JP4264521B2 - Manufacturing method for ceramic glass bottles - Google Patents

Manufacturing method for ceramic glass bottles Download PDF

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JP4264521B2
JP4264521B2 JP2004137404A JP2004137404A JP4264521B2 JP 4264521 B2 JP4264521 B2 JP 4264521B2 JP 2004137404 A JP2004137404 A JP 2004137404A JP 2004137404 A JP2004137404 A JP 2004137404A JP 4264521 B2 JP4264521 B2 JP 4264521B2
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ceramic
beads
coating
glass bottle
particles
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JP2005320019A (en
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俊夫 玉井
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Ishizuka Glass Co Ltd
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Description

この発明は陶器調ガラスびん製造方法に関する。 This invention relates to a method of manufacturing a porcelain tone vial.

陶器は、食品、酒類、飲料水、調味料等を収納する容器として広く用いられている。ガラスびんも食品等の収納容器として広く使われている。ガラスびんは、陶器と比べて成形が容易であり成形寸法の精度が高く、陶器に代えて使用されるようになって久しい。   Pottery is widely used as a container for storing food, alcoholic beverages, drinking water, seasonings and the like. Glass bottles are also widely used as storage containers for food. Glass bottles are easier to mold than pottery and have high accuracy in molding dimensions, and have been used for a long time instead of pottery.

ガラスびんは、上述した利点を有し食品等の収容容器として優れているが、陶器のような風合いを醸し出すことができない。ガラスびんの表面を加工する技術として、着色剤を混入させた樹脂をコーティングすることあるいは球状のシリカ質ビーズや樹脂製ビーズを混入させた樹脂によってフロスト調被膜を形成することが行われている。   Glass bottles have the above-mentioned advantages and are excellent as containers for food and the like, but cannot produce a texture like pottery. As a technique for processing the surface of a glass bottle, coating a resin mixed with a colorant or forming a frosted film with a resin mixed with spherical siliceous beads or resin beads is performed.

しかしながら、ガラスびんの表面に陶器調の加工をする技術は出願人の知るところではなく、他の加工技術としては、球形の固定樹脂を配合した樹脂組成物を静電塗装することによってサテン(繻子織模様)調模様をガラスびんの表面に施することが知られている(特許文献1参照。)。   However, the technology for processing ceramics on the surface of glass bottles is not known to the applicant, and other processing technologies include satin (insulator) by electrostatic coating of a resin composition containing a spherical fixing resin. It is known to apply a woven pattern to the surface of a glass bottle (see Patent Document 1).

近年は、陶器が高級感を与えることや親しみやすく温かみを感じさせることから日本酒や焼酎の収納容器として見直されて愛好されている。   In recent years, pottery has been reconsidered as a container for sake and shochu because it gives a high-class feel and makes it feel friendly and warm.

しかるに、陶器は、製造コストがかかることや量産に不向きなものであるとの欠点を有する。さらに、陶器は、仕上がり寸法を均一にすることも困難であり、口部を単一の種類のキャップによっては密封することができないとの問題も有している。
特許第3029021号明細書
However, pottery has drawbacks that it is expensive to manufacture and is unsuitable for mass production. Furthermore, it is difficult for the earthenware to have uniform finished dimensions, and the mouth portion cannot be sealed with a single type of cap.
Japanese Patent No. 3029021

この発明は、このような状況に鑑み提案されたものであって、製造コストを抑えて量産することができ、仕上がり寸法の精度を向上させさらに高級感を与えることができる陶器調ガラスびん製造方法を提供することを目的とする。 This invention, which was proposed in view of such circumstances, can be mass-produced with reduced manufacturing costs, the production of pottery tone vial can give more luxurious improve the accuracy of the finished dimension It aims to provide a method.

すなわち、請求項1の発明は、アクリル系とウレタン系を組み合わせた熱硬化性樹脂あるいはアクリル系とメラミン系を組み合わせた熱硬化性樹脂に対して、自然石,セラミックを砕いたもの,セラミック系顔料の粉末で構成される0.1〜1mmの大きさの異色粒子と、ガラスビーズ,シリカビーズ,セラミックビーズ,樹脂製ビーズで構成される0.1〜1mmの大きさの凹凸粒子とを、それぞれ0.1〜10重量部となるように分散するとともに、着色剤を配合した着色不透明材料を、回転するガラスびんの表面に対して噴霧塗装によって塗着し、熱硬化して厚さ15〜20μmで鉛筆硬度が3H以上の塗膜を形成することを特徴とする陶器調ガラスびんの製造方法に係る。 That is, the invention of claim 1 relates to a thermosetting resin combining acrylic and urethane, or a thermosetting resin combining acrylic and melamine, natural stone, ceramic crushed, ceramic pigment Different colored particles having a size of 0.1 to 1 mm composed of powder of the above and uneven particles having a size of 0.1 to 1 mm composed of glass beads, silica beads, ceramic beads, and resin beads, respectively. Disperse to 0.1 to 10 parts by weight, and apply a colored opaque material containing a colorant to the surface of the rotating glass bottle by spray coating and heat cure to a thickness of 15 to 20 μm. And a method for producing a ceramic glass bottle, wherein a coating film having a pencil hardness of 3H or more is formed .

