JP4389562B2 - Electrical contacts made of internal silver oxide-oxide material for miniaturized electromagnetic relays with high conductivity - Google Patents
Electrical contacts made of internal silver oxide-oxide material for miniaturized electromagnetic relays with high conductivity Download PDFInfo
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- 239000000463 material Substances 0.000 title claims description 21
- ZUMMKALUNVXLCS-UHFFFAOYSA-N O=[Ag]=O Chemical compound O=[Ag]=O ZUMMKALUNVXLCS-UHFFFAOYSA-N 0.000 title claims description 6
- 230000003647 oxidation Effects 0.000 claims description 32
- 238000007254 oxidation reaction Methods 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000009792 diffusion process Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 229910001316 Ag alloy Inorganic materials 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000011362 coarse particle Substances 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 2
- 238000003466 welding Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000020169 heat generation Effects 0.000 description 5
- 238000004220 aggregation Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 238000005491 wire drawing Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
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Description
この発明は、高導電性を有し、小径化した状態で長期に亘ってすぐれた電気接点特性、すなわち、すぐれた耐溶着性と耐消耗性を発揮し、特に小寸化した電磁リレーに用いるのに適した内部酸化銀−酸化物系材料製電気接点に関するものである。 The present invention has high electrical conductivity and excellent electrical contact characteristics over a long period of time in a reduced diameter state, that is, excellent welding resistance and wear resistance, and is used particularly for a miniaturized electromagnetic relay. The present invention relates to an electrical contact made of an internal silver oxide-oxide material suitable for the above.
一般に自動車や事務機などの構造部品として、各種の電磁リレーが用いられている。
上記電磁リレーが、例えば図3(a),(b)に概略縦断面図で示される通り、鉄心磁極とコイルからなる電磁石、接極子、および電気接点がそれぞれ一方側の先端部に対向配置された状態で固着された固定接点バネと可動接点バネで構成され、さらに前記電磁石のコイルに電流を流すと図1(b)の状態、すなわち前記接極子の一方端部が鉄心磁極に磁気吸着され、これによって前記接極子の他方端部が前記可動接点バネの一方端部を上方に変位させ、これの先端部に固着された電気接点が前記固定接点バネの先端部に固着された電気接点と接触して電流が流れ、リレーが機能する状態となり、一方前記電磁石のコイルの通電を停止すると、図1(a)に示される状態となって、前記電気接点が開離し、リレー機能が停止するようになる作動機能をもつことも知られている。
上記構造の電磁リレーの場合、例えば自動車用であれば、電源電圧:直流14V、定格電流:20〜30Aの負荷条件で用いられ、この場合の電気接点の寸法は通常のリッベト形状のもので頭経が3〜5mmのものが一般である。
また、上記構造の電磁リレーの電気接点には各種の材料が実用され、かつ提案されているが、中でも以下に示す材料、すなわち、質量%で(以下、%は質量%を示す)、
Sn:4.5〜10%、
In:0.1〜5%、
Bi:0.01〜5%、
を含有し、残りがAgと不可避不純物からなる組成を有するAg合金を内部酸化処理、すなわち酸化雰囲気中、650〜750℃に15〜30時間保持の条件で処理して、Agの素地に超微粒のSn系酸化物とIn系酸化物が析出した組織としてなる内部酸化銀−酸化物系材料が注目されている。
In the electromagnetic relay, for example, as shown in a schematic longitudinal sectional view in FIGS. 3A and 3B, an electromagnet including an iron core magnetic pole and a coil, an armature, and an electrical contact are respectively arranged to be opposed to one end portion. When the current is passed through the coil of the electromagnet, the state shown in FIG. 1B, that is, one end of the armature is magnetically attracted to the iron core magnetic pole. Thus, the other end of the armature displaces one end of the movable contact spring upward, and the electrical contact fixed to the tip of the movable contact spring is fixed to the tip of the fixed contact spring. When contact is made and current flows and the relay functions, on the other hand, when energization of the coil of the electromagnet is stopped, the state shown in FIG. 1 (a) is reached and the electrical contact is opened and the relay function is stopped. Work to become It is also known to have a function.
