having a longitudinal dimension of 15 cm (length) and a weft dimension of 2.5 cm (width), and a longitudinal direction of the fabric Test pieces (b) each having a dimension of 2.5 cm (width) and a dimension in the weft direction of 15 cm (length) were cut out.
(2) A 1 g weight is attached to the center (the center in the width direction) of one end portion in the length direction of the test piece (a) cut out in the above (1), and the end portion to which the weight is attached is directed downward. The test piece was hung vertically and left in that state for 1 minute, and the length (La 1 ) of the test piece (a) at that time was measured.
Next, the 1 g weight is removed from the end of the test piece (a). Instead, a 300 g weight is attached to the same place and hung vertically and left in that state for 3 minutes. The length (La 2 ) (cm) was measured, and the elongation percentage (%) in the warp direction of the fabric was determined from the following mathematical formula (i).
Elongation rate in warp direction (%) = {(La 2 −La 1 ) / La 1 } × 100 (i)
(3) A 1 g weight is attached to the center (one center in the width direction) of one end portion in the length direction of the test piece (b) cut out in the above (1), and the end portion with the weight is turned down. The test piece was suspended vertically and left in that state for 1 minute, and the length (Lb 1 ) of the test piece (b) at that time was measured.
Next, the 1 g weight is removed from the end of the test piece (b). Instead, a 300 g weight is attached to the same location and hung vertically and left in that state for 3 minutes. At that time, the test piece (b) The length (Lb 2 ) (cm) of the fabric was measured, and the elongation rate (%) in the weft direction of the fabric was determined from the following mathematical formula (ii).
Elongation rate in the weft direction (%) = {(Lb 2 −Lb 1 ) / Lb 1 } × 100 (ii)

《実施例1》
(1)(i) 紡績糸として、撚数が800回/m(Z撚)の木綿100%の40番手紡績糸(都築紡績社製「TS40単糸」)を準備した。なお、この紡績糸は、2.54cm当りの撚数T=20.32回であり、番手S=40であることにより、式:K=(T/√S)から求められる撚り係数Kは、20.32/√40=20.32/6.32=3.22である。
(ii) 水溶性糸として、ポリビニルアルコールマルチフィラメント糸(56dtex)(80℃の水に溶解)(株式会社クラレ製「水溶性ビニロン」)を準備した。
Example 1
(1) (i) As a spun yarn, a 40th spun yarn having a twist number of 800 times / m (Z-twisted) 100% cotton (“TS40 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) was prepared. The spun yarn has a twist number T = 20.32 times per 2.54 cm and a count S = 40, so that the twist coefficient K obtained from the formula: K = (T / √S) is 20.32 / √40 = 20.332 / 6.32 = 3.22.
(Ii) As a water-soluble yarn, a polyvinyl alcohol multifilament yarn (56 dtex) (dissolved in water at 80 ° C.) (“water-soluble vinylon” manufactured by Kuraray Co., Ltd.) was prepared.

(2) 上記(1)で準備した紡績糸2本と水溶性糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が700回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚り数)=紡績糸の撚数の0.875倍]。
(3) 上記(2)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸84質量%(2本の紡績糸の合計質量)および水溶性糸16質量%からなっていた。
(2) Two spun yarns and one water-soluble yarn prepared in (1) above are supplied to a double twister (“36M” manufactured by Murata Machinery Co., Ltd.), and the twist number (upper twist) is 700 times / m ( The composite twisted yarn was manufactured by twisting together so that it would be (S twist) [twisted number of composite twisted yarn (upper twisted number) = 0.875 times the twisted number of spun yarn].
(3) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (2) above to obtain a sample yarn, the sample yarn is untwisted, and the two types of spun yarn and water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement result. The composite twisted yarn was 84% by weight of spun yarn (the total of the two spun yarns). Mass) and 16% by mass of water-soluble yarn.

