JP4114428B2 - Method for manufacturing paper container molded paper - Google Patents

Method for manufacturing paper container molded paper Download PDF

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Publication number
JP4114428B2
JP4114428B2 JP2002222684A JP2002222684A JP4114428B2 JP 4114428 B2 JP4114428 B2 JP 4114428B2 JP 2002222684 A JP2002222684 A JP 2002222684A JP 2002222684 A JP2002222684 A JP 2002222684A JP 4114428 B2 JP4114428 B2 JP 4114428B2
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paper
container
foaming agent
density
low
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JP2004060123A (en
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実 永江
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Toppan Inc
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Toppan Inc
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Description

【0001】
【発明の属する技術分野】
本発明は、紙箱等のカートン、紙カップ、紙製トレー容器、紙パック等の紙製容器成形用紙の製造方法に関する。
【0002】
【従来の技術】
従来の紙カップ等の紙製容器成形用紙には、通常は、カップ原紙が使用されるが、紙カップの保温性や断熱性や手触り感等を考慮した場合は、成形用紙として紙層内部に空気を抱き込んだ発泡タイプの発泡紙が使用される。
【0003】
この発泡紙は、抄紙工程でパルプ材に発泡剤を混入させて抄紙するとともに、この抄紙工程の段階で加熱発泡又は化学発泡処理されたものであり、既に発泡処理された既発泡タイプ(低密度タイプ)の発泡紙であるため、紙カップ成形工程において、皺になり易く、また発泡時の紙粉が多く発生したり、発泡されているために紙面が平滑でなく、そのため印刷適性が良好でないし、また、発泡紙は低密度であるため良好な輸送効率や保管効率が得られない等の問題がある。
【0004】
また、従来の発泡紙としては、抄紙工程でパルプ材に発泡剤を混入させて抄紙して、この抄紙工程の段階では発泡剤が発泡しないように乾燥処理し、その後の段階で加熱発泡処理するようにした後発泡タイプ(混抄タイプ)の発泡紙があるが、抄紙工程で発泡剤を混抄して製造するため、製造ロット毎の抄紙量が大きくなり、また発泡紙の抄紙機専用化が必要になって、少量生産が採算的に困難で、発泡紙供給の小回りが効かないなどの問題がある。
【0005】
【発明が解決しようとする課題】
そこで、既発泡タイプ及び後発泡タイプの従来の発泡紙の上記問題を解決するために、本発明者は、不織布等の低密度の用紙を用いて、それに熱発泡性発泡剤をコーティングし、後に発泡させる後発泡タイプの後発泡コート紙を作成し、その後発泡コート紙を、従来から紙製容器の成形加工に通常使用されているようなコートボールや、カップ原紙、ノーコートアイボリー等の容器成形原紙の片面にラミネートした紙製容器成形用紙を出願した。
【0006】
上記紙製容器成形用紙は、上述したように、熱発泡性発泡剤をコーティングした後発泡コート紙と、コートボール、カップ原紙、ノーコートアイボリー、晒しクラフト、カード紙等の容器成形原紙とをラミネートして製造するものであるが、後発泡コート紙を作成する際に、例えばグラビア塗布方式のように熱発泡性発泡剤を周面に付着供給した塗布ロールとプレスロールとの間に不織布の様な低密度用紙を導入し、一度に低密度用紙面に、その紙坪量と同程度の塗布量をウエットコーティングすると、コーティング面に対して反対面の低密度用紙面にコーティング発泡剤が染み出し、プレスロールやガイドロール等に発泡剤が付着したり、付着した発泡剤が再度紙面に付着して用紙面を汚損したりして良好にコーティングできない場合がある。
【0007】
本発明は、後発泡タイプの後発泡コート紙をラミネートした紙製容器成形用紙の製造において、上記不都合を解消し、ウエットコーティングされた発泡剤がプレスロールやガイドロール等に付着したり、用紙面を汚損したりしないようにすることにある。
【0008】
【課題を解決するための手段】
本発明の請求項1に係る発明は、紙製容器成形用原紙1の片面に耐水・疎水性層3を介して低密度用紙4をラミネートする低密度用紙ラミネート工程と、該低密度用紙4面に発泡剤をコーティングして含浸させる発泡剤コーティング含浸工程とからなることを特徴とする紙製容器成形用紙の製造方法である。
【0009】
本発明の請求項2に係る発明は、低密度用紙4の一面に耐水・疎水性層3を積層接着する耐水・疎水性層形成工程と、該低密度用紙4の他面に発泡剤をコーティングして含浸させる発泡剤コーティング含浸工程と、前記発泡剤をコーティングして含浸させた低密度用紙4を前記耐水・疎水性層3を介して紙製容器成形用原紙1とラミネートする低密度用紙ラミネート工程とからなることを特徴とする紙製容器成形用紙の製造方法である。
【0011】
本発明の請求項に係る発明は、上記請求項1又は請求項に係る紙製容器成形用紙の製造方法において、前記紙製容器成形用原紙1が、コートボール、カップ原紙、晒しクラフト、カード紙、ノーコートアイボリーのいずれか1種である紙製容器成形用紙の製造方法である。
