JP4283782B2 - Manufacturing method of resin molding - Google Patents

Description

  The present invention relates to a method for producing a resin molded body using a printed film, and in particular, vehicles, ships, aircraft interior / exterior panels, building materials, home appliances, furniture, wallpaper, Buddhist altars, Buddhist accessories, nameplates, containers, clothing, shoes The present invention relates to a simple manufacturing technique of a resin molded body suitable for manufacturing a resin molded body such as a back, a telephone card, a credit card, and an IC card.

  The printing film used for the production of the resin molded body is a step of feeding the film, a step of screen-printing, for example, an ultraviolet curable resin or a thermosetting resin on the surface of the film, and a step of curing the resin layer. And it manufactures through the process of winding up the film which has a hardened resin layer one by one (for example, refer nonpatent literatures 1-3).

Roll-to-roll, [online], [October 8, 2002 search], Internet <URL: http://www.mino.co.jp/fap.html> Mino Group, Roll to Roll System, [online], [October 8, 2002 search], Internet <URL: http://www.mino.co.jp/kikai_pdf/RtoR.pdf> Tokai Shoji Co., Ltd., roll-to-roll printing line, roll-to-roll cylinder 2-color printing machine, page 2, [online], [October 8, 2002 search], Internet <URL: http: //www.seria .jp / seria_product / line_system / line_system.htm>

  In the screen printing process such as the ultraviolet curable resin described in Non-Patent Documents 1 to 3, the resin layer is usually formed only in a partial region on the film. For this reason, when the film is wound on the roll core in the subsequent film winding process, a gap is formed in a portion where the resin layer on the film is not formed, and the winding form is unstable. For this reason, orderly winding of the film is difficult, and this winding work has a problem that skill is required.

  Therefore, in view of the above problems, the present invention is a printing film that can be rolled up in an orderly manner in the production of a printing film, and that the winding operation can be easily performed without requiring skill. It aims at providing the manufacturing method of the resin molding using a manufacturing method.

The method for producing a resin molded body according to the present invention includes a step of painting and printing on the back surface of a film to form a printed painting layer, a region for printing a resin molded body on the surface of the film, and a region for printing a spacer molded body. In addition, a step of forming a plurality of types of resin layers by screen printing a predetermined resin, a step of curing the resin layer, and a resin layer made of a resin used in a region for printing the spacer molded body, The step of removing together with the film, and burying the resin layer in the film, and at a distance from the surface between the region corresponding to the region where the resin layer of the printed painting layer is provided and other regions A step of molding and integrating a resin base material on the printed painting layer so as to produce a difference, and the step of curing the resin layer is a tree used for a region where the resin molded body is printed. Curing only the surface portion of the resin layer made of the resin, and then curing the entire resin layer made of the resin used for the region where the resin molded body is printed and the resin used for the region where the spacer molded body is printed. It is characterized by .

According to the manufacturing method of the resin molded body, the resin used in the area of printing a resin molding on the film (hereinafter sometimes referred to as "resin for resin molding") in an area other than the printing area a When the film is wound around the roll core in the subsequent film winding process, the resin used in the region where the spacer molded body is printed (hereinafter, sometimes referred to as “resin for spacer”) is printed. The above-mentioned gap does not occur between the films, and the winding form becomes stable. Therefore, according to the method for producing a printed film, orderly winding of the film is easy, and this winding work can be performed without requiring skill. In order to surely obtain the above effect, it is desirable to print the resin for resin molding and the resin for spacer at substantially the same height.