(4) 上記(2)で得られた複合撚糸を経糸および緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率100%)。この製織工程では、糸切れなどのトラブルを全く生ずることなく、平織生地を高速で織ることができ、製織量産性において何ら問題がなかった(織速度0.1m/分)。
(5) 上記(4)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が22%および緯方向の伸長率が23%であり、高い伸縮性を有していた。しかも、この生地は、ふっくらとしていて風合に優れ、軽量性よび通気性にも優れており、その上、生地からの綿繊維の素抜けがなく、強力にも優れていた。
(4) A plain weave fabric having a warp of 25 / cm and a weft of 20 / cm was woven using the composite twisted yarn obtained in (2) above as a warp and a weft (100% blend ratio of composite twist yarn in a plain weave fabric). . In this weaving process, the plain weave fabric could be woven at high speed without causing any troubles such as thread breakage, and there was no problem in weaving mass productivity (weaving speed 0.1 m / min).
(5) The plain weave fabric obtained in (4) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. Dissolved and removed, washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. When the stretch rate in the warp direction and the weft direction of the fabric thus obtained was measured by the method described above, the stretch rate in the warp direction was 22% and the stretch rate in the weft direction was 23%, which had high stretchability. It was. In addition, this fabric was plump and excellent in texture, lightweight and breathable, and further, the cotton fibers from the fabric did not come off, and it was excellent in strength.

《実施例2》
(1) 木綿40番双糸を経糸として使用し、実施例1の(2)で得られた複合撚糸を緯糸として使用し、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)。この製織工程では、糸切れなどのトラブルを全く生ずることなく、平織生地を高速で織ることができ、製織量産性において何ら問題がなかった(織速度0.1m/分)。
(2) 上記(1)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地の緯糸をなす複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が23%であり、緯方向に高い伸縮性を有していた。その上、この生地は、ふっくらとしていて風合に優れ、しかも軽量性および通気性にも優れていた。しかも、生地を形成している緯糸からの綿繊維の素抜けがなく、緯糸の糸強力にも優れていた。
Example 2
(1) A cotton No. 40 double yarn was used as the warp, and the composite twisted yarn obtained in (2) of Example 1 was used as the weft to weave a plain weave fabric of warp 25 / cm and weft 20 / cm. (The mixing ratio of the composite twisted yarn in the plain woven fabric is 40%). In this weaving process, the plain weave fabric could be woven at high speed without causing any troubles such as thread breakage, and there was no problem in weaving mass productivity (weaving speed 0.1 m / min).
(2) The plain weave fabric obtained in (1) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15) to dissolve the water-soluble yarn in the composite twisted yarn that forms the weft of the fabric. It was then removed and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), after which the dough was removed from the water and dried at 150 ° C. When the elongation rate in the warp direction and the weft direction of the fabric thus obtained was measured by the method described above, the stretch rate in the warp direction was 11% and the stretch rate in the weft direction was 23%. Had. In addition, the fabric was plump and excellent in texture, and also excellent in lightness and breathability. In addition, there was no loosening of the cotton fibers from the wefts forming the fabric, and the weft strength of the wefts was excellent.

《実施例3》
(1) 撚数が800回/m(Z撚)の木綿100%の40番手紡績糸(都築紡績社製「TS40単糸」)を準備し、この紡績糸2本と実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が300回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚り数)=紡績糸の撚数の0.375倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸86質量%および水溶性糸14質量%からなっていた。
Example 3
(1) A 40th spun yarn (“TS40 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) with 100% cotton of 800 times / m (Z twist) was prepared and used in Example 2 and the two spun yarns. Is supplied to a double twister (“36M” manufactured by Murata Machinery Co., Ltd.) and twisted so that the number of twists (upper twist) is 300 times / m (S twist). Thus, a composite twisted yarn was produced [the number of twists of the composite twisted yarn (the number of upper twists) = 0.375 times the number of twists of the spun yarn].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement result. The composite twisted yarn was obtained from 86% by weight of spun yarn and 14% by weight of water-soluble yarn. It was.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)。この製織工程では、糸切れなどのトラブルを全く生ずることなく、平織生地を高速で織ることができ、製織量産性において何ら問題がなかった(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が21%であり、緯方向に高い伸縮性を有していた。また、この生地は、ふっくらとしていて風合に優れ、軽量性および通気性にも優れていた。しかも、生地を形成している緯糸からの綿繊維の素抜けがなく、緯糸の糸強力にも優れていた。
(3) A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) 40% of mixed twisted yarn in the fabric). In this weaving process, the plain weave fabric could be woven at high speed without causing any troubles such as thread breakage, and there was no problem in weaving mass productivity (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. When the elongation rate in the warp direction and the weft direction of the fabric thus obtained was measured by the method described above, the stretch rate in the warp direction was 11% and the stretch rate in the weft direction was 21%. Had. Further, this fabric was plump and excellent in texture, and was excellent in lightness and breathability. In addition, there was no loosening of the cotton fibers from the wefts forming the fabric, and the weft strength of the wefts was excellent.

