JP4245970B2 - Water resistant nonwoven fabric - Google Patents
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Description
【０００１】
【発明の属する技術分野】
本発明は、耐水性能が要求され、また同時に柔らかさと強度等も要求される分野、例えば衛生材料の表面素材、特に使い捨ておむつのサイドギャザー等において有用なポリプロピレン不織布に関する。
【０００２】
【従来の技術】
従来、衛生材料のサイド部における表面材、特に使い捨ておむつのサイドギャザーには、ポリプロピレンスパンボンド（以下、「ＳＢ」と言う。）不織布やメルトブロー不織布層がポリプロピレンスパンボンド不織布層により挟み込まれた積層構造体（以下、「ＳＭＳ」と言う。）不織布が用いられてきた。しかしながら、ＳＢ不織布単体では耐水性能が悪く、尿洩れを防止する上で、低目付化が難しく、経済性の面でも好ましくなかった。また、従来のＳＭＳ不織布では、耐水性能は向上するが、低目付化による強力の低下や、ごわつき感があるため肌に触れた際の感触があまり良くないという問題があった。
【０００３】
従来の方法では、ポリプロピレンスパンボンド不織布をサイドギャザー用途に提供する場合、高耐水性を得るには、積層体の高目付化やＭＢ不織布層の目付のみを大きくしたり、繊度を細くする方法があったが、積層体の高目付化は、経済性に劣ってしまい、厚みも増すためオムツ構造をコンパクト化しにくく、廃棄量の増大にも繋がり環境面でも好ましくなかった。
また、ＭＢ不織布層の目付のみを大きくしたり、繊度を細くする方法での低目付化はＭＢ不織布層における耐水性能の向上は見られるが、ＳＢ不織布層との積層構造体にした場合では十分な性能を得ることが出来なかった。
【０００４】
【発明が解決しようとする課題】
本発明は、防水性に優れかつ柔らかさや引張強度も高い不織布を提供することを目的とする。
【０００５】
【課題を解決するための手段】
本発明者らは、前記課題を解決するため鋭意研究をした結果、本発明をなすに至った。
即ち、本発明は、ＭＦＲが２０〜７０で繊度が０．７〜１．５ｄｔｅｘのポリプロピレンスパンボンド（ＳＢ）不織布と繊径が１〜３μｍ、ＭＦＲが５００以上１３００未満であるポリプロピレンメルトブロー（ＭＢ）不織布とからなり、ＭＢ不織布層がＳＢ不織布層により挟み込まれた積層構造体であり、部分的熱圧着で一体化してなるＭＢ不織布層の目付が１ｇ／ｍ2 以上総目付の３３％以下で、総目付が８ｇ／ｍ2 以上であり、５％モジュラス指数が下記式（１）に示す範囲を満足させる防水性に優れかつ柔らかさを併せ持った耐水性不織布である。
５％モジュラス指数≧０．４１ ・・・（１）
但し、５％モジュラス指数＝５％モジュラス（Ｎ／３ｃｍ）／目付（ｇ／ｍ2 ）
【０００６】
以下、本発明に関して詳述する。
本発明に使用されるポリプロピレンは、一般的なチーグラナッタ触媒により合成されるポリマーでもよいし、メタロセンに代表されるシングルサイト活性触媒により合成されたポリマーであっても良い。また、ポリプロピレン中にポリエチレンを添加したポリマーや他の添加剤を添加したポリマーでも良い。
本発明のスパンボンド不織布を構成するポリプロピレン繊維のＭＦＲは、２０以上である。ＭＦＲ２０未満では、細い繊度の繊維を得る場合、紡糸することが困難となる。また、７０以上でも安定した紡糸は可能だが繊維の引張り強度等の物性値が低下してしまうため実用的でない。一般に繊度が１．５ｄｔｅｘを下回るような細い糸のスパンボンド不織布を製造するためには、特開平１０−２９２２５６号公報に開示されているような紡糸方法が用いられている。しかし、この特許文献中で開示された技術では繊度的には限界に近く、強度や柔らかさ、原料の単一化、生産性を考えると、特願２００１−２７６９５１に開示のスパンボンド法が、最も本発明に適している。
また、本発明のメルトブロー不織布を構成するポリプロピレン繊維のＭＦＲは５００以上１３００未満である。５００未満では細い繊度を得るのが困難となりまた、１３００以上になると紡糸性が悪くなるため好ましくない。
