JP4266989B2 - Dry cell - Google Patents

Description

  The present invention relates to a dry battery, and more particularly to a dry battery with an expanded battery capacity.

  A conventional dry battery has a metal plate with a decorative layer (pattern, product name, manufacturer name, precautions, etc.) printed on the outer surface of the outer surface of the body of the dry battery body via an insulating material. Although it has a structure, in the case of a dry battery with such a structure, it is difficult to print on the metal plate, and the metal plate needs a certain thickness to perform printing, so the cost of the metal plate There was a problem of high.

  In order to solve such problems, in recent years, a dry battery having a structure in which a shrink film having a decorative layer on the outer surface or the inner surface is wound on the outer peripheral surface of the body of the dry battery body has been proposed. In the case of this dry battery, the decorative layer can be formed by printing on the film, so it has the advantage of being beautiful, and there is no need for an insulating material between the shrink film and the dry battery body, and the shrink film is thinner than the metal plate Since the outer diameter of the metal container of the dry battery main body can be enlarged using the battery, the battery capacity is increased and the battery life can be extended.

  Recently, electrical products powered by dry batteries, such as remote controls and portable music players used in TVs and VCRs, are rapidly spreading, and along with this, the battery life of dry batteries can be further extended. It is requested. To that end, it is necessary to expand the volume inside the metal container of the dry cell body in a range where the outer diameter of the dry cell does not exceed the standard value, but in the dry cell wound with the shrink film described above, as shown in FIG. Since the left and right end portions of the shrink film 102 overlap each other so that there is no gap, the outer diameter D ′ of the metal container 103 is smaller than the outer diameter D of the dry battery 101 of the shrink film 102 (thickness: about 70 to 100 μm). It must be reduced by three sheets, that is, by 210 to 300 μm or more, which is a great obstacle to increasing the volume of the metal container 103. Although the metal container 103 is formed by drawing to reduce the thickness of the metal container 103, it is difficult to make the metal container 103 thinner than this, and improvement of the above points is desired.

  In addition, since the dry cell used for the electric product mentioned above has many small-sized batteries, such as AA or AAA, the proportion of the thickness of the shrink film in the outer diameter increases as the outer diameter of the dry battery becomes smaller. The point becomes a bigger problem.

  This invention is made | formed in view of the situation mentioned above, The objective is to provide the dry battery which aimed at expansion of battery capacity.

  In order to achieve the above-described object, the present invention provides a dry battery in which a decorative layer is formed on the outer peripheral surface of a body portion of a dry cell body using a transfer sheet, and the decorative layer is a body portion of the dry cell body. A surface protective layer is formed as an outermost layer covering the decorative layer, and a release layer transferred from the transfer sheet together with the decorative layer is the surface protective layer. It is characterized by forming a layer.

  Further, the present invention is a dry battery in which a decorative layer is formed by transfer on the outer peripheral surface of the body portion of the dry cell main body and the peripheral edge portions of the upper and lower end surfaces of the dry cell main body using a transfer sheet, and the decorative layer is the dry cell main body. And a surface protective layer is formed as an outermost layer covering the decorative layer, on the outer peripheral surface of the body portion and on the peripheral edges of the upper and lower end surfaces of the dry cell body, The release layer transferred together with the decorative layer from the sheet forms the surface protective layer.

  According to the present invention, in the dry battery having the above-described configuration, the release layer is formed of polyester, urethane, or melamine.

  Further, in the dry battery having the above-described configuration, the present invention provides an outer peripheral surface of the body portion of the dry cell body, a plating layer formed on a surface of a thin metal plate that forms the body portion of the dry cell body, And a coating layer formed on the plating layer by a plastic resin.

  According to the present invention, the thickness of the portion formed on the outer peripheral surface of the body portion of the dry cell main body is greatly reduced compared to the conventional product, and the outer diameter of the dry cell main body can be enlarged accordingly, so the battery Capacity can be expanded. In addition, the transfer sheet is formed by laminating a release layer that forms a surface protective layer on the surface of the decorative layer after transfer, so that the transfer sheet further overlaps and is heated and pressed. Even if it becomes, since retransfer is prevented by the peeling layer located in the outermost layer, it is not necessary to perform transfer in accordance with the outer shape of the dry battery accurately. Therefore, the manufacturing is easy and the transfer speed can be increased. Moreover, the wear resistance of the decorative layer is improved by providing the surface protective layer covering the decorative layer on the outer peripheral surface of the body portion of the dry cell body.

  Further, according to the present invention, the appearance is improved by providing the decorative layer along the peripheral edge portions of the upper and lower end faces of the dry battery body.