In the case of an electromagnetic relay having the above structure, for example, for an automobile, it is used under a load condition of power supply voltage: DC 14V, rated current: 20 to 30A. In this case, the dimensions of the electrical contact are those of a normal ribbed shape. Those having a warp of 3 to 5 mm are common.
In addition, various materials have been put to practical use and proposed for the electrical contacts of the electromagnetic relay having the above structure. Among them, materials shown below, that is, in mass% (hereinafter,% indicates mass%),
Sn: 4.5-10%,
In: 0.1 to 5%,
Bi: 0.01-5%,
And the rest of the Ag alloy having a composition composed of Ag and inevitable impurities is subjected to an internal oxidation treatment, that is, in an oxidizing atmosphere at a temperature of 650 to 750 ° C. for 15 to 30 hours. An internal silver oxide-oxide-based material that has a structure in which a Sn-based oxide and an In-based oxide are precipitated has attracted attention.
近年の自動車および事務機などの高機能化および高性能化はめざましく、さらに小型化および軽量化の進展も著しく、これに伴ない、これの構造部品である電磁リレーも小寸化し、したがってこれに組み込まれている電気接点も小径化の傾向にあり、リッベト形状のもので頭径が1.5〜2.5mmのものが要求されている。一方、電磁リレーを小寸化しても、例えば自動車用であれば、従来の負荷条件と変わらない負荷条件、すなわち電源電圧:直流14V、定格電流:20〜30Aの負荷条件での使用となるので、電気接点を小径化すればするほど単位面積当たりの電流密度は飛躍的に高いものとなるが、上記の電磁リレー用の内部酸化銀−酸化物系材料製電気接点(以下、単に電気接点という)においては、具備する導電性が相対的に低いものであるために、小径化によって接点間の発熱が高くなり、接点自身が軟化することから、耐溶着性が急激に低下するようになり、この結果耐消耗性が著しく低下し、比較的短時間で使用寿命に至るのが現状である。 In recent years, the functions and performance of automobiles and office machines have been remarkably improved, and the progress of miniaturization and weight reduction has been remarkable. As a result, the structural electromagnetic relays have also been reduced in size. The built-in electrical contacts are also tending to have a small diameter, and a ribbed shape with a head diameter of 1.5 to 2.5 mm is required. On the other hand, even if the size of the electromagnetic relay is reduced, for example, for automobiles, it is used under load conditions that are not different from the conventional load conditions, that is, power supply voltage: DC 14V, rated current: 20-30A. The smaller the electrical contact diameter, the higher the current density per unit area becomes. However, the electrical contact made of the internal silver oxide-oxide material for electromagnetic relay (hereinafter simply referred to as electrical contact). ), Since the conductivity is relatively low, the heat generation between the contacts is increased by reducing the diameter, and the contact itself softens, so that the resistance to welding suddenly decreases, As a result, the wear resistance is remarkably lowered and the service life is reached in a relatively short time.