【０００７】
本発明の積層体不織布の構成は、繊度が０．７〜１．５ｄｔｅｘであるＳＢ不織布層の上からＭＢ不織布層を積層し、更にはその上から同様に繊度が０．７〜１．５ｄｔｅｘのＳＢ不織布層を積層させ、部分的熱圧着で一体化させることが最も好ましく、少なくともＳＢの片層の繊度が０．７〜１．５ｄｔｅｘでも良い。ＭＢ不織布層がＳＢ不織布層に覆われていれば、構造体として例えば、ＭＢ不織布層を２層にしたり、ＳＢ不織布層を２層重ねる等の多層化としても良い。ＳＢ不織布層の繊径を細くすることで、分散性を良くし繊維開孔径を小さくできるため、ＭＢ不織布層を重ねる際にＳＢ不織布層へのＭＢ不織布の突き抜け（Ｓｈｏｏｔｉｎｇ Ｅｆｆｅｃｔ）を防止できる。ＳＢ不織布層へのＭＢ不織布の突き抜けは、熱圧着する際に、ピンホールや穴空きの原因となり、耐水性能を低下させる要因となるため好ましくない。
【０００８】
ＭＢ不織布の繊径を細くするには、ホール当たり吐出量を少なくする必要があり生産性の低下に繋がる。また、ホットエアー量を増加させねばならず、フライ（糸切れ）の発生など紡糸が不安定となる。逆にＭＢ不織布の繊径が太くなれば、繊維開孔径も増加し耐水性能の低下に繋がるため、ＭＢ不織布の繊径範囲としては１〜５μｍであり、３μｍ以下が好ましい。総目付の範囲は８ｇ／ｍ2 以上あれば良いが、１０〜５０ｇ／ｍ2 の範囲がより好ましい。ＭＢ不織布層の目付は目付が１ｇ／ｍ2以上総目付の３３％以下である。ＭＢ不織布層の割合を増やせば、ＭＢ不織布層自体の耐水性能は向上するが、ＳＢ不織布層の目付の低下から５％モジュラス値や強力値が低下するためＭＢ不織布層の形態保持効果が低くなり好ましくない。また、ＭＢ不織布層の割合を低くすれば、耐水性能の向上があまり望めず生産性の低下にも繋がるため好ましくない。
本発明は、以上のような積層体を構成することにより防水性に優れかつ柔らかさや引張強度も高い不織布を得ることに成功した。
【０００９】
【発明の実施の形態】
以下、実施例を挙げて更に説明する。
尚、各特性の評価方法は下記の通りである。
（１）繊度（ｄｔｅｘ：フィラメント10000 ｍ長の重量をグラム数で表示）
生産された不織布の両端１０ｃｍを除き、ＣＤ方向に５等分して１ｃｍ角の試験片をサンプリングし、顕微鏡で繊維の直径を各５０点ずつ測定し、ポリプロピレンの繊維密度を０．９１ｇ／ｃｍ3 として、その平均値から繊度を算出した（小数点第２位を四捨五入）。
測定には、キーエンス社製の高倍率マイクロスコープＶＨ−８０００を用いた。
【００１０】
（２）ＭＦＲ（メルトフローレート）
ＪＩＳ−Ｋ−７２１０「熱可塑性プラスチックの流れ試験方法」の表１の条件１４、試験温度２３０℃、試験荷重２１．１８Ｎに準じて測定を行いＭＦＲを求めた。
（３）耐水圧（ｍｂ又は１００Ｐａ）
生産された不織布の両端１０ｃｍを除き、ＣＤ方向に５等分、ＭＤ方向に３等分して計１５点に関して２０ｃｍ角の試験片をサンプリングし、ＪＩＳ−Ｌ−１０９２に準じて測定を実施し、その平均値から耐水圧を算出した。
【００１１】
（４）毛羽性
生産された不織布の両端１０ｃｍを除き、ＣＤ方向に５等分してＣＤ、ＭＤ方向に２５ｍｍ×３００ｍｍの試験片を採取し、日本学術振興会型の堅牢度試験機を用いて、摩擦子の荷重が２００ｇ、摩擦子側には摩擦係数が適当と考えられるリンレイクロス−重梱包用Ｎｏ．３１４布粘着テープを使用し、５０回動作させて以下の基準で毛羽性を等級付け、表裏の平均値により毛羽等級を決定した（小数点第２位で四捨五入）。
１．０級：試験片が破損するほど繊維が剥ぎ取られている。
２．０級：試験片が薄くなるほど甚だしく繊維が剥ぎ取られている。
２．５級：毛玉が大きくはっきり見られ、複数箇所で繊維が浮き上がり始めている。
３．０級：はっきりした毛玉が出来始め、又は小さな毛玉が複数見られる。
３．５級：一箇所に小さな毛玉が出来始める程度に毛羽立っている。
４．０級：毛羽立ちがない。
【００１２】
（５）５％モジュラス、５％モジュラス指数