In such a method for producing a resin molded body , it is desirable to print spacer resin in a dot shape. As will be described later, the resin molded body is manufactured by integrating a printing film and a resin base material. In this integration, a resin layer made of a resin for a resin molded body (hereinafter referred to as “resin molded body layer”) is integrated with a resin base material to constitute a design surface. The resin layer made of spacer resin (hereinafter referred to as “spacer layer”) is removed as an unnecessary layer together with a film in contact with the spacer layer prior to the integration. That is, the spacer layer is formed only for height adjustment with the resin molding layer on the film so as to facilitate the winding operation of the printing film. For this reason, the formation mode of the spacer layer on the film may be in any form as long as the height adjustment is possible. According to such a technique, it is possible to suppress an increase in manufacturing cost of the printing film by printing the spacer resin in a dot shape. In addition, the manufacturing cost of a printing film can be reduced further by containing fillers, such as a silica gel, an alumina, a starch, a calcium carbonate, and a talc, for resin for spacers.

In such a method for producing a resin molded body , the step of curing the resin layer is performed by curing only the surface portion of the resin layer (resin molded body layer) made of resin for the resin molded body, and then for the resin molded body. it is characterized by the resin layer made of the resin (molded resin layer) and the resin layer made of a resin spacer as to cure the entire (spacer layer). As described above, the resin molded body layer is integrated with the resin base material in the manufacturing process of the resin molded body to constitute the design surface. For this reason, in order to make a resin molded object have high designability, the desired shape must be provided to the resin molded object layer in the manufacturing process of a printing film. The shape of the resin layer formed on the film is determined in a subsequent curing step. Therefore, in this curing step, it is necessary to apply an appropriate curing mode to give the resin molded body layer a desired shape. On the other hand, an appropriate curing mode is not required in the curing step for the spacer layer that is removed together with a part of the film or the like prior to the integration. In such a technique, before the entire resin molded body layer and the spacer layer are cured, only the surface portion of the resin molded body layer can be cured to give a desired shape to the surface portion of the resin molded body layer. Therefore, it is possible to obtain a resin molded article that can represent a high degree of design quality.

  FIG. 1 relates to a method for producing a printed film, which is a premise of the method for producing a resin molded body of the present invention, and shows an example of a curing mode of a resin layer. That is, in the example shown in FIG. 1, an ultraviolet curable resin layer is obtained by screen-printing two types of ultraviolet curable resins corresponding to a resin for a resin molding and a resin for a spacer in different regions on one surface of a film. Is an example of forming. When the printing film manufacturing method is carried out in the form shown in the figure, the resin molded body layer 2 and the spacer layer 3 are formed by screen printing UV curable resins having different compositions on the surface of the film 1. Thereafter, the resin molded body layer 2 and the surface portions 2a and 3a of the spacer layer 3 formed on the film 1 are irradiated with ultraviolet rays having the first wavelength by a first ultraviolet irradiator (not shown). Since the resin molded body layer 2 and the spacer layer 3 have different compositions, the curing (crosslinking) mode is made different from each other during the first ultraviolet irradiation. In the first ultraviolet irradiation step, only the surface portion 2a of the resin molded body layer 2 is cured (crosslinked), and the surface portion 3a of the spacer layer 3 is not cured (crosslinked). The first wavelength is appropriately selected so that the surface portion 2a is cured to have a desired shape. After such a first irradiation step is completed, the entire resin molded body layer 2 and the spacer layer 3 are cured by ultraviolet irradiation with a second wavelength longer than the first wavelength by a second ultraviolet irradiator (not shown). The desired shape of the resin layer 5 is obtained.

  In the above-described two-stage irradiation of ultraviolet rays, the first wavelength is set short so that the ultraviolet rays can reach only the surface portions 2a and 3a of the resin molded body layer 2 and the spacer layer 3, and are cured by ultraviolet rays. Only the surface portion 2a is cured to a desired shape by selecting a suitable composition of the conductive resin layers 2 and 3. In this state, the resin molded body layer 2 has a two-layer structure of the hardened surface portion 2a and the viscous portion 2b, and the resin of the viscous portion 2b penetrates into the cross-linked mesh and the surface portion. The volume of 2a increases. And the wavy pattern 4 is formed when the volume of the surface part 2a swells. On the other hand, since the surface portion 3a of the spacer layer 3 is not cured (crosslinked), there is no volume change between the surface portion 3a and the lower portion 3b, and no wavy pattern is formed on the surface portion 3a. According to this aspect, since the three-dimensional wave pattern 4 can be formed in a desired shape by using two types of ultraviolet curable resin layers and irradiating the two types of ultraviolet rays in a stepwise manner, a high degree of design is achieved. A print film suitable for production of a resin molded body that can be expressed can be obtained. As this first wavelength, a short wavelength of 180 to 300 nm is used, and preferably a short wavelength of 230 to 270 nm is used. The second wavelength is a long wavelength of 300 to 400 nm, preferably a long wavelength of 320 to 370 nm.

