JP4374937B2 - Molded body with foamed in-mold label that forms uneven patterns - Google Patents
Molded body with foamed in-mold label that forms uneven patterns Download PDFInfo
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- JP4374937B2 JP4374937B2 JP2003270608A JP2003270608A JP4374937B2 JP 4374937 B2 JP4374937 B2 JP 4374937B2 JP 2003270608 A JP2003270608 A JP 2003270608A JP 2003270608 A JP2003270608 A JP 2003270608A JP 4374937 B2 JP4374937 B2 JP 4374937B2
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Description
本発明は、所定表面位置に凹凸模様を形成する発泡インモールドラベル付成形体に関するものである。 The present invention relates to a molded body with a foamed in-mold label that forms a concavo-convex pattern at a predetermined surface position.
従来、射出成形や中空成形などにおいては、前もって、インモールドラベルを金型内に挿着し、成形体を成形と同時に、インモールドラベルをその成形体に熱融着したインモールドラベル付成形体が、一般的に知られていた。 Conventionally, in injection molding or hollow molding, an in-mold label is inserted into a mold in advance, and the molded body is molded at the same time that the in-mold label is heat-sealed to the molded body. However, it was generally known.
しかしながら、上述の従来のインモールドラベル付成形体は、インモールドラベルの主体材質が紙又は合成樹脂フィルムであった。このため、インモールドラベルの表面に凹凸模様をつける場合には、浮き上げの高さに限界があり、意匠性の高いものを得ることが難しかった。表1に示すように、通常の紙ラベルの場合には、浮き上げ可能な高さが1mm以下であり、金型再現性が悪く、美粧性が劣っていた。また、通常の合成樹脂フィルムラベルの場合は、浮き上げ可能な高さが2mm以下であり、紙ラベルに比較して美粧性が良好であるが、成形時の耐熱性が劣り、溶融樹脂の温度や圧力に負けて破れてしまうことがあった。耐熱性樹脂を使用することもできるが、この場合には製造費用が非常に高価となった。 However, in the above-described conventional molded body with an in-mold label, the main material of the in-mold label is paper or a synthetic resin film. For this reason, when providing a concavo-convex pattern on the surface of the in-mold label, there is a limit to the height of lifting, and it has been difficult to obtain a high design property. As shown in Table 1, in the case of a normal paper label, the height that can be lifted was 1 mm or less, the mold reproducibility was poor, and the cosmetics were inferior. In the case of a normal synthetic resin film label, the height that can be lifted is 2 mm or less, and the cosmetics are better than paper labels, but the heat resistance during molding is poor, and the temperature of the molten resin Sometimes it was torn under pressure. Although a heat resistant resin can be used, in this case, the manufacturing cost becomes very expensive.
本発明は、上述の従来のインモールドラベル付成形体の問題を解決したものであり、金型に対する再現性が良好で、所定表面位置に意匠性の高い凹凸模様を形成する発泡インモールドラベル付成形体を提供するものである。 The present invention solves the problems of the above-described conventional molded body with an in-mold label, has a reproducibility to a mold, and has a foam in-mold label that forms an uneven pattern with high designability at a predetermined surface position. A molded body is provided.
すなわち、本発明の第1の発明は、前もって、熱発泡性マイクロカプセルを分散させた紙である後発泡紙を主体層とする未発泡のインモールドラベルを、金型内の凹凸模様を形成するキャビティー面の所定位置に挿着し、成形体を成形すると同時に、前記インモールドラベルを前記成形体に熱融着及び発泡させて、該発泡インモールドラベルの所定表面位置に凹凸模様を発現させたことを特徴とする凹凸模様を形成する発泡インモールドラベル付成形体である。 That is, the first invention of the present invention forms an uneven pattern in a mold from an unfoamed in-mold label whose main layer is a post-foamed paper, which is a paper in which thermally foamable microcapsules are dispersed in advance. At the same time as inserting into a predetermined position on the cavity surface and molding the molded body, the in-mold label is thermally fused and foamed to the molded body to develop a concavo-convex pattern at a predetermined surface position of the foamed in-mold label. It is a molded body with a foam in-mold label which forms the uneven | corrugated pattern characterized by the above-mentioned.
次に、本発明の第2の発明は、前記後発泡紙が、紙を抄紙するときに、混抄する熱発泡性マイクロカプセルを発泡させないように乾燥し、かつ、天然繊維分が固形分の51重量%以上であり、発泡開始温度が成形温度以下であることを特徴とする第1の発明に記載の凹凸模様を形成する発泡インモールドラベル付成形体である。 Next, according to a second aspect of the present invention, the post-foamed paper is dried so as not to foam the thermally foamable microcapsules to be mixed when the paper is made, and the natural fiber content is 51% of solid content. The molded body with a foamed in-mold label for forming a concavo-convex pattern according to the first invention, characterized by being at least wt% and having a foaming start temperature not higher than the molding temperature.
