JP4136831B2 - Functional water - Google Patents

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JP4136831B2
JP4136831B2 JP2003273544A JP2003273544A JP4136831B2 JP 4136831 B2 JP4136831 B2 JP 4136831B2 JP 2003273544 A JP2003273544 A JP 2003273544A JP 2003273544 A JP2003273544 A JP 2003273544A JP 4136831 B2 JP4136831 B2 JP 4136831B2
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functional water
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清紀 渡邉
徹 奥村
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清紀 渡邉
斎久工業株式会社
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Description

本発明は、溶解性、浸透性などの水の機能を高め、その効果を持続せしめた機能水に関するものである。   The present invention relates to functional water that enhances the function of water such as solubility and permeability and maintains its effect.

従来、水の機能を高めるには、水素イオン濃度を調節したり、界面活性剤を溶解したり、油溶水溶両性の物質を混合したりして行う化学的な方法が一般的であって、水そのものの機能と言うよりは、添加物質の機能の助けを利用する技術が主体であった。また、物質を水に溶解して、水溶液として利用するプロセスは工業的にしばしば行われるが、このようなプロセスでは、熱エネルギによって、溶解度を上昇させたり、攪拌によって物質移動の速度を速めたりすることが常法として採用される。攪拌の範疇に入る物理的なプロセス手法として近年では、超音波振動を利用することも行われている。その他水に不溶な有機物質を、生物化学的に除去若しくは溶解して、分離する方法も行われている。   Conventionally, in order to enhance the function of water, chemical methods are generally performed by adjusting the hydrogen ion concentration, dissolving the surfactant, or mixing the oil-soluble water-soluble amphoteric substance, Rather than the function of water itself, it was mainly technology that used the help of the function of the additive substance. In addition, a process of dissolving a substance in water and using it as an aqueous solution is often carried out industrially. In such a process, the solubility is increased by thermal energy, or the speed of mass transfer is increased by stirring. It is adopted as a conventional method. In recent years, ultrasonic vibration has also been used as a physical process technique that falls into the category of stirring. In addition, organic substances that are insoluble in water are also biochemically removed or dissolved to separate them.

一方、近年化学物質によらない、水の機能を高める技術が種々開示されている。例えば、特許文献1には通水管のまわりに磁気ブロックを流れ方向に位置と角度を順次ずらして配設、若しくは通水管のまわりに無誘導巻型コイルで発生する波動を照射した磁気ブロックを4個以上配設して、水を通過させ磁化水とすると、洗浄効果のすぐれた水とすることができるとある。   On the other hand, various techniques for enhancing the function of water that do not depend on chemical substances have been disclosed in recent years. For example, in Patent Document 1, a magnetic block is arranged around a water pipe with a position and an angle being sequentially shifted in the flow direction, or four magnetic blocks irradiated with a wave generated by a non-inductive winding coil around the water pipe. If one or more of them are arranged and water is passed through to obtain magnetized water, it is possible to obtain water having an excellent cleaning effect.

また、特許文献2では、排水処理のプロセスで、排水にマイクロ波、低周域の超音波及び高周域の電磁超音波を照射して排水の浮遊物を分離し且つ脱臭を行う液体の処理方法が開示されている。   Further, in Patent Document 2, in the process of wastewater treatment, a process of liquid that separates floating wastewater and deodorizes by irradiating the wastewater with microwaves, low-frequency ultrasonic waves, and high-frequency electromagnetic ultrasonic waves. A method is disclosed.

また、特許文献3では、廃棄物中のダイオキシン等の難分解物質をヒドロオキシルラジカル存在下で酸化分解するにあたり、廃棄物の水分散系スラリを前もって電磁波処理、磁場処理をすることで、界面活性剤添加と同様な効果を出させるようにしている。   Further, in Patent Document 3, in order to oxidize and decompose hardly decomposable substances such as dioxins in waste in the presence of hydroxyl radicals, surface treatment is performed by subjecting the waste water dispersion slurry to electromagnetic treatment and magnetic field treatment in advance. The same effect as adding the agent is produced.