そこで、本発明者等は、上述のような観点から、特に上記の従来電気接点に着目し、これの導電性向上を図るべく、研究を行った結果、
上記の従来電気接点を構成する内部酸化処理前のAg合金の合金成分であるSn、In、およびBiの含有量を、
Sn:5.1〜9%、
In:1.5〜5%、
Bi:0.005〜0.06%、
に特定した上で、これに上記の通常の条件で内部酸化処理を施した後で、大気雰囲気中、900〜960℃に10〜20時間保持の条件で熱処理を施すと、合金成分として含有するBi成分の作用で、内部酸化処理で析出した超微粒のSn系酸化物およびIn系酸化物が前記熱処理で拡散集合して成長し、粗粒化して、複合酸化物粗粒となり、これがAg素地に分散分布した組織をもつようになり、前記Ag素地には内部酸化処理で析出した超微粒のSn系酸化物およびIn系酸化物が存在しないものとなり、この結果接点自身の導電性が著しく向上し、小径化による高電流密度での実用に際しても発熱が著しく抑制されることから、接点間の溶着現象がなくなり、長期に亘ってすぐれた接点特性を発揮するようになる、という研究結果を得たのである。
Therefore, the present inventors have focused on the above-described conventional electrical contact from the above viewpoint, and as a result of conducting research to improve the conductivity thereof,
The contents of Sn, In, and Bi, which are alloy components of the Ag alloy before the internal oxidation treatment constituting the conventional electrical contact,
Sn: 5.1-9%
In: 1.5-5%
Bi: 0.005 to 0.06%,
After being subjected to internal oxidation treatment under the above normal conditions, and then subjected to heat treatment at 900 to 960 ° C. for 10 to 20 hours in the air atmosphere, it is contained as an alloy component. Due to the action of the Bi component, the ultrafine Sn-based oxide and In-based oxide precipitated by the internal oxidation treatment are diffused and aggregated by the heat treatment, and are coarsened to become complex oxide coarse particles, which are formed on the Ag base. As a result, the Ag base material is free of ultra-fine Sn-based oxides and In-based oxides deposited by internal oxidation treatment. As a result, the conductivity of the contact itself is remarkably improved. However, since the heat generation is remarkably suppressed even in practical use at a high current density due to the small diameter, there has been a research result that the welding phenomenon between the contacts is eliminated and excellent contact characteristics are exhibited over a long period of time. Than is.
この発明は、上記の研究結果に基づいてなされたものであって、
Sn:5.1〜9%、
In:1.5〜5%、
Bi:0.005〜0.06%、
を含有し、残りがAgと不可避不純物からなる組成を有するAg合金の内部酸化処理材に、析出酸化物拡散集合成長熱処理を施して、前記内部酸化処理材のAg素地に析出した超微粒のSn系酸化物およびIn系酸化物を拡散集合して成長させ、粗粒化してなる複合酸化物粗粒がAg素地に分散分布し、前記超微粒のSn系酸化物およびIn系酸化物が存在しない組織を有するものとした内部酸化銀−酸化物系材料で構成してなる小寸化電磁リレーに用いるのに適した高導電性電気接点に特徴を有するものである。
This invention was made based on the above research results,
Sn: 5.1-9%
In: 1.5-5%
Bi: 0.005 to 0.06%,
An ultra-fine Sn precipitate deposited on an Ag substrate of the internal oxidation treatment material by subjecting the internal oxidation treatment material of the Ag alloy having the composition of Ag and inevitable impurities to the inner oxidation treatment material to a precipitation oxide diffusion collective growth heat treatment. Composite oxide coarse particles obtained by diffusing and growing oxide-based oxides and In-based oxides and coarsening are dispersed and distributed on the Ag base, and the ultrafine Sn-based oxides and In-based oxides are not present. It is characterized by a highly conductive electrical contact suitable for use in a miniaturized electromagnetic relay composed of an internal silver oxide-oxide material having a texture .
つぎに、この発明の電気接点において、これを構成するAg合金の組成を上記の通りに限定した理由を説明する。
(a)Sn
Sn成分には、内部酸化処理で熱的に安定なSn系酸化物を形成し、接点の開離性と耐溶着性を向上させる作用があるが、その含有割合が5.1%未満では、析出するSn系酸化物の割合が十分でないために、前記作用に所望の向上効果が得られず、一方その含有割合が9%を越えると、硬さが急激に上昇し、伸線加工性およびヘッダ加工性が損なわれるようになることから、その含有割合を5.1〜9%と定めた。
Next, the reason why the composition of the Ag alloy constituting the electrical contact of the present invention is limited as described above will be described.
(A) Sn
The Sn component has the effect of forming a thermally stable Sn-based oxide by internal oxidation treatment and improving the contact detachability and welding resistance. However, when the content ratio is less than 5.1%, Since the ratio of the Sn-based oxide to be precipitated is not sufficient, a desired improvement effect cannot be obtained in the above-described action. On the other hand, when the content ratio exceeds 9%, the hardness rapidly increases, the wire drawing workability and Since the header processability is impaired, the content ratio is set to 5.1 to 9%.
