JP4167380B2 - Method and apparatus for manufacturing hot-dip galvanized steel wire for outdoor exposure - Google Patents
Method and apparatus for manufacturing hot-dip galvanized steel wire for outdoor exposure Download PDFInfo
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- JP4167380B2 JP4167380B2 JP2000091898A JP2000091898A JP4167380B2 JP 4167380 B2 JP4167380 B2 JP 4167380B2 JP 2000091898 A JP2000091898 A JP 2000091898A JP 2000091898 A JP2000091898 A JP 2000091898A JP 4167380 B2 JP4167380 B2 JP 4167380B2
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【0001】
【発明の属する技術分野】
本発明は、建築用部材、護岸工事用部材、魚網、フェンス等の屋外で暴露して使用する表面に高摩擦性を有する模様付鋼線の製造方法とこの模様を付与するための表面加工装置を備えた溶融亜鉛めっき鋼線の製造装置に関するものである。めっき鋼線としては、金網用鉄線、橋梁用ワイヤ、PWSワイヤ、PC鋼線。ロープ等のめっき鋼線、ねじ、ボルト、スプリング等の機械部品用めっき鋼線である。
【0002】
【従来の技術】
めっき鋼線としては、亜鉛めっき鋼線や、これよりも耐食性に優れた亜鉛−アルミニウム合金めっき鋼線が使用されている。この亜鉛−アルミニウム合金めっき鋼線は、一般に鋼線を洗浄、脱脂等により清浄化処理し、次いで、フラックス処理を行った後、第一段として亜鉛を主体とする溶融めっきを施し、次いで、第二段としてAl添加量10%のZn−Al合金浴にて溶融めっきするか、または、直接Al添加量10%のZn−Al合金浴でめっきし、次いで、めっき浴から垂直に引き上げて、冷却後、巻取る方法で製造されている。そして、前述した製造方法に使用される設備構成は、めっき鋼線を供給する装置、めっき合金を溶解し所定の温度に保持するめっき浴装置、めっき浴中に鋼線を通過させ取り出す通線装置、めっき浴から出てきた鋼線を冷却する冷却装置、および鋼線を巻取る巻取り装置から構成されているが、製造されためっき鋼線の表面状態は光沢性を有し、かつ滑らかであり摩擦性を有するものではない。
【0003】
前述した製造方法および設備上の問題点は、前述したように、製造されためっき鋼線の表面状態は光沢性を有し、かつ滑らかであり一般的な用途に用いられるものである。このための製造設備としては、表面の滑らかさを維持するために、めっき浴から出てきた鋼線を冷却する冷却装置において、冷却の目的のみからホース状ノズルで冷却水をめっき後の凝固状態にあるめっき鋼線表面に注水する構造を有するように設計されている。このように製造されためっき鋼線の表面は滑らかで光沢を有している。
【0004】
また、従来より各種の溶融亜鉛めっき鋼線が製造されているが、これらの鋼線は機能性を重視することに終始し、金属光沢を有するため、周囲の美観を長年にわたって損なう。環境に優しく、美観性を配慮した審美観を有する鋼線は製造されていないのが現状である。
【0005】
【発明が解決しようとする課題】
本発明は、溶融亜鉛合金めっき鋼線において、耐食性および加工性に優れ、めっき合金層に割れ、剥離が起きず、かつ表面に高摩擦性を有する模様付鋼線の製造方法とこの模様を付与するための模様付与装置を備えた溶融亜鉛めっき鋼線の製造装置を提供することを目的とする。
【0006】
【課題を解決するための手段】