生産された不織布の両端１０ｃｍを除き、ＣＤ方向に５等分、ＭＤ方向に３等分して計１５点に関してＣＤ、ＭＤ方向に３ｃｍ×２０ｃｍの試験片をサンプリングし、低速伸張試験型の引張試験機に把握長１０ｃｍで取付け、引張速度３０ｃｍ／分で試験片が破断するまで荷重を加える。試験片の５％伸張時の強さの平均値をＭＤ、ＣＤ方向で求めた（小数点第２位を四捨五入）。
また、５％モジュラス指数は次の式で求めることが出来る。
５％モジュラス指数＝５％モジュラス［Ｎ／３ｃｍ］／総目付［ｇ／ｍ2 ］
【００１３】
（６）引張強度
生産された不織布の両端１０ｃｍを除き、ＣＤ方向に５等分、ＭＤ方向に３等分して計１５点に関してＣＤ、ＭＤ方向に３ｃｍ×２０ｃｍの試験片をサンプリングし、低速伸張試験型の引張試験機に把握長１０ｃｍで取付け、引張速度３０ｃｍ／分で試験片が破断するまで荷重を加える。試験片の最大荷重時の強さの平均値をＭＤ、ＣＤ方向で求めた（小数点第２位を四捨五入）。
（７）表面特性
生産された不織布を用いて測定者５人に対し、柔らかさ、ぬめり感、ざらつき感の３項目に関して３段階でランク付け（数値大で良好）を実施し、それぞれの合計ポイントにて評価を実施した（ランク付けは、それぞれの同一目付に対して評価を実施）。
【００１４】
【実施例１〜２０、比較例１〜１４】
ＭＢ不織布層の繊度を１．８μｍ、目付を１ｇ／ｍ2 とし、ＳＭＳ構造体の総目付が１３ｇ／ｍ2 におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例１）、１．２ｄｔｅｘ（実施例２）、１．５ｄｔｅｘ（実施例３）、１．７ｄｔｅｘ（比較例１）、２．８ｄｔｅｘ（比較例２）、また総目付が１７ｇ／ｍ2におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例４）、１．２ｄｔｅｘ（実施例５）、１．５ｄｔｅｘ（実施例６）、１．７ｄｔｅｘ（比較例３）、２．８ｄｔｅｘ（比較例４）と変化させた。
同様にＭＢ不織布層の目付を２ｇ／ｍ2とし、ＳＭＳ構造体の総目付が１０ｇ／ｍ2におけるＳＢ不織布層の繊度を１．２ｄｔｅｘ（実施例７）、また総目付が１３ｇ／ｍ2 におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例８）、１．２ｄｔｅｘ（実施例９）、１．５ｄｔｅｘ（実施例１０）、１．７ｄｔｅｘ（比較例５）、２．８ｄｔｅｘ（比較例６）、また総目付が１７ｇ／ｍ2におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例１１）、１．２ｄｔｅｘ（実施例１２）、１．５ｄｔｅｘ（実施例１３）、１．７ｄｔｅｘ（比較例７）、２．８ｄｔｅｘ（比較例８）、また総目付が４０ｇ／ｍ2におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例１４）、１．２ｄｔｅｘ（実施例１５）、１．７ｄｔｅｘ（比較例９）、２．８ｄｔｅｘ（比較例１０）と変化させた。
同様に、ＭＢ不織布層の目付を４ｇ／ｍ2とし、ＳＭＳ構造体の総目付が１７ｇ／ｍ2におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例１６）、１．２ｄｔｅｘ（実施例１７）、１．５ｄｔｅｘ（実施例１８）、１．７ｄｔｅｘ（比較例１１）、２．８ｄｔｅｘ（比較例１２）、また総目付が５０ｇ／ｍ2におけるＳＢ不織布層の繊度を０．９ｄｔｅｘ（実施例１９）、１．２ｄｔｅｘ（実施例２０）、１．７ｄｔｅｘ（比較例１３）、２．８ｄｔｅｘ（比較例１４）と変化させ、それぞれの毛羽等級が４．０級になるよう圧着温度を調整し採取した布により、強力値、耐水圧及び表面特性を評価した結果を表１、２、３に示す。
【００１５】
【表１】
【表２】
【表３】
繊度を細くしたＳＭＳ構造体は、繊度を太くしたＳＭＳ構造体に比べて圧着特性が良いため、低温圧着が可能となり、表面特性項目のぬめり感に関してはあまり差が見られなかったが、柔らかさとざらつき感に関しては共に数値は向上し、効果は明らかであった。また、５％モジュラス指数が高くなり、ＭＢ不織布層の形態保持効果が良くなることや、ＳＢ不織布層の繊径を細くすることで繊維密度が大きくなり地合も良くなるため、Ｓｈｏｏｔｉｎｇ Ｅｆｆｅｃｔの影響も受けにくく、特に低目付け領域での耐水性能に関して数値は向上し効果は明らかであった。