特開平11−165178号公報JP-A-11-165178 特開平11−90420号公報JP-A-11-90420 特開2002−273369公報JP 2002-273369 A

しかしながら、特許文献1の方法では、磁場通過中若しくは通過直後の水は文献記載の効果を有するかもしれないが、例えば、その水を容器にいれて持ち運んだりすることにより時間が経過すれば、与えられたエネルギの放出に伴い、いずれその効果は消滅する。特許文献2若しくは特許文献3の方法においても、プロセスの中での処理方法であって、機能を有する水そのものを生産できるわけではない。   However, in the method of Patent Document 1, water during or immediately after passing through a magnetic field may have the effect described in the literature. For example, if the water passes in a container and is carried, the water is given. With the release of the energy, the effect will eventually disappear. The method of Patent Document 2 or Patent Document 3 is also a treatment method in the process, and cannot produce water having a function itself.

従って、本発明はかかる従来技術の問題に鑑みてなされたもので、溶解性、浸透性などの水の機能を持続的に保持する機能水を提供することを目的とする。   Accordingly, the present invention has been made in view of the problems of the prior art, and an object of the present invention is to provide functional water that continuously maintains the functions of water such as solubility and permeability.

そこで、かかる課題を解決するために、本発明は、溶解性、浸透性などの水の機能を持続的に保持する機能水であって、該機能水のゼータ電位の絶対値を20mVから60mVの範囲に処理したことを特徴とする。すなわち、機能水のゼータ電位の絶対値が20mVより低ければ、目的の機能が発現せず、60mVより高いときには、あたかも電解質を溶解したような様相となり、目的とする温和な機能からかけ離れる。   Therefore, in order to solve such a problem, the present invention is a functional water that continuously maintains the functions of water such as solubility and permeability, and the absolute value of the zeta potential of the functional water is 20 mV to 60 mV. It is characterized by being processed into a range. That is, if the absolute value of the zeta potential of the functional water is lower than 20 mV, the target function is not expressed.

更に、本発明の機能水は、前記ゼータ電位の絶対値が、シリカコロイド存在下に処理され、該機能水は該シリカコロイドを含んでいることを特徴とする。ゼータ電位を発現させるのはコロイドの表面電荷であり、この電荷の存在により水の分子構造を左右するエネルギ源が持続すると考えられる。   Furthermore, the functional water of the present invention is characterized in that the absolute value of the zeta potential is treated in the presence of a silica colloid, and the functional water contains the silica colloid. It is the surface charge of the colloid that develops the zeta potential, and the presence of this charge is thought to sustain the energy source that governs the molecular structure of water.

更に、本発明の機能水は、前記シリカコロイドの粒子の前記機能水中における濃度が1000個/cm〜20000個/cmであることを特徴とする。いわゆるエネルギを担う担体の密度がこの範囲にあるのが好ましいことが、本発明により経験的に見出された。 Furthermore, the functional water of the present invention is characterized in that the concentration of the silica colloid particles in the functional water is 1000 / cm 3 to 20000 / cm 3 . It has been empirically found according to the invention that the density of the so-called energy carrier is preferably in this range.

更に、本発明の機能水は、一つの軸芯に、巻回数及び巻径が厳密に同一で、左右巻回方向の異なるように巻回された一対のコイルに、同一位相の交番電流を、互いに正逆方向に流し、発生する電磁波の波形分布空域内に、シリカ微粒子を分散させた水を通過させて、前記ゼータ電位の絶対値を上げたことを特徴とする。前記したコイルで発生する特殊な電磁波は、縦波で構成されると考えられ、本発明の機能水を生産するにあたって、ゼータ電位の絶対値を上げる方法において、前記特殊な電磁波を水に照射するステップが特に重要な要件であって、通常の磁場を通過させるのみでは本発明の機能水が持つ機能は得られない。   Furthermore, in the functional water of the present invention, an alternating current having the same phase is applied to a pair of coils wound in such a manner that the number of turns and the winding diameter are exactly the same on one shaft core and are different in the left and right winding directions. The absolute value of the zeta potential is increased by passing water in which silica fine particles are dispersed in the wave distribution airspace of the generated electromagnetic waves flowing in the forward and reverse directions. The special electromagnetic wave generated in the coil is considered to be composed of a longitudinal wave. In producing the functional water of the present invention, water is irradiated with the special electromagnetic wave in the method of increasing the absolute value of the zeta potential. The step is a particularly important requirement, and the function of the functional water of the present invention cannot be obtained only by passing a normal magnetic field.