(b)In
In成分には、内部酸化処理でのSn系酸化物の析出を促進し、かつ自身も熱的に安定なIn系酸化物を形成して、Sn系酸化物との共存において、開離性と耐溶着性を向上させる作用があるが、その含有割合が1.5%未満では、Sn系酸化物の析出が不十分となり、この結果Sn成分が合金成分として素地中に固溶含有するようになることから、高導電性の確保が困難となり、一方その含有割合が5%を越えると、硬さに上昇傾向が現れ、伸線加工性やヘッダー加工性が低下するようになることから、その含有割合を1.5〜5%と定めた。
(B) In
The In component promotes the precipitation of Sn-based oxides in the internal oxidation treatment, and also forms a thermally stable In-based oxide itself. In the coexistence with the Sn-based oxides, Although there is an effect of improving the welding resistance, if the content ratio is less than 1.5%, the precipitation of the Sn-based oxide becomes insufficient, and as a result, the Sn component is contained as a solid solution in the substrate as an alloy component. As a result, it is difficult to ensure high conductivity. On the other hand, if the content exceeds 5%, the hardness tends to increase, and the wire drawing workability and header workability will decrease. The content ratio was set to 1.5 to 5%.
(c)Bi
Bi成分には、析出酸化物拡散集合成長熱処理で、内部酸化処理で析出した超微粒のSn系酸化物およびIn系酸化物の拡散集合成長を著しく促進し、これらを粗粒化して複合酸化物粗粒を形成する作用があるが、その含有割合が0.005%未満では、前記超微粒のSn系酸化物およびIn系酸化物の拡散集合成長が満足に行われず、素地に前記超微粒のSn系酸化物およびIn系酸化物が残留して、十分な導電性向上効果が得られず、一方その含有割合が0.06%を越えると、複合酸化物粗粒が大きくなり過ぎ、素地の占める面積割合が大きくなり過ぎ、これが耐溶着性低下の原因となることから、その含有割合を0.005〜0.06%と定めた。
(C) Bi
In the Bi component, the precipitation oxide diffusion aggregate growth heat treatment significantly promotes the diffusion aggregation growth of ultrafine Sn-based oxides and In-based oxides precipitated by internal oxidation treatment, and these are coarsened to form composite oxides. Although there is an effect of forming coarse grains, if the content ratio is less than 0.005%, the diffusion aggregate growth of the ultrafine Sn-based oxide and In-based oxide is not performed satisfactorily, and the ultrafine particles are not formed on the substrate. Sn-based oxide and In-based oxide remain, and a sufficient conductivity improvement effect cannot be obtained. On the other hand, if the content ratio exceeds 0.06%, the complex oxide coarse particles become too large, Since the area ratio which occupies becomes too large, and this causes a decrease in welding resistance, the content ratio is determined to be 0.005 to 0.06%.
この発明の電気接点は、すぐれた導電性を有するので、電磁リレーの小寸化による小径化で電流密度の高い使用条件になっても接点間の発熱が著しく抑制され、この結果接点自身の温度上昇による軟化がなくなり、接点間にすぐれた耐溶着性が保持されることから、きわめて長期に亘ってすぐれた電気接点特性、すなわち、すぐれた耐溶着性および耐消耗性を示すものである。 Since the electrical contact of the present invention has excellent conductivity, heat generation between the contacts is remarkably suppressed even under the use conditions where the current density is high due to the reduction in the diameter of the electromagnetic relay, resulting in the temperature of the contact itself. Since softening due to the rise is eliminated and excellent welding resistance is maintained between the contacts, excellent electrical contact characteristics over a very long period, that is, excellent welding resistance and wear resistance are exhibited.
つぎに、この発明の電気接点を実施例により具体的に説明する。 Next, the electrical contact of the present invention will be specifically described with reference to examples.