  Further, according to the present invention, since the release layer is formed of polyester, urethane, or melamine, which is a transparent synthetic resin having good wear resistance and insulation, the wear resistance and insulation of the release layer are improved. improves. Moreover, it can prevent more reliably that a positive electrode and a negative electrode electrically contact and discharge.

  According to the present invention, even if a plating layer is applied for rust prevention on the surface of a thin metal plate that forms the body of a dry battery, etc., by forming a coating layer of thermosetting or thermoplastic resin, The decorative layer can be easily transferred onto the outer peripheral surface of the body portion of the dry cell body.

  Hereinafter, specific embodiments of the present invention will be described with reference to the drawings. 1 is a partially broken side view of a dry battery 1 according to an embodiment of the present invention, FIG. 2 is a plan view of the dry battery 1 of FIG. 1, FIG. 3 is a bottom view of the dry battery 1 of FIG. It is sectional drawing of the trunk | drum 4 and the upper end wall 5 of 1 metal container 3. FIG.

  The dry battery 1 of the present embodiment is an alkaline dry battery and includes a cylindrical dry battery body 2. The dry cell main body 2 has a metal container 3 formed by drawing a conductive metal thin plate, and the metal container 3 has a cylindrical body 4 and an upper end wall for sealing the upper end surface of the body 4. The positive terminal 6 is integrally formed on the upper end wall 5. The lower end portion of the body portion 4 is bent inward at a substantially right angle to form a bent portion 4a.

  The interior of the metal container 3 is partitioned by a separator 7 into a central negative electrode chamber 8 and an annular positive electrode chamber 9 formed around the center, and the lower end opening of the metal container 3 is sealed by a resin sealing body 10. Has been. The negative electrode chamber 8 is filled with a gelatinous material obtained by mixing zinc powder, which is a negative electrode active material, and an electrolytic solution and adding a gelling agent thereto. On the other hand, the positive electrode chamber 9 accommodates a molded body of manganese dioxide which is a positive electrode active material. This molded body is electrically connected to the negative electrode terminal 12 attached to the lower end portion of the container 3 via the current collecting rod 11.

  On the outer peripheral surface of the body portion 4 of the metal container 3, there are provided decorative layers 13 such as patterns, product names, manufacturing company names, precautions, etc., as shown in FIGS. Are provided with strip-like decorative layers 14 and 15 along the peripheral edge. Moreover, as shown in FIG. 4, the outer surface of the trunk | drum 4 and the upper end wall 5 of the metal container 3 consists of a transparent synthetic resin, and the surface protection layer 16 which covers the decoration layer 13 and the strip | belt-shaped decoration layers 14 and 15 is provided. Is provided. The surface protective layer 16 also serves as an insulating layer. The decoration layer 13, the belt-like decoration layers 14 and 15, and the surface protective layer 16 are simultaneously formed on the metal container 3 by transfer, as will be described later.

  Next, an embodiment of the production method of the present invention will be described. 5 is a cross-sectional view of the transfer sheet 17 used in the present embodiment, FIG. 6 is a schematic configuration diagram of the transfer device, and FIG. 7 is a view in the direction of arrow A in FIG.

  As shown in FIG. 5, the transfer sheet 17 is formed by sequentially laminating a release layer 19, a decorative layer 20 formed by printing, and a thermoadhesive resin layer 21 on one side of a belt-like base material sheet 18 made of PET or the like. Thus, as shown in FIG. 6, it is stretched between the pair of rollers 22, 23 so as to be freely extended in the length direction (arrow B direction).

  The peeling layer 19 peels off from the base material sheet 18 at the time of transfer and is transferred onto the dry battery body 2 together with the decorative layer 20 to become the surface protective layer 16 (see FIG. 4). Polyester, acrylic, urethane, melamine, etc. It is formed of a transparent synthetic resin having good wear resistance and insulation. The width of the transfer sheet 17 is slightly longer than the axial length of the body portion 4 of the dry cell body 2.

  The dry cell main body 2 is continuously transported to the thermal adhesive resin layer 21 side of the transfer sheet 17 by a transport mechanism (not shown), both ends are clamped by a clamp mechanism (not shown), and the central axis is parallel to the width direction of the transfer sheet 17. Further, the outer peripheral surface is disposed so as to be in contact with the heat-adhesive resin layer 21 of the transfer sheet 18. The clamp mechanism is connected to a rotation drive device (not shown), and when the rotation drive device is driven, the dry cell main body 2 rotates in the direction of arrow C around the central axis at the same speed as the transfer speed of the transfer sheet 17. It has become.