本発明は、溶融亜鉛めっきされた鋼線のめっき層表面に、長手方向、横方向および/または斜め方向に連続して刻印した点または線状の高摩擦性凹凸幾何学模様を有することを特徴とする屋外暴露用溶融亜鉛めっき鋼線の製造方法であり、その製造装置としては、溶融めっき鋼線を製造する装置において、めっき合金を溶解し所定の温度に保持するめっき浴装置、めっき浴中に鋼線を通過させ取り出す通線装置、めっき浴から鋼線を取り出す際にめっき表面の酸化を防止する断気装置、めっき浴から出てきた鋼線を冷却する冷却装置、めっきされた鋼線表面に高摩擦性模様を付与する機械的手段による表面加工装置、および鋼線を巻取る巻取り装置を連続的に配置して構成したことを特徴とする屋外暴露用溶融亜鉛めっき鋼線製造装置であり、より具体的構成としては、溶融めっき鋼線を製造する装置において、めっき鋼線を供給する装置、めっき合金を溶解し所定の温度に保持するめっき浴装置、めっき浴中に鋼線を通過させ取り出す通線装置、めっき浴から鋼線を取り出す際に、めっき鋼線をめっき合金浴から引き上げる部分を窒素ガス、アルゴンガス、炭酸ガスのいずれか1種または2種以上の混合ガスによりパージすることによりめっき合金浴表面およびめっき鋼線の酸化を防止する断気装置、めっき浴から出てきた鋼線にノズルから直接水流当てるか、或いは霧状の水を噴霧することにより250℃以下に連続的に冷却する冷却装置、めっきされた鋼線表面に高摩擦性模様を付与する機械的手段による表面加工装置、および鋼線を巻取る巻取り装置を連続的に配置して構成したことを特徴とする屋外暴露用溶融亜鉛めっき鋼線製造装置、である。
【0007】
【発明の実施の形態】
以下に本発明の実施の形態について説明する。
図1は、本発明にかかる溶融亜鉛めっき鋼線製造装置の概略構成図である。図1において、被めっき鋼線Sは、オンライン或いはオフラインで製造された線径4〜6mmの圧延鋼線が巻戻しリール1から巻戻されて、或いは純亜鉛めっき、亜鉛−アルミめっき、フラックス処理等のプレメッキが施され、鋼線表面に合金層を形成させるために前処理が行われる。この前処理装置2から搬送されてメッキラインに単線或いは複数線が並列して送給される。次いで、この鋼線は450〜470℃の温度に維持されためっき浴3を収容する溶融亜鉛めっき浴槽4内に導かれ溶融亜鉛めっき処理される。この時のめっきラインスピードは約10〜100m/minであり、実操業では約50m/minでめっきされる。
【0008】
上記めっき処理が施されためっき鋼線Sは、めっき浴出側で断面が筒状或いは矩形状を有するめっき鋼線の長手方向に平行な箱型の断気装置5内を通過する。この断気装置5は、めっき鋼線をめっき合金浴から引き上げる部分を窒素ガス、アルゴンガス、炭酸ガスのいずれか1種または2種以上の混合ガスによりパージすることによりめっき合金浴表面およびめっき鋼線の酸化を防止するために設けるのもであり、本発明においては必須の構成装置である。また、この断気装置5では前記混合ガスをガス供給源(図示せず)から任意の圧力で送られ、めっきされた鋼線表面に吹きつけられるが、この混合ガス吹きつけにより鋼線温度は約430〜450℃まで冷却される。また、この断気装置5の下端部はめっき浴に浸漬された状態に配置されることが好ましい。
【0009】
前記断気装置5を通過しためっき鋼線Sは、次いで冷却装置6に導かれ、250℃以下の温度に冷却される。冷却方法としては、複数のノズルから直接水流をかける方法、複数の水スプレーノズルまたは複数の空気と水の混合ノズルによりミスト状態の水滴をめっき鋼線に連続的にかけることで行われる。これら複数のノズルは、めっき鋼線円周に対向する位置に規則的に間隔を設けて配置されるか、または千鳥状に配置される。亜鉛めっき合金は連続的に冷却された場合、250℃近傍で変態を起こし、変態点以上で加工した場合には変態時にめっきの割れや剥離が発生する。それを避けるためには、めっき温度を250℃以下に冷却することが必要である。
【0010】
これに対して従来のめっき鋼線の冷却装置においては、表面状態の平滑性を維持して商品価値を高めるために、冷却装置内に任意の数だけ設けた水道ホース状の比較的太く、大量の冷却水が間断なく表面で凝固状態にあるめっき鋼線表面に付与される。そのために、めっき鋼線表面は均一に冷却作用を受けて平滑な表面状態に維持されることにある。このようにして製造されためっき鋼線は前述した摩擦性が要求される建築用部材、護岸工事用部材、魚網、フェンス等の屋外で暴露して使用する用途には使用できないことになる。
【0011】