表1に示される成分組成をもったAg合金を高周波溶解炉を用いて溶製し、円柱状のインゴットに鋳造し、前記インゴットに700℃に加熱した状態で熱間押出し加工を施して幅:30mm×厚さ:10mmの寸法をもった板材とし、この板材に、700℃の加熱温度で熱間圧延を施して幅:30mm×厚さ:3mmの板材とし、さらにこの板材に中間焼鈍を加えながら冷間圧延を行って幅:30mm×厚さ:0.6mmの薄板材とし、これに長さ方向に沿って幅:2mmの間隔で切断して長さ:30mm×幅:2mm×厚さ:0.6mmの寸法をもった短冊片とし、この短冊片に、酸素雰囲気中、温度:700℃に24時間保持の条件で内部酸化処理を施して、従来内部酸化電気接点用内部酸化処理材A−1〜A−13、および比較内部酸化電気接点用内部酸化処理材B−1〜B−9をそれぞれ形成し、ついで前記短冊片形状の内部酸化処理材のそれぞれを金型に装入し、圧縮成形して直径:70mm×長さ:70mmの寸法をもった円柱状成形体とし、この円柱状成形体に800℃の加熱温度で熱間押出し加工を施して直径:7mmの線材とし、さらに800℃の加熱温度で熱間伸線加工を行って直径:2mmの線材とし、この線材からヘッダーマシンを用いて、リベット形状および頭径:2.3mm×頭厚:0.3mm×足径:1.5mm×足長:1.5mmの寸法をもった従来内部酸化電気接点1〜13、および比較内部酸化電気接点1〜9をそれぞれ製造した。 An Ag alloy having the component composition shown in Table 1 is melted using a high-frequency melting furnace, cast into a cylindrical ingot, and subjected to hot extrusion in a state where the ingot is heated to 700 ° C. 30 mm × thickness: a plate with a dimension of 10 mm, this plate is subjected to hot rolling at a heating temperature of 700 ° C. to obtain a plate with a width of 30 mm × thickness: 3 mm, and intermediate annealing is added to this plate While cold rolling, a thin plate material having a width of 30 mm × thickness: 0.6 mm was cut along the length direction at an interval of width: 2 mm, and length: 30 mm × width: 2 mm × thickness. : A strip having a size of 0.6 mm, and this strip is subjected to internal oxidation treatment in an oxygen atmosphere and at a temperature of 700 ° C. for 24 hours to obtain an internal oxidation treatment material for a conventional internal oxidation electrical contact. A-1 to A-13 and comparative internal oxidation electricity Each of the internal oxidation treatment materials B-1 to B-9 for air contact is formed, and then each of the strip-shaped internal oxidation treatment materials is placed in a mold and compression-molded to have a diameter: 70 mm × length: A cylindrical molded body having a dimension of 70 mm is formed, and this cylindrical molded body is hot-extruded at a heating temperature of 800 ° C. to form a wire with a diameter of 7 mm, and further hot drawn at a heating temperature of 800 ° C. To obtain a wire rod having a diameter of 2 mm, and using this header, a rivet shape and a head diameter: 2.3 mm × head thickness: 0.3 mm × foot diameter: 1.5 mm × foot length: 1.5 mm Conventional internal oxidized electrical contacts 1-13 having dimensions and comparative internal oxidized electrical contacts 1-9 were produced respectively.
ついで、上記の短冊片形状の従来内部酸化電気接点用内部酸化処理材A−1〜A−13および比較内部酸化電気接点用内部酸化処理材B−1〜B−9をそれぞれ金型に装入し、圧縮成形して直径:70mm×長さ:70mmの寸法とした円柱状成形体に、大気雰囲気中、900〜950℃の範囲内の所定の温度に12時間保持の条件で析出酸化物拡散集合成長熱処理を施す以外は同一の条件で、表2に示される通り本発明電気接点1〜13および合金成分としてBiを含有しない比較電気接点1〜9をそれぞれ製造した。 Subsequently, the above-mentioned strip-shaped conventional internal oxidation treatment materials A-1 to A-13 for internal oxidation electrical contacts and internal oxidation treatment materials B-1 to B-9 for comparative internal oxidation electrical contacts are respectively charged into the molds. Then, it is compression molded to form a cylindrical molded body having a diameter of 70 mm × length of 70 mm, and the diffusion of precipitated oxides in an air atmosphere at a predetermined temperature within a range of 900 to 950 ° C. for 12 hours. As shown in Table 2, electrical contacts 1 to 13 of the present invention and comparative electrical contacts 1 to 9 containing no Bi as an alloy component were produced under the same conditions except that the aggregate growth heat treatment was performed.