請求項の発明に係る陶器調ガラスびんの製造方法によれば、アクリル系とウレタン系を組み合わせた熱硬化性樹脂あるいはアクリル系とメラミン系を組み合わせた熱硬化性樹脂に対して、自然石,セラミックを砕いたもの,セラミック系顔料の粉末で構成される0.1〜1mmの大きさの異色粒子と、ガラスビーズ,シリカビーズ,セラミックビーズ,樹脂製ビーズで構成される0.1〜1mmの大きさの凹凸粒子とを、それぞれ0.1〜10重量部となるように分散するとともに、着色剤を配合した着色不透明材料を、回転するガラスびんの表面に対して噴霧塗装によって塗着し、熱硬化して厚さ15〜20μmで鉛筆硬度が3H以上の塗膜を形成することより、着色不透明塗料を効率良く塗着させてガラスびんの表面に微細な凹凸を形成して陶器調の塗膜を形成することができ、陶器調ガラスびんの表面に傷がつくことを防ぐとともに陶器調の色合が長期間損なわれることがなく、しかも紫外線の透過を抑えて壜の内容物の劣化を防ぐことができるまた、製造コストを抑えて陶器調ガラスびんを量産することができて仕上がり寸法の精度を向上させさらに高級感を与えることができる。 According to the method for producing a ceramic glass bottle according to the invention of claim 1 , natural stone, in contrast to a thermosetting resin combining acrylic and urethane or a thermosetting resin combining acrylic and melamine, 0.1 to 1 mm composed of crushed ceramic, 0.1 to 1 mm different colored particles composed of ceramic pigment powder, glass beads, silica beads, ceramic beads and resin beads Disperse the uneven particles having a size of 0.1 to 10 parts by weight, and apply a colored opaque material containing a colorant to the surface of the rotating glass bottle by spray coating. than to the pencil hardness in a thickness of 15~20μm thermally cured to form a more coating 3H, colored opaque coating efficiently Nurigi is not form fine irregularities on the surface of a glass bottle And pottery tone by coating can be formed, without shades of porcelain tone is impaired long period while preventing the scratch the surface of the pottery tone glass bottles, yet the bottle by suppressing the transmission of ultraviolet light Deterioration of contents can be prevented . In addition, it is possible to mass-produce ceramic glass bottles at a reduced manufacturing cost, improving the accuracy of the finished dimensions and giving a higher-class feeling.

以下添付の図面に従ってこの発明を詳細に説明する。図1陶器調ガラスびんの外観図、図2は同陶器調ガラスびんの部分拡大断面図、図3はスプレーガンによる静電塗装の概略説明図、図4は回転ディスク型塗装装置による静電塗装の概略説明図である。 Hereinafter, the present invention will be described in detail with reference to the accompanying drawings. 1 is an external view of a ceramic glass bottle, FIG. 2 is a partially enlarged sectional view of the ceramic glass bottle, FIG. 3 is a schematic explanatory diagram of electrostatic coating with a spray gun, and FIG. 4 is an electrostatic diagram with a rotating disk type coating device. It is a schematic explanatory drawing of coating.

陶器調ガラスびん10は、図1及び図2に図示したように、ガラスびんの表面11に異色粒子21及び凹凸粒子25を含有する合成樹脂からなる着色不透明塗膜20が形成されてなるものである。 As shown in FIGS. 1 and 2, the ceramic glass bottle 10 is formed by forming a colored opaque coating film 20 made of a synthetic resin containing different color particles 21 and uneven particles 25 on the surface 11 of the glass bottle. is there.