更に、本発明の機能水は、一本の導線を二つの平行な軸芯に、同一の巻径で8の字状に巻回されたコイルに、交番電流を流し、発生する電磁波の波形分布空域内に、シリカ微粒子を分散させた水を通過させて、前記ゼータ電位の絶対値を上げたことを特徴とする。前記一対のコイルでは、巻回数及び巻径が厳密に同一で、左右巻回方向の異なるように巻回された一対のコイルは製作に手数がかかるが、本発明の一本の導線を二つの平行な軸芯に、同一の巻径で8の字状に巻回されたコイルは比較的容易に製作可能で、コスト的に有利である。   Furthermore, the functional water of the present invention is a waveform distribution of electromagnetic waves generated by passing an alternating current through a coil in which a single conducting wire is wound around two parallel shaft cores and wound in an 8-shape with the same winding diameter. The absolute value of the zeta potential is increased by passing water in which silica fine particles are dispersed in the airspace. In the pair of coils, the number of windings and the winding diameter are exactly the same, and the pair of coils wound so as to be different in the left and right winding directions are troublesome to manufacture. A coil wound on a parallel shaft core in the shape of figure 8 with the same winding diameter can be manufactured relatively easily and is advantageous in terms of cost.

更に、本発明の機能水は、シリカ微粒子を分散させた水を、第一段階で静磁界を通過させて磁化し、第二段階で一つの軸芯に、巻回数が厳密に同一で、左右巻回方向の異なるように巻回された一対のコイルに、同一位相の交番電流を、互いに正逆方向に流し、発生する電磁波の波形分布空域内に、前記第一段階を経た水を通過させて、前記ゼータ電位の絶対値を上げたことを特徴とする。即ち特殊電磁波を照射する前段で通常の磁場を通過させて前処理を施せば、更に機能が向上することを見出した。   Furthermore, the functional water of the present invention magnetizes water in which silica fine particles are dispersed by passing a static magnetic field in the first stage, and in the second stage, the number of windings is exactly the same, A pair of coils wound in different winding directions are supplied with alternating currents having the same phase in the forward and reverse directions, and the water that has undergone the first stage is passed through the waveform distribution airspace of the generated electromagnetic wave. Thus, the absolute value of the zeta potential is increased. In other words, it has been found that if the pretreatment is performed by passing a normal magnetic field before the irradiation with the special electromagnetic wave, the function is further improved.

更に、本発明の機能水は、シリカ微粒子を分散させた水を、第一段階で静磁界を通過させて磁化し、第二段階で一本の導線を二つの平行な軸芯に、8の字状に巻回されたコイルに、交番電流を流し、発生する電磁波の波形分布空域内に、前記第一段階を経た水を通過させて、前記ゼータ電位の絶対値を上げたことを特徴とする。   Furthermore, the functional water of the present invention magnetizes water in which silica fine particles are dispersed by passing a static magnetic field in the first stage, and in the second stage, one conductive wire is formed on two parallel shaft cores. An alternating current is passed through the coil wound in the shape of a letter, and the absolute value of the zeta potential is increased by passing the water that has passed through the first stage into the waveform distribution airspace of the generated electromagnetic wave. To do.

以上記載のごとく本発明の機能水はその、溶解性、浸透性などの水の機能を持続的に保持するという利点がある。   As described above, the functional water of the present invention has the advantage of maintaining the water functions such as solubility and permeability.

以下、図面を参照して本発明の好適な実施例を例示的に詳しく説明する。但しこの実施例に記載されている構成部品の寸法、材質、形状、その相対的配置等は特に特定的な記載がない限りは、この発明の範囲をそれに限定する趣旨ではなく、単なる説明例に過ぎない。   Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the drawings. However, the dimensions, materials, shapes, relative arrangements, and the like of the components described in this embodiment are not intended to limit the scope of the present invention unless otherwise specified, but are merely illustrative examples. Not too much.

