JP4074946B2 - Base fabric provided with anti-slip resin coating and coating formation method - Google Patents
Base fabric provided with anti-slip resin coating and coating formation method Download PDFInfo
- Publication number
- JP4074946B2 JP4074946B2 JP2005301364A JP2005301364A JP4074946B2 JP 4074946 B2 JP4074946 B2 JP 4074946B2 JP 2005301364 A JP2005301364 A JP 2005301364A JP 2005301364 A JP2005301364 A JP 2005301364A JP 4074946 B2 JP4074946 B2 JP 4074946B2
- Authority
- JP
- Japan
- Prior art keywords
- slip
- resin
- layer
- slip resin
- coating film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920005989 resin Polymers 0.000 title claims description 118
- 239000011347 resin Substances 0.000 title claims description 118
- 238000000576 coating method Methods 0.000 title claims description 63
- 239000011248 coating agent Substances 0.000 title claims description 59
- 239000004744 fabric Substances 0.000 title claims description 29
- 238000000034 method Methods 0.000 title description 4
- 230000015572 biosynthetic process Effects 0.000 title 1
- 239000010410 layer Substances 0.000 claims description 101
- 239000000835 fiber Substances 0.000 claims description 69
- 239000011247 coating layer Substances 0.000 claims description 23
- 239000000758 substrate Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 230000001066 destructive effect Effects 0.000 claims 1
- 239000000463 material Substances 0.000 description 25
- 239000011148 porous material Substances 0.000 description 20
- 238000005187 foaming Methods 0.000 description 14
- 239000004745 nonwoven fabric Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 230000006378 damage Effects 0.000 description 5
- 238000004080 punching Methods 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000002649 leather substitute Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- PPWGXYXJMQAWSX-UHFFFAOYSA-N 2-methylhexa-1,3,5-triene Chemical compound CC(=C)C=CC=C PPWGXYXJMQAWSX-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 241000219492 Quercus Species 0.000 description 2
- -1 acrylate ester Chemical class 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 229920006173 natural rubber latex Polymers 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 229910000870 Weathering steel Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、防滑性の要求される品物の外面に形成される防滑性樹脂塗膜の構造に関するものである。 The present invention relates to the structure of an anti-slip resin coating film formed on the outer surface of an article requiring anti-slip properties.
従来、床面、敷物裏面、握り柄、手袋、ショルダーバック肩当て、靴底、テーブルクロス、コースター、シートカバー、電気カーペットカバー、荷崩れ防止シート、運搬作業着、パッキン、搬送ローラ等の外面に防滑性樹脂を塗布することは公知である（例えば、特許文献１、２、３、４、５、６、７、８、９、１０、１１、１２）。防滑性樹脂には、ゴムラテックス（例えば、特許文献４参照）、アクリル酸エステル・エチレンカルボン酸共重合体（例えば、特許文献５参照）、エポキシ化天然ゴムとスチレン・ビニルイソプレン・スチレン・ブロックポリマー（例えば、特許文献６参照）、エチレン酢酸ビニル共重合体、エチレン・アクリル酸メチル共重合体（例えば、特許文献８参照）、水素添加スチレン共役ジエン共重合体（例えば、特許文献１０参照）、水素添加ポリオレフィン・ポリスチレン・ブロック共重合体等（例えば、特許文献１２参照）が使用されている。防滑性樹脂の塗布される基層は、ループパイルトリコット等の有毛布帛（例えば、特許文献３、４参照）、スパンボンド不織布（例えば、特許文献８参照）、ニードルパンチ不織布（例えば、特許文献１０参照）、ネット（例えば、特許文献１１参照）等で構成されている。 Conventionally, on the outer surface of floor surface, rug back surface, grip pattern, gloves, shoulder back shoulder pad, shoe sole, table cloth, coaster, seat cover, electric carpet cover, load collapse prevention sheet, transport work clothes, packing, transport roller, etc. It is known to apply an anti-slip resin (for example, Patent Documents 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12). Examples of the anti-slip resin include rubber latex (for example, see Patent Document 4), acrylate ester / ethylene carboxylic acid copolymer (for example, see Patent Document 5), epoxidized natural rubber and styrene / vinyl isoprene / styrene / block polymer. (For example, refer to Patent Document 6), ethylene vinyl acetate copolymer, ethylene / methyl acrylate copolymer (for example, refer to Patent Document 8), hydrogenated styrene conjugated diene copolymer (for example, refer to Patent Document 10), Hydrogenated polyolefin / polystyrene / block copolymers and the like (see, for example, Patent Document 12) are used. The base layer to which the anti-slip resin is applied includes a hair fabric such as a loop pile tricot (see, for example, Patent Documents 3 and 4), a spunbond nonwoven fabric (for example, see Patent Document 8), and a needle punch nonwoven fabric (for example, Patent Document 10). Reference), a net (for example, see Patent Document 11), and the like.
本発明は、従来公知の防滑性樹脂によって形成される防滑性樹脂塗膜の防滑性能を高めることを目的とする。 An object of the present invention is to improve the anti-slip performance of an anti-slip resin coating film formed from a conventionally known anti-slip resin.
本発明に係る防滑性樹脂塗膜を備えている基布は、（ａ） 単繊維繊度５０ｄｔｅｘ以下の繊維１１によって表面が構成されており毛羽立った基層１２の表面に防滑性樹脂による塗膜層１３を積層して成り、（ｂ） その防滑性樹脂の皮膜１４に被覆された基層の表面の繊維１１が隆起し、その繊維１１によって基層１２の表面の凹凸形状に応じた凹凸形状が、塗膜層１３の表面に顕現しており、（ｃ） その防滑性樹脂が発泡した気泡１５を形成しており、（ｄ） その防滑性樹脂の気泡１５の破壊された破壊痕１６が塗膜層１３の表面に露出しており、（ｅ） その防滑性樹脂の皮膜１４の表面に防滑性樹脂によるフィルム状のスキン層が形成されていないことを第１の特徴とする。
The base fabric provided with the anti-slip resin coating film according to the present invention comprises: (a) a coating layer 13 made of an anti-slip resin on the surface of the fluffy base layer 12 whose surface is constituted by fibers 11 having a single fiber fineness of 50 dtex or less. (B) The fiber 11 on the surface of the base layer covered with the anti-slip resin film 14 is raised, and the uneven shape corresponding to the uneven shape on the surface of the base layer 12 is formed by the fiber 11. (C) the slip-proof resin forms foamed
本発明に係る防滑性樹脂塗膜を備えている基布の第２の特徴は、上記第１の特徴に加えて、防滑性樹脂の発泡倍率が２〜１５倍である点にある。 A second feature of the base fabric provided with the anti-slip resin coating film according to the present invention is that, in addition to the first feature, the foaming ratio of the anti-slip resin is 2 to 15 times.