出願人は、陶器の持つ質感、ぬくもり感、色彩、ざらついた手触り感のある陶器調の塗膜を形成することを鋭意検討した。この陶器調の塗膜は、滑らかでさらさらな手触り感のあるサテン(繻子織模様)調模様を形成する塗膜とは全く異なるものである。   The applicant diligently studied to form a ceramic-like coating film that has the texture, warmth, color, and texture of the pottery. This ceramic-like coating film is completely different from a coating film that forms a satin-like pattern with a smooth and smooth touch.

実施例では、塗膜20を形成する合成樹脂を、アクリル系、エポキシ系、ウレタン系、メラミン系等の熱硬化性樹脂あるいはこれらを組み合せたものとした。特に、この合成樹脂は、所定の鉛筆硬度を確保するためアクリル系とウレタン系の熱硬化性樹脂を組み合せたものあるいはアクリル系とメラミン系の熱硬化性樹脂を組み合せたものが好ましい。塗膜20は、厚さを15〜20μmとすることが好ましく必要に応じて紫外線吸収剤が配合される。厚さが10μmより薄いときは、紫外線の遮断効果を発揮することができない。この塗膜20は、紫外線が透過することを抑えてびん10の内容物が劣化することを防ぐ。   In the examples, the synthetic resin for forming the coating film 20 was a thermosetting resin such as acrylic, epoxy, urethane, or melamine, or a combination thereof. In particular, the synthetic resin is preferably a combination of acrylic and urethane thermosetting resins or a combination of acrylic and melamine thermosetting resins in order to ensure a predetermined pencil hardness. The coating film 20 preferably has a thickness of 15 to 20 μm, and an ultraviolet absorber is blended as necessary. When the thickness is less than 10 μm, the ultraviolet blocking effect cannot be exhibited. The coating film 20 prevents the contents of the bottle 10 from deteriorating by suppressing the transmission of ultraviolet rays.

異色粒子21は、ガラスびんの表面に形成する塗膜20の色彩に応じて適宜のものが選ばれて陶器調の雰囲気を醸し出す。この実施例では、この異色粒子21が、大理石や石灰石等の自然石、陶器、磁器等のセラミックをそれぞれ砕いたもの、セラミック系顔料の粉末等で構成される。   The different color particles 21 are appropriately selected according to the color of the coating film 20 formed on the surface of the glass bottle to create a ceramic atmosphere. In this embodiment, the different colored particles 21 are composed of natural stones such as marble and limestone, crushed ceramics such as ceramics and porcelain, and ceramic pigment powders.

凹凸粒子25は、塗膜20の表面に凹凸を形成して陶器調の仕上げを可能にする。この実施例では、この凹凸粒子25が、ガラスビーズ、シリカビーズ、セラミックビーズ、樹脂製のビーズ等で構成される。   The uneven particles 25 form unevenness on the surface of the coating film 20 to enable a ceramic finish. In this embodiment, the uneven particles 25 are made of glass beads, silica beads, ceramic beads, resin beads, or the like.

着色剤は、陶器調の色合を醸し出すために茶色系、黒色系、白色系、黄色系のものが好ましい。この着色剤は、異色粒子21や凹凸粒子25とともに合成樹脂に配合されて紫外線の透過を抑えびん10の内容物が劣化することを防ぐ。黒色系の着色剤は、薄い色合の塗膜を形成するびんの表面に下塗りされて紫外線が透過することを防ぐ。   The colorant is preferably brown, black, white, or yellow in order to bring out a pottery tone. This colorant is blended in the synthetic resin together with the different color particles 21 and the uneven particles 25 to suppress the transmission of ultraviolet rays and prevent the contents of the bottle 10 from deteriorating. The black colorant is primed on the surface of the bottle forming a thin-colored coating film to prevent ultraviolet rays from being transmitted.

この陶器調ガラスびん10は、陶器と比べて仕上がり寸法の精度を向上させることができ単一の種類のキャップ11によって口部を密封することができる。ここでは、キャップ11をコルク栓とした。   This pottery glass bottle 10 can improve the accuracy of the finished dimensions as compared to pottery, and the mouth can be sealed with a single type of cap 11. Here, the cap 11 was a cork stopper.

この陶器調ガラスびん10の製造方法は、ガラスびんの表面に異色粒子21及び凹凸粒子25を分散した熱硬化性合成樹脂よりなる着色不透明塗料を噴霧塗装によって塗着し、熱硬化して塗膜20を形成するものである。 The method for producing the ceramic glass bottle 10 is to apply a colored opaque paint made of a thermosetting synthetic resin in which different colored particles 21 and uneven particles 25 are dispersed on the surface of the glass bottle by spray coating, and then thermally cure to form a coating film. 20 is formed.