図1は、本実施例のプロセスであり、第1段では水(本例では水道水)とシリカとより、既知のシリカコロイド製造プロセスで常法によりシリカコロイド水を製造する。第2段で特殊電磁波を照射して本発明の機能水を製造する。   FIG. 1 shows the process of this embodiment. In the first stage, silica colloid water is produced from water (tap water in this example) and silica by a conventional method using a known silica colloid production process. The functional water of the present invention is produced by irradiating special electromagnetic waves in the second stage.

図2は、特殊電磁波照射装置の主要部分であるコイル3の構造及び結線を示す。図2(A)、(B)において、4は円筒状のカーボンで作られた芯であり、この芯に導線5が図2(A)に示すように、8の字を呈して、巻回されている。このコイル3には、電流調節用抵抗器2を介して、交流電圧1(100V50Hz)が印加され、電流が流される。   FIG. 2 shows the structure and connection of the coil 3 which is the main part of the special electromagnetic wave irradiation apparatus. 2 (A) and 2 (B), 4 is a core made of cylindrical carbon, and the conductor 5 has a figure 8 as shown in FIG. 2 (A). Has been. An AC voltage 1 (100 V, 50 Hz) is applied to the coil 3 via the current adjusting resistor 2, and a current flows.

図3は、機能水を製造するための特殊電磁波発生装置を示す図で、図3(A)がその平面図、図3(B)がその正面図である。前記により製造したコロイド水を入口10より導入し、ポンプ8にて圧送して、処理部7を通過させ、機能水は出口12より取り出される。ポンプ8と処理部7は繋ぎ管11で連結されている。また、ポンプは電動機9により回転駆動される。   FIG. 3 is a diagram showing a special electromagnetic wave generator for producing functional water, FIG. 3 (A) is a plan view thereof, and FIG. 3 (B) is a front view thereof. The colloidal water produced as described above is introduced from the inlet 10, pumped by the pump 8, passed through the processing unit 7, and the functional water is taken out from the outlet 12. The pump 8 and the processing unit 7 are connected by a connecting pipe 11. The pump is driven to rotate by the electric motor 9.

図3(B)を参照して、円筒状の処理部7の下段はマグネットケーシング7Bになっており、その上段は特殊電磁波照射部7Aであって前記したコイル3が、水の流れ方向及び円筒の軸芯を中心とする回転方向に関して、異なった位置に、3個配置されている。   Referring to FIG. 3B, the lower stage of the cylindrical processing unit 7 is a magnet casing 7B, and the upper stage is a special electromagnetic wave irradiation unit 7A. Three are arranged at different positions with respect to the rotation direction around the axis of the.

前記第一段のプロセスで製造したシリカコロイド水を入口10より導入し、ポンプ8により一定流量で処理部7に流した。シリカコロイド水は先ずマグネットケーシング7Bを通過して磁化され、次いで処理部7の特殊電磁波照射部7Aのコイル3に電流が流されて発生する電磁波の波形分布空域内を通過して、機能水として出口12より取り出した。   The silica colloidal water produced in the first stage process was introduced from the inlet 10 and flowed to the processing unit 7 at a constant flow rate by the pump 8. Silica colloidal water first passes through the magnet casing 7B and is magnetized, and then passes through the waveform distribution airspace of the electromagnetic wave generated when a current is passed through the coil 3 of the special electromagnetic wave irradiation unit 7A of the processing unit 7 as functional water. It was taken out from the outlet 12.

