JP4159200B2 - Golf ball - Google Patents

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Publication number
JP4159200B2
JP4159200B2 JP27036099A JP27036099A JP4159200B2 JP 4159200 B2 JP4159200 B2 JP 4159200B2 JP 27036099 A JP27036099 A JP 27036099A JP 27036099 A JP27036099 A JP 27036099A JP 4159200 B2 JP4159200 B2 JP 4159200B2
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Japan
Prior art keywords
cover layer
white
layer
golf ball
additive
Prior art date
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Expired - Fee Related
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JP27036099A
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Japanese (ja)
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JP2001087423A (en
Inventor
路彦 杉浦
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Yokohama Rubber Co Ltd
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Yokohama Rubber Co Ltd
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Priority to JP27036099A priority Critical patent/JP4159200B2/en
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Publication of JP4159200B2 publication Critical patent/JP4159200B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は、ゴルフボールに関し、更に詳しくは最外カバー層を光輝性添加剤を配合した透明カバー層とし、近くでは白色ボールとの識別性に優れ、遠くからでは白く見え、しかもファッション性の高い耐久性の良好なゴルフボールに関する。
【0002】
【従来の技術】
ゴルフボールは、通常、白色に着色されたものが多く使用されているが、白色であることにより遠くからでもよく見分けられる視認性の良さといった利点を有する反面、自己のボールと他人のボールとの識別性の悪さといった欠点を持っていた。このため、白色以外に着色された所謂カラーボールも一部で使用されているが、カラーボールは濃い色合いのものが多く、白色ボールに比べファッション性はあるものの、ゴルファーがアドレスした時違和感を感じるといった使用時の視覚的使い易さの点で不具合があった。
【0003】
こうした欠点を改善すべく、例えば、特開平10−155937号公報では、ボールの色調を明度Lと色相、彩度を表す色座標a、bの値を規定することにより、上述のアドレスした時の構え難さや視覚的違和感を改善するあるいはボールの識別性を向上させる試みがなされている。この試みにより、確かに上記欠点の改善、向上が図られているものの、十分満足されたとは言えず更なる改善、向上の余地があった。
【0004】
また、実開昭61−82657号公報では、カバー層表面に白色ペイント層を被覆し、次いで、強反射性微粉末および蛍光増白剤を含有する反射層である塗膜を被覆することにより、光の中での輝きを持たせて、球筋がよく見える等の視認性の更なる改良がなされている。しかし、この場合、反射層が最外層を形成する非常に薄いクリヤー層のすぐ下の層に設けられていてゴルフボール表面に近く、しかも10〜40μmと薄層であるため、クラブで打撃された際に反射層が傷つき易く剥脱し易いといった耐久性に問題があった。
【0005】
以上のように、ゴルフボールに求められる視覚的諸性能とその耐久性を十分に、しかもバランスよく併せ持ったゴルフボールはこれまでなく、その開発が望まれていた。
【0006】
【発明が解決しようとする課題】
このため、本発明は、白色ボールに近い使用時の視覚的使い易さを保持するとともに、近くでは白色ボールとの識別性に優れ、遠くからでは白く見えて視認性のよい視覚的諸性能とその耐久性を有するゴルフボールを提供するとともに、従来にも増してファッション性の高いゴルフボールを提供することを目的とする。
【0007】
【課題を解決するための手段】
本発明は、前記目的を達成するため、1層以上のカバー層を有するゴルフボールにおいて、最外カバー層を粒度が0.1〜1.0mmの金属鏡面加工粉末からなる光輝性添加剤を配合した透明カバー層とし、その下に白色のカバー層又はコア層を配すると共に、前記最外カバー層において、透明樹脂100重量部に対し前記光輝性添加剤をA重量部配合した場合、前記最外カバー層の厚さをBmmとすると、A×Bが0.38〜0.76重量部・mmとなり、前記最外カバー層の厚さが0.5〜3.0mmであることを特徴とするゴルフボールを提供する。
【0010】
【発明の実施の形態】