本発明に係る防滑性樹脂塗膜を備えている基布の第３の特徴は、上記第１および第２の何れかの特徴に加えて、繊維を被覆している防滑性樹脂の皮膜の厚みが０．５ｍｍ以下である点にある。 The third feature of the base fabric provided with the anti-slip resin coating film according to the present invention is the thickness of the anti-slip resin coating film covering the fiber in addition to any of the first and second features. Is 0.5 mm or less.
本発明に係る防滑性樹脂塗膜を備えている基布の第４の特徴は、上記第１、第２および第３の何れかの特徴に加えて、毛羽立った基層１２の表面を構成している繊維１１の単繊維繊度が２０ｄｔｅｘ以下である点にある。 The fourth feature of the base fabric provided with the anti-slip resin coating film according to the present invention is that, in addition to any of the first, second and third features, the surface of the fuzzy base layer 12 is configured. The single fiber fineness of the fibers 11 is 20 dtex or less.
本発明に係る防滑性樹脂塗膜形成法は、（１） 単繊維繊度５０ｄｔｅｘ以下の繊維によって表面が構成されている毛羽立った基層の表面に防滑性樹脂を泡立てて塗布し、（２） その防滑性樹脂の未乾燥の塗布面に単繊維繊度５０ｄｔｅｘ以下の繊維によって表面が構成されている毛羽立った多孔質資材の表面を重ね合わせ、（３） それらの基層と多孔質資材の間に気泡の介在する防滑性樹脂の固化した塗膜層を形成し、それらの基層と多孔質資材を固化した防滑性樹脂の塗膜層を介して接合し、（４） その固化した塗膜層を層内剥離させて、それらの基層と多孔質資材を剥離し、それらの基層と多孔質資材の各表面に気泡の破壊された気泡痕の露出した厚みが１ｍｍ以下に防滑性樹脂塗膜を形成することを特徴とする。 The anti-slip resin coating film forming method according to the present invention comprises: (1) foaming and applying anti-slip resin on the surface of a fuzzy base layer whose surface is constituted by fibers having a single fiber fineness of 50 dtex or less; The surface of the fluffy porous material whose surface is constituted by fibers having a single fiber fineness of 50 dtex or less is superimposed on the wet coating surface of the functional resin, and (3) the inclusion of bubbles between the base layer and the porous material Forming a solidified coating layer of the anti-slip resin, bonding the base layer and the porous material through the solidified anti-slip resin coating layer, and (4) peeling the solidified coating layer into the layer The base layer and the porous material are peeled off, and a non-slip resin coating film is formed on each surface of the base layer and the porous material so that the exposed thickness of the bubble trace in which bubbles are broken is 1 mm or less. Features.
本発明によると、（ａ） 単繊維繊度５０ｄｔｅｘ以下の繊維１１によって表面が構成されている毛羽立った基層１２の表面に防滑性樹脂による塗膜層１３を積層して成り、（ｂ） その防滑性樹脂の皮膜１４に被覆された基層の表面の繊維１１が隆起し、その繊維１１によって基層１２の表面の凹凸形状に応じた凹凸形状が、塗膜層１３の表面に顕現しており、（ｃ） その防滑性樹脂が発泡した気泡１５を形成しており、（ｄ） その防滑性樹脂の気泡１５の破壊された破壊痕１６が塗膜層１３の表面に露出しており、（ｅ）
表面にスキン層が形成されていない防滑性樹脂塗膜を形成することが出来る。
According to the present invention, (a) a coating layer 13 made of an anti-slip resin is laminated on the surface of a fluffy base layer 12 whose surface is constituted by fibers 11 having a single fiber fineness of 50 dtex or less, and (b) the anti-slip property. The fiber 11 on the surface of the base layer covered with the resin film 14 is raised, and the fiber 11 reveals an uneven shape corresponding to the uneven shape on the surface of the base layer 12 on the surface of the coating layer 13. ) The
It is possible to form an anti-slip resin coating film on which no skin layer is formed.
本発明の防滑性樹脂塗膜では、防滑性樹脂の皮膜１４に被覆された基層の表面の繊維１１が隆起し、その繊維１１によって基層１２の表面の凹凸形状に応じた凹凸形状が、塗膜層１３の表面に顕現する程度に防滑性樹脂塗膜層１３が薄く、而も、防滑性樹脂が発泡しているので皮膜１４が柔らかく、その上、破壊痕１６による細かい凹凸が介在するので皮膜１４の表面積が大きいので、防滑性樹脂塗膜が被防滑品物に密着し易い。 In the anti-slip resin coating film of the present invention, the fiber 11 on the surface of the base layer covered with the anti-slip resin film 14 is raised, and the uneven shape corresponding to the uneven shape on the surface of the base layer 12 is formed by the fiber 11. The anti-slip resin coating layer 13 is so thin that it appears on the surface of the layer 13, and the anti-slip resin is foamed, so that the film 14 is soft, and in addition, fine irregularities due to the fracture marks 16 are interposed. Since the surface area of 14 is large, the anti-slip resin coating film tends to adhere to the article to be protected.