  FIG. 2 relates to a method for producing a printed film, which is a premise of the method for producing a resin molded body according to the present invention, and shows another example of the curing mode of the resin layer. That is, in the example shown in FIG. 2, two types of thermosetting resins corresponding to the resin for the resin molding and the resin for the spacer are screen-printed in different regions on one surface of the film, respectively. Is an example of forming. When the printing film manufacturing method is carried out in the form shown in the figure, the resin molded body layer 6 and the spacer layer 7 are formed by screen-printing thermosetting resins having different compositions on the surface of the film 1. Thereafter, first heat radiation is performed on the surface portions 6 a and 7 a of the resin molded body layer 6 and the spacer layer 7 formed on the film 1 by a first heat dryer (not shown). Since the resin molded body layer 6 and the spacer layer 7 have different compositions, the curing (crosslinking) modes are made different from each other during the first heat radiation. In the first heat radiation step, only the surface portion 6a of the resin molded body layer 6 is cured (crosslinked), and the surface portion 7a of the spacer layer 7 is not cured (crosslinked). The amount of heat in the first heat radiation is appropriately selected so that the surface portion 6a is cured to have a desired shape. After the completion of the first heat radiation step, a second heat dryer (not shown) radiates a larger amount of heat to the entire resin molded body layer 6 and the spacer layer 7 than the amount of heat in the first heat radiation. The desired shape of the resin layer 9 is obtained by performing thermal radiation and curing the entire layers 6 and 7.

  In the two-stage radiation of heat shown above, the first heat quantity is set to be small so that the heat reaches only the surface portions 6a and 7a of the resin molded body layer 6 and the spacer layer 7, and thermosetting is performed. Only the surface portion 6a is cured to a desired shape by selecting a suitable composition of the conductive resin layers 6 and 7. In this state, the resin molded body layer 6 has a two-layer structure of the hardened surface portion 6a and the viscous portion 6b, and the resin of the viscous portion 6b enters the mesh of the crosslinked structure and the surface portion. The volume of 6a increases. And the wavy pattern 8 is formed when the volume of the surface part 6a swells. On the other hand, since the surface portion 7a of the spacer layer 7 is not cured (crosslinked), there is no volume change between the surface portion 7a and the lower portion 7b, and no wavy pattern is formed on the surface portion 7a. According to this aspect, by using two types of thermosetting resin layers and radiating two types of heat in a stepwise manner, the three-dimensional wavy pattern 8 can be formed into a desired shape. A print film suitable for production of a resin molded body that can be expressed can be obtained.

  Even when a printed film is manufactured using a thermosetting resin, it is easy to orderly wind the film as in the case of using the ultraviolet curable resin described above, and the winding does not require skill. Can be realized. Moreover, the printing cost of the printing film can be prevented from increasing by printing the spacer resin in a dot shape. Furthermore, before the entire resin molded body layer and the spacer layer are cured, only the surface portion of the resin molded body layer can be cured and a desired shape can be imparted to the surface portion of the resin molded body layer. A printed film suitable for the production of a resin molded body capable of expressing the properties can be obtained.