【００１９】
【実施例２１、２２、２３、比較例１５】
実施例８と同様の方法でＭＢ不織布層の繊径を１．０μｍ（実施例２１）、１．８μｍ（実施例２２）、２．８μｍ（実施例２３）、６．０μｍ（比較例１５）と変化させ、それぞれの毛羽等級が４．０級になるように圧着温度を調整し採取した布により、強力値、耐水圧及び表面特性を評価した結果を表４に示す。
ＭＢ繊度が５．０μｍを超えても５％モジュラス指数及び柔らかさやざらつき感の特性は殆ど変化しないが、耐水圧値に関しては極端に低下してしまう。
【００２０】
【表４】
【実施例２４、２５、比較例１６】
実施例２と同様の方法でＭＢ不織布層の目付を１ｇ／ｍ2（実施例２４）、２ｇ／ｍ2（実施例２５）、４ｇ／ｍ2（実施例２６）、６ｇ／ｍ2（比較例１６）と変化させ、それぞれの毛羽等級が４．０級になるように圧着温度を調整し採取した布により、強力値、耐水圧値及び表面特性を評価した結果を表５に示す。ＭＢの目付が６ｇ／ｍ2においても、柔らかさやざらつき感を維持することは出来るが、ＳＢ層の割合が低下するため、５％モジュラス指数及び強力値及び、耐水圧値も低下してしまう。
【００２２】
【表５】
【発明の効果】
本発明のポリプロピレン不織布は、従来の不織布（ＳＭＳ）に比べ耐水性が良く、引張強度も大きくまた、柔らかさにも優れており、厚みも薄くなるといった諸特性をバランスよく確保しているため、使い捨てオムツの表面材料、特にサイドギャザーをはじめとして各種用途に好適にかつ経済的に使用でき、また軽量化できることで産廃の削減にもなり環境面においても有用である。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a polypropylene non-woven fabric useful in fields requiring water resistance and at the same time requiring softness and strength, for example, surface materials of sanitary materials, particularly side gathers of disposable diapers.
[0002]
[Prior art]
Conventionally, a laminated structure in which a polypropylene spunbond (hereinafter referred to as “SB”) non-woven fabric or a melt blown non-woven fabric layer is sandwiched by a polypropylene spunbond non-woven fabric layer on the side material of the sanitary material side part, particularly the side gathers of disposable diapers. Body (hereinafter referred to as “SMS”) nonwovens have been used. However, the SB nonwoven fabric alone has poor water resistance, and it is difficult to reduce the weight per unit in preventing urine leakage. In addition, the conventional SMS nonwoven fabric has improved water resistance, but there is a problem that the touch when touching the skin is not so good due to a decrease in strength due to low basis weight and a feeling of stiffness.