【0012】
本発明の請求項に係る発明は、上記請求項1乃至請求項のいずれか1項に係る紙製容器成形用紙の製造方法において、前記低密度用紙4が、紙密度0.75cm 3 以下であって、不織布、コースター原紙のいずれか1種の用紙である紙製容器成形用紙の製造方法である。
【0013】
【発明の実施の形態】
本発明の紙製容器成形用紙の製造方法の実施の形態を、図1に基づいて以下に詳細に説明すれば、まず、図1(a)に示すように、低密度用紙ラミネート工程において、片面に合成樹脂製の耐水・疎水性層3を塗布又はラミネートした紙製容器成形用原紙1と低密度用紙4とを、耐水・疎水性層3を内面にして重ね合わせ、対向するラミネート用のプレスロール10、11の対向間に導入してラミネートし、紙製容器成形用原紙1と耐水・疎水性層3と低密度用紙4からなる積層シートを形成する。
【0014】
次に、図1(b)に示すように、発泡剤コーティング含浸工程において、前記積層シートを、グラビアコーティング方式にて、供給層12内に循環貯留する発泡剤液7に浸漬して回転するグラビアコーティングロール13とプレスロール15との対向間に導入し、回転する前記グラビアコーティングロール13周面に付着供給される発泡剤液7の余剰液をドクター14にて掻き取りながら、ロール13周面に形成された多数セル凹部13a内に供給された発泡剤液7を前記積層シートの低密度用紙4の外面にコーティングして、低密度用紙4の層内に発泡剤を含浸させるものである。
【0015】
なお、上記発泡剤コーティング含浸工程において用いられるコーティング方式はグラビアコーティング方式に限定されず、ロールコーティング、コンマコーティング、ナイフコーティング等の適宜な方式を採用することができる。
【0016】
これにより、図3に示すように、紙製容器成形用原紙1の片面に、耐水・疎水性層3を介して、低密度用紙4に発泡剤がコーティングされた後発泡コート紙2がラミネートされた紙製容器成形用紙が得られる。
【0017】
原紙1と低密度用紙4とは、エクストルーダー方式にて接着性の加熱溶融樹脂を原紙1面に塗布して耐水・疎水性層3を形成して、エクストルーダーラミネート方式にて加圧にて接着してもよいし、あるいはドライラミネート用接着剤を塗布して耐水・疎水性層3を形成し、加熱加圧してドライラミネート方式にて接着してもよいし、ウエットラミネート用接着剤を塗布して耐水・疎水性層3を形成し、加圧乾燥(溶剤揮散)させてウエットラミネート方式にて接着してもよい。
【0018】
また、本発明の紙製容器成形用紙の製造方法の他の実施の形態としては、図2(a)に示すように、耐水・疎水性層形成工程において、ロールコーティング方式にて、供給層12内に循環貯留する耐水・疎水性層形成用樹脂液3aに浸漬して回転するコーティングロール16とプレスロール17との対向間に、低密度用紙4を導入し、回転する前記ロール16周面に付着供給される耐水・疎水性層形成用樹脂液3aを前記低密度用紙4の片面にコーティングして、耐水・疎水性層3を積層形成する。
【0019】
続いて、図2(b)に示すように、発泡剤コーティング含浸工程において、ロールコーティング方式にて、供給層12内に循環貯留する発泡剤液7に浸漬して回転するコーティングロール18とプレスロール19との対向間に、耐水・疎水性層3を積層形成した低密度用紙4を導入し、回転する前記ロール18周面に付着供給される発泡剤液7を、前記低密度用紙4の耐水・疎水性層3と反対面にコーティングして低密度用紙4の層内に発泡剤を含浸させ、後発泡コート紙2を形成する。
【0020】
続いて、図2(c)に示すように、低密度用紙ラミネート工程において、紙製容器成形用原紙1と前記後発泡コート紙2とを、耐水・疎水性層3を内面にして重ね合わせ、プレスロール10、11の対向間に導入し、耐水・疎水性層3を介してラミネートする。
【0021】
これにより、図3に示すように、紙製容器成形用原紙1の片面に、耐水・疎水性層3を介して、低密度用紙4に発泡剤がコーティングされた後発泡コート紙2がラミネートされた紙製容器成形用紙が得られる。
【0022】
また、本発明の紙製容器成形用紙の製造方法のその他の実施の形態としては、抄紙工程において、紙製容器成形用原紙層1と、耐水・疎水性層3と、低密度用紙層4とを三層抄き合わせして、三層抄合紙を抄紙する。
【0023】
次に、発泡剤コーティング含浸工程において、三層抄合紙の前記低密度用紙層4面に、熱発泡性発泡剤をコーティングして含浸させるものである。
【0024】
これにより、図3に示すように、紙製容器成形用原紙1の片面に、耐水・疎水性層3を介して、低密度用紙4に熱発泡性発泡剤がコーティングされた後発泡コート紙2がラミネートされた紙製容器成形用紙が得られる。
【0025】
本発明方法における前記耐水・疎水性層3は、ポリエチレン、ポリプロピレン等のポリオレフィン系樹脂、ポリエチレンテレフタレート等のポリアミド系樹脂、アクリル系樹脂等の熱可塑性の接着性樹脂が使用され、又はドライラミネート接着剤やウエットラミネート接着剤を用いて塗布量を多くして耐水・疎水性層3としたり、あるいは撥水薬剤を用いて耐水・疎水性層3としてもよく、接着剤層としての作用だけではなく、熱発泡性発泡剤を低密度用紙4の外面側にコーティングした際に、熱発泡性発泡剤が低密度用紙4を浸透して、その内面側に染み出すのを防ぐ作用があり、また紙製容器成形用原紙1面に熱発泡性発泡剤が到達するのを防ぐ作用があり、また、紙製容器の耐水性層や疎水性層として作用する。
【0026】
前記紙製容器成形用原紙1には、通常の紙製容器の成形用原紙として使用されている坪量150g/m2 〜200g/m2 又はそれ以上のコートボール、カップ原紙、ノーコートアイボリー、カード紙、晒しクラフトのいずれか1種又は1種以上が使用できる。
【0027】
また、前記低密度用紙4としては、紙密度が0.75g/cm3 以下、層間剥離強度が300gf/15mm幅以下の不織布、あるいはコースター原紙等が使用できる。
【0028】