The above is a method for producing a printed film which is a premise of the present invention. Hereinafter, a method for producing a resin molded body of the present invention using the method for producing a printed film described above will be described.
The method for producing a resin molded body according to the present invention includes a step of painting and printing on the back surface of a film to form a printed painting layer, a region for printing a resin molded body on the surface of the film, and a region for printing a spacer molded body. In addition, a step of forming a plurality of types of resin layers by screen printing a predetermined resin, a step of curing the resin layer, and a resin layer made of a resin used for a region for printing the spacer molded body The step of removing together with the film, and burying the resin layer in the film, and at a distance from the surface between the region corresponding to the region where the resin layer of the printed painting layer is provided and the other region. A step of molding and integrating a resin base material on the printed painting layer so as to produce a difference.

  According to the method for producing a resin molded body of the present invention, an orderly winding of a film is easy in a film winding process performed between a resin layer curing process and a resin molded body layer embedding process in a film. In addition, it is possible to realize a winding operation that does not require skill. Moreover, the increase in the manufacturing cost of a resin molding can be suppressed by printing the resin for spacers in dot shape. Furthermore, before the entire resin molded body layer and the spacer layer are cured, only the surface portion of the resin molded body layer can be cured and a desired shape can be imparted to the surface portion of the resin molded body layer. A resin molded body capable of expressing the properties can be obtained.

  Further, in the method for producing a resin molded body according to the present invention, a printed painting layer is provided on the back surface of the film, and a resin is formed from the printed painting layer side on the printed film having a resin molded body layer provided on the surface of the film. By molding the base material, it is possible to adopt a mode in which the thickness of the printed film in the region where the resin molded body layer is provided is different from the thickness of the printed film in the region where the resin molded body layer is not provided. Thereby, it is possible to partially form a printed painting layer having a different distance from the surface, and at the same time, it is possible to embed the resin molding layer in a flexible film during molding.

Hereinafter, the manufacturing method of the resin molding of this invention is demonstrated about the case where an ultraviolet curable resin is used for resin. Prior to the description, a method for producing a printed film, which is a premise of the method for producing a resin molded body of the present invention, will be described.
(Printing film manufacturing method)
FIG. 3 is a diagram showing a screen printing apparatus having two ultraviolet irradiators, and is used for producing a printing film. In the figure, reference numeral 10 denotes a film delivery unit, 11 denotes a screen printing unit, 12 denotes a first ultraviolet irradiation unit, 13 denotes a second ultraviolet irradiation unit, and 14 denotes a film winding unit.

  Here, the film delivery unit 10 includes a roll core 10a and a support column 10b, and one end of a film 15 is wound around the roll core 10a. The other end of the film 15 extends to the film winding unit 14 via the screen printing unit 11, the first ultraviolet irradiation unit 12, and the second ultraviolet irradiation unit 13.

  The screen printing unit 11 includes a printing machine 11a and struts 11b and 11c that print two types of ultraviolet curable resins 16 and 17 having different compositions on the surface of the film 15 to form a resin molded body layer 18 and a spacer layer 19. I have. Further, the first ultraviolet irradiation unit 12 irradiates the surfaces of the resin molded body layer 18 and the spacer layer 19 with ultraviolet rays having a first wavelength (hereinafter referred to as “short wavelength”), and thereby the surface portion of the resin molded body layer 18. The second ultraviolet irradiation unit 13 includes the entire resin molded body layer 18 and the spacer layer 19 at the second wavelength (hereinafter referred to as “long wavelength”). A long wavelength irradiator 13a that is cured by irradiation with ultraviolet rays. The film winding unit 14 includes a roll core 14a, and the other end of the film 15 is wound around the roll core 14a. In addition, between the film delivery unit 10 and the screen printing unit 11, and between the screen printing unit 11 and the first ultraviolet irradiation unit 12, that is, between the column 10b and the column 11b, and between the column 11c and the column 12b. The slack portions 15a and 15b of the film 15 are formed between the two. This is for absorbing the moving speed of the film 15 in each of the parts 10, 11, and 12 because they are different.