図4はこのようにして製造した実施例の機能水(処理水(コロイド水))のゼータ電位を測定したグラフである。測定はシスメックス(株)製のゼータサイザー3000HSDATA type1256によっておこなった。測定は三度行いその平均値として、−27.7mVが得られた。一方、図5は使用した原水(水道水)のゼータ電位を同様にして測定したグラフで、やはり、測定は三度行いその平均値として、−8.1mVが得られた。即ち、機能水のゼータ電位は原水の三倍以上のゼータ電位(絶対値)となった。そしてこの機能水(処理水(コロイド水))は700時間後においても顕著なゼータ電位(絶対値)の減少は観察されなかった。得られた処理水は溶解性、浸透性、殺菌性などの機能を有しており種々の用途、例えば、醸造用水、化粧水、肥料、養魚用水などに利用が考えられる。また、現在試験研究中であるが、有機肥料として近年再び注目を浴びているものの、水溶性に乏しいため、施肥に難点のあるフミンの水溶体の製造に利用が開ける目処もついている。   FIG. 4 is a graph obtained by measuring the zeta potential of the functional water (treated water (colloidal water)) of the example manufactured as described above. The measurement was performed using a Zetasizer 3000 HSDATA type 1256 manufactured by Sysmex Corporation. The measurement was performed three times, and an average value of −27.7 mV was obtained. On the other hand, FIG. 5 is a graph in which the zeta potential of the raw water (tap water) used was measured in the same manner. Again, the measurement was performed three times, and an average value of −8.1 mV was obtained. That is, the zeta potential of the functional water became a zeta potential (absolute value) more than three times that of the raw water. This functional water (treated water (colloidal water)) did not show a significant decrease in zeta potential (absolute value) even after 700 hours. The treated water thus obtained has functions such as solubility, permeability and bactericidal properties, and can be used for various purposes such as brewing water, lotion, fertilizer, and fish farming water. In addition, although it is currently undergoing experimental research, it has recently attracted attention as an organic fertilizer. However, because it is poor in water solubility, there is a possibility that it can be used for the production of a humic water solution that is difficult to fertilize.

以上説明したように、本発明により本来の目的である溶解性、浸透性などの水の機能を持続的に保持する機能水を提供することを可能としたが、本機能水の性質を利用して化粧品、肥料、養魚、醸造などの産業に広く応用がひらけることが、推察される。   As described above, according to the present invention, it is possible to provide functional water that continuously retains water functions such as solubility and permeability that are the original purposes. It is speculated that it can be widely applied to industries such as cosmetics, fertilizer, fish farming and brewing.

本発明の機能水を製造するプロセスフロー図である。It is a process flow figure which manufactures functional water of the present invention. (A)は本発明の機能水を製造するための装置の主要な部分である特殊電磁波発生コイルの平面図、(B)は正面図である。(A) is a top view of the special electromagnetic wave generating coil which is the principal part of the apparatus for manufacturing the functional water of this invention, (B) is a front view. (A)は本発明の機能水を製造するための特殊電磁波発生装置の平面図、(B)は正面図である。(A) is a top view of the special electromagnetic wave generator for manufacturing the functional water of this invention, (B) is a front view. 本発明の実施例で得られた機能水(処理水)のZeta電位の測定値を示したグラフである。It is the graph which showed the measured value of Zeta potential of functional water (treated water) obtained in the example of the present invention. 本発明の実施例で用いた原水(水道水)のZeta電位の測定値を示したグラフである。It is the graph which showed the measured value of Zeta potential of raw water (tap water) used in the example of the present invention.

符号の説明Explanation of symbols

1 100V50Hz電源
2 電流調節用抵抗器
3 コイル
4 芯(カーボン棒)
5 導線
7 処理部
7A 特殊電磁波照射部
7B マグネットケーシング
8 循環ポンプ
9 電動機
10 シリカコロイド水入口
11 繋ぎ管
12 機能水(処理水)出口
1 100V 50Hz power supply 2 Current adjusting resistor 3 Coil 4 Core (carbon rod)
5 Conductor 7 Processing section 7A Special electromagnetic wave irradiation section
7B Magnet casing 8 Circulation pump 9 Electric motor
10 Silica colloid water inlet 11 Connecting pipe 12 Functional water (treated water) outlet

Claims (6)

