JP4274964B2 - Oily solid cosmetics - Google Patents

Description

  The present invention relates to an oil-based solid cosmetic, and more specifically, it is excellent in feeling of use such as “nobi”, “smoothness”, “non-stickiness”, etc. when applied with cosmetics, and also has excellent drop strength and storage stability. The present invention relates to an excellent oil-based solid cosmetic.

  Cosmetics such as foundations, eye shadows, and lipsticks are mainly composed of oils, surfactants, and powders, and have various shapes and properties in order to obtain comfortable use and a feeling of use as cosmetics. Studies have been made on the composition of the ingredients it has. In addition to these components, the blending of specific components has been studied in order to directly cast into sticks, metal plates, resin plates, pallets, etc. as desired, and to mold into desired shapes.

  In order to improve the strength of lipsticks and other sticky cosmetics, there are methods such as blending a large amount of high melting point wax or solidifying by adding an oil gelling agent such as sucrose fatty acid ester or organically modified clay mineral. It has been adopted so far (see, for example, Patent Documents 1, 2, 3, and 4). Further, in solid powder cosmetics such as powder foundations, methods such as blending a viscous viscous oil or solid oil as a binder between powders have been used (see, for example, Patent Document 5). ). Patent Document 5 discloses a solid powder cosmetic containing a cross-linked organopolysiloxane, a paste, and a solid oil.

  However, although the above-described conventional techniques improve the strength for molding, on the other hand, there are cases where a problem in use feeling occurs depending on the combination amount and the combination with other components. For example, when a large amount of high melting point wax is added to form a stick shape, the strength is improved, but the elongation is poor and smoothness is lost, and when solidified by the addition of a gelling agent, liquid oil becomes sticky and feels good. There is a drawback that the oil becomes worse or the liquid oil comes out on the surface with time. Furthermore, when fuming silicic anhydride or a plate-like powder having a large oil absorption amount is blended in order to eliminate this stickiness, the appearance is impaired, the system becomes brittle, the strength is lowered, and the usability is inferior. Moreover, although the method of solving the said fault is proposed by containing a whisker-like calcium carbonate powder (for example, refer patent document 6), the effect which can fully be satisfied was not acquired.

  In addition, in the dish shape, although the molding strength is maintained to some extent by the blending of the above-described oil agent, the usability may become heavy, or the system may be tightened over time and the usability may deteriorate. Therefore, it has been desired to develop an oily solid cosmetic material having good strength and shape retaining property without impairing usability and usability.

Japanese Patent Laid-Open No. 63-230618 JP-A-3-63206 JP 7-118121 A JP-A-8-59428 JP 2000-281532 A Japanese Patent Laid-Open No. 9-295914

  The present invention has been made in view of the above circumstances, and its purpose is excellent in feeling of use such as “nobi”, “smoothness”, “no stickiness”, etc. when applying cosmetics, drop strength, storage stability An object of the present invention is to provide an oil-based solid cosmetic which is excellent in properties.

  As a result of intensive studies to solve the above problems, the present inventor has solved the above problems by blending a basic magnesium carbonate powder having a specific shape as a powder component with an oily solid cosmetic containing solid oil. As a result, the present invention has been completed.

  That is, the present invention is an oily solid cosmetic comprising columnar or tubular basic magnesium carbonate and a solid oil component.

In the present invention, solid, solid, and liquid represent states at normal temperature. In addition, the specific surface area is the specific surface area according to the BET method.
model-1201). The pore distribution is CE
Measurement was performed with a mercury intrusion porosimeter manufactured by Instruments (series 140 type, 440 type).

  According to the present invention, it is possible to obtain an oil-based solid cosmetic that is excellent in feeling of use such as “nobi”, “smoothness”, “no stickiness”, etc. when applied with cosmetics, and excellent in drop strength and storage stability. It is done.

  Hereinafter, the best mode for carrying out the present invention will be described in detail.