  On the base sheet 18 side of the transfer sheet 17, the pressing roller 24 is disposed so that the central axis thereof is parallel to the width direction of the transfer sheet 17 and faces the dry cell body 2 with the transfer sheet 17 interposed therebetween. . The pressing roller 24 is detachable from the transfer sheet 17 and is connected to a rotation driving device (not shown). When the rotation driving device is driven, the pressing roller 24 rotates in the direction of arrow D at substantially the same speed as the transfer speed of the transfer sheet 17. It is supposed to be. The pressing roller 24 is made of a material having flexibility such as rubber. As shown in FIG. 7, the axial length E is longer than the axial length F of the body portion 4 of the dry cell body 2, and the dry cell body 2. Is pressed along the outer surface of the dry battery body 2. As a result, both side end portions 17 a and 17 b of the transfer sheet 17 are bent substantially at right angles and come into contact with the peripheral edge portions of the upper and lower end surfaces of the dry battery body 2.

  Further, as shown in FIG. 6, a heat source 25 for heating the heat-adhesive resin layer 21 of the transfer sheet 17 fed from the roller 22 is disposed upstream of the dry cell main body 2 and the pressing roller 24.

  When the rollers 22 and 23 are rotated and the transfer sheet 17 is drawn out in the direction of arrow B, the heat-adhesive resin layer 21 of the transfer sheet 17 is heated and melted by the heat source 25. Then, the pressing roller 24 presses the transfer sheet 17 against the outer peripheral surface of the body portion 4 of the dry battery body 2 and the peripheral edge portions of the upper and lower end faces, and the pressing roller 24 and the dry battery body 2 rotate in the directions of arrows C and D, respectively. . As a result, the decorative layer 20 and the release layer 21 of the transfer sheet 17 are transferred to the outer peripheral surface of the body portion 4 and the peripheral edge portions of the upper and lower end surfaces of the dry cell body 2.

  When the transfer to one dry cell body 2 is completed, the rotation of the rollers 22 and 23 stops, and the clamping mechanism carries the dry cell body 2 after the transfer to the transport mechanism, and the dry cell body 2 is transported to the next process by the transport mechanism. Is done. Then, the clamp mechanism clamps the bare dry battery main body 2 that has not been transferred on the transport mechanism and sets it at the transfer position. And the process mentioned above is repeated to the dry cell main body 2, and transcription | transfer is performed.

  In order to ensure that both end portions of the transfer sheet 17 are in close contact with the peripheral portions of the upper and lower end surfaces of the dry cell body 2, as shown in FIG. 8, on both sides of the dry cell body 2, in the direction of the central axis of the dry cell body 2. Heating holders 26 and 26 that contact and separate are provided, both end portions of the transfer sheet 17 are bent inward by a jig (not shown), and both end portions of the transfer sheet 17 are pressed against both end surfaces of the dry cell body 2 by the heating holders 26 and 26. You may do it.

  Further, as shown in FIGS. 9 and 10, rollers 27 and 27 are provided on both sides of the dry cell main body 2 so that the central axis L is perpendicular to the central axis of the dry cell main body 2 and contacts and separates from both end surfaces of the dry cell main body 2. Both ends of the sheet 17 are bent inward by a jig (not shown), and both ends of the transfer sheet 17 are pressed against both end surfaces of the dry cell body 2 by the rollers 27 and 27 while rotating the rollers 27 and 27 around the central axis L. You may do it.

  When the mechanisms shown in FIGS. 8 and 9 are employed, the pressing roller 24 does not need to have flexibility, and may be formed of metal or hard resin.

  Of the decorative layer 20 of the transfer sheet 17 transferred onto the dry cell main body 2, the decorative layer 13 (see FIG. 1) is formed by the portion transferred onto the outer peripheral surface of the body 4, and both upper and lower end surfaces of the dry cell main body 2 are formed. The belt-shaped decorative layers 14 and 15 (see FIGS. 2 and 3) are formed by the portion transferred to the peripheral edge of the film. Further, the surface protective layer 16 (see FIG. 4) is formed by the release layer 19 transferred to the dry battery body 2.

  The total thickness of the decorative layer 13 and the surface protective layer 16 formed on the outer peripheral surface of the body portion 4 of the dry cell main body 2 is about 10 μm or less, and the dry cell main body has a thickness of about 10 μm or less compared to the conventional product (about 210 to 300 μm). Since the thickness of the part formed on the outer peripheral surface of the trunk portion is significantly reduced, and the outer diameter of the metal container 3 can be increased correspondingly, the battery capacity is increased.

  In the above-described embodiment, the dry cell main body is rotated on the heat-adhesive resin layer of the heated transfer sheet to transfer the decorative layer of the transfer sheet onto the dry cell main body. After winding on the outer peripheral surface of the body part of the dry battery body so that the layer becomes the inner surface, the transfer sheet may be heated to transfer the decorative layer onto the outer peripheral surface of the body part of the dry battery body.