通常、基材に発泡樹脂を塗布し、そのまま固化（ゲル化）させて発泡樹脂層を形成する場合、発泡樹脂層の内部は気泡が介在する多孔質層となるが、発泡樹脂層の表面は気泡の介在しないスキン層となる。そのスキン層は、気泡が介在しないので、内部の気泡の介在する多孔質層に比して硬く強靱なフィルムとなる。しかし、本発明における皮膜１４の表面では、防滑性樹脂による硬いスキン層が形成されず、防滑性樹脂塗膜の内部と同様に気泡が介在するので、防滑性樹脂が素材として有する防滑機能を硬いスキン層に損なわれることなく発揮する。
本発明に言う「スキン層が形成されていない防滑性樹脂塗膜」とは、言わば、その塗膜の表面（皮膜１４）と内部（塗膜層１３）が、硬さ、柔らかさ、気泡の介在する度合い、その介在する気泡の大きさ等において同質であることを意味する。
そのように、本発明の防滑性樹脂塗膜（１４）は、その表面（皮膜１４）が、その内部（塗膜層１３）と同質なので、発泡した従来の防滑性樹脂塗膜に比して防滑性能が優れたものとなる。
Usually, when a foamed resin is applied to a base material and solidified (gelled) as it is to form a foamed resin layer, the inside of the foamed resin layer is a porous layer in which bubbles are interposed, but the surface of the foamed resin layer is It becomes a skin layer without bubbles. Since the skin layer does not contain air bubbles, it becomes a hard and tough film as compared with the porous layer in which internal air bubbles are present. However, on the surface of the film 14 in the present invention, a hard skin layer is not formed by the anti-slip resin, and air bubbles are present in the same manner as the inside of the anti-slip resin film, so that the anti-slip function possessed by the anti-slip resin is hard. Demonstrate without damaging the skin layer.
The “slip-proof resin coating film on which no skin layer is formed” as used in the present invention means that the surface (coating film 14) and the inside (coating film layer 13) of the coating film have hardness, softness, and bubbles. It means that the degree of interposition, the size of the intervening bubbles, and the like are the same.
Thus, since the surface (film 14) of the anti-slip resin coating film (14) of the present invention is the same quality as the inside (coating film layer 13), compared with the foamed conventional anti-slip resin coating film. Excellent anti-slip performance.
本発明による防滑性樹脂塗膜では、その基層の繊維１１が表面凹凸となって塗膜層１３の表面に顕現する程度に防滑性樹脂皮膜１４が薄く、その防滑性樹脂皮膜１４に基層の繊維１１が補強材の如く介在し、防滑性樹脂皮膜１４が細かく分布する繊維１１を個々に被覆する樹脂皮膜の集合体の如き形態を成し、その塗膜の表面（皮膜１４）と内部（塗膜層１３）との間に層内剥離する余地は殆どなく、而も、基層１２が単繊維繊度５０ｄｔｅｘ以下の繊維１１に成る多孔質層構造を成すので、防滑性樹脂の基層１２に対するアンカリング効果も大きく、皮膜１４と基層１２の間での層間剥離は考えられず、硬いスキン層の形成されている従来の防滑性樹脂塗膜のようにスキン層（皮膜１４）が剥離して耐久性が損なわれるようなこともない。 In the anti-slip resin coating film according to the present invention, the anti-slip resin film 14 is so thin that the base layer fibers 11 become surface irregularities and appear on the surface of the coating layer 13, and the base anti-slip resin film 14 has the base layer fibers. 11 is formed as a reinforcing material, and forms a resin film aggregate that individually covers the fibers 11 in which the anti-slip resin film 14 is finely distributed. The surface (film 14) and the inside (coating) There is almost no room for separation within the layer with the membrane layer 13), and since the base layer 12 has a porous layer structure consisting of fibers 11 having a single fiber fineness of 50 dtex or less, the anti-slip resin is anchored to the base layer 12 The effect is great, and delamination between the film 14 and the base layer 12 cannot be considered, and the skin layer (film 14) peels off like a conventional anti-slip resin coating film on which a hard skin layer is formed. Will not be damaged.
このように、本発明によると、可撓性に富み、防滑性と耐久性に優れた防滑性樹脂塗膜を形成することが出来る。 Thus, according to the present invention, it is possible to form an anti-slip resin coating film which is rich in flexibility and excellent in anti-slip property and durability.
防滑性樹脂には、天然ゴム・ラテックス（ＮＲ）、スチレン・ブタジエン・ラバー・ラテックス（ＳＢＲ）、メチルメタクリレート・ブタジエン・ラバー・ラテックス（ＭＢＲ）等どのゴムラテックス、アクリル酸エステル・エチレンカルボン酸共重合体エマルジョン、エポキシ化天然ゴムとスチレン・ビニルイソプレン・スチレン・ブロックポリマーエマルジョン、エチレン酢酸ビニル共重合体エマルジョン、エチレン・アクリル酸メチル共重合体エマルジョン、水素添加スチレン共役ジエン共重合体エマルジョン、水素添加ポリオレフィン・ポリスチレン・ブロック共重合体エマルジョン等の公知の防滑性樹脂を使用することが出来る。防滑性樹脂には、起泡剤（界面活性剤）、充填剤、架橋剤、ゲル化剤、安定剤、紫外線吸収剤、増粘剤等の助剤や、帯電防止剤、難燃剤、顔料、消臭剤、芳香剤等の機能性薬剤を適宜配合することが出来る。 Non-slip resin includes natural rubber latex (NR), styrene butadiene rubber latex (SBR), methyl methacrylate butadiene rubber latex (MBR) rubber latex, acrylate ester / ethylene carboxylic acid copolymer Combined emulsion, epoxidized natural rubber and styrene / vinyl isoprene / styrene block polymer emulsion, ethylene vinyl acetate copolymer emulsion, ethylene / methyl acrylate copolymer emulsion, hydrogenated styrene conjugated diene copolymer emulsion, hydrogenated polyolefin A known anti-slip resin such as a polystyrene block copolymer emulsion can be used. Anti-slip resins include foaming agents (surfactants), fillers, cross-linking agents, gelling agents, stabilizers, UV absorbers, thickeners, antistatic agents, flame retardants, pigments, Functional agents such as deodorants and fragrances can be appropriately blended.
