JP4231469B2 - Fake eyebrow cosmetic - Google Patents
Fake eyebrow cosmetic Download PDFInfo
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- JP4231469B2 JP4231469B2 JP2004247827A JP2004247827A JP4231469B2 JP 4231469 B2 JP4231469 B2 JP 4231469B2 JP 2004247827 A JP2004247827 A JP 2004247827A JP 2004247827 A JP2004247827 A JP 2004247827A JP 4231469 B2 JP4231469 B2 JP 4231469B2
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- Prior art keywords
- eyebrow
- skin
- cosmetic
- pseudo
- dihydroxyacetone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 210000004709 eyebrow Anatomy 0.000 title claims description 56
- 239000002537 cosmetic Substances 0.000 title claims description 33
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical group OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims description 18
- 229940120503 dihydroxyacetone Drugs 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- UQPHVQVXLPRNCX-UHFFFAOYSA-N erythrulose Chemical compound OCC(O)C(=O)CO UQPHVQVXLPRNCX-UHFFFAOYSA-N 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- 230000002618 waking effect Effects 0.000 claims 1
- 210000003491 skin Anatomy 0.000 description 23
- 239000000049 pigment Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 210000004243 sweat Anatomy 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- IEARKITUAGDUHB-UHFFFAOYSA-N 1,1-dihydroxypropan-2-one;1,3-dihydroxypropan-2-one Chemical compound CC(=O)C(O)O.OCC(=O)CO IEARKITUAGDUHB-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 206010040829 Skin discolouration Diseases 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001058 brown pigment Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000035618 desquamation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 210000000245 forearm Anatomy 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- -1 mole Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、顔の眉部分に擬似的な眉形状を付与する、擬似眉形成化粧料に関する。 The present invention relates to a pseudo eyebrow forming cosmetic that imparts a pseudo eyebrow shape to the eyebrows of a face.
顔のメイクアップの一つとして、眉を所望の形状に整える化粧品には、眉墨、アイブロウ、眉マスカラ等と呼ばれる商品が実用化されている。これは、主に黒色ないし茶色系統の顔料を含んだ、粉末状、固形粉末状、液状、ペースト状等の形態で商品化され、所定のチップ、筆等を用い、あるいは鉛筆状として眉形状を描く化粧品である。 As one of facial makeup, products called eyebrow ink, eyebrow, eyebrow mascara and the like have been put into practical use as cosmetics for adjusting the eyebrows into a desired shape. This is commercialized in the form of powder, solid powder, liquid, paste, etc., mainly containing black or brown pigments, using a predetermined tip, brush, etc. Cosmetics to draw.
即ち、使用者が眉部分の地肌に所望の長さ、太さ、濃淡で眉形状を描くことで、本来の眉毛を補い、あるいはそれに代わる眉形状を形成して、美麗な仕上がりを意図するものである。 In other words, the user intends to create a beautiful finish by drawing the eyebrow shape with the desired length, thickness, and shade on the background of the eyebrow part to supplement the original eyebrows or form an alternative eyebrow shape. It is.
しかし、従来のこれらの商品は、本質的に色材を皮膚上に塗布するものであるため、持続性に乏しく、指等の摩擦や、汗、洗顔等により、容易に取れてしまう問題点があった。特に色材として顔料を主成分とした、ペンシル形やプレス成型してパレットに収納するパウダータイプの製品は、仕上がりが自然であるが、摩擦や汗等の水分により化粧落ちしやすく、汗をかきやすい季節や、スポーツ時、水泳時など、形成した眉の維持に悩む場合が多い。 However, these conventional products essentially have a color material applied on the skin, so they have poor sustainability and can be easily removed by finger friction, sweat, face washing, etc. there were. In particular, pencil-type and press-molded powder-type products that have pigments as the main component and are stored in pallets have a natural finish, but they tend to remove makeup due to moisture such as friction and sweat. There are many cases where it is difficult to maintain the formed eyebrows, such as during easy seasons, sports, and swimming.