  In the above embodiment, in the step of providing the decorative layer, the belt-like decorative layer, the surface protective layer, and the insulating layer are also provided at the same time. However, these layers may be provided in separate steps. Moreover, you may make it provide layers other than a decoration layer by methods (for example, coating, sticking, etc.) other than transcription | transfer.

  Although not specifically described in the above embodiment, the surface of the metal thin plate that forms the body of the dry battery is usually nickel-plated for rust prevention, in which case Since the heat-adhesive resin layer does not adhere to the surface, in the case of the production method for transferring while heating according to the present invention, it is necessary to coat the surface of the metal thin plate in advance with a thermosetting or thermoplastic resin. is there. In particular, when coating is performed before deep drawing, it is necessary to use a resin that follows the deep drawing, such as polyester, urethane, latex, and other elastomers.

  In the case of the transfer method as shown in FIG. 6, the transfer sheet shown in FIG. 5 has a release layer for forming a surface protective layer laminated on the surface of the decorative layer after transfer. Furthermore, even if the transfer sheets overlap and are heated and pressurized, the release layer located on the outermost layer prevents retransfer, so it is necessary to perform transfer precisely in accordance with the external shape of the dry cell. There is no. Therefore, the manufacturing is easy and the transfer speed can be increased.

  Moreover, you may make it provide an insulating layer only in the part around the negative electrode in the lower end surface of a dry cell main body.

  Also, the transfer sheet base sheet is made of heat-shrinkable, and the transfer sheet is formed in a cylindrical shape so that the heat-adhesive resin layer is on the inner surface. The transfer sheet may be removed after the sheet is heated to transfer the printed layer to the outer peripheral surface of the body portion of the dry battery body.

  In this case, in a state where the transfer sheet is formed in a cylindrical shape, if both ends are formed so as to slightly protrude from both ends in the axial direction of the body of the dry cell body, when the transfer sheet contracts, Since both end portions of the transfer sheet are bent inward and are in close contact with the peripheral edge portions of the upper and lower end surfaces of the dry battery body, it is possible to form a belt-like decorative layer and an insulating layer at the same time as forming the decorative layer.

  In addition, this invention is applicable also to dry batteries other than an alkaline battery. The present invention is particularly effective when applied to small-sized dry batteries.

The partially broken side view of the dry battery 1 of one Embodiment of this invention. The top view of the dry battery 1 of FIG. The bottom view of the dry battery 1 of FIG. Sectional drawing of the trunk | drum 4 and the upper end wall 5 of the metal container 3 of the dry battery 1 of FIG. Sectional drawing of the transfer sheet 17 used for the manufacturing method of one Embodiment of this invention. The schematic block diagram of the transfer apparatus which enforces the manufacturing method of one Embodiment of this invention. FIG. 7 is a view taken along line AA in FIG. 6. The schematic perspective view of other embodiment of a transfer device. The schematic perspective view of other embodiment of a transfer device. The right view of FIG. The cross-sectional view of the conventional dry battery 101.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Dry cell 2 Dry cell main body 3 Metal container 4 Trunk part 13 Decoration layer

Claims (4)

A dry battery in which a decorative layer is formed by transfer on the outer peripheral surface of the body of the dry battery body using a transfer sheet,
The decorative layer is formed by transfer over substantially the entire circumference on the outer peripheral surface of the body portion of the dry cell body, and a surface protective layer is formed as an outermost layer covering the decorative layer,
A dry battery, wherein the release layer transferred together with the decorative layer from the transfer sheet forms the surface protective layer. A dry cell in which a decorative layer is formed by transfer on the outer peripheral surface of the body portion of the dry cell body and the peripheral edge portions of the upper and lower end surfaces of the dry cell body using a transfer sheet,
The decorative layer is formed on the outer peripheral surface of the body portion of the dry battery body and on the peripheral edge portions of the upper and lower end surfaces of the dry battery body over substantially the entire circumference, and a surface protective layer is provided as an outermost layer covering the decorative layer. Formed,
A dry battery, wherein the release layer transferred together with the decorative layer from the transfer sheet forms the surface protective layer.   The dry battery according to claim 1 or 2, wherein the release layer is made of polyester, urethane, or melamine.   The outer peripheral surface of the body portion of the dry cell body is formed on the plated layer by a plating layer formed on the surface of a metal thin plate forming the body portion of the dry cell body, and a thermosetting or thermoplastic resin. The dry battery according to claim 1, further comprising a coating layer.

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