《実施例4》
(1) 撚数が800回/m(Z撚)の木綿100%の40番手紡績糸(都築紡績社製「TS40単糸」)を準備し、この紡績糸2本と実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が1400回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚り数)=紡績糸の撚数の1.75倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸84質量%および水溶性糸16質量%からなっていた。
Example 4
(1) A 40th spun yarn (“TS40 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) with 100% cotton of 800 times / m (Z twist) was prepared and used in Example 2 and the two spun yarns. Is supplied to a double twister ("36M" manufactured by Murata Machinery Co., Ltd.) and twisted so that the number of twists (upper twist) is 1400 times / m (S twist). To produce a composite twisted yarn [number of twists of composite twisted yarn (number of upper twists) = 1.75 times the number of twisted spun yarns].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement results. The composite twisted yarn was obtained from 84% by mass of spun yarn and 16% by mass of water-soluble yarn. It was.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)。この製織工程では、糸切れなどのトラブルを全く生ずることなく、平織生地を高速で織ることができ、製織量産性において何ら問題がなかった(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が21%であり、緯方向に高い伸縮性を有していた。また、この生地は、ふっくらとしていて風合に優れ、軽量性および通気性にも優れていた。しかも、生地を形成している緯糸からの綿繊維の素抜けがなく、緯糸の糸強力にも優れていた。
(3) A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) 40% of mixed twisted yarn in the fabric). In this weaving process, the plain weave fabric could be woven at high speed without causing any troubles such as thread breakage, and there was no problem in weaving mass productivity (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. When the elongation rate in the warp direction and the weft direction of the fabric thus obtained was measured by the method described above, the stretch rate in the warp direction was 11% and the stretch rate in the weft direction was 21%. Had. Further, this fabric was plump and excellent in texture, and was excellent in lightness and breathability. In addition, there was no loosening of the cotton fibers from the wefts forming the fabric, and the weft strength of the wefts was excellent.

《実施例5》
(1) 撚数が900回/m(Z撚)の木綿100%の60番手紡績糸(都築紡績社製「TS60単糸」)と、撚数が700回/m(Z撚)の木綿100%の30番手紡績糸(都築紡績社製「TS30単糸」)を準備し、これらの紡績糸の各1本(合計2本)と実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が800回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚り数)=60番手の紡績糸の撚数の0.89倍、30番手の紡績糸の撚数の1.14倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸85質量%および水溶性糸15質量%からなっていた。
Example 5
(1) 60th-yarn spun yarn with a twist of 900 times / m (Z-twisted) 100% cotton (“TS60 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) and 100 cottons with a twist number of 700 times / m (Z-twisted) % 30th spun yarn (“TS30 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.), one of each of these spun yarns (two in total) and the same polyvinyl alcohol multifilament yarn 1 used in Example 1 The product was supplied to a double twister ("36M" manufactured by Murata Machinery Co., Ltd.) and twisted so that the number of twists (upper twist) was 800 times / m (S twist) to produce a composite twisted yarn The number of twists (the number of upper twists) = 0.89 times the number of twists of the 60th spun yarn, 1.14 times the number of twists of the 30th spun yarn].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement results. The composite twisted yarn was obtained from 85% by weight spun yarn and 15% by weight water-soluble yarn. It was.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)。この製織工程では、糸切れなどのトラブルを全く生ずることなく、平織生地を高速で織ることができ、製織量産性において何ら問題がなかった(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が12%および緯方向の伸長率が22%であり、緯方向に高い伸縮性を有していた。また、この生地は、ふっくらとしていて風合に優れ、軽量性および通気性にも優れていた。しかも、異番手の紡績糸2本を使用したことによる撚の凹凸が表現された生地となった。さらに、生地を形成している緯糸からの綿繊維の素抜けがなく、緯糸の糸強力にも優れていた。
(3) A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) 40% of mixed twisted yarn in the fabric). In this weaving process, the plain weave fabric could be woven at high speed without causing any troubles such as thread breakage, and there was no problem in weaving mass productivity (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. When the elongation rate in the warp direction and the weft direction of the fabric thus obtained was measured by the above-described method, the stretch rate in the warp direction was 12% and the stretch rate in the weft direction was 22%. Had. Further, this fabric was plump and excellent in texture, and was excellent in lightness and breathability. In addition, a twisted unevenness due to the use of two spun yarns with different counts was obtained. Furthermore, there was no looseness of the cotton fibers from the wefts forming the fabric, and the weft strength of the wefts was excellent.