ついで、この結果得られた各種の電気接点について、その組織を走査型電子顕微鏡(倍率:2万倍)を用いて観察したところ、本発明電気接点1〜13は、いずれも内部酸化処理で析出したままの超微粒のSn系酸化物およびIn系酸化物が存在せず、これらの超微粒酸化物が析出酸化物拡散集合成長熱処理で拡散集合成長し粗粒化して複合酸化物粗粒となり、この複合酸化物粗粒がAg素地に分散分布した組織を示すのに対して、従来内部酸化電気接点1〜13では、いずれもAg素地に超微粒のSn系酸化物およびIn系酸化物が内部酸化処理で析出したままの状態で存在する組織を示し、また同様の組織は合金成分としてBiを含有しない比較電気接点1〜9でも見られた。これらの組織観察結果のうち、本発明電気接点3の組織を図1に、従来内部酸化電気接点3の組織を図2にそれぞれ模写図で示した。 Next, regarding the various electrical contacts obtained as a result, when the structure was observed using a scanning electron microscope (magnification: 20,000 times), all of the electrical contacts 1 to 13 of the present invention were precipitated by internal oxidation treatment. There is no ultra-fine Sn-based oxide and In-based oxide as they are, and these ultra-fine oxides are diffusion-growth-growth by precipitation oxide diffusion-aggregation heat treatment and coarsened to become composite oxide coarse-grains, In contrast to the composite oxide coarse particles dispersed and distributed in the Ag substrate, the conventional internal oxidation electrical contacts 1 to 13 have ultrafine Sn-based oxides and In-based oxides in the Ag substrate. The structure | tissue which exists in the state as deposited by oxidation treatment was shown, and the same structure | tissue was seen also in the comparative electrical contacts 1-9 which do not contain Bi as an alloy component. Of these structural observation results, the structure of the electrical contact 3 of the present invention is shown in FIG. 1, and the structure of the conventional internal oxidation electrical contact 3 is shown in FIG.
さらに、上記の各種の電気接点について、ASTM電気接点試験機を用い、
モーターロック負荷方式、
電源電圧:直流14V、
定格電流:23A、
接点接触力:15gf、
接点開離力:15gf、
の条件で開閉試験を行い、開閉不能に至るまでの開閉回数(耐久開閉回数)を測定した。これらの結果を表1,2に示した。なお、表1,2には電気接点の導電性を評価する目的で、電気伝導度(IACS%)の測定結果を示し、さらにマイクロビッカース硬さ(Hv)も示した。
Furthermore, for the various electrical contacts described above, an ASTM electrical contact testing machine was used.
Motor lock load system,
Power supply voltage: DC 14V,
Rated current: 23A
Contact contact force: 15 gf,
Contact opening force: 15 gf
The open / close test was conducted under the conditions described above, and the number of open / close operations (endurance open / close count) until opening / closing was impossible was measured. These results are shown in Tables 1 and 2. Tables 1 and 2 show the measurement results of electrical conductivity (IACS%) and the micro Vickers hardness (Hv) for the purpose of evaluating the electrical conductivity of the electrical contacts.