  The columnar or tubular basic magnesium carbonate used in the present invention is a columnar or tubular basic magnesium carbonate composed of aggregated particles of flaky fine crystals of basic magnesium carbonate, and the flaky fine crystals forming the aggregated particles are , Having a thickness of 0.005 to 0.5 μm and a diameter of 0.1 to 10 μm are preferable, and the crystals are aggregated into a card house structure to form a columnar or tubular shape.

  The columnar or tubular aggregated particles of basic magnesium carbonate are not aggregated particles in which flaky microcrystals are easily dispersed by simple stirring, environmental changes such as temperature and pH.

The columnar or tubular basic magnesium carbonate in the present invention has an outer diameter of 1 to 20 μm, a length of 5 to 200 μm, and a length / outer diameter ratio of 2 to 50, preferably 4 to 50, or It is preferable that the specific surface area by BET method is 40-200 m < ² > / g. It is preferable that only one of these shapes and specific surface areas is within the above range, and it is more preferable that both are within the above range. By these, the effect of this invention is expressed more effectively.

  In the present invention, columnar basic magnesium carbonate and tubular basic magnesium carbonate may be used in combination. In the present invention, the shape is preferably tubular. By being tubular, the effects of the present invention can be sufficiently exerted. The tubular basic magnesium carbonate can exhibit a particularly excellent effect by having a shape having an inner diameter of 0.5 to 5 μm and an inner diameter / outer diameter ratio of 0.1 to 0.95.

Whether the tubular basic magnesium carbonate suitably used in the present invention has a specific surface area by the BET method of 70 to 200 m ² / g, preferably 85 to ²⁰⁰ m ² / g, more preferably 90 to ²⁰⁰ m ² / g. Alternatively, in the pore distribution measured by mercury porosimetry, the pore volume (A) having a pore diameter of 0.01 to 100 μm is 5000 to 12000 mm ³ / g, and the pore diameter is 0.5 to 5 μm. It is preferable that B / A, which is a ratio to the volume (B), is 0.45 to 0.85, and it is more preferable that both of these are in the above range, thereby forming the tubular shape. The derived properties are more effectively expressed.

  The columnar or tubular basic magnesium carbonate of the present invention can be obtained, for example, by the method described in JP-A-2003-306325. That is, a first step of mixing a water-soluble magnesium salt and a water-soluble carbonate in an aqueous solution to produce columnar particles of normal magnesium carbonate at a temperature of 20 to 60 ° C., and The suspension can be produced by a second step of heat treatment at a temperature higher than the temperature at which normal magnesium carbonate was produced in the first step and at a temperature of 35 to 80 ° C.

  As the columnar or tubular basic magnesium carbonate in the present invention, those whose surface is modified to be hydrophobic by a hydrophobic treatment can be used. The method of hydrophobizing treatment is not particularly limited. For example, coating baking using methyl hydrogen polysiloxane, metal soap, fatty acid dextrin, trimethylsiloxysilicic acid, dimethyl polysiloxane, methylphenyl polysiloxane And a coating treatment with a polymer having a fluorine group.

  The content of the columnar or tubular basic magnesium carbonate is preferably 1 to 45% by mass in the total amount of the oily solid cosmetic. If it uses in this range, the elongation at the time of cosmetics use is favorable, and the oil-based solid cosmetics with more excellent drop strength can be obtained. A more preferable content is 5 to 30% by mass in the total amount of the oily solid cosmetic.

  In the present invention, powders other than the essential component columnar or tubular basic magnesium carbonate can be blended within a range not impairing the effects of the present invention. Other powders include, for example, mica, talc, kaolin, sericite, synthetic mica, calcium carbonate, anhydrous silicic acid (silica), aluminum oxide, barium sulfate, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine , Bitumen, titanium oxide, zinc oxide, titanium mica, boron nitride, calcium silicate, aluminum powder, fish phosphorus foil, bismuth oxychloride, red 228, red 226, blue 404, yellow 4, orange 204, Blue No. 1, Green No. 3,