このようにして冷却されためっき鋼線は、ブライダルロール7等の旋回手段により所定の搬送ラインに導かれる。次いで、高摩擦性を有する模様を付与する機械的手段による表面加工装置8により、審美観を備えた各種模様が付与される。この模様は、鋼線表面に凹凸を有する幾何学的模様、或いは製造メーカーのサービスマーク等、また使用環境に応じた各種マーク、キャラクターマーク等の鋼線表面に凹凸を有する模様で、それらが高摩擦性の条件を満たしていれば良い。典型的には、前記表面加工装置8の構成は、一対の内表面または外表面に各種模様を有する凹凸模様付割り型ロール、または一対の凹凸模様付ロール等により多少の圧下率を付与しながら鋼線の通線速度に応じた速度で連続的に刻印可能な構成を有している。本発明においては、鋼線の長手方向、横方向および/または斜め方向に連続する点または線状態の幾何学模様を付与して高摩擦性を付与することが簡便で、かつコスト面でも有利であるので、前記幾何学模様を採用して製造した。
【0012】
このようにして付与された高摩擦性を有する模様付溶融亜鉛めっき鋼線は、巻取りリール9にて巻き取られて製品化される。
なお、本発明のめっき組成としては、純亜鉛の他に特許第2732398号公報に記載されたZn−Al合金、特願平11−302685号明細書に記載されたZn−Al−Mg合金など亜鉛合金めっきにも適用可能である。
【0013】
【実施例】
<実施例1>
鋼線材JIS G 3505 SWRM6の4mm径の鋼線にプレメッキとして純Znめっきを行った。めっき合金として10質量%のAlを含むZnを溶解し、450℃でめっき合金を溶解しためっき浴に鋼線を搬送速度50m/minで通線させ、窒素ガスを使用した断気筒、水スプレーによる冷却装置、ロールによる表面加工装置を経由してめっき鋼線を製造した。
【0014】
ロール表面には予め溝を加工しておき、めっき鋼線をその間に通線することで表面に模様を転写した。ロールには、一方向に平行に溝を加工したもの、編み目を加工したもの、模様を加工したもの等を用意した。また、向きが異なる一方向に平行に溝を加工したものを2つ組み合わせることで編目状の模様を作成することができる。
【0015】
得られためっき鋼線について、一定荷重をかけたゴムとの摩擦係数を線の長手方向に平行な向きに測定した。表1にその測定結果を示す。比較例である従来のめっき鋼線の摩擦係数を1とした場合に、本発明による実施例のめっき鋼線は高い摩擦力を示した。
【0016】
【表1】
【0017】
【発明の効果】
以上説明したように、本発明は、建築用部材、護岸工事用部材、魚網、フェンス等の屋外で暴露して使用する高摩擦性めっき鋼線を極めて簡素化した設備により高摩擦性を有する模様付溶融亜鉛めっき鋼線を量産することが可能になる。
【図面の簡単な説明】
【図1】本発明による溶融亜鉛めっき鋼線製造装置の概略構成を示す図である。
【図2】(a)は従来の表面加工を施さないめっき鋼線であり、(b)、(c)、(d)は本発明による模様付鋼線の一例を示す図である。
【図3】本発明による模様付ロール配置の一例を示す図である。
【符号の説明】
1…巻戻しリール
2…前処置装置
3…めっき浴
4…めっき槽
5…断気装置
6…冷却装置
7…ブライダルロール
8…模様付与装置
9…巻取りリール[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method of manufacturing a patterned steel wire having high friction on the surface used by exposing outdoors such as building members, revetment members, fish nets, fences, etc., and a surface processing apparatus for imparting this pattern The present invention relates to a hot-dip galvanized steel wire manufacturing apparatus. As the plated steel wire, iron wire for wire mesh, wire for bridge, PWS wire, PC steel wire. These are plated steel wires such as ropes and plated steel wires for machine parts such as screws, bolts and springs.