本発明の透明カバー層に使用する樹脂としては、アイオノマー樹脂、ウレタン系樹脂、エステル系樹脂等が例示されるが、通常カバー材料として使用されしかも透明性があるものであれば差し支えない。透明カバー層の厚さは、0.5〜3.0mmであるのが好ましい。厚さが0.5mm未満ではクラブの打撃による破損等耐久性が懸念され、また、3.0mmを超えると飛距離に悪影響を及ぼす恐れがあるからである。なお、該カバー層には、上記樹脂のほかに透明性を阻害しないかぎり、酸化防止剤、紫外線吸収剤、紫外線安定剤等の公知の添加剤を配合することができる。
【0011】
前記透明カバー層に続く下層がカバー層である場合には、カバー材は通常用いるものでよい。また、透明カバー層に続く下層がコア層である場合も、同様に、通常用いるコア材でよい。しかし、色は、共に白色であることを必須とする。白色とするには、例えば二酸化チタンのような白色顔料を添加すればよい。白色とするのは、透明カバー層を通して見た時ボールがより鮮明に白く見えるようにするためである。
【0012】
本発明に使用する光輝性添加剤とは、アルミニウム、ニッケル、ステンレス、鉄、銅、銀等の金属を鏡面加工し光輝性と反射性能を良くした粉末(A)例示される。このような粉末としては、例えば、粉末(A)ではダイヤ工業(株)製「ダイヤモンドピースH」等とし入手可能である。また、ボールの識別性を向上させるために任意の色に着色することもできる。
【0013】
前記光輝性添加剤の形状は特に規定する必要はないが、粒度が0.1〜1.0mmであることが望ましい。粒度が0.1mm未満では、近くでの識別性が弱くなってしまい好ましくなく、また1.0mm超では白色性に悪影響を及ぼすとともに視覚的違和感を与えるため好ましくない。
【0014】
前記光輝性添加剤は、透明樹脂100重量部に対し該光輝性添加剤をA重量部配合した場合、カバー層の厚さをBとすると、A×Bが0.38〜0.76重量部・mmとなるように配合する前記A×Bを0.38〜0.76重量部・mmとすることで、十分な識別効果が得られるとともに、遠望した時鮮明な白に見え、また、使用時の視覚的違和感を抑えられる。
【0015】
以上のような構成とするため、クラブで打撃された場合、前述した反射層である塗膜に強反射性微粉末を配合したボールのような該反射層が、極めてボール表面に近く、しかも非常に薄い層であると傷つき易く剥脱し易いのに対し、本発明では、光輝性添加剤を0.5〜3.0mmの厚さをもつ透明カバー層中に配合し点在させることから、光輝性添加剤が剥脱することなく、かかる視覚的効果はボールが使用されている間常に維持される等非常に耐久性の優れたゴルフボールとなる。
【0016】
更に、透明カバー層に前記光輝性添加剤を配合することにより、いろいろな色彩をもつ粉末が点在するゴルフボールとすることもでき、従来にない豊かなファッション性を付与することができる。
【0017】
本発明の光輝性添加剤を配合した透明カバー層は、例えば、透明樹脂および他の配合剤と前記光輝性添加剤を所定量計量した後、通常の混練機、例えば一軸あるいは二軸混練機等を用いて混練し、一旦ペレットとし、続いて射出成型機により、白色のコア層又はカバー層上に被覆する。
【0018】
【実施例】
以下、実施例によって本発明を具体的に説明するが、本発明はこれらに限られるものではない。
【0019】
評価に供したゴルフボールは、ポリブタジエンからなるコア層に、射出成形機を用いて表1に示す配合内容(重量部)により、中間層(下層カバー)を、続いて、最外層(最外カバー)を被覆した後、透明塗料(クリヤー層)を塗装した。なお、光輝性添加剤は、アルミニウムを鏡面加工した後着色処理した青色粉末を用いた。
【0020】
ボールの評価方法は、下記の通りとした。
【0021】
白色ボールとの識別性:ゴルファーにより目視にて白色ボールと比較した。
【0022】
遠くからの見え方:ゴルファーにより50m離れた位置から目視にて次のような基準で評価した。白色に近いほど視認性に優れる。
【0023】
遠くからの見え方
1 白色に見える
2 殆ど白色に見える
3 青白色に見える
視覚的使い易さ:ゴルファーによりアドレスした時の視覚的違和感を次のような基準で評価した。
【0024】
アドレスした時の視覚的違和感
◎ 違和感を感じない
○ 殆ど違和感を感じない
× 違和感を感じる
【0025】
【表1】

Figure 0004159200
【0026】
表1から明らかなように、本発明のゴルフボールは白色ボールとの識別性が良好であり、遠くからの見え方では白色ボールと同様の白さに見え視認性も良好であった。また、使用時の視覚的使い易さについても満足できるものであった。
【0027】
【発明の効果】
本発明のゴルフボールは、白色ボールに近い使用時の視覚的使い易さを保持するとともに、近くでは白色ボールとの識別性に優れ、遠くからでは白く見えて視認性がよく、更に、光輝性添加剤を配合した層の耐久性に優れ、しかも従来にも増してファッション性の高いものである。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a golf ball. More specifically, the outermost cover layer is a transparent cover layer containing a glittering additive, which is excellent in distinguishability from a white ball in the vicinity, looks white from a distance, and has high fashionability. The present invention relates to a golf ball having good durability.