防滑性樹脂塗膜は、床面、敷物、握り柄、手袋、ショルダーバック肩当て、靴底、テーブルクロス、コースター、シートカバー、電気カーペットカバー、荷崩れ防止シート、運搬作業着、パッキン、搬送ローラ等、防滑性の要求される品物の外面に直接積層することが出来る。防滑性樹脂塗膜は、単繊維繊度５０ｄｔｅｘ以下の繊維１１によって表面が構成されている基層１２を有する布帛や基材に積層し、それを防滑材１８として床面に置き敷きし、或いは、積み荷の間に挟み込み、或いは又、肩に当てる等して、そのまま使用することが出来る。その防滑性樹脂塗膜の積層してなる防滑材１８は、床面、敷物、握り柄、手袋、ショルダーバック肩当て、靴底、テーブルクロス、コースター、シートカバー、電気カーペットカバー、荷崩れ防止シート、運搬作業着、パッキン、搬送ローラ等に貼り合わせて使用することも出来る。
Anti-slip resin coatings are floor surface, rug, grip pattern, gloves, shoulder back, shoe sole, table cloth, coaster, seat cover, electric carpet cover, load collapse prevention sheet, transport work clothes, packing, transport roller Etc., and can be directly laminated on the outer surface of an article requiring slip resistance. The anti-slip resin coating is laminated on a fabric or substrate having a base layer 12 whose surface is constituted by fibers 11 having a single fiber fineness of 50 dtex or less, and is laid on the floor surface as an
防滑性樹脂は、ミキサーによる機械発泡、分解ガスの発生による化学発泡、防滑性樹脂に中空球体やマイクロバルーンを配合する疑似発泡の何れの方法によって発泡させてもよい。しかし、防滑性樹脂の皮膜内１４での気泡密度を上げ、皮膜内１４の表面に破壊痕１６が緻密に形成され、その破壊痕１６による凹凸によって皮膜１４の表面積を可能な限り大きくするうえでは、直径５００μｍ以下の細かい気泡１５を均一且つ緻密に発生させることが出来る機械発泡による方が望ましい。
The anti-slip resin may be foamed by any method of mechanical foaming by a mixer, chemical foaming by generation of decomposition gas, or pseudo-foaming in which a hollow sphere or a microballoon is blended with the anti-slip resin. However, in order to increase the bubble density in the film 14 of the anti-slip resin and to form the destruction marks 16 densely on the surface of the film 14, and to increase the surface area of the film 14 as much as possible by the unevenness due to the destruction marks 16. It is preferable to use mechanical foaming that can generate
スキン層のない皮膜１４を形成するためには、基層１２に塗布した防滑性樹脂の塗布面に多孔質資材を重ね合わせ、そのまま塗膜を固化（ゲル化）させ、その後、その多孔質資材を剥離するとよい。何故なら、その剥離の際に、基層１２と多孔質資材の双方に固着して一体化していた塗膜が強制的に基層１２と多孔質資材との双方に引き離されることになるので、その塗膜に層内剥離が生じ、基層１２と多孔質資材の双方に塗膜の断面としてのスキン層のない皮膜１４が形成されることになるからである。このように、本発明のスキン層が形成されていない防滑性樹脂塗膜は、スキン層が形成される余地のない状態で防滑性樹脂の塗膜（１３・１４）を固化させることによって形成される。 In order to form the film 14 without the skin layer, the porous material is superimposed on the surface of the anti-slip resin applied to the base layer 12, and the coating film is solidified (gelled) as it is. It is good to peel. This is because, during the peeling, the coating film fixed and integrated on both the base layer 12 and the porous material is forcibly separated from both the base layer 12 and the porous material. This is because in-layer peeling occurs in the film, and a film 14 having no skin layer as a section of the coating film is formed on both the base layer 12 and the porous material. Thus, the slip-resistant resin coating film in which the skin layer of the present invention is not formed is formed by solidifying the slip-resistant resin coating film (13, 14) in a state where there is no room for the skin layer to be formed. The
本発明において、「防滑性樹脂の皮膜１４に被覆された基層の表面の繊維１１が隆起し、その繊維１１によって基層１２の表面の凹凸形状に応じた凹凸形状が、塗膜層１３の表面に顕現している」、つまり、「繊維１１が防滑性樹脂皮膜１４に被覆されている状態」とは、繊維１１が皮膜１４によって完全に被覆されており、繊維１１の一部たりとも皮膜１４に被覆されずに露出している状態は含まれない。
具体的に言えば、弾性樹脂を含浸し固化した不織布等をスライスして２枚同時に製造される人工皮革の表面のように、スライスされた繊維の切断面が表面に露出している状態は、本発明に言う「繊維が防滑性樹脂皮膜に被覆されている状態」には該当しない。
本発明が、繊維の切断面が露出している状態を排除する理由は、繊維の切断面が露出している状態では、その露出している繊維の切断面が防滑性樹脂の防滑機能を阻害し、その繊維の切断面が露出している分だけ、防滑性樹脂塗膜層（１３）の表面（皮膜１４）において、防滑性樹脂の防滑機能の発揮されるべき余地が狭められることになるためである。
In the present invention, “the fibers 11 on the surface of the base layer coated with the anti-slip resin film 14 are raised, and the uneven shape on the surface of the base layer 12 is formed on the surface of the coating layer 13 by the fibers 11. “Appearance”, that is, “the state where the fiber 11 is covered with the anti-slip resin film 14” means that the fiber 11 is completely covered with the film 14, and part of the fiber 11 is covered with the film 14. The state exposed without being covered is not included.
Specifically, the state where the cut surface of the sliced fiber is exposed on the surface, such as the surface of artificial leather that is manufactured by slicing a nonwoven fabric impregnated and solidified with an elastic resin, This does not correspond to the “state where the fiber is covered with the anti-slip resin film” in the present invention.