[0002]
[Prior art]
As the plated steel wire, a galvanized steel wire or a zinc-aluminum alloy plated steel wire that is more excellent in corrosion resistance is used. This zinc-aluminum alloy-plated steel wire is generally cleaned by cleaning, degreasing, etc., then flux-treated, and then hot-plated mainly with zinc as the first stage, Hot-dip plating in a Zn-Al alloy bath with 10% Al addition as two stages or plating directly with a Zn-Al alloy bath with 10% Al addition and then pulling up vertically from the plating bath and cooling After that, it is manufactured by a winding method. And the equipment configuration used in the manufacturing method described above is an apparatus for supplying a plated steel wire, a plating bath apparatus for melting a plating alloy and maintaining it at a predetermined temperature, and a wiring apparatus for passing the steel wire through the plating bath and taking it out. The cooling device for cooling the steel wire coming out of the plating bath, and the winding device for winding the steel wire, but the surface state of the manufactured plated steel wire is glossy and smooth. There is no friction.
[0003]
As described above, the above-described problems in the manufacturing method and equipment are that the surface state of the manufactured plated steel wire is glossy, smooth, and used for general purposes. As a manufacturing facility for this purpose, in order to maintain the smoothness of the surface, in the cooling device that cools the steel wire coming out of the plating bath, the cooling water is solidified after plating with a hose-like nozzle only for the purpose of cooling. It is designed to have a structure for pouring water on the surface of the plated steel wire. The surface of the plated steel wire thus produced is smooth and glossy.
[0004]
In addition, various hot dip galvanized steel wires have been manufactured conventionally. However, these steel wires have always been focused on functionality, and have a metallic luster, so that the surrounding aesthetics are impaired for many years. The current situation is that no steel wire has been manufactured that is environmentally friendly and has an aesthetic that takes aesthetics into consideration.
[0005]
[Problems to be solved by the invention]
The present invention provides a method for producing a patterned steel wire that has excellent corrosion resistance and workability in a hot dip galvanized steel wire, does not crack or peel off in the plated alloy layer, and has high friction on the surface. It aims at providing the manufacturing apparatus of the hot dip galvanized steel wire provided with the pattern provision apparatus for doing.
[0006]
[Means for Solving the Problems]
The present invention is characterized in that the surface of a plated layer of a hot-dip galvanized steel wire has a point or linear high frictional uneven geometric pattern engraved continuously in the longitudinal direction, the lateral direction and / or the oblique direction. The method of manufacturing a hot-dip galvanized steel wire for outdoor exposure is as follows. In the device for manufacturing a hot-dip galvanized steel wire, a plating bath device that melts the plating alloy and maintains it at a predetermined temperature. A wire passing device that allows the steel wire to pass through, a gas isolator that prevents oxidation of the plating surface when the steel wire is removed from the plating bath, a cooling device that cools the steel wire coming out of the plating bath, and a plated steel wire A hot-dip galvanized steel wire manufacturing apparatus for outdoor exposure, comprising a surface processing device using mechanical means for imparting a high friction pattern on the surface and a winding device for winding the steel wire. And More specifically, in an apparatus for producing a hot-dip plated steel wire, an apparatus for supplying the plated steel wire, a plating bath apparatus for melting the plating alloy and maintaining it at a predetermined temperature, and passing the steel wire through the plating bath and taking it out When the steel wire is taken out from the plating device and the plating bath, the portion where the plated steel wire is pulled up from the plating alloy bath is purged with a mixed gas of one or more of nitrogen gas, argon gas and carbon dioxide gas Air-separation device for preventing oxidation of plating alloy bath surface and plating steel wire, water flow directly from nozzle to steel wire coming out of plating bath, or sprayed with mist-like water continuously at 250 ° C or below A cooling device for cooling, a surface processing device by mechanical means for imparting a highly frictional pattern to the surface of the plated steel wire, and a winding device for winding the steel wire are continuously arranged. Exposed outdoors for galvanized steel wire manufacturing apparatus characterized by the a.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below.