[0003]
In the conventional method, when providing a polypropylene spunbonded nonwoven fabric for side gather use, in order to obtain high water resistance, there are methods of increasing the basis weight of the laminate or increasing the basis weight of the MB nonwoven fabric layer or reducing the fineness. However, increasing the weight per unit area of the laminate is inferior in economic efficiency and increases in thickness, making it difficult to make the diaper structure compact, leading to an increase in the amount of waste, which is not preferable in terms of environment.
In addition, the increase in the basis weight of the MB nonwoven fabric layer or the reduction in the basis weight by the method of reducing the fineness can improve the water resistance performance of the MB nonwoven fabric layer, but it is sufficient when the laminated structure with the SB nonwoven fabric layer is used. I was not able to get a good performance.
[0004]
[Problems to be solved by the invention]
An object of this invention is to provide the nonwoven fabric which is excellent in waterproofness and has high softness and tensile strength.
[0005]
[Means for Solving the Problems]
As a result of intensive studies to solve the above problems, the present inventors have made the present invention.
That is, the present invention relates to a polypropylene spunbond (SB) nonwoven fabric having an MFR of 20 to 70 and a fineness of 0.7 to 1.5 dtex , a polypropylene melt blow (MB) having a fine diameter of 1 to 3 μm, and an MFR of 500 to less than 1300. It is a laminated structure in which the MB nonwoven fabric layer is sandwiched between SB nonwoven fabric layers, and the basis weight of the MB nonwoven fabric layer formed by partial thermocompression bonding is 1 g / m 2 or more and 33% or less of the total basis weight, It is a water-resistant nonwoven fabric having a total basis weight of 8 g / m 2 or more and excellent waterproofness and softness that satisfies the range shown in the following formula (1) by 5% modulus index.
5% modulus index ≧ 0.41 (1)
However, 5% modulus index = 5% modulus (N / 3 cm) / weight per unit (g / m 2 )
[0006]
Hereinafter, the present invention will be described in detail.
The polypropylene used in the present invention may be a polymer synthesized by a general Ziegler-Natta catalyst or a polymer synthesized by a single site active catalyst typified by metallocene. Moreover, the polymer which added the polyethylene in polypropylene, and the polymer which added the other additive may be sufficient.
The MFR of the polypropylene fiber constituting the spunbonded nonwoven fabric of the present invention is 20 or more. If it is less than MFR20, when obtaining a fine fiber, it is difficult to spin. Further, stable spinning is possible even at 70 or more, but it is not practical because physical properties such as tensile strength of the fiber are lowered. In general, in order to produce a spunbonded nonwoven fabric having a fine yarn with a fineness of less than 1.5 dtex, a spinning method as disclosed in JP-A-10-292256 is used. However, in the technology disclosed in this patent document, the fineness is close to the limit, and considering the strength and softness, unification of raw materials, and productivity, the spunbond method disclosed in Japanese Patent Application No. 2001-276951, Most suitable for the present invention.
Moreover, MFR of the polypropylene fiber which comprises the melt blown nonwoven fabric of this invention is 500 or more and less than 1300. If it is less than 500, it is difficult to obtain a fine fineness, and if it is 1300 or more, the spinnability deteriorates, which is not preferable.
[0007]
The structure of the laminated nonwoven fabric of the present invention is such that the MB nonwoven fabric layer is laminated on the SB nonwoven fabric layer having a fineness of 0.7 to 1.5 dtex, and the fineness is 0.7 to 1.5 dtex in the same manner from above. It is most preferable that the SB nonwoven fabric layers are laminated and integrated by partial thermocompression bonding, and the fineness of at least one SB layer may be 0.7 to 1.5 dtex. If the MB non-woven fabric layer is covered with the SB non-woven fabric layer, for example, the structure may be multi-layered such as two MB non-woven fabric layers or two SB non-woven fabric layers. By reducing the fine diameter of the SB nonwoven fabric layer, the dispersibility is improved and the fiber opening diameter can be reduced. Therefore, when the MB nonwoven fabric layer is stacked, the MB nonwoven fabric can be prevented from penetrating into the SB nonwoven fabric layer (Shooting Effect). The penetration of the MB non-woven fabric into the SB non-woven fabric layer is not preferable because it causes pinholes and holes when thermocompression-bonded and causes a decrease in water resistance.