The reason why the present invention excludes the state in which the cut surface of the fiber is exposed is that, when the cut surface of the fiber is exposed, the exposed cut surface of the fiber inhibits the anti-slip function of the anti-slip resin. In addition, the extent to which the anti-slip function of the anti-slip resin is to be exerted on the surface (coating 14) of the anti-slip resin coating layer (13) is narrowed as much as the cut surface of the fiber is exposed. Because.
本発明において、防滑性樹脂塗膜に気泡１５を介在させる理由は、その塗膜の表面に破壊された痕跡として露出する気泡の破壊痕１５の窪みの周囲に細かい凹凸が形成され、その凹凸が形成された分だけ皮膜１４の表面積が大きくなるためであり、又、防滑性樹脂の塗布面に重ね合わせた多孔質資材を剥離するとき、基層１２と多孔質資材の間で固化した塗膜（１３・１４）が層内剥離し易くするためでもある。
その防滑性樹脂の塗布面に重ね合わせた多孔質資材を剥離するとき、壁面下地に全面接着して施工された壁紙を剥離する場合に壁面下地に接着剤の塗膜が部分的に残る糊落ちのように、塗膜（１３・１４）が或る部分では基層１２に厚く残り他の部分では薄く残って塗膜（１３・１４）の厚みが不均一になるようなことがなく、防滑性樹脂の皮膜１４に被覆された基層の表面の繊維１１が隆起し、その繊維１１によって基層１２の表面の凹凸形状に応じた凹凸形状が、塗膜層１３の表面に顕現するようにするためには、基層１２と多孔質資材の間に塗布積層される防滑性樹脂の塗布厚みを２ｍｍ以下に、好ましくは１ｍｍ前後にし、層内剥離して現れる防滑性樹脂の皮膜１４の厚みが０．５ｍｍ以下になるようにするとよい。
In the present invention, the reason why the
When peeling the porous material superimposed on the application surface of the anti-slip resin, the adhesive film partially remains on the wall surface when peeling the wallpaper that is adhered to the entire wall surface. As described above, the coating film (13, 14) is thick on the base layer 12 in a certain part and remains thin in the other part, and the thickness of the coating film (13, 14) does not become non-uniform, and is anti-slip. In order for the fibers 11 on the surface of the base layer covered with the resin film 14 to be raised, and for the fibers 11 to have an uneven shape corresponding to the uneven shape on the surface of the base layer 12 manifested on the surface of the coating layer 13 The coating thickness of the anti-slip resin applied and laminated between the base layer 12 and the porous material is 2 mm or less, preferably around 1 mm, and the thickness of the anti-slip resin film 14 that appears by peeling off in the layer is 0.5 mm. It should be as follows.
防滑性樹脂の発泡倍率は２〜１５倍に、好ましくは４〜１２倍にする。そのように防滑性樹脂の発泡倍率を２〜１５倍とするのは、その発泡倍率が２倍未満の場合は塗膜（１３・１４）が強靱になり、重ね合わせた基層１２と多孔質資材の間で塗膜が層内剥離を起こし難くなるためであり、それとは逆に、その発泡倍率が１５倍を超える場合には層内剥離して現れる防滑性樹脂の皮膜１４の厚みにバラツキが生じるからである。 The foaming ratio of the anti-slip resin is 2 to 15 times, preferably 4 to 12 times. The reason why the foaming ratio of the anti-slip resin is 2 to 15 times is that when the foaming ratio is less than 2 times, the coating film (13, 14) becomes tough and the laminated base layer 12 and porous material On the other hand, when the foaming ratio exceeds 15 times, the coating film 14 of the antislip resin that appears by peeling off within the layer has a variation in thickness. Because it occurs.
そのように、スキン層のない防滑性樹脂皮膜１４を形成するために防滑性樹脂の塗布面に重ね合わせて適用される多孔質資材は、基層１２と多孔質資材の間で塗膜（１３・１４）の層内剥離を促すものであるから、多孔質資材には、防滑性樹脂に対して基層１２と同程度の接着性を有するものが適用される。
従って、好ましい多孔質資材は、基層１２と同様に単繊維繊度５０ｄｔｅｘ以下の繊維１１によって表面が構成されている資材である。つまり、互いに一方が他方の多孔質資材として作用するように、２つの基層（１２・１２）を防滑性樹脂によって貼り合わせ、その２つの基層（１２・１２）の間に挟まれて固化した塗膜（１３・１４）を、その２つの基層（１２・１２）の間で層内剥離させる訳である。例えば、敷物では、その裏面に防滑性樹脂を塗布し、その塗布面にもう１枚の敷物の裏面を重ね合わせ、防滑性樹脂の固化後、それら２枚の敷物を剥離し、その各敷物の裏面に防滑性樹脂塗膜層１２を積層することが出来る。手袋では、左右何れか一方の手袋の掌面に防滑性樹脂を転写塗布し、その塗布面に他の片側の手袋の掌面を重ね合わせ、防滑性樹脂の固化後、それら左右一番の手袋を剥離し、左右一番を成す各手袋の掌面に防滑性樹脂塗膜層１２を積層することが出来る。
As described above, the porous material to be applied in an overlapping manner on the application surface of the anti-slip resin in order to form the anti-slip resin film 14 having no skin layer is formed between the base layer 12 and the porous material. 14) which promotes in-layer peeling, a porous material having the same degree of adhesiveness as the base layer 12 is applied to the anti-slip resin.
Therefore, a preferable porous material is a material whose surface is constituted by the fibers 11 having a single fiber fineness of 50 dtex or less, like the base layer 12. In other words, the two base layers (12, 12) are bonded together with an anti-slip resin so that one of them functions as the other porous material, and is solidified by being sandwiched between the two base layers (12, 12). The film (13, 14) is peeled in-layer between the two base layers (12, 12). For example, in a rug, an anti-slip resin is applied to the back surface of the rug, and the back surface of another rug is overlaid on the coated surface. After the anti-slip resin is solidified, the two rugs are peeled off, An anti-slip resin coating layer 12 can be laminated on the back surface. For gloves, transfer and apply anti-slip resin to the palm surface of one of the left and right gloves, overlay the palm surface of the other glove on the applied surface, and solidify the anti-slip resin, then the left and right gloves The anti-slip resin coating layer 12 can be laminated on the palm surface of each glove that forms the left and right most.