FIG. 1 is a schematic configuration diagram of a hot-dip galvanized steel wire manufacturing apparatus according to the present invention. In FIG. 1, a steel wire S to be plated is obtained by rolling a rolled steel wire having a diameter of 4 to 6 mm, which is manufactured online or offline, from a rewinding reel 1, or pure zinc plating, zinc-aluminum plating, flux treatment. Pre-plating is performed, and pretreatment is performed to form an alloy layer on the surface of the steel wire. A single line or a plurality of lines are conveyed in parallel from the pretreatment device 2 and fed to the plating line. Next, this steel wire is introduced into a hot dip galvanizing bath 4 containing a plating bath 3 maintained at a temperature of 450 to 470 ° C. and subjected to hot dip galvanizing treatment. The plating line speed at this time is about 10 to 100 m / min, and plating is performed at about 50 m / min in actual operation.
[0008]
The plated steel wire S subjected to the above-described plating treatment passes through a box-shaped air isolator 5 parallel to the longitudinal direction of the plated steel wire having a cylindrical or rectangular cross section on the plating bath exit side. The air-separation device 5 is configured to purge the plated steel wire from the plating alloy bath by purging the plating alloy bath surface and the plated steel with one or more mixed gases of nitrogen gas, argon gas and carbon dioxide gas. It is provided to prevent the oxidation of the wire, and is an indispensable constituent device in the present invention. Further, in the gas isolator 5, the mixed gas is sent from a gas supply source (not shown) at an arbitrary pressure, and blown onto the plated steel wire surface. Cool to about 430-450 ° C. Moreover, it is preferable to arrange | position the lower end part of this air isolation apparatus 5 in the state immersed in the plating bath.
[0009]
The plated steel wire S that has passed through the air separation device 5 is then guided to the
[0010]
On the other hand, in the conventional cooling device for plated steel wire, in order to maintain the smoothness of the surface state and increase the commercial value, a relatively large and large amount of water hose-like provided in any number in the cooling device The cooling water is applied to the surface of the plated steel wire in a solidified state on the surface without interruption. For this purpose, the surface of the plated steel wire is uniformly cooled and maintained in a smooth surface state. The plated steel wire produced in this way cannot be used for applications that are exposed outdoors such as building members, revetment members, fish nets, fences and the like that require the above-described friction.
[0011]
The plated steel wire thus cooled is guided to a predetermined transport line by a turning means such as the bridal roll 7. Next, various patterns having an aesthetic appearance are imparted by the surface processing apparatus 8 using mechanical means for imparting a pattern having high friction properties. This pattern is a geometric pattern with irregularities on the surface of the steel wire, or a service mark of the manufacturer, etc., or a pattern with irregularities on the surface of the steel wire such as various marks and character marks according to the usage environment. What is necessary is just to satisfy the conditions of friction. Typically, the configuration of the surface processing apparatus 8 is such that a pair of concave / convex pattern split rolls having various patterns on the inner surface or outer surface, or a pair of concave / convex pattern rolls and the like, while giving a certain rolling reduction. It has a configuration that can be continuously engraved at a speed corresponding to the wire speed of the steel wire. In the present invention, it is simple and advantageous in terms of cost to impart a high-friction property by imparting a geometric pattern of points or lines that are continuous in the longitudinal direction, lateral direction and / or oblique direction of the steel wire. So, it was manufactured using the geometric pattern.
[0012]
The high-friction patterned hot-dip galvanized steel wire thus imparted is wound up by the take-up reel 9 to be commercialized.
The plating composition of the present invention includes zinc, zinc-alloy described in Japanese Patent No. 2732398, and Zn-Al-Mg alloy described in Japanese Patent Application No. Hei 11-302585. It can also be applied to alloy plating.