噴霧塗装は、塗料を圧縮空気によって霧状にして吹き付ける塗装(エア霧化塗装)、塗料を圧縮空気や油圧等によって霧化して吹き付ける塗装(エアレス(液圧)霧化塗装)、塗料を帯電させて噴霧する塗装(静電塗装)、粉末の塗料を吹き付ける粉体塗装を含む。この実施例では、金属粉末を分散させた着色不透明塗料が公知の静電塗装によって塗着される。ガラスびんは外表面が水洗いされて汚れが落された後に塗装ラインに搬入される。搬入されたガラスびん10Aは、図3に図示するように、回転しながら進行しスプレーガン30によって帯電した着色不透明塗料が外表面に吹き付けられる。このスプレーガン30は、塗料をびん10Aの外表面に斜め上方及び下方から吹き付けるように配置される。ここでは、塗料が2台のスプレーガン30によって吹き付けられる。このスプレーガンによる塗装は多段階に分けて行われることもある。例えば、色違いの塗料を重ねて塗着することによって、より陶器調の雰囲気を醸し出させることができる。図中の符号35はガラスびん10Aに嵌入される回転軸である。   Spray coating is a coating in which the paint is sprayed in the form of a mist with compressed air (air atomization coating), a coating in which the paint is atomized with compressed air or hydraulic pressure (airless (hydraulic pressure) atomization coating), and the paint is charged. Spray coating (electrostatic coating) and powder coating that sprays powder paint. In this embodiment, a colored opaque paint in which metal powder is dispersed is applied by a known electrostatic coating. Glass bottles are brought into the painting line after the outer surface is washed with water and cleaned. As shown in FIG. 3, the carried glass bottle 10 </ b> A advances while rotating, and the colored opaque paint charged by the spray gun 30 is sprayed on the outer surface. The spray gun 30 is disposed so as to spray paint on the outer surface of the bottle 10A from obliquely above and below. Here, the paint is sprayed by two spray guns 30. The spray gun may be applied in multiple stages. For example, it is possible to create a more ceramic-like atmosphere by applying different color paints. Reference numeral 35 in the drawing denotes a rotating shaft fitted into the glass bottle 10A.

着色不透明塗料は、いわゆる回転ディスク型静電塗装装置40によってガラスびん10Aの表面に塗着することもできる。ガラスびん10Aは、図4に図示するように、荷電した回転ディスクDによって帯電し霧化した着色不透明塗料が放射状に飛散してびん10Aの外表面全面に塗着される。これによって、微細な噴霧塗装をガラスびん10Aの外表面に行うことができる。図中の符号41はモータ、42は塗料供給装置である。   The colored opaque paint can be applied to the surface of the glass bottle 10 </ b> A by a so-called rotating disk type electrostatic coating apparatus 40. As shown in FIG. 4, the glass bottle 10 </ b> A is applied to the entire outer surface of the bottle 10 </ b> A by the colored opaque paint charged and atomized by the charged rotating disk D being scattered radially. Thereby, fine spray coating can be performed on the outer surface of the glass bottle 10A. Reference numeral 41 in the figure is a motor, and 42 is a paint supply device.

所定の着色不透明塗料が塗着されたガラスびんは、170℃〜180℃に保たれた硬化炉で20分間加熱されることにより塗着した塗料が熱硬化して塗膜が形成される。   The glass bottle on which a predetermined colored opaque paint is applied is heated for 20 minutes in a curing furnace maintained at 170 ° C. to 180 ° C., whereby the applied paint is thermally cured to form a coating film.

この塗膜の鉛筆硬度は3H以上である。これによって、陶器調ガラスびん10の表面に傷がつくことを防ぐとともに陶器調の色合が長期間損なわれることがない。 The pencil hardness of this coating film is not less than 3H. This prevents the surface of the ceramic glass bottle 10 from being scratched and prevents the color of the ceramic glass from being damaged for a long time.