  Polyamide spherical resin powder (nylon spherical powder), spherical polyethylene powder, polymethyl methacrylate spherical powder, cross-linked poly (meth) methyl methacrylate spherical resin powder, spherical polyester powder, cross-linked polystyrene spherical resin powder, co-polymerization of styrene and acrylic acid Polymer spherical resin powder, benzoguanamine spherical resin powder, polytetrafluoroethylene spherical powder, spherical cellulose, spherical styrene resin powder, spherical polymethylsilsesquioxane powder, spherical organopolysiloxane elastomer powder, spherical urethane powder, siloxane bond From polymethylsilsesquioxane spherical powder, silicone rubber spherical powder, and heterogeneous organopolysiloxane having a three-dimensionally stretched network structure and an inorganic and organic intermediate structure in which a methyl group is bonded to one silicon atom. Spherical composite powder, sphere Examples include silica, spherical alumina, spherical titanium oxide, spherical magnesium carbonate, spherical magnesium silicate, spherical calcium silicate, and spherical anhydrous silicic acid.

  One or two or more kinds of these arbitrarily blended powders can be arbitrarily selected and blended.

  In addition, these optional powders may have a hydrophilic surface or a hydrophobic surface. For example, when the surface is hydrophilic, the surface can be used as it is, or the surface can be made hydrophobic by a hydrophobic treatment. The method of hydrophobizing treatment is not particularly limited. For example, coating baking using methyl hydrogen polysiloxane, metal soap, fatty acid dextrin, trimethylsiloxysilicic acid, dimethyl polysiloxane, methylphenyl polysiloxane And a coating treatment with a polymer having a fluorine group.

  The solid oil used in the present invention is not particularly limited as long as it is a solid oil that can be blended in cosmetics. Examples of solid oils include, for example, hardened oil, owl, cocoa butter, hardened castor oil, partially hydrogenated sesame oil, partially hydrogenated beef tallow, partially hydrogenated palm oil and the like; solid paraffin, ceresin, microcrystalline Solid hydrocarbons such as wax and polyethylene wax; solid waxes (esters) such as beeswax, lanolin, gay wax, candelilla wax, carnauba wax, ibota wax, partially hydrogenated jojoba oil, rice bran wax; stearic acid, palmitic acid, myristic acid, 12 -Solid higher fatty acids such as hydroxystearic acid and behenic acid; solid higher alcohols such as cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, and lanolin fatty acid; myristyl myristate, cetyl palmitate, trimyristate group Solid esters such as seryl; silicone waxes such as alkyl modified polysiloxane wax. One or more solid oil components are selected and blended.

  The content of the solid oil is preferably 2 to 40% by mass in the total amount of the oily solid cosmetic. A more preferable content is 5 to 20% by mass in the total amount of the oily solid cosmetic.

  In the present invention, a liquid oil component may be contained. Liquid oils include, for example, olive oil, castor oil, macadamia nut oil, liquid oils such as evening primrose oil, avocado oil, liquid waxes (esters) such as jojoba oil, liquid lanolin, liquid paraffin, squalane, polybutene, light liquid isoparaffin, Liquid hydrocarbons such as α-olefin oligomers, liquid fatty acid monoesters such as isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, octyldodecyl myristate, octyl stearate, octyl palmitate, diisopropyl adipate, sebacic acid Liquid dibasic acid diesters such as di-2-ethylhexyl, liquid glycol esters such as neopentyl glycol dicaprate, liquid glycerides such as glyceryl tri-2-ethylhexanoate and glyceryl triisostearate Esters, liquid polyglycerol esters such as diglyceryl diisostearate and diglyceryl triisostearate, liquid pentaerythritol esters such as tetra-2-ethylhexanoic acid pentaerythritol and dioctanoic acid pentaerythritol, trimethylol tri-2-ethylhexanoate Propane, liquid trimethylolpropane ester such as triisostearic acid trimethylolpropane, liquid esters such as liquid malic acid ester such as diisostearyl malate, liquid higher fatty acids such as isostearic acid, oleic acid, linoleic acid, linolenic acid, Liquid higher alcohols such as isostearyl alcohol, oleyl alcohol and octyldodecanol, liquid chain polysiloxanes such as dimethylpolysiloxane and methylphenylpolysiloxane, octame Liquid silicone oils such as liquid cyclic silicones such as tilcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, amino-modified polysiloxanes, alkyl-modified polysiloxanes, fluorine-modified polysiloxanes, etc., perfluoro Examples thereof include liquid fluorine compounds such as polyether. One or more liquid oil components are selected and blended.