この問題点を解決するために、汗や皮脂に対してくずれにくいフッ素系のポリマーを用いた化粧料等が提案されているが、先に述べた、スポーツ時、水泳時の定着性は十分でなく、また仕上がりも平板で不自然に見えるという問題点があった。 In order to solve this problem, cosmetics using fluorine-based polymers that are hard to break down against sweat and sebum have been proposed, but the above-mentioned fixability during sports and swimming is sufficient. There was also a problem that the finish looked unnatural with a flat plate.
また、半恒久的な化粧手段として刺青法があるが、施術に痛みを伴うとともに時間もかかり、日常的な化粧で行えるものではない。 In addition, there is a tattoo method as a semi-permanent makeup means, but the treatment is painful and time consuming, and it cannot be performed with daily makeup.
一方、日光や紫外線への暴露を必要とせずに、皮膚を広範囲に、あるいは部分的に日焼け色にする薬剤が知られている。例えば、ジヒドロキシアセトン(DHA)は、皮膚のアミノ酸やケラチンのアミノ基との反応により、塗布部分が黄色ないし茶褐色に着色する性質を利用して、自己着色剤あるいはセルフタンニング剤と呼ばれる商品に応用されている(非特許文献1)。
本発明は、従来のアイブロウ等の持続性に乏しい欠点を解決し、ある程度の期間、形成した眉形状を保持することができる擬似眉形成化粧料を提供する。 The present invention provides a pseudo-eyebrow cosmetic that solves the short-lasting drawbacks of conventional eyebrows and the like, and can maintain the formed eyebrow shape for a certain period of time.
本発明者らは、皮膚成分との反応で塗布部分が染色される化粧料を、所望の部位、形状に塗布することにより、上記の課題が解決されることを見出した。 The present inventors have found that the above-described problems can be solved by applying a cosmetic whose application part is dyed by reaction with a skin component to a desired part and shape.
本発明の擬似眉形成化粧料は、皮膚上に塗布した後、皮膚成分との反応により呈色し、摩擦、汗、洗浄等によっても落ちにくい擬似眉を形成することができる。塗布後数時間で塗布した部分が染色されるので、例えば就寝前に塗布した場合、起床時には所望の眉形状が形成されている。従って、通常のメイクアップを施す前の状態でも、支障なく人前に出ることができる。 The pseudo eyebrow forming cosmetic of the present invention can form a pseudo eyebrow that is applied to the skin and then colored by reaction with skin components, and is difficult to be removed by friction, sweat, washing or the like. Since the applied part is dyed within a few hours after application, for example, when applied before going to bed, a desired eyebrow shape is formed when getting up. Therefore, even in a state before applying normal make-up, it can go out to the public without hindrance.
また、染色は皮膚の浅部にとどまるため、形成された眉形状は、数日から1週間程度で表皮の落屑とともに消失する。したがって、その間は当該眉形状が維持され、実用的に問題のない持続性を示す。この点で、半恒久的な刺青とも異なる利便性を有する。 In addition, since the dyeing stays in the shallow part of the skin, the formed eyebrow shape disappears with the epidermis desquamation within a few days to a week. Therefore, during that time, the eyebrow shape is maintained, and the practically no problem is maintained. In this respect, it has a different convenience from semi-permanent tattoos.
本発明の擬似眉形成化粧料は、塗布部分において皮膚成分と反応して着色する化合物を含有する。かかる化合物としては、例えば、ジヒドロキシアセトン(1,3−ジヒドロキシ−2−プロパノン)やエリトルロース(1,3,4−トリヒドロキシ−2−ブタノン)等のポリヒドロキシケトン類を例示することができ、1種を単独で、又は2種以上を組合わせて用いることができる。特に、ジヒドロキシアセトンが容易に入手でき、皮膚上での発色性にも優れるので好ましい。 The pseudo eyebrow forming cosmetic of the present invention contains a compound that reacts with a skin component and colors in the applied part. Examples of such compounds include polyhydroxy ketones such as dihydroxyacetone (1,3-dihydroxy-2-propanone) and erythrulose (1,3,4-trihydroxy-2-butanone). One species can be used alone, or two or more species can be used in combination. In particular, dihydroxyacetone is preferred because it is readily available and has excellent color development on the skin.