本発明方法において作成される後発泡コート紙2の層は、図4に示すように、パルプ不織布等の天然繊維不織布、レーヨン不織布等の化学繊維不織布、あるいはコースター原紙などの低密度用紙4に、熱膨張性マイクロカプセル6(又は化学反応膨張性マイクロカプセル)と、低密度用紙3の繊維5とマイクロカプセル6とを結び付けるアクリル樹脂などのバインダーを配合した発泡剤をコートして含浸させたものである。
【0029】
本発明方法により製造された紙製容器成形用紙は、紙製容器成形原紙1側の面を容器外面側に、後発泡コート紙2側の面を容器内面側にして、従来の紙製容器の成形加工に使用する一般的なコートボール、カップ原紙、ノーコートアイボリー等の紙製容器成形用原紙の成形加工と同様の公知の成形加工により、紙箱、紙カップ、トレー容器、紙パック容器等の紙製容器を成形加工することができる。
【0030】
そして、その後、成形加工された前記紙製容器の後発泡コート紙2の層を、加熱発泡方式(又は化学反応発泡方式)にて発泡処理することにより、後発泡コート紙2の紙層内に膨張性マイクロカプセル6による多数の膨張発泡した中空状の発泡部を発生させて、後発泡コート紙2の厚さが増加した断熱、保温性のある紙製容器が得られる。
【0031】
以下に本発明の紙製容器成形用紙の具体的実施例を説明する。
【0032】
<実施例1>
図1(a)に示すように、低密度用紙ラミネート工程において、紙製容器成形用原紙1として坪量190g/m2 のカップ原紙(日本板紙(株)製)と低密度用紙4として坪量40g/m2 の不織布(KP9340、三和製紙(株)製)とを、その重ね合わせ内面に熱溶融したポリエチレン樹脂を厚さ15μmにて押し出しながら重ね合わせ、プレスロール10、11に導入し、サンドポリエチレンによるエクストルーダーラミネート方式にてラミネートして積層シートを得た。
【0033】
続いて、図1(b)に示すように、発泡剤コーティング含浸工程において、上記積層シートを、グラビアコーティング方式にて、供給層12内に循環貯留する下記組成の発泡剤液7(固形分25%)に浸漬して回転するグラビアコーティングロール13とプレスロール15との対向間に導入し、回転する前記グラビアコーティングロール13周面に付着供給される発泡剤液7の余剰液をドクター14にて掻き取りながら、ロール13周面に形成された多数セル凹部13a内に供給された発泡剤液7を前記積層シートの低密度用紙4の外面に、下記コーティング条件により40g/m2 wet塗布量にてコーティングし、低密度用紙4の層内に発泡剤を含浸させた。
【0034】
その後、発泡剤をコーティング含浸させた上記積層シートを、インラインにてオーブン乾燥機に120℃、20秒間導入して乾燥させて、実施例1による本発明の紙製容器成形用紙を得た。
発泡剤;

Figure 0004114428
コーティング条件;
Figure 0004114428
【0035】
上記実施例1にて作成した本発明の紙製容器成形用紙を用いて、公知の紙カップ成形加工により、紙製容器として紙カップを成形加工し、その紙カップを、オーブンにて140℃、2分間加熱して、紙カップの後発泡コート紙2の層を発泡させて、断熱性のある紙カップを得た。
紙カップの厚み:加熱前 0.3mm
加熱後 1.0mm
【0036】
<実施例2>
耐水・疎水性層形成工程において、低密度用紙4として坪量40g/m2 の不織布(KP9340、三和製紙(株)製)の片面に、エクストルーダーラ方式にて、熱溶融したポリエチレン樹脂を厚さ15μmにて押し出しながらコーティングして、低密度用紙4の片面に耐水・疎水性層3を積層形成した。(図2(a)参照)
【0037】
続いて、図2(b)に示すように、発泡剤コーティング含浸工程において、耐水・疎水性層3を積層形成した上記低密度用紙4を、ロールコーティング方式にて、供給層12内に循環貯留する発泡剤液7に浸漬して回転するコーティングロール18とプレスロール19との対向間に導入し、回転する前記ロール18周面に付着供給される下記組成による発泡剤液7を、前記低密度用紙4の耐水・疎水性層3と反対面に、下記コーティング条件にてコーティングして低密度用紙4の層内に発泡剤を含浸させた。
【0038】
その後、発泡剤をコーティング含浸させた上記低密度用紙4を、インラインにてオーブン乾燥機に120℃、20秒間導入して乾燥させ、後発泡コート紙2を得た。
発泡剤;
Figure 0004114428
コーティング条件;
Figure 0004114428
【0039】
続いて、図2(c)に示すように、低密度用紙ラミネート工程において、紙製容器成形用原紙1として坪量190g/m2 のカップ原紙(日本板紙(株)製)と上記後発泡コート紙2とを、耐水・疎水性層3を内面にして重ね合わせ、耐水・疎水性層3を加熱手段にて加熱溶融しながらプレスロール10、11の対向間に導入し、紙製容器成形用原紙1と後発泡コート紙2とを耐水・疎水性層3を介してラミネートして、実施例2による本発明の紙製容器成形用紙を得た。
【0040】
上記実施例2にて作成した本発明の紙製容器成形用紙を用いて、公知の紙カップ成形加工により、紙製容器として紙カップを成形加工し、その紙カップを、オーブンにて140℃、2分間加熱して、紙カップの後発泡コート紙2の層を発泡させて、断熱性のある紙カップを得た。
紙カップの厚み:加熱前 0.3mm
加熱後 1.0mm
【0041】
<比較例1>
上記実施例2の図2(a)に示す耐水・疎水性層形成工程を省略して、低密度用紙4として坪量40g/m2 の不織布(KP9340、三和製紙(株)製)の片面に、耐水・疎水性層3を積層形成しない不織布を、上記実施例2の図2(b)に示す発泡剤コーティング含浸工程において、ロールコーティング方式にて供給層12内に循環貯留する発泡剤液7に浸漬して回転するコーティングロール18とプレスロール19との対向間に導入し、回転する前記ロール18周面に付着供給される上記実施例2と同様の組成による発泡剤液7を、前記低密度用紙4の片面に上記実施例2と同様のコーティング条件にてコーティングして低密度用紙4の層内に発泡剤を含浸させた。
【0042】
その後、発泡剤をコーティング含浸させた上記低密度用紙4を、インラインにてオーブン乾燥機に120℃、20秒間導入して乾燥させ、比較例1の後発泡コート紙2を得た。