  The manufacturing method of the printing film used as the premise of this invention can be implemented using an apparatus as shown above. First, the film 15 is transferred from the film delivery section 10 to the film winding section 14 via the screen printing section 11, the first ultraviolet irradiation section 12 and the second ultraviolet irradiation section 13 (bold arrow in FIG. 3). When moving, first, two kinds of ultraviolet curable resins 16 and 17 having different compositions are printed on the surface of the film 15 to form a resin molded body layer 18 and a spacer layer 19. At this time, the resin molded body layer 18 is in a normal printing form, and the spacer layer 19 is in a dot-like printing form. Then, the surface of the resin molded body layer 18 and the spacer layer 19 is irradiated with short wavelength ultraviolet rays to cure only the surface portion of the resin molded body layer 18 to form a wavy pattern, and then the resin molded body layer 18 and the spacer The entire layer 19 is cured by long-wave ultraviolet irradiation. Finally, the film 15 having the resin molded body layer 18 and the spacer layer 19 is wound and stored in the film winding portion 14.

  According to the method for producing a printed film using the apparatus as shown in FIG. 3, since the resin molded body layer 18 and the spacer layer 19 are formed in different regions on one side of the film, the subsequent film winding step When the film 15 is wound around the roll core 14a, no gap is generated between the films 15. For this reason, orderly winding of the film 15 can be facilitated, and a winding operation that does not require skill can be realized. Moreover, the printing cost of a printing film can be prevented from increasing by printing the spacer resin 17 in a dot shape. Furthermore, before the entire resin molded body layer 18 and the spacer layer 19 are cured, only the surface portion of the resin molded body layer 18 can be cured to give a desired shape to the surface portion of the resin molded body layer 18. Thus, it is possible to obtain a printing film suitable for a resin molded body that can express a high degree of design.

  FIG. 4 is a plan view showing an example of the printing film 20 obtained by the manufacturing method as described above. Reference numeral 21 in the figure denotes an ultraviolet curable resin layer corresponding to the resin molded body layer 18 in FIG. 3, and reference numeral 22 denotes an ultraviolet curable resin layer corresponding to the spacer layer 19 in FIG. As described above, the ultraviolet curable resin layer 22 formed in a dot shape is formed only for the purpose of simplifying the winding operation of the printing film. Prior to integration with the resin substrate, the film is removed together with a part of the film, for example, by press cutting.

(Production method of resin molding)
"Process for forming printed painting layer"
As the film, for example, a thermoplastic film can be used. Specifically, the film is not particularly limited as long as it is a transparent and printable film. In particular, acrylic, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyvinylidene fluoride (PVDF), and polystyrene (PS). Polycarbonate (PC), polypropylene (PP), polyethylene (PE) and the like are preferable.

  There is no limitation in particular as a printing painting layer, A pattern, a pattern, a character, etc. can be printed. Moreover, as a base color such as a pattern of a printed painting layer, one having a high luminance color tone using an aluminum pigment or the like is preferable, and an excellent contrast can be obtained.

  As a method for forming the printed painting layer, known techniques such as gravure printing, offset printing, and screen printing can be used, and as a result, printed painting is applied to the back surface of the film 31 as shown in FIG. Layer 32 is formed by printing.

"Formation process of UV curable resin layer"
As the ultraviolet curable resin, generally known resins such as formaldehyde resin, amino resin, phenol resin, epoxy resin, polyurethane resin, urea resin, melamine resin, alkyd resin, unsaturated polyester, acrylic resin, and the like can be used. . These ultraviolet curable resins can generally print a desired pattern on the surface of a thermoplastic film by screen printing, gravure printing, etc., and then the ultraviolet curable resin layer is appropriately cured with ultraviolet rays. To produce a printed film. In the present invention, as shown in FIG. 5 (b), the resin molding body layer 33 and the spacer layer 34 are formed by printing two types of resins having different compositions on the film 31 as shown in FIG. 5B. After only the surface portion of 33 is once cured, the entire resin molding layer 33 and the spacer layer 34 are cured to obtain the printing film 40. Then, the printing film 40 is wound up and temporarily stored. In addition, the printing film 40 shown in FIG.5 (b) is corresponded to the area | region shown with the virtual line V of the printing film 20 of FIG. Thereafter, as shown in FIGS. 5B and 5C, the spacer layer 34 is removed from the printed film 40 together with a part of the film 31 and a part of the printed painting layer 32 that are in contact with each other by press cutting. A printing film 50 suitable for integration with a resin substrate is obtained.