表1,2に示される結果から、Ag素地に内部酸化処理で析出したままの超微粒のSn系酸化物およびIn系酸化物の存在がなく、これらの超微粒酸化物が拡散集合して成長し、複合酸化物粗粒を形成している本発明電気接点1〜13は、リベット形状の頭径が2.3mmと小径化され、この結果電流密度の高い使用条件となるが、いずれもすぐれた導電性を有するので、接点間の発熱が著しく抑制され、接点自身の温度上昇による軟化がなくなり、接点間にすぐれた耐溶着性が保持されることから、きわめて長い使用寿命を示すのに対して、Sn系酸化物およびIn系酸化物が内部酸化処理で析出したままの超微粒の状態でAg素地に分散分布する従来内部酸化電気接点1〜13およびBiを含有しない比較電気接点1〜9は、いずれも導電性が低く、電流密度の高い使用条件では接点間の発熱が高くなり、良好な耐溶着性を維持することが困難になることから、比較的短時間で使用寿命に至ることが明らかである。
上述のように、この発明の電気接点は、小径化して単位面積当たりの電流密度が高くなっても長期に亘ってすぐれた電気接点特性、すなわち、すぐれた耐溶着性および耐消耗性を発揮するものであり、電磁リレーの小寸化に十分満足に対応できるものである。
From the results shown in Tables 1 and 2, there is no presence of ultrafine Sn-based oxides and In-based oxides that have been deposited on the Ag substrate by the internal oxidation treatment, and these ultrafine oxides grow by diffusion aggregation. In addition, the electrical contacts 1 to 13 of the present invention forming the complex oxide coarse grains have a rivet-shaped head diameter of 2.3 mm, which results in a high current density operating condition. Because of its high conductivity, heat generation between the contacts is remarkably suppressed, softening due to temperature rise of the contact itself is eliminated, and excellent welding resistance is maintained between the contacts. In addition, conventional internal oxidation electrical contacts 1 to 13 in which Sn-based oxide and In-based oxide are dispersed and distributed in an Ag base in a state of ultrafine particles that have been deposited by internal oxidation treatment, and comparative electrical contacts 1 to 9 that do not contain Bi. Are both Sex is low, the heat generation between the contacts becomes high at high operating conditions of current density, since it becomes difficult to maintain a good welding resistance, it is apparent that lead to a relatively short time service life.
As described above, the electrical contact of the present invention exhibits excellent electrical contact characteristics over a long period of time, that is, excellent welding resistance and wear resistance even when the diameter is reduced and the current density per unit area is increased. Therefore, it can sufficiently satisfy the miniaturization of electromagnetic relays.
Claims (1)
Sn:5.1〜9%、
In:1.5〜5%、
Bi:0.005〜0.06%、
を含有し、残りがAgと不可避不純物からなる組成を有するAg合金の内部酸化処理材に、析出酸化物拡散集合成長熱処理を施して、前記内部酸化処理材のAg素地に析出した超微粒のSn系酸化物およびIn系酸化物を拡散集合して成長させ、粗粒化してなる複合酸化物粗粒がAg素地に分散分布し、前記超微粒のSn系酸化物およびIn系酸化物が存在しない組織を有するものとした内部酸化銀−酸化物系材料で構成したことを特徴とする小寸化電磁リレーに用いるのに適した高導電性電気接点。 % By mass
Sn: 5.1-9%
In: 1.5-5%
Bi: 0.005 to 0.06%,
An ultra-fine Sn precipitate deposited on an Ag substrate of the internal oxidation treatment material by subjecting the internal oxidation treatment material of the Ag alloy having the composition of Ag and inevitable impurities to the inner oxidation treatment material to a precipitation oxide diffusion collective growth heat treatment. Composite oxide coarse particles obtained by diffusing and growing oxide-based oxides and In-based oxides and coarsening are dispersed and distributed on the Ag base, and the ultrafine Sn-based oxides and In-based oxides are not present. A highly conductive electrical contact suitable for use in a miniaturized electromagnetic relay, characterized by comprising an internal silver oxide-oxide-based material having a texture .
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JP2003401297A JP4389562B2 (en) | 2003-12-01 | 2003-12-01 | Electrical contacts made of internal silver oxide-oxide material for miniaturized electromagnetic relays with high conductivity |
DE602004020844T DE602004020844D1 (en) | 2003-08-08 | 2004-08-03 | A method of making an electrical contact of high electrical conductivity for an electromagnetic relay and electrical contact therewith |
EP04018360A EP1505164B1 (en) | 2003-08-08 | 2004-08-03 | Process for producing an electrical contact having high electrical conductivity for a compact electromagnetic relay and produced electrical contact |
US10/913,863 US8187395B2 (en) | 2003-08-08 | 2004-08-06 | Electrical contact having high electrical conductivity made of internally oxidized silver-oxide material for compact electromagnetic relay |
CN200410076655.3A CN1603443B (en) | 2003-08-08 | 2004-08-06 | Electrical contact having high electrical conductivity made of internally oxidized silver-oxide material for compact electromagnetic relay |
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