溶解性、浸透性などの水の機能を持続的に保持する機能水であって、一つの軸芯に、巻回数及び巻径が厳密に同一で、左右巻回方向の異なるように巻回された一対のコイルに、同一位相の交番電流を、互いに正逆方向に流し、発生する電磁波の波形分布空域内に、シリカ微粒子を分散させた水を通過させて、該機能水のゼータ電位の絶対値を20mVから60mVの範囲に処理したことを特徴とする機能水。 It is functional water that continuously maintains the water functions such as solubility and permeability, and is wound around one shaft core so that the number of windings and the winding diameter are exactly the same, and the right and left winding directions are different. a pair of coil, an alternating current of the same phase flowed in forward and reverse directions, the generated electromagnetic wave distribution within the airspace, the silica fine particles is passed through the dispersed water, absolute zeta potential of the functional water it characterized by processing the values from 20mV in the range of 60mV machine Nosui. 溶解性、浸透性などの水の機能を持続的に保持する機能水であって、一本の導線を二つの平行な軸芯に、同一の巻径で8の字状に巻回されたコイルに、交番電流を流し、発生する電磁波の波形分布空域内に、シリカ微粒子を分散させた水を通過させて、該機能水のゼータ電位の絶対値を20mVから60mVの範囲に処理したことを特徴とする機能水。 Coil that continuously retains the functions of water such as solubility and permeability, and is a coil in which a single conductor is wound around two parallel shaft cores in the shape of a figure 8 with the same winding diameter In addition, by passing an alternating current and passing water in which silica fine particles are dispersed in the waveform distribution airspace of the generated electromagnetic wave, the absolute value of the zeta potential of the functional water is processed in the range of 20 mV to 60 mV. It shall be the machine Nosui. 溶解性、浸透性などの水の機能を持続的に保持する機能水であって、シリカ微粒子を分散させた水を、第一段階で静磁界を通過させて磁化し、第二段階で一つの軸芯に、巻回数が厳密に同一で、左右巻回方向の異なるように巻回された一対のコイルに、同一位相の交番電流を、互いに正逆方向に流し、発生する電磁波の波形分布空域内に、前記第一段階を経た水を通過させて、該機能水のゼータ電位の絶対値を20mVから60mVの範囲に処理したことを特徴とする機能水。 Functional water that continuously retains water functions such as solubility and permeability, in which water in which silica fine particles are dispersed is magnetized by passing a static magnetic field in the first stage, Waveform distribution airspace of generated electromagnetic waves by causing alternating currents of the same phase to flow in the forward and reverse directions through a pair of coils wound on the shaft core with exactly the same number of turns and different in the left and right winding directions within the first stage and water is passed through passed through, machine you characterized in that processing the absolute value of the zeta potential of the functional water from 20mV in the range of 60mV Nosui. 溶解性、浸透性などの水の機能を持続的に保持する機能水であって、シリカ微粒子を分散させた水を、第一段階で静磁界を通過させて磁化し、第二段階で一本の導線を二つの平行な軸芯に、8の字状に巻回されたコイルに、交番電流を流し、発生する電磁波の波形分布空域内に、前記第一段階を経た水を通過させて、該機能水のゼータ電位の絶対値を20mVから60mVの範囲に処理したことを特徴とする機能水。 Functional water that continuously maintains the functions of water such as solubility and permeability, in which water in which silica fine particles are dispersed is magnetized by passing a static magnetic field in the first stage, and one in the second stage The two lead wires are parallel to each other, an alternating current is passed through a coil wound in the shape of figure 8, and the water that has passed through the first stage is passed through the waveform distribution airspace of the generated electromagnetic wave, features and to that machine Nosui that the absolute value of the zeta potential of the functional water treated from 20mV in the range of 60 mV. 前記ゼータ電位の絶対値は、シリカコロイド存在下に処理され、該機能水は該シリカコロイドを含んでいることを特徴とする請求項1乃至4いずれかの項記載の機能水。 The functional water according to any one of claims 1 to 4 , wherein the absolute value of the zeta potential is treated in the presence of silica colloid, and the functional water contains the silica colloid. 前記シリカコロイドの粒子の前記機能水中における濃度が1000個/cm〜20000個/cmであることを特徴とする請求項記載の機能水。 The functional water according to claim 5 , wherein the concentration of the silica colloid particles in the functional water is 1000 particles / cm 3 to 20000 particles / cm 3 .
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