[0013]
【Example】
<Example 1>
Pure Zn plating was performed as a pre-plating on a 4 mm diameter steel wire of steel wire JIS G 3505 SWRM6. As a plating alloy, Zn containing 10% by mass of Al is dissolved, and a steel wire is passed at a conveyance speed of 50 m / min in a plating bath in which the plating alloy is dissolved at 450 ° C. A plated steel wire was manufactured via a cooling device and a surface processing device using a roll.
[0014]
Grooves were processed in advance on the roll surface, and a pattern was transferred to the surface by passing a plated steel wire between them. Rolls were prepared in which grooves were processed parallel to one direction, in which stitches were processed, in which patterns were processed. Further, a stitch-like pattern can be created by combining two grooves processed in parallel in one direction different in direction.
[0015]
About the obtained plated steel wire, the friction coefficient with the rubber which applied the fixed load was measured in the direction parallel to the longitudinal direction of the wire. Table 1 shows the measurement results. When the friction coefficient of the conventional plated steel wire as a comparative example was set to 1, the plated steel wire of the example according to the present invention showed a high frictional force.
[0016]
[Table 1]
[0017]
【The invention's effect】
As described above, the present invention is designed to have high frictional properties due to extremely simplified equipment for high-friction plated steel wire used by exposing outdoors such as building members, revetment members, fish nets, and fences. It becomes possible to mass produce hot-dip galvanized steel wires.
[Brief description of the drawings]
FIG. 1 is a diagram showing a schematic configuration of a hot-dip galvanized steel wire manufacturing apparatus according to the present invention.
FIG. 2 (a) is a conventional plated steel wire that is not subjected to surface treatment, and FIGS. 2 (b), (c), and (d) are diagrams showing an example of a patterned steel wire according to the present invention.
FIG. 3 is a diagram showing an example of a patterned roll arrangement according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Rewinding reel 2 ... Pretreatment apparatus 3 ... Plating bath 4 ... Plating tank 5 ... Air-
Claims (5)
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JP2000091898A JP4167380B2 (en) | 2000-03-29 | 2000-03-29 | Method and apparatus for manufacturing hot-dip galvanized steel wire for outdoor exposure |
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JP2000091898A JP4167380B2 (en) | 2000-03-29 | 2000-03-29 | Method and apparatus for manufacturing hot-dip galvanized steel wire for outdoor exposure |
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JP2001279416A JP2001279416A (en) | 2001-10-10 |
JP4167380B2 true JP4167380B2 (en) | 2008-10-15 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109760222A (en) * | 2019-01-16 | 2019-05-17 | 镇江耐丝新型材料有限公司 | A kind of semiconductor slice cutting steel wire and preparation method thereof |
Families Citing this family (6)
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JP5005888B2 (en) * | 2005-03-24 | 2012-08-22 | 旭テックTdm株式会社 | Production method of metal products |
CN109280869A (en) * | 2018-08-29 | 2019-01-29 | 广州倬粤动力新能源有限公司 | The processing method of zinc silk |
JP7339531B2 (en) | 2019-11-29 | 2023-09-06 | 日本製鉄株式会社 | Hot dip plated steel sheet |
JP7328541B2 (en) | 2019-11-29 | 2023-08-17 | 日本製鉄株式会社 | Hot dip plated steel sheet |
KR20220084134A (en) * | 2019-11-29 | 2022-06-21 | 닛폰세이테츠 가부시키가이샤 | hot dip galvanized steel |
CN112708841B (en) * | 2021-03-26 | 2021-06-11 | 山东大业股份有限公司 | Tire bead steel wire processing equipment with high plating solution utilization rate |
-
2000
- 2000-03-29 JP JP2000091898A patent/JP4167380B2/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109760222A (en) * | 2019-01-16 | 2019-05-17 | 镇江耐丝新型材料有限公司 | A kind of semiconductor slice cutting steel wire and preparation method thereof |
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