  In the resin molded body of the present invention, it is preferable to make the surface of the resin molded body layer 33 a matte state in order to improve the design and aesthetics. As a method for forming this matte state, when an ultraviolet curable resin is used, for example, a fine wrinkle is formed on the surface of the resin molded body layer 33 by using a method disclosed in Japanese Patent Application Laid-Open No. 9-53024. A matte state can be formed. This matting method is preferable because any area can be matted without depending on the mold.

  Furthermore, since the resin molded body layer 33 in the present invention is configured to be buried in the film, there is an advantage that the resin molded body layer 33 is hardly peeled regardless of the shape. In order to further improve the durability of the resin molded body layer 33, as shown in FIGS. 5B to 5E, the area of the contact surface of the resin molded body layer 33 with the film 31 is larger than the area of the printing surface. It is preferable to make the shape larger. Even if the resin molded body layer 33 has such a shape, according to the manufacturing method of the present invention, the film 31 has flexibility due to heating in the resin substrate forming step described later, and the resin is contained in the film 31. The molded body layer 33 can be completely buried.

“Process of forming a resin base material and bonding and integrating a printed film”
Resin base materials include acrylonitrile-butadiene-styrene copolymer (ABS), polycarbonate (PC), polypropylene (PP), polyphenyl ether (PPE), polystyrene (PS), polyvinyl chloride (PVC), polyethylene terephthalate (PET) and polybutylene terephthalate (PBT) can be used singly or in combination.

  As a molding method of the resin base material in the present invention, vacuum molding, pressure molding, simultaneous injection molding in an injection mold, simultaneous extrusion molding, and the like can be used. Among these, in the present invention, a resin base material molding method by simultaneous decorating in an injection mold is particularly suitable.

  Moreover, in the adhesion integration process of this invention, the resin molding of this invention can be suitably manufactured by heating a printing film previously and softening a film. The heating time and heating temperature of the printing film vary depending on the thermoplastic resin, but when a general thermoplastic resin is used, it is preferably in the range of 150 to 550 ° C. and 1 to 60 seconds.

  In the bonding and integration method of the present invention, first, as shown in FIG. 5 (d), the printing surface of the resin molded body layer 33 on the printing film 50 heated in advance is brought into close contact with the inner wall of the mold 35. Subsequently, the resin base material 36 is shape | molded by said shaping | molding method from the printing painting layer 32 side of the printing film 50. FIG. By the pressure at the time of molding of the resin base material 36, the entire printing film 50 is pressed against the mold 35, and the resin molded body layer 33 is completely formed in the flexible film 31 by the heat at the time of preheating and molding. At the same time, a printed painting layer 32 which is partially different in distance from the surface is formed as shown in FIG.

  As shown in FIG. 5 (e), the shape of such a painting layer 32 is thinner in the region where the resin molding layer 33 is not provided than in the region where the resin film layer 33 is provided. Therefore, when the printing film 50 is pressed against the mold 35, the region not provided with the printed painting layer 32 in the region where the resin molded body layer 33 is provided is brought closer to the die 35, and the resin This is formed because a partial level difference due to the presence or absence of the molded body layer 33 occurs in the printed painting layer 32. Thereby, the resin molding 60 of this invention provided with the resin base material 36 and the printing film 50 integrated on this is obtained.