そのように、一方が他方の多孔質資材として作用するように２つの基層（１２・１２）を貼り合わせる場合は、その剥離後に、その２つの何れの基層（１２・１２）も、防滑性樹脂塗膜層１３・１３を構成することになり、その何れの基層（１２・１２）も産業廃棄物として廃棄されることがないので経済的であり、又、２つの防滑材１８・１８を同時に得られることになるので、防滑材１８の生産効率が２倍にアップすることにもなる。
Thus, when two base layers (12, 12) are bonded together so that one of them acts as the other porous material, after the peeling, any of the two base layers (12, 12) is anti-slip resin. The coating layers 13 and 13 will be constituted, and any of the base layers (12 and 12) will not be discarded as industrial waste, and it is economical. As a result, the production efficiency of the
基層には、単繊維繊度５０ｄｔｅｘ以下の繊維によって構成される紙、不織布、織布、編布等の紙や布帛を使用することが出来る。その基層となる紙や布帛は、床面、敷物、握り柄、手袋、ショルダーバック肩当て、靴底、テーブルクロス、コースター、シートカバー、電気カーペットカバー、荷崩れ防止シート、運搬作業着、パッキン、搬送ローラ等、防滑性の要求される品物としての形態を成すものでもよい。
表裏が単繊維繊度５０ｄｔｅｘの繊維によって構成される紙や布帛では、その表裏両面に防滑性樹脂塗膜層（１３ａ・１３ｂ）を形成し、積荷の間に挟み込んで使用される荷崩れ防止シートや、床面とマットの間に挟み込んで使用されるマットズレ防止下敷シート等のように、両面防滑材として使用することも出来る。その両面防滑材を構成する表裏の基層（１２ａ・１２ｂ）の間には、補強材や防水材、吸音材、クッション材等の中間層１７を積層することも出来る。
For the base layer, paper or fabric such as paper, non-woven fabric, woven fabric, knitted fabric or the like composed of fibers having a single fiber fineness of 50 dtex or less can be used. The base layer of paper and fabric is floor, rug, grip pattern, gloves, shoulder back shoulder rest, shoe sole, table cloth, coaster, seat cover, electric carpet cover, load collapse prevention sheet, transport work clothes, packing, It may be in the form of an article requiring slip resistance, such as a transport roller.
For paper and fabric that are composed of fibers with a single fiber fineness of 50 dtex, anti-slip resin coating layers (13a and 13b) are formed on both front and back surfaces, and a load collapse prevention sheet that is sandwiched between loads and used. Moreover, it can also be used as a double-sided anti-slip material such as a mat slip prevention underlay sheet used by being sandwiched between a floor surface and a mat. Between the front and back base layers (12a and 12b) constituting the double-sided anti-slip material, an intermediate layer 17 such as a reinforcing material, a waterproof material, a sound absorbing material, or a cushion material can be laminated.
好ましい基層１２は、表面が毛羽立ったステッチボンド、スパンボンド、ニードルパンチフエルト、繊維ウエブ等の不織布、静電植毛布帛、フエルト、起毛布帛、シェニール織物、モケット、別珍、コール天等の織パイル布帛、トリコットやダブルラッシェル等の編パイル布帛等の表面立毛層と裏面基布層との二層構造を成す多層布帛等の有毛布帛、表面が毛羽立った短繊維紡績糸を織編込んで成る織編である。その表面の単繊維繊度を５０ｄｔｅｘ以下とするのは防滑性樹脂との接着性を確保し、防滑性樹脂と基層１２とのアンカリング効果を高めるためである。そのためには、単繊維繊度５０ｄｔｅｘ以下の繊維１１によって表面が構成されている基層１２の表面を構成する繊維１１の単繊維繊度を２０ｄｔｅｘ以下に、好ましくは５ｄｔｅｘ以下にする。
単繊維繊度が５ｄｔｅｘ以下、更には１ｄｔｅｘ以下の極細繊維に成る布帛を基層１２として防滑性樹脂塗膜層１３を形成した防滑材（１８）は、人工皮革や合成皮革の一種として椅子張り地や壁張り地等の内装材や衣料生地等に使用することも出来る。
Preferable base layer 12 is a nonwoven fabric such as stitch bond, spun bond, needle punch felt, fiber web, etc. having a fluffy surface, electrostatic flocked fabric, felt, raised fabric, chenille fabric, moquette, benji, woven pile fabric such as corten, Woven knitted fabric made by weaving and weaving short-fiber spun yarn with a fluffy surface, such as a multi-layered fabric such as a multi-layer structure of a surface raised layer such as a knitted pile fabric such as tricot or double raschel and a back base fabric layer It is. The reason why the single fiber fineness of the surface is 50 dtex or less is to secure adhesiveness with the anti-slip resin and to enhance the anchoring effect between the anti-slip resin and the base layer 12. For this purpose, the single fiber fineness of the fibers 11 constituting the surface of the base layer 12 whose surface is constituted by the fibers 11 having a single fiber fineness of 50 dtex or less is set to 20 dtex or less, preferably 5 dtex or less.
An anti-slip material (18) in which an anti-slip resin coating layer 13 is formed using a fabric made of ultrafine fibers having a single fiber fineness of 5 dtex or less, and further 1 dtex or less, as a kind of artificial leather or synthetic leather, It can also be used for interior materials such as wall coverings and clothing fabrics.