【0043】
続いて、上記実施例2の図2(c)に示す低密度用紙ラミネート工程として、紙製容器成形用原紙1として坪量190g/m2 のカップ原紙(日本板紙(株)製)と、上記発泡剤コーティング含浸工程にて得られた後発泡コート紙2とを、その重ね合わせ内面に耐水・疎水性層3(接着層)として、エクストルーダーラ方式にて熱溶融したポリエチレン樹脂を厚さ15μmにて押し出しコーティングして重ね合わせながら、プレスロール10、11の対向間に導入してラミネートした以外は、上記実施例2と同様にして比較例1の紙製容器成形用紙を得た。
【0044】
上記比較例1にて作成した紙製容器成形用紙を用いて、公知の紙カップ成形加工により、紙製容器として紙カップを成形加工し、その紙カップを、オーブンにて140℃、2分間加熱して、紙カップの後発泡コート紙2の層を発泡させて、断熱性のある紙カップを得た。
紙カップの厚み:加熱前 0.3mm
加熱後 1.0mm
【0045】
<比較例2>
紙製容器成形用紙として、通常紙製容器成形用原紙として使用されている坪量190g/m2 のカップ原紙(日本板紙(株)製)を用いて、公知の紙カップ成形加工により、紙製容器として紙カップを成形加工した。
【0046】
上記実施例1、2の本発明品(後発泡タイプの容器成形用紙及びそれを用いた紙カップ及び発泡後の紙カップ)と、比較例1の後発泡タイプの容器成形用紙及びそれを用いた発泡後の紙カップ)及び比較例2の通常のカップ原紙との比較評価結果を下記表1に示す。○・・・良好 ×・・・不良
【0047】
【表1】
Figure 0004114428
【0048】
【発明の効果】
本発明の紙製容器成形用紙の製造方法は、断熱性や保温性のある紙製容器の成形加工に使用する後発泡タイプのラミネート発泡紙の製法であり、製造される紙製容器成形用紙は、紙カップ、紙トレー容器、紙パック容器など紙製容器の成形工程後において発泡させることができ、紙製容器成形工程においては、通常の容器成形用原紙と同様に成形でき、成形加工適性も良好であって発泡による紙粉の発生もなく成形でき、また成形加工における皺の発生を解消できる効果がある。
【0049】
また、本発明の製造方法により得られる紙製容器成形用紙は、紙製容器成形工程後の発泡処理までは紙面が平滑であり、それまでは印刷適性が良好であり、また発泡処理までは発泡紙は、従来の既発泡タイプの用紙とは異なり比較的高密度であるため、容器成形材料及び半製品としての良好な輸送効率や保管効率が得られる効果がある。
【0050】
また、本発明の製造方法は、後発泡タイプの発泡紙でありながら、ラミネート方式とコーティング方式により製造でき、ラミネート方式の場合、抄紙工程でパルプ材に発泡剤を混入する工程が省略でき、したがって製造ロット毎の抄紙量が大きくならず小ロット生産に対応でき、採算的に見合う少量生産が可能であり、発泡紙の供給小回りが効くという効果があり、断熱性能や手触り感の良好な紙製容器の成形加工用の成形用紙の製法として効果的である。
【図面の簡単な説明】
【図1】本発明の紙製容器成形用紙の製造方法の一例を説明する側面図。
【図2】本発明の紙製容器成形用紙の製造方法の他の例を説明する側面図。
【図3】本発明の紙製容器成形用紙の製造方法により得られた紙製容器成形用紙の積層断面図。
【図4】本発明の紙製容器成形用紙の製造方法により発泡剤をコートした後発泡コート紙の層内構造を説明する側断面模式図。
【符号の説明】
1…紙製容器成形用原紙 2…後発泡コート紙 3…耐水・疎水性層
4…低密度紙 5…パルプ繊維6…発泡性マイクロカプセル 7…発泡剤液[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing a paper container-molded paper such as a carton such as a paper box, a paper cup, a paper tray container, or a paper pack.
[0002]
[Prior art]
Conventionally, cup base paper is used for paper container molding paper such as conventional paper cups.However, in consideration of the heat retention, heat insulation, touch feeling, etc. of paper cups, air is formed inside the paper layer as molding paper. A foam-type foam paper that is embraced is used.
[0003]
This foamed paper is made by mixing a foaming agent into a pulp material in the papermaking process, and is heat-foamed or chemically foamed at the stage of the papermaking process. Type) foamed paper, which is prone to wrinkles in the paper cup molding process, and a lot of paper powder is generated at the time of foaming, and because it is foamed, the paper surface is not smooth, so printability is not good. Moreover, since foamed paper has a low density, there is a problem that good transportation efficiency and storage efficiency cannot be obtained.