本発明の凹凸模様を形成する発泡インモールドラベル付成形体は、使用する未発泡のインモールドラベルの主体層が熱発泡性マイクロカプセルを含有する後発泡紙であり、金型内で成形体を成形すると同時に、未発泡のインモールドラベルを成形体に熱融着及び発泡させるものであり、この結果、金型のキャビティー面の凹凸模様の再現性が良好で、発泡インモールドラベルの表面に意匠性の高い凹凸模様を形成することができる。 The molded body with a foamed in-mold label forming the uneven pattern according to the present invention is a post-foamed paper in which the main layer of the unfoamed in-mold label used contains thermally foamable microcapsules, and the molded body is molded in a mold. At the same time as molding, an unfoamed in-mold label is heat-sealed and foamed on the molded body, and as a result, the reproducibility of the uneven pattern on the cavity surface of the mold is good, and the surface of the foamed in-mold label is An uneven pattern with high designability can be formed.
また、本発明の凹凸模様を形成する発泡インモールドラベル付成形体は、発泡インモールドラベルの天然繊維分が51重量%以上であり、成形時の耐熱性が良好で、廃棄性も良い。また、発泡効果により断熱性が良好である。 Moreover, the foamed in-mold-labeled molded body forming the uneven pattern of the present invention has a natural fiber content of 51% by weight or more in the foamed in-mold label, has good heat resistance during molding, and has good disposal properties. Moreover, heat insulation is favorable by the foaming effect.
次に、本発明の凹凸模様を形成する発泡インモールドラベル付成形体の実施の形態について説明する。 Next, an embodiment of the molded body with a foamed in-mold label for forming the concavo-convex pattern of the present invention will be described.
本発明の凹凸模様を形成する発泡インモールドラベル付成形体の成形方法は、まず、射出成形や中空成形などの金型内の凹凸模様を形成するキャビティー面の所定位置に、前もって、表面層が二次加工層(ニス塗工層、印刷層、樹脂層など)で、主体層が後発泡紙層で、裏面層が接着性樹脂層の未発泡のインモールドラベルを、表面をキャビティー面に静電気法、接着剤法、バキューム法などにより仮接着させて挿着し、次に、金型を型締めして、溶融樹脂により容器などの成形体を成形すると同時に、インモールドラベルを成形体の表面に熱融着させ、このときの成形体の熱によりインモールドラベルの主体層の後発泡紙層を発泡させて、この発泡インモールドラベルの所定表面位置に、金型の凹凸模様を形成するキャビティー面の凹凸模様を発現させるものである。 The molding method of the molded body with a foam in-mold label for forming the concavo-convex pattern of the present invention is as follows. First, the surface layer is formed in a predetermined position on the cavity surface for forming the concavo-convex pattern in the mold such as injection molding or hollow molding. Is the secondary processing layer (varnish coating layer, printing layer, resin layer, etc.), the main layer is the post-foamed paper layer, the back layer is the unfoamed in-mold label with the adhesive resin layer, and the surface is the cavity surface Are attached by temporary adhesion by electrostatic method, adhesive method, vacuum method, etc., and then molds are clamped and molded products such as containers are molded with molten resin, and at the same time, in-mold labels are molded The foamed paper layer is foamed after the main layer of the in-mold label by the heat of the molded body at this time, and the uneven pattern of the mold is formed at a predetermined surface position of the foamed in-mold label. Of the cavity surface It is intended to express.
上述の未発泡のインモールドラベルの主体層に用いる後発泡紙としては、混抄タイプと含浸タイプとがあり、混抄タイプの後発泡紙は、紙を抄紙するときに、混抄する熱発泡性マイクロカプセルを発泡させないようにして乾燥させたものであり、含浸タイプの後発泡紙は、層間強度の弱い紙に、熱発泡性マイクロカプセルと、紙繊維とカプセルとをつなぐ熱可塑性樹脂とを混合した薬剤を含浸し、発泡させないようにして乾燥させたものである。そして、両タイプの後発泡紙とも、天然繊維分が固形分の51重量%以上であり、発泡開始温度が成形温度以下に作製されるものである。 As the post-foamed paper used for the main layer of the above-mentioned unfoamed in-mold label, there are a mixed paper type and an impregnated type, and the mixed foam type post-foamed paper is a thermally foamable microcapsule that is mixed when paper is made. The impregnated post-foamed paper is a compound of a paper with low interlaminar strength mixed with thermally foamable microcapsules and a thermoplastic resin that connects the paper fibers and the capsules. And dried so as not to foam. In both types of post-foamed paper, the natural fiber content is 51% by weight or more of the solid content, and the foaming start temperature is made below the molding temperature.