[0008]
In order to reduce the fine diameter of the MB nonwoven fabric, it is necessary to reduce the discharge amount per hole, which leads to a decrease in productivity. Further, the amount of hot air must be increased, and spinning becomes unstable due to the occurrence of fly (yarn breakage). Conversely, if the fiber diameter of the MB nonwoven fabric increases, the fiber opening diameter also increases, leading to a decrease in water resistance. Therefore, the fiber diameter range of the MB nonwoven fabric is 1 to 5 μm, preferably 3 μm or less. Range of total basis weight may be at 8 g / m 2 or more, the scope of 10 to 50 g / m 2 is more preferable. The basis weight of the MB nonwoven fabric layer is 1 g / m 2 or more and 33% or less of the total basis weight. If the proportion of the MB nonwoven fabric layer is increased, the water resistance performance of the MB nonwoven fabric layer itself is improved, but the 5% modulus value and strength value are lowered due to the decrease in the basis weight of the SB nonwoven fabric layer, so that the shape retention effect of the MB nonwoven fabric layer is lowered. It is not preferable. Further, if the ratio of the MB nonwoven fabric layer is lowered, it is not preferable because improvement in water resistance cannot be expected so much and the productivity is lowered.
This invention succeeded in obtaining the nonwoven fabric which was excellent in waterproofness, and had high softness and tensile strength by comprising the above laminated bodies.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, an example is given and it demonstrates further.
In addition, the evaluation method of each characteristic is as follows.
(1) Fineness (dtex: Weight of filament 10000 m long is displayed in grams)
Except for 10cm at both ends of the produced non-woven fabric, sample in 1cm square by dividing into 5 equal parts in the CD direction, and measure fiber diameter by 50 points with a microscope, and fiber density of polypropylene is 0.91g / cm3 As a result, the fineness was calculated from the average value (the second decimal place was rounded off).
For the measurement, a high magnification microscope VH-8000 manufactured by Keyence Corporation was used.
[0010]
(2) MFR (melt flow rate)
MFR was determined by measurement according to condition 14 in Table 1 of JIS-K-7210 “Thermoplastic flow test method”, test temperature 230 ° C., test load 21.18N.
(3) Water pressure resistance (mb or 100 Pa)
Except 10cm at both ends of the produced non-woven fabric, sample in 20cm squares for a total of 15 points by dividing into 5 equal parts in the CD direction and 3 equal parts in the MD direction, and measure according to JIS-L-1092 The water pressure resistance was calculated from the average value.
[0011]
(4) Except for 10cm at both ends of the non-woven fabric produced with fluff, it is divided into 5 equal parts in the CD direction, and 25mm x 300mm test specimens are taken in the CD and MD directions, and a fastness tester of the Japan Society for the Promotion of Science is used. The load of the friction element is 200 g, and the friction coefficient on the friction element side is considered to be appropriate for the Linlay cloth-heavy packing No. Using 314 cloth adhesive tape, it was operated 50 times, and the fluff property was graded according to the following criteria, and the fluff grade was determined by the average value of the front and back sides (rounded to the first decimal place).
1.0 grade: The fiber is peeled off so that the test piece is broken.
2.0 grade: As the test piece becomes thinner, the fiber becomes more severed.
Grade 2.5: Hairballs are large and clearly visible, and fibers are starting to float up at multiple locations.
3.0 grade: A clear hairball starts to appear or a plurality of small hairballs are seen.
Grade 3.5: Fluffy enough to start making small pills in one place.
4.0 grade: No fuzz.
[0012]
(5) 5% modulus, 5% modulus index Except for 10cm on both ends of the nonwoven fabric produced, the test was performed in 5 parts in the CD direction and 3 parts in the MD direction to obtain a total of 15 points in the CD and 3cm x 20cm in the MD direction. Samples are sampled, attached to a low-speed extension test type tensile tester with a grasping length of 10 cm, and a load is applied at a tensile rate of 30 cm / min until the test piece breaks. The average value of the strength at the time of 5% elongation of the test piece was determined in the MD and CD directions (rounded to the first decimal place).