[0004]
Also, as conventional foamed paper, paper is made by mixing a foaming agent with pulp material in the papermaking process, and in this papermaking process, the foaming agent is dried so as not to foam, and then heated and foamed in the subsequent stage. After that, there is foaming type (mixed paper type) foamed paper, but since the foaming agent is mixed and manufactured in the papermaking process, the amount of papermaking for each production lot becomes large, and it is necessary to dedicate foamed paper to a paper machine As a result, there are problems such as that small-scale production is profitably difficult, and that the supply of foamed paper does not work.
[0005]
[Problems to be solved by the invention]
Therefore, in order to solve the above-mentioned problems of the conventional foamed paper of the pre-foamed type and the post-foamed type, the present inventor used a low-density paper such as a nonwoven fabric and coated it with a heat-foamable foaming agent. After foaming, create foam-type post-foamed coated paper, and then form the foam-coated paper into containers such as coated balls, cup base paper, and uncoated ivory that are conventionally used for molding paper containers. An application was filed for a paper container molded paper laminated on one side of the base paper.
[0006]
As described above, the paper container-molded paper is laminated with a foam-coated paper coated with a heat-foamable foaming agent and container-formed base paper such as coated balls, cup base paper, uncoated ivory, bleached craft, and card paper. However, when creating post-foamed coated paper, for example, a non-woven fabric is used between a coating roll and a press roll that are supplied with a thermally foamable foaming agent attached to the peripheral surface as in the gravure coating method. If a low density paper is introduced and wet coating is applied to the surface of the low density paper at the same time as the paper basis weight, the coating foaming agent will ooze out on the low density paper surface opposite to the coating surface. If the foaming agent adheres to the press roll or guide roll, or the adhered foaming agent adheres to the paper surface again and soils the paper surface, it may not be coated well. .
[0007]
The present invention eliminates the above disadvantages in the production of paper container molded paper laminated with a post-foaming type post-foam coated paper, and the wet-coated foaming agent adheres to a press roll, a guide roll, etc. It is to avoid fouling.
[0008]
[Means for Solving the Problems]
The invention according to claim 1 of the present invention includes a low-density paper laminating step of laminating a low-density paper 4 via a water-resistant / hydrophobic layer 3 on one side of a paper container forming base paper 1, and the low-density paper 4 side And a foaming agent coating impregnation step in which a foaming agent is coated and impregnated with the foaming agent.
[0009]
The invention according to claim 2 of the present invention includes a water-resistant / hydrophobic layer forming step of laminating and adhering the water-resistant / hydrophobic layer 3 to one surface of the low-density paper 4, and a foaming agent coating on the other surface of the low-density paper 4 And a low-density paper laminate for laminating the low-density paper 4 coated and impregnated with the foaming agent with the base paper 1 for forming a paper container through the water / hydrophobic layer 3. A process for producing a paper container-molded paper.
[0011]
The invention according to claim 3 of the present invention is the method for manufacturing a paper container-molded paper according to claim 1 or claim 2 , wherein the paper container-forming base paper 1 is a coated ball, a cup base paper, a bleached craft, This is a method for producing a paper container-molded paper, which is one of card paper and uncoated ivory.
[0012]
The invention according to claim 4 of the present invention is the method for manufacturing a paper container-molded paper according to any one of claims 1 to 3 , wherein the low density paper 4 has a paper density of 0.75 cm 3. a less, nonwoven, is a method for producing a paper container forming sheet is any one of the paper coaster original paper.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
An embodiment of a method for producing a paper container-molded paper of the present invention will be described in detail below with reference to FIG. 1. First, as shown in FIG. A paper container forming base paper 1 coated with or laminated with a synthetic resin water-resistant / hydrophobic layer 3 and a low-density paper 4 are laminated with the water-resistant / hydrophobic layer 3 on the inner surface, and a laminating press facing each other. It is introduced between the rolls 10 and 11 and laminated to form a laminated sheet comprising the paper container forming base paper 1, the water / hydrophobic layer 3 and the low density paper 4.
[0014]
Next, as shown in FIG. 1 (b), in the foaming agent coating impregnation step, the gravure rotating by immersing the laminated sheet in the foaming agent liquid 7 circulating and stored in the supply layer 12 by the gravure coating method. The surplus liquid of the foaming agent liquid 7 introduced between the coating roll 13 and the press roll 15 and attached to the rotating peripheral surface of the gravure coating roll 13 is scraped off by the doctor 14 while being applied to the peripheral surface of the roll 13. The foaming agent liquid 7 supplied into the formed multi-cell recess 13a is coated on the outer surface of the low-density paper 4 of the laminated sheet, and the layer of the low-density paper 4 is impregnated with the foaming agent.
[0015]
In addition, the coating system used in the said foaming agent coating impregnation process is not limited to a gravure coating system, Appropriate systems, such as roll coating, comma coating, knife coating, can be employ | adopted.
[0016]
As a result, as shown in FIG. 3, the foam coated paper 2 is laminated on one side of the paper container forming base paper 1 after the foaming agent is coated on the low density paper 4 through the water-resistant / hydrophobic layer 3. A paper container molded paper is obtained.
[0017]
The base paper 1 and the low-density paper 4 are formed by applying an adhesive heat-melting resin on one surface of the base paper by the extruder method to form a water-resistant / hydrophobic layer 3 and applying pressure by the extruder laminating method. It may be bonded, or a dry laminating adhesive is applied to form the water-resistant / hydrophobic layer 3 and heated and pressed to adhere by a dry laminating method, or a wet laminating adhesive is applied. Then, the water-resistant / hydrophobic layer 3 may be formed, dried under pressure (solvent volatilization), and bonded by a wet lamination method.