  In the oily solid cosmetic of the present invention, in addition to the above-mentioned components, other components that are usually used in cosmetics, quasi drugs, pharmaceuticals, and the like can be appropriately blended as long as the effects of the present invention are not impaired. Examples of the optional ingredients include surfactants, humectants, polyhydric alcohols, water-insoluble polymers, oil gelling agents, lower alcohols, ultraviolet absorbers, sequestering agents, antioxidants, preservatives, A fragrance | flavor, water, etc. can be mentioned.

  Examples of the oily solid cosmetic of the present invention include foundation, white powder, blusher, lipstick, eye shadow, eyebrow, concealer, sunscreen cosmetic, and the like. It is.

  Hereinafter, the present invention will be specifically described with reference to examples. A compounding quantity is the mass%. Prior to the description of the examples, the preparation of columnar or tubular basic magnesium carbonate used in the present invention and the effect test method will be described.

[Preparation of columnar or tubular basic magnesium carbonate]

[Production Example 1]
0.50 L of anhydrous sodium carbonate aqueous solution (220 g / L) was gradually added to 2.0 L of magnesium sulfate heptahydrate aqueous solution (125 g / L) adjusted to 40 ° C. while maintaining the temperature at 40 ° C., and stirred for 50 minutes. Thus, normal magnesium carbonate was obtained (first step). When this normal magnesium carbonate was observed with an SEM, it was confirmed to be columnar particles having a diameter of 1 to 3 μm and a length of 10 to 50 μm. Subsequently, the suspension of regular magnesium carbonate columnar particles (pH 10.2) obtained in the first step is heated and stirred for 120 minutes while maintaining the temperature at 55 ° C. to produce basic magnesium carbonate. (Second step). The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.04 μm and a diameter of 0.5 to 2 μm were obtained. It was confirmed that the aggregated particles were tubular basic magnesium carbonate having an outer diameter of 1 to 5 μm, an inner diameter of 0.5 to 3 μm, and a length of 5 to 20 μm.

[Production Example 2]
0.50 L of sodium carbonate aqueous solution (210 g / L) was gradually added to 2.0 L of magnesium chloride hexahydrate aqueous solution (105 g / L) adjusted to 35 ° C. while maintaining the temperature at 35 ° C., and stirred for 30 minutes. To obtain normal magnesium carbonate (first step). When this normal magnesium carbonate was observed with an SEM, it was confirmed to be columnar particles having a diameter of 1 to 3 μm and a length of 10 to 60 μm. Subsequently, the suspension of columnar particles of normal magnesium carbonate (pH 9.6) obtained in the first step is heated and stirred for 180 minutes while maintaining the temperature at 50 ° C. to produce basic magnesium carbonate. (Second step). The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.05 μm and a diameter of 0.5 to 3 μm were obtained. Agglomerated particles with an outer diameter of 2 to 3 μm, an inner diameter of 1 to 1.5 μm, a tubular basic magnesium carbonate with a length of 10 to 20 μm, a thickness of 0.01 to 0.05 μm, and a diameter of 0 It was confirmed to be a mixture of columnar basic magnesium carbonate having a diameter of 1 to 3 μm and a length of 10 to 20 μm.