Hereinafter, the present invention will be described specifically by way of examples. Here, even when the film can be wound up in an orderly manner and the winding operation can be easily performed without requiring skill, a resin molded body having a three-dimensional effect and having a high design property is obtained. It was verified whether or not.
<Invention Example 1>
First, a metallic printed painting layer using an aluminum pigment was formed on the back surface of an acrylic film (thermoplastic film) by gravure printing. Next, 666 parts of isophorone diisocyanate, 440 parts of tetrahydrofurfuryl acrylate, and 300 parts of polyethylene glycol diacrylate are mixed, and further stirred at 70 ° C. while adding 1200 parts of a ring-opening reaction product of trimethylolpropane and epsilon caprolactone. After confirming that the isocyanate groups were reduced, 350 parts of 2-hydroxyethyl acrylate was added and reacted at 70 ° C. to completely eliminate the isocyanate groups, thereby synthesizing urethane acrylate. Next, a blend of 97: 3 parts by weight of this urethane acrylate and 2-hydroxy-2-methyl-1-phenylpropan-1-one (resin A) is screened on one area of one side of the acrylic film. In addition to printing, a mixture of urethane acrylate and 2-hydroxy-2-methyl-1-phenylpropan-1-one (resin B) is screen-printed in dots on the other area of one side of the acrylic film. Two types of ultraviolet curable resin layers (resin molded body layer and spacer layer) were formed.

  Thereafter, the surfaces of the resin molded body layer and the spacer layer are first irradiated with ultraviolet rays having a wavelength of 254 nm to cure only the surface portion of the resin molded body layer, and 3 seconds later, the resin molded body layer and the spacer layer purple are entirely formed. Ultraviolet rays having a wavelength of 350 nm were irradiated. Specifically, the moving speed of the film in the first ultraviolet irradiation section and the second ultraviolet irradiation section is 10 m / min, and the distance between the first ultraviolet irradiation point and the second ultraviolet irradiation point of the film is 85 cm. It was. After producing a printing film as described above, the printing film was wound up and temporarily stored.

Next, the spacer layer made of resin B was removed by press cutting together with a part of the film and the like with which it was in contact. Thereafter, a printing film in which the acrylic film is softened by heating to 360 to 390 ° C. for about 10 seconds is vacuum-formed so that the printed surface of the resin molded body layer is pressure-bonded to the mold, and then printed on the printing film. An acrylonitrile-butadiene-styrene copolymer was injection molded from the layer side to obtain a resin molded body of the present invention. At this time, the cylinder temperature was 240 degrees, the injection pressure was 1800 kg / cm ² , the holding pressure was 1400 kg / cm ² (2 seconds), and 1000 kg / cm ² (2 seconds).

  FIG. 6 is a part of the produced resin molding of the present invention. That is, it corresponds to a region indicated by a virtual line VI of the printed film 20 in FIG. The area where the resin molded body layer is provided is visible in the back, and the area where the resin molded body layer is not provided is visible in the foreground. However, since the resin molded body layer surface and the thermoplastic film surface located on the outermost surface of the resin molded body are substantially flat, a surface having an excellent hand feeling without unevenness is formed. That is, the resin molded body of the present invention expresses a high degree of design such as a three-dimensional feeling (depth feeling).

<Comparative example 1> (original injection)
The resin for the resin base material was directly injection molded to produce a resin molded body of Comparative Example 1.
<Comparative example 2> (Color mix injection)
Resin for resin base material mixed with paint was injection molded to produce a resin molded body of Comparative Example 2.
<Comparative example 3> (Injection + painting)
The resin molded body of Comparative Example 1 was coated to produce the resin molded body of Comparative Example 3.

<Comparative example 4> (Injection + water transfer film)
A water-soluble film on which a desired pattern is printed is immersed in a container containing water, and the film is melted. When the ink floats on the water surface, the resin molded body of Comparative Example 1 previously submerged in water is lifted. Ink was adhered to the surface of the molded body to produce a resin molded body of Comparative Example 4.