まず、熱発泡性マイクロカプセルを20重量%含有する混抄タイプの後発泡紙(100g/m2 )を作製し、この後発泡紙の裏面にエチレン・酢酸ビニル共重合体系ホットメルト接着性樹脂を25μm厚みで塗工し、表面に直鎖低密度ポリエチレンを15μm厚みで押し出し加工したのち、その表面をコロナ処理して文字と絵柄を印刷し、さらにその表面に、金型との剥離性を良好にするためのシリコン入り剥離ニスを塗工した。そして、所定ラベル形状に打ち抜いて、図2に示す〔表面側〕ニス層(110)/印刷層(120)/ポリエチレンフィルム層(130)/後発泡紙層(140)/接着樹脂層(150)〔裏面側〕構成の未発泡のインモールドラベル(100a)を作製した。 First, a mixed paper type post-foamed paper (100 g / m 2 ) containing 20% by weight of thermally foamable microcapsules was prepared, and then an ethylene / vinyl acetate copolymer hot melt adhesive resin was applied to the back of the foamed paper at 25 μm. After coating with a thickness and extruding a linear low density polyethylene with a thickness of 15 μm on the surface, the surface is corona-treated to print characters and patterns, and the surface has good releasability from the mold. A peeling varnish containing silicon for coating was applied. Then, it is punched into a predetermined label shape, and the [surface side] varnish layer (110) / printing layer (120) / polyethylene film layer (130) / post-foamed paper layer (140) / adhesive resin layer (150) shown in FIG. [Back side] An unfoamed in-mold label (100a) having a configuration was prepared.
次に、図1(a)に示す上述の未発泡のインモールドラベル(100a)を、射出成形機上の型開きした射出成形用金型(200)の3mm径のドット状の凹状模様(211)を形成したキャビティー面(210)に、図1(b)に示すように、静電気法で仮接着して挿着し、金型を型締めをして、キャビティー内へゲートより220℃の成形温度で溶融したポリプロピレンを射出して、図1(c)に示す成形体(300)を成形すると同時に、インモールドラベルを成形体の表面に熱融着させ、このときの成形体の熱によりインモールドラベルの主体層の後発泡紙中に分散する熱発泡性マイクロカプセルを発泡させ、その膨張力によって金型のキャビティー面に形成された凹状模様を発泡インモールドラベルの表面が埋め、この発泡インモールドラベルの所定表面位置に凸状模様を発現させ、型開きした金型から離型して、図1(c)に示す本実施例の凸状模様(101)を形成する発泡インモールドラベル(100b)付成形体(400)を作製した。なお、上述の金型キャビティー面に形成した3mm径のドット状の凹状模様は、深さを変えて、発泡したインモールドラベルがどの程度まで入るかも調べた。 Next, the above-mentioned unfoamed in-mold label (100a) shown in FIG. 1 (a) is formed into a 3 mm-diameter dot-like concave pattern (211) of an injection mold (200) opened on an injection molding machine. As shown in FIG. 1 (b), it is temporarily bonded by an electrostatic method and inserted into the cavity surface (210) formed with a die, and the mold is clamped to enter the cavity at 220 ° C. from the gate. The molded polypropylene (300) shown in FIG. 1 (c) is molded by injecting polypropylene melted at the molding temperature, and at the same time, the in-mold label is thermally fused to the surface of the molded body. The foamed thermally foamable microcapsules dispersed in the foamed paper after the main layer of the in-mold label are foamed, and the surface of the foamed in-mold label fills the concave pattern formed on the cavity surface of the mold by the expansion force. This foam immo A foamed in-mold label (100b) that forms a convex pattern at a predetermined surface position of the mold label and is released from the mold that is opened to form the convex pattern (101) of this embodiment shown in FIG. ) A molded body (400) was produced. It should be noted that the depth of the 3 mm diameter dot-like concave pattern formed on the mold cavity surface was changed to examine how much the foamed in-mold label could enter.
作製した凸状模様を形成する発泡インモールドラベル付成形体については、発泡インモールドラベルの凸状模様の浮き上げ高さ、美粧性、廃棄性、金型の凹状模様の再現性、成形時の耐熱性、また、ラベルの断熱効果について評価した。この結果を表1に記載する。 For the molded product with foamed in-mold label that forms the convex pattern produced, the raised height of the convex pattern of the foamed in-mold label, cosmetics, disposability, reproducibility of the concave pattern of the mold, The heat resistance and the heat insulating effect of the label were evaluated. The results are listed in Table 1.
100a……未発泡のインモールドラベル
100b……発泡インモールドラベル
101……凸状模様
110……ニス層
120……印刷層
130……ポリエチレンフィルム層
140……後発泡紙層
150……接着性樹脂層
200……射出成形用金型
210……キャビティー面
211……凹状模様
300……成形体
400……インモールドラベル付成形体
100a: Unfoamed in-mold label 100b ... Foamed in-mold label 101 ... Convex pattern 110 ... Varnish layer 120 ... Print layer 130 ... Polyethylene film layer 140 ... Post-foamed paper layer 150 ... Adhesiveness Resin layer 200 ... Injection mold 210 ... Cavity surface 211 ... Concave pattern 300 ... Molded body 400 ... Molded body with in-mold label
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JP2009006667A (en) * | 2007-06-29 | 2009-01-15 | Yoshino Kogyosho Co Ltd | Container with in-mold label and molding method |
US8389080B2 (en) | 2008-07-16 | 2013-03-05 | Ws Packaging Group, Inc. | Label-wrapped foam cups with patterned adhesive |
JP5750747B1 (en) * | 2014-09-18 | 2015-07-22 | 内藤プロセス株式会社 | Fine line pattern forming method |
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