［実施例］
樹脂固形分含有率を５２重量％に調整したメチルメタクリレート・ブタジエン・ラバー・ラテックス（ＭＢＲ）に、表１に示す通り、架橋剤３ＰＨＲ（樹脂分１００重量部に対する配合量が３重量部を意味する。以下、同じ）、界面活性剤６ＰＨＲ、充填剤１００〜２００ＰＨＲを配合し、水を加えて粘度を調整した３種類の防滑性樹脂組成物（実施例１〜３）を、それぞれオークスミキサーにて発泡倍率５〜１０倍に泡立て、それぞれ単繊維繊度８ｄｔｅｘのポリエステル繊維に成る目付３６０ｇ／ｍ2 のニードルパンチング不織布（下側基層１２Ｂ）に塗布厚を１ｍｍに設定してドクターコート法によって塗布し、塗膜質量が約１００ｇ／ｍ2 の塗膜（１３）を積層し、それらの塗布面にそれぞれ単繊維繊度８ｄｔｅｘのポリエステル繊維に成る目付１２０ｇ／ｍ2 のニードルパンチング不織布（上側基層１２Ａ）を重ね合わせ、塗膜（１３）がゲル化（固化）した冷却後に、上下のニードルパンチング不織布（上側基層１２Ａと下側基層１２Ｂ）を剥離して塗膜（１３）を層内剥離させ、表面に防滑性樹脂皮膜１４の積層された上側の防滑材（１８Ａ）と下側の防滑材（１８Ｂ）との２枚１組の防滑材をそれぞれ同時に作成した。
[Example]
As shown in Table 1, cross-linking agent 3PHR (mixing amount with respect to 100 parts by weight of resin means 3 parts by weight) in methyl methacrylate / butadiene / rubber latex (MBR) with the resin solids content adjusted to 52% by weight. The same applies hereinafter), surfactant 6PHR, filler 100 to 200PHR, and three types of anti-slip resin compositions (Examples 1 to 3) adjusted for viscosity by adding water, respectively, in an Oaks mixer Foaming at a foaming ratio of 5 to 10 times, each applied to a needle punching nonwoven fabric (lower base layer 12B) having a basis weight of 360 g / m 2 and made of polyester fiber having a single fiber fineness of 8 dtex, and applied by a doctor coating method. A coating film (13) having a coating film mass of about 100 g / m 2 is laminated, and a polyester fiber having a single fiber fineness of 8 dtex is applied on each coated surface. After the needle punching nonwoven fabric (upper base layer 12A) having a basis weight of 120 g / m 2 is superposed and the coating film (13) is gelled (solidified) and cooled, the upper and lower needle punching nonwoven fabrics (upper base layer 12A and lower base layer 12B) And the coating film (13) is peeled off in the layer, and a set of two anti-slip materials consisting of an upper anti-slip material (18A) and a lower anti-slip material (18B) having an anti-slip resin film 14 laminated on the surface. Each material was made simultaneously.
［比較例］
樹脂固形分含有率５２重量％のメチルメタクリレート・ブタジエン・ラバー・ラテックス（ＭＢＲ）に架橋剤３ＰＨＲと界面活性剤６ＰＨＲを配合し、水を加えて粘度を調整した防滑性樹脂組成物をオークスミキサーにて発泡倍率１０倍に泡立て、単繊維繊度８ｄｔｅｘのポリエステル繊維に成る目付３６０ｇ／ｍ2 のニードルパンチング不織布（基層）に塗布厚を１ｍｍに設定してドクターコート法によって塗布して防滑材を作成した。
[Comparative example]
Blending 3PHR and surfactant 6PHR with methyl methacrylate / butadiene / rubber latex (MBR) with a resin solids content of 52% by weight and adding water to adjust the viscosity to an Oaks mixer An anti-slip material was prepared by foaming at a foaming ratio of 10 times and applying a doctor punching method to a needle punching nonwoven fabric (base layer) having a basis weight of 360 g / m 2 made of polyester fiber having a single fiber fineness of 8 dtex and applying the doctor coating method. .
［防滑効果試験］
実施例と比較例の防滑材の塗膜とは反対側となる面にそれぞれ厚紙を貼り、サイズが３０ｃｍ×３０ｃｍの正方形の試験片を切り取り、それらの各試験片をアルコールで洗浄して水平に支持したガラス板に塗膜を向けて載置し、それらの各試験片にサイズが３０ｃｍ×３０ｃｍで質量が３２０ｇの正方形のアクリル板を載せ、そのアクリル板に重り（２００ｇ，６００ｇ，１０００ｇ）を載せ、それらの各試験片をプッシュブルゲージで水平に引っ張り、試験片が摺動し始めた時点での張力を測定し、その摺動開始時点の張力によって試験片（防滑性樹脂塗膜）の防滑性を比較し、表１に示す結果を得た。
[Anti-slip effect test]
A cardboard is pasted on the surface opposite to the anti-slip coating film of the example and the comparative example, respectively, a square test piece having a size of 30 cm × 30 cm is cut out, each of the test pieces is washed with alcohol, and horizontally. Place the coated film on the supported glass plate and place a square acrylic plate with a size of 30cm x 30cm and a mass of 320g on each test piece, and weights (200g, 600g, 1000g) on the acrylic plate. Place each test piece horizontally with a push bull gauge, measure the tension when the test piece starts to slide, and measure the tension of the test piece (anti-slip resin coating) by the tension at the start of sliding. The anti-slip properties were compared, and the results shown in Table 1 were obtained.