<Comparative Example 5> (Injection molding and printing film simultaneous pasting (current printing film))
The resin film of Comparative Example 5 was manufactured by performing injection molding using a mold in which the print film was previously pressure-bonded to the inner side, thereby attaching the print film simultaneously with the injection molding.

The following evaluation was performed using the resin moldings of Invention Example 1 and Comparative Examples 1 to 5, and the results are shown in Table 1.
1. Color Pattern Pattern It was evaluated whether a desired pattern and pattern can be easily expressed on a resin molded body.
○: Using printing film.
(Triangle | delta): Coloring directly to a resin molding without using a film.
X: The thing which cannot express a picture at all.

2. Three-dimensional effect It was evaluated whether or not the color pattern drawn on the resin molded body was three-dimensionally visible.
○: It looked three-dimensional.
X: It was not visible in three dimensions.

  The resin molded product of Invention Example 1 exhibited excellent characteristics in both the color pattern and the three-dimensional effect. On the other hand, at least one item was inferior in the comparative example of the prior art. As will be described in detail, as for the color pattern, Comparative Examples 4 and 5 use the printing film as in Invention Example 1, and thus can easily create a complicated pattern or the like industrially. Although 3 can draw a pattern, it takes much time and is not industrially suitable. In Comparative Example 2, a pattern such as a marble pattern can be created by mixing the paint, but a certain pattern cannot be created. In Comparative Example 1, the color of the resin itself is obtained. Expression is impossible. Further, regarding the three-dimensional effect, there was no one having a high design property such that the color pattern looked three-dimensional in the comparative example.

  As described above, according to the present invention, the resin molded body obtained by using the printed film obtained by the predetermined manufacturing method has a three-dimensional effect and is verified to have high design properties. It was done. Therefore, the present invention is promising in that a suitable resin molded body can be produced. For example, vehicles, ships, aircraft interior / exterior panels, building materials, home appliances, furniture, wallpaper, Buddhist altars, Buddhist wares, nameplates, containers It can be applied to the production of resin moldings such as clothing, shoes, bags, telephone cards, credit cards, and IC cards.

It is a figure which shows an example of the hardening aspect of a resin layer regarding the manufacturing method of a printing film used as the premise which implements the manufacturing method of the resin molding of this invention. It is a figure which shows the other example of the hardening aspect of a resin layer regarding the manufacturing method of a printing film used as the premise which implements the manufacturing method of the resin molding of this invention. It is a figure which shows the screen printing apparatus which has two units | sets of ultraviolet irradiation devices used for manufacture of a printing film. It is a figure which shows one Embodiment of a printing film. It is a figure which shows each process of the manufacturing method of the resin molding of this invention. It is a photograph which shows a part of one Embodiment of the resin molding of this invention.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 31 ... Film, 32 ... Print painting layer, 33 ... Resin molding body layer, 34 ... Spacer layer, 35 ... Mold, 36 ... Resin base material, 40 ... Printing film, 50 ... Printing film, 60 ... Resin molding

Claims (2)

A predetermined resin is screen-printed on the surface of the film and printed on the back surface of the film to form a printed painting layer, and on the surface of the film on which the resin molded body is printed and on which the spacer molded body is printed. A step of molding a plurality of types of resin layers, a step of curing the resin layer, a step of removing a resin layer made of a resin used in a region for printing the spacer molded body together with the film, and the resin layer The printed painting layer is buried in the film and has a difference in distance from the surface between a region corresponding to the region where the resin layer of the printed painting layer is provided and another region. to possess a step of integrally molding a resin base material, curing the resin layer, hard only the surface portion of the resin layer made of a resin to be used in the area of printing the resin molded body Is allowed, then the production method of the resin molded body characterized by curing the whole of the resin layer made of a resin to be used in the area for printing the resin molded body and resin layer made of a resin to be used in the area of printing a spacer moldings .    The method for producing a resin molded body according to claim 1, wherein the resin used in a region where the spacer molded body is printed is printed in a dot shape.

Images