《比較例1》
(1) 撚数が800回/m(Z撚)の木綿100%の40番手紡績糸(都築紡績社製「TS40単糸」)2本と、実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸(56dtex)よりなる水溶性糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が200回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚りの数)=紡績糸の撚数の0.25倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸84質量%および水溶性糸16質量%からなっていた。
<< Comparative Example 1 >>
(1) Two 40-number spun yarns (“TS40 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) with 100% cotton of 800 times / m (Z twist) and the same polyvinyl alcohol multi as used in Example 1 Supply one water-soluble yarn made of filament yarn (56 dtex) to a double twister (“36M” manufactured by Murata Machinery Co., Ltd.) so that the number of twists (upper twist) is 200 times / m (S twist). A composite twisted yarn was produced by twisting together [number of twists of composite twisted yarn (number of upper twists) = 0.25 times the number of twisted spun yarns].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement results. The composite twisted yarn was obtained from 84% by mass of spun yarn and 16% by mass of water-soluble yarn. It was.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が14%であって、実施例1〜4に比べて伸縮性が低いものであった。
(3) A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) 40% of mixed twisted yarn in the fabric) (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. The warp direction elongation rate and the weft direction elongation rate of the fabric thus obtained were measured by the method described above. The warp direction elongation rate was 11% and the weft direction elongation rate was 14%. Examples 1-4 The elasticity was low compared to.

《比較例2》
撚数が800回/m(Z撚)の木綿100%の40番手紡績糸(都築紡績社製「TS40単糸」)2本と、実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸(56dtex)よりなる水溶性糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が2000回/m(S撚)となるようにして撚り合わせて複合撚糸を製造したが[複合撚糸の撚数(上撚りの数)=紡績糸の撚数の2.5倍]、糸切れが多くて撚糸が困難で、複合撚糸を製造することができなかった。
<< Comparative Example 2 >>
Two 40-degree spun yarns (“TS40 single yarn” manufactured by Tsuzuki Boseki Co., Ltd.) with 100% cotton of 800 turns / m (Z twist) and the same polyvinyl alcohol multifilament yarn used in Example 1 ( 56 dtex) is supplied to a double twister ("36M" manufactured by Murata Machinery Co., Ltd.) and twisted so that the number of twists (upper twist) is 2000 times / m (S twist). Although a composite twisted yarn was manufactured [the number of twists of the composite twisted yarn (number of top twists) = 2.5 times the number of twists of the spun yarn], the twisted yarn was difficult because of many yarn breaks, and the composite twisted yarn could not be manufactured. It was.

《比較例3》
(1) 撚数が350回/m(Z撚)の木綿100%の10番手紡績糸(都築紡績社製「TS10単糸」)5本と、実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸(56dtex)よりなる水溶性糸1本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が200回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚りの数)=紡績糸の撚数の0.571倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸98.2質量%および水溶性糸1.8質量%からなっていた。
<< Comparative Example 3 >>
(1) Five tenth-yarn spun yarns (“TS10 single yarn” manufactured by Tsuzuki Spinning Co., Ltd.) with 100% cotton of 350 turns / m (Z twist) and the same polyvinyl alcohol multi used in Example 1 Supply one water-soluble yarn made of filament yarn (56 dtex) to a double twister (“36M” manufactured by Murata Machinery Co., Ltd.) so that the number of twists (upper twist) is 200 times / m (S twist). A composite twisted yarn was manufactured by twisting together [number of twists of composite twisted yarn (number of upper twists) = 0.571 times the number of twisted spun yarns].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. After separating into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement result. As a result, the composite twisted yarn was 98.2% by weight of spun yarn and 1. It was 8% by mass.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯5本/cmの平織生地を製織した(平織生地における複合撚糸の混率60%)(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が13%であって、実施例1〜4に比べて伸縮性が低いものであった。
(3) A plain weave fabric of warp 25 / cm and weft 5 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) (Mixing ratio of composite twisted yarn in the fabric 60%) (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. When the elongation rate in the warp direction and the weft direction of the fabric thus obtained was measured by the method described above, the elongation rate in the warp direction was 11% and the elongation rate in the weft direction was 13%. The elasticity was low compared to.

《比較例4》
(1) 撚数が1500回/m(Z撚)の木綿100%の120番手紡績糸[Royal Textile Mills Ltd.(インド)製「Royal 120」]2本と、実施例1で使用したのと同じポリビニルアルコールマルチフィラメント糸(56dtex)よりなる水溶性糸3本を、ダブルツイスター(村田機械社製「36M」)に供給して、撚数(上撚)が1500回/m(S撚)となるようにして撚り合わせて複合撚糸を製造した[複合撚糸の撚数(上撚りの数)=紡績糸の撚数の1.0倍]。
(2) 上記(1)で得られた複合撚糸から所定長(1m)の糸を切り取って、試料糸とし、その試料糸の上撚を解除して、紡績糸と水溶性糸の2種類の糸に分離し、分離したそれぞれの糸の質量を測定し、その測定結果から複合撚糸におけるそれぞれの糸の割合を求めたところ、該複合撚糸は紡績糸37質量%および水溶性糸63質量%からなっていた。
<< Comparative Example 4 >>
(1) 100th cotton yarn having a twist number of 1500 times / m (Z twist), 120th spun yarn [Royal Textile Mills Ltd. (India) “Royal 120”] and two water-soluble yarns made of the same polyvinyl alcohol multifilament yarn (56 dtex) used in Example 1 were double twisted (“36M” manufactured by Murata Machinery Co., Ltd.). And twisted so that the number of twists (upper twist) was 1500 times / m (S twist) to produce a composite twisted yarn [twisted number of composite twisted yarn (number of upper twisted) = twisted spun yarn 1.0 times the number].
(2) A yarn of a predetermined length (1 m) is cut from the composite twisted yarn obtained in (1) above to obtain a sample yarn, and the upper twist of the sample yarn is released, and two types of yarn, a spun yarn and a water-soluble yarn are used. It was separated into yarns, the mass of each separated yarn was measured, and the proportion of each yarn in the composite twisted yarn was determined from the measurement results. The composite twisted yarn was obtained from 37% by mass of spun yarn and 63% by mass of water-soluble yarn. It was.

(3) 木綿40番双糸を経糸として使用し、上記(1)で得られた複合撚糸を緯糸として使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率40%)(織速度0.1m/分)。
(4) 上記(3)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地は、形態安定性に劣っていて、目寄れが生じ易く、実用性の低いものであったため、経方向および緯方向の伸長率を測定しなかった。
(3) A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven using the No. 40 cotton double yarn as the warp and the composite twisted yarn obtained in (1) above as the weft (plain weave) 40% of mixed twisted yarn in the fabric) (weaving speed 0.1 m / min).
(4) The plain weave fabric obtained in (3) above is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is removed. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. The dough thus obtained was inferior in form stability, easily slipped and low in practicality, so the elongation in the warp direction and the weft direction was not measured.

《参考例1》
(1) 経糸として木綿40番双糸の1本を使用し、緯糸として実施例1の(2)で得られた複合撚糸と木綿30番双糸を1本:4本の比率で使用して、経25本/cm、緯20本/cmの平織生地を製織した(平織生地における複合撚糸の混率8%)。
(2) 上記(1)で得られた平織生地を、90℃の熱水中に15分間浸漬して(浴比=1:15)、生地を形成している複合撚糸中の水溶性糸を溶解除去し、次いで60℃の熱水で10分間水洗し(浴比=1:15)、その後、生地を水から取り出して150℃で乾燥した。これにより得られた生地の経方向および緯方向の伸長率を上記した方法で測定したところ、経方向の伸長率が11%および緯方向の伸長率が11%であった。
<< Reference Example 1 >>
(1) Use one piece of cotton No. 40 double yarn as the warp, and use the composite twisted yarn obtained in (2) of Example 1 and No. 30 cotton double yarn in the ratio of 1: 4 as the weft. A plain weave fabric with a warp of 25 / cm and a weft of 20 / cm was woven (mixing ratio of composite twisted yarn in plain weave fabric was 8%).
(2) The plain woven fabric obtained in the above (1) is immersed in hot water at 90 ° C. for 15 minutes (bath ratio = 1: 15), and the water-soluble yarn in the composite twisted yarn forming the fabric is obtained. It was removed by dissolution, and then washed with hot water at 60 ° C. for 10 minutes (bath ratio = 1: 15), and then the dough was taken out of the water and dried at 150 ° C. The warp direction elongation rate and the weft direction elongation rate of the fabric thus obtained were measured by the method described above, and the warp direction elongation rate was 11% and the weft direction elongation rate was 11%.