[0018]
As another embodiment of the method for producing a paper container-molded paper of the present invention, as shown in FIG. 2 (a), in the water / hydrophobic layer forming step, the supply layer 12 is formed by a roll coating method. The low-density paper 4 is introduced between the coating roll 16 and the press roll 17 which are immersed and rotated in the water-resistant / hydrophobic layer forming resin liquid 3a which is circulated and stored therein, and the rotating roll 16 has a peripheral surface. The water-resistant / hydrophobic layer forming resin liquid 3a attached and supplied is coated on one surface of the low-density paper 4 to form the water-resistant / hydrophobic layer 3 in a laminated manner.
[0019]
Subsequently, as shown in FIG. 2 (b), in the foaming agent impregnation step, the coating roll 18 and the press roll that rotate by being immersed in the foaming agent liquid 7 circulating and stored in the supply layer 12 by the roll coating method. The low-density paper 4 in which the water-resistant / hydrophobic layer 3 is laminated is introduced between the low-density paper 4 and the foaming agent liquid 7 adhered and supplied to the rotating roll 18 peripheral surface. Coating on the surface opposite to the hydrophobic layer 3 and impregnating the foaming agent into the layer of the low-density paper 4 to form the post-foamed coated paper 2.
[0020]
Subsequently, as shown in FIG. 2 (c), in the low density paper laminating step, the paper container forming base paper 1 and the post-foamed coated paper 2 are superposed with the water-resistant / hydrophobic layer 3 as the inner surface, It introduce | transduces between the opposition of the press rolls 10 and 11, and laminates it through the water-resistant and hydrophobic layer 3. FIG.
[0021]
As a result, as shown in FIG. 3, the foam coated paper 2 is laminated on one side of the paper container forming base paper 1 after the foaming agent is coated on the low density paper 4 through the water-resistant / hydrophobic layer 3. A paper container molded paper is obtained.
[0022]
As another embodiment of the method for producing a paper container-molded paper of the present invention, a paper container-forming base paper layer 1, a water-resistant / hydrophobic layer 3, and a low-density paper layer 4 are used in the paper making process. Are combined to make a three-layer paper.
[0023]
Next, in the foaming agent coating impregnation step, the surface of the low-density paper layer 4 of the three-layered paper is coated and impregnated with a thermal foaming foaming agent.
[0024]
As a result, as shown in FIG. 3, the foamed coated paper 2 is formed after the low-density paper 4 is coated with the thermal foaming foaming agent on one side of the paper container forming base paper 1 via the water-resistant / hydrophobic layer 3. Can be obtained.
[0025]
The water-resistant / hydrophobic layer 3 in the method of the present invention is made of a polyolefin resin such as polyethylene or polypropylene, a polyamide resin such as polyethylene terephthalate, or a thermoplastic adhesive resin such as an acrylic resin, or a dry laminate adhesive. Or a water-resistant / hydrophobic layer 3 by using a wet laminate adhesive to increase the coating amount, or a water-repellent / hydrophobic layer 3 using a water-repellent agent, and not only acting as an adhesive layer, When the heat-foaming foaming agent is coated on the outer surface side of the low-density paper 4, the heat-foaming foaming agent penetrates the low-density paper 4 and prevents it from seeping out to the inner surface side. It has the effect of preventing the heat-foaming foaming agent from reaching the surface of the container-forming base paper, and also acts as a water-resistant layer and a hydrophobic layer of the paper container.
[0026]
The paper container forming base paper 1 includes coated balls, cup base paper, uncoated ivory having a basis weight of 150 g / m 2 to 200 g / m 2 or more, which are used as base paper for forming ordinary paper containers. Any one or more of card paper and bleached craft can be used.
[0027]
Further, as the low density paper 4, a nonwoven fabric having a paper density of 0.75 g / cm 3 or less and an interlaminar peel strength of 300 gf / 15 mm width or less, or a coaster base paper can be used.
[0028]
As shown in FIG. 4, the layer of the post-foam coated paper 2 produced in the method of the present invention is formed on a low density paper 4 such as a natural fiber nonwoven fabric such as a pulp nonwoven fabric, a chemical fiber nonwoven fabric such as a rayon nonwoven fabric, or a coaster base paper. It is impregnated with a thermal expansion microcapsule 6 (or chemically reactive expansion microcapsule) and a foaming agent containing a binder such as an acrylic resin that binds the fibers 5 and the microcapsules 6 of the low-density paper 3. is there.
[0029]
The paper container-molded paper produced by the method of the present invention has a paper container-forming base paper 1 side surface on the container outer surface side and a rear foam coated paper 2 side surface on the container inner surface side. Paper such as paper boxes, paper cups, tray containers, paper pack containers, etc., by a known forming process similar to the forming process of base paper for forming paper containers such as general coated balls, cup base paper, and uncoated ivory used for forming processing The container can be molded.
[0030]
After that, the layer of the post-foamed coated paper 2 that has been molded is foamed by the heating foaming method (or the chemical reaction foaming method), so that the paper layer of the post-foamed coated paper 2 is placed in the paper layer. A large number of inflated and foamed hollow foamed portions are generated by the inflatable microcapsules 6 to obtain a heat-insulated and heat-retaining paper container in which the thickness of the post-foamed coated paper 2 is increased.
[0031]
Specific examples of the paper container molded paper of the present invention will be described below.
[0032]
<Example 1>
As shown in FIG. 1 (a), in a low density paper laminating step, a cup base paper (manufactured by Nippon Paperboard Co., Ltd.) having a basis weight of 190 g / m 2 as a paper container forming base paper 1 and a basis weight as a low density paper 4 are used. A 40 g / m 2 non-woven fabric (KP9340, manufactured by Sanwa Paper Co., Ltd.) was superposed on the inner surface of the superposed melt while extruding polyethylene resin at a thickness of 15 μm, and introduced into press rolls 10 and 11. Lamination was performed by an extruder laminating method using sand polyethylene to obtain a laminated sheet.