The 5% modulus index can be obtained by the following formula.
5% modulus index = 5% modulus [N / 3 cm] / total weight [g / m 2 ]
[0013]
(6) Tensile strength Except 10cm at both ends of the produced nonwoven fabric, sample in 5cm in the CD direction and 3 in the MD direction and sample a test piece of 3cm x 20cm in the CD and MD directions for a total of 15 points. Attach to an extension test type tensile tester with a grasping length of 10 cm, and apply a load at a tensile speed of 30 cm / min until the specimen breaks. The average value of the strength of the test piece at the maximum load was determined in the MD and CD directions (rounded to the first decimal place).
(7) Surface characteristics For the five measurers using the produced non-woven fabric, the three items of softness, slimy feeling, and rough feeling were ranked in three stages (numerical value is good), and the total points for each. (The ranking was evaluated for each same basis weight).
[0014]
Examples 1-20, Comparative Examples 1-14
The fineness of the MB nonwoven fabric layer is 1.8 μm, the basis weight is 1 g / m 2, and the total basis weight of the SMS structure is 13 g / m 2 , the fineness of the SB nonwoven fabric layer is 0.9 dtex (Example 1), 1.2 dtex (implementation) Example 2), 1.5 dtex (Example 3), 1.7 dtex (Comparative Example 1), 2.8 dtex (Comparative Example 2), and the fineness of the SB nonwoven fabric layer with a total basis weight of 17 g / m 2 is 0.9 dtex ( Example 4), 1.2 dtex (Example 5), 1.5 dtex (Example 6), 1.7 dtex (Comparative Example 3), and 2.8 dtex (Comparative Example 4).
Similarly, the basis weight of the MB nonwoven fabric layer is 2 g / m 2 , the fineness of the SB nonwoven fabric layer is 1.2 dtex (Example 7) when the total basis weight of the SMS structure is 10 g / m 2 , and the total basis weight is 13 g / m 2 . The fineness of the SB nonwoven fabric layer is 0.9 dtex (Example 8), 1.2 dtex (Example 9), 1.5 dtex (Example 10), 1.7 dtex (Comparative Example 5), 2.8 dtex (Comparative Example 6). In addition, the fineness of the SB nonwoven fabric layer having a total basis weight of 17 g / m 2 is 0.9 dtex (Example 11), 1.2 dtex (Example 12), 1.5 dtex (Example 13), and 1.7 dtex (Comparative Example 7). ) 2.8 dtex (Comparative Example 8), and the fineness of the SB nonwoven fabric layer with a total basis weight of 40 g / m 2 is 0.9 dtex (Example 14), 1.2 dtex (Example 15), 1.7 dtex (Comparative Example) 9) 2.8 It was changed to dtex (Comparative Example 10).
Similarly, the basis weight of the MB nonwoven fabric layer is 4 g / m 2, and the fineness of the SB nonwoven fabric layer is 0.9 dtex (Example 16) and 1.2 dtex (Example 17) when the total basis weight of the SMS structure is 17 g / m 2 . 1.5 dtex (Example 18), 1.7 dtex (Comparative Example 11), 2.8 dtex (Comparative Example 12), and the fineness of the SB nonwoven fabric layer with a total basis weight of 50 g / m 2 is 0.9 dtex (Example 19). ), 1.2 dtex (Example 20), 1.7 dtex (Comparative Example 13), and 2.8 dtex (Comparative Example 14), and adjusting the crimping temperature so that the respective fluff grades are 4.0 grades. Tables 1, 2 and 3 show the results of evaluating the strength value, the water pressure resistance and the surface characteristics with the cloths made.
[0015]
[Table 1]
[Table 2]
[Table 3]
The SMS structure with finer fineness has better pressure-bonding characteristics than the SMS structure with thicker fineness, so low-temperature pressure bonding is possible, and there is not much difference in the feeling of slimness in the surface characteristic items. Regarding the feeling of roughness, the numerical values were improved and the effect was obvious. In addition, the 5% modulus index is increased, the shape retention effect of the MB nonwoven fabric layer is improved, and the fiber density is increased and the formation is improved by reducing the diameter of the SB nonwoven fabric layer. The numerical value was improved and the effect was clear, especially with respect to the water resistance performance in the low weight area.