[Production Example 3]
The magnesium sulfate-containing solution generated in the flue gas desulfurization process by the magnesium hydroxide method was filtered to remove solids, and then an appropriate amount of ion-exchanged water was added to prepare 2.0 L of a 50 g / L magnesium sulfate solution. After adjusting this magnesium sulfate solution to 50 ° C., 0.50 L of an aqueous sodium carbonate solution (210 g / L) was gradually added while maintaining the same temperature and stirred for 20 minutes to obtain normal magnesium carbonate (first step). ). When this normal magnesium carbonate was observed with an SEM, it was confirmed to be columnar particles having a diameter of 1 to 3 μm and a length of 10 to 60 μm. This normal magnesium carbonate suspension was filtered, and the solid content was washed with ion-exchanged water, and then again dispersed in 2.0 L of ion-exchanged water to remove impurities such as sodium sulfate. A suspension was prepared. Subsequently, an appropriate amount of aqueous sodium hydroxide solution was added to the suspension of columnar particles of magnesium carbonate obtained in the first step to adjust the pH to 10.6. Was maintained for 60 minutes while maintaining at 70 ° C. to produce basic magnesium carbonate (second step). The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.05 μm and a diameter of 0.5 to 3 μm were obtained. It was confirmed that the aggregated particles were tubular basic magnesium carbonate having an outer diameter of 2 to 3 μm, an inner diameter of 1 to 1.5 μm, and a length of 10 to 20 μm.

[Production Example 4]
0.50 L of anhydrous sodium carbonate aqueous solution (220 g / L) was gradually added to 2.0 L of magnesium sulfate heptahydrate aqueous solution (125 g / L) adjusted to 45 ° C. while maintaining the temperature at 45 ° C., and stirred for 30 minutes. Thus, normal magnesium carbonate was obtained (first step). When this normal magnesium carbonate was observed with an SEM, it was confirmed to be columnar particles having a diameter of 1 to 3 μm and a length of 10 to 50 μm. Subsequently, the suspension of regular magnesium carbonate columnar particles (pH 10.5) obtained in the first step is heated and stirred for 120 minutes while maintaining the temperature at 55 ° C. to produce basic magnesium carbonate. (Second step). The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.04 μm and a diameter of 0.5 to 2 μm were obtained. The agglomerated particles were confirmed to be tubular basic magnesium carbonate having an outer diameter of 2 to 4 μm, an inner diameter of 1 to 2 μm, and a length of 5 to 20 μm.

[Production Example 5]
0.50 L of anhydrous sodium carbonate aqueous solution (225 g / L) was gradually added to 2.0 L of magnesium sulfate heptahydrate aqueous solution (125 g / L) adjusted to 48 ° C. while maintaining the temperature at 48 ° C., followed by stirring for 30 minutes. Thus, normal magnesium carbonate was obtained (first step). When this normal magnesium carbonate was observed with an SEM, it was confirmed to be columnar particles having a diameter of 1 to 2 μm and a length of 10 to 50 μm. Subsequently, the suspension of regular magnesium carbonate columnar particles (pH 10.7) obtained in the first step is heated and stirred for 120 minutes while maintaining the temperature at 53 ° C. to produce basic magnesium carbonate. (Second step). The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.04 μm and a diameter of 0.5 to 2 μm were obtained. It was confirmed that the aggregated particles were tubular basic magnesium carbonate having an outer diameter of 1 to 3 μm, an inner diameter of 0.5 to 1.5 μm, and a length of 5 to 20 μm.

[Comparative Production Example 1]
0.50 L of anhydrous sodium carbonate aqueous solution (220 g / L) was gradually added to 2.0 L of magnesium sulfate heptahydrate aqueous solution (125 g / L) adjusted to 80 ° C. while maintaining the temperature at 80 ° C. While maintaining the temperature at 80 ° C., the mixture was stirred for 60 minutes to produce basic magnesium carbonate. The obtained product was washed with ion-exchanged water and ethanol, dried, and then observed with an SEM. As a result, flaky primary particles having a thickness of 0.01 to 0.05 μm and a diameter of 0.3 to 2 μm were obtained. It was confirmed that the agglomerated particles were irregular basic magnesium carbonate having a diameter of 2 to 4 μm. In Comparative Production Example 1, formation of normal magnesium carbonate could not be confirmed during the reaction process.

  Table 1 shows the physical property values of the basic magnesium carbonate obtained in Production Examples 1 to 5 and Comparative Production Example 1.