本発明の複合撚糸は製編織性に優れ、織物や編物を作製する際に糸切れなどのトラブルが生じず、しかも本発明の複合撚糸から織編物を作製し、その織編物中の水溶性糸を水に溶解して除去することにより、高い伸縮性を有し、ふっくらとしていて良好な感触および風合を有し、軽量性、通気性などの特性にも優れ、更には織編物を形成する紡績糸からの繊維の素抜けが生じず、強力に優れる織編物が得られるので、本発明の複合撚糸は、前記した高伸縮性織編物の製造に有効に用いることができる。
本発明の複合撚糸を含む織編物を水で処理して複合撚糸中の水溶性糸を水で溶解除去して得られる本発明の織編物は、その高い伸縮性、優れた風合、感触、軽量性、通気性などの特性を活かして、スポーツ衣料、肌着、ファンデーション、その他の衣料用、弾性包帯などの医療用途、車輛内装材、ベルトコンベア用生地、その他の工業資材などの広範な分野に有効に使用することができる。
The composite twisted yarn of the present invention is excellent in knitting and weaving properties, and does not cause trouble such as yarn breakage when producing a woven fabric or knitted fabric. In addition, a woven or knitted fabric is produced from the composite twisted yarn of the present invention, and the water-soluble yarn in the woven or knitted fabric Is dissolved in water to remove it and has high elasticity, it is plump, has a good feel and texture, is excellent in properties such as lightness and breathability, and further forms a woven or knitted fabric Since the fiber does not come off from the spun yarn and a woven or knitted fabric excellent in strength is obtained, the composite twisted yarn of the present invention can be effectively used for the production of the above highly stretchable woven or knitted fabric.
The woven or knitted fabric of the present invention obtained by treating the woven or knitted fabric containing the composite twisted yarn of the present invention with water and dissolving and removing the water-soluble yarn in the composite twisted yarn with water has high stretchability, excellent texture, feel, Utilizing characteristics such as lightness and breathability, sports clothing, underwear, foundations, other clothing, medical applications such as elastic bandages, vehicle interior materials, belt conveyor fabrics, and other industrial materials It can be used effectively.

Claims (4)

(i) 撚り方向を同じくする紡績糸の2本以上と水溶性糸を撚り合わせた複合撚糸であって;
(ii) 複合撚糸の撚り方向が紡績糸の撚り方向と逆であり;
(iii) 複合撚糸の撚数が、2本以上の紡績糸のそれぞれの撚数のいずれに対しても、0.3〜2倍の範囲にあり;且つ、
(iv) 複合撚糸の質量に基づいて、紡績糸の割合が98〜40質量および水溶性糸の割合が2〜60質量%である;
ことを特徴とする複合撚糸。
(I) a composite twisted yarn obtained by twisting two or more spun yarns having the same twist direction and a water-soluble yarn;
(Ii) the twist direction of the composite twist yarn is opposite to the twist direction of the spun yarn;
(Iii) the number of twists of the composite twisted yarn is in the range of 0.3 to 2 times the number of twists of each of the two or more spun yarns; and
(Iv) based on the mass of the composite twisted yarn, the proportion of spun yarn is 98-40 mass and the proportion of water-soluble yarn is 2-60 mass%;
A composite twisted yarn characterized by that.
水溶性糸が、水溶性のフィラメント糸である請求項1に記載の複合撚糸。   The composite twisted yarn according to claim 1, wherein the water-soluble yarn is a water-soluble filament yarn. 請求項1または2に記載の複合撚糸を含む織編物から、複合撚糸中の水溶性糸を水で溶解除去したことを特徴とする織編物。   A woven or knitted fabric obtained by dissolving and removing water-soluble yarn in the composite twisted yarn with water from the woven or knitted fabric containing the composite twisted yarn according to claim 1 or 2. 請求項1または2に記載の複合撚糸を10質量%以上の割合で含む織編物から、複合撚糸中の水溶性糸を水で溶解除去してなる請求項3に記載の織編物。
The woven or knitted fabric according to claim 3, wherein the water-soluble yarn in the composite twisted yarn is dissolved and removed from the woven or knitted fabric containing the composite twisted yarn according to claim 1 or 2 at a ratio of 10% by mass or more.
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