この陶器調ガラスびんの製造方法は前記異色粒子21及び凹凸粒子25の大きさを0.1〜1mmとするものである。異色粒子21及び凹凸粒子25の大きさがこの範囲を外れると、陶器調の塗膜を形成することができない。凹凸粒子が0.1mmより小さいときは、陶器のような手触りを出すことができない。この凹凸粒子が1mmを超えるときは、スプレーガンの目詰りが生じて所定の塗装をすることができない。特に、この異色粒子21及び凹凸粒子25の大きさは0.2〜0.5mmとすることが好ましい。この異色粒子21及び凹凸粒子25は、前記合成樹脂に対して0.1ないし10重量部となるように加えられることが好ましい。 Method for manufacturing ceramics regulating glass bottles are those 0.1~1mm the size of the different-color particles 21 and uneven particles 25. If the sizes of the different color particles 21 and the uneven particles 25 are out of this range, a ceramic-like coating film cannot be formed. When the concavo-convex particles are smaller than 0.1 mm, a touch like pottery cannot be obtained. When the uneven particles exceed 1 mm, the spray gun is clogged and a predetermined coating cannot be performed. In particular, the size of the different color particles 21 and the uneven particles 25 is preferably 0.2 to 0.5 mm. It is preferable that the different color particles 21 and the uneven particles 25 are added so as to be 0.1 to 10 parts by weight with respect to the synthetic resin.

実施例の各種評価およびその測定方法を表1および表2に示す。各種の評価(表1)は、表中の測定方法や測定条件によって行った。平均表面粗さRa(表2)は、各陶器調ガラスびんの任意の2箇所(合計12箇所)を測定した。   Tables 1 and 2 show various evaluations of the examples and measurement methods thereof. Various evaluations (Table 1) were performed according to the measurement methods and measurement conditions in the table. The average surface roughness Ra (Table 2) was measured at any two locations (12 locations in total) of each ceramic glass bottle.

Figure 0004264521
Figure 0004264521

Figure 0004264521
Figure 0004264521

この発明の陶器調ガラスびんの外観図である。It is an external view of the earthenware glass bottle of this invention. 同陶器調ガラスびんの部分拡大断面図である。It is a partial expanded sectional view of the earthenware glass bottle. スプレーガンによる静電塗装の概略説明図である。It is a schematic explanatory drawing of the electrostatic coating by a spray gun. 回転ディスク型塗装装置による静電塗装の概略説明図である。It is a schematic explanatory drawing of the electrostatic coating by a rotating disk type coating device.

符号の説明Explanation of symbols

10 陶器調ガラスびん
20 塗膜
21 異色粒子
25 凹凸粒子
10 Ceramic-like glass bottles 20 Coating films 21 Different colored particles 25 Concave and convex particles

Claims (1)

アクリル系とウレタン系を組み合わせた熱硬化性樹脂あるいはアクリル系とメラミン系を組み合わせた熱硬化性樹脂に対して、自然石,セラミックを砕いたもの,セラミック系顔料の粉末で構成される0.1〜1mmの大きさの異色粒子と、ガラスビーズ,シリカビーズ,セラミックビーズ,樹脂製ビーズで構成される0.1〜1mmの大きさの凹凸粒子とを、それぞれ0.1〜10重量部となるように分散するとともに、着色剤を配合した着色不透明材料を、回転するガラスびんの表面に対して噴霧塗装によって塗着し、熱硬化して厚さ15〜20μmで鉛筆硬度が3H以上の塗膜を形成することを特徴とする陶器調ガラスびんの製造方法。 0.1 consisting of natural stone, crushed ceramic, and ceramic pigment powder for thermosetting resin combining acrylic and urethane or thermosetting resin combining acrylic and melamine 0.1 to 10 parts by weight of different colored particles having a size of ˜1 mm and uneven particles having a size of 0.1 to 1 mm composed of glass beads, silica beads, ceramic beads, and resin beads A colored opaque material blended with a coloring agent is applied to the surface of a rotating glass bottle by spray coating, heat-cured, and has a thickness of 15 to 20 μm and a pencil hardness of 3H or more. A method of manufacturing a ceramic glass bottle characterized by forming a glass.
JP2004137404A 2004-05-06 2004-05-06 Manufacturing method for ceramic glass bottles Expired - Fee Related JP4264521B2 (en)

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CN104260971A (en) * 2014-09-11 2015-01-07 张俊峰 Black pottery wine bottle

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JP5930849B2 (en) * 2012-05-31 2016-06-08 将太 富田 Manufacturing method of glass container

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JPS5916799A (en) * 1982-07-20 1984-01-27 前田 弘 China-like decorative material and its manufacture
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JPH05201199A (en) * 1992-01-30 1993-08-10 Toshinori Oguro Manufacture of decorative substrate and decorative substrate manufactured through said method
JP2005169353A (en) * 2003-12-15 2005-06-30 Wako Kagaku Kogyo Kk Glass vessel and production method therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104260971A (en) * 2014-09-11 2015-01-07 张俊峰 Black pottery wine bottle
CN104260971B (en) * 2014-09-11 2016-03-23 张俊峰 A kind of black pottery bottle

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