上記の皮膚着色化合物の含有量は、その種類及び化粧料の剤型にもよるが、好ましくは0.1〜100質量%、より好ましくは1〜50質量%である。また、粉末化粧料の場合は10〜50質量%が、液状化粧料の場合は1〜20質量%が好ましい。 Although content of said skin coloring compound is based also on the kind and cosmetics dosage form, Preferably it is 0.1-100 mass%, More preferably, it is 1-50 mass%. Moreover, in the case of powder cosmetics, 10-50 mass% is preferable, and in the case of liquid cosmetics, 1-20 mass% is preferable.
また、ジヒドロキシアセトン自体は白色結晶の化合物であり、そのままでは皮膚成分と反応し難いが、水に溶けることで皮膚成分と反応して発色すると考えられる。このため、水に溶解して用いるとより効果的であるが、粉体のままでも、皮膚上及び空気中の水分により溶解し、皮膚に浸透して発色機能を発揮する。 In addition, dihydroxyacetone itself is a white crystalline compound that hardly reacts with the skin component as it is, but is considered to develop color by reacting with the skin component when dissolved in water. For this reason, it is more effective when used by being dissolved in water, but even if it is in powder form, it is dissolved by moisture on the skin and in the air, penetrates into the skin and exhibits a coloring function.
本発明の擬似眉形成化粧料は、一般的に眉用化粧料として適用できる原料とともに、各種形状の化粧料とすることができる。かかる化粧料は、それ自体は特に着色していないものでもよいが、顔料を含み、それ自体がある程度着色されたものでもよい。また、アイブロウ下地として用いることもできる。 The pseudo eyebrow forming cosmetic of the present invention can be made into various shapes of cosmetics together with raw materials generally applicable as eyebrow cosmetics. Such cosmetics may not be particularly colored per se, but may contain pigments and may be colored to some extent. It can also be used as an eyebrow base.
本発明の擬似眉形成化粧料とともに用いられる顔料としては、黒色酸化鉄、黄色酸化鉄、赤色酸化鉄、酸化チタン、カーボンブラック等の着色顔料、タルク、マイカ、セリサイト等の体質顔料及びパール顔料が挙げられる。 Examples of the pigment used together with the artificial eyebrow cosmetic of the present invention include black iron oxide, yellow iron oxide, red iron oxide, titanium oxide, carbon black and other colored pigments, extenders such as talc, mica and sericite, and pearl pigments. Is mentioned.
本発明の擬似眉形成化粧料をペンシル状にするには、固形油分に少量の液状油分と顔料及び本発明の皮膚染色成分を練り合わせる。ここで固形あるいは液状の油分としては、ステアリン酸、モクロウ、ミツロウ、固形パラフィン、ワセリン、ラノリン、流動パラフィン、ミリスチン酸イソプロピル等が挙げられる。 In order to make the artificial eyebrow forming cosmetic of the present invention into a pencil shape, a small amount of liquid oil and pigment and the skin dyeing component of the present invention are kneaded with the solid oil. Examples of the solid or liquid oil include stearic acid, mole, beeswax, solid paraffin, petrolatum, lanolin, liquid paraffin, and isopropyl myristate.
本発明の擬似眉形成化粧料を粉末固形状とする場合、前記顔料及び本発明の皮膚染色成分に油剤等の少量の結合剤を加え、押し固めるか容器に流し込んで成形する。この場合、筆、チップ、スポンジ等の道具を用いて所望の部位に眉形状を描くことができる。 When the artificial eyebrow forming cosmetic of the present invention is made into a powdered solid, a small amount of a binder such as an oil is added to the pigment and the skin dyeing component of the present invention and pressed or cast into a container for molding. In this case, an eyebrow shape can be drawn on a desired part using tools such as a brush, a tip, and a sponge.
本発明の擬似眉形成化粧料を液状とする場合、水系として、アクリル系ポリマーエマルション等の皮膜形成樹脂を用い、眉そのものを濃く見せることができる。この場合、擬似眉形成化粧料を筆付き容器に充填し、筆を用いて所望の部位に眉形状を描くことができる。 When the pseudo eyebrow forming cosmetic of the present invention is in a liquid state, a film forming resin such as an acrylic polymer emulsion can be used as an aqueous system to make the eyebrows themselves appear dark. In this case, the artificial eyebrow forming cosmetic can be filled in a container with a brush, and the shape of the eyebrow can be drawn at a desired site using a brush.
次に、実施例をあげて本発明を詳しく説明する。 Next, the present invention will be described in detail with reference to examples.
表1に示す組成のアイブロウ下地(実施例1)を常法により調製した。 An eyebrow base (Example 1) having the composition shown in Table 1 was prepared by a conventional method.
表2に示す組成のリキッドアイブロウ(実施例2)を常法により調製した。 A liquid eyebrow (Example 2) having the composition shown in Table 2 was prepared by a conventional method.
表3に示す組成のパウダーアイブロウ(実施例3)を常法により調製した。 Powder eyebrow (Example 3) having the composition shown in Table 3 was prepared by a conventional method.
以上のとおり調製した実施例1〜3の擬似眉形成化粧料の性能を以下の方法により評価した。比較例としては、実施例1のアイブロウ下地のジヒドロキシアセトンを精製水に置き換えたもの(比較例1)を用いた。 The performance of the artificial eyebrow cosmetics of Examples 1 to 3 prepared as described above was evaluated by the following method. As a comparative example, the eyebrow base dihydroxyacetone in Example 1 was replaced with purified water (Comparative Example 1).
1.腕での染色実験:
化粧料を被験者の前腕内側に塗布して染色性を調べる。塗布して放置する時間は、実際の化粧料の使用条件を考慮して1日あたり10時間とし、3日間継続塗布した。塗布による肌色変化、及び塗布中止後の退色変化を、開始前の素肌色との色差(ΔE*)により経時測色した。
1. Staining experiments with arms:
A cosmetic is applied to the inner side of the subject's forearm and examined for staining. The time to apply and leave was set to 10 hours per day in consideration of the actual use conditions of the cosmetics, and was continuously applied for 3 days. The skin color change by application and the color fading change after application stop were measured over time by the color difference (ΔE *) from the bare skin color before the start.
結果は非塗布部位の測定値により素肌色の日間変動分を相殺した値で示す。 A result is shown by the value which offset the daily fluctuation | variation of the bare skin color by the measured value of a non-application part.
2.眉での発色実験:
実施例1のアイブロウ下地を、朝、肌を整えた被験者(女性3名)の眉領域に塗布し、その上から通常のファンデーションその他のメイクアップを施した。塗布時間は被験者のメイク落としまで12時間とし、3日間継続塗布した。以下の基準に従って、塗布開始3日後までの眉地肌の着色変化、及び使用中止後の退色変化を評価した。
2. Coloring experiment with eyebrows:
The eyebrow base of Example 1 was applied in the morning to the eyebrows of subjects (three women) whose skin was conditioned, and a normal foundation or other makeup was applied thereon. The application time was 12 hours until the subject's makeup was removed, and the application was continued for 3 days. According to the following criteria, the color change of the eyebrow skin until 3 days after the start of application and the color change after discontinuation of use were evaluated.
<評価基準>
0:眉の地肌に着色なし。
1:眉の一部にかすかに地肌の着色がわかる。
2:眉全体の地肌の着色がわかる。
3:眉全体の地肌にはっきり着色している。
<Evaluation criteria>
0: No coloring on the background of the eyebrows.
1: The color of the background is faintly seen on part of the eyebrows.
2: The coloring of the background of the entire eyebrows can be seen.
3: The background of the entire eyebrows is clearly colored.
一般的に肌色領域ではΔE*≧1で見た目に色差を認知できるが、表4からわかるように実施例1〜3の化粧料はいずれも塗布3日以内で見た目にはっきりわかる肌の色変化が起こり、中止後7日後には塗布前の肌色に戻っている。 In general, in the skin color region, the color difference can be recognized visually by ΔE * ≧ 1, but as can be seen from Table 4, all the cosmetics of Examples 1 to 3 have a clearly visible skin color change within 3 days of application. Occurs and returns to the skin color before application 7 days after discontinuation.
表5に示すように、実際に眉部位に塗布しても、眉の地肌に着色が起こり、塗布中止5日後で退色した。 As shown in Table 5, even when actually applied to the eyebrows, coloring occurred on the background of the eyebrows, and the color faded 5 days after the application was stopped.
Claims (6)
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JP2004247827A JP4231469B2 (en) | 2004-08-27 | 2004-08-27 | Fake eyebrow cosmetic |
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KR101490700B1 (en) * | 2008-04-30 | 2015-02-11 | (주)아모레퍼시픽 | Self tanning Eye Make-up Composition Comprising Film former |
DE102008052520A1 (en) * | 2008-10-21 | 2010-04-22 | Cognis Ip Management Gmbh | Cosmetic and / or pharmaceutical preparations |
JP6813165B2 (en) * | 2016-07-26 | 2021-01-13 | ピアス株式会社 | Pseudo eyebrow forming cosmetics |
KR101922470B1 (en) * | 2017-02-08 | 2018-11-28 | 코스맥스 주식회사 | Self tanning Eye Make-up composition |
JP6195402B1 (en) * | 2017-03-17 | 2017-09-13 | ウィントレーディング株式会社 | Eyebrows formation method |
CN113974300B (en) * | 2021-10-27 | 2024-03-26 | 娇时日化(杭州)股份有限公司 | Eyebrow pencil and preparation method thereof |
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BE588291A (en) * | 1959-03-09 | |||
FR2085208B1 (en) * | 1970-02-05 | 1973-10-19 | Oreal | |
FR2673103B1 (en) * | 1991-02-22 | 1993-07-02 | Oreal | COMBINATION OF DIHYDROXYACETONE AND DISUBSTITUTED INDOLIC DERIVATIVES FOR GIVING SKIN COLOR SIMILAR TO NATURAL TANNING, COLORING PROCESS AND AGENTS. |
JPH0867611A (en) * | 1994-08-30 | 1996-03-12 | Mieko Wanibuchi | Liquid eyebrow |
FR2725998B1 (en) * | 1994-10-25 | 1996-11-29 | Oreal | NOVEL COMPOUNDS IN THE FORM OF 5,6-DIHYDROXYINDOLE POLYMER, PROCESS FOR THEIR PREPARATION AND CONPOSITIONS COMPRISING THE SAME |
CA2282699C (en) * | 1997-03-05 | 2007-09-18 | Pentapharm Ag | Combination of erythrulose and a reducing sugar with self-browning properties |
JP3065033U (en) * | 1999-04-09 | 2000-01-28 | 正樹 後藤 | Eyebrow and eyeliner cosmetics that are difficult to remove |
JP2002161024A (en) * | 2000-11-24 | 2002-06-04 | Chemiprokasei Kaisha Ltd | Composition for eyebrow |
JP4518683B2 (en) * | 2001-02-20 | 2010-08-04 | 三菱鉛筆株式会社 | Eyebrow cosmetics |
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