[0033]
Subsequently, as shown in FIG. 1 (b), in the foaming agent coating impregnation step, the laminated sheet is circulated and stored in the supply layer 12 by the gravure coating method. %)) Is introduced between the rotating gravure coating roll 13 and the press roll 15, and the surplus liquid of the foaming agent liquid 7 is supplied to the rotating gravure coating roll 13 around the rotating surface by the doctor 14. While scraping off, the foaming agent liquid 7 supplied in the many cell recesses 13a formed on the circumferential surface of the roll 13 is applied to the outer surface of the low-density paper 4 of the laminated sheet to a coating amount of 40 g / m 2 wet according to the following coating conditions. The layers of the low density paper 4 were impregnated with a foaming agent.
[0034]
Thereafter, the laminated sheet impregnated with the foaming agent was introduced into an oven dryer at 120 ° C. for 20 seconds in-line and dried to obtain a paper container-formed paper of the present invention according to Example 1.
Foaming agent;
Figure 0004114428
Coating conditions;
Figure 0004114428
[0035]
Using the paper container molding paper of the present invention prepared in Example 1 above, a paper cup is molded as a paper container by a known paper cup molding process, and the paper cup is heated in an oven at 140 ° C. for 2 minutes. Then, after the paper cup, the layer of the foam coated paper 2 was foamed to obtain a heat insulating paper cup.
Paper cup thickness: 0.3 mm before heating
1.0mm after heating
[0036]
<Example 2>
In the water-resistant / hydrophobic layer forming process, a low-density paper 4 having a basis weight of 40 g / m 2 of non-woven fabric (KP9340, manufactured by Sanwa Paper Co., Ltd.) is coated with a heat-melted polyethylene resin by an extruder method. Coating was performed while extruding at a thickness of 15 μm, and a water-resistant / hydrophobic layer 3 was laminated on one side of the low-density paper 4. (See Fig. 2 (a))
[0037]
Subsequently, as shown in FIG. 2B, in the foaming agent coating impregnation step, the low-density paper 4 formed by laminating the water-resistant / hydrophobic layer 3 is circulated and stored in the supply layer 12 by the roll coating method. The low-density foaming agent liquid 7 having the following composition is introduced between the coating roll 18 and the press roll 19 which are immersed in the foaming agent liquid 7 which rotates and adhered to the peripheral surface of the rotating roll 18. The surface opposite to the water resistant / hydrophobic layer 3 of the paper 4 was coated under the following coating conditions, and the layer of the low density paper 4 was impregnated with a foaming agent.
[0038]
Thereafter, the low-density paper 4 impregnated with a foaming agent was introduced in-line into an oven dryer at 120 ° C. for 20 seconds and dried to obtain a post-foamed coated paper 2.
Foaming agent;
Figure 0004114428
Coating conditions;
Figure 0004114428
[0039]
Subsequently, as shown in FIG. 2 (c), in the low density paper laminating step, a cup base paper (manufactured by Nippon Paperboard Co., Ltd.) having a basis weight of 190 g / m 2 as the paper container forming base paper 1 and the above post-foaming coat The paper 2 is overlapped with the water-resistant / hydrophobic layer 3 as an inner surface, and the water-resistant / hydrophobic layer 3 is introduced between the press rolls 10 and 11 while being heated and melted by a heating means. The base paper 1 and the post-foamed coated paper 2 were laminated through a water-resistant / hydrophobic layer 3 to obtain a paper container-formed paper of the present invention according to Example 2.
[0040]
Using the paper container molding paper of the present invention prepared in Example 2 above, a paper cup is molded as a paper container by a known paper cup molding process, and the paper cup is heated in an oven at 140 ° C. for 2 minutes. Then, after the paper cup, the layer of the foam coated paper 2 was foamed to obtain a heat insulating paper cup.
Paper cup thickness: 0.3 mm before heating
1.0mm after heating
[0041]
<Comparative Example 1>
The water-resistant / hydrophobic layer forming step shown in FIG. 2A of Example 2 is omitted, and one side of a nonwoven fabric (KP9340, manufactured by Sanwa Paper Co., Ltd.) having a basis weight of 40 g / m 2 as the low-density paper 4 In addition, in the foaming agent coating impregnation step shown in FIG. 2B of Example 2 above, the foaming agent liquid that circulates and stores the nonwoven fabric without the water-resistant / hydrophobic layer 3 in the supply layer 12 by the roll coating method. The foaming agent liquid 7 having the same composition as that of the second embodiment is introduced between the coating roll 18 and the press roll 19 that are immersed in the rotary 7 and opposed to each other, and is attached to the peripheral surface of the rotating roll 18. One side of the low density paper 4 was coated under the same coating conditions as in Example 2 above, and the layer of the low density paper 4 was impregnated with a foaming agent.
[0042]
Thereafter, the low-density paper 4 impregnated with the foaming agent was introduced in-line into an oven dryer at 120 ° C. for 20 seconds and dried to obtain a post-foam coated paper 2 of Comparative Example 1.
[0043]
Subsequently, as a low-density paper laminating step shown in FIG. 2C of Example 2 above, a cup base paper (manufactured by Nippon Paperboard Co., Ltd.) having a basis weight of 190 g / m 2 as the paper container forming base paper 1 and the above After the foam coated paper 2 obtained in the foaming agent coating impregnation step, a polyethylene resin that is heat-melted by an extruder method is used as a water-resistant / hydrophobic layer 3 (adhesive layer) on the inner surface of the laminated paper 15 μm thick A paper container-molded paper of Comparative Example 1 was obtained in the same manner as in Example 2 except that it was introduced and laminated between the opposing press rolls 10 and 11 while being extruded and laminated at.