[0002]
[Prior art]
Many golf balls are usually colored in white. However, the white golf ball has the advantage of good visibility that can be easily distinguished from a distance. It had drawbacks such as poor identification. For this reason, so-called color balls that are colored in addition to white are also used in some areas, but color balls are often darker and more fashionable than white balls, but feel uncomfortable when addressed by golfers. There was a problem in terms of visual ease of use.
[0003]
In order to remedy these drawbacks, for example, in Japanese Patent Application Laid-Open No. 10-155937, the color tone of the ball is defined by the values of the color coordinates a and b representing the lightness L, hue, and saturation. Attempts have been made to improve difficulty in holding and visual discomfort, or to improve ball discrimination. Although this attempt has steadily improved and improved the above-mentioned drawbacks, it has not been fully satisfied and there is room for further improvement and improvement.
[0004]
In Japanese Utility Model Laid-Open No. 61-82657, a white paint layer is coated on the surface of the cover layer, and then a coating that is a reflective layer containing a highly reflective fine powder and a fluorescent brightening agent is coated. Further improvement of visibility has been made, such as giving the brilliance in the light and seeing the spherical muscles well. However, in this case, since the reflective layer is provided in a layer immediately below the very thin clear layer forming the outermost layer and is close to the surface of the golf ball and is a thin layer of 10 to 40 μm, it was hit with a club. At this time, there was a problem in durability that the reflective layer was easily damaged and easily peeled off.
[0005]
As described above, there has never been a golf ball having a sufficient balance of visual performance and durability required for a golf ball, and the development thereof has been desired.
[0006]
[Problems to be solved by the invention]
For this reason, the present invention maintains visual ease of use when used close to that of a white ball, and is excellent in distinguishability from a white ball in the vicinity, and has various visual performances that appear white and visible from a distance. An object of the present invention is to provide a golf ball having durability, and to provide a golf ball having higher fashion than ever before.
[0007]
[Means for Solving the Problems]
In order to achieve the above object, in the present invention, in a golf ball having one or more cover layers, the outermost cover layer is blended with a glittering additive composed of a metal mirror-finished powder having a particle size of 0.1 to 1.0 mm. When the white cover layer or the core layer is disposed under the transparent cover layer, and when the bright additive is blended in an amount of A part by weight with respect to 100 parts by weight of the transparent resin in the outermost cover layer, When the thickness of the outer cover layer is Bmm , A × B is 0.38 to 0.76 parts by weight / mm, and the thickness of the outermost cover layer is 0.5 to 3.0 mm. Provide a golf ball.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Examples of the resin used in the transparent cover layer of the present invention include ionomer resins, urethane resins, ester resins, and the like. However, any resin that is usually used as a cover material and has transparency may be used. The thickness of the transparent cover layer is preferably 0.5 to 3.0 mm. If the thickness is less than 0.5 mm, there is a concern about durability such as breakage due to the impact of the club, and if it exceeds 3.0 mm, the flight distance may be adversely affected. In addition to the above resin, the cover layer may contain known additives such as an antioxidant, an ultraviolet absorber, and an ultraviolet stabilizer as long as the transparency is not impaired.
[0011]
When the lower layer subsequent to the transparent cover layer is a cover layer, the cover material may be a usual one. Moreover, when the lower layer following a transparent cover layer is a core layer, the core material used normally may be used similarly. However, it is essential that the colors are both white. In order to obtain white, for example, a white pigment such as titanium dioxide may be added. The reason for the white color is to make the ball look clearer and white when viewed through the transparent cover layer.
[0012]
Examples of the glittering additive used in the present invention include powder (A) in which a metal such as aluminum, nickel, stainless steel, iron, copper, and silver is mirror-finished to improve the glitter and reflection performance. Such powders, for example, is available as a powder (A) in Diamond Industrial Co., Ltd., "Diamond-piece H" and the like. Moreover, in order to improve the distinguishability of a ball | bowl, it can also color in arbitrary colors.
[0013]
The shape of the glittering additive need not be specified, but it is desirable that the particle size is 0.1 to 1.0 mm. If the particle size is less than 0.1 mm, the discrimination in the vicinity is weak, which is not preferable, and if it exceeds 1.0 mm, the whiteness is adversely affected and visually uncomfortable.