(Note 1) Pore volume with pore diameter of 0.01-100 μm (Note 2) Pore volume with pore diameter of 0.5-5 μm

1. Usage test Each test product is subjected to a usage test by a panel of 10 women. When applied, the evaluation items of “Nobi,” “Smoothness,” and “No stickiness” are based on the following evaluation criteria. And evaluated.

(Evaluation criteria)
0 ← 1 ← 2 → 3 → 4
0: Poor, 1: Slightly bad, 2: Not good at all, 3: Good, 4: Very good

Subsequently, the average score of the evaluation points given by each person was evaluated based on the following evaluation criteria.
(Evaluation criteria)
◎: 3.5 points or more ○: 2.0 points or more to less than 3.5 points △: 0.5 points or more to less than 2.0 points ×: Less than 0.5 points

2. Drop strength A sample filled in a normal oily solid cosmetic container was dropped from a height of 30 cm into an acrylic plate. Three cycles were performed with one cycle consisting of upright, inverted, and sideways falling.
<Evaluation criteria>
A: No break in 3 cycles.
○: It breaks in any one condition in the third cycle.
(Triangle | delta): It breaks in any one condition in the 2nd cycle. Or it breaks in two conditions in the third cycle.
X: It breaks in any one condition in the 1st cycle. Or it breaks in two conditions in the second cycle.

3. Storage stability A constant temperature bath held at 25 ° C., a constant temperature bath held at 50 ° C., a constant temperature bath held at 40 ° C. (humidity 85%), and after holding at −5 ° C. for 8 hours, Each of the thermostats in which the internal atmosphere changes in a cycle of holding for 4 hours at a humidity of 85%, then holding for 8 hours at 40 ° C. (85% humidity), and further holding for 4 hours at 20 ° C. (85% humidity). The cosmetics held for 1 month were evaluated for the presence or absence of changes in state according to the following criteria.

(Evaluation criteria)
○: No change was observed in the samples stored in any thermostat.
(Triangle | delta): The change was seen by any one of the samples preserve | saved at 25 degreeC, 40 degreeC, 50 degreeC, the thermostat of the cycle.
X: A change was observed in any two or more of the samples stored in a constant temperature bath of 25 ° C., 40 ° C., 50 ° C., cycle.

[Examples 1 to 12, Comparative Examples 1 to 5]
Oily solid cosmetics (feed-out type stick-shaped lipstick) having the components and blending amounts shown in Tables 2 to 4 (total amount of blending 100% by mass) were prepared by the following method. Among the basic magnesium carbonates used, (Note 1) is the tubular basic magnesium carbonate of Production Example 1, (Note 2) is the tubular / columnar basic magnesium carbonate of Production Example 2, and (Note 3) is the Production Example. (Note 4) is the tubular basic magnesium carbonate of Production Example 4, (Note 5) is the tubular basic magnesium carbonate of Production Example 5, and (Note 6) is the irregular shape of Comparative Production Example 1. Basic magnesium carbonate.

(Preparation method)
A: The oil component (oil component) was heated to 105 ° C. and then uniformly dissolved at 95 ° C.
B: Powder components and others were added to A and mixed and dispersed with a roll mill.
C: B was dissolved again, and mica titanium was added and mixed and dispersed with a disper.
D: B was filled into a container and then cooled to obtain a stick-shaped lipstick.

  The effect test was done about the feeding type stick-shaped lipstick of Examples 1 to 12 and Comparative Examples 1 to 5, and the evaluation results are shown in Tables 2 to 4.

  As can be seen from Tables 2 and 3, all of the pay-out type stick-shaped lipsticks of Examples 1 to 12 according to the present invention have excellent effects.

  On the other hand, as can be seen from Table 4, none of the payout-type stick-like lipsticks of Comparative Examples 1 to 5 that do not satisfy the configuration of the present invention can exhibit the effects of the present invention. .

  Hereinafter, examples of the oily solid cosmetic of the present invention will be shown. In addition, manufacture was performed according to the method of Examples 1-12. Moreover, when the said effect test was done in these, the outstanding result was obtained in all.