[0044]
Using the paper container molding paper prepared in Comparative Example 1 above, a paper cup is molded as a paper container by a known paper cup molding process, and the paper cup is heated in an oven at 140 ° C. for 2 minutes, After the paper cup, the foamed coated paper 2 layer was foamed to obtain a heat-insulating paper cup.
Paper cup thickness: 0.3 mm before heating
1.0mm after heating
[0045]
<Comparative example 2>
A paper container is formed by a known paper cup molding process using a cup base paper (manufactured by Nippon Paperboard Co., Ltd.) having a basis weight of 190 g / m 2 which is used as a base paper for forming a paper container as a paper container forming paper. As a result, a paper cup was molded.
[0046]
The present invention products of Examples 1 and 2 (post-foaming type container-molded paper and paper cup using the same, and post-foamed paper cup), and post-foaming type container-formed paper of Comparative Example 1 and after foaming using the same Table 1 below shows the results of comparative evaluation with the normal cup base paper of Comparative Example 2. ○ ・ ・ ・ Good × ・ ・ ・ Bad [0047]
[Table 1]
Figure 0004114428
[0048]
【The invention's effect】
The method for producing a paper container-molded paper of the present invention is a method for producing a post-foam type laminated foamed paper used for molding a heat-insulating and heat-retaining paper container. It can be foamed after the forming process of paper containers such as paper cups, paper tray containers, paper pack containers, etc. In the paper container forming process, it can be molded in the same way as normal container forming base paper, and the molding processability is also good Thus, it can be molded without the generation of paper powder due to foaming, and it has the effect of eliminating wrinkles in the molding process.
[0049]
In addition, the paper container molded paper obtained by the production method of the present invention has a smooth paper surface until the foaming process after the paper container molding process, and until that time, the printability is good. Since the paper has a relatively high density unlike conventional foamed paper, there is an effect that good transport efficiency and storage efficiency as a container molding material and a semi-finished product can be obtained.
[0050]
In addition, the production method of the present invention can be produced by a laminating method and a coating method, although it is a post-foaming type foamed paper. The papermaking volume of each production lot is not increased, it can be used for small lot production, small production that is profitable is possible, the effect of turning the supply of foamed paper is effective, and the paper made with good thermal insulation performance and touch feeling It is effective as a method for producing a forming sheet for forming a container.
[Brief description of the drawings]
FIG. 1 is a side view for explaining an example of a method for producing a paper container molded paper of the present invention.
FIG. 2 is a side view for explaining another example of the method for producing a paper container molded paper of the present invention.
FIG. 3 is a cross-sectional view of a laminate of paper container molded paper obtained by the method for producing paper container molded paper of the present invention.
FIG. 4 is a schematic side cross-sectional view illustrating the inner layer structure of foam-coated paper after coating with a foaming agent by the method for producing a paper container-molded paper of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Paper container forming base paper 2 ... Post foaming coated paper 3 ... Water-resistant and hydrophobic layer 4 ... Low density paper 5 ... Pulp fiber 6 ... Foamable microcapsule 7 ... Foaming agent liquid

Claims (4)

紙製容器成形用原紙1の片面に耐水・疎水性層3を介して低密度用紙4をラミネートする低密度用紙ラミネート工程と、該低密度用紙4面に発泡剤をコーティングして含浸させる発泡剤コーティング含浸工程とからなることを特徴とする紙製容器成形用紙の製造方法。  A low density paper laminating step of laminating a low density paper 4 on one side of a paper container forming base paper 1 through a water-resistant / hydrophobic layer 3, and a foaming agent that coats and impregnates the low density paper 4 with a foaming agent A method for producing a paper container-molded paper comprising a coating impregnation step. 低密度用紙4の一面に耐水・疎水性層3を積層接着する耐水・疎水性層形成工程と、該低密度用紙4の他面に発泡剤をコーティングして含浸させる発泡剤コーティング含浸工程と、前記発泡剤をコーティングして含浸させた低密度用紙4を前記耐水・疎水性層3を介して紙製容器成形用原紙1とラミネートする低密度用紙ラミネート工程とからなることを特徴とする紙製容器成形用紙の製造方法。  A water-resistant / hydrophobic layer forming step of laminating and adhering the water-resistant / hydrophobic layer 3 to one surface of the low-density paper 4, and a foaming agent coating impregnation step of coating and impregnating a foaming agent on the other surface of the low-density paper 4; A low density paper laminating step of laminating the low density paper 4 coated with the foaming agent and impregnated with the base paper 1 for forming a paper container through the water / hydrophobic layer 3; A method for producing container-formed paper. 前記紙製容器成形用原紙1が、コートボール、カップ原紙、晒しクラフト、カード紙、ノーコートアイボリーのいずれか1種である請求項1又は請求項2記載の紙製容器成形用紙の製造方法。  The method for producing a paper container-molded paper according to claim 1 or 2, wherein the paper container-forming base paper 1 is any one of coated balls, cup base paper, bleached craft, card paper, and uncoated ivory. 前記低密度用紙4が、紙密度0.75cm 3 以下であって、不織布、コースター原紙のいずれか1種の用紙である請求項1乃至請求項3のいずれか1項記載の紙製容器成形用紙の製造方法。The low density paper 4, there is a paper density 0.75 cm 3 or less, a nonwoven fabric, paper containers according to any one of claims 1 to 3 is any one of the paper coaster original paper A method for producing molded paper.
JP2002222684A 2002-07-31 2002-07-31 Method for manufacturing paper container molded paper Expired - Fee Related JP4114428B2 (en)

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