[0019]
Examples 21, 22, 23, Comparative Example 15
In the same manner as in Example 8, the diameter of the MB nonwoven fabric layer was 1.0 μm (Example 21), 1.8 μm (Example 22), 2.8 μm (Example 23), 6.0 μm (Comparative Example 15). Table 4 shows the results of evaluation of the strength value, the water pressure resistance and the surface characteristics using the cloths collected by adjusting the pressure bonding temperature so that each fluff grade becomes 4.0 grade.
Even if the MB fineness exceeds 5.0 μm, the 5% modulus index and the characteristics of softness and roughness are hardly changed, but the water pressure resistance is extremely lowered.
[0020]
[Table 4]
Examples 24 and 25, Comparative Example 16
In the same manner as in Example 2, the basis weight of the MB nonwoven fabric layer was 1 g / m 2 (Example 24), 2 g / m 2 (Example 25), 4 g / m 2 (Example 26), 6 g / m 2 (Comparison) Table 5 shows the results of the evaluation of the strength value, the water pressure resistance value, and the surface characteristics by using the cloths obtained by changing the pressure temperature and adjusting the crimping temperature so that each fluff grade becomes 4.0 grade. Even when the basis weight of MB is 6 g / m 2 , the softness and roughness can be maintained, but since the ratio of the SB layer decreases, the 5% modulus index, the strength value, and the water pressure resistance value also decrease.
[0022]
[Table 5]
【The invention's effect】
The polypropylene nonwoven fabric of the present invention has good water resistance compared to the conventional nonwoven fabric (SMS), has a large tensile strength, is excellent in softness, and has a good balance of various properties such as thinning, It is suitable for various uses including surface materials of disposable diapers, especially side gathers, and can be used economically, and can be reduced in weight, thereby reducing industrial waste and is also useful in terms of the environment.
Claims (1)
５％モジュラス指数≧０．４１ ・・・（１）
但し、５％モジュラス指数＝５％モジュラス（Ｎ／３ｃｍ）／目付（ｇ／ｍ2 ）A polypropylene spunbond nonwoven fabric having an MFR of 20 to 70 and a fineness of 0.7 to 1.5 dtex and a polypropylene meltblown nonwoven fabric having a fine diameter of 1 to 3 μm and an MFR of 500 to less than 1300, and the meltblown nonwoven fabric layer is a polypropylene spunbond A laminated structure sandwiched between non-woven fabric layers, and the basis weight of the melt blown non-woven fabric layer integrated by partial thermocompression bonding is 1 g / m 2 or more and 33% or less of the total basis weight, and the total basis weight is 8 g / m 2 or more. A water-resistant nonwoven fabric having excellent water resistance and a softness that satisfies the 5% modulus index shown in the following formula (1).
5% modulus index ≧ 0.41 (1)
However, 5% modulus index = 5% modulus (N / 3 cm) / weight per unit (g / m 2 )
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| DK1980390T4 (en) * | 2006-02-03 | 2017-01-23 | Mitsui Chemicals Inc | Nonwoven laminate, moisture permeable nonwoven laminated sheet material comprising nonwoven laminate and hygiene article using these |
| US8129298B2 (en) | 2006-05-31 | 2012-03-06 | Mitsui Chemicals, Inc. | Nonwoven laminates and process for producing the same |
| MY144778A (en) | 2006-05-31 | 2011-11-15 | Mitsui Chemicals Inc | Nonwoven fabric laminate and production thereof |
| CN102471968B (en) * | 2010-07-13 | 2012-12-19 | 三井化学株式会社 | Nonwoven fabric laminate for expansion molding |
| EP2882585B1 (en) * | 2012-08-13 | 2021-03-31 | The Procter and Gamble Company | Multilayered nonwoven webs with visually distinct bond sites and method of making |
| US11718065B2 (en) | 2013-03-14 | 2023-08-08 | Imertech Sas | Composite structures |
| US20190136426A1 (en) | 2016-05-18 | 2019-05-09 | Fibertex Personal Care A/S | Nonwoven laminate fabric comprising meltblown and spundbond layers |
| CN113677516B (en) * | 2019-03-27 | 2023-07-11 | 三井化学株式会社 | Nonwoven fabric laminate and sanitary article |
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