[Example 13] Compact foundation Component Compounding amount (% by mass)
Carnauba 0.5
Ceresin 4.0
Isotridecyl isononanoate 10.0
Dimethylpolysiloxane 6cs 10.0
Octyl palmitate 30.4
Tubular basic magnesium carbonate (Note 1) 5.0
Tubular basic magnesium carbonate (Note 2) 5.0
Tubular basic magnesium carbonate (Note 3) 5.0
Sericite 11.5
Nylon spherical powder 10.0
Bengala 0.8
Yellow iron oxide 2.5
Black iron oxide 0.2
Titanium oxide 5.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 1 (Note 2) Tubular basic magnesium carbonate of Production Example 3 (Note 3) Tubular basic magnesium carbonate of Production Example 4

[Example 14] Stick foundation component Amount (% by mass)
Ceresin 8.0
Polyethylene wax 1.0
Isotridecyl isononanoate 15.0
Dimethylpolysiloxane 6cs 10.0
Octyl palmitate 24.5
Tubular basic magnesium carbonate (Note 1) 5.0
Tubular basic magnesium carbonate (Note 2) 5.0
Sericite 18.3
Bengala 1.5
Yellow iron oxide 6.0
Black iron oxide 0.6
Titanium oxide 5.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 3 (Note 2) Tubular basic magnesium carbonate of Production Example 5

[Example 15] Stick eye shadow component Amount (% by mass)
Carnauba 1.0
Ceresin 8.0
Isotridecyl isononanoate 15.0
Glyceryl tri-2-ethylhexanoate 15.0
Octyl palmitate 25.9
Tubular basic magnesium carbonate (Note 1) 5.0
Tubular basic magnesium carbonate (Note 2) 5.0
Tubular basic magnesium carbonate (Note 3) 5.0
Polymethyl methacrylate spherical powder 4.0
Blue No. 1 aluminum lake 0.1
Yellow No. 4 aluminum rake 0.4
Titanium oxide 0.5
Mica titanium 15.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 3 (Note 2) Tubular basic magnesium carbonate of Production Example 4 (Note 3) Tubular basic magnesium carbonate of Production Example 5

[Example 16] Stick-shaped lipstick Ingredient amount (% by mass)
Ceresin 12.0
Polyethylene wax 2.0
Isotridecyl isononanoate 15.0
Diisostearyl malate 6.0
Methylphenylpolysiloxane 16.9
Decamethylcyclopentasiloxane 25.0
Tubular basic magnesium carbonate (Note 1) 5.0
Tubular basic magnesium carbonate (Note 2) 5.0
Red No. 202 2.2
Yellow No. 4 aluminum rake 0.5
Bengala 0.3
Titanium oxide 2.0
Mica titanium 8.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 1 (Note 2) Tubular basic magnesium carbonate of Production Example 5

[Example 17] Stick concealer Component Compounding amount (mass%)
Ceresin 8.0
Polyethylene wax 1.0
Isotridecyl isononanoate 10.0
Dimethylpolysiloxane 6cs 10.0
Octyl palmitate 30.9
Tubular basic magnesium carbonate (Note 1) 8.0
Tubular basic magnesium carbonate (Note 2) 2.0
Sericite 4.0
Bengala 0.8
Yellow iron oxide 3.0
Black iron oxide 0.2
Titanium oxide 22.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 3 (Note 2) Tubular basic magnesium carbonate of Production Example 4

[Example 18] Cartridge pencil eyeliner Component content (% by mass)
Ceresin 15.0
Polyethylene wax 5.0
Owl 5.0
Castor oil 20.0
Squalane 9.9
Tubular basic magnesium carbonate (Note 1) 10.0
Black iron oxide 35.0
Antioxidant 0.1
Total 100.0

(Note 1) Tubular basic magnesium carbonate of Production Example 2

Claims (1)

Oily solid cosmetic which is characterized by containing a 1 to 45 wt% the tube-like basic magnesium carbonate and solid oil component 2-40% by weight.