[0014]
In the case where the glittering additive is blended with A part by weight of the glittering additive with respect to 100 parts by weight of the transparent resin, when the thickness of the cover layer is B, A × B is 0.38 to 0.76 parts by weight.・ Blend to be mm . By setting the A × B to 0.38 to 0.76 parts by weight / mm, it is possible to obtain a sufficient discrimination effect, a clear white when viewed from a distance , and a visual discomfort during use. .
[0015]
Because of the above-described structure, when hit with a club, the reflective layer such as a ball in which a highly reflective fine powder is mixed with the above-described coating film, which is the reflective layer, is very close to the ball surface. In the present invention, the glittering additive is blended in the transparent cover layer having a thickness of 0.5 to 3.0 mm, and the glittering additive is scattered. Such a visual effect is always maintained while the ball is in use without causing the exfoliation additive to exfoliate, resulting in a golf ball having excellent durability.
[0016]
Furthermore, by blending the glittering additive in the transparent cover layer, it is possible to obtain a golf ball in which powders having various colors are scattered, and it is possible to impart an unprecedented rich fashionability.
[0017]
The transparent cover layer blended with the glittering additive of the present invention is prepared, for example, after measuring a predetermined amount of the transparent resin and other blending agents and the glittering additive, and then a normal kneader, such as a uniaxial or biaxial kneader. Are then used to form pellets, which are then coated on a white core layer or cover layer by an injection molding machine.
[0018]
【Example】
EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto.
[0019]
The golf ball subjected to the evaluation was prepared by using an injection molding machine to add a middle layer (lower layer cover) to the core layer made of polybutadiene, followed by the outermost layer (outermost cover). After coating, a transparent paint (clear layer) was applied. The glittering additive used was a blue powder that was color-treated after mirror-finishing aluminum.
[0020]
The ball evaluation method was as follows.
[0021]
Distinguishing from white ball: visually compared with white ball by golfer.
[0022]
Visibility from a distance: The golf ball was visually evaluated from the position 50 m away by the following criteria. The closer to white, the better the visibility.
[0023]
How to see from a distance 1 Appears white 2 Appears almost white 3 Appears blue-white Ease of use: Visual discomfort when addressed by a golfer was evaluated according to the following criteria.
[0024]
Visual discomfort when addressing ◎ No discomfort ○ Almost discomfort × Feeling discomfort [0025]
[Table 1]
Figure 0004159200
[0026]
As is clear from Table 1, the golf ball of the present invention had good discrimination from the white ball, and when viewed from a distance, it looked as white as the white ball and had good visibility. Moreover, it was satisfactory also about the visual ease of use at the time of use.
[0027]
【The invention's effect】
The golf ball of the present invention retains the visual ease of use when used close to that of a white ball, is excellent in distinguishability from a white ball in the vicinity, looks white and has good visibility from a distance, and has a glittering property. The layer containing the additive is excellent in durability and more fashionable than ever.

Claims (2)

1層以上のカバー層を有するゴルフボールにおいて、最外カバー層を粒度が0.1〜1.0mmの金属鏡面加工粉末からなる光輝性添加剤を配合した透明カバー層とし、その下に白色のカバー層又はコア層を配すると共に、前記最外カバー層において、透明樹脂100重量部に対し前記光輝性添加剤をA重量部配合した場合、前記最外カバー層の厚さをBmmとすると、A×Bが0.38〜0.76重量部・mmとなり、前記最外カバー層の厚さが0.5〜3.0mmであることを特徴とするゴルフボール。In the golf ball having one or more cover layers, the outermost cover layer is a transparent cover layer in which a glittering additive composed of a metal mirror-finished powder having a particle size of 0.1 to 1.0 mm is blended, and a white layer is formed thereunder When arranging the cover layer or the core layer and blending A part by weight of the glittering additive with respect to 100 parts by weight of the transparent resin in the outermost cover layer, when the thickness of the outermost cover layer is Bmm, A golf ball, wherein A × B is 0.38 to 0.76 parts by weight / mm, and the thickness of the outermost cover layer is 0.5 to 3.0 mm. 前記光輝性添加剤を任意の色に着色した請求項1に記載のゴルフボール。  The golf ball according to claim 1, wherein the glittering additive is colored in an arbitrary color.
JP27036099A 1999-09-24 1999-09-24 Golf ball Expired - Fee Related JP4159200B2 (en)

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