［考察］
表１の実施例と比較例のデータが示す通り、本発明（実施例）によると、従来（比較例）の防滑材に比して防滑性能が約３倍高い防滑材に得られ、その防滑性能が防滑性樹脂組成物に配合された充填剤の配合量によって格別左右されることなく、その充填剤の配合量に応じて防滑性樹脂組成物のコストダウンを図ることが出来る。又、上側基層と下側基層とに防滑性樹脂組成物の塗膜が二分されるので防滑材の１枚当りの防滑性樹脂組成物の使用量も実質的に半減する。更に、防滑材を上下２枚１組にして同時に製造することが出来るので、防滑材の製造コストも半減する。このように、本発明によると、防滑性能に優れた防滑材を経済的且つ効率的に得ることが出来る。
[Discussion]
As shown in the data of Examples and Comparative Examples in Table 1, according to the present invention (Example), the anti-slip material having anti-slip performance approximately three times higher than that of the conventional (Comparative Example) anti-slip material is obtained. The performance of the anti-slip resin composition can be reduced according to the amount of the filler without depending on the amount of the filler added to the anti-slip resin composition. In addition, since the coating film of the anti-slip resin composition is divided into the upper base layer and the lower base layer, the amount of the anti-slip resin composition used per anti-slip material is substantially halved. Furthermore, since the anti-slip material can be manufactured simultaneously as a set of two upper and lower anti-slip materials, the manufacturing cost of the anti-slip material is also halved. Thus, according to the present invention, an anti-slip material excellent in anti-slip performance can be obtained economically and efficiently.
１１：繊維
１２：基層
１３：塗膜層
１４：皮膜
１５：気泡
１６：破壊痕
１７：中間層
１８：防滑材
11: Fiber 12: Base layer 13: Coating layer 14: Coating 15: Bubble 16: Destruction mark 17: Intermediate layer 18: Anti-slip material
Claims (4)
（ｂ） その防滑性樹脂塗膜に被覆された基層の表面の単繊維繊度５０ｄｔｅｘ以下の繊維が隆起し、その繊維によって基層の表面の凹凸形状に応じた凹凸形状が塗膜層の表面に顕現しており、且つ、その繊維が介在して防滑性樹脂塗膜が補強されており、
（ｃ） 防滑性樹脂が発泡した気泡を形成しており、
（ｄ） 防滑性樹脂の気泡の破壊された破壊痕が塗膜層の表面に露出しており、
（ｅ） 防滑性樹脂塗膜の表面に防滑性樹脂によるスキン層が形成されていない防滑性樹脂塗膜を備えている基布。 (A) is configured surface by a single fiber fineness 50dtex following fibers coated bubbled slip resistant resin on the surface of the substrate stood fluff, its slip resistant resin undried coating surface to single fiber fineness 50dtex following The surfaces of other fuzzy base layers whose surfaces are constituted by fibers are overlapped to form a solid coating film of an anti-slip resin in which bubbles are interposed between the two base layers, and the two base layers are solidified. Joined via a coating layer of anti-slip resin, formed by peeling the solidified coating layer in-layer and peeling the two base layers, the exposed thickness of the bubble traces where the bubbles were destroyed is 1 mm or less Of non-slip resin coatings,
(B) manifest on the surface of the slip resistant resin coating film single fiber fineness 50dtex following fibers coated substrate surface is raised, irregularities coating layer corresponding to the uneven shape of the surface of the substrate by the fiber And the anti-slip resin coating is reinforced with the intervening fibers,
(C) Anti-slip resin forms foamed bubbles,
(D) Destructive traces in which bubbles of the anti-slip resin are broken are exposed on the surface of the coating layer,
(E) slip resistant resin coating film base fabric has a non-slip resin coating film skin layer is not formed by slip resistant resin on the surface of the.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005301364A JP4074946B2 (en) | 2005-10-17 | 2005-10-17 | Base fabric provided with anti-slip resin coating and coating formation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005301364A JP4074946B2 (en) | 2005-10-17 | 2005-10-17 | Base fabric provided with anti-slip resin coating and coating formation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007106068A JP2007106068A (en) | 2007-04-26 |
| JP4074946B2 true JP4074946B2 (en) | 2008-04-16 |
Family
ID=38032305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005301364A Active JP4074946B2 (en) | 2005-10-17 | 2005-10-17 | Base fabric provided with anti-slip resin coating and coating formation method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4074946B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017023675A (en) * | 2015-07-19 | 2017-02-02 | まさみ 黒田 | Load carriage auxiliary tool |
| KR102358077B1 (en) * | 2021-06-24 | 2022-02-08 | 박병기 | A nonslip film adhesion composite sheet for a gabled roof and for a flat roof top floor |
-
2005
- 2005-10-17 JP JP2005301364A patent/JP4074946B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007106068A (en) | 2007-04-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20060183389A1 (en) | Fabric-faced composites and methods for making same | |
| JP2001501682A (en) | Decorative composite floor covering | |
| JP2000505845A (en) | Decorative composite floor covering | |
| US20120121849A1 (en) | Automobile use mat with a distinguished anti-slip feature | |
| JP2008162399A (en) | Sound absorbing laying type car mat | |
| US20130089718A1 (en) | Cut-to-size format | |
| US20130065043A1 (en) | Cushioned foam mat with porous backing | |
| JP6093961B2 (en) | Floor structure and underlay sheet | |
| US10337141B2 (en) | Textile floor-covering with liquid blocking surface | |
| TW415983B (en) | Modified secondary backing fabric, method for the manufacture thereof and carpet containing the same | |
| JP5707610B2 (en) | Decorative flooring and floor structure | |
| JP4074946B2 (en) | Base fabric provided with anti-slip resin coating and coating formation method | |
| JP2005256527A (en) | Laying type tile carpet | |
| JP2018104981A (en) | Laminated tatami surface and tatami using thereof | |
| JP6369846B2 (en) | Rug cushion material | |
| KR20140003667U (en) | Non woven fabric flooring | |
| JP4601749B2 (en) | Tufted products | |
| US20090191382A1 (en) | Floor mat and process for manufacturing same | |
| JP2008188202A (en) | Waterproof and gas permeable carpet | |
| JP5650930B2 (en) | Carpet and manufacturing method thereof | |
| JPS61119780A (en) | Tile carpet | |
| JP2000297944A (en) | Skin material for electric heating carpet and electric heating carpet | |
| JP3543136B2 (en) | carpet | |
| JPH10155633A (en) | Carpet | |
| RU2781447C1 (en) | Anti-slip underlay |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20070823 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070925 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070926 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20071106 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20071113 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20071218 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20080115 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4074946 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110208 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120208 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130208 Year of fee payment: 5 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130208 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140208 